Claims
- 1. A spinel-type lithium-manganese oxide represented by the following formula:{Li}[Lix.Mn2−x−y1−y2.M1y1.M2y2]O4+d, wherein { } represents oxygen tetrahedral sites in a spinel structure, [ ] represents oxygen octahedral sites in the spinel structure, 0<x≦0.33, 0<y1, 0<y2, 0<y1+y2≦1.0, −0.5<d<0.8; M1 and M2 are each at least one element selected from the group consisting of Be, Mg, Ca, Sr, Ba, Zn, B, Al, Ga, In, Si, Ge, Sn, Pb, P, As, Sb and Bi; and M1 and M2 are different.
- 2. The spinel-type lithium-manganese oxide according to claim 1, wherein 0<x≦0.15 and 0.02≦y1+y2≦0.2.
- 3. The spinel-type lithium-manganese oxide according to claim 1, which has a cubic crystal structure having a lattice constant a of not less than 8.19 angstroms and not more than 8.24 angstroms.
- 4. The spinel-type lithium-manganese oxide according to claim 1, which has an average diameter of aggregated particles of 1-50 μm and a BET specific surface area of 0.1-5 m2/g.
- 5. The spinel-type lithium-manganese oxide according to claim 1, which has an average primary particle diameter of not more than 3 μm.
- 6. A process for preparing a spinel-type lithium-manganese oxide, the process comprisingforming a mixture including a starting manganese compound, a starting lithium compound, and a starting compound containing a heteroelement; calcining the mixture; and forming the spinel-type lithium-manganese oxide of claim 1, wherein a manganese oxide having an average diameter of aggregated particles of 0.5-50 μm is used as the starting manganese compound.
- 7. The process according to claim 6, wherein a density of the starting manganese compound is not less than 2.7 g/cm3.
- 8. The process according to claim 6, wherein Na and K contents in the starting manganese compound are each not more than 500 ppm.
- 9. The process according to claim 6, wherein BET specific surface area of the starting lithium compound is not less than 1 m2/g.
- 10. The process according to claim 9, wherein lithium carbonate is used as the starting lithium compound.
- 11. The process according to claim 6, wherein the calcining is conducted at a temperature of 500 to 1000° C. in air.
- 12. The process according to claim 6, further comprising granulating the starting manganese compound and the starting lithium compound before calcining the mixture.
- 13. A Li secondary battery comprising a positive electrode, a negative electrode, a non-aqueous electrolyte that comprises a Li-containing electrolyte dissolved therein, and a separator, wherein the spinel-type lithium-manganese oxide of claim 1 is used as an active material for the positive electrode.
- 14. The Li secondary battery according to claim 13, wherein a carbonaceous material electrochemically intercalated/deintercalated with lithium ions is used as an active material for the negative electrode.
Priority Claims (1)
Number |
Date |
Country |
Kind |
9-162131 |
Jun 1997 |
JP |
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Parent Case Info
This application is a Division of application Ser. No. 09/099,131, filed on Jun. 18, 1998, U.S. Pat. No. 6,168,888.
US Referenced Citations (11)
Foreign Referenced Citations (1)
Number |
Date |
Country |
09-147863 |
Jun 1997 |
JP |
Non-Patent Literature Citations (2)
Entry |
JPO Machine Translation for JP 09-147863 A (Jun. 1997).* |
Pistoia et al. (“Doped Li-Mn Spinels: Physical/Chemical Charateristics and Electrochemical Performance in Li Batteries”, Chem. Mater. 1997, vol. 9, pp. 1443-1450). |