This Application claims priority to French Patent Application No. 1872508, filed Dec. 7, 2018, the contents of which is incorporated herein by reference in its entirety.
The present application concerns the field of avalanche photodiodes for the detection of single photons, also called SPAD “Single Photon Avalanche Diode”) photodiodes.
A SPAD photodiode is essentially formed by a PN junction reverse biased at a voltage greater than its avalanche threshold. When no electric charge is present in the depletion area or space charge area of the PN junction, the photodiode is in a non-conductive pseudo-steady state. When a photogenerated electric charge is injected into the depletion area, if the displacement speed of this charge in the depletion area is sufficiently high, that is, if the electric field in the depletion area is sufficiently intense, the photodiode is capable of avalanching. A single photon is thus capable of generating a measurable electric signal, and this, with a very short response time. SPAD photodiodes enable to detect radiations of very low intensity, and are in particular used for single photon detection and photon counting.
It would be desirable to at least partly improve certain aspects of known SPAD photodiodes.
Thus, an embodiment provides a SPAD-type photodiode comprising, in an upper portion of a semiconductor substrate of a first conductivity type, an alternation of vertically stacked regions of the first conductivity type and regions of a second conductivity type, the regions of the first conductivity type being in contact with a same first semiconductor via of the first conductivity type and the regions of the second conductivity type being in contact with a same second semiconductor via of the second conductivity type.
According to an embodiment, the alternation of regions of the first conductivity type and of regions of the second conductivity type forms a vertical stack of a plurality of PN junctions, each defining an avalanche area of the photodiode.
According to an embodiment, the PN junctions all substantially have the same avalanche voltage.
According to an embodiment, the regions of the first conductivity type have a doping level greater than that of the substrate.
According to an embodiment, in a first portion of a peripheral region of the photodiode, the regions of the first conductivity type extend laterally beyond the regions of the second conductivity type and, in a second portion of the peripheral region of the photodiode, the regions of the second conductivity type extend laterally beyond the regions of the first conductivity type, the first semiconductor via being arranged in the first portion of the peripheral region of the photodiode and the second semiconductor via being arranged in the second portion of the peripheral region of the photodiode.
According to an embodiment, except for the end regions of said alternation, each region of the first conductivity type is in contact, by its lower surface, with one of the regions of the second conductivity type and, by its upper surface, with another one of the regions of the second conductivity type, and each region of the second conductivity type is in contact, by its lower surface, with one of the regions of the first conductivity type and, by its upper surface, with another one of the regions of the first conductivity type.
According to an embodiment, the regions of the first conductivity type and the regions of the second conductivity type have substantially the same thickness.
According to an embodiment, the regions of the first conductivity type have a thickness greater than the thickness of the regions of the second conductivity type.
According to an embodiment, each region of the first conductivity type is in contact with a single region of the second conductivity type.
According to an embodiment, each region of the second conductivity type is in contact, by its lower surface, with one of the regions of the first conductivity type and, by its upper surface, with another one of the regions of the first conductivity type.
According to an embodiment:
According to an embodiment, the first and second conductivity types respectively are type P and type N.
Another embodiment provides a method of manufacturing a SPAD-type photodiode such as defined hereabove, wherein the substrate is formed by a sequence of successive epitaxy steps.
According to an embodiment, any two successive steps of the sequence of successive epitaxy steps are separated by at least one step of local implantation of dopant elements for the forming of at least one of the regions of the first or second conductivity type.
According to an embodiment, the method comprises no anneal of activation of the dopant elements between two successive steps of the sequence of epitaxy steps, the method comprising a single anneal of activation of the dopant elements common to all the regions of the first and second conductivity types at the end of the sequence of successive epitaxy steps.
The foregoing and other features and advantages will be discussed in detail in the following non-limiting description of specific embodiments in connection with the accompanying drawings, in which:
The same elements have been designated with the same reference numerals in the different drawings. In particular, the structural and/or functional elements common to the different embodiments may be designated with the same reference numerals and may have identical structural, dimensional, and material properties.
For clarity, only those steps and elements which are useful to the understanding of the described embodiments have been shown and are detailed. In particular, a SPAD-type photodiode generally comprises secondary circuits, particularly a circuit for biasing its PN junction to a voltage greater than its avalanche threshold, a readout circuit capable of detecting that an avalanche of the photodiode has been triggered, as well as a quenching circuit having the function of interrupting the avalanche of the photodiode once the latter has been triggered. Such secondary circuits have not been shown in the drawings and will not be detailed, the described embodiments being compatible with the secondary circuits equipping known SPAD photodiodes.
Throughout the present disclosure, the term “connected” is used to designate a direct electrical connection between circuit elements with no intermediate elements other than conductors, whereas the term “coupled” is used to designate an electrical connection between circuit elements that may be direct, or may be via one or more other elements.
In the following description, when reference is made to terms qualifying absolute positions, such as terms “front”, “back”, “top”, “bottom”, “left”, “right”, etc., or relative positions, such as terms “above”, “under”, “upper”, “lower”, “lateral”, etc., or to terms qualifying directions, such as terms “horizontal”, “vertical”, etc., unless otherwise specified, it is referred to the orientation of the drawings, it being understood that, in practice, the described devices may be oriented differently.
The terms “about”, “approximately”, “substantially”, and “in the order of” are used herein to designate a tolerance of plus or minus 10%, preferably of plus or minus 5%, of the value in question.
A problem which is posed in known SPADs is that of the collection of the charges photogenerated in depth in the substrate, at a distance remote from the avalanche area of the photodiode, that is, the portion of the photodiode depletion area where the electric field is sufficiently intense for the avalanche to be triggered by a single charge. Indeed, beyond a certain distance from the PN junction, the electric field resulting from the reverse biasing of the PN junction becomes zero or is strongly attenuated, and no longer enables to drive the photogenerated charges towards the avalanche area. Only the random diffusion in the substrate is then capable of driving the photogenerated charges towards the avalanche area, with a non-negligible probability for the photogenerated charges never to reach the avalanche area or to reach it with a significant delay. This problem especially arises when charges photogenerated under the effect of a luminous radiation of high wavelength, for example, a radiation having a wavelength in the range from 750 to 1,200 nm in silicon, are desired to be collected.
Photodiode 100 comprises a semiconductor substrate 101, for example, made of silicon. In the shown example, substrate 101 is P-type doped (P-). In this example, the lower surface of substrate 101 rests on the upper surface of a support layer 103, for example, an insulating layer, for example, a silicon oxide layer. Layer 103 may itself rest on a support substrate, not shown, for example, made of silicon. As an example, layer 103 corresponds to a buried oxide layer of a structure of semiconductor-on-insulator type (SOI). As a variation, layer 103 is a semiconductor layer, for example, made of the same material as substrate 101, for example having a conductivity type opposite to that of substrate 101.
Photodiode 100 further comprises, in an upper portion of substrate 101, an alternation of vertically stacked semiconductor regions of opposite conductivity types, forming a plurality of stacked horizontal PN junctions, each PN junction defining an avalanche region of the photodiode.
More particularly, in the shown example, photodiode 100 comprises, in an upper portion of substrate 101, an alternation of vertically stacked N-type doped regions 105_i (N) and P-type doped regions 107_j (P), i being an integer ranging from 1 to m and m being an integer greater than or equal to 2 designating the number of N-type regions 105_i of the photodiode, and j being an integer ranging from 1 to n and n being an integer greater than or equal to 2 designating the number of P-type regions 107_j of the photodiode. In the example of
In the example of
Thus, the vertical stack of regions 105_i and 107_j comprises (2*m)−1 PN junctions 109 between neighboring regions 105_i and 107_j, that is, 7 PN junctions 109 in the shown example. PN junctions 109 are substantially horizontal (that is, parallel to the main surfaces of substrate 101) and vertically aligned (that is, opposite or vertically in line with one another).
In the example of
Photodiode 100 of
The photodiode 100 of
In the shown example, via 115 is in contact, by its upper surface, with a cathode contact metallization 119 of the photodiode, and via 117 is in contact, by its upper surface, with an anode contact metallization 121 of the photodiode.
In the shown example, photodiode 100 is laterally surrounded with a peripheral insulation wall 123 vertically extending from the upper surface of substrate 101 to layer 103. Insulation wall 123 is for example formed of a trench filled with an insulating material, for example, silicon oxide. As a variation, wall 123 comprises a conductive (for example, made of metal) or semiconductor (for example, made of doped polysilicon) central region insulated from substrate 101 by lateral insulating walls (not detailed in
In operation, regions 105_i, forming cathode regions of the photodiode, are biased to a positive potential V+ by means of via 115, and regions 107_j, forming anode regions of the photodiode, are biased to a negative potential V− by means of via 117, so that the cathode-anode voltage of the photodiode is greater than its avalanche voltage.
The doping levels of regions 105_i and 107_j and the bias voltage of the photodiode are selected so that the electric field in the space charge area of each PN junction 109 is sufficiently intense for the avalanche to be triggered by a single photogenerated charge, for example, greater than 500 kV/cm.
Preferably, the doping level of substrate 101 is selected to be sufficiently low for the electric field in the space charge area of the PN junctions formed between N-type regions 105_i and substrate 101 at the periphery of PN junctions 109 to be sufficiently low for the avalanche not to be triggered by a single photogenerated charge, for example, smaller than 500 kV/cm. This enables to decrease risks of spurious triggering of the avalanche due to edge effects at the periphery of PN junctions 109.
As an example, the reverse breakdown voltage or avalanche voltage of the photodiode is in the range from 10 V to 50 V, and the reverse bias voltage of the photodiode is greater than its breakdown voltage by a value in the range from 0.5 to 10 V. The avalanche voltage of the photodiode particularly depends on the doping levels of regions 105_i and 107_j. As an example, P-type regions 107_j have a doping level in the range from 1*10{circumflex over ( )}17 to 1*10{circumflex over ( )}19 atoms/cm{circumflex over ( )}3 and N-type regions 105_i have a doping level in the range from 1*10{circumflex over ( )}17 to 1*10{circumflex over ( )}19 atoms/cm{circumflex over ( )}3. The doping level of each N-type region 105_i is for example in the order of 1*10{circumflex over ( )}17 atoms/cm{circumflex over ( )}3 at the level of the junction with the neighboring P-type region(s) 107_j. The doping level of substrate 101 is for example smaller than 5*10{circumflex over ( )}16 atoms/cm{circumflex over ( )}3 and preferably smaller than 5*10{circumflex over ( )}14 atoms/cm{circumflex over ( )}3.
The provision of a plurality of vertically stacked avalanche areas enables to efficiently collect the charges photogenerated in the photodiode, whatever the photon absorption depth. In particular, in the photodiode of
To obtain a good detection performance, regions 105_i and 107_j are preferably sized so that the different avalanche areas substantially have the same breakdown voltage whatever the photon detection depth. In other words, regions 105_i and 107_j are preferably such that the different PN junctions 109 of the photodiode have substantially the same avalanche voltage. To achieve this, N-type regions 105_i preferably all have substantially the same dimensions and the same doping level. Further, P-type regions 107_j preferably all have substantially the same dimensions and the same doping level.
As an example, regions 105_i and 107_j each have a thickness in the range from 500nm to 2 μm. In the example of
The implantation steps of
The epitaxial regrowth step of
At this stage, an anneal of activation of the implanted dopant species may be performed, for example, an anneal at a temperature in the range from 800 to 1,200° C., for example, at a temperature in the order of 1,000° C., for example, for a duration in the range from 1 to 10 seconds. Preferably, a single activation anneal common for all regions 105_i and 107_j of the photodiode is performed at the end of all the epitaxy and implantation steps. In other words, no intermediate activation anneal is performed between two successive steps of implantation of regions 105_i and 107_j of the photodiode, so that all the PN junctions 109 of the photodiode are submitted to the same number of anneals. This enables to obtain substantially identical avalanche diodes for all the PN junctions 109 of the photodiode.
Steps (not detailed) of forming of contact metallizations 119 and 121 on the upper surfaces of vias 115 and 117 and of forming of peripheral insulating walls 123 may then be implemented to obtain the structure of
In the method described in relation with
It should be noted that before each epitaxy, a cleaning of the upper surface of the substrate may be provided, for example, by means of a solution based on hydrofluoric acid, to improve the quality of the epitaxy.
The photodiode 200 of
An advantage of such a configuration is that it enables to increase the proportion of photons absorbed in P-type regions 107_j over the photons absorbed in N-type regions 105_i. This enables to improve the sensitivity of the photodiode. Indeed, in the case of an absorption of a photon in an N-type region, the electron of the photogenerated electron-hole pair is discharged by means of via 115, and the remaining photogenerated charge capable of triggering the avalanche is a hole, while in case of an absorption of a photon in a P-type region, the hole of the photogenerated electron-hole pair is discharged by mean of via 117, and the remaining photogenerated charge capable of triggering the avalanche is an electron. The mobility of electrons being greater than that of holes, the avalanche is more easily detected by a photogenerated electron than by a photogenerated hole. In other words, the avalanche is more easily detected by a photon absorbed in a P-type region 107_j than by a photon absorbed in an N-type region 105_i.
In the example of
The photodiode 300 of
More particularly, in the example of
Each N-type region 105_i is in contact, by its lower surface, with the P-type region 107_j of rank j=(2*i)−1 and, by its upper surface, with the P-type region of rank j=2*i. Thus, photodiode 300 comprises 2*m PN junctions 109 between neighboring regions 105_i and 107_j, that is, 4 PN junctions 109 in the shown example.
In the example of
In the shown example, the thicknesses of regions 105_i and 107_j are substantially identical. As a variation, regions 105_i and 107_j may have different thicknesses.
The photodiode 400 of
Specific embodiments have been described. Various alterations, modifications, and improvements will occur to those skilled in the art. In particular, the described embodiments are not limited to the numerical examples of dimensions and of doping levels mentioned in the description.
Further, the above-described advantages can be obtained by inverting all the conductivity types with respect to the examples described in relation with
Further, the described embodiments are not limited to the example of a manufacturing method described in relation with
Number | Date | Country | Kind |
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1872508 | Dec 2018 | FR | national |