Different tools and techniques may generally be utilized for solidification and/or solid production, such as ice production, drop forming, block freezing, flake freezing, and many other devices.
There may be a need for new tools and techniques to address solidification and/or solid production.
Methods, systems, and device for solidification and/or solid production, such as ice production, are provided in accordance with various embodiments.
For example, some embodiments include a method of solid production that may include contacting a first fluid with a second fluid to facilitate solidifying the second fluid; the first fluid and the second fluid may be immiscible with respect to each other. The method may include solidifying the second fluid.
In some embodiments of the method, the first fluid includes a non-polar material and the second fluid includes a polar material. In some embodiments, the first fluid includes at least hydrocarbon oil, aromatic oil, fluorinated oil, or silicone oil. In some embodiments, the second fluid includes at least water, acidic acid, formic acid, carbocyclic acids, sulfuric acid, ethylene glycol, polyethylene glycol, tert-butyl, or DMSO.
In some embodiments of the method, the first fluid includes a polar material and the second fluid includes a non-polar material. In some embodiments, the first fluid includes at least water, alcohol, propylene glycol, ethylene glycol, DMSO, ammonia, or nitric acid. In some embodiments, the second fluid includes at least fluorinated oil, cresol, high molecular weight silicon oil, high molecular weight hydrocarbon oil, high molecular weight paraffin, thermoset polymer, or metallic alloy. In some embodiments, the first fluid includes water and the second fluid includes at least high-molecular weight paraffin or thermoset polymer, for example.
In some embodiments of the method, contacting the first fluid with the second fluid includes entraining the second fluid within the first fluid. In some embodiments, the first fluid includes aromatic oil and the second fluid includes water. Some embodiments further include cooling the first fluid before entraining the second fluid within the first fluid. In some embodiments, the first fluid and the second fluid are cooled simultaneously.
In some embodiments of the method, entraining the second fluid within the first fluid includes flowing the first fluid and the second fluid through a coil to solidify at least a portion of the second fluid. In some embodiments, one or more hydrodynamic properties of the first fluid form the second fluid into one or more solidified shapes. The one or more solidified shapes may be formed with at least a predictable size or a predictable shape. One or more features of the coil may control the one or more hydrodynamic properties of the first fluid that form the second fluid into the one or more solidified shapes formed with at least the predictable size or the predictable shape. The one or more features of the coil may include at least one or more diameters of the coil, one or more geometries of the coil, one or more interior structures of the coil, one or more orientations of the coil, or one or more lengths of the coil. The one or more features of the coil may include a change in orientation of the coil. The one or more features of the coil may include a change in diameter of the coil.
In some embodiments of the method, entraining the second fluid within the first fluid includes introducing the second fluid as a parallel flow to the first fluid. In some embodiments, entraining the second fluid within the first fluid includes introducing the second fluid as a perpendicular flow to the first fluid.
In some embodiments of the method, contacting the first fluid with the second fluid includes introducing the first fluid and the second fluid with respect to one or more cold surfaces; the first fluid may have an affinity for the one or more cold surfaces. Some embodiments include removing a solidified form of the second fluid from the one or more cold surfaces. The first fluid may coat at least a portion of the one or more cold surfaces and may interfere with the second fluid from adhering to the one or more cold surfaces. In some embodiments, the first fluid includes hydrocarbon oil and the second fluid includes water.
In some embodiments of the method, contacting the first fluid with the second fluid includes mixing the second fluid with the first fluid before introducing the first fluid and the second fluid with respect to the one or more cold surfaces. In some embodiments, contacting the first fluid with the second fluid includes separately introducing the first fluid and the second fluid with respect to the one or more cold surfaces.
In some embodiments of the method, the one or more cold surfaces are comprised of a metal. Some embodiments may include other materials such as plastic, ceramic, and/or glass for the one or more cold surfaces.
In some embodiments of the method, removing the solidified form of the second fluid from the one or more cold surfaces includes utilizing an auger to remove the solidified form of the second fluid from a cylindrically-shaped cold surface. In some embodiments, removing the solidified form of the second fluid from the one or more cold surfaces includes utilizing a rotating scrapper to remove the solidified form of the second fluid from a drum-shaped cold surface. In some embodiments, removing the solidified form of the second fluid from the one or more cold surfaces includes utilizing one or more linear scrappers to remove the solidified form of the second fluid from one or more planar cold surfaces.
Some embodiments include a solid production system that may include a first fluid and a second fluid; the first fluid and the second fluid may be immiscible with respect to each other. The system may include one or more surfaces configured to contact the first fluid and the second fluid with each other and to form one or more solids from the second fluid.
In some embodiments of the system, the one or more surfaces are configured such that the first fluid and the second fluid are contacted with each other such that the second fluid is entrained within the first fluid. The one or more surfaces may include one or more coils configured to solidify at least a portion of the second fluid.
In some embodiments of the system, the one or more surfaces include one or more cold surfaces such that the first fluid has an affinity for the one or more cold surfaces. Some embodiments include one or more solid removers configured to remove a solidified form of the second fluid from the one or more cold surfaces.
In some embodiments of the system, the first fluid includes a non-polar material and the second fluid includes a polar material. In some embodiments, the first fluid includes at least hydrocarbon oil, aromatic oil, fluorinated oil, or silicone oil. In some embodiments, the second fluid includes at least water, acidic acid, formic acid, carbocyclic acids, sulfuric acid, ethylene glycol, polyethylene glycol, tert-butyl, or DMSO. In some embodiments, the first fluid includes aromatic oil and the second fluid includes water. In some embodiments, the first fluid includes hydrocarbon oil and the second fluid includes water.
In some embodiments of the system, the first fluid includes a polar material and the second fluid includes a non-polar material. In some embodiments, the first fluid includes at least water, alcohol, propylene glycol, ethylene glycol, DMSO, ammonia, or nitric acid. In some embodiments, the second fluid includes at least fluorinated oil, cresol, high molecular weight silicon oil, high molecular weight hydrocarbon oil, high molecular weight paraffin, thermoset polymer, or metallic alloy. In some embodiments, the first fluid includes water and the second fluid includes at least high-molecular weight paraffin or thermoset polymer.
Some embodiments of the system include a heat exchanger positioned to cool the first fluid before entraining the second fluid within the first fluid. In some embodiments, the first fluid and the second fluid are cooled simultaneously within the one or more coils. In some embodiments of the system, one or more hydrodynamic properties of the first fluid within the one or more coils form the second fluid into one or more solidified shapes. In some embodiments of the system, the one or more solidified shapes are formed with at least a predictable size or a predictable shape. In some embodiments, one or more features of the coil control the one or more hydrodynamic properties of the first fluid that form the second fluid into the one or more solidified shapes formed with at least the predictable size or the predictable shape. In some embodiments, the one or more features of the coil include at least one or more diameters of the coil, one or more geometries of the coil, one or more interior structures of the coil, one or more orientations of the coil, or one or more lengths of the coil. In some embodiments, the one or more features of the coil include a change in orientation of the coil. In some embodiments, the one or more features of the coil include a change in diameter of the coil.
Some embodiments of the system include a mixing nozzle configured to entrain the second fluid within the first fluid. Some embodiments include a tube positioned within the mixing nozzle such that the second fluid is introduced as a parallel flow to the first fluid. Some embodiments include a tube positioned within the mixing nozzle such that the second fluid is introduced as a perpendicular flow to the first fluid.
In some embodiments of the system, the first fluid coats at least a portion of the one or more cold surfaces and interferes with the second fluid from adhering to the one or more cold surfaces. Some embodiments include a first storage container configured to hold the first fluid and a second storage container configured to hold the second fluid. Some embodiments include a combiner configured to combine the first fluid from the first storage container with the second fluid from the second storage container for delivery to the one or more cold surfaces. Some embodiments include a first conduit coupled with the first storage container and a second conduit coupled with the second storage container; the first conduit and the second conduit may be configured to deliver the first fluid and the second fluid separately to the one or more cold surfaces. In some embodiments, the first conduit is coupled with the one or more solid removers to facilitate delivery of the first fluid to the one or more cold surfaces.
In some embodiments of the system, the one or more cold surfaces are comprised of a metal. Some embodiments may include other materials such as plastic, ceramic, and/or glass for the one or more cold surfaces.
In some embodiments of the system, the one or more solid removers configured to remove the solidified form of the second fluid from the one or more cold surfaces include an auger to remove the solidified form of the second fluid from a cylindrically-shaped cold surface. In some embodiments, the one or more solid removers configured to remove the solidified form of the second fluid from the one or more cold surfaces include a rotating scrapper to remove the solidified form of the second fluid from a drum-shaped cold surface. In some embodiments, the one or more solid removers configured to remove the solidified form of the second fluid from the one or more cold surface include one or more linear scrappers to remove the solidified form of the second fluid from one or more planar cold surfaces.
Some embodiments include methods, systems, and/or devices as described in the specification and/or shown in the figures.
The foregoing has outlined rather broadly the features and technical advantages of embodiments according to the disclosure in order that the detailed description that follows may be better understood. Additional features and advantages will be described hereinafter. The conception and specific embodiments disclosed may be readily utilized as a basis for modifying or designing other structures for carrying out the same purposes of the present disclosure. Such equivalent constructions do not depart from the spirit and scope of the appended claims. Features which are believed to be characteristic of the concepts disclosed herein, both as to their organization and method of operation, together with associated advantages will be better understood from the following description when considered in connection with the accompanying figures. Each of the figures is provided for the purpose of illustration and description only, and not as a definition of the limits of the claims.
A further understanding of the nature and advantages of different embodiments may be realized by reference to the following drawings. In the appended figures, similar components or features may have the same reference label. Further, various components of the same type may be distinguished by following the reference label by a dash and a second label that distinguishes among the similar components. If only the first reference label is used in the specification, the description is applicable to any one of the similar components having the same first reference label irrespective of the second reference label.
This description provides embodiments, and is not intended to limit the scope, applicability or configuration of the disclosure. Rather, the ensuing description will provide those skilled in the art with an enabling description for implementing embodiments of the disclosure. Various changes may be made in the function and arrangement of elements.
Thus, various embodiments may omit, substitute, or add various procedures or components as appropriate. For instance, it should be appreciated that the methods may be performed in an order different than that described, and that various stages may be added, omitted, or combined. Also, aspects and elements described with respect to certain embodiments may be combined in various other embodiments. It should also be appreciated that the following systems, devices, and methods may individually or collectively be components of a larger system, wherein other procedures may take precedence over or otherwise modify their application.
Methods, systems, and device for solidification and/or solid production, such as ice production, are provided in accordance with various embodiments. Some embodiments may provide for the creation of a solid with a high volumetric surface area, the amount of surface area per a given volume of material, using a machine and/process that may involve minimal energy consumption, mechanical complexity, and/or heat transfer area.
Some embodiments may include hydraulically forming the solid while simultaneously causing it to solidify via cooling.
In some embodiments, the hydraulic formation is controlled by the introduction of the two materials into a coil where the hydrodynamic properties of the entraining fluid (the first fluid) may cause the solidifying fluid (the second fluid) to automatically form shapes of a predictable size and/or shape. The hydrodynamic properties of the first fluid may be controlled by specific design features of the coil including, for example, its diameter, geometry, interior structure, length, and/or combination of different zones with changing features.
The fluids in various embodiments are generally immiscible, which may allow for them to directly physical and thermal contact throughout the process. In some embodiments, the first fluid is a non-polar material and the second fluid is a polar material. For example, the first fluid may include a hydrocarbon, aromatic, fluorinated, or silicone oil, where an example of the second fluid may include an immiscible polar fluid, such as water, acidic acid, formic acid or other carbocyclic acids, sulfuric acid, ethylene or polyethylene glycol, medium sized alcohols such as tert-butyl, or DMSO. In some embodiments, the first fluid is a polar material and the second fluid is a non-polar material. For example, the first fluid may include water, alcohol, propylene or ethylene glycol, DMSO, ammonia, or nitric acid where the second fluid may include a fluorinated oil, cresol, a high molecular weight silicon oil, a high molecular weight hydrocarbon oil or paraffin, a thermoset polymer, or a metallic alloy.
Some embodiments include a coil assembly and/or various peripheral equipment that may be utilized for the coil to operate. Those peripherals may include, for example, a pump for the first fluid, a mixing nozzle for both fluids, a heat exchanger for cooling the first fluid or the mixture, and/or containers for storing both the mixture, the first fluid, and the second fluid.
Some embodiments may utilize a cold surface that may be protected by a first fluid. A second fluid may be allowed to come in near contact with the cold surface and solidify. The protection from the immiscible fluid may allow for the solid to be removed using a less or minimally complicated and/or low power mechanical device.
The fluids used in various embodiments are generally immiscible, which may allow for them to physically and/or thermally contact each other throughout the process. Additionally, the first fluid may be chosen based on its affinity for the cold surface. If it has a higher affinity for the surface than the second fluid, surface tension effects may overpower buoyancy or mechanical forces and the cold surface may be protected.
In some embodiments, the first fluid may be an oil such as a hydrocarbon oil, an aromatic oil, or a silicone oil. The second fluid may be a polar fluid such as water or DMSO. In some embodiments, if the cold surface is a metal or plastic, the oil may preferentially cover the surface protecting it even under high hydrostatic or mechanical loading from the water, which may allow for high heat transfer between the water and cold surface but leaving the water poorly adhered to the cold surface so it may be removed with low power and mechanical complexity.
Various examples in accordance with various embodiments are provided. Some embodiments may in general show fluid lines and heat exchangers as non-integral from any other pieces of process equipment. One skilled in the art generally knows that this may not always the case and may be depicted here for clarity. Additionally, not all the representations in these figures are illustrative and may not represent the geometric features of the coil; some may provide greater detail.
Turning now to
In some embodiments of the system 100, the one or more surfaces 109 are configured such that the first fluid 104 and the second fluid 102 are contacted with each other such that the second fluid 102 is entrained within the first fluid 104. The one or more surfaces 109 may include one or more coils configured to solidify at least a portion of the second fluid 102.
In some embodiments of the system 100, the one or more surfaces 109 include one or more cold surfaces such that the first fluid 104 has an affinity for the one or more cold surfaces. Some embodiments include one or more solid removers configured to remove a solidified form of the second fluid 102 from the one or more cold surfaces.
In some embodiments of the system 100, the first fluid 104 includes a non-polar material and the second fluid 102 includes a polar material. In some embodiments, the first fluid 104 includes at least hydrocarbon oil, aromatic oil, fluorinated oil, or silicone oil. In some embodiments, the second fluid 102 includes at least water, acidic acid, formic acid, carbocyclic acids, sulfuric acid, ethylene glycol, polyethylene glycol, tert-butyl, or DMSO. In some embodiments, the first fluid 104 includes aromatic oil and the second fluid 102 includes water. In some embodiments, the first fluid 104 includes hydrocarbon oil and the second fluid 102 includes water.
In some embodiments of the system 100, the first fluid 104 includes a polar material and the second fluid 102 includes a non-polar material. In some embodiments, the first fluid 104 includes at least water, alcohol, propylene glycol, ethylene glycol, DMSO, ammonia, or nitric acid. In some embodiments, the second fluid 102 includes at least fluorinated oil, cresol, high molecular weight silicon oil, high molecular weight hydrocarbon oil, high molecular weight paraffin, thermoset polymer, or metallic alloy. In some embodiments, the first fluid 104 includes water and the second fluid 102 includes at least high-molecular weight paraffin or thermoset polymer.
Some embodiments of the system 100 include a heat exchanger positioned to cool the first fluid 104 before entraining the second fluid 102 within the first fluid 104. In some embodiments, the first fluid 104 and the second fluid 102 are cooled simultaneously within the one or more coils. In some embodiments of the system 100, one or more hydrodynamic properties of the first fluid 104 within the one or more coils form the second fluid 102 into one or more solidified shapes. In some embodiments of the system 100, the one or more solidified shapes are formed with at least a predictable size or a predictable shape. In some embodiments, one or more features of the coil control the one or more hydrodynamic properties of the first fluid 104 that form the second fluid 102 into the one or more solidified shapes formed with at least the predictable size or the predictable shape. In some embodiments, the one or more features of the coil include at least one or more diameters of the coil, one or more geometries of the coil, one or more interior structures of the coil, one or more orientations of the coil, or one or more lengths of the coil. In some embodiments, the one or more features of the coil include a change in orientation of the coil. In some embodiments, the one or more features of the coil include a change in diameter of the coil.
Some embodiments of the system 100 include a mixing nozzle configured to entrain the second fluid 102 within the first fluid 104. Some embodiments include a tube positioned within the mixing nozzle such that the second fluid 102 is introduced as a parallel flow to the first fluid 104. Some embodiments include a tube positioned within the mixing nozzle such that the second fluid 102 is introduced as a perpendicular flow to the first fluid 104.
In some embodiments of the system 100, the first fluid 104 coats at least a portion of the one or more cold surfaces and interferes with the second fluid 102 from adhering to the one or more cold surfaces. Some embodiments include a first storage container configured to hold the first fluid 104 and a second storage container configured to hold the second fluid 102. Some embodiments include a combiner configured to combine the first fluid 104 from the first storage container with the second fluid 102 from the second storage container for delivery to the one or more cold surfaces; the combiner may be an example of a mixing nozzle. Some embodiments include a first conduit coupled with the first storage container and a second conduit coupled with the second storage container; the first conduit and the second conduit may be configured to deliver the first fluid 104 and the second fluid 102 separately to the one or more cold surfaces. In some embodiments, the first conduit is coupled with the one or more solid removers to facilitate delivery of the first fluid 104 to the one or more cold surfaces.
In some embodiments of the system 100, the one or more cold surfaces are comprised of a metal. Some embodiments may include other materials such as plastic, ceramic, and/or glass for the one or more cold surfaces.
In some embodiments of the system 100, the one or more solid removers configured to remove the solidified form of the second fluid 102 from the one or more cold surfaces include an auger to remove the solidified form of the second fluid 102 from a cylindrically-shaped cold surface. In some embodiments, the one or more solid removers configured to remove the solidified form of the second fluid 102 from the one or more cold surfaces include a rotating scrapper to remove the solidified form of the second fluid 102 from a drum-shaped cold surface. In some embodiments, the one or more solid removers configured to remove the solidified form of the second fluid 102 from the one or more cold surface include one or more linear scrappers to remove the solidified form of the second fluid 102 from one or more planar cold surfaces.
Turning now to
In some embodiments, the first fluid 104-a may be extracted from the first fluid storage container 103 and may be sent to the one or more surfaces 109-a that may be configured as an entraining or mixing assembly, which may be an example of the one or more surfaces 109 of
Some embodiments of the system 100-a include a heat exchanger positioned to cooling the first fluid 104-a before entraining the second fluid 102-a within the first fluid 104-a. In some embodiments, the first fluid 104-a and the second fluid 102-a are cooled simultaneously within the one or more coils. In some embodiments of the system 100-a, one or more hydrodynamic properties of the first fluid 104-a within the one or more coils form the second fluid 102-a into one or more solidified shapes. In some embodiments of the system 100-a, the one or more solidified shapes are formed with at least a predictable size or a predictable shape. In some embodiments, one or more features of the coil control the one or more hydrodynamic properties of the first fluid 104-a that form the second fluid 102-a into the one or more solidified shapes formed with at least the predictable size or the predictable shape. In some embodiments, the one or more features of the coil include at least one or more diameters of the coil, one or more geometries of the coil, one or more interior structures of the coil, one or more orientations of the coil, or one or more lengths of the coil. In some embodiments, the one or more features of the coil include a change in orientation of the coil. In some embodiments, the one or more features of the coil include a change in diameter of the coil.
Some embodiments of the system 100-a include a mixing nozzle configured to entrain the second fluid 102-a within the first fluid 104-a. Some embodiments include a tube positioned within the mixing nozzle such that the second fluid 102-a is introduced as a parallel flow to the first fluid 104-a. Some embodiments include a tube positioned within the mixing nozzle such that the second fluid 102-a is introduced as a perpendicular flow to the first fluid 104-a.
Turning now to
The one or more surfaces 109-b may include one or more cold surfaces such that the first fluid 104-b has an affinity for the one or more cold surfaces. For example, the one or more cold surfaces may include a metal while the first fluid may include an oil. In an example case where the second fluid is water, the first fluid's surface energy-based affinity for the metallic cold surface may cause the first fluid to preferentially coat the cold surface. System 100-b may include one or more solid removers 107 configured to remove a solidified form of the second fluid 102-b from the one or more cold surfaces.
In some embodiments of the system 100-b, the first fluid 104-b coats at least a portion of the one or more cold surfaces and interferes with the second fluid 102-b from adhering to the one or more cold surfaces. Some embodiments include a combiner configured to combine the first fluid 104-b from the first storage container 103-b with the second fluid 102-b from the second storage container 101-b for delivery to the one or more cold surfaces. Some embodiments include a first conduit coupled with the first storage container 103-b and a second conduit coupled with the second storage container 101-b; the first conduit and the second conduit may be configured to deliver the first fluid 104-b and the second fluid 102-b separately to the one or more cold surfaces. In some embodiments, the first conduit is coupled with the one or more solid removers 107 to facilitate delivery of the first fluid 104-b to the one or more cold surfaces.
In some embodiments of the system 100-b, the one or more solid removers 107 configured to remove the solidified form of the second fluid 102-b from the one or more cold surfaces include an auger to remove the solidified form of the second fluid 102-b from a cylindrically-shaped cold surface. In some embodiments, the one or more solid removers 107 configured to remove the solidified form of the second fluid 102-b from the one or more cold surfaces include a rotating scrapper to remove the solidified form of the second fluid 102-b from a drum-shaped cold surface. In some embodiments, the one or more solid removers 107 configured to remove the solidified form of the second fluid 102-b from the one or more cold surface include one or more linear scrappers to remove the solidified form of the second fluid 102-b from one or more planar cold surfaces.
Turning now to
Turning now to
The fluids used in various embodiments are generally immiscible, which may allow for them to physically and/or thermally contact each other throughout the process. Additionally, the first fluid may be chosen based on its affinity for the cold surface. If it has a higher affinity for the surface than the second fluid, surface tension effects may overpower buoyancy or mechanical forces and the cold surface may be protected.
In some embodiments, the first fluid is a non-polar material and the second fluid is a polar material. For example, the first fluid may include a hydrocarbon, aromatic, fluorinated, or silicone oil, where an example of the second fluid may include an immiscible polar fluid, such as water, acidic acid, formic acid or other carbocyclic acids, sulfuric acid, ethylene or polyethylene glycol, medium sized alcohols such as tert-butyl, or DMSO. In some embodiments, the first fluid is a polar material and the second fluid is a non-polar material. For example, the first fluid may include water, alcohol, propylene or ethylene glycol, DMSO, ammonia, or nitric acid where the second fluid may include a fluorinated oil, cresol, a high molecular weight silicon oil, a high molecular weight hydrocarbon oil or paraffin, a thermoset polymer, or a metallic alloy. In some embodiments, if the cold surface is a metal or plastic, the oil may preferentially cover the surface protecting it even under high hydrostatic or mechanical loading from the water, which may allow for high heat transfer between the water and cold surface but leaving the water poorly adhered to the surface so it may be removed with low power and mechanical complexity.
For example,
A first fluid 104-o may be released from a storage container 103-o and allowed to flow into a volume 155. A second fluid 102-o may be released from a storage container 101-o and allowed to flow into the same volume 155. The first fluid 104-o and the second fluid 102-o may be immiscible with respect to each other. Inside the volume 155, there may a mechanism such as solid remover 107-o, that may move along a cold surface 109-o that surrounds the volume 155. The first fluid 104-o may have an affinity for the surface 109-o such that the second fluid 102-o may approach the cold surface 109-o and may solidify due to its cold temperature, but it cannot adhere well to the surface 109-o. This may allow the solid remover 107-o to remove solid form of the second fluid 102-o from the surface 109-o at a low speed and torque. The second fluid 102-o may solidify to the desired solid content before leaving the system as a mixture of the first fluid and the second fluid 106-o. The cold surface 109-o may be maintained by a second volume 188 that may surround the first volume 155 and may be chilled with a supply of refrigerant 110. Once the refrigerant 110 removes heat from the cold surface 109-o, it may leave the system via as outlet refrigerant 111.
The first fluid 104-o and the second fluid 102-o may be delivered to the volume 155 and/or cold surfaced 109-o through a variety of conduits 160. For example, conduit 160-o-1 may deliver second fluid 102-o to a combiner 161 where it may be combined with the first fluid 104-o delivered through conduit 160-o-2; the combined fluids may then be delivered to the volume 155 and/or cold surface 109-o. In some embodiments, the first fluid 104-o and the second fluid 102-o may be separately delivered to volume 155 and/or cold surface 109-o. For example, conduit 160-o-3 may deliver the second fluid 102-o separately from the first fluid 104-o delivered through conduit 160-o-4. In some embodiments, the first fluid 104-o may be delivered to the volume 155 and/or cold surface 109-o through conduit 160-o-6 that may be coupled with the solid remover 107-o, which may facilitate deliver of the first fluid 104-o to the cold surface 109-o. In some embodiments, the second fluid 102-o may be delivered to the volume 155 and/or cold surface 109-o through conduit 160-o-5 that may be coupled with the solid remover 107-o, which may facilitate deliver of the second fluid 102-o to the cold surface 109-o. In some embodiments, the first fluid 104-o may be delivered to the volume 155 and/or cold surface 109-o through conduit 160-o-6 coupled with solid remover 107-o, while the second fluid 102-o may be delivered through conduit 160-o-3.
The first fluid 104-q and the second fluid 102-q may be delivered to the volume 155-q and/or cold surface 109-q through a variety of conduits 160-q. For example, conduit 160-q-1 may deliver second fluid 102-q to a combiner 161-q where it may be combined with the first fluid 104-q delivered through conduit 160-q-2; the combined fluids may then be delivered to the volume 155-q and/or cold surface 109-q.
In some embodiments, the first fluid 104-q and the second fluid 102-q may be separately delivered to volume 155-q and/or cold surface 109-q. For example, conduit 160-q-3 may deliver the second fluid 102-q separately from the first fluid 104-q delivered through conduit 160-q-4. In some embodiments, the first fluid 104-q may be delivered to the volume 155-q and/or cold surface 109-q through conduit 160-q-6 that may be coupled with the rotating tool 107-q, which may facilitate deliver of the first fluid 104-q to the cold surface 109-q. In some embodiments, the second fluid 102-q may be delivered to the volume 155-q and/or cold surface 109-q through conduit 160-q-5 that may be coupled with the rotating tool 107-q, which may facilitate deliver of the second fluid 102-q to the cold surface 109-q. In some embodiments, the first fluid 104-q may be delivered to the volume 155-q and/or cold surface 109-q through conduit 160-q-6 coupled with rotating tool 107-q, while the second fluid 102-q may be delivered through conduit 160-q-3.
The first fluid 104-r and the second fluid 102-r may be delivered to the cold surface 109-r through a variety of conduits 160-r. For example, conduit 160-r-1 may deliver second fluid 102-r to a combiner 161-r where it may be combined with the first fluid 104-r delivered through conduit 160-r-2; the combined fluids may then be delivered to the cold surface 109-r. In some embodiments, the first fluid 104-r and the second fluid 102-r may be separately delivered to the cold surface 109-r. For example, conduit 160-r-3 may deliver the second fluid 102-r separately from the first fluid 104-r delivered through conduit 160-r-4. In some embodiments, the first fluid 104-r may be delivered to the cold surface 109-r through conduit 160-r-6 that may be coupled with the linear scrapper 107-r, which may facilitate deliver of the first fluid 104-r to the cold surface 109-r. In some embodiments, the second fluid 102-r may be delivered to the cold surface 109-r through conduit 160-r-5 that may be coupled with the linear scraper 107-r, which may facilitate deliver of the second fluid 102-r to the cold surface 109-r. In some embodiments, the first fluid 104-r may be delivered to the cold surface 109-r through conduit 160-r-6 coupled with linear scrapper 107-r, while the second fluid 102-r may be delivered through conduit 160-r-3.
The first fluid 104-s and the second fluid 102-s may be delivered to the cold surface 109-s through a variety of conduits 160-s. For example, conduit 160-s-1 may deliver second fluid 102-s to a combiner 161-s where it may be combined with the first fluid 104-s delivered through conduit 160-s-2; the combined fluids may then be delivered to the cold surface 109-s. In some embodiments, the first fluid 104-s and the second fluid 102-s may be separately delivered to the cold surface 109-s. For example, conduit 160-s-3 may deliver the second fluid 102-s separately from the first fluid 104-s delivered through conduit 160-s-4. In some embodiments, the first fluid 104-s may be delivered to the cold surface 109-s through conduit 160-s-6 that may be coupled with the linear scrapper 107-s-1 (and/or linear scrapper 107-s-2), which may facilitate deliver of the first fluid 104-s to the cold surface 109-s. In some embodiments, the second fluid 102-s may be delivered to the cold surface 109-s through conduit 160-s-5 that may be coupled with the linear scraper 107-s-1 (and/or linear scrapper 107-s-2), which may facilitate deliver of the second fluid 102-s to the cold surface 109-s. In some embodiments, the first fluid 104-s may be delivered to the cold surface 109-s through conduit 160-s-6 coupled with linear scrapper 107-s-1, while the second fluid 102-s may be delivered through conduit 160-s-3.
Turning now to
At block 1710, a first fluid may be contacted with a second fluid to facilitate solidifying the second fluid; the first fluid and the second fluid may be immiscible with respect to each other. At block 1720, the second fluid may be solidified.
In some embodiments of the method 1700, the first fluid includes a non-polar material and the second fluid includes a polar material. In some embodiments, the first fluid includes at least hydrocarbon oil, aromatic oil, fluorinated oil, or silicone oil. In some embodiments, the second fluid includes at least water, acidic acid, formic acid, carbocyclic acids, sulfuric acid, ethylene glycol, polyethylene glycol, tert-butyl, or DMSO.
In some embodiments of the method 1700, the first fluid includes a polar material and the second fluid includes a non-polar material. In some embodiments, the first fluid includes at least water, alcohol, propylene glycol, ethylene glycol, DMSO, ammonia, or nitric acid. In some embodiments, the second fluid includes at least fluorinated oil, cresol, high molecular weight silicon oil, high molecular weight hydrocarbon oil, high molecular weight paraffin, thermoset polymer, or metallic alloy. In some embodiments, the first fluid includes water and the second fluid includes at least high-molecular weight paraffin or thermoset polymer.
In some embodiments of the method 1700, contacting the first fluid with the second fluid includes entraining the second fluid within the first fluid. In some embodiments, the first fluid includes aromatic oil and the second fluid includes water. Some embodiments further include cooling the first fluid before entraining the second fluid within the first fluid. In some embodiments, the first fluid and the second fluid are cooled simultaneously.
In some embodiments of the method 1700, entraining the second fluid within the first fluid includes flowing the first fluid and the second fluid through a coil to solidify at least a portion of the second fluid. In some embodiments, one or more hydrodynamic properties of the first fluid form the second fluid into one or more solidified shapes. The one or more solidified shapes may be formed with at least a predictable size or a predictable shape. The one or more features of the coil may control the one or more hydrodynamic properties of the first fluid that form the second fluid into the one or more solidified shapes formed with at least the predictable size or the predictable shape. The one or more features of the coil may include at least one or more diameters of the coil, one or more geometries of the coil, one or more interior structures of the coil, one or more orientations of the coil, or one or more lengths of the coil. The one or more features of the coil may include a change in orientation of the coil. The one or more features of the coil may include a change in diameter of the coil.
In some embodiments of the method 1700, entraining the second fluid within the first fluid includes introducing the second fluid as a parallel flow to the first fluid. In some embodiments, entraining the second fluid within the first fluid includes introducing the second fluid as a perpendicular flow to the first fluid.
In some embodiments of the method 1700, contacting the first fluid with the second fluid includes introducing the first fluid and the second fluid with respect to one or more cold surfaces; the first fluid may have an affinity for the one or more cold surfaces. Some embodiments include removing a solidified form of the second fluid from the one or more cold surfaces. The first fluid may coat at least a portion of the one or more cold surfaces and interferes with the second fluid from adhering to the one or more cold surfaces. In some embodiments, the first fluid includes hydrocarbon oil and the second fluid includes water.
In some embodiments of the method 1700, contacting the first fluid with the second fluid includes mixing the second fluid with the first fluid before introducing the first fluid and the second fluid with respect to the one or more cold surfaces. In some embodiments, contacting the first fluid with the second fluid includes separately introducing the first fluid and the second fluid with respect to the one or more cold surfaces.
In some embodiments of the method 1700, the one or more cold surfaces are comprised of a metal. Some embodiments may include other materials such as plastic, ceramic, and/or glass for the one or more cold surfaces.
In some embodiments of the method 1700, removing the solidified form of the second fluid from the one or more cold surfaces includes utilizing an auger to remove the solidified form of the second fluid from a cylindrically-shaped cold surface. In some embodiments, removing the solidified form of the second fluid from the one or more cold surfaces includes utilizing a rotating scrapper to remove the solidified form of the second fluid from a drum-shaped cold surface. In some embodiments, removing the solidified form of the second fluid from the one or more cold surfaces includes utilizing one or more linear scrappers to remove the solidified form of the second fluid from one or more planar cold surfaces.
At block 1710-a, a second fluid may be entrained within a first fluid to facilitate solidifying the second fluid; the first fluid and the second fluid may be immiscible with respect to each other. At block 1720-a, the second fluid may be solidified within the first fluid.
Some embodiments of method 1700-a further include cooling the first fluid before entraining the second fluid within the first fluid. In some embodiments, the first fluid and the second fluid are cooled simultaneously.
In some embodiments of the method 1700-a, entraining the second fluid within the first fluid includes flowing the first fluid and the second fluid through a coil to solidify at least a portion of the second fluid. In some embodiments, one or more hydrodynamic properties of the first fluid form the second fluid into one or more solidified shapes. The one or more solidified shapes may be formed with at least a predictable size or a predictable shape. The one or more features of the coil may control the one or more hydrodynamic properties of the first fluid that form the second fluid into the one or more solidified shapes formed with at least the predictable size or the predictable shape. The one or more features of the coil may include at least one or more diameters of the coil, one or more geometries of the coil, one or more interior structures of the coil, one or more orientations of the coil, or one or more lengths of the coil. The one or more features of the coil may include a change in orientation of the coil. The one or more features of the coil may include a change in diameter of the coil.
In some embodiments of the method 1700-a, entraining the second fluid within the first fluid includes introducing the second fluid as a parallel flow to the first fluid. In some embodiments, entraining the second fluid within the first fluid includes introducing the second fluid as a perpendicular flow to the first fluid.
In some embodiments of method 1700-a, the first fluid includes a non-polar material and the second fluid includes a polar material. In some embodiments, the first fluid includes at least hydrocarbon oil, aromatic oil, fluorinated oil, or silicone oil. In some embodiments, the second fluid includes at least water, acidic acid, formic acid, carbocyclic acids, sulfuric acid, ethylene glycol, polyethylene glycol, tert-butyl, or DMSO. In some embodiments, the first fluid includes aromatic oil and the second fluid includes water.
In some embodiments of the method 1700-a, the first fluid includes a polar material and the second fluid includes a non-polar material. In some embodiments, the first fluid includes at least water, alcohol, propylene glycol, ethylene glycol, DMSO, ammonia, or nitric acid. In some embodiments, the second fluid includes at least fluorinated oil, cresol, high molecular weight silicon oil, high molecular weight hydrocarbon oil, high molecular weight paraffin, thermoset polymer, or metallic alloy. In some embodiments, the first fluid includes water and the second fluid includes at least high-molecular weight paraffin or thermoset polymer.
At block 1710-b, a first fluid and a second fluid may be introduced with respect to one or more cold surfaces. The first fluid may have an affinity for the one or more cold surfaces. Furthermore, the first fluid and the second fluid may be immiscible with respect to each other. At block 1720-b, the second fluid may be solidified with respect to the one or more cold surfaces. At block 1730, a solidified form of the second fluid may be removed from the one or more cold surfaces.
In some embodiments of method 1700-b, the first fluid may coat at least a portion of the one or more cold surfaces and interferes with the second fluid from adhering to the one or more cold surfaces. In some embodiments, the first fluid includes hydrocarbon oil and the second fluid includes water.
In some embodiments of the method 1700-b, contacting the first fluid with the second fluid includes mixing the second fluid with the first fluid before introducing the first fluid and the second fluid with respect to the one or more cold surfaces. In some embodiments, contacting the first fluid with the second fluid includes separately introducing the first fluid and the second fluid with respect to the one or more cold surfaces.
In some embodiments of the method 1700-b, the one or more cold surfaces are comprised of a metal. Some embodiments may include other materials such as plastic, ceramic, and/or glass for the one or more cold surfaces.
In some embodiments of the method 1700-b, removing the solidified form of the second fluid from the one or more cold surfaces includes utilizing an auger to remove the solidified form of the second fluid from a cylindrically-shaped cold surface. In some embodiments, removing the solidified form of the second fluid from the one or more cold surfaces includes utilizing a rotating scrapper to remove the solidified form of the second fluid from a drum-shaped cold surface. In some embodiments, removing the solidified form of the second fluid from the one or more cold surfaces includes utilizing one or more linear scrappers to remove the solidified form of the second fluid from one or more planar cold surfaces.
In some embodiments of method 1700-b, the first fluid includes a non-polar material and the second fluid includes a polar material. In some embodiments, the first fluid includes at least hydrocarbon oil, aromatic oil, fluorinated oil, or silicone oil. In some embodiments, the second fluid includes at least water, acidic acid, formic acid, carbocyclic acids, sulfuric acid, ethylene glycol, polyethylene glycol, tert-butyl, or DMSO. In some embodiments, the first fluid includes hydrocarbon oil and the second fluid includes water.
In some embodiments of the method 1700-b, the first fluid includes a polar material and the second fluid includes a non-polar material. In some embodiments, the first fluid includes at least water, alcohol, propylene glycol, ethylene glycol, DMSO, ammonia, or nitric acid. In some embodiments, the second fluid includes at least fluorinated oil, cresol, high molecular weight silicon oil, high molecular weight hydrocarbon oil, high molecular weight paraffin, thermoset polymer, or metallic alloy. In some embodiments, the first fluid includes water and the second fluid includes at least high-molecular weight paraffin or thermoset polymer.
These embodiments may not capture the full extent of combination and permutations of materials and process equipment. However, they may demonstrate the range of applicability of the method, devices, and/or systems. The different embodiments may utilize more or fewer stages than those described.
It should be noted that the methods, systems and devices discussed above are intended merely to be examples. It must be stressed that various embodiments may omit, substitute, or add various procedures or components as appropriate. For instance, it should be appreciated that, in alternative embodiments, the methods may be performed in an order different from that described, and that various stages may be added, omitted or combined. Also, features described with respect to certain embodiments may be combined in various other embodiments. Different aspects and elements of the embodiments may be combined in a similar manner. Also, it should be emphasized that technology evolves and, thus, many of the elements are exemplary in nature and should not be interpreted to limit the scope of the embodiments.
Specific details are given in the description to provide a thorough understanding of the embodiments. However, it will be understood by one of ordinary skill in the art that the embodiments may be practiced without these specific details. For example, well-known circuits, processes, algorithms, structures, and techniques have been shown without unnecessary detail in order to avoid obscuring the embodiments.
Also, it is noted that the embodiments may be described as a process which may be depicted as a flow diagram or block diagram or as stages. Although each may describe the operations as a sequential process, many of the operations can be performed in parallel or concurrently. In addition, the order of the operations may be rearranged. A process may have additional stages not included in the figure.
Having described several embodiments, it will be recognized by those of skill in the art that various modifications, alternative constructions, and equivalents may be used without departing from the spirit of the different embodiments. For example, the above elements may merely be a component of a larger system, wherein other rules may take precedence over or otherwise modify the application of the different embodiments. Also, several stages may be undertaken before, during, or after the above elements are considered. Accordingly, the above description should not be taken as limiting the scope of the different embodiments.
This application is a non-provisional patent application claiming priority benefit of U.S. provisional patent application Ser. No. 62/553,738, filed on Sep. 1, 2017 and entitled “SOLID PRODUCTION METHODS, SYSTEMS, AND DEVICES,” the entire disclosure of which is herein incorporated by reference for all purposes.
This invention was made with Government support under Contract 1533939 awarded by the National Science Foundation. The Government has certain rights in the invention.
Number | Name | Date | Kind |
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5858957 | Donoghue | Jan 1999 | A |
20170167770 | Hemrle | Jun 2017 | A1 |
Entry |
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International Search Report and Written Opinion, Int'l Appl. No. PCT/US2018/049288, dated Dec. 26, 2018, USPTO. |
Number | Date | Country | |
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20190101315 A1 | Apr 2019 | US |
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62553738 | Sep 2017 | US |