The present invention generally relates to a solid state battery, and more particularly to a solid state battery having a positive electrode layer, a solid electrolyte layer and a negative electrode layer which are laminated.
A lithium ion secondary battery using a nonaqueous electrolytic solution and the like are used for a power supply for small electronic equipment, an auxiliary power supply for memory backup or the like. However, the lithium ion secondary battery of the above configuration has a risk that an electrolyte solution leaks. Therefore, if the lithium ion secondary battery of the above configuration is used for an auxiliary power supply for memory backup or the like, when surrounding electronic circuits become wet by a leaked electrolytic solution, problems that the electronic circuit breaks down or malfunctions arise. In order to avoid the problem, it has been conventionally performed to mount a lithium ion secondary battery and an electronic circuit on different locations.
However, in recent years, in an electronic equipment in which further miniaturization is required, it becomes an impediment to miniaturization to mount a battery and an electronic circuit on different locations. Hence, in recent years, a battery capable of being mounted on a substrate on which an electronic circuit is mounted has been contrived.
For example, in Japanese Patent Laid-open Publication No. 2002-42885 (hereinafter, referred to as Patent Document 1) and Japanese Patent Laid-open Publication No. 2010-118159 (hereinafter, referred to as Patent Document 2), a configuration of a battery which can be mounted on a substrate together with electronic circuit parts has been proposed.
In these batteries, a battery laminate body including a positive electrode layer, a negative electrode layer and a solid electrolyte layer disposed between these layers is housed in a case (outer casing) which can be mounted on a substrate. Further, in these batteries, battery laminate bodies are arranged so as to be laminated in a direction perpendicular to a mounting surface of the substrate. That is, the battery laminate bodies are laminated in such a way that the positive electrode layers or negative electrode layers in the battery laminate bodies are positioned at a top surface of the battery laminate body. The positive electrode layer and negative electrode layer of the battery laminate body are respectively connected to an external terminal or a current collector by wire bonding, a conductive adhesive or the like in a case.
Patent Document 1: Japanese Patent Laid-open Publication No. 2002-42885
Patent Document 2: Japanese Patent Laid-open Publication No. 2010-118159
In the configuration of the battery described in Patent Document 1, an IC chip is disposed on the battery, and the IC chip is connected to an electrode of the battery through an opening. In this case, since the IC chip is disposed on the battery, a low-profile configuration is insufficient. Also when the battery and the IC chip are lined laterally and mounted on a circuit board or the like, since the IC chip is connected to an electrode of the battery by wire bonding through an opening, a mounting area is increased. For these reasons, it is difficult that the configuration of the battery responds to the demand of further downsizing of electronic equipment.
Further, in the configuration of the battery described in Patent Document 2, a connecting electrode part of a case formed on the bottom surface of the case is connected to an electronic circuit wiring or the like on a substrate by reflow soldering or the like, and thereby, the battery is mounted on the substrate. This battery can be easily mounted on the substrate without increasing a mounting area since the connecting electrode part of the case, which is connected to the electronic circuit wiring or the like on the substrate, is positioned at the bottom surface of the case. However, also in this battery, it is difficult to further downsize a mounting type battery including a battery laminate body and a case housing the battery laminate body since an electrode of the battery laminate body is connected to the connecting electrode part of the case located at the bottom surface of the case by wire bonding.
Hence, it is an object of the present invention to downsize a solid state battery including a battery laminate body and a case housing the battery laminate body.
The solid state battery according to the present invention comprises a battery laminate body formed by laminating a positive electrode layer, a solid electrolyte layer and a negative electrode layer in order, and a case main body housing the battery laminate body. The case main body has a base part which supports the battery laminate body. The positive electrode layer and the negative electrode layer are laminated in a direction in which the base part of the case main body extends.
In the solid state battery of the present invention, the positive electrode layer and the negative electrode layer are laminated in the direction in which the base part of the case main body extends. Therefore, when the base part of the case main body is placed on the surface of a substrate, the positive electrode layer and the negative electrode layer can be arranged next to each other in the direction in which the surface of the substrate extends. According to this configuration, the respective surfaces of the positive electrode layer and the negative electrode layer can face the surface of the substrate. Accordingly, since each of the positive electrode layer and the negative electrode layer can be easily connected to an electronic circuit wiring or the like on the substrate, a battery can be easily mounted on the substrate, for example, when the battery is surface-mounted on the substrate.
Further, it is not necessary that in the case main body, the positive electrode layer and negative electrode layer of the battery laminate body are connected to a connection terminal part for connecting to an electronic circuit wiring or the like on the substrate by wire bonding or the like. According to this configuration, a mounting type solid state battery including a battery laminate body and a case housing the battery laminate body can be downsized.
In the solid state battery of the present invention, an electrode connecting part for bringing an inner side surface of the case main body into conduction with an outer side surface of the case main body is formed at the base part of the case main body, and the electrode connecting part preferably includes a positive electrode connecting part to be connected to the positive electrode layer and a negative electrode connecting part to be connected to the negative electrode layer. According to this configuration, a mounting type solid state battery, which can be easily surface-mounted on a substrate and includes a battery laminate body and a case housing the battery laminate body, can be downsized.
In the above case, a current collector layer is preferably formed on each of the surface of the positive electrode layer on a side which is connected to the positive electrode connecting part and the surface of the negative electrode layer on a side which is connected to the negative electrode connecting part.
Moreover, in the above case, preferably, the battery laminate body has one surface opposite to the surface of the base part, and the other surface opposite to the one surface, and an insulating layer is arranged so as to be brought into contact with the other surface described above.
Preferably, the case main body has a lid portion arranged so as to cover the battery laminate body, and the insulating layer is disposed between the lid portion and the battery laminate body.
Further, the case main body has a lid portion arranged so as to cover the battery laminate body, and the insulating layer may be configured so as to form a part of the lid portion.
When the insulating layer is not formed, a bump layer is preferably formed on each of the surface of the positive electrode connecting part on a side which is connected to the positive electrode layer and the surface of the negative electrode connecting part on a side which is connected to the negative electrode layer.
In the above case, the case main body preferably has a lid portion arranged so as to cover the battery laminate body.
According to the present invention, a state battery including a battery laminate body and a case housing the battery laminate body can be downsized.
Hereinafter, embodiments of the solid state battery of the present invention will be described.
As shown in
As shown in
As shown in
In addition, in the solid state batteries 1 to 3, a gap is present between an outer peripheral surface of the battery laminate body and an inner peripheral surface of the lid portion 30 of the case main body, but the outer peripheral surface of the battery laminate body may be in close contact with the lid portion 30 of the case main body without the gap. The base part 20 and lid portion 30 of the case main body are formed from metal, ceramic or the like. The base part 20 may be formed from ceramic such as alumina, and the lid portion 30 may be formed from metal such as Kovar (Co—Ni—Fe alloy). The insulating layer 40 is formed from ceramic such as alumina, synthetic resins such as fluorine resins (tetrafluoroethylene resin, etc.) and polyimide resins, or the like. The positive electrode connecting part 21 and the negative electrode connecting part 22 are formed from metal such as tungsten filled into a through-hole formed in the base part 20. The positive electrode bump layer 51 and the negative electrode bump layer 52 are made of solder, gold or the like.
In the solid state batteries 1 to 3 of the present invention thus configured, the positive electrode layer 11 and the negative electrode layer 12 are laminated in a direction in which the base part 20 of the case main body extends. Therefore, when the base part 20 of the case main body is placed on the surface of a substrate, the positive electrode layer 11 and the negative electrode layer 12 can be arranged next to each other in a direction in which the surface of the substrate extends. According to this configuration, the respective surfaces of the positive electrode layer 11 and the negative electrode layer 12 can face the surface of the substrate. As a result, since both the positive electrode layer 11 and the negative electrode layer 12 can be directly connected to one surface of the substrate, routing of wiring becomes unnecessary. Therefore, an area necessary for wiring is reduced. As described above, since each of the positive electrode layer 11 and the negative electrode layer 12 can be easily connected to an electronic circuit wiring or the like on the substrate, the solid state batteries 1 to 3 can be easily mounted on the substrate.
Further, it is not necessary that in the case main body, the positive electrode layer 11 and negative electrode layer 12 of the battery laminate body are connected to the positive electrode connecting part 21 and the negative electrode connecting part 22, respectively, as a connection terminal part for connecting to an electronic circuit wiring or the like on the substrate by wire bonding or the like. According to this configuration, mounting type solid state batteries 1 to 3 including a battery laminate body and a case housing the battery laminate body can be downsized. In addition, it is particularly effective in the case of surface-mounting the solid state batteries 1 to 3 of the present invention since each of the positive electrode layer and the negative electrode layer can be connected to an electronic circuit wiring or the like on the substrate without increasing a mounting area.
In the solid state batteries 1 and 2, since the insulating layer 40 is located on the battery laminate body, the insulating layer 40 acts to press the battery laminate body against the base part 20 of the case main body. Therefore, a displacement of the battery laminate body in the case main body can be prevented. Further, when the lid portion 30 is formed from metal, electric short can be prevented.
A battery laminate body formed by laminating a positive electrode layer 11, a solid electrolyte layer 13 and a negative electrode layer 12 in order is shown in
In the solid state batteries 1 and 2 shown in
As shown in
In addition, the number of the battery laminate bodies connected in series is not limited to three and may be two or more. Further, two or more battery laminate bodies connected in series may be housed in the case main body in the form shown in
As shown in
In addition, the number of the battery laminate bodies connected in parallel is not limited to two, and may be two or more. In consideration of a balance between solid state batteries, an even number of battery laminate bodies of two or more are preferably connected. Further, two or more battery laminate bodies connected in parallel may be housed in the case main body in the form shown in
Next, Examples of the solid state battery of the present invention prepared according to the above embodiment will be described. In addition, the embodiment of the solid state battery of the present invention is not limited to the above embodiments.
Hereinafter, Examples 1 to 8 where the solid state batteries of the present invention were prepared will be described.
Li2S and P2S5 were weighed so as to have a molar ratio of 7:3, mixed, mechanically milled, and heated at a temperature of 300° C. for 2 hours, and thereby, a sulfide-based glass ceramics was synthesized. The resulting Li2S—P2S5 as a sulfide-based compound was used as a solid electrolyte. In addition, as the solid electrolyte, sulfide-based compounds such as Li2S—P2S5-GeS2 and Li2S—P2S5—SiS2 other than Li2S—P2S5 can also be used. Further, Li2FeS2 was used as a positive active material, and graphite was used as a negative active material. In addition, as the positive active material, lithium cobalt oxide, lithium manganese oxide and the like can also be used. In addition, as the negative active material, lithium titanium oxide and the like can also be used.
The positive active material and the solid electrolyte were mixed in a weight ratio of 1:1 to prepare a positive electrode material. Further, the negative active material and the solid electrolyte were mixed in a weight ratio of 1:1 to prepare a negative electrode material. Then, a solid electrolyte layer was prepared by putting the solid electrolyte in a 2.6-millimeter-square die, and pressing the solid electrolyte. The positive electrode material was fitted to one side of the solid electrolyte layer in the die, and the negative electrode material was fitted to the other side of the solid electrolyte layer, and the resulting solid electrolyte layer was pressed at a pressure of 330 MPa to prepare a battery laminate body. A battery laminate body of an all solid state secondary battery was prepared in this manner. In addition, an example of a method for preparing an all solid state secondary battery has been described above, but the preparing method is not limited to the above-mentioned method.
In addition, with respect to the size of the battery laminate body prepared, when as shown in
Then, as shown in
On the other hand, as a member constituting a case main body as shown in
Then, the battery laminate body was arranged on the base part 20 in such a way that the current collector layers 111, 121 formed on one side surfaces of the positive electrode layer 11 and the negative electrode layer 12 of the battery laminate body were superimposed on the positive electrode connecting part 21 and the negative electrode connecting part 22, respectively, which were disposed at the base part 20 of the case main body. Moreover, an insulating layer 40 (insulating sheet) made of polyimide was disposed on the battery laminate body.
Next, as another member constituting the case main body as shown in
A charge-discharge test of the solid state battery 1 prepared as described above was carried out at a current density of 0.8 mA/cm2. Consequently, the discharge capacity was 0.1 mAh.
A mounting type solid state battery 3 as described in
A charge-discharge test of the solid state battery 3 prepared as described above was carried out in the same manner as in Example 1. Consequently, the discharge capacity was 0.1 mAh.
A mounting type solid state battery 1 described in
A charge-discharge test of the solid state battery 1 prepared as described above was carried out in the same manner as in Example 1. Consequently, the discharge capacity was 0.1 mAh.
A mounting type solid state battery 1 described in
A charge-discharge test of the solid state battery 1 prepared as described above was carried out in the same manner as in Example 1. Consequently, the discharge capacity was 0.05 mAh.
A mounting type solid state battery 1 described in
A charge-discharge test of the solid state battery 1 prepared as described above was carried out in the same manner as in Example 1. Consequently, the discharge capacity was 0.4 mAh.
A mounting type solid state battery 1 described in
A charge-discharge test of the solid state battery 1 prepared as described above was carried out in the same manner as in Example 1. Consequently, the discharge capacity was 0.6 mAh.
A mounting type solid state battery 1 described in
A charge-discharge test of the solid state battery 1 prepared as described above was carried out in the same manner as in Example 1. Consequently, the discharge capacity was 0.1 mAh.
A mounting type solid state battery 1 described in
A charge-discharge test of the solid state battery 1 prepared as described above was carried out in the same manner as in Example 1. Consequently, the discharge capacity was 0.6 mAh.
It is found from the results of the charge-discharge tests in Examples 1, 3 and 4 that when the width w3 of the solid electrolyte layer 13 is smaller, the discharge capacity of the battery is higher, and therefore the width w3 of the solid electrolyte layer 13 is preferably small.
It is found from the results of the charge-discharge tests in Examples 1, 5, 6 and 8 that when the width w1 of the positive electrode layer 11 and the width w2 of the negative electrode layer 12 are larger, the discharge capacity of the battery is higher. In general, in an all solid state battery, when the width of an electrode is increased, the discharge capacity of the battery often becomes small, but in the solid state battery of the present invention, a high discharge capacity can be achieved even in the case of a large electrode width.
In addition, in the battery laminate body, the electrode width, that is, each of the width w1 of the positive electrode layer 11 and the width w2 of the negative electrode layer 12 is preferably larger than the width w3 of the solid electrolyte layer 13. When the width w3 of the solid electrolyte layer 13 is large, resistance is increased, the resulting capacity is decreased, a rate characteristic is also deteriorated and a capacity per volume of the battery is reduced.
Further, the width w3 of the solid electrolyte layer 13 is preferably 150 μm or more and 300 μm or less. When the width w3 of the solid electrolyte layer 13 falls within the above-mentioned range, a battery having excellent battery characteristics can be obtained. When the width w3 of the solid electrolyte layer 13 is out of the above-mentioned range, the battery characteristics are slightly low.
Moreover, the electrode width, that is, each of the width w1 of the positive electrode layer 11 and the width w2 of the negative electrode layer 12 is preferably 300 μm or more and 2000 μm or less. When the electrode width is more than 1000 μm, an overvoltage is high and the voltage to be applied reaches an end voltage quickly. When the electrode width is less than 300 μm, the capacity becomes small. The electrode width is more preferably 300 μm or more and 1500 μm or less.
It should be considered that the embodiments and Examples disclosed herein are illustrative in all respects and are not intended to be restrictive. The scope of the present invention is defined by the claims rather than by the above-mentioned embodiments and examples, and all modifications and variations which fall within the scope of the claims, or equivalence of the scope of the claims are therefore intended to be embraced by the claims.
A solid state battery which can be easily mounted on a substrate can be obtained, and a mounting type solid state battery can be downsized.
1,2,3,4,5: solid state battery; 11: positive electrode layer; 12: negative electrode layer,; 13: solid electrolyte layer; 20: base part (of a case main body); 21: positive electrode connecting part; 22: negative electrode connecting part; 24: electrode layer; 25: conductive layer; 30: lid part (of a case main body); 31, 40: insulating layer; 51: positive electrode bump layer; 52: negative electrode bump layer; 23, 60, 111, 112, 121, 122: current collector layer
Number | Date | Country | Kind |
---|---|---|---|
2010-279104 | Dec 2010 | JP | national |
The present application is a continuation of International application No. PCT/JP2011/076997, filed Nov. 24, 2011, which claims priority to Japanese Patent Application No. 2010-279104, filed Dec. 15, 2010, the entire contents of each of which are incorporated herein by reference.
Number | Date | Country | |
---|---|---|---|
Parent | PCT/JP2011/076997 | Nov 2011 | US |
Child | 13917765 | US |