The present invention relates to a spark plug, and more particularly to a spark plug formed by joining a tip principally made of noble metal to a base material principally made of Ni (nickel) together.
As such spark plug, for instance, International Publication WO2010113404 discloses a spark plug formed by joining a tip principally made of noble metal to a base material principally made of Ni (nickel) together through a fusion portion.
In the International Publication WO2010113404, however, since there is a difference in coefficient of linear expansion between the base material and the tip, a thermal stress occurs at the fusion portion due to temperature change of an engine in which the spark plug is mounted, and there is a possibility that a crack will appear at the fusion portion due to the thermal stress and develop around the fusion portion, then the tip will come off the base material. A technique of solving this problem, i.e. a technique of suppressing the coming-off of the tip from the base material even if the crack appearing at the fusion portion due to the thermal stress develops, has therefore been required.
The present invention was made to meet the above requirement. An object of the present invention is therefore to provide a spark plug that is capable of suppressing the coming-off of the tip from the base material.
To achieve the above object, according to one aspect of the present invention, a spark plug comprises: a first electrode having a tip principally made of noble metal and a base material principally made of Ni, the tip being joined to the base material through a fusion portion; and a second electrode provided so as to face a discharge surface of the tip. And, the fusion portion has an overlap portion where a first interface between the tip and the fusion portion and a second interface between the base material and the fusion portion overlap each other in a first direction that is perpendicular to the discharge surface, and when viewing a cross section which passes through a center of gravity of the overlap portion projected onto a virtual surface parallel to the discharge surface and which is perpendicular to the discharge surface, a noble metal content is greater than 50 mass % at one end portion of the overlap portion in a second direction that extends along the discharge surface, and a Ni content is greater than 50 mass % at the other end portion of the overlap portion in the second direction.
According to the above spark plug, on the cross section perpendicular to the discharge surface, the noble metal content is greater than 50 mass % at the one end portion of the overlap portion in the second direction extending along the discharge surface of the tip, and the Ni content is greater than 50 mass % at the other end portion of the overlap portion in the second direction. Therefore, at the one end portion of the overlap portion, a thermal stress occurring at the second interface between the base material and the fusion portion is greater than a thermal stress occurring at the first interface between the tip and the fusion portion. On the other hand, at the other end portion of the overlap portion, a thermal stress occurring at the first interface is greater than a thermal stress occurring at the second interface. Consequently, at the one end portion side, a crack tends to appear at the second interface, whereas at the other end portion side, a crack tends to appear at the first interface. The crack tends to develop along the interface. However, even if the cracks develop, thanks to the above structure, it is possible to reduce a tendency for the cracks developing along the first and second interfaces to join together. Hence, coming-off of the tip from the base material can be suppressed.
According to the above spark plug, the overlap portion has a shape on the cross section such that a distance between the first interface and the second interface along the first direction is gradually longer toward the second direction, and in the overlap portion on the cross section, a middle portion at which the noble metal content is 50 mass % and also the Ni content is 50 mass % exists on the second direction side with respect to a center position in the second direction of the overlap portion.
Therefore, a position where the cracks developing along the first interface and the second interface respectively overlap each other in the first direction tends to shift to or get closer to the second direction side with respect to the center position. Thus, even if the cracks develop along the first direction at this position, since a distance between the first interface and the second interface at this position is relatively long, in addition of the above effect, the coming-off of the tip can be further suppressed.
According to the above spark plug, in the overlap portion on the cross section, a shortest portion at which a distance between the first interface and the second interface along the first direction is shortest exists at a portion except the one end portion and the other end portion, and a middle portion at which the noble metal content is 50 mass % and also the Ni content is 50 mass % exists at a portion except the shortest portion in the overlap portion on the cross section.
Therefore, a position where the cracks developing along the first interface and the second interface respectively overlap each other in the first direction tends to be located at a portion except the shortest portion. Thus, even if the cracks develop along the first direction at this position, since a distance between the first interface and the second interface at this position is relatively long, in addition of the above effect, the coming-off of the tip can be further suppressed.
According to the above spark plug, at least one relationship described above is established on the cross section on which a length of the overlap portion in the second direction becomes longest. Therefore, in addition of the above effect, lengths of the first interface and the second interface on which the cracks tend to develop can be longest.
The other objects and features of this invention will become understood from the following description with reference to the accompanying drawings.
An embodiment of the present invention will be explained below with reference to the drawings.
An insulator 11 is a substantially tubular member provided with an axial hole 12 that extends along the axis O. The insulator 11 is made of ceramic such as alumina which is superior in mechanical characteristics and insulation performance under high temperature. The insulator 11 has, at a front side on an inner peripheral surface of the axial hole 12 thereof, a rear-end-facing surface 13 that is an annular surface facing the rear end side. A diameter of the rear-end-facing surface 13 is reduced toward the front end side.
The center electrode 20 is a rod-shaped member engaged with and supported on the rear-end-facing surface 13. A top end of the center electrode 20 protrudes from a top end of the insulator 11 toward the front end side. The center electrode 20 is formed by covering a core 21 principally made of copper with a closed-bottomed tubular base material 22. The base material 22 has a chemical composition containing 50 wt % or more of Ni. Here, the core 21 could be omitted. A tip 24 is joined to a top end of the base material 22 through a fusion portion (or a melting portion) 23. The tip 24 has a chemical composition containing 50 wt % or more of at least one noble metal selected from Pt, Rh, Ir, Ru etc. A discharge surface 25 of the tip 24 faces the ground electrode 40. The center electrode 20 is electrically connected to a metal terminal 26 in the axial hole 12.
The metal terminal 26 is a rod-shaped member to which a high-tension cable (not shown) is connected. The metal terminal 26 is made of metal material (e.g. low-carbon steel) having conductivity. The metal terminal 26 is fixed at a rear end side of the insulator 11 with a top end of the metal terminal 26 inserted into the axial hole 12 of the insulator 11.
A metal shell 30 is secured to an outer periphery at the top end side of the insulator 11 by caulking. The metal shell 30 is a substantially tubular member made of metal material (e.g. low-carbon steel) having conductivity. The metal shell 30 has a brim-shaped seat portion 31 extending or bulging in a radially outward direction and a thread portion 32 formed on an outer peripheral surface at a top end side of the metal shell 30 with respect to the seat portion 31. By screwing the thread portion 32 into a screw hole (not shown) of an engine (a cylinder head), the metal shell 30 is fixed to the engine (the cylinder head). The ground electrode 40 is connected to a top end portion of the metal shell 30.
The ground electrode 40 is a rod-shaped member made of metal material having conductivity. The ground electrode 40 has a base material 41 connected to the metal shell 30 and a tip 44 located on an inner surface 42, which faces the center electrode 20, of the base material 41 and joined to the base material 41 through a fusion portion (or a melting portion) 43. The base material 41 has a chemical composition containing 50 wt % or more of Ni. The tip 44 has a chemical composition containing 50 wt % or more of at least one noble metal selected from Pt, Rh, Ir, Ru etc. A discharge surface 45 of the tip 44 faces the center electrode 20. A spark gap G is formed between the discharge surface 45 of the tip 44 and the center electrode 20.
The fusion portion 43 has an overlap portion 48 where a first interface (or a first boundary) 46 between the tip 44 and the fusion portion 43 and a second interface (or a second boundary) 47 between the base material 41 and the fusion portion 43 overlap each other in the first direction (the arrow Z direction).
An example of a method of producing the ground electrode 40 will be explained with reference to
A groove bottom 42b, which is a bottom of the groove on the inner surface 42 of the base material 41, inclines or slopes from the wall surface 42a toward the top end surface 41a such that a depth of the groove is deeper from the wall surface 42a toward the top end surface 41a. A bottom surface 45a of the tip 44 also inclines or slopes such that a portion, located close to the wall surface 42a of the base material 41, of the tip 44 is thinner than a portion, located close to the top end surface 41a of the base material 41, of the tip 44.
After placing the tip 44 on the groove of the base material 41, high-energy beam such as laser beam and electron beam is radiated from a beam-machining head 54 provided so as to face to the top end surface 41a of the base material 41. By moving the beam-machining head 54 along the groove bottom 42b while radiating the beam, the fusion portion 43 is formed, then the tip 44 is joined to the base material 41. Since the beam is radiated to the top end surface 41a of the base material 41, a melting amount at the top end surface 41a side is large as compared with that at the wall surface 42a side. Further, as mentioned above, since the bottom surface 45a of the tip 44 and the groove bottom 42b of the inner surface 42 of the base material 41 slope, at the top end surface 41a side in the fusion portion 43, a melting amount of the tip 44 is larger than a melting amount of the base material 41, whereas at the wall surface 42a side in the fusion portion 43, a melting amount of the base material 41 is larger than a melting amount of the tip 44.
Returning to
As mentioned above, since the differences in the noble metal content and the Ni content exist between the end portions 50 and 51, at the end portion 50, a thermal stress occurring at the second interface 47 is greater than a thermal stress occurring at the first interface 46. On the other hand, at the end portion 51, a thermal stress occurring at the first interface 46 is greater than a thermal stress occurring at the second interface 47. Consequently, at the end portion 50 side, a crack tends to appear at the second interface 47, whereas at the end portion 51 side, a crack tends to appear at the first interface 46. Further, the crack appearing at the first interface 46 tends to develop along the first interface 46, and the crack appearing at the second interface 47 tends to develop along the second interface 47. However, even if the cracks develop in this way, thanks to the above structure, it is possible to reduce a tendency for the cracks developing along the first and second interfaces 46 and 47 to join together. Therefore, as compared with a case where cracks appearing at both ends of one interface develop toward the middle of the interface along the interface, coming-off of the tip 44 from the base material 41 due to rupture of the fusion portion 43 can be suppressed.
Here, quantitative analysis to measure the noble metal content and the Ni content at the end portions 50 and 51 of the overlap portion 48 can be carried out by WDS (Wavelength Dispersive Spectrometry) analysis using EPMA (Electron Probe Micro Analyzer). A width of each of the end portions 50 and 51 (a thickness of each line segment) in the second direction is a width required for the quantitative analysis (in the present embodiment, it is at least 20 μm). Each of the noble metal content and the Ni content at the end portions 50 and 51 can be measured by taking an average of measurement values of a plurality of measurement points which are set at the same regular intervals on both line segments of the end portions 50 and 51. Instead of this, a measurement value of a midpoint of each line segment of the end portions 50 and 51 could be a central value.
As mentioned above, in the fusion portion 43, since the melting amount at the top end surface 41a side is large as compared with that at the wall surface 42a side, the overlap portion 48 is shaped so that a distance between the first interface 46 and the second interface 47 along the first direction (the arrow Z direction) is gradually longer toward the second direction (the arrow Y direction). In the overlap portion 48, a middle portion 53 at which the noble metal content is 50 mass % and also the Ni content is 50 mass % exists on the second direction side (the arrow Y direction side) with respect to a center position 52 in the second direction of the overlap portion 48. The center position 52 is a position including a middle point that is located at the same L distance from the end portion 50 and from the end portion 51.
Therefore, as compared with a section of the first interface 46 from the end portion 50 up to the middle portion 53, at a section of the first interface 46 from the end portion 51 up to the middle portion 53, the crack appearing at the end portion 51 side tends to develop along the first interface 46. On the other hand, as compared with a section of the second interface 47 from the end portion 51 up to the middle portion 53, at a section of the second interface 47 from the end portion 50 up to the middle portion 53, the crack appearing at the end portion 50 side tends to develop along the second interface 47. Consequently, a position where the cracks developing along the first interface 46 and the second interface 47 respectively overlap each other in the first direction (the arrow Z direction) tends to shift to or get closer to the second direction (the arrow Y direction) side with respect to the center position 52. Therefore, even if the cracks develop along the first direction (the arrow Z direction) at this position in the fusion portion 43, since a distance between the first interface 46 and the second interface 47 at this position is longer than that at the end portion 51 side with respect to the center position 52 of the overlap portion 48, rupture of the fusion portion 43 is suppressed, then the coming-off of the tip 44 from the base material 41 can be further suppressed.
It is noted that a relationship showing that the noble metal content is greater than 50 mass % at the one side end portion 50 and the Ni content is greater than 50 mass % at the other side end portion 51 is established on the cross section on which the length of the overlap portion 48 in the second direction (the arrow Y direction) becomes a maximum (becomes longest). Since lengths of the first interface 46 and the second interface 47 on which the cracks tend to develop are longest at this cross section position, the coming-off of the tip 44 from the base material 41 can be further suppressed.
A modified example of the ground electrode 40 will be explained with reference to
After placing the tip 44 on the groove of the base material 41, by radiating high-energy beam from the beam-machining head 54 provided so as to face to the top end surface 41a of the base material 41, the fusion portion 43 is formed, then the tip 44 is joined to the base material 41. Because of the slopes of the bottom surface 45b of the tip 44 and the groove bottom 42c of the inner surface 42 of the base material 41, at the top end surface 41a side in the fusion portion 43, a melting amount of the base material 41 is larger than a melting amount of the tip 44, whereas at the wall surface 42a side in the fusion portion 43, a melting amount of the tip 44 is larger than a melting amount of the base material 41.
Returning to
Therefore, at the end portion 50, a thermal stress occurring at the first interface 46 is greater than a thermal stress occurring at the second interface 47. On the other hand, at the end portion 51, a thermal stress occurring at the second interface 47 is greater than a thermal stress occurring at the first interface 46. Consequently, at the end portion 50 side, a crack tends to appear at the first interface 46, whereas at the end portion 51 side, a crack tends to appear at the second interface 47. Further, the crack appearing at the first interface 46 tends to develop along the first interface 46, and the crack appearing at the second interface 47 tends to develop along the second interface 47. However, even if the cracks develop in this way, thanks to the above structure, it is possible to reduce a tendency for the cracks developing along the first and second interfaces 46 and 47 to join together. Therefore, as compared with a case where cracks appearing at both ends of one interface develop toward the middle of the interface along the interface, coming-off of the tip 44 from the base material 41 due to rupture of the fusion portion 43 can be suppressed.
Next, the center electrode 20 will be explained.
The fusion portion 23 has an overlap portion 62 where a first interface (or a first boundary) 60 between the tip 24 and the fusion portion 23 and a second interface (or a second boundary) 61 between the base material 22 and the fusion portion 23 overlap each other in the first direction (which is identical with the axis O direction, the arrow Z direction).
An example of a method of producing the center electrode 20 will be explained with reference to
A top end surface 22a of the base material 22 and an end surface 24a, located at an opposite side to the discharge surface 25, of the tip 24 are flat surfaces that obliquely cross the axis O. With these shapes, regarding both side portions 24b and 24c of the tip 24 which are located at opposite sides of the axis O, a length of the portion 24b between the discharge surface 25 and the end surface 24a of the tip 24 is longer than that of the portion 24c. In other words, a length of the portion 24c between the discharge surface 25 and the end surface 24a is shorter than that of the portion 24b. The tip 24 is placed on the base material 22 with its end surface 24a contacting the top end surface 22a of the base material 22 so that the discharge surface 25 of the tip 24 is orthogonal to the axis O.
After placing the tip 24 on the base material 22, by radiating high-energy beam such as laser beam and electron beam from a beam-machining head 54 provided so as to face to side surfaces of the base material 22 and the tip 24 while turning the base material 22 and the tip 24 on the axis O, the fusion portion 23 is formed, then the tip 24 is joined to the base material 22. Since the beam is radiated to the side surface of the base material 22, a melting amount at an outer side in a radial direction of the base material 22 is large as compared with that at a middle in the radial direction of the base material 22. Further, since the top end surface 22a of the base material 22 and the end surface 24a of the tip 24 slope, at the portion 24b of the tip 24 in the fusion portion 23, a melting amount of the tip 24 is larger than a melting amount of the base material 22, whereas at the portion 24c opposite to the portion 24b with respect to the axis O, a melting amount of the base material 22 is larger than a melting amount of the tip 24.
Returning to
Therefore, at the one end portion 64, a thermal stress occurring at the second interface 61 is greater than a thermal stress occurring at the first interface 60. On the other hand, at the other end portion 65, a thermal stress occurring at the first interface 60 is greater than a thermal stress occurring at the second interface 61. Consequently, at the one end portion 64 side, a crack tends to appear at the second interface 61, whereas at the other end portion 65 side, a crack tends to appear at the first interface 60. Further, the crack appearing at the first interface 60 tends to develop along the first interface 60, and the crack appearing at the second interface 61 tends to develop along the second interface 61. However, even if the cracks develop in this way, thanks to the above structure, it is possible to reduce a tendency for the cracks developing along the first and second interfaces 60 and 61 to join together. Therefore, as compared with a case where cracks appearing at both ends of one interface develop toward the middle of the interface along the interface, coming-off of the tip 24 from the base material 22 due to rupture of the fusion portion 23 can be suppressed.
As mentioned above, in the fusion portion 23, since the melting amount at the outer side in the radial direction of the base material 22 is large as compared with that at the middle in the radial direction of the base material 22, the overlap portion 62 is shaped so that a distance between the first interface 60 and the second interface 61 along the first direction (the arrow Z direction) is gradually shorter from the outer side toward the middle. Thus, in the overlap portion 62, between the one end portion 64 and the other end portion 65, a shortest portion 66 at which the distance between the first interface 60 and the second interface 61 along the first direction is shortest exists at a portion except the one end portion 64 and the other end portion 65. Further, in the overlap portion 62, a middle portion 67 at which the noble metal content is 50 mass % and also the Ni content is 50 mass % exists at a portion except the shortest portion 66.
Therefore, as compared with a section of the first interface 60 from the one end portion 64 up to the middle portion 67, at a section of the first interface 60 from the other end portion 65 up to the middle portion 67, the crack appearing at the other end portion 65 side tends to develop along the first interface 60. On the other hand, as compared with a section of the second interface 61 from the other end portion 65 up to the middle portion 67, at a section of the second interface 61 from the one end portion 64 up to the middle portion 67, the crack appearing at the one end portion 64 side tends to develop along the second interface 61. Since the middle portion 67 is positioned at a different position from the shortest portion 66 in the second direction (the arrow Y direction), a position where the cracks developing along the first interface 60 and the second interface 61 respectively overlap each other in the first direction (the arrow Z direction) tends to be located at a portion except the shortest portion 66. Therefore, even if the cracks develop along the first direction at this position, since a distance between the first interface 60 and the second interface 61 at this position is longer than that at the shortest portion 66, rupture of the fusion portion 23 is suppressed, then the coming-off of the tip 24 from the base material 22 can be further suppressed.
A modified example of the center electrode 20 will be explained with reference to
Also in this case, a relationship, showing that in a sectional view of the center electrode 20 cut by a cutting-plane line passing through a center of gravity 63 of a projected planform of the overlap portion 62 onto a virtual surface parallel to the discharge surface 25 of the tip 24, the noble metal content is greater than 50 mass % (the melting amount of the tip 24 is larger than the melting amount of the base material 22) at the end portion of the overlap portion 62 on the portion 24b side and the Ni content is greater than 50 mass % (the melting amount of the base material 22 is larger than the melting amount of the tip 24) at the other end portion of the overlap portion 62 on the other portion 24c side, is established. Hence, the same mechanism and effect can be obtained.
Although the present invention is explained on the basis of the above embodiment, the present invention is not limited to the above embodiment. The present invention includes all design modifications and equivalents belonging to the technical scope of the present invention.
The above embodiment shows the example in which the groove is formed on the base material 41 of the ground electrode 40, and the tip 44, a part of which is accommodated in the groove, is joined to the base material 41. However, structures of the base material 41 and the tip 44 are not limited to this example. The base material 41 is not necessarily provided with the groove. And, the tip 44 could be joined to the base material 41 without forming the groove on the base material 41.
The above embodiment shows the example in which a top end surface of the tip 44 is positioned at a slightly inner side with respect to the top end surface 41a of the base material 41. However, the position of the tip 44 is not limited to this example. For instance, the tip 44 could be set so that its top end surface is positioned at an outer side with respect to the top end surface 41a of the base material 41, namely that the top end surface of the tip 44 protrudes from the top end surface 41a of the base material 41.
The above embodiment shows the example in which the tip 44 is joined to the inner surface 42 of the base material 41 of the ground electrode 40. However, the joining of the tip 44 is not limited to this example. The tip 44 could be joined to other portions such as the top end surface 41a of the base material 41, except the inner surface 42.
The above embodiment shows the example in which the tip 44 of the ground electrode 40 has the rectangular parallelepiped (a square column). However, a shape of the tip 44 is not limited to this example. As the shape of the tip 44, a cylindrical column and a polygonal column except the square column could be employed as necessary.
The above embodiment shows the example in which the tip 44 is directly joined to the base material 41 of the ground electrode 40 through the fusion portion 43. However, the joining of the tip 44 is not limited to this example. It could be possible to interpose an intermediate member principally made of Ni between the base material and the tip, and join the tip to the intermediate member joined to the base material through the fusion portion.
The above embodiment shows the example in which the relationship, showing that the noble metal content is greater than 50 mass % at the one end portions of the overlap portions 48 and 62 and the Ni content is greater than 50 mass % at the other end portions of the overlap portions 48 and 62, is established in both of the center electrode 20 and the ground electrode 40. However, the present invention is not limited to this example. As long as this relationship is established in either one of the center electrode 20 and the ground electrode 40, the present invention can be realized, and the tip of the electrode having this relationship can be prevented from coming off the base material.
In the above embodiment, as the example of the production of (the fusion portion 23 of) the center electrode 20, the tip 24 is set on the base material 22, and the high-energy beam is radiated while turning this set of the base material 22 and the tip 24 on the axis O. However, the production of (the fusion portion 23 of) the center electrode 20 is not limited to this example. For instance, the fusion portion 23 could be formed by setting the tip 24 on the base material 22 and performing the high-energy beam scan around the base material 22 and the tip 24 using one or more mirrors with this set of the base material 22 and the tip 24 remaining at rest.
The entire contents of Japanese Patent Applications No. 2018-112958 filed on Jun. 13, 2018 is incorporated herein by reference.
Although the invention has been described above by reference to certain embodiment of the invention, the invention is not limited to the embodiment described above. Modifications and variations of the embodiment described above will occur to those skilled in the art in light of the above teachings. The scope of the invention is defined with reference to the following claims.
Number | Date | Country | Kind |
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2018-112958 | Jun 2018 | JP | national |
Number | Name | Date | Kind |
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20120015578 | Nakayama | Jan 2012 | A1 |
Number | Date | Country |
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2010113404 | Oct 2010 | WO |
Number | Date | Country | |
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20190386466 A1 | Dec 2019 | US |