The present disclosure discusses embodiments with regard to the semiconductor field. The present disclosure particularly discusses solution-processed thin film transistors, devices utilizing such transistors, and methods of forming such transistors.
This application is a continuation-in-part of U.S. application Ser. No. 10/617,114, filed Jul. 9, 2003, now allowed.
Solution-processed thin film transistors hold great promise to fundamentally change the semiconductor industry. Solution-processed, as applied to modify material and thin film and used herein, refers to those materials that are either soluble in a solution or capable of suspension in a solution so they may be processed by a solution technique, e.g., ink jet printing or spin coating, and formed into a thin film. Their uses run the gamut of transistor uses, and may be formed into light emitting structures. Materials used in the thin films, such as conductive polymers, are durable and can be flexible, thereby providing a range of uses in demanding environments.
The solution-processed thin film transistors also hold the potential to be fabricated by simple techniques, e.g., direct printing of circuits. A long-term goal is to have circuits of solution-processed thin film transistors printed on a substrate in similar fashion to the way ink is patterned in a printing press. Proposed manufacturing techniques seek to employ relatively simple procedures such as inkjet printing. A critical issue, however, remains feature size. Small feature sizes, e.g., small channel lengths, produce small threshold voltages and fast operation. However, introducing techniques to produce small feature sizes, e.g., lithography, may add complexity and expense that contradicts the goal of achieving simply manufactured devices and circuits.
Screen printing is an example technique for patterning drain and source regions of solution-processed thin film transistors. A gap of about 100 μm may be produced by this technique. Other techniques may produce smaller sized gaps, but have limitations such as being limited to use on small substrates. An example is a technique that converts portions of organic polymer materials to dielectric through selective use of UV radiation.
An exemplary solution-processed thin film transistor of the present disclosure includes conductive solution-processed thin film contacts, semiconductor solution-processed thin film active regions, and dielectric solution-processed thin film isolations in a sequence and organization to provide a solution-processed thin film structure capable of transistor operation. During or after the formation of the transistor structure, laser ablation can be applied to one or more of the conductive solution-processed thin film contacts, the semiconductor solution-processed thin film active regions and the dielectric solution-processed thin film isolations to pattern or complete patterning of a material being selectively ablated.
Another exemplary embodiment provides a solution-processed thin film transistor having a number of conductive solution-processed thin film contacts, semiconductor solution-processed thin film active regions, and dielectric solution-processed thin film isolations formed in a sequence and organization to form a solution-processed thin film structure. The embodiment includes the feature that one or more of the semiconductor solution-processed thin film active regions and the dielectric solution-processed thin film isolations have been selectively ablated.
This process can be repeated to form transistors having a number of components and to form a plurality of thin film structures capable of transistor operation and further including a number of device isolations formed by ablating material between structures. Further, in some embodiments, the transistor can include one or more selectively ablated conductive solution-processed thin film contacts.
The transistor embodiments of the present disclosure can be used in many different fields and for many different functions. Some examples of these functions will be discussed in detail herein. For example, transistor embodiments can be used as sensors or switches. With respect to sensors applications, transistors can, for instance, be used to detect the presence of gas, moisture, and/or chemicals contacting the transistor and/or a change in temperature. This can be accomplished by using materials to fabricate at least a portion of the transistor out of materials sensitive to the item to be detected. The sensitivity can be measured, for example, by a change in the resistance and/or the current of the transistor.
The present disclosure also includes a number of display device embodiments. For example, in various embodiments, the display device can include an electro-optical device, a pixel controller for changing optical state of the pixel, and a solution-processed thin film transistor associated with the pixel controller. The solution-processed thin film transistor having a number of conductive solution-processed thin film contacts, semiconductor solution-processed thin film active regions, and dielectric solution-processed thin film isolations formed in a sequence and organization to form a solution-processed thin film structure where one or more of the semiconductor solution-processed thin film active regions and the dielectric solution-processed thin film isolations have been selectively ablated.
In such display device embodiments, transistors can be used to provide many different functions. For example, transistors can provide a logic function, such as being a part of a logic circuit of the pixel controller. Transistors can also provide switching functionality such as being a switch provided between the pixel controller and the electro-optical device.
The present disclosure also includes a number of identification device embodiments. For example, in various embodiments, the identification device can include a logic circuit, an antenna coupled to the logic circuit, and a solution-processed thin film transistor associated with the logic circuit. The solution-processed thin film transistor including a number of conductive solution-processed thin film contacts, semiconductor solution-processed thin film active regions, and dielectric solution-processed thin film isolations formed in a sequence and organization to form a solution-processed thin film structure where one or more of the semiconductor solution-processed thin film active regions and the dielectric solution-processed thin film isolations have been selectively ablated.
Identification devices can come in a variety of form factors, such as: tags, which can be hung or worn by an individual (e.g., necklace, bracelet, anklet, etc.); patches that can be attached to items to be identified and/or tracked; and labels that can be adhered to an item, for example.
In various embodiments, the identification device can communicate wirelessly with a remote device, for example, to provide information during an identification process. In some embodiments, the identification device communicates via radio frequency with a remote device, such as an RFID device (i.e., identification device) communicating with an RFID reader (i.e., remote device).
A remote device can be any suitable device for communicating with the identification device. For example, various remote devices, such as desktop, laptop, portable computing devices, or other devices having logic circuitry and the capability of communicating with the identification device, can be used with embodiments of the present disclosure. Additionally, transistors used in identification devices can be used for various purposes, such as a part of a logic circuit or as a switch.
Embodiments of the present disclosure also include solution-processed thin film transistors including drain, source, and gate contacts formed of conductive solution-processed thin film materials, a semiconductor solution-processed thin film material active region contacting the drain and source contacts and isolated from the gate contact by a dielectric solution-processed thin film material. In some embodiments, the transistor can be formed by a process including depositing, in a rough pattern, the drain and source contacts, and refining the rough pattern by selective laser ablation the semiconductor solution-processed thin film active region.
In such embodiments, the transistor can be formed by a process including refining the rough pattern to create a transistor channel. The transistor can also be formed by a process including refining the rough pattern through an optical mask to ablate multiple features simultaneously. In some embodiments, the transistor can be formed by a process including varying one or both of a laser wavelength and intensity during the laser ablation process.
The present disclosure also includes embodiments providing a solution-processed thin film transistor formation method. For example, in various embodiments, the method includes forming solution-processed thin film layers into a transistor structure, wherein the transistor structure includes a semiconductor solution-processed thin film active region, and a dielectric solution-processed thin film isolation. During the forming process, portions of the transistor structure may be patterned via laser ablation, using laser wavelength tuned to be absorbed by material being patterned and to minimally damage material underlying material being patterned. This process can be repeated to form a plurality of thin film structures capable of transistor operation and further including forming device isolations by ablating material between structures.
In various embodiments, methods can also include filling the device isolations with dielectric solution-processed thin film material
The present disclosure includes solution-processed thin film transistor formation that makes use of selective laser ablation to remove material as part of a patterning process, transistors formed by such processes, and devices having transistors therein. Solution-processed, as applied to modify material and thin film and used herein, refers to those materials that are either soluble in a solution or capable of suspension in a solution so they may be processed by a solution technique, e.g., ink jet printing or spin coating, and formed into a thin film. Exemplary categories of solution-processed thin films include organic thin films and polymer thin film categories.
For instance, the majority of the solution-processed materials that can be formed into thin films are the conductive polymers, semiconductive polymers, and dielectric polymers. However, a solution-processed material may also be a precursor of small organic molecular material that is soluble in a solvent. One example is the pentacene precursor that is soluble in chloroform. It can be spin-coated to form a thin film and then heated to reduce to pentacene, for example, at temperatures of ˜200 C. Pentacene is an organic semiconductor but is not a polymer. Also, there may be inorganics that may be solution-processed to form thin films.
In exemplary embodiments, a solution based processing is used to roughly pattern a portion of a solution-processed thin film transistor being formed. For example, solution processing techniques may form into rough pattern conductive solution-processed thin film contacts, semiconductor solution-processed thin film active regions, or dielectric solution-processed thin film isolations in a sequence and organization to form a solution-processed thin film structure capable of transistor operation.
Patterning of contacts, active regions, or isolations may be refined by selective laser ablation. For example, the ablation can be tuned to a wavelength to achieve maximum absorption by the material being ablated and to minimize damage to material under the material being ablated. In other embodiments of the present disclosure, laser ablation can be used to partially or to completely pattern a contact, active region, and/or dielectric.
In such embodiments, rough patterning in the solution based processing deposition may be unnecessary. As an example, conductive polymer material is deposited by solution based processing without a pattern. Selective laser ablation then is used to pattern contacts, e.g., circuit interconnect patterns, in the solution-processed conductive material. The laser radiation may also be directed through an optical mask, permitting the formation of relatively complex patterns simultaneously, e.g., the ablation of multiple channel areas, on one or more transistors, at the same time.
The embodiments of the present disclosure will now be illustrated with respect to exemplary embodiment thin film transistor devices. In describing the embodiments of the present disclosure, particular exemplary devices and device applications will be used for purposes of illustration, but the embodiments of the present disclosure are not limited to the formation of the particular illustrated devices.
Dimensions and illustrated devices may be exaggerated for purposes of illustration and understanding of the embodiments of the present disclosure. Reference numerals may be used in different embodiments to indicate similar features. The elements of the drawings are not necessarily to scale relative to each other. Rather, emphasis has instead been placed upon clearly illustrating the embodiments of the present disclosure. A device illustrated in one fashion by a two-dimensional schematic layer structure will be understood by artisans to provide teaching of three-dimensional device structures and integrations, for example.
The exemplary embodiments may be constructed with any combination of solution-processed electronic materials capable of being formed into thin films. By way of example, poly (e.g., 3, 4-ethylenedioxythiophene), also called PEDOT, is a conductive polymer suitable for drain, gate, and source contacts. An exemplary suitable semiconductive polymer is poly (3-hexylthiophene-2, 5-diyl), also called P3HT. An exemplary dielectric polymer is poly (vinylphenol), also called PVP. Other suitable exemplary polymer materials, like the above examples, will exhibit the ability to be solution processed and formed into very thin films.
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Formation of the thin film layer may be conducted by a suitable solution processed deposition. For example, spin coating is an exemplary suitable deposition technique. Spin coating can also be utilized for the deposition of a dielectric solution-processed thin film material to form an isolation layer 24 over the active region thin film layer 22. Conductive solution-processed thin film material is then deposited upon the isolation layer 24 to form a gate contact 26.
The gate contact deposit can be accomplished by inkjet printing. In addition, there may be a rough deposition of the gate contact 26 followed by selective ablation for refining the pattern. The gate contact 26 may form part of a circuit interconnect pattern, as well.
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A dielectric solution-processed thin film material thin film layer 24 can then be formed over the gate contact 26 and exposed portions of the substrate. This can then be followed by deposit of a semiconductor solution-processed thin film material active region thin film layer 22. In
In
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A dielectric solution-processed thin film material thin film layer 24 can then be formed over the gate contact 26 and exposed portions of the substrate. Conductive solution-processed thin film material 16 can be deposited on the dielectric solution-processed thin film material layer 24.
In
The resultant transistors illustrated in
In sensor embodiments, a portion of the transistor can be formed from a material that is sensitive to a particular item, such as temperature, light, moisture, one or more gases, and/or one or more chemicals. For example, in the transistor illustrated in
In
In various embodiments, such as that shown in
It will be appreciated from reading the present disclosure that displays having small numbers of pixel cells are illustrated in various
The gate lines are connected to the row scanning circuit 124 enabling the gate lines to be scanned. The signal lines are similarly connected respectively through scanning switches 128 to respective input lines for red, green and blue video signals. Thus each switch and local liquid crystal material defines a sub-pixel for a given color.
The three sub-pixels for the three colors define a pixel area. Typically each sub-pixel is oval or rectangular in shape, while the three sub-pixels forming the pixel generally define a square shape. By driving the switch and selectively applying voltage to the pixel electrode through the transistor 130, an electrical field is created which changes the orientation of the liquid crystal material. Selective control of the switches thus leads to control of the liquid crystal in each pixel area so as to form a desired image.
Circuitry can control such structure through hardware circuitry that uses solid state logic, for example, or through computer executable instructions or a combination of the two. For instance, circuitry, such as data processing circuitry, can receive encoded data, decode the encoded data, and convey the decoded data to one, multiple, and/or groups of pixel cells. Circuitry can also be used to provide control signals 126. The sending, receiving, decoding, and conveying functions can also be accomplished by computer executable instructions or a combination of hardware and software.
In these embodiments, a processor can be provided to control a number of display device functions. Processors and other logic circuit can incorporate transistors and described in the embodiments of the present disclosure.
The display device can also include memory in some embodiments. The memory can be used, for example, to hold the computer executable instructions and other information useful in providing the above described functions. Memory can include the various volatile and non-volatile memory types, such as ROM, RAM, and flash memory, for example. Computer readable medium, as it is used herein, includes the various types of memory within a display system or device.
In various embodiments, the signals regarding when a pixel cell is to be illuminated can be conveyed to the pixel cells. For example, in some embodiments, a transmitter transmits encoded data regarding the illumination of a pixel and the display device circuitry decodes the encoded data and conveys the decoded data to one or more pixel cells to activate each pixel cell. As used herein, activating means to illuminate one or more pixel cells based upon the signal received. In various embodiments, pixel cell 106-1-1 can include circuitry for receiving and interpreting a signal.
While specific embodiments of the present disclosure have been shown and described, it should be understood that other modifications, substitutions and alternatives are apparent to one of ordinary skill in the art. Such modifications, substitutions and alternatives can be made without departing from the spirit and scope of the present disclosure, which should be determined from the appended claims.
Although specific embodiments have been illustrated and described herein, it is to be understood that the above descriptions have been made in an illustrative fashion and not a restrictive one. Those of ordinary skill in the art will appreciate that an arrangement calculated to achieve the same results with different permutations of the disclosed techniques can be substituted for the specific embodiments shown or described. The scope of the various embodiments of the present disclosure includes other applications in which the devices, methods, and systems described herein are utilized. Therefore, the scope of various embodiments of the present disclosure should be determined with reference to the appended claims, along with the full range of equivalents to which such claims are entitled.
In the foregoing Detailed Description, various features are grouped together in a single embodiment for the purpose of streamlining the disclosure. This method of disclosure is not to be interpreted as reflecting an intention that the embodiments of the invention require more features than are expressly recited in each claim. Rather, as the following claims reflect, inventive subject matter may lie in less than all features of a single disclosed embodiment. Thus, the following claims are hereby incorporated into the Detailed Disclosure by reference, with each claim standing on its own as a separate embodiment.
Number | Date | Country | |
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Parent | 10617114 | Jul 2003 | US |
Child | 11166443 | Jun 2005 | US |