The present invention relates to a spark plug including a center electrode and a ground electrode and particularly to a spark plug having a structure in which at least one of the center electrode and the ground electrode includes a cover portion and a core portion.
A spark plug used for ignition of an internal combustion engine such as a gasoline engine generally includes a center electrode, an insulator provided externally of the center electrode, a metallic shell provided externally of the insulator, and a ground electrode attached to the metallic shell with a gap (discharge gap) formed between the ground electrode and the center electrode to allow spark discharge to occur therebetween (the ground electrode is also referred to as an “outer electrode”). In the following description, the side toward the gap is referred to as the “front side” of the center electrode or the ground electrode, and the side opposite to the “front side” is referred to as the “rear side.”
In known spark plugs, at least one of the center electrode and the ground electrode (hereinafter may be collectively referred to simply as “electrodes”) includes a cover portion formed of a prescribed material (e.g., nickel or a nickel alloy) and a core portion formed of a material (e.g., copper) having a thermal expansion coefficient different from that of the cover portion and covered with the cover portion (see, for example, Patent Documents 1 and 2). In such a spark plug, when a material having high thermal conductivity is selected as the material of the core portion, the heat transfer performance of the electrode can be improved.
When an electrode of a spark plug is configured to include a cover portion and a core portion, the difference in thermal expansion coefficient between the cover portion and the core portion may cause a gap to occur near the boundary between the cover portion and the core portion on the front side of the electrode during use under exposure to thermal cycles (this gap is hereinafter referred to as a “front gap”). When such a front gap occurs in the electrode, heat transfer from the cover portion to the core portion is hindered, so that the heat transfer performance of the electrode deteriorates. In this case, problems such as occurrence of voids (pores) in the core portion and breakage of the electrode or other members due to expansion of the electrode may occur. In recent years, spark plugs are being reduced in diameter. Therefore, there is a growing demand to reduce the diameters of electrodes, and one important task is to suppress the occurrence of a front gap.
The present invention has been made to solve the foregoing problems. An object of the invention is, in a spark plug having a structure in which at least one of a center electrode and a ground electrode includes a cover portion and a core portion formed of a material having a thermal expansion coefficient different from that of the cover portion, to suppress occurrence of a gap between the cover portion and the core portion during use of the spark plug.
To solve, at least partially, the above problem, the present invention can be embodied in the following modes or application examples.
A spark plug comprising a center electrode and a ground electrode which forms a gap between the ground electrode and the center electrode,
wherein, when a side toward the gap is taken as a front side of the center electrode or the ground electrode, at least one of the center electrode and the ground electrode has a cover portion and a core portion covered with the cover portion and formed of a material having a thermal expansion coefficient different from a thermal expansion coefficient of the cover portion,
the core portion of the at least one electrode has a concave portion and a convex portion formed at a front end thereof, and
the convex portion is such that, in a cross section passing through a barycenter of a front surface of the electrode and also passing through the convex portion, an area of the convex portion delimited by a line perpendicular to a bisector of the convex portion and passing through a point 0.2 mm shifted from a front end of the convex portion in a direction of the bisector is smaller than an area of a triangle formed by connecting the front end of the convex portion and intersections of the line perpendicular to the bisector and a contour of the convex portion.
The spark plug described in the application example 1, wherein a ratio of a diameter of the core portion at a position 1 mm shifted from a position of a front end of the core portion in a direction perpendicular to a radial direction to a diameter of the core portion at a position 5 mm shifted from the position of the front end of the core portion in the direction perpendicular to the radial direction is 0.6 or larger.
The spark plug described in the application example 1 or 2, wherein a radial cross section of the electrode at a front end of the core portion has an area of 3.5 mm2 or smaller.
The spark plug described in any of the application examples 1 to 3, wherein the core portion has a diameter reduction portion formed such that a diameter thereof decreases toward a rear end of the core portion.
The spark plug described in any of the application examples 1 to 4, wherein at least one of the center electrode and the ground electrode has, as a radial cross section, a cross section in which the core portion, the cover portion, the core portion, the cover portion, and the core portion are arranged in this order on at least one straight line passing through a center of the cross section.
The spark plug described in the application example 5, wherein at least one of the center electrode and the ground electrode has, as a radial cross section, a cross section in which the core portion, the cover portion, the core portion, the cover portion, and the core portion are arranged in this order on any straight line passing through the center of the cross section.
A spark plug comprising a center electrode and a ground electrode which forms a gap between the ground electrode and the center electrode,
wherein, when a side toward the gap is taken as a front side of the center electrode or the ground electrode, at least one of the center electrode and the ground electrode has a cover portion and a core portion covered with the cover portion and formed of a material having a thermal expansion coefficient different from a thermal expansion coefficient of the cover portion,
the core portion of the at least one electrode has a concave portion formed at a front end thereof, and
the core portion has a diameter reduction portion formed such that a diameter thereof decreases toward a rear end of the core portion.
The spark plug described in the application example 7, wherein a ratio of a diameter of the core portion at a position 1 mm shifted from a position of a front end of the core portion in a direction perpendicular to a radial direction to a diameter of the core portion at a position 5 mm shifted from the position of the front end of the core portion in the direction perpendicular to the radial direction is 0.6 or larger.
The spark plug described in the application example 7 or 8, wherein a radial cross section of the electrode at a front end of the core portion has an area of 3.5 mm2 or smaller.
The spark plug described in any of the application examples 7 to 9, wherein at least one of the center electrode and the ground electrode has, as a radial cross section, a cross section in which the core portion, the cover portion, the core portion, the cover portion, and the core portion are arranged in this order on at least one straight line passing through a center of the cross section.
The spark plug described in the application example 10, wherein at least one of the center electrode and the ground electrode has, as a radial cross section, a cross section in which the core portion, the cover portion, the core portion, the cover portion, and the core portion are arranged in this order on any straight line passing through the center of the cross section.
The present invention can be implemented in various forms. For example, the present invention may be implemented as a spark plug, a center electrode for a spark plug, a ground electrode for a spark plug, or a method of manufacturing these.
In the spark plug according to application example 1, since the core portion has a concave portion and a convex portion formed at the front end thereof, the area of contact between the core portion and the cover portion is relatively large, and a relatively large diffusion layer is formed between the core portion and the cover portion. The convex portion formed is such that, in a cross-section passing through the barycenter of the front end surface of the electrode and also passing through the convex portion, the area of the convex portion delimited by a line perpendicular to the bisector of the convex portion and passing through a point 0.2 mm shifted from the front end of the convex portion in the direction of the bisector is smaller than the area of a triangle formed by connecting the front end of the convex portion and intersections of the line perpendicular to the bisector and the contour of the convex portion. Such a convex portion (small convex portion) functions as a wedge for the cover portion. Therefore, in this spark plug, the occurrence of a gap between the cover portion and the core portion can be suppressed even during use under exposure to thermal cycles.
In the spark plug according to application example 2, the volume of the core portion on the front side of the electrode is relatively large. Therefore, the heat transfer performance of the electrode is improved, so that the occurrence of a gap between the cover portion and the core portion can be satisfactorily suppressed.
In the spark plug according to application example 3, the electrode has a cross-sectional area of 3.5 mm2 or smaller. The heat capacity of such an electrode is small, and therefore a front gap is likely to occur during thermal cycles. However, in the above electrode, the occurrence of a gap between the cover portion and the core portion can be suppressed.
In the spark plug according to application example 4, the diameter reduction portion functions to prevent the cover portion from coming off. Also, due to the presence of the diameter reduction portion, the area of contact between the core portion and the cover portion increases further, so that the occurrence of a gap between the cover portion and the core portion can be satisfactorily suppressed.
In the spark plug according to application example 5, the area of contact between the core portion and the cover portion increases further, and the small convex portion is formed over a relatively large region in the radial cross section. Therefore, the occurrence of a gap between the cover portion and the core portion can be more satisfactorily suppressed.
In the spark plug according to application example 6, the area of contact between the core portion and the cover portion is still further increased, and the small convex portion is formed in a wide region extending over the entire circumference of the radial cross section. Therefore, the occurrence of a gap between the cover portion and the core portion can be very satisfactorily suppressed.
In the spark plug according to application example 7, since the concave portion is formed at the front end of the core portion, the area of contact between the core portion and the cover portion is relatively large, and a relatively large diffusion layer is formed between the core portion and the cover portion. In addition, the core portion has a diameter reduction portion tapered such that its diameter decreases toward the rear side. This diameter reduction portion functions to prevent the cover portion from coming off. Also, due to the presence of the diameter reduction portion, the area of contact between the core portion and the cover portion increases further. Therefore, in this spark plug, the occurrence of a gap between the cover portion and the core portion can be suppressed even during use under exposure to thermal cycles.
In the spark plug according to application example 8, the volume of the core portion on the front side of the electrode is relatively large. Therefore, the heat transfer performance of the electrode is improved, so that the occurrence of a gap between the cover portion and the core portion can be satisfactorily suppressed.
In the spark plug according to application example 9, the electrode has a cross-sectional area of 3.5 mm2 or smaller. The heat capacity of such an electrode is small, and therefore a front gap is likely to occur during thermal cycles. However, in the above electrode, the occurrence of a gap between the cover portion and the core portion can be suppressed.
In the spark plug according to application example 10, the area of contact between the core portion and the cover portion is further increased. Therefore, the occurrence of a gap between the cover portion and the core portion can be very satisfactorily suppressed.
In the spark plug according to application example 11, the area of contact between the core portion and the cover portion is still further increased. Therefore, the occurrence of a gap between the cover portion and the core portion can be very satisfactorily suppressed.
Modes for carrying out the invention will next be described on the basis of embodiments in the following order.
A. Embodiment
A-1. Structure of spark plug
A-2. Specific structure of center electrode for spark plug
A-3. Method of producing center electrode for spark plug
A-4. Performance evaluation
B. Modified embodiments
As shown in
The ceramic insulator 10 is a tubular insulator having an axial bore 12 formed at the center thereof, and the axial bore 12 serves as a through hole for accommodating the center electrode 20 and the metal terminal 40. The ceramic insulator 10 is formed by firing a ceramic material such as alumina. The ceramic insulator 10 has a central trunk portion 19 formed near the center thereof in the direction of the axis OL and having a larger diameter than the other portions. A rear trunk portion 18 for insulation between the metal terminal 40 and the metallic shell 50 is formed rearward of the central trunk portion 19. A front trunk portion 17 is formed frontward of the central trunk portion 19, and a leg portion 13 smaller in outer diameter than the front trunk portion 17 is formed frontward of the front trunk portion 17.
The metallic shell 50 is a substantially cylindrical metallic member that surrounds a portion of the ceramic insulator 10 extending from a part of the rear trunk portion 18 to the leg portion 13 to hold the ceramic insulator 10. The metallic shell 50 is formed of a metal such as low carbon steel. The metallic shell 50 has a substantially cylindrical screw portion 52, and a screw thread that is to be threadingly engaged with a threaded hole of an engine head when the spark plug 100 is attached to the engine head is formed on the side surface of the screw portion 52. A front end surface 57, which is the front end surface of the metallic shell 50, has a hollow circular shape, and the front end of the leg portion 13 of the ceramic insulator 10 protrudes from the hollow portion of the front end surface 57. The metallic shell 50 further has a tool engagement portion 51 and a flange-like seal portion 54. When the spark plug 100 is attached to the engine head, a tool is engaged with the tool engagement portion 51. The seal portion 54 is formed rearward of the screw portion 52. An annular gasket 5 formed by bending a plate is fitted between the seal portion 54 and the engine head. The tool engagement portion 51 has, for example, a hexagonal cross-sectional shape.
The center electrode 20 is a substantially rod-shaped electrode having a cover portion 21 and a core portion 25 covered with the cover portion 21. A material having higher thermal conductivity than the material of the cover portion 21 is used as the material of the core portion 25. Therefore, the presence of the core portion 25 improves the heat transfer performance of the center electrode 20. The material of the core portion 25 and the material of the cover portion 21 are different in thermal expansion coefficient. In the present embodiment, a nickel alloy composed mainly of nickel is used as the material of the cover portion 21, and copper or an alloy composed mainly of copper is used as the material of the core portion 25. The center electrode 20 is accommodated in the axial bore 12 of the ceramic insulator 10 with the front end of the cover portion 21 protruding from the axial bore 12 of the leg portion 13 of the ceramic insulator 10 and is electrically connected through a ceramic resistor 3 and a seal body 4 to the metal terminal 40 disposed at the rear end of the ceramic insulator 10. An electrode tip formed of, for example, a noble metal may be joined to the front end of the center electrode 20, in order to improve resistance to spark-induced erosion and resistance to oxidation-induced erosion.
The ground electrode 30 is a substantially rod-shaped bent electrode. The ground electrode 30 has a base end portion 37 at one end that is joined to the front end surface 57 of the metallic shell 50 and a distal end portion 38 at the other end that is bent so as to face the front end portion of the center electrode 20. A gap for spark discharge (a discharge gap DG) is formed between the distal end portion 38 of the ground electrode 30 and the front end portion of the center electrode 20. An electrode tip formed of, for example, a noble metal may be joined to the distal end portion 38 of the ground electrode 30 on the side facing the center electrode 20, in order to improve resistance to spark-induced erosion and resistance to oxidation-induced erosion.
As shown in
The flange-shaped support portion 27 protruding in a direction perpendicular to the axis OL is formed near the rear end of the center electrode 20. As shown in
As shown in
As shown in
In the present description, a convex portion CP at the front end of the core portion 25 is classified as a small convex portion or a large convex portion.
<Condition 1>
In at least one cross section of the core portion 25 that passes through the barycenter of the front end surface of the center electrode 20 and also passes through a convex portion CP, the area of the convex portion CP delimited by a line PL perpendicular to the bisector BL of the convex portion CP and passing through a point located at a distance H1 (=0.2 mm) from the front end P0 of the convex portion CP in the direction of the bisector BL is smaller than the area of a triangle formed by connecting the front end P0 of the convex portion CP and intersections P1 and P2 of the line PL perpendicular to the bisector BL and the contour of the convex portion CP (i.e., a triangle P0-P1-P2).
The second convex portion CP(2) does not meet condition 1. In the present description, such a convex portion CP that does not meet condition 1 is referred to as a large convex portion. The small convex portion can also be expressed as a thin convex portion or a sharp convex portion, and the large convex portion can also be expressed as a thick convex portion or a blunt convex portion.
In the center electrode 20 shown in
In the center electrode 20 shown in
In the core portion 25 of the center electrode 20 shown in
The work W is formed into a columnar shape about the work axis WA. Since the center electrode 20 of the present embodiment is composed of the cover portion 21 and the core portion 25 as described above, the work W is formed from a cover material 28 used as the material for forming the cover portion 21 and a core material 29 used as the material for forming the core portion 25. The cover material 28 covers a first end face EF1 of the core material 29, which is one end surface thereof, and at least part of the side face continuous with the first end face EF1 but does not cover a second end face EF2 of the core material 29, which is the other end surface thereof. More specifically, the work W is such that the end face of the cover material 28 toward the second end face EF2 is covered with the core material 29. In the following description, the side of the work W toward the first end face EF1 (the side on which the cover material 28 forms an end portion) is referred to as a cover side, and the side toward the second end face EF2 (the side on which the core material 29 forms an end portion) is referred to as a core side. The method of producing the work W having the structure shown in
Next, the work W is subjected to first extrusion molding (primary extrusion molding) using a die Ca1 to produce a primary molded product M1 (step S120 in
In the primary molded product M1, an end face of the cover material 28 and a surface of a part of the core material 29 that protrudes from the cover material 28 are separated from each other at the core-side end of the primary molded product M1, and a gap GA is present therebetween. This gap GA can be formed by, for example, subjecting the work W to heat treatment under controlled heat treatment conditions before insertion into the die Ca1 so that the thickness of a diffusion layer at the boundary between the core material 29 and the cover material 28 is controlled (the thickness of the diffusion layer is controlled to, for example, about 5 μm). As described above, the primary extrusion molding is performed such that the gap GA is formed in the primary molded product M1. In this case, the core material 29 presses the end face of the cover material 28 in the cover-side end portion of the primary molded product M1, and therefore formation of a gap near the boundary between the core material 29 and the cover material 28 in the core-side end portion of the primary molded product M1 can be suppressed. After the primary extrusion molding, the primary molded product M1 is kicked out and removed from the die Ca1.
Next, the orientation of the removed primary molded product M1 is reversed (step S130 in
Next, the orientation of the primary molded product M1 is again reversed (step S150 in
Next, as shown in
Next, burr treatment is performed on the cover side of the secondary molded product M2 (step S180 in
Next, the orientation of the secondary molded product M2 is reversed (step S190 in
With the production method described above, the center electrode 20 shown in
Performance evaluation was performed on the center electrode 20 of the above-described embodiment and on a center electrode 20 of a comparative example which will be described below.
In the first thermal test, the front end portion of each center electrode 20 was heated for 2 minutes using a burner and then cooled for 1 minute, and this cycle was repeated 1,000 times. The temperature setting used was such that the temperature of the front end of the center electrode 20 of sample No. 8 reached 800° C. Then a cross section of the center electrode 20 was observed visually and under a microscope (magnification: 30×) to judge whether or not a gap (front gap TG) occurred between the cover portion 21 and the core portion 25 on the front side. Each sample was rated as follows. A sample in which no front gap TG occurred was rated good (indicated by a circle). A sample in which a small front gap TG (a gap of 0.1 mm or smaller) occurred was rated fair (indicated by a triangle). A sample in which a large front gap TG (a gap of larger than 0.1 mm) occurred was rated poor (indicated by a cross).
In the first thermal test, no front gap TG occurred in samples (samples Nos. 1 to 7) in which the radial cross section of the center electrode 20 at the front end of the core portion 25 had an area larger than 3.5 mm2, irrespective of the type of the front end shape of the core portion 25, as shown in
As can be seen from the results of the first thermal test, when the front end portion of the core portion 25 of the center electrode 20 has a concave-convex shape (a concave portion and a convex portion are formed at the front end), the occurrence of a front gap TG is suppressed as compared with the case in which the front end portion of the core portion 25 does not have a concave-convex shape (the front end portion has a simple convex shape). This may be because of the following reason. When the front end portion of the core portion 25 of the center electrode 20 has a concave-convex shape, the area of contact between the core portion 25 and the cover portion 21 becomes relatively large, and a relatively large diffusion layer is formed therebetween, so that the occurrence of a front gap TG is suppressed.
In the second thermal test, the front end portion of each center electrode 20 was heated for 2 minutes using a burner and then cooled for 1 minute, and this cycle was repeated. The temperature setting used was such that the temperature of the front end of the center electrode 20 of sample No. 15 reached 850° C. A cross-section of the center electrode 20 was observed visually and under a microscope after 1,000 cycles, 1,500 cycles, and 2,000 cycles to judge whether or not a front gap TG occurred between the cover portion 21 and the core portion 25 on the front side. As described above, the second thermal test was performed to examine whether or not a front gap TG occurred under severer conditions than those in the first thermal test described above.
In the second thermal test, the occurrence of a large front gap TG was found after 1,000 cycles in samples with the front end shape of type 1 (samples Nos. 15 and 16) and a sample with the front end shape of type 2 and having a value of the diameter ratio W1/W2 of 0.5 (sample No. 17), as shown in
In a sample having a value of the diameter ratio W1/W2 of 0.5 (sample No. 20) among samples with the front end shape of type 4, the occurrence of a front gap TG was not found after 1,000 cycles, but the occurrence of a small front gap TG was found after 1,500 cycles. However, the front gap TG formed was small even after 2,000 cycles. In a sample having a value of the diameter ratio W1/W2 of 0.6 (sample No. 21) among the samples with the front end shape of type 4, the occurrence of a front gap TG was not found after 1,500 cycles, and a front gap TG formed was small even after 2,000 cycles. These results show that when a concave portion and a convex portion are formed at the front end of the core portion 25 and at least part of the convex portion is a small convex portion, the occurrence of a front gap TG can be suppressed. This may be because the concave-convex shape of the front end portion of the core portion 25 provides the effect of increasing the area of contact between the core portion 25 and the cover portion 21 and because the small convex portion of the core portion 25 functions as a wedge for the cover portion 21. These results also show that when the value of the diameter ratio W1/W2 is large (for example, 0.6 or larger), the occurrence of a front gap TG can be more satisfactorily suppressed. This may be because the larger the value of the diameter ratio W1/W2, the larger the volume of the core portion 25 on the front side of the center electrode 20, and the higher the heat transfer performance of the center electrode 20.
In a sample having a value of the diameter ratio W1/W2 of 0.5 (sample No. 22) among samples with the front end shape of type 5, the occurrence of a front gap TG was not found after 1,000 cycles. Although the occurrence of a small front gap TG was found after 1,500 cycles, the formed front gap TG was still small even after 2,000 cycles. In a sample having a value of the diameter ratio W1/W2 of 0.7 (sample No. 23) among the samples with the front end shape of type 5, the occurrence of a front gap TG was not found after 1,500 cycles, and a front gap TG formed was still small even after 2,000 cycles. These results show that when a concave portion and a convex portion are formed at the front end of the core portion 25 and a diameter reduction portion SR is also formed, the occurrence of a front gap TG can be suppressed. This may be because of the following reasons. The concave-convex shape of the front end portion of the core portion 25 provides the effect of increasing the area of contact between the core portion 25 and the cover portion 21. In addition, the diameter reduction portion SR of the core portion 25 functions to prevent the cover portion 21 from coming off and increases the area of contact between the cover portion 21 and the core portion 25. These results also show that when the value of the diameter ratio W1/W2 is large (for example, 0.7 or larger), the occurrence of a front gap TG can be more satisfactorily suppressed. This may be because the larger the value of the diameter ratio W1/W2, the larger the volume of the core portion 25 on the front side of the center electrode 20, and the higher the heat transfer performance of the center electrode 20.
In a sample with the front end shape of type 6 (sample No. 24), the occurrence of a front gap TG was not found even after 2,000 cycles. This result shows that the occurrence of a front gap TG can be very satisfactorily suppressed when a concave portion and a convex portion are formed at the front end of the core portion 25, at least part of the convex portion is a small convex portion, a diameter reduction portion SR is formed, and the center electrode 20 has a cross section perpendicular to the axis OL (a radial cross section) in which the core portion 25, the cover portion 21, the core portion 25, the cover portion 21, and the core portion 25 are arranged in that order on at least one straight line passing through the center CG of the cross section. This may be because of the following reasons. When the core portion 25 has the above-described shape, the area of contact between the cover portion 21 and the core portion 25 is further increased, and the wedge effect due to the small convex portion and the effect of preventing coming-off due to the diameter reduction portion SR are achieved over a relatively wide region on the radial cross section.
The present invention is not limited to the above embodiments and modes and may be embodied in various other forms without departing from the scope of the invention. For example, the following modifications are possible.
The structures of the spark plug 100 and the center electrode 20 serving as a component thereof in the above embodiment are only examples and can be modified variously. For example, in the above embodiment, the center electrode 20 has a two-layer structure composed of the cover portion 21 and the core portion 25. However, for example, the center electrode 20 may include a double-layered core portion 25 (in this structure, for example, an inner portion formed of a nickel alloy is covered with an outer portion formed of copper) and have a structure including a total of three layers. Alternatively, the center electrode 20 may have a structure including four or more layers. The materials of the layers in the center electrode 20 are not limited to the materials described in the above embodiment. Of course, the structure and material of the work W used as the starting member for producing the center electrode 20 are not limited to the structure and material described in the above embodiment.
The effects of the present invention are achieved when the diameter R1 of the radial cross section of the center electrode 20 at the front end position of the core portion 25 is larger than 2.1 mm (i.e., the radial cross-sectional area of the center electrode 20 at this position is larger than 3.5 mm2). When the diameter R1 is 2.1 mm or less (the cross-sectional area is 3.5 mm2 or less) as in the above embodiment, a front gap TG is more likely to occur during thermal cycles. Therefore, the application of the present invention can provide a higher effect of suppressing the occurrence of a front gap TG.
The effects of the present invention can be achieved even when the value of the diameter ratio W1/W2 is less than 0.6. However, by setting the value of the diameter ratio W1/W2 to be 0.6 or larger, higher effects can be achieved, as in the above embodiment.
In the example shown in
In the above embodiment, when the center electrode 20 is produced, the work W is subjected to extrusion molding twice, and then the support portion 27 is formed. However, the number of extrusion molding processes performed before the formation of the support portion 27 may be one or three or more. In the above embodiment, the molded products M1 and M2 are cut to remove prescribed regions. However, the prescribed regions may be removed by another removing means such as polishing instead of cutting. In the above embodiment, burr treatment is performed after the cutting treatment for the secondary molded product M2. However, burr treatment may be performed also after cutting treatment for the primary molded product M1. The burr treatment may not be performed.
In the description of the above embodiment, the present invention is applied to the center electrode 20. However, the present invention is applicable to the ground electrode 30.
Among the components of the invention in the above embodiments, components other than components described in an independent claim are optional components and can be appropriately omitted or combined.
Number | Date | Country | Kind |
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2011-134752 | Jun 2011 | JP | national |
Filing Document | Filing Date | Country | Kind | 371c Date |
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PCT/JP2012/001561 | 3/7/2012 | WO | 00 | 12/6/2013 |
Publishing Document | Publishing Date | Country | Kind |
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WO2012/172712 | 12/20/2012 | WO | A |
Number | Name | Date | Kind |
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20080122334 | Kishimoto et al. | May 2008 | A1 |
20100275870 | Kameda | Nov 2010 | A1 |
Number | Date | Country |
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60-142487 | Sep 1985 | JP |
4-206376 | Jul 1992 | JP |
7-37678 | Feb 1995 | JP |
2008130463 | Jun 2008 | JP |
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JPO/ISA, International Search Report issued in the international stage of subject application, PCT/JP2012/001561, mailed Jun. 12, 2012. |
Number | Date | Country | |
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20140111079 A1 | Apr 2014 | US |