The present invention relates to fuel cells and, more particularly, high-temperature solid oxide fuel cells to generate electricity and ammonia as byproduct available for further use.
Fuel cells are electrochemical devices which convert chemical energy of fuel and an oxidizing agent into electricity. Hydrogen or substances that include hydrogen are used as fuel in fuel cells. The fuel cells where ammonia is directly fed to an anode of the fuel cell are known in the art (see, for example U.S. Pat. No. 7,157,166). An alternative technical solution concerns the fuel cells fueled by hydrogen generated in decomposition of ammonia fuel into hydrogen and nitrogen (U.S. Pat. No. 3,532,547).
U.S. Pat. No. 8,034,499 discloses an energy conversion system comprising ammonia for fueling an SOFC stack to generate electricity and a hydrogen-rich tailgas. In the SOFC stack, ammonia is cracked to hydrogen and nitrogen. Ammonia is stored in a metal halide complex and is released therefrom as gaseous ammonia by waste heat from the SOFC. A heat exchanger is positioned across the SOFC cathode such that incoming air is tempered by the cathode exhaust air. In a two-stage energy conversion system, the hydrogen-rich tailgas from the SOFC is supplied as fuel to a secondary energy conversion device which may be, for example, an internal combustion engine or a gas turbine engine which may operate, for example, either a generator for generating additional electricity or a vehicle for motive power, or a second fuel cell stack.
There is a long-felt need of further efficiency enhancement of high-temperature solid oxide fuel cells fed with hydrogen or hydrocarbon fuels by providing a device and a method enabling utilization of ammonia generated as a byproduct by the aforesaid fuel cells.
Briefly, energy conversional system, that include a solid oxide fuel cell stack to generate electricity and ammonia gas as byproduct that fueling a second energy conversion device such as other fuel cell or different using.
The aforesaid solid oxide fuel cell comprises: (a) an anode area fed with the hydrogen or hydrocarbon fuel; (b) a cathode area fed with a humid air; (c) an oxygen-conducting electrolyte disposed between the cathode and anode areas.
It is a core purpose of the invention to provide the cathode area has an ammonia-rich tail-gas stream. The fuel cell further comprises a gas separator configured for separating ammonia generated on the cathode from tail-gas stream and means for utilizing separated ammonia selected from the group consisting of: an ammonia reformer configured for generating hydrogen to be admixed to the fuel fed to the anode, a collecting tank for storing the ammonia and an auxiliary solid oxide fuel cell fueled by the separated ammonia and any combination thereof.
A further object of the invention is to disclose the fuel cell comprising heat transfer means configured to transfer heat generated by the fuel cell to the ammonia gas separator. A further object of the invention is to disclose the gas separator alternatively comprising:
A further object of the invention is to disclose a method of generating ammonia as a byproduct by a high-temperature solid oxide fuel cell arrangement fueled by a hydrogen or hydrocarbon fuel. The aforesaid method comprises steps of: (a) providing a high-temperature solid oxide fuel cell arrangement comprising: (i) a cathode area fed with a humid air; (ii) an anode area fed with the fuel; (iii) an oxygen-conducting electrolyte disposed between the cathode and anode areas; the cathode has an ammonia-rich tail-gas stream; the fuel cell further comprises a gas separator configured for separating ammonia generated on the cathode from tail-gas stream and means for utilizing separated ammonia selected from the group consisting of: an ammonia reformer configured for generating hydrogen to be admixed to the fuel fed to the anode, a collecting tank for storing the ammonia and an auxiliary solid oxide fuel cell fueled by the separated ammonia and any combination thereof; (b) feeding the fuel to the anode area; (c) feeding humid air to the cathode area; (d) operating the fuel cell; (e) generating the ammonia as a byproduct in the cathode area; (f) separating the ammonia from the tail-gas stream; and (g) utilizing separated ammonia by at least one way selected from the group consisting of reforming ammonia to hydrogen, storing ammonia in the collecting tank and fueling an auxiliary fuel cell.
In order to understand the invention and to see how it may be implemented in practice, a plurality of embodiments is adapted to now be described, by way of non-limiting example only, with reference to the accompanying drawings, in which:
The following description is provided, so as to enable any person skilled in the art to make use of said invention and sets forth the best modes contemplated by the inventor of carrying out this invention. Various modifications, however, are adapted to remain apparent to those skilled in the art, since the generic principles of the present invention have been defined specifically to provide high-temperature solid oxide fuel cell arrangement fueled by a hydrogen or hydrocarbon fuel and generating electricity and ammonia as a byproduct.
Reference is now made to
Referring to
In arrangement 100a (
In
Electric energy generated by auxiliary fuel cell 180 is designated by 140a. A tail-gas stream from anode area 111 includes water vapor and carbon dioxide (). A tail-gas stream from cathode area 115 includes ammonia generated within cathode area 115. The cathode tail-gas stream is fed into ammonia separator 150 via passage 119. Optionally, as disclosed below, heat generated within fuel cell 110 is transferred to ammonia separator 150, based on vaporization and dephlegmation of ammonia absorbed in water by means of heat transferring means 117.
Operation of fuel cell 10 can be schematically described by the following equations:
In case of using methane as fuel:
Cathode N2+3H2O+6e−→2NH3+3O2− (1)
O2+4e−→2O2− (2)
Anode CH4+5O2−→CO2+2H2O+½O2+10e− (3)
Integral reaction CH4+N2+H2O+½O2→2NH3+CO2+O2 (4)
For a hydrogen fuel cell:
Cathode N2+3H2O+6e−→2NH3+3O2− (1a)
O2+4e−→2O2− (2a)
Anode 5H2+5O2−→5H2O+10e− (5)
Integral reaction N2+O2+5H2→2NH3+2H2O (6)
Reference is now made
Referring to
In
According to the present invention, a high-temperature solid oxide fuel cell arrangement fueled by a hydrogen or hydrocarbon fuel and generating ammonia as a byproduct is disclosed. The aforesaid fuel cell comprises: (a) a cathode area fed with a humid air; (b) an anode area fed with said fuel; (c) an oxygen-conducting electrolyte disposed between said cathode and anode areas.
It is a core purpose of the invention to provide the cathode having an ammonia-rich tail-gas stream; said fuel cell further comprises a gas separator configured for separating ammonia generated on said cathode from tail-gas stream and means for utilizing separated ammonia selected from the group consisting of: an ammonia reformer configured for generating hydrogen to be admixed to said fuel fed to said anode, a collecting tank for storing said ammonia and an auxiliary solid oxide fuel cell fueled by said separated ammonia and any combination thereof.
According to a further embodiment of the present invention, the gas separator comprises an ammonia absorber, an ammonia evaporator and a dephlegmator; said evaporator is heated by heat generated by an electrochemical reaction between cathode and anode transferred to said evaporator.
According to a further embodiment of the present invention, the gas separator comprises a compressor and a membrane arrangement. The compressor configured for pumping said tail-gasses via said membrane arrangement such that ammonia is separated from other exhausted gases.
According to a further embodiment of the present invention, the gas separator comprises a compressor configured for pressurizing the tail-gases such that ammonia is liquefied while other constituents of the tail-gases are exhausted to the atmosphere.
According to a further embodiment of the present invention, a method of generating ammonia as a byproduct by a high-temperature solid oxide fuel cell arrangement fueled by a hydrogen or hydrocarbon fuel is disclosed. The aforesaid method comprises steps of: (a) providing a high-temperature solid oxide fuel cell arrangement comprising: (i) a cathode area fed with a humid air; (ii) an anode area fed with said fuel; (iii) an oxygen-conducting electrolyte disposed between said cathode and anode areas; said cathode has an ammonia-rich tail-gas stream; said fuel cell further comprises a gas separator configured for separating ammonia generated on said cathode from tail-gas stream and means for utilizing separated ammonia selected from the group consisting of: an ammonia reformer configured for generating hydrogen to be admixed to said fuel fed to said anode, a collecting tank for storing said ammonia and an auxiliary solid oxide fuel cell fueled by said separated ammonia and any combination thereof; (b) feeding said fuel to said anode area; (c) fed humid air to said cathode area; (d) operating said fuel cell; (e) generating said ammonia as a byproduct in said cathode area; (f) separating said ammonia from said tail-gas stream; (g) utilizing separated ammonia by at least one way selected from the group consisting of reforming ammonia to hydrogen, storing ammonia in said collecting tank and fueling an auxiliary fuel cell.
According to a further embodiment of the present invention, the step of separating said ammonia from said tail-gas stream comprises heating said tail-gas stream by heat transfer means configured to transfer heat generated by said fuel cell to said ammonia gas separator.
The above-described embodiments of the present invention are intended to be examples only. Alterations, modifications and variations may be effected to the particular embodiments by those of skill in the art without departing from the scope of the invention, which is defined solely by the claims appended hereto.
Filing Document | Filing Date | Country | Kind |
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PCT/IL2019/051035 | 9/18/2019 | WO | 00 |
Number | Date | Country | |
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62787387 | Jan 2019 | US |