This disclosure is generally related to photovoltaic (or “PV”) roof tile modules. More specifically, this disclosure is related to photovoltaic roof modules with improved aesthetic and power efficiency.
In residential and commercial solar energy installations, a building's roof typically is installed with photovoltaic (PV) modules, also called PV or solar panels, that can include a two-dimensional array (e.g., 6×12) of solar cells. A PV roof tile (or solar roof tile) can be a particular type of PV module offering weather protection for the home and a pleasing aesthetic appearance, while also functioning as a PV module to convert solar energy to electricity. The PV roof tile can be shaped like a conventional roof tile and can include one or more solar cells encapsulated between a front cover and a back cover, but typically encloses fewer solar cells than a conventional solar panel.
The front and back covers can be fortified glass or other material that can protect the PV cells from the weather elements. Note that a typical roof tile may have a dimension of 15 in×8 in =120 in2=774 cm2, and a typical solar cell may have a dimension of 6 in×6 in =36 in2=232 cm2. Similar to a conventional PV panel, the PV roof tile can include an encapsulating layer, such as an organic polymer. A lamination process can seal the solar cells between the front and back covers.
The arrangement of PV cells encapsulated within each PV roof tile can determine not only the size and shape of the PV roof tile but also its power efficiency. Moreover, to facilitate scalable production and easy installation of PV roof tiles, a group of tiles can be fabricated together as a single module. The arrangement of the tiles within the module can also determine the power efficiency of the module.
One embodiment can provide a photovoltaic roof tile module. The photovoltaic roof tile module can include at least: a first photovoltaic roof tile and a second photovoltaic roof tile positioned adjacent to each other, and a spacer coupled to and positioned between the first and second photovoltaic roof tiles. A respective photovoltaic roof tile can include front and back glass covers, and multiple cascaded strings encapsulated between the front and back glass covers. A respective cascaded string can include a plurality of photovoltaic structures electrically coupled to each other in series, and the multiple cascaded strings can be electrically coupled to each other in parallel. The first and second photovoltaic roof tiles can be electrically coupled to each other in parallel.
In a variation on this embodiment, a respective photovoltaic structure can include a first edge busbar positioned near an edge of a first surface and a second edge busbar positioned near an opposite edge of a second surface. The plurality of photovoltaic structures can be arranged in such a way that the first edge busbar of a first photovoltaic structure overlaps the second edge busbar of an adjacent photovoltaic structure.
In a further variation, the multiple cascaded strings can be arranged in such a way that an edge busbar of a first cascaded string and a corresponding edge busbar of a second cascaded string are substantially aligned in a straight line.
In a further variation, the photovoltaic roof tile module can further include a metallic strip coupled to the corresponding edge busbars of the first and second cascaded strings to enable in-parallel coupling between the first and second cascaded strings.
In a further variation, a front-facing edge busbar of a respective cascaded string can be coupled to a bridge electrode.
In a variation on this embodiment, the back glass cover can include a glass substrate and a pre-laid circuit attached to the glass substrate.
In a further variation, the spacer can include an embedded circuit configured to couple to pre-laid circuits of the first and second photovoltaic roof tiles.
In a variation on this embodiment, each of the first and second photovoltaic roof tiles is oriented in a portrait fashion, and the first and second photovoltaic roof tiles are placed in such a way that a longer edge of the first photovoltaic roof tile is adjacent to a corresponding longer edge of the second photovoltaic roof tile.
One embodiment can provide a photovoltaic roof tile. The photovoltaic roof tile can include front and back glass covers, and multiple cascaded strings encapsulated between the front and back glass covers. A respective cascaded string can include a plurality of photovoltaic structures electrically coupled to each other in series, and the multiple cascaded strings can be electrically coupled to each other in parallel.
One embodiment can provide a method for fabricating a photovoltaic roof tile. The method can include preparing first and second back covers and obtaining multiple cascaded strings. A respective cascaded string can include a plurality of photovoltaic structures electrically coupled to each other in series. The method can further include encapsulating the multiple cascaded strings and a circuit between the first and second back covers. The circuit can facilitate in-parallel electrical coupling between the multiple cascaded strings.
A “solar cell” or “cell” is a photovoltaic structure capable of converting light into electricity. A cell may have any size and any shape, and may be created from a variety of materials. For example, a solar cell may be a photovoltaic structure fabricated on a silicon wafer or one or more thin films on a substrate material (e.g., glass, plastic, or any other material capable of supporting the photovoltaic structure), or a combination thereof.
A “solar cell strip,” “photovoltaic strip,” “smaller cell,” or “strip” is a portion or segment of a photovoltaic structure, such as a solar cell. A photovoltaic structure may be divided into a number of strips. A strip may have any shape and any size. The width and length of a strip may be the same as or different from each other. Strips may be formed by further dividing a previously divided strip.
A “cascade” is a physical arrangement of solar cells or strips that are electrically coupled via electrodes on or near their edges. There are many ways to physically connect adjacent photovoltaic structures. One way is to physically overlap them at or near the edges (e.g., one edge on the positive side and another edge on the negative side) of adjacent structures. This overlapping process is sometimes referred to as “shingling.” Two or more cascading photovoltaic structures or strips can be referred to as a “cascaded string,” or more simply as a “string.”
“Finger lines,” “finger electrodes,” and “fingers” refer to elongated, electrically conductive (e.g., metallic) electrodes of a photovoltaic structure for collecting carriers.
“Busbar,” “bus line,” or “bus electrode” refer to elongated, electrically conductive (e.g., metallic) electrodes of a photovoltaic structure for aggregating current collected by two or more finger lines. A busbar is usually wider than a finger line, and can be deposited or otherwise positioned anywhere on or within the photovoltaic structure. A single photovoltaic structure may have one or more busbars.
A “photovoltaic structure” can refer to a solar cell, a segment, or a solar cell strip. A photovoltaic structure is not limited to a device fabricated by a particular method. For example, a photovoltaic structure can be a crystalline silicon-based solar cell, a thin film solar cell, an amorphous silicon-based solar cell, a polycrystalline silicon-based solar cell, or a strip thereof.
In the figures, like reference numerals refer to the same figure elements.
The following description is presented to enable any person skilled in the art to make and use the embodiments, and is provided in the context of a particular application and its requirements. Various modifications to the disclosed embodiments will be readily apparent to those skilled in the art, and the general principles defined herein may be applied to other embodiments and applications without departing from the spirit and scope of the present disclosure. Thus, the disclosed system is not limited to the embodiments shown, but is to be accorded the widest scope consistent with the principles and features disclosed herein.
Overview
Embodiments of the invention solve at least the technical problem of improving the aesthetics and efficiency of photovoltaic roof tile modules. More specifically, each roof tile can include multiple sets of photovoltaic strips arranged in a portrait fashion, with one set of photovoltaic strips positioned on top of the other neighboring set of photovoltaic strips. Photovoltaic strips within each set are arranged in a shingling fashion with adjacent edges of neighboring strips overlapping each other. These shingled photovoltaic strips are electrically coupled to each other in series. On the other hand, different sets of photovoltaic structures are coupled to each other in parallel. Moreover, multiple photovoltaic roof tiles can be assembled into a module. In some embodiments, the roof tiles are arranged in a lateral fashion. The multiple photovoltaic roof tiles can be electrically coupled to each other in parallel. The portrait layout of the roof tiles can provide better aesthetics than roof tiles with landscape layout. Moreover, the parallel coupling between the different sets of photovoltaic strips within each tile can reduce the internal resistance of each tile, thus improving power efficiency.
PV Roof Tiles and Multi-Tile Modules
A PV roof tile (or solar roof tile) is a type of PV module shaped like a roof tile and typically enclosing fewer solar cells than a conventional solar panel. Note that such PV roof tiles can function as both PV cells and roof tiles at the same time. PV roof tiles and modules are described in more detail in U.S. Provisional Patent Application No. 62/465,694, entitled “SYSTEM AND METHOD FOR PACKAGING PHOTOVOLTAIC ROOF TILES” filed Mar. 1, 2017, which is incorporated herein by reference. In some embodiments, the system disclosed herein can be applied to PV roof tiles and/or other types of PV module.
A PV roof tile can enclose multiple solar cells or PV structures, and a respective PV structure can include one or more electrodes, such as busbars and finger lines. The PV structures within a PV roof tile can be electrically and, optionally, mechanically coupled to each other. For example, multiple PV structures can be electrically coupled together by a metallic tab, via their respective busbars, to create serial or parallel connections. Moreover, electrical connections can be made between two adjacent tiles, so that a number of PV roof tiles can jointly provide electrical power.
To facilitate more scalable production and easier installation, multiple photovoltaic roof tiles can be fabricated together, while the tiles are linked in a rigid or semi-rigid way.
It is possible to use a single piece of glass as glass cover 420. In one embodiment, grooves 422 and 424 can be made on glass cover 420, so that the appearance of three separate roof tiles can be achieved. It is also possible to use three separate pieces of glass to cover the six cells, which are laid out on a common backsheet. In this case, gaps 422 and 424 can be sealed with an encapsulant material, establishing a semi-rigid coupling between adjacent tiles. Prefabricating multiple tiles into a rigid or semi-rigid multi-tile module can significantly reduce the complexity in roof installation, because the tiles within the module have been connected with the tabbing strips. Note that the number of tiles included in each multi-tile module can be more or fewer than what is shown in
The gap between two adjacent PV tiles can be filled with encapsulant, protecting tabbing strips interconnecting the two adjacent tiles from the weather elements. For example, encapsulant 470 fills the gap between tiles 454 and 456, protecting tabbing strip 468 from weather elements. Furthermore, the three glass covers, backsheet 452, and the encapsulant together form a semi-rigid construction for multi-tile module 450. This semi-rigid construction can facilitate easier installation while providing a certain degree of flexibility among the tiles.
In addition to the examples shown in
In the example shown in
Although dividing a standard cell into smaller pieces can reduce the internal resistance of each piece due to shortened finger lines, arranging multiple strips into a single long cascaded string also creates the problem of the long distance between the two polarities of the cascaded string. As one can see from
To reduce the internal resistance of a photovoltaic roof tile, in some embodiments, instead of forming a single cascaded string, multiple cascaded strings can be formed within each photovoltaic roof tile, and an in-parallel coupling can be established among the multiple cascaded strings. For example, photovoltaic strips to be encapsulated within a photovoltaic roof tile can be divided into two sets, and each set of photovoltaic strips can form a cascaded string. The resulting two cascaded strings can then be coupled to each other in parallel. In some embodiments, the two cascaded strings can be arranged vertically in a portrait fashion, with one cascaded string positioned on top of the other.
In some embodiments, a bridge electrode can include a Si substrate and a metallic layer deposited on the back side of the Si substrate. An edge of the bridge electrode can overlap the top edge busbar of the cascaded string, and the other edge of the bridge electrode can serve as a back side electrical contact for the cascaded string. In addition to a metallic layer that can cover the entire back surface of the Si substrate, additional busbar structures can also be formed on one or both edges of the bridge electrode to simulate the edge busbar of a photovoltaic strip. Detailed descriptions of the Si-based bridge electrode can be found in U.S. patent application Ser. No. 16/006,645, filed Jun. 12, 2018, and entitled “SOLAR ROOF TILE CONNECTORS,” the disclosure of which is incorporated herein by reference in its entirety. In alternative embodiments, bridge electrodes 608 and 610 can include simple metal tabs coupled to the front edge busbar of each cascaded string.
Photovoltaic strip sets 604 and 606 are arranged into a portrait configuration, with photovoltaic strip set 604 positioned above photovoltaic strip set 606. More specifically, in
To facilitate in-parallel coupling between the two cascaded strings, in some embodiments, metallic strips that couple the corresponding electrodes can be used. For example, metallic strip 622 can be placed on top of back-side edge busbars 614 and 616, electrically coupling them to each other. Similarly, metallic strip 624 can be placed on top of back-side edge busbars 618 and 620, electrically coupling them to each other. In other words, metallic strips 622 and 624 can each couple electrodes of the same polarity of the cascaded strings. Note that the electrical coupling between the metallic strip and the back-side edge busbars can be achieved via direct metal-to-metal contact or by applying a conductive adhesive in between. Note that, to prevent current leakage, insulation tapes can be used to wrap around portions of the metallic strip that are not covered by the cascaded strings or bridge electrodes. For example, insulation tape 626 and 628 can be used to wrap around the exposed portions of metallic strips 622 and 624, respectively. Electrical coupling between different photovoltaic tiles is not shown in
In most cases, photovoltaic roof tiles as shown in
As discussed previously, multiple photovoltaic roof tiles can be pre-assembled to form a multi-tile module to facilitate easy installation of the roof, because they can be laid down as a single unit. The photovoltaic roof tiles within each multi-tile module not only are mechanically coupled to each other, but also are electrically coupled to each other. The arrangement of the photovoltaic roof tiles within each multi-tile module can affect the electrical coupling among them, and the electrical coupling among the photovoltaic roof tiles within each module can affect the power efficiency of the multi-tile module. In some embodiments, the multiple photovoltaic roof tiles within a tile module can be placed in a lateral configuration. In other words, they can be arranged side by side, as shown in
Each tile can include at least two cascaded strings that form a vertical array. For example, tile 802 can include cascaded strings 812 and 814. Moreover, each cascaded string can be coupled to a bridge electrode for converting a front-side electrode to a back-side electrode. For example, cascaded string 812 is coupled to bridge electrode 816, and cascaded string 814 is coupled to bridge electrode 818.
As discussed previously, a pair of metallic strips can be used to achieve in-parallel electrical coupling between the cascaded strings. For example, vertically oriented metallic strips 820 and 822 each couple the electrodes of a particular polarity of the cascaded strings. More specifically, metallic strip 820 can electrically couple the back-side edge busbars of cascaded strings 812 and 814, and metallic strip 822 can couple the back-side edge busbars of bridge electrodes 816 and 818, which are coupled to the front-side edge busbars of cascaded strings 812 and 814, respectively.
In addition to electrical coupling within each photovoltaic roof tile, inter-tile electrical coupling among the photovoltaic tiles within a multi-tile module is also needed. In some embodiments, an additional pair of metallic strips (e.g., metallic strips 824 and 826) can be used to achieve the inter-tile electrical coupling. More specifically, each metallic strip can extend laterally along all three tiles to electrically couple the vertically oriented metallic strips, which in fact act as the two polarity electrodes of each tile. Depending on the desired type of electrical coupling (e.g., in-parallel or in-series), the coupling between the lateral and vertical metallic strips can be configured accordingly.
In the example shown in
Note that, because each lateral metallic strip actually crosses vertical metallic strips of different polarities, appropriate insulation is needed. More specifically, insulation tapes 828 and 830 can be used to wrap portions of metallic strip 824, and insulation tapes 832 and 834 can be used to wrap portions of metallic strip 826, thus ensuring only desired electrical contacts are created. In addition to those regions where metallic strips cross, other portions of the metallic strips may require insulation to prevent current or voltage leakage. In fact, in some embodiments, each lateral metallic strip can be insulated in its entirety except at certain regions where metal-to-metal contacts are desired. Moreover, the vertical metallic strips may also be partially insulated (e.g., at regions not covered by the cascaded strings). For simplicity of illustration, not all insulated regions are marked in
In addition to in-parallel electrical coupling, in-series electrical coupling among the photovoltaic roof tiles within a multi-tile module can also be achieved, as shown in
In
In the examples shown in
In addition to inter-tile electrical coupling, electrical coupling among different multi-tile modules is also needed. In some embodiments, to facilitate inter-module electrical coupling, each multi-tile module can include external electrical contacts.
In the example shown in
Fabrication of a Photovoltaic Roof Tile Module
Depending on whether or not the back covers include pre-laid circuits, the photovoltaic roof tile module may be fabricated using a slightly different process.
In some embodiments, instead of conductive paste, electrical and mechanical bonding between the adjacent strips at their corresponding edges can be achieved via adhesive conductive films. Detailed descriptions about the bonding of adjacent photovoltaic strips using adhesive conductive films can be found in U.S. patent application Ser. No. 16/007,599, entitled “CASCADED SOLAR CELL STRING USING ADHESIVE CONDUCTIVE FILM,” filed Jun. 13, 2018, the disclosure of which is incorporated herein by reference in its entirety. In addition to photovoltaic strips, each cascaded string can also include a bridge electrode that can convert the front-side edge busbar to a back-side contact.
One or more glass front covers for solar roof tiles can be obtained (operation 1304), and a front encapsulant layer can be laid onto each front cover (operation 1306). Subsequently, multiple cascaded strings can be laid onto each front glass cover, arranged in such a way that they form a vertical array (operation 1308). In some embodiments, a robotic arm with vacuum-enabled wafer pickers can pick up the cascaded strings and lay them at desired locations. Note that the arrangement of the cascaded strings ensures that the edge busbars of the same polarity of the cascaded strings are substantially aligned on a straight line. This can ensure that in-parallel coupling among the cascaded strings can be achieved using a pair of straight metallic strips. Note that, because they are laid onto the front covers, the cascaded strings are laid facing down, with their sun-facing surfaces facing downward.
If the tile module includes multiple tiles, spacers can be placed between adjacent tiles (operation 1310). The inter-tile circuit that can include multiple standalone metallic strips can be laid at appropriate locations (operation 1312). More specifically, the inter-tile circuit can include metallic strips that extend laterally across multiple tiles and vertical metallic strips for electrically coupling the multiple cascaded strings within each tile. The coupling between a metallic strip and an edge busbar of the cascaded string or the coupling between two intersecting metallic strips can be achieved using electrically conductive adhesive (ECA). Alternatively, no adhesive is needed.
Subsequently, a back encapsulant layer can then be placed on top of the cascaded strings and the inter-tile circuit (operation 1314), and glass back covers can be placed on top of the back encapsulant layer (operation 1316). In some embodiments, the glass back covers can include external electrical contacts similar to the ones shown in
A number of glass back covers with pre-laid circuit can be obtained (operation 1404). In some embodiments, the pre-laid circuit can be formed on glass substrate by attaching (e.g., using an adhesive) individual metallic strips at desired locations. In alternative embodiments, the pre-laid circuit can be formed by printing, or depositing using other metallization techniques (e.g., evaporation, sputtering, plating, etc.) metallic traces at desired locations of the back covers. Appropriate insulation is needed to prevent unwanted electrical coupling. In some embodiments, the back covers can also include external electrical contacts similar to the ones shown in
The cascaded strings can then be placed onto the back covers with pre-laid circuit (operation 1406). Note that, because they are laid onto the back covers, the cascaded strings are laid with their sun-facing side up. Also note that the cascaded strings are placed in such a way that the electrodes of the cascaded strings are coupled to the pre-laid circuit, and that the cascaded strings placed on a same back cover are electrically coupled to each other in parallel.
In some embodiments, prior to laying down the cascaded strings, a back encapsulant layer can be placed on the back covers. This operation is optional and is not shown in
If the tile module is a multi-tile module, specially designed tile spacers with embedded circuit can be placed between the tile covers (operation 1408). In some embodiments, a tile spacer can be formed by first forming (e.g., using a molding technique) upper and lower portions of the tile spacer and then placing one or more metallic strips between the upper and lower portions of the tile spacer in such a way that the metallic strips are sandwiched between the upper and lower portions of the tile spacer with their ends extending beyond either side of the tile spacer. In some embodiments, forming a tile spacer can involve placing, beforehand, one or more metallic strips inside a mold for the tile spacer, and then injecting molting thermalplastic (e.g., PVDF or PTFE) into the mold. The metallic strips can be shaped into a desired shape and placed at a desired location. Therefore, after cooling, a tile spacer with embedded metallic strips can be obtained. The length of the metallic strips can be designed such that the two ends of a metallic strip can extend beyond the two wings of the tile spacer. In some embodiments, the tile spacers can be placed in such a way that the base of a tile spacer snugly fits in the space between two adjacent back tile covers, with its two wings positioned above the back covers. More specifically, the metallic strips extending out of the wings can come into contact with the pre-laid circuit on the back tile covers. In some embodiments, conductive paste or film can be deposited onto the pre-laid circuit to facilitate electrical coupling between the embedded circuit in the tile spacer and the pre-laid circuit on the back covers.
Subsequently, a front encapsulant layer can then be placed on top of the cascaded strings (operation 1410), and front glass covers can be placed on top of the front encapsulant layer (operation 1412). A lamination operation can be performed to encapsulate the cascaded strings between the front and back covers (operation 1414). A post-lamination process (e.g., trimming of overflowed encapsulant and attachment of the junction box and other roofing components) can then be performed to complete the fabrication of a PV roof tile (operation 1416).
The foregoing descriptions of various embodiments have been presented only for purposes of illustration and description. They are not intended to be exhaustive or to limit the present system to the forms disclosed. Accordingly, many modifications and variations will be apparent to practitioners skilled in the art. Additionally, the above disclosure is not intended to limit the present system.
Number | Name | Date | Kind |
---|---|---|---|
352424 | Owen et al. | Nov 1886 | A |
3076861 | Samulon | Feb 1963 | A |
3369939 | Myer | Feb 1968 | A |
3459391 | Haynos | Aug 1969 | A |
3461602 | Heinz | Aug 1969 | A |
4040867 | Forestieri | Aug 1977 | A |
4239810 | Alameddine | Dec 1980 | A |
4336413 | Tourneux | Jun 1982 | A |
4400577 | Spear | Aug 1983 | A |
4623753 | Feldman et al. | Nov 1986 | A |
4724011 | Turner | Feb 1988 | A |
4946512 | Fukuroi et al. | Aug 1990 | A |
5112408 | Melchior | May 1992 | A |
5118540 | Hutchison | Jun 1992 | A |
5316592 | Dinwoodie | May 1994 | A |
5338369 | Rawlings | Aug 1994 | A |
5427961 | Takenouchi | Jun 1995 | A |
5437735 | Younan et al. | Aug 1995 | A |
5482569 | Ihara et al. | Jan 1996 | A |
5571338 | Kadonome et al. | Nov 1996 | A |
5575861 | Younan et al. | Nov 1996 | A |
5590495 | Bressler et al. | Jan 1997 | A |
5596981 | Soucy | Jan 1997 | A |
5667596 | Tsuzuki | Sep 1997 | A |
5701067 | Kaji et al. | Dec 1997 | A |
5919316 | Bogorad et al. | Jul 1999 | A |
5942048 | Fujisaki | Aug 1999 | A |
6093884 | Toyomura et al. | Jul 2000 | A |
6133522 | Kataoka | Oct 2000 | A |
6186698 | Knapp | Feb 2001 | B1 |
6307144 | Mimura et al. | Oct 2001 | B1 |
6311436 | Mimura | Nov 2001 | B1 |
6365824 | Nakazima | Apr 2002 | B1 |
6465724 | Garvison et al. | Oct 2002 | B1 |
6472594 | Ichinose | Oct 2002 | B1 |
6515216 | Zenko et al. | Feb 2003 | B2 |
6586271 | Hanoka | Jul 2003 | B2 |
6620645 | Chandra et al. | Sep 2003 | B2 |
6670541 | Nagao et al. | Dec 2003 | B2 |
6672018 | Shingleton | Jan 2004 | B2 |
6883290 | Dinwoodie | Apr 2005 | B2 |
6959520 | Hartman | Nov 2005 | B2 |
6960716 | Matsumi | Nov 2005 | B2 |
7012188 | Erling | Mar 2006 | B2 |
7259321 | Oswald | Aug 2007 | B2 |
7276724 | Sheats | Oct 2007 | B2 |
7328534 | Dinwoodie | Feb 2008 | B2 |
7506477 | Flaherty | Mar 2009 | B2 |
7534956 | Kataoka | May 2009 | B2 |
7772484 | Li | Aug 2010 | B2 |
7833808 | Xu | Nov 2010 | B2 |
7851700 | Luch | Dec 2010 | B2 |
7858874 | Ruskin | Dec 2010 | B2 |
7902451 | Shimizu | Mar 2011 | B2 |
7964440 | Salleo | Jun 2011 | B2 |
8109048 | West et al. | Feb 2012 | B2 |
8141306 | Masuda et al. | Mar 2012 | B2 |
8156697 | Miros et al. | Apr 2012 | B2 |
8205400 | Allen | Jun 2012 | B2 |
8206664 | Lin | Jun 2012 | B2 |
8276329 | Lenox | Oct 2012 | B2 |
8307606 | Rego et al. | Nov 2012 | B1 |
8471141 | Stancel | Jun 2013 | B2 |
8519531 | Pilat et al. | Aug 2013 | B2 |
8601754 | Jenkins et al. | Dec 2013 | B2 |
8664030 | Luch | Mar 2014 | B2 |
8674377 | Farquhar | Mar 2014 | B2 |
8697981 | Adriani et al. | Apr 2014 | B2 |
8701360 | Ressler | Apr 2014 | B2 |
8713861 | Desloover | May 2014 | B2 |
8740642 | Keenihan et al. | Jun 2014 | B2 |
8763322 | Hamamura | Jul 2014 | B2 |
8822810 | Luch | Sep 2014 | B2 |
8869470 | Lanza | Oct 2014 | B2 |
8919075 | Erickson | Dec 2014 | B2 |
9000288 | Hoang | Apr 2015 | B2 |
9012763 | Frolov et al. | Apr 2015 | B2 |
9038330 | Bellavia | May 2015 | B2 |
9150966 | Xu | Oct 2015 | B2 |
9206520 | Barr | Dec 2015 | B2 |
9343592 | Hunt | May 2016 | B2 |
9356173 | Okandan et al. | May 2016 | B2 |
9362527 | Takemura | Jun 2016 | B2 |
9412884 | Heng | Aug 2016 | B2 |
9412890 | Meyers | Aug 2016 | B1 |
9435568 | Smidt et al. | Sep 2016 | B2 |
9496423 | Loeckenhoff et al. | Nov 2016 | B2 |
9496819 | Hsueh et al. | Nov 2016 | B2 |
9518391 | Haynes et al. | Dec 2016 | B2 |
9525092 | Mayer | Dec 2016 | B2 |
9673750 | Schoop et al. | Jun 2017 | B2 |
9685579 | Gonzalez et al. | Jun 2017 | B2 |
9825582 | Fernandes | Nov 2017 | B2 |
9882077 | Morad et al. | Jan 2018 | B2 |
9899554 | Yang | Feb 2018 | B2 |
9954480 | Haynes et al. | Apr 2018 | B2 |
9966487 | Magnusdottir | May 2018 | B2 |
10056522 | Gonzalez | Aug 2018 | B2 |
10145116 | Holt et al. | Dec 2018 | B2 |
10151114 | Stearns et al. | Dec 2018 | B2 |
10177708 | Cruz | Jan 2019 | B2 |
10256765 | Rodrigues et al. | Apr 2019 | B2 |
10461685 | Anderson et al. | Oct 2019 | B2 |
10563406 | Kalkanoglu et al. | Feb 2020 | B2 |
20010054435 | Nagao | Dec 2001 | A1 |
20020015782 | Abys | Feb 2002 | A1 |
20030010377 | Fukuda et al. | Jan 2003 | A1 |
20030180983 | Oswald | Sep 2003 | A1 |
20040261840 | Schmit | Dec 2004 | A1 |
20050022857 | Daroczi et al. | Feb 2005 | A1 |
20050039788 | Blieske | Feb 2005 | A1 |
20050268963 | Jordan | Dec 2005 | A1 |
20060048798 | McCoy | Mar 2006 | A1 |
20060086620 | Chase | Apr 2006 | A1 |
20060102380 | Hu | May 2006 | A1 |
20060204730 | Nakamura | Sep 2006 | A1 |
20070011898 | Frank et al. | Jan 2007 | A1 |
20080053511 | Nakamura | Mar 2008 | A1 |
20080135085 | Corrales | Jun 2008 | A1 |
20080149170 | Hanoka | Jun 2008 | A1 |
20080231768 | Okabe | Sep 2008 | A1 |
20080271773 | Jacobs et al. | Nov 2008 | A1 |
20080302030 | Stancel et al. | Dec 2008 | A1 |
20090101192 | Kothari | Apr 2009 | A1 |
20090120497 | Schetty | May 2009 | A1 |
20090133739 | Shiao | May 2009 | A1 |
20090133740 | Shiao | May 2009 | A1 |
20090233083 | Inoue | Sep 2009 | A1 |
20090242021 | Petkie | Oct 2009 | A1 |
20090287446 | Wang | Nov 2009 | A1 |
20090308435 | Caiger | Dec 2009 | A1 |
20100000603 | Tsuzuki | Jan 2010 | A1 |
20100006147 | Nakashima | Jan 2010 | A1 |
20100018568 | Nakata | Jan 2010 | A1 |
20100116330 | Inoue | May 2010 | A1 |
20100132762 | Graham | Jun 2010 | A1 |
20100147363 | Huang | Jun 2010 | A1 |
20100147364 | Gonzalez et al. | Jun 2010 | A1 |
20100180929 | Raymond | Jul 2010 | A1 |
20110017278 | Kalkanoglu et al. | Jan 2011 | A1 |
20110023937 | Daniel | Feb 2011 | A1 |
20110023942 | Soegding | Feb 2011 | A1 |
20110030761 | Kalkanoglu | Feb 2011 | A1 |
20110047902 | Cryar | Mar 2011 | A1 |
20110048507 | Livsey et al. | Mar 2011 | A1 |
20110100436 | Cleereman | May 2011 | A1 |
20110203637 | Patton et al. | Aug 2011 | A1 |
20110253193 | Korman et al. | Oct 2011 | A1 |
20110277825 | Fu | Nov 2011 | A1 |
20110290307 | Workman et al. | Dec 2011 | A1 |
20120000502 | Wiedeman et al. | Jan 2012 | A1 |
20120012162 | Kobayashi | Jan 2012 | A1 |
20120031470 | Dimov | Feb 2012 | A1 |
20120048349 | Metin | Mar 2012 | A1 |
20120060911 | Fu | Mar 2012 | A1 |
20120125391 | Pinarbasi | May 2012 | A1 |
20120199184 | Nie | Aug 2012 | A1 |
20120204927 | Peterson et al. | Aug 2012 | A1 |
20120237670 | Lim | Sep 2012 | A1 |
20130048062 | Min | Feb 2013 | A1 |
20130061913 | Willham | Mar 2013 | A1 |
20130098420 | Sherman et al. | Apr 2013 | A1 |
20130160823 | Khouri | Jun 2013 | A1 |
20130206213 | He | Aug 2013 | A1 |
20130209776 | Kim | Aug 2013 | A1 |
20130233378 | Moslehi | Sep 2013 | A1 |
20130239495 | Galitev et al. | Sep 2013 | A1 |
20130247959 | Kwon | Sep 2013 | A1 |
20130255755 | Chich | Oct 2013 | A1 |
20130280521 | Mori | Oct 2013 | A1 |
20130284241 | Georgi | Oct 2013 | A1 |
20140120699 | Hua | May 2014 | A1 |
20140124014 | Morad | May 2014 | A1 |
20140196768 | Heng et al. | Jul 2014 | A1 |
20140246549 | West et al. | Sep 2014 | A1 |
20140313574 | Bills | Oct 2014 | A1 |
20140360582 | Cui | Dec 2014 | A1 |
20150068582 | Chaney | Mar 2015 | A1 |
20150083191 | Gmundner | Mar 2015 | A1 |
20150090314 | Yang | Apr 2015 | A1 |
20150155824 | Chien | Jun 2015 | A1 |
20150194552 | Ogasahara | Jul 2015 | A1 |
20150243931 | Fukuura | Aug 2015 | A1 |
20150270410 | Heng | Sep 2015 | A1 |
20150349145 | Morad | Dec 2015 | A1 |
20150349152 | Voss | Dec 2015 | A1 |
20150349703 | Morad | Dec 2015 | A1 |
20160013329 | Brophy | Jan 2016 | A1 |
20160105144 | Haynes | Apr 2016 | A1 |
20160163902 | Podlowski | Jun 2016 | A1 |
20160181446 | Kalkanoglu | Jun 2016 | A1 |
20160225931 | Heng | Aug 2016 | A1 |
20170033250 | Ballif | Feb 2017 | A1 |
20170077343 | Morad | Mar 2017 | A1 |
20170194516 | Reddy | Jul 2017 | A1 |
20170194900 | Erben | Jul 2017 | A1 |
20170222082 | Lin | Aug 2017 | A1 |
20170358699 | Juliano et al. | Dec 2017 | A1 |
20180054157 | Kapla et al. | Feb 2018 | A1 |
20180166601 | Inaba | Jun 2018 | A1 |
20180254738 | Yang et al. | Sep 2018 | A1 |
20180316302 | Okawa et al. | Nov 2018 | A1 |
20180351501 | Seery et al. | Dec 2018 | A1 |
20180351502 | Almy et al. | Dec 2018 | A1 |
20190028055 | Yang et al. | Jan 2019 | A1 |
20190260328 | Nguyen et al. | Aug 2019 | A1 |
20190393361 | Lin | Dec 2019 | A1 |
20200044599 | Nguyen et al. | Feb 2020 | A1 |
20210091712 | Nguyen et al. | Mar 2021 | A1 |
Number | Date | Country |
---|---|---|
102544380 | Aug 2015 | CN |
103426957 | Mar 2016 | CN |
102956730 | Jun 2016 | CN |
206401337 | Aug 2017 | CN |
206595269 | Oct 2017 | CN |
102007054124 | May 2009 | DE |
0828036 | Mar 1998 | EP |
1058320 | Dec 2000 | EP |
1362967 | Nov 2003 | EP |
1485547 | Dec 2004 | EP |
2051124 | Apr 2009 | EP |
2243901 | Oct 2010 | EP |
2362429 | Aug 2011 | EP |
2709160 | Mar 2014 | EP |
2784241 | Oct 2014 | EP |
2950018 | Dec 2015 | EP |
2278618 | Dec 1994 | GB |
2497276 | Jun 2013 | GB |
S57141979 | Sep 1982 | JP |
S6020586 | Feb 1985 | JP |
H06140657 | May 1994 | JP |
H06264571 | Sep 1994 | JP |
10-46769 | Feb 1998 | JP |
2000-58894 | Feb 2000 | JP |
2000091610 | Mar 2000 | JP |
2000216415 | Aug 2000 | JP |
2001-12038 | Jan 2001 | JP |
2001-15788 | Jan 2001 | JP |
2006-144267 | Jun 2006 | JP |
2013211385 | Oct 2013 | JP |
2014-22702 | Feb 2014 | JP |
2017-517145 | Jun 2017 | JP |
10-0276185 | Dec 2000 | KR |
10-1162675 | Jul 2012 | KR |
2003074812 | Sep 2003 | WO |
2008136872 | Nov 2008 | WO |
2009062106 | May 2009 | WO |
2009099418 | Aug 2009 | WO |
2009137347 | Nov 2009 | WO |
2010128375 | Nov 2010 | WO |
2011128757 | Oct 2011 | WO |
201359441 | Apr 2013 | WO |
2013067541 | May 2013 | WO |
2013102181 | Jul 2013 | WO |
2014178180 | Nov 2014 | WO |
2015155356 | Oct 2015 | WO |
2016024310 | Feb 2016 | WO |
2016090341 | Jun 2016 | WO |
Entry |
---|
Bulucani et al., “A new approach: low cost masking material and efficient copper metallization for higher efficiency silicon solar cells” 2015 IEEE. |
Fan et al., “Laser micromachined wax-covered plastic paper as both sputter deposition shadow masks and deep-ultraviolet patterning masks for polymethylmacrylate-based microfluidic systems” via google scholar, downloaded Mar. 31, 2016. |
“An inorganic/organic hybrid coating for low cost metal mounted dye-sensitized solar cells” Vyas, N. et al. |
“Recovery Act: Organic Coatings as Encapsulants for Low Cost, High Performance PV Modules” Jim Poole et al. Nov. 16, 2011. |
Pelisset: “Efficiency of Silicon Thin-Film photovoltaic Modules with a Front Coloured Glass”, Proceedings CISBAT 2011, Jan. 1, 2011, pp. 37-42, XP055049695, the Whole Document. |
Non-Final Office Action received for U.S. Appl. No. 15/686,109, dated Nov. 25, 2020, 11 pages. |
Notice of Allowance received for U.S. Appl. No. 15/686,064, dated Dec. 30, 2020, 8 pages. |
Advisory Action received for U.S. Appl. No. 15/686,109, dated Jun. 16, 2020, 3 pages. |
Final Office Action received for U.S. Appl. No. 15/909,181, dated Dec. 20, 2018, 23 pages. |
Final Office Action received for U.S. Appl. No. 15/656,794, dated Jul. 29, 2019, 19 pages. |
Final Office Action received for U.S. Appl. No. 15/686,109, dated Dec. 12, 2019, 10 pages. |
Final Office Action received for U.S. Appl. No. 15/686,064, dated Jul. 28, 2020, 13 pages. |
International Preliminary Report on Patentability received for PCT Patent Application No. PCT/US2018/020508, dated Sep. 10, 2020, 10 pages. |
International Preliminary Report on Patentability received for PCT Patent Application No. PCT/US2018/035918, dated Dec. 19, 2019, 11 pages. |
International Preliminary Report on Patentability received for PCT Patent Application No. PCT/US2018/035924, dated Dec. 19, 2019, 8 pages. |
International Preliminary Report on Patentability received for PCT Patent Application No. PCT/US2018/042418, dated Jan. 30, 2020, 12 pages. |
International Search Report and Opinion received for PCT Patent Application No. PCT/US2018/035918, dated Nov. 6, 2018, 15 pages. |
International Search Report and Written Opinion received for PCT Patent Application No. PCT/US2018/020508, dated Mar. 4, 2019, 14 pages. |
International Search Report and Written Opinion received for PCT Patent Application No. PCT/US2018/035924, dated Sep. 12, 2018, 10 pages. |
International Search Report and Written Opinion received for PCT Patent Application No. PCT/US2018/042418, dated Nov. 28, 2018, 14 pages. |
International Search Report and Written Opinion received for PCT Patent Application No. PCT/US2019/044308, dated Oct. 14, 2019, 9 pages. |
Invitation to Pay Additional Fee received for PCT Patent Application No. PCT/US2018/035918, mailed on Sep. 12, 2018, 11 pages. |
Invitation to Pay Additional Fees received for PCT Patent Application No. PCT/US2018/020508, mailed on Jan. 9, 2019, 9 pages. |
Non-Final Office Action received for U.S. Appl. No. 15/686,064, dated Nov. 29, 2019, 13 pages. |
Non-Final Office Action received for U.S. Appl. No. 15/900,636, dated Jan. 28, 2020, 16 pages. |
Non-Final Office Action received for U.S. Appl. No. 16/050,994, dated Sep. 23, 2020, 11 pages. |
Notice of Allowance received for U.S. Appl. No. 15/656,794, dated Mar. 27, 2020, 10 pages. |
Notice of Allowance received for U.S. Appl. No. 15/900,636, dated Aug. 6, 2020, 10 pages. |
Notice of Allowance received for U.S. Appl. No. 15/909,181, dated Sep. 10, 2019, 11 pages. |
Office Action received for Australian Patent Application No. 2018410566, dated Jul. 9, 2020, 9 pages. |
Office Action received for European Patent Application No. 18711759.3, dated Sep. 24, 2020, 4 pages. |
Pre-Interview First Office Action received for U.S. Appl. No. 15/656,794, dated Apr. 16, 2019, 5 pages. |
Pre-Interview First Office Action received for U.S. Appl. No. 15/686,109, dated May 24, 2019, 10 pages. |
Pre-Interview First Office Action received for U.S. Appl. No. 15/909,181, dated Sep. 18, 2018, 6 pages. |
Decision to Grant received for European Patent Application No. 18711759.3, dated Jul. 1, 2021, 2 pages. |
Final Office Action received for U.S. Appl. No. 15/686,109, dated Jun. 18, 2021, 9 pages. |
Final Office Action received for U.S. Appl. No. 16/050,994, dated Mar. 26, 2021, 13 pages. |
Intention to Grant received for European Patent Application No. 18711759.3, dated Feb. 18, 2021, 7 pages. |
International Preliminary Report on Patentability received for PCT Patent Application No. PCT/US2019/044308, dated Feb. 11, 2021, 7 pages. |
Non-Final Office Action received for U.S. Appl. No. 16/050,994, dated Jul. 9, 2021, 13 pages. |
Notice of Acceptance received for Australian Patent Application No. 2018410566, dated Feb. 3, 2021, 3 pages. |
Notice of Allowance received for U.S. Appl. No. 15/686,109, dated Sep. 29, 2021, 8 pages. |
Office Action received for Canadian Patent Application No. 3,066,407, dated Jan. 29, 2021, 3 pages. |
Office Action received for Canadian Patent Application No. 3,066,410, dated Feb. 9, 2021, 4 pages. |
Office Action received for Canadian Patent Application No. 3,066,410, dated May 6, 2021, 3 pages. |
Office Action received for Canadian Patent Application No. 3055609, dated Aug. 18, 2021, 5 pages. |
Office Action received for European Patent Application No. 18733485.9, dated Mar. 11, 2021, 5 pages. |
Office Action received for European Patent Application No. 18733486.7, dated Mar. 12, 2021, 3 pages. |
Office Action received for Indian Patent Application No. 201947052632, dated Mar. 31, 2021, 5 pages. |
Office Action received for Japanese Patent Application No. 2019-547652, dated Aug. 18, 2021, 10 pages (4 pages of English Translation and 6 pages of Official copy). |
Office Action received for Korean Patent Application No. 10-2020-7000127, dated Mar. 22, 2021, 10 pages (4 pages of English Translation and 6 pages of Official copy). |
Office Action received for Korean Patent Application No. 10-2020-7000130, dated Mar. 24, 2021, 10 pages (3 pages of English Translation and 7 pages of Official copy). |
Number | Date | Country | |
---|---|---|---|
20200076352 A1 | Mar 2020 | US |