Claims
- 1. A rigid, non-cellular, solid composition having a density of at least 1 g/cc, a percent elongation of less than 100 and which is demoldable within about 5 minutes, without the application of an external source of heat, after admixture of the components of a rapid-setting polyurethane-forming composition, free of catalytic quantities of a catalyst for urethane formation, and comprising
- A. an amine initiated polyol having an OH equivalent weight of from about 50 to less than about 250;
- B. an organic aromatic polyisocyanate;
- C. a liquid modifier compound having a boiling point above about 150.degree. C selected from the group consisting of chlorinated aliphatic compounds and mixtures thereof; and
- wherein components (A) and (B) are present in quantities such that the NCO:OH ratio is from about 0.8:1 to about 1.5:1 and component (C) is employed in quantities of from about 5% to about 60% by weight of the combined weight of components (A), (B) and (C).
- 2. The polyurethane composition of claim 1 wherein components (A) and (B) are present in quantities such that the NCO:OH ratio is from about 0.90:1 to about 1.2:1 and component (C) is present in quantities of from about 15% to about 40% by weight of the combined weight of components (A), (B) and (C) and wherein component (A) has an OH equivalent weight of from about 50 to about 200.
- 3. The polyurethane composition of claim 2 wherein components (A) and (B) are present in quantities such that the NCO:OH ratio is from about 0.95:1 to about 1.05:1.
- 4. The composition of claim 3 wherein component (C) is selected from the group consisting of hexachlorobutadiene, tetrachlorobutadiene, 1,2,3,3-tetrachlorobutane, 1,2,3-trichloropropane, polyepichlorohydrin diol having an equivalent weight above about 700 up to about 4000, chlorinated paraffins, e.g., "Chlorowax" No.40, 1-mercapto-3-chloropropanol-2, 3-chloropropane-1,2-diol, 2-chloropropane-1,3-diol, 1,3-dichloro-2-propanol, and mixtures thereof.
- 5. The composition of claim 4 wherein component (C) is a chlorinated paraffin.
- 6. The composition of claim 5 wherein component (C) has a specific gravity of about 1.15, a viscosity at 25.degree. C of about 25 poises and contains about 40% chlorine by weight.
- 7. The composition of claim 1 cast as a decorative object.
- 8. The composition of claim 1 cast as a machine component.
- 9. The composition of claim 1 cast as a furniture component.
- 10. The composition of claim 3 wherein component (A) is selected from the group consisting of triethanolamine, an adduct of diethylenetriamine with propylene oxide and an adduct of aminoethylethanolamine with propylene oxide.
- 11. The composition of claim 3 wherein component (B) is selected from the group consisting of 2,4-toluenediisocyanate, 2,6-toluenediisocyanate, diphenylmethanediisocyanate, and mixtures thereof.
- 12. The composition of claim 1 wherein component (A) additionally contains a non-amine initiated polyol having an equivalent weight of less than about 200 and the weight ratio of non-amine initiated polyol to amine initiated polyol is less than about 2:1.
- 13. The composition of claim 12 wherein the weight ratio of non-amine initiated polyol to amine initiated polyol is less than about 1:1.
Parent Case Info
This application is a continuation of application Ser. No. 573,679, filed May 1, 1975, now 3,983,069 which is a division of application Ser. No. 405,244, filed Oct. 10, 1973, now 4,001,166 which is a continuation-in-part of application Ser. No. 327,630, filed Jan. 29, 1973 now abandoned, which is a continuation-in-part of Ser. No. 221,784, filed Jan. 28, 1972, now abandoned.
Divisions (1)
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Number |
Date |
Country |
Parent |
405244 |
Oct 1973 |
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Continuations (1)
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Number |
Date |
Country |
Parent |
573679 |
May 1975 |
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Continuation in Parts (2)
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Number |
Date |
Country |
Parent |
327630 |
Jan 1973 |
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Parent |
221784 |
Jan 1972 |
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