The invention relates to a device for deflecting electromagnetic, particularly solar and/or thermal radiation, according to claim 1.
Solar reactor systems generally comprise a solar concentrator that is designed to collect and concentrate solar radiation and to provide said radiation as an energy source for driving various processes. Such processes for example comprise chemical reactions or physical processes the latter for example driving a motor or a turbine. Solar reactor systems designed for driving the H2O/CO2-splitting thermochemical redox cycle using concentrated solar radiation are of particular interest.
Such splitting reactions for example comprise a two-step process that is given by a first endothermic step comprising a solar-driven thermal reduction of a metal oxide that requires thermal energy for being reduced to a metal or a lower valence metal oxide and a second, non-solar step that is exothermic that comprises the oxidation reaction of the reduced lower valence metal oxide with water or carbon dioxide to the higher valence metal oxide and hydrogen or carbon monoxide:
2 MOox→2 MOred+O2 1st step, reduction:
MOred+H2O→MOox+H2 or
MOred+CO2→MOox+CO 2nd step, oxidation:
The use of solar reactor systems provides a sustainable way for energy conversion. However, as can be seen for example from the above equations, a two-step process that particularly requires a cooling period (for example the 2nd step), would need interruption of the solar radiation exposure. On the other hand, solar radiation is not permanently available as weather conditions might change or it is interrupted by the day-night circle. It might be economically disadvantageous to interrupt (and thus discard) solar radiation exposure of the process, when weather conditions are favorable, i.e. sunny. In order to circumvent this problem, reactor systems comprising two reaction chambers have been designed in order to alternately provide solar radiation to one of the two chambers. These reactor systems offer the possibility of moving the two cavities such that each cavity's aperture is alternately centered at the focal plane of the solar concentrator. Alternatively the concentrator is moved in order to shift the focal plane relative to a fixed cavity. Both solutions are deemed unpractical due to complications that might arise by moving high-temperature reactors or by moving the solar concentrating system.
One solution to this problem is to provide a secondary optical element that is rotatably arranged in a solar reactor such that it can be rotated between two positions, wherein in each position the solar radiation from the solar concentrator is guided in one of the reaction chambers, leading to an alternating distribution of the solar radiation to the reaction chambers. Such secondary optical element, subsequently termed solar deflection device, has the advantage that it is comparably more cost-effective and more robust than moving solar reactors or moving concentrators.
Such a deflection device—by design—has a nominal half acceptance angle that describes the highest angle under which radiation incident on the deflection device is still guided through the device and is not rejected.
As the incident solar radiation from the solar concentrator is not collimated, reflections inside of such a deflection device are leading to energy losses. Several designs of deflection devices are known, such as a funnel being a torus segment (a so-called toroidal angle rotator) as suggested by [1], but suffer from various disadvantages, most importantly a high number of reflections.
Therefore, the problem underlying the present invention is to provide a solar deflection device particularly for a solar reactor system, allowing solar radiation to be guided with minimal losses at a given angular acceptance angle, and at the same time providing additional concentration.
Such a deflection device is particularly used as a secondary optical arrangement that is incorporated into a solar reactor system in tandem with a solar concentrator.
The problem according the invention is solved by a device having the features of claim 1. Preferred embodiments are stated in the sub claims.
According to the present invention, a solar deflection device comprises at least the following components:
Electromagnetic radiation in this context refers particularly to solar and/or thermal radiation.
The reflective surface particularly reflects electromagnetic radiation from solar or thermal radiation sources, particularly in a wavelength range that covers the ultra-violet, visible, near-infrared, and/or infrared portion of the electromagnetic spectrum. In order to maximize the collection efficiency, the reflective surface material is particularly reflective from 280 nm to 4000 nm, as this is particularly the range used for the ASTM (American Society for Testing and Materials) Air Mass 1.5 Direct Solar Spectrum specification that for example provides terrestrial reference spectra for photovoltaic performance evaluation.
Furthermore the reflective surface has particularly predominantly specular reflectivity properties, wherein particularly a small fraction of small angle scattering and diffuse reflection is permissible. The term specular reflectivity particularly refers to a mirror-like reflection that stands in contrast to diffuse reflection.
In a preferred embodiment the reflective surface wall has a reflectivity that is larger than 60%, particularly larger than 90%, more particularly larger than 95% particularly within a design wavelength range or within regions of the design wavelength range.
For example pure aluminium has a reflectance above 85% across the range 200 nm to 4000 nm; pure silver has a reflectance above 90% from 500 nm to 4000 nm.
It is particularly advantageous that the material used for reflection of radiation comprises a large total reflectance over that wavelength range, i.e. a high spectral power weighted average.
As the solar deflection device comprises a funnel, said funnel particularly comprises a rim at the inlet and exit aperture respectively. It is noted that said rim might not be planar (i.e. lies within a plane) but can exhibit various shapes. In one embodiment of the invention the rim at the exit aperture particularly encloses an opening that follows a line along the surface of a cone. Said cone-shaped rim is particularly necessary to allow for rotation in a solar reactor system.
In most practical cases where the solar deflection device is intended to rotate, the rim of the exit aperture will therefore particularly be defined as the area enclosed by a closed curve traced on a cone, wherein the exit aperture nonetheless is comprised in an exit plane.
The curved line is of virtual nature. Furthermore the curved line particularly comprises short sections that are straight. These sections particularly add up to less than 20%, particularly less than 10% of the total length of the curved line. In one embodiment said curved line does not exhibit a change of the sign of the curvature, i.e. the curve does particularly not comprise a point of inflection or a point where the curvature is zero.
The above mentioned center of an area, particularly the area of the inlet and exit aperture, is particularly given by the center of area.
The term “perpendicularly” refers to a 90° angle enclosed between a tangent of the curved line at a point of contact or intersection with a respective plane. Such planes are for example the inlet plane, the exit plane or the plane of the cross-section.
The solar deflection device particularly has the advantage that it can be used for particularly secondary solar concentration and that it might be designed for a maximum optical efficiency of the solar deflection device, which is a compromise between number of reflections and ray-rejection. For example a long slender design has lower rejection but more reflections; a short design has higher rejection but less reflections. The optimal design depends on the reflectance of the surface as this dictates how much energy is lost per reflection.
In preferred embodiment of the invention, the area enclosed by the inlet aperture, the exit aperture and/or the cross-section has/have an oval, particularly a circular shape or elliptical shape.
Thus, particularly the inlet and exit aperture might comprise different shapes, such that they particularly are suitable for various inlet and/or exit geometries of particularly solar reactor systems. Particularly intermediate cross-sectional shapes of the solar deflection device can for example be derived by a so-called lofting process.
In another embodiment of the invention at preferably each point of the curved line, the curved line has a curvature that is other, particularly larger than zero. Thus, the solar deflection device exhibits particularly a shape that is curved along one direction, preferably without being sinuous. This geometry particularly is ensuring a low number of reflections with the funnel of the solar deflection device.
According to another embodiment of the invention, said curved line is an arc, particularly a circular arc line or a non-parabolic line that in case of a circular shape particularly has a center in a common origin of a Cartesian coordinate system.
In some cases it might be advantageous if the curved line has a parabolic shape.
According to a preferred embodiment of the invention, the aperture area of the inlet aperture is larger than the aperture area of the exit aperture, such that the solar deflection device exhibits particularly a tapered funnel. This embodiment is particularly advantageous as such a solar deflection device might further concentrate incident electromagnetic radiation while simultaneously redirecting said radiation along a predefined direction.
In another embodiment of the invention, the size of the enclosed area of the cross-section, particularly the diameter of the cross-section is a continuous function of said deflection angle. Particularly if the cross-section has a circular shape, said function is a continuous function of the diameter or radius of the cross-section and the deflection angle. This is an advantageous way to particularly parametrize the shape of the reflective surface of the solar deflection device with a single parameter, namely with the deflection angle.
In another preferred embodiment of the invention, the function is continuously differentiable at least once, particularly twice, more particularly three times. This allows particularly for a smooth shape of the reflective surface of the funnel, which in turn is advantageous to keep losses due to transmission of the electromagnetic radiation through the funnel at a minimum.
In a variation of the invention, the function is a monotonic function, particularly a strictly monotonic function. This in turn particularly allows for a tapered shape of the reflective surface of the funnel, such that particularly a concentration of the incident electromagnetic radiation is achievable.
In another embodiment of the invention, the function is an interpolating function, comprising the area, particularly the diameter or the radius, of the inlet aperture and the area, particularly the diameter or the radius of the exit aperture as interpolation points. This embodiment is advantageous as only a few interpolations points are required particularly in order to fully describe the reflective surface of the funnel.
In another embodiment of the invention the function comprises a spline, particularly a linear, a quadratic or a cubic, particularly a natural cubic spline. Spline functions are a specific form of interpolation functions. Depending on the number of interpolation points different kinds of splines might be used as interpolation function.
A spline is a function that is particularly piecewise-defined by polynomial functions. A spline particularly possesses a sufficiently high degree of smoothness at the places where the polynomial pieces connect. These places are called interpolation points or knots.
A spline is an advantageous interpolating function that is comparably easy to handle computationally (as compared to e.g. polynomial interpolants).
In another embodiment of the invention the function comprises or is a piecewise particularly natural cubic spline connecting a plurality of interpolation points, wherein particularly the size of the enclosed area, particularly the diameter or radius of the inlet aperture and the size of the enclosed area, particularly the diameter or the radius of the exit aperture are two of the plurality of interpolation points and wherein particularly a third interpolation point corresponds to the size of the enclosed area, particularly to the diameter or radius of the cross-section of the reflective surface of the funnel wall that lies in a plane that is particularly perpendicular to the curved line between the inlet plane and the exit plane.
Particularly due to the high degree of smoothness, the cubic spline is a preferred interpolation function.
In order to maximize the transfer efficiency of the solar deflection device, that is to minimize reflective losses of the electromagnetic radiation within the funnel and keep ray rejection low, particularly the position of the third interpolation point corresponding to the area of the cross-section can be tailored by e.g. ray-tracing simulations. Furthermore optimization of transfer efficiency might be achieved also by varying the area of the cross-section(s).
In another embodiment of the invention, the solar deflection device comprises a nominal half acceptance angle between 30° and 60°, preferably 45°. The nominal half acceptance angle is particularly defined as the angle under which electromagnetic radiation incident on the inlet aperture of the solar deflection device is theoretically guided through the funnel. Said acceptance angle is measured with respect to a surface normal of the area of the inlet aperture.
In another embodiment of the invention, the inlet plane comprising the inlet aperture and the exit plane comprising the exit aperture enclose a deflection angle between 30° and 60°, preferably 45°.
In another embodiment of the invention the inlet plane and the exit plane are perpendicular to the curved line at the respective point of contact.
Further features and advantages of the invention shall be described by means of a detailed description of embodiments with reference to the Figures and examples. It is specifically shown in:
Wherein C is the geometric concentration and θ is the nominal half acceptance angle 9.
In the following some figures of merit will be introduced that are typically used to describe a solar concentrator and/or solar deflection device 1.
Geometric Concentration:
The geometric concentration C is the ratio of the inlet aperture area 3b to the exit aperture area 4b. For circular inlet and exit apertures 3, 4 the geometric concentration C is equal to the ratio of the square of the inlet aperture diameter 3d to the exit aperture diameter 4d.
C=A
i
/A
o=(Di/Do)2 (Eq. 1)
with
Di denoting the inlet aperture diameter 3d,
Do denoting the exit aperture diameter 4d,
Ai denoting the inlet aperture area 3b, and
Ao denoting the exit aperture area 4b.
While the geometric concentration C can in principle have any value (Do may be made arbitrarily small), there is a theoretical upper limit of C above which some of the radiation within the half acceptance angle θ must be rejected by the solar deflection device 1. This limit is set by conservation of étendue and is equal in three dimensions to:
C=1/sin2(θ) (Eq. 2)
Usually this is taken as the limit for C, since a higher geometric concentration C will necessarily lead to losses in acceptance efficiency. For the given problem with θ=45°, the maximum geometric concentration C equals 2. Unless otherwise stated, the following designs considered here are constructed with C=2.
Optical Efficiency
The optical efficiency ηoptical is the fraction of radiant power entering the inlet aperture 3 of the solar deflection device 1, which reaches the exit aperture 4 accounting for all loss mechanisms (rejection and absorption):
Θoptical=Qo/Qi (Eq. 3)
with Qi being the power of the radiation incident on the inlet aperture within the nominal half acceptance angel, and Qo being the power at the exit aperture.
Acceptance Efficiency
The acceptance efficiency ηacc is the optical efficiency ηoptical considering losses only by ray rejection, i.e. for a solar deflection device 1 with perfect mirrors (reflectivity ρ of 1). It is a function only of the geometry of the solar deflection device 1 and the distribution of incident radiation at the inlet aperture 3.
ηacc=ηoptical(ρ=1) (Eq. 4)
A solar deflection device 1, particularly a solar radiation concentrator is called ideal, if it has no rejection, i.e. an acceptance efficiency of 1, for all rays within the nominal half acceptance angle 9 (also referred to as θ).
Average Number of Reflections
The average number of reflections n
is a figure of merit for assessing the degree to which electromagnetic radiation is absorbed by mirror surfaces of finite reflectivity.
Following the work of Rabl [2] an approximation for the optical efficiency ηoptical of an optical system with finite reflectivity ρ is:
ηoptical(ρ)≈ηacc· (Eq. 5)
The average number of reflections n
can therefore be obtained from:
Eq. (5) can subsequently be used to estimate the optical efficiency ηoptical for a different reflectivity ρ, provided the reflectivity ρ is high and reasonably close to the value used in the Eq. (6) to evaluate n
.
Expected Efficiency
An estimate of the attainable efficiency of a redirecting and concentrating solar deflection device can be estimated by considering typical values of the acceptance efficiency ηacc and the average number of reflections n
. Assuming an acceptance efficiency ηacc of 90% and on average one reflection to redirect the ray plus one reflection to concentrate yields:
ηoptical(ρ)=0.9ρ2 (Eq. 7)
Assuming a mirror reflectivity ρ of 95% yields ηoptical equals 81%. This is regarded as a reasonable value to aim for with the solar deflection device 1 according to the invention.
Design Strategy—from Two Dimensions to Three Dimensions
In general, solar deflection devices profiles are designed in two dimensions. Most three dimensional designs considered have circular inlet and exit apertures. Where axial symmetry is possible three dimensional profiles are obtained by revolving 2D axes about the optic axis. Where not, three dimensional profiles are obtained by lofting circular inlet and exit apertures using the two dimensional profile as guide curves.
Examples of Various Designs of Solar Deflection Devices
wherein R is the outer radius of the torus and r is the inner radius of the torus.
Tailored Toroid Concentrator (TTC)
Such a TTC concentrates and redirects electromagnetic radiation and might be used for directing concentrated electromagnetic radiation particularly from a single stationary source particularly to a plurality of apertures of a multiple-cavity receiver, for example an array of cavities, each with an individual aperture.
The TTC is a tailored concentrator based on a torus with geometry modified to achieve ideal concentration at maximum optical efficiency. The TTC particularly comprises all or some of the following features:
The construction of such a tailored toroidal concentrator particularly begins in the x-z plane with a curved line 5, particularly a circular arc centerline covering a rotation angle φ and radius Rc centered at the origin as shown in
The reflective surface 2b of the TTC is defined by a series of circular cross-sections 6 from the inlet to exit aperture 3 on planes 6a whose normals n are tangent to the curved line 5 at the intersection point where the respective plane 6a intersects the curved line, as shown in
r=S(φ)
x=(r cos(ψ)+Rc)cos(φ)
y=(r cos(ψ)+Rc)sin(φ)
z=r sin(ψ)
for 0≦φ≦φ, and 0≦ψ<2π. The resulting shape is a surface from the circular inlet aperture 3 to the circular exit aperture 4 through the circular cross-sections 6 of radius r=S(φ).
Various taper functions S are possible, but generally interpolating functions are used. Depending on the number of interpolation points (also termed knots) used in addition to the endpoints (φ=0, ri) and (φ=φ, ro), different interpolation functions (also termed interpolants) may be used. The simplest interpolant is (with zero additional knots) the linear interpolant r(φ)=ri−(ri−ro)φ/φ. An additional interpolation point may be defined at the “waist” of the device at a deflection angle φw (given a nominal value of ½φ) and radius rw. It is then possible to define a piecewise linear spline, a parabola (quadratic), or piecewise cubic spline through the three knots. For φw=½φ, a value of rw=½(ri+ro) produces a linear interpolant for a spline of any degree. The waist control point can be tailored to maximize the optical transfer efficiency of the TTC. Additional knots provide additional degrees of freedom to tailor the TTC.
Due to its high degree of smoothness, the cubic spline is a preferred interpolant for the taper function S. For one additional interpolation point at the waist, a natural cubic spline S(φ) may be fitted through knots I(0, ri), W(φw, rw) and O(φo, ro). The 3-point spline has two segments: the first segment ranges from the inlet to the waist, and second segment ranges from the waist to the exit, with second derivatives set to zero at the two ends (natural spline), and first and second derivatives matched at W.
The interpolant for the jth segment has the form:
S
j(φ)=aj+bjtj+cjtj2+djtj3
where tj=t1=φ/φw for the first segment, and tj=t2=(φ−φw)/(φ−φw) for the second segment. The coefficients of the interpolant are:
a
1
=r
i
a
2
=r
w
b
1=0.25(−5ri+6rw−ro)
b
2=0.5(−ri+ro)
c
1=0
c
2=0.75(ri−2rw+ro)
d
1=0.25(ri−2rw+ro)
d
2=0.25(−ri+2rw−ro)
One way to design such a TTC is to choose the inlet (and/or exit) aperture for maximum concentration C=1/sin2(θ), and subsequently tailor the waist radius rw at half the rotation angle φ to yield the highest optical efficiency ηoptical.
The particularly highest optical efficiency ηoptical can be estimated for example by a computer simulation.
Results of Estimating a TTC Shape with Computer Simulations
Ray-tracing simulations were performed in LightTools 7.1.0 using solid model geometries built in SolidWorks 2011. The radiation source was modelled as a Lambertian disk of radius 2.5 m at a distance of 2.5 m from the focal plane (i.e. subtending a rim angle of 45°). A low number of rays (25 000) were traced for each simulation to facilitate the investigation of many designs. The estimated error on the power reaching the exit plane was below 1% for all simulations (see
The results are compared to other solar deflection devices.
The acceptance efficiency of a 45° three dimensional Compound parabolic concentrator (CPC) is used as a reference. As mentioned above, the CPC is an ideal concentrator in two dimensions for an infinite source of half-angular aperture θacc. In revolved three-dimensional geometry, it falls short of ideality due to partial rejection of non-meridian (skew) rays.
In
In n
for high eccentricities e0. The EAR-CPC 104 and TTC 100 designs have a comparable average number of reflections
n
. The TAR-CPC 105 has the lowest average number of reflections
n
owing to its extremely compact design.
The combined effect of the acceptance efficiency ηacc and the average number of reflections n
is shown in
n
. The EAR-CPC 104 is a potential candidate for medium eccentricities ec, but is long for a given aperture diameter. The TTC 100 is particularly the best design for high eccentricities ec. Furthermore the results of an EAR-CPC 106 and an EFLC 107 design each with a geometric concentration C of 1.8 are shown.
Source Specification
Simulations were performed with a Lambertian disk source approximating the geometry of a solar simulator.
Geometry Specification
Three different geometric constructions with an increasing number of degrees-of-freedom were investigated. In all cases, the three dimensional geometry was obtained by lofting from the circular inlet aperture to the circular outlet aperture along the specified guide curves.
Baseline
The baseline design consists of a circular centerline 5 with a radius Rc which governs the position of the inlet and outlet aperture 3, 4. The cross-section through the reflective surface are represented by two curved lines (i.e. the guide profiles), particularly a circular arc. The design has no degrees of freedom to be used as optimization parameters.
Spline 1
The Spline 1 design utilizes the height H and eccentricity ec to position the inlet and outlet apertures 3, 4. The two guide profiles 300, 301—that are the cross-sectional lines of the funnel 2 representing the funnel wall 2a—are natural cubic splines passing through the inlet and outlet aperture 3, 4 edges wherein the guide profile's 300, 301 shape is controlled by a knot 302 placed between a beginning and an end of the respective guide profile, particularly at the “waist” of the solar deflection device 1. There are three degrees of freedom which may be used as optimization parameters. The optimization parameters are particularly given by the radius Rw from one of the guide profiles 300, the radius rw of the funnel 2 at a particular deflection angle and the height H of the funnel 2 as shown in
Spline 2
The Spline 2 design is similar to the Spline 1 design, but the placement of the knots is not restricted to be collinear with the origin. The two guide profiles 300, 301 on the inside and outside of the solar deflection device 1 may be chosen independently. There are five degrees of freedom which may be used as optimization parameters. The optimization parameters are particularly given by
Optimization was performed to maximize optical efficiency for a reflectivity of 95% at the nominal acceptance angle using 105 rays. The “alternate engine” in LightTools was used with an exit criterion of less than a 10-5% improvement on the objective function. However, it is likely that the noise floor of the MC simulation provides a less strict exit criterion.
After the optimization, the resulting designs were traced with 106 rays. The results for an incident radiant power of Qi=100 W, are shown below. The values of the output power Qo are equal to the percent optical efficiency of the design.
The design parameters for the optimized designs are given below:
Number | Date | Country | Kind |
---|---|---|---|
15159194.8 | Mar 2015 | EP | regional |
Filing Document | Filing Date | Country | Kind |
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PCT/EP2016/055443 | 3/14/2016 | WO | 00 |