Claims
- 1. A rigid, non-cellular, solid composition having a density of at least 1 g/cc, a percent elongation of less than 100 and which is demoldable within about 5 minutes, without the application of an external source of heat, after admixture in the absence of a catalytic quantity of a catalyst for urethane formation and also in the absence of a chemically hindered aromatic diamine of the components of a rapid-setting polyurethane-forming composition comprising
- A. an amine initiated polyol having an OH equivalent weight of from about 50 to less than about 250 and from about 3 to about 8 hydroxyl groups;
- B. an organic aromatic polyisocyanate;
- C. a liquid modifier compound having a boiling point above about 150.degree. C selected from the group consisting of organic phosphates, organic phosphites, organic phosphonates and mixtures thereof; and
- wherein Components (A) and (B) are present in quantities such that the NCO:OH ratio is from about 0.8:1 to about 1.5:1 and Component (C) is employed in quantities of from about 5% to about 60% by weight of the combined weight of components (A), (B) and (C).
- 2. The polyurethane composition of claim 1 wherein components (A) and (B) are present in quantities such that the NCO:OH ratio is from about 0.90:1 to about 1.2:1 and component (C) is present in quantities of from about 15% to about 40% by weight of the combined weight of components (A), (B) and (C) and wherein component (A) has an OH equivalent weight of from about 50 to about 200.
- 3. The polyurethane composition of claim 2 wherein components (A) and (B) are present in quantities such that the NCO:OH ratio is from about 0.95:1 to about 1.05.1.
- 4. The composition of claim 3 wherein component (C) is an organic phosphate.
- 5. The composition of claim 4 wherein component (C) is tricresyl phosphate, triethyl phosphate, or .beta.-chloroethyl phosphate.
- 6. The composition of claim 3 wherein component (C) is an organic phosphite.
- 7. The composition of claim 6 wherein component (C) is tributyl phosphite.
- 8. The composition of claim 3 wherein component (C) is an organic phosphonate.
- 9. The composition of claim 8 wherein component (C9 is bis(2-bromopropyl)-2-bromopropane phosphonate.
- 10. The composition of claim 1 cast as a furniture component.
- 11. The composition of claim 1 cast as a decorative object.
- 12. The composition of claim 1 cast as a machine component.
- 13. The composition of claim 2 wherein Component (A) additionally contains a non-amine initiated polyol having an equivalent weight of less than about 200 and the weight ratio of non-amine initiated polyol to amine initiated polyol is less than about 2:1.
- 14. The composition of claim 13 wherein the weight ratio of non-amine initiated polyol to amine initiated polyol is less than about 1:1.
Parent Case Info
This application is a continuation of application Ser. No. 573,714, filed May 1, 1975, now U.S. Pat. No. 3,966,662 which is a division of application Ser. No. 405,244, filed Oct. 10, 1973, now U.S. Pat. No. 4,001,166 which is a continuation-in-part of application Ser. No. 327,630, filed Jan. 29, 1973, now abandoned which is a continuation-in-part of Ser. No. 221,784, filed Jan. 28, 1972, now abandoned.
Divisions (1)
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Number |
Date |
Country |
Parent |
405244 |
Oct 1973 |
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Continuations (1)
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Number |
Date |
Country |
Parent |
573714 |
May 1975 |
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Continuation in Parts (2)
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Number |
Date |
Country |
Parent |
327630 |
Jan 1973 |
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Parent |
221784 |
Jan 1972 |
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