This application is the U.S. National Stage of International Application No. PCT/EP2013/000344 filed on Feb. 5, 2013, which claims priority to European patent application no. EP 12 154 994.3 filed on Feb. 10, 2012.
The present invention relates to spacer profiles and to insulating glass units with elements in the interspace between glass panes such as screens, blinds or similar interspace elements incorporating the spacer profiles.
Insulating glass units having at least two glass panes, which are held apart from each other in the insulating glass unit, are known. Insulating glass units are normally formed from an inorganic or organic glass or from other materials like Plexiglas. Therefore, the panes are also named glazing panes. Normally, the separation of the glazing panes is secured by a spacer frame (see reference number 1 in
Various designs have been utilized for insulating glass units that are intended to provide good heat insulation. According to one design, the intervening space between the panes is preferably filled with inert, insulating gas, e.g., such as argon, krypton, xenon, etc. Naturally, this filling gas should not be permitted leak out of the intervening space between the panes. Consequently, the intervening space between the panes must be sealed accordingly. Moreover, nitrogen, oxygen, water, etc., contained in the ambient air naturally also should not be permitted to enter into the intervening space between the panes. Therefore, the spacer profile must be designed so as to prevent such diffusion. In the description below, when the term “diffusion impermeability” is utilized with respect to the spacer profiles and/or the materials forming the spacer profile, vapor diffusion impermeability, as well as also gas diffusion impermeability for the gases relevant herein, are meant to be encompassed within the meaning thereof.
Furthermore, the heat transmission of the edge connection, i.e. the connection of the frame of the insulating glass unit, of the glazing panes, and of the spacer frame, in particular, plays a very large role for achieving low heat conduction of these insulating glass units. Insulating glass units, which ensure high heat insulation along the edge connection, fulfill “warm edge” conditions as this term is utilized in the art.
Conventionally, spacer profiles were manufactured from metal. Such metal spacer profiles can not, however, fulfill “warm edge” conditions. Thus, in order to improve upon such metal spacer profiles, the provision of synthetic material on the metal spacer profile has been described, e.g., in U.S. Pat. No. 4,222,213 or DE 102 26 268 A1.
Although a spacer, which exclusively consists of a synthetic material having a low specific heat conductivity, could be expected to fulfill the “warm edge” conditions, the requirements of diffusion impermeability and strength would be very difficult to satisfy.
Other known solutions include spacer profiles made of synthetic material that are provided with a metal film as a diffusion barrier and reinforcement layer, as shown, e.g., in EP 0 953 715 A2 (family member U.S. Pat. No. 6,192,652) or EP 1 017 923 (family member U.S. Pat. No. 6,339,909) or DE 10 2010 006 127 A1 (family member US 2012/0297708 A1).
Such composite spacer profiles use a profile body made of synthetic material with a metal film, which should be as thin as possible in order to satisfy the “warm edge” conditions, but should have a certain minimum thickness in order to guarantee diffusion impermeability and strength. Such prior art “warm edge” spacer elements are usually solely designed with the purpose of obtaining “warm edge” conditions in insulating glass units such as double glazing systems, and hence cannot act as supports for interspace elements such as screens or blinds to be mounted therein. In other words, these “warm edge” spacer elements do not have the physical properties that can be typically obtained in extruded aluminum elements or bended/folded metal sheets, and hence cannot act as supports for interspace elements such as screens or blinds to be mounted in insulating glass units such as double glazing systems.
A double window pane assembly with a blind as an interspace element using spacer elements made of folded metal sheets or extruded metal profiles as guide elements for the interspace blinds is known from WO 2006/000219 A1 and U.S. Pat. No. 2,915,793. EP 0 688 934 A2 (family member U.S. Pat. No. 5,313,761) discloses a spacer assembly for an insulating glass unit for forming a spacer frame to which a mounting bar assembly is to be secured using clip means, which are secured to the spacer frame via latches connecting to flanges at the spacer frame.
EP 0 230 160 A1, U.S. Pat. No. 4,604,840, EP 1 129 270 B1, JP 2000-319091 A, CN 2329746 Y, WO 03/087519 A1 and GB 2 432 179 A also describe interspace blind element arrangements. U.S. Pat. No. 6,108,999, GB 2 411 201 A and DE 42 26 883 A1 describe to arrange double glass units with a specific type of outer glass panes and different types of panes arranged in the interspace for providing impact-resistance, fire-resistance or additional insulation.
It is an object of the invention to provide improved spacer profiles, which enable to fulfill the “warm edge” conditions and mount interspace elements such as blinds in the interspace(s) of insulating glazing units.
Additional features and objects will be apparent from the description of the exemplary embodiments with consideration of the figures, which show:
a) and b), respectively, perspective cross-sectional views of the configuration of the glazing panes and spacer profile in a conventional insulating glazing unit.
Embodiments of the present teachings will be described in greater detail below with references to the figures. The same features/elements are marked with the same reference numbers in all figures. For the purpose of clarity, all reference numbers have not been inserted into all figures. The 3-dimensional (x, y, z) reference system shown in
A spacer profile 1 according to a first embodiment and an insulating glazing unit 50 using the same with a blind as an interspace element will now be described with reference to
In
Herein, the term “elastic-plastic deformable” preferably means that elastic restoring forces are active in the material after a bending process, as is typically the case for synthetic materials for which only a part of the bending takes place with a plastic, irreversible deformation. Further, the term “poor heat conducting” preferably means that the specific heat conductivity (thermal conductivity) λ is less than or equal to about 0.3 W/(mK).
The first material is preferably a synthetic material, more preferably a polyolefin and still more preferably polypropylene, polyethylene terephthalate, polyamide or polycarbonate. An example of such a polypropylene is Novolen® 1040K. The first material preferably has an E-modulus of less than or equal to about 2200 N/mm2 and a specific heat conductivity λ less than or equal to about 0.3 W/(mK), preferably less than or equal to about 0.2 W/(mK).
The profile body 10 is firmly bonded (e.g., fusion and/or adhesive bonded) with a one-piece diffusion barrier film 30. The diffusion barrier film 30 is formed from a second material. The second material is preferably a plastic deformable material. Herein, the term “plastic deformable” preferably means that practically no elastic restoring forces are active after the deformation. This is typically the case, for example, when metals are bent beyond their elastic limit (apparent yield limit). Preferably, the second material is a metal, more preferably stainless steel or steel having a corrosion protection of tin (such as tin plating) or zinc. If necessary or desired, a chrome coating or a chromate coating may be applied thereto.
Herein, the term “firmly bonded” preferably means that the profile body 10 and the diffusion barrier film 30 are durably connected with each other, e.g. by co-extrusion of the profile body with the diffusion barrier film, and/or if necessary, by the application of an adhesive material. Preferably, the cohesiveness of the connection is sufficiently large that the materials are not separable in the peel test according to DIN 53282.
Furthermore, the diffusion barrier film additionally also preferably acts as a reinforcement element. Its thickness (material thickness) d1 is preferably less than or equal to about 0.30 mm, more preferably less than or equal to 0.20 mm, still more preferably less than or equal to 0.15 mm, still more preferably less than or equal to 0.12 mm, and still more preferably less than or equal to 0.10 mm. Moreover, the thickness d1 preferably is greater than or equal to about 0.10 mm, preferably greater than or equal to 0.08 mm, still preferably greater than or equal to 0.05 mm and still preferably greater than or equal to 0.03 mm. The maximum thickness is chosen so as to correspond to the desired specific heat conductivity and stability. As the film is made thinner, the “warm edge” conditions will be increasingly fulfilled. Each of the embodiments shown in the figures preferably has a thickness in the range of 0.05 mm-0.13 mm.
The preferred material for the diffusion barrier film is steel and/or stainless steel having a specific heat conductivity λ less than or equal to about 50 W/(mK), more preferably less than or equal to about 25 W/(mK) and still more preferably less than or equal to 15 W/(mK). The E-modulus of the second material preferably falls in the range of about 170-240 kN/mm2 and is preferably about 210 kN/mm2. The breaking elongation of the second material is preferably greater than or equal to about 15%, and more preferably greater than or equal to about 20%. An example of stainless steel film is the steel film 1.4301 or 1.4016 according to DIN EN 10 08812 having a thickness of 0.05 mm and an example of a tin plate film is a film made of Antralyt E2, 8/2, 8T57 having a thickness of 0.125 mm.
The profile body 10 comprises an inner wall 21 and an outer wall 22 separated by a distance h4 in the height direction y and two side walls 11, 12 that are separated by a distance b2 in the traverse direction x, and extend essentially in the height direction y. The side walls 11, 12 are connected via the inner wall 21 and outer wall 22, so that a chamber 20 is formed for accommodating hygroscopic material. The chamber 20 is defined on its respective sides in cross-section by the walls 11, 12, 21, 22 of the profile body 10. The chamber 20 comprises the height h4 in the height direction y. The side walls 11, 12 are formed as attachment bases for attachment to the inner sides of the glazing panes. In other words, the spacer profile is preferably adhered to the respective inner sides of the glazing panes via these attachment bases (see
The inner wall 21 is defined herein as the “inner” wall, because it faces inward toward the intervening space 53 between the glazing panes in the assembled state of the insulating glazing unit. This side of the spacer profile, which faces towards the intervening space between the glazing (e.g. window) panes, is designated in the following description as the inner side 13 in the height direction y of the spacer profile 1. The outer wall 22, which is arranged in the height direction y on the opposite side of the chamber 20, faces away from the intervening space 53 between the glazing panes in the assembled state and therefore is defined herein as the “outer” wall. This side of the spacer profile, which faces away from the intervening space between the glazing (e.g. window) panes, is designated in the following description as the outer side 14 in the height direction y of the spacer profile 1.
According to the Wave-configuration shown in
The side walls 11, 12 extend in the height direction y beyond the inner wall 21, in the shown embodiment over a height h3. These portions of the side walls 11, 12, extending beyond the inner wall 21 are named side wall legs 11b, 12b in the following. The portions of the side walls 11, 12 defining the chamber 20, i.e. those portions adjacent to the legs 11b, 12b, are indicated as upper side wall portions 11a, 12a in the following. As can be seen in
The legs 11b, 12b have a thickness d1 in the transverse direction x and the upper side wall portions 11a, 11b have a thickness d2 in the transverse direction x. The inner wall 21 has a thickness d4 in the height direction y and the outer wall 22 has a thickness d5 in the height direction y. The thicknesses d1 and d2 are selected essentially based on stability criteria, whereas the thicknesses d4 and d5 are selected according to stability criteria but also in view of heat insulating characteristic criteria. The thicknesses d4 and d5 can be selected to be identical, but preferably the thickness d5 is smaller than the thickness d4 as the barrier layer 30 will contribute to the stability of the outer wall 22.
The concave portions 22a, 22b representing the connection/transitions between the side walls 11, 12 and the outer wall 22 have a width b5 in the transverse direction x from the outside of the upper side wall portions 11a, 12a to the last vertical portion forming the direct transition into the outer wall 22. The width b5 is selected to be as small as possible but still allowing a concave portion with a bottom being closer to the inner side 13 than the tips of the upper side wall portions 11a, 12a. The width b5 is preferably in the range of 5 to 15% of the width b4, i.e. of the distance b4 between the outer sides of the upper side wall portions 11a, 12a.
The legs 11b, 12b have a distance b2 in the transverse direction x. The legs and the inner wall 21 define a recess 40 open to the inner side 13, which open recess 40 may be embodied as a groove. At the sides of the legs 11b, 12b facing each other in transverse direction x, protrusions 16a, 16b are provided in a height h2=hp. The protrusions have a distance b3 in the transverse direction x smaller than the width b2 of the open recess 40. The protrusions 16a, 16b have, seen in the plane x-y, an approximately rectangular shape and extend along the longitudinal direction z as can be seen in
The protrusions 16a, 16b have a height or thickness d6 in the height direction y.
In the embodiment shown in
Openings 15 (only shown in
The diffusion barrier film 30 is formed on the outer sides of the outer wall 22 and of the side walls 11, 12, which face away from the chamber 20. The film 30 extends along the side walls 11, 12 in the height direction y (seen from the outer side 14) to the height h4 of the chamber 20 and then inside the side walls 11, 12 to the (same) height h2=hp of protrusions 16a, 16b and horizontally into the same to a depth b6. In an alternative, the protrusions 16a, 16b may be provided at different heights. The L-shaped or flange shaped portions 31a, 31b of the diffusion barrier film 30 are profiled portions, each having a profile 31a, 31b. Herein, the term “profile” preferably means that the elongation portion not only means a linear elongation of the diffusion barrier film 30, but instead that a two-dimensional profile is formed in the two-dimensional view of the cross-section in the x-y plane, which profile is formed, for example, by one or more bends and/or angles in the elongation portion 31a, 31b or 31c, 31d.
According to the embodiment shown in
As is shown in
The protrusions 16a, 16b and the recesses 17a, 17b are formed to be capable of retaining an interspace element holding means 70. An embodiment of an interspace holding element 70 is shown in
The interspace element holding means 70 shown in
The interspace holding means 70 in form of the metal clamp shown in
As can bee seen from
The spacer profile 1 shown in
As can be seen very well in
In
After mounting the interspace element 80 and connecting it to the interspace element holding means 70, the second glazing pane 51 is attached to the spacer profile frame 100 using adhesive material 61 and the sealing 62 is attached in the manner already described. The corresponding assembly is shown in
All details concerning the first embodiment also apply to all the other described embodiments, except when a difference is expressly noted or is shown in the figures.
A second embodiment of the spacer profile 1 is shown in
Further possible modifications of the embodiments are discussed below. Obviously, an interspace element 80 could also be directly held by the retaining means 17a, 17b without using the intermediate interspace element holding means 70, if the interspace elements 80 are adapted to be retained. However, it is preferable to use the interspace element holding means 70 to ensure better heat insulation characteristics. In particular, the interspace holding element retaining means could be formed to provide a heat conduction cross-section as small as possible, in comparison to a direct holding of the interspace elements 80. In order to maintain “warm edge” characteristics, this may be of great importance. The legs 11b, 12b are in particular useful, if elements moving in the intervening space 53 are used such as blinds.
The interspace element holding means 70 can also be integrated in the spacer profile 1, e.g., by coextruding the spacer profile with the interspace holding means 70 in form of a metal clamp. The legs 11b, 12b of the spacer profile 1 may be adapted to guide moving portions of the interspace element 80. For example, the legs 11b, 12b may be adapted to guide the slats of a blind. In case of insulating glass units with a low emissivity coating on the insides of the glass panes, the legs 11b, 12b may be adapted to prevent a contact/damage of the same by the interspace element, especially by providing a shape and/or thickness of the legs preventing such a contact even in case of thermal expansion or other deformation of the glass pane and/or the interspace element. The legs 11b, 12b of the spacer profile 1 may be adapted to cover a lateral gap between the interspace element 80 and the spacer profile 1. For example, the legs 11b, 12b may be adapted to cover a lateral gap between a box of the blind at the top of the insulating glass unit or at the bottom end of the same and/or they may be adapted to cover the lateral ends of the slats of a blind. For example, the legs may entirely enclose the outer pats of a blind or other interspace element 80 and hide any end imperfection or the like. The spacer profile may be manufactured in different colors. In case of using suitable materials, especially PP, the coloring material may be provided “inside” the PP and no film or coated surfaces are necessary, which may be subject to visible scratches. Different colors of different portions such as a difference between the indoor and outdoor sides are possible. The diffusion barrier film 30 may be formed and positioned in the spacer profile 1 such that the diffusion barrier film 30 forms the surface of the spacer profile 1 at those portions of the spacer profile 1, which are in contact with the retained interspace element holding means 70 or the retained interspace element 80. For example, such contact portions are those portions of the protrusions 16a, 16b which contact the retained portion 71 at the lateral edges 72a, 72b under load. When the diffusion barrier film 30 forms the surface of the spacer profile 1 at those portions of the spacer profile 1, no flow of the elastic-plastic deformable material such as PP will occur under the weight load exerted at the contact portions. In the second embodiment, the barrier film portions 31x, 31y extending in the legs 11b, 12b may be formed of two parts separated e.g. at the 180° bends in the protrusions. In such a case the lower parts are basically L-shaped parts added to but separated from the barrier film of
The insulating glass units can be used for doors, windows, facade elements, indoor partition walls, roofs and the like. The material of the glazing panes is not limited to glass but can be other transparent or semi-transparent glazing materials like Plexiglas or others.
It is explicitly stated that all features disclosed in the description and/or the claims are intended to be disclosed separately and independently from each other for the purpose of original disclosure as well as for the purpose of restricting the claimed invention independent of the composition of the features in the embodiments and/or the claims. It is explicitly stated that all value ranges or indications of groups of entities disclose every possible intermediate value or intermediate entity for the purpose of original disclosure as well as for the purpose of restricting the claimed invention, in particular as limits of value ranges.
Number | Date | Country | Kind |
---|---|---|---|
12154994 | Feb 2012 | EP | regional |
Filing Document | Filing Date | Country | Kind |
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PCT/EP2013/000344 | 2/5/2013 | WO | 00 |
Publishing Document | Publishing Date | Country | Kind |
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WO2013/117320 | 8/15/2013 | WO | A |
Number | Name | Date | Kind |
---|---|---|---|
2094381 | Slayter | Sep 1937 | A |
2235680 | Haven et al. | Mar 1941 | A |
2525717 | Ottenheimer | Oct 1950 | A |
2741809 | Englehart | Apr 1956 | A |
2838809 | Zeolla | Jun 1958 | A |
2873486 | Hughes | Feb 1959 | A |
2877516 | Bobel | Mar 1959 | A |
2915793 | Berg | Dec 1959 | A |
2934801 | Blaszkowski | May 1960 | A |
2974377 | Kunkle | Mar 1961 | A |
3008196 | Springer et al. | Nov 1961 | A |
3168089 | Larkin | Feb 1965 | A |
3220065 | Graham | Nov 1965 | A |
3702040 | Roy | Nov 1972 | A |
3758996 | Bowser | Sep 1973 | A |
3872198 | Britton | Mar 1975 | A |
3998680 | Flint | Dec 1976 | A |
4015394 | Kessler | Apr 1977 | A |
4080482 | Lacombe | Mar 1978 | A |
4149348 | Pyzewski | Apr 1979 | A |
4222213 | Kessler | Sep 1980 | A |
4407105 | Frank | Oct 1983 | A |
4479988 | Dawson | Oct 1984 | A |
4604840 | Mondon | Aug 1986 | A |
4658553 | Shinagawa | Apr 1987 | A |
4979552 | van der Zanden | Dec 1990 | A |
5079054 | Davies | Jan 1992 | A |
5125195 | Brede | Jun 1992 | A |
5178200 | Hagen | Jan 1993 | A |
5209034 | Box et al. | May 1993 | A |
5290611 | Taylor | Mar 1994 | A |
5302425 | Taylor | Apr 1994 | A |
5313761 | Leopold | May 1994 | A |
5313762 | Guillemet | May 1994 | A |
5424111 | Farbstein | Jun 1995 | A |
5439716 | Larsen | Aug 1995 | A |
5460862 | Roller | Oct 1995 | A |
5678377 | Leopold | Oct 1997 | A |
5679419 | Larsen | Oct 1997 | A |
5851609 | Baratuci et al. | Dec 1998 | A |
5851627 | Farbstein | Dec 1998 | A |
5962090 | Trautz | Oct 1999 | A |
6061994 | Goer et al. | May 2000 | A |
6108999 | Smith et al. | Aug 2000 | A |
6192652 | Goer et al. | Feb 2001 | B1 |
6223414 | Hodek et al. | May 2001 | B1 |
6250045 | Goer et al. | Jun 2001 | B1 |
6272811 | Hagen | Aug 2001 | B1 |
6339909 | Brunnhofer et al. | Jan 2002 | B1 |
6355328 | Baratuci et al. | Mar 2002 | B1 |
6389779 | Brunnhofer | May 2002 | B1 |
6457294 | Virnelson et al. | Oct 2002 | B1 |
6537629 | Ensinger | Mar 2003 | B1 |
6613404 | Johnson | Sep 2003 | B2 |
6796102 | Virnelson et al. | Sep 2004 | B2 |
6989188 | Brunnhofer | Jan 2006 | B2 |
7081300 | Laurence et al. | Jul 2006 | B2 |
7827760 | Brunnhofer et al. | Nov 2010 | B2 |
7997037 | Crandell et al. | Aug 2011 | B2 |
8453415 | Brunnhofer et al. | Jun 2013 | B2 |
8640406 | Brunnhofer et al. | Feb 2014 | B2 |
20010001357 | Reichert | May 2001 | A1 |
20030037493 | Guhl et al. | Feb 2003 | A1 |
20030066614 | Sun et al. | Apr 2003 | A1 |
20030173036 | Kwon et al. | Sep 2003 | A1 |
20030226645 | Toti | Dec 2003 | A1 |
20040163347 | Hodek et al. | Aug 2004 | A1 |
20050034386 | Crandell et al. | Feb 2005 | A1 |
20050100691 | Bunnhofer et al. | May 2005 | A1 |
20050153517 | Kim et al. | Jul 2005 | A1 |
20050210780 | Lyness et al. | Sep 2005 | A1 |
20060130427 | Hodek et al. | Jun 2006 | A1 |
20060150577 | Hodek et al. | Jul 2006 | A1 |
20060162281 | Pettit et al. | Jul 2006 | A1 |
20060260227 | Winfield | Nov 2006 | A1 |
20070116907 | Landon et al. | May 2007 | A1 |
20070125504 | Early et al. | Jun 2007 | A1 |
20070261358 | Davis et al. | Nov 2007 | A1 |
20080053037 | Gallagher | Mar 2008 | A1 |
20080110109 | Hermens | May 2008 | A1 |
20080134596 | Brunnhofer et al. | Jun 2008 | A1 |
20090120019 | Trpkovski | May 2009 | A1 |
20090120035 | Trpkovski | May 2009 | A1 |
20090246802 | Langen | Oct 2009 | A1 |
20100011703 | Seele et al. | Jan 2010 | A1 |
20100107526 | Brunnhofer et al. | May 2010 | A1 |
20100205881 | Sønderkaer et al. | Aug 2010 | A1 |
20110041427 | Bouesnard | Feb 2011 | A1 |
20120061031 | Zhang | Mar 2012 | A1 |
20120297707 | Lenz et al. | Nov 2012 | A1 |
20120297708 | Brunnhofer et al. | Nov 2012 | A1 |
Number | Date | Country |
---|---|---|
894946 | Mar 1983 | BE |
1082095 | Jul 1980 | CA |
2269715 | May 1998 | CA |
2329746 | Jul 1999 | CN |
1784948 | May 1971 | DE |
2314013 | Oct 1973 | DE |
2426718 | Dec 1975 | DE |
2614236 | Oct 1977 | DE |
2921608 | Dec 1980 | DE |
3432113 | Mar 1986 | DE |
3812819 | Oct 1989 | DE |
3904763 | Oct 1989 | DE |
4101277 | Jul 1992 | DE |
4226883 | Mar 1993 | DE |
9304381 | May 1993 | DE |
9305852 | Jul 1993 | DE |
4341905 | Jun 1994 | DE |
9408764 | Oct 1995 | DE |
19603638 | Oct 1996 | DE |
19530838 | Feb 1997 | DE |
29705765 | Jul 1997 | DE |
19644346 | Apr 1998 | DE |
19709938 | Sep 1998 | DE |
19716890 | Nov 1998 | DE |
29812573 | Nov 1998 | DE |
29814768 | Jan 1999 | DE |
19733801 | Feb 1999 | DE |
19805265 | Apr 1999 | DE |
29822689 | Apr 1999 | DE |
19751255 | May 1999 | DE |
29807430 | May 1999 | DE |
29822686 | May 1999 | DE |
19805348 | Aug 1999 | DE |
19807454 | Aug 1999 | DE |
19832731 | Jun 2000 | DE |
19858961 | Jun 2000 | DE |
19858960 | Jul 2000 | DE |
20111569 | Sep 2001 | DE |
10053408 | May 2002 | DE |
10060183 | Jun 2002 | DE |
20204044 | Jul 2002 | DE |
20301926 | Apr 2003 | DE |
20302826 | May 2003 | DE |
10226268 | Oct 2003 | DE |
10342605 | Dec 2004 | DE |
102005029066 | Feb 2006 | DE |
202005016444 | Feb 2006 | DE |
202005019973 | Apr 2006 | DE |
102004062060 | May 2006 | DE |
69734014 | Jun 2006 | DE |
202006002859 | Jun 2006 | DE |
202006002860 | Jun 2006 | DE |
202006013257 | Nov 2006 | DE |
202006017741 | Feb 2007 | DE |
202008009334 | Oct 2008 | DE |
102009020597 | Nov 2009 | DE |
202009005021 | Dec 2009 | DE |
102009009504 | Apr 2010 | DE |
102010006127 | Aug 2011 | DE |
0029984 | Jun 1981 | EP |
0230160 | Jul 1987 | EP |
0483528 | May 1992 | EP |
601488 | Jun 1994 | EP |
0601488 | Jun 1994 | EP |
0688934 | Dec 1995 | EP |
0953715 | Nov 1999 | EP |
0984131 | Mar 2000 | EP |
0989279 | Mar 2000 | EP |
1188895 | Mar 2002 | EP |
1129270 | Aug 2005 | EP |
1840320 | Oct 2007 | EP |
1970525 | Sep 2008 | EP |
1429920 | Mar 2010 | EP |
1475287 | Mar 1967 | FR |
796249 | Jun 1958 | GB |
1138992 | Jan 1969 | GB |
1520257 | Aug 1978 | GB |
2142367 | Jan 1985 | GB |
2411201 | Aug 2005 | GB |
2432179 | May 2007 | GB |
S59190243 | Oct 1984 | JP |
H03172446 | Jul 1991 | JP |
H0545885 | Feb 1993 | JP |
H0589778 | Dec 1993 | JP |
H0711685 | Feb 1995 | JP |
H0813957 | Jan 1996 | JP |
H0886167 | Apr 1996 | JP |
H0886168 | Apr 1996 | JP |
H0893356 | Apr 1996 | JP |
H1122344 | Jan 1999 | JP |
H1181820 | Mar 1999 | JP |
H1181821 | Mar 1999 | JP |
H1193544 | Apr 1999 | JP |
11247540 | Sep 1999 | JP |
H11336451 | Dec 1999 | JP |
2000136681 | May 2000 | JP |
2000199388 | Jul 2000 | JP |
2000199389 | Jul 2000 | JP |
2000248857 | Sep 2000 | JP |
2000319091 | Nov 2000 | JP |
2002206383 | Jul 2002 | JP |
2003227279 | Aug 2003 | JP |
2004324284 | Nov 2004 | JP |
2006090053 | Apr 2006 | JP |
2010084440 | Apr 2010 | JP |
20100106081 | Oct 2010 | KR |
0005474 | Feb 2000 | WO |
0005475 | Feb 2000 | WO |
0214642 | Feb 2002 | WO |
03024715 | Mar 2003 | WO |
03087519 | Oct 2003 | WO |
2004070150 | Aug 2004 | WO |
2006000219 | Jan 2006 | WO |
2006025953 | Mar 2006 | WO |
2006027146 | Mar 2006 | WO |
2006075922 | Jul 2006 | WO |
2007098737 | Sep 2007 | WO |
2008110362 | Sep 2008 | WO |
2010133144 | Nov 2010 | WO |
2011091986 | Aug 2011 | WO |
Entry |
---|
International Search Report from PCT/EP2013/000344. |
Written Opinion of the International Searching Authority in PCT/EP2013/000344. |
Number | Date | Country | |
---|---|---|---|
20150292258 A1 | Oct 2015 | US |