Information
-
Patent Grant
-
6746226
-
Patent Number
6,746,226
-
Date Filed
Friday, December 8, 200024 years ago
-
Date Issued
Tuesday, June 8, 200420 years ago
-
Inventors
-
Original Assignees
-
Examiners
- Davis; Robert
- De Sole; Joseph S
Agents
- Russell; Linda K.
- Haynes; Elwood L.
-
CPC
-
US Classifications
Field of Search
US
- 425 3822
- 425 DIG 217
- 425 463
- 425 1315
- 264 17211
- 264 17215
- 264 541
- 264 17127
-
International Classifications
-
-
Disclaimer
Terminal disclaimer Term Extension
16
Abstract
The invention provides a spinnerette assembly for forming multicomponenthollow fibers of the sheath/core type. The spinnerette assembly contains an extrusion orifice and a core forming material passage in communication with the extrusion orifice. A hollow needle extends through the extrusion orifice in a concentric manner to define an annular passage surrounding the needle. The core forming material passage includes a core forming material inlet port extending from a surface of the spinnerette assembly to an interior of the assembly and a transverse passage extending from the core forming material port to the annular passage surrounding the needle. A bore forming fluid passage communicates with the interior of the needle. The spinnerette assembly contains at least one sheath forming material passage also in communication with the extrusion orifice.
Description
FIELD OF THE INVENTION
This invention relates to spinnerette assemblies for forming hollow fibers. It particularly relates to an improved spinnerette for more efficient and precise production of multi-component hollow fibers.
BACKGROUND OF THE INVENTION
It is well known to use various hollow fibers, generally made of one or more polymer materials, for various applications. For example, hollow fibers are used in carpets, as fill materials for pillows, as insulation materials for blankets and garments, and as membranes for gas separation, blood dialysis, purification of water, and other filtering applications. For membrane applications, the hollow fibers may be composed of a single component or a plurality of components, such as a hollow structured core with a sheath disposed around the core acting as a separating layer. The fibers can be bundled together and disposed in a tubular housing to provide a separation device known as a permeator. Ordinarily, the hollow fibers are relatively small, having a diameter on the order of 30 to 1000 micrometers. Accordingly, the apparatus and method for manufacturing hollow fibers must be very precise to be able to control the diameter of the fiber, and the concentricity of the core and sheath around the bore.
Numerous spinning assemblies have been devised for the production of single-component hollow fibers and multi-component hollow fibers of the sheath/core type. Particularly, devices have been proposed for ensuring uniform supply of the fiber-forming fluid or fluids to the orifices of a spinnerette with the object of producing hollow fibers identical in diameter, composition, and concentricity. These spinnerettes use a means for supplying the bore fluid positioned in the spinning orifice for forming the hollow fiber. Usually, a tube or needle is used for this purpose and a gaseous or liquid fluid is injected from the tube, thus forming the bore of the fiber as it is being extruded from the spinnerette orifice. For melt spinning, the nascent fiber can be solidified by cooling in a gaseous or liquid cooling fluid. For solution spinning, the nascent fiber can be solidified by evaporation of the solvent or by contacting the fiber with a solvent-extracting liquid that results in coagulation of the polymer solution(s) to form the fiber wall.
A typical spinning assembly, such as described in U.K. Patent No. 830,441 for a multi-component fiber, comprises a front and back plate spaced apart from but facing each other so as to provide a liquid channel there between. The front plate is provided with an extrusion orifice therethrough, and at least one of the plates, on the side facing the other plate, is provided with a plateau-type protrusion so as to constrict the liquid channel in a region surrounding the extrusion orifice entrance and, thus, cause the stream of the sheath-forming material to converge substantially radially towards the orifice entrance. A tube is positioned in the orifice entrance to supply the bore fluid. However, a continuing problem is the uniform supply of core- and sheath-forming material during the formation of the multi-component fiber. Most spinnerettes of this type are made largely by hand, one at a time. As a result, parts made for one spinnerette will not always fit another spinnerette. When parts are not interchangeable, any damage to one part of the spinnerette assembly may render the entire assembly useless. In assembling or cleaning conventional bicomponent or hollow-fiber spinnerettes, it is very easy to slightly bend the fluid-injection tube or needle, such that it is off center of the spinning orifice. When this happens, the spinnerette cannot be used until repaired.
Another related problem of conventional spinnerettes for multi-component hollow fibers is that the sheath and core of the hollow fiber are not concentric. Concentricity of the sheath and core are important to obtain uniform fibers. Concentricity of the sheath and core was customarily obtained by adjustment of metering surfaces to regulate (meter) the flow of the polymers. The metering surfaces are produced by closely machining two surfaces so as to produce a narrow opening which will effectively meter polymer at a uniform pressure and rate as it is being extruded. U.S. Pat. No. 3,458,615 discloses a method for maintaining sheath/core concentricity by circumferential metering of the polymer sheath to be extruded about the polymeric core involving the creation of an annular wedged-shaped flow of sheath polymer around the axially-contained fluid stream.
In order to maintain the concentricity of fiber diameter and the bore diameter, other spinnerettes have been provided with members for centering the tube and the bore of the spinnerette plate. For example, U.S. Pat. No. 4,493,629 describes a modular spinnerette assembly fitted with multiple screws threaded through the spinnerette plate to center the tube and orifice of the spinnerette. These adjusting screws are unreliable and are prone to error when the spinnerette is disassembled, cleaned and then reassembled. Many devices have been proposed for ensuring uniform supply of homogenous sheath-forming liquid to the orifices of a multi-orifice spinnerette with the object of producing multiple hollow fibers with concentric layers, identical in denier and other characteristics. Such devices usually involve variations in the diameter or the location of orifices and single or multiple spinnerette plates. Lack of concentricity and uniformity remain a problem in the manufacture of such single-component and multi-component fibers.
Another problem with existing spinnerettes is the ability to deliver the polymer fluid or fluids uniformly around the tube or needle within the spinnerette. U.S. Pat. No. 5,320,512 discloses a spinneret that has a plurality of discrete material passages formed around the needle to deliver the polymer fluid around the needle. The polymer fluid from these individual passages must converge and meld together to form a singular annular flow around the tube or needle as the polymer fluid traverses through the main polymer fluid passage. If complete melding is not attained, seams may develop down the length of the fiber at the interfaces where the individual flows did not fully converge.
Therefore, it would be desirable to have a spinnerette design which would permit the production of concentric and uniform fibers without the risk of seaming.
SUMMARY OF THE INVENTION
The present invention provides an improved spinnerette for the production of hollow fibers.
It is an object of the invention to overcome the limitations of conventional spinnerettes.
It is another object of the invention to reduce imperfections in hollow fibers.
It is another object of the invention to extend hollow-fiber production run times.
It is another object of the invention to reduce the time for spinnerette maintenance.
It is another object of the invention to simplify spinnerette fabrication.
It is another object of the invention to produce high quality composite fibers having one or more sheath layers in an efficient manner.
To achieve these objects, a first aspect of the invention is a spinnerette assembly for forming a composite hollow fiber comprising:
at least one extrusion orifice formed in said spinnerette assembly;
a hollow needle extending through each said extrusion orifice in a concentric manner to define an annular passage around said needle in said extrusion orifice;
a bore forming fluid passage communicating with an interior of each said needle;
at least one core forming material passage formed in said spinnerette assembly, wherein each said core forming material passage comprises a core forming material inlet port extending from a surface of said assembly to an interior of said assembly and at least one transverse passage extending from said core forming material port to each said annular passage, wherein a portion of said transverse passage entirely surrounds each said needle in a continuous manner; and at least one sheath forming material passage, wherein each said sheath forming material passage comprises a sheath forming material port extending from a surface of said assembly to each said annular passage.
A second aspect of the invention is a method of forming a composite hollow fiber comprising the steps of:
delivering a core forming material to each annular passage in the spinnerette assembly, said core forming material entering the spinnerette assembly through one or more core forming material inlet ports and passing through the interior of said assembly to a transverse passage, a portion of said transverse passage entirely surrounding each needle in a continuous manner, and through an annular passage in communication with an extrusion orifice, and
delivering at least one sheath forming material concentrically around the core forming material as it traverses through each said annular passage,
extruding the layered core forming material and at least one sheath forming material through the extrusion orifice and around each said needle,
injecting a bore forming fluid into each needle to thereby provide a layered composite fiber comprising a bore forming fluid, a core forming material, and a sheath forming material as it exits the spinnerette assembly through the extrusion orifice,
optionally passing the nascent extruded hollow fiber through an air gap, and
solidifying the hollow fiber by cooling, solvent evaporation, or solvent extraction.
BRIEF DESCRIPTION OF THE DRAWINGS
The invention is described through a preferred embodiment and the attached drawings in which:
FIG. 1
is a top view of a spinnerette according to a first preferred embodiment of the invention;
FIG. 2
is a sectional view of the first preferred embodiment taken along line A—A in
FIG. 1
showing one extrusion arrangement;
FIG. 3
is an alternative construction of spinnerette body of the first preferred embodiment;
FIG. 4
is a top view of a second preferred embodiment of the invention for spinning multiple filaments from a single core forming material passage; and
FIG. 5
is a sectional view of a third preferred embodiment of the invention for spinning multiple-sheath hollow fibers.
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT
In the first preferred embodiment of the invention for the extrusion of multiple hollow fibers, as illustrated in
FIGS. 1 and 2
, a spinnerette assembly
100
comprises a spinnerette body
110
, bottom plate
120
, and needles
130
. The specific arrangement shown in
FIG. 1
is for simultaneous extrusion of twelve hollow fibers, but the spinneret assembly
100
can be modified to produce a single filament or any number of multiple filaments as may be required. A proximal end of each needle
130
is secured in a respective needle mounting hole
111
formed in spinnerette body
110
by drilling or another machining process. The outer diameter of the proximal end of needle
130
and the diameter of mounting hole
111
preferably are sized such that the proximal end of needle
130
can be pressure fitted into needle mounting hole
111
to secure needle
130
to spinnerette body
110
. Needle
130
can be secured to spinnerette body
110
in any appropriate manner that permits access of the bore at the proximal end of needle
130
to the bore forming fluid passages
112
in the spinnerette body
110
. Bottom plate
120
is secured to spinnerette body
110
by fasteners
131
, such as bolts or the like threaded through holes
132
. Channels
144
and
145
formed in the bottom surface of spinnerette body
110
are in communication with gap
141
defined between spinnerette body
110
and bottom plate
120
. Shim
140
disposed between spinnerette body
110
and bottom plate
120
defines the dimension of gap
141
that provides uniform delivery of the sheath forming material around the core forming material in a concentric fashion as the core forming material flows through annular passages
153
and
154
respectively. Flared recesses
156
are formed in bottom plate
120
to permit the multiplicity of extruded fibers to exit spinnerette assembly
100
without interference. In the preferred embodiment, the multiple extrusion arrangements are situated in a linear or circular fashion.
Bore forming fluid passage
112
is formed in spinnerette body
110
and extends through spinnerette body
110
to a respective needle mounting hole
111
to be in communication with the passage formed through needle
130
. Each bore forming fluid passage
112
includes a bore forming fluid inlet port
113
at the surface of spinnerette body
110
. This structure permits a bore forming fluid to be introduced into an extruded fiber to maintain the hollow structure of the extruded fiber in the manner described below.
Core forming material passages
150
are formed in spinnerette body
110
through which a core forming material, such as a polymer material, is delivered to the extrusion orifices
155
. Each core forming material passage
150
includes an inlet port
151
that is a hole extending in a direction that is substantially parallel to needle
130
. Each core forming material passage
150
also includes a transverse passage
152
that extends from core forming inlet port
151
to a top portion of annular passage
153
that defines the upper portion of extrusion orifice
155
. Transverse passage
152
is defined by a backcut portion formed in spinnerette body
110
by a tool inserted through core forming material port
151
. Transverse passage
152
extends entirely around needle
130
to permit core forming material to be evenly distributed around needle
130
and evenly introduced into annular passages
153
and
154
.
Sheath forming material inlet port
142
and sheath forming material passage
143
are formed in spinnerette body
110
to be in communication with channels
144
to permit sheath forming material to be delivered through sheath forming material inlet port
142
and sheath forming material passage
143
, through channels
144
and
145
, and through gap
141
. As sheath forming material exits gap
141
, it is distributed evenly around core forming material at the intersection of gap
141
and annular passage
154
.
In operation, spinnerette assembly
100
is mounted to a spinning machine through mounting holes
115
using an appropriate fastening mechanism such as bolts or the like. A bore forming fluid supply, a core forming material supply, and a sheath forming material supply of the machine are coupled respectively to the bore forming fluid inlet port
113
, the core forming material inlet port
151
, and the sheath forming material inlet port
142
. Note that there is one bore forming material inlet port
113
and one core forming material inlet port
151
for each extrusion orifice
155
; whereas, one sheath forming material inlet port
142
provides delivery of sheath forming material to each extrusion orifice through sheath forming material passage
143
and channels
144
and
145
and gap
141
. These ports can be arranged in any way and can be of any number as is appropriate to deliver the materials to the proper passages. For the spinning of hollow fibers, a core forming material, a sheath forming material, and a bore forming fluid are simultaneously delivered into spinneret
100
at known pressures and flow rates to extrude (i.e., spin) hollow fibers. Typically, the core forming material is injected at about 300-500 psig, the sheath forming material is injected at about 150-300 psig, and the bore forming fluid is injected at about 4-5 psig.
Core forming material travels through core forming material inlet port
151
, through the core forming material passage
150
, into transverse passage
152
, and into upper annular passage
153
. At the same time, sheath forming material travels through sheath forming material inlet port
142
, through sheath forming material passage
143
, and into channel
144
. It should be noted that the dimensions of channel
144
are designed to provide sheath forming material at the entrance to each channel
145
at essentially the same pressure so as to provide uniform delivery of sheath forming material through gap
141
. At the exit of gap
141
, the flow of sheath forming material circumferentially intersects with the flow of core forming material at the gap between the upper and lower annular passages
153
and
154
respectively, thus forming a uniform layer or coating of sheath forming material concentrically around the outer surface of the core forming material. Further, simultaneous with the delivery of the core forming material and the sheath forming material through the spinnerette assembly
100
, a bore forming fluid is injected into the bore forming fluid inlet port
113
, through bore forming fluid passage
112
, and into needle
130
. The bore fluid emerges from the distal end of needle
130
at a position within or just downstream of extrusion orifice
155
. Since the core forming material and sheath forming material are being simultaneously extruded through the lower annular passage
154
and out of the extrusion orifice
155
concentrically around needle
130
and the emerging bore forming fluid therefrom, the resultant extrudate is a fiber comprised of a bore forming fluid at the center, concentrically surrounded by a core forming material that is concentrically coated with a sheath forming material.
As best illustrated in
FIGS. 1 and 2
, transverse passage
152
is a backcut portion having a terminal portion that entirely surrounds needle
130
in a continuous manner and is in communication with upper annular passage
153
. This construction eliminates the problem of uniform distribution of core forming material around needle
130
. It also eliminates the problem of longitudinal seaming down the fiber wall due to incomplete melding of a plurality of core forming material streams within the annular passage as disclosed in U.S. Pat. No. 5,320,512. Also, since the core forming material passage
150
and transverse passage
152
are readily accessible when the spinnerette assembly is removed from the spinning machine, cleaning of the spinnerette is relatively easy. This facilitates cleaning and reduces turnaround time for the spinnerette. Also, core forming material passage
150
can be easily machined in spinnerette body
110
by drilling, and transverse passage
152
can be easily and precisely formed by EDM techniques using an angular electrode. Further, since needle
130
is securely fixed to the spinnerette body into mounting hole
111
, alignment of the needle concentrically within upper and lower annular passages
153
and
154
is assured and thus laborious and intricate alignment processes are obviated, thereby further reducing turnaround time.
Spinnerette assembly
100
of the preferred embodiment has fewer parts and is more easily manufactured as compared to conventional spinnerettes.
FIG. 3
illustrates an alternative construction of the spinnerette body of the first preferred embodiment that further simplifies the spinnerette manufacturing process. In the first preferred embodiment depicted in
FIG. 2
, bore forming fluid passage
112
must be machined, e.g. drilled, at an angle and with a high degree of precision to accurately meet and communicate with needle mounting hole
111
without damaging the integrity of needle mounting hole
111
, which has a relatively small diameter. The spinnerette body of
FIG. 3
has an alternative design that obviates this intricate machining step and thus reduces the cost of manufacturing a spinnerette. In particular, a secondary bore forming fluid passage
114
is machined substantially parallel to core forming material passage
150
and extends from the surface of spinnerette body
110
to needle mounting hole
111
, and is concentric with needle mounting hole
111
. Since secondary bore forming fluid passage
114
is coaxial with needle mounting hole
111
, the machining process is greatly simplified. Bore forming fluid passage
112
′ is machined in spinnerette body
110
so as to originate at bore forming fluid inlet port
113
and intersect with secondary bore forming fluid passage
114
at a point substantially removed from needle mounting hole
111
. Angled bore forming fluid passage
112
′ is readily machined to communicate with secondary bore forming fluid passage
114
(that can be machined prior to machining angled passage
112
′) because the diameters of angled passage
112
′ and passage
114
are relatively large as compared to the diameter of needle mounting hole
111
. The opening of secondary bore forming fluid passage
114
at the face of spinnerette body
110
can be plugged or otherwise sealed prior to or during mounting of the spinnerette assembly
100
onto the spinning machine to avoid leakage of the bore forming fluid. Other aspects of the alternative design of
FIG. 3
are similar to the design of
FIG. 2
described above.
A second preferred embodiment in accordance with the invention is illustrated in
FIG. 4
, which depicts a method for increasing the number of fibers per spinnerette by a factor of two. For illustrative purposes and clarity, the numeration used in
FIG. 4
is 100 greater than for corresponding components in
FIGS. 1
,
2
, and
3
.
FIG. 4
is a top view of spinnerette body
210
. The distinguishing feature between this embodiment and the one depicted in
FIGS. 1
,
2
, and
3
is that for each core forming material passage
250
are formed two transverse passages
252
a
and
252
b
, each in the form of a backcut portion. Each traverse passage
252
a
and
252
b
are provided with an annular passage
253
a
and
253
b
respectively (corresponding to annular passage
153
in FIGS.
2
and
3
), and needles
230
a
and
230
b
(corresponding to needles
130
in FIGS.
2
and
3
). Similarly, other features in spinnerette body
110
and bottom plate
120
depicted in
FIGS. 1
,
2
, and
3
are provided as corresponding features in spinnerette body
210
and bottom plate
220
. Thus, with reference to
FIGS. 3 and 4
the transverse passages
252
a
and
252
b
extend from core forming material passage
250
to the edge of the annular passages
253
a
and
253
b
around each needle
230
a
and
230
b
of the corresponding extrusion orifice. Plural needles
230
a
and
230
b
are disposed in spinnerette body
210
and are in communication with bore forming fluid passage
214
a
and
214
b
. Each needle extends through a corresponding extrusion orifice
255
a
and
255
b
defined by the cylindrical upper and lower annular passages
253
a
and
253
b
, and
254
a
and
254
b
respectively. Channels
244
and
245
formed in the bottom surface of spinnerette body
210
are in communication with gap
241
a
and
241
b
defined between spinnerette body
210
and bottom plate
220
. Shim
240
disposed between spinnerette body
210
and bottom plate
220
defines the dimension of gap
241
that provides uniform delivery of the sheath forming material around the core forming material in a concentric fashion at the intersection of gaps
241
a
and
241
b
and annular passages
254
a
and
254
b
respectively. Sheath forming material inlet port
242
and sheath forming material passage
243
are formed in spinnerette body
210
to be in communication with channels
244
to permit sheath forming material to be delivered through sheath forming material inlet port
242
and sheath forming material passage
243
, through channels
244
and
245
, and through gaps
241
a
and
241
b
. The bore forming fluid is supplied to spinnerette body
210
through bore forming fluid inlet port
213
. The bore forming fluid is distributed from each bore forming fluid inlet port
213
through channels
212
′
a
and
212
′
b
to each bore forming fluid passages
214
a
and
214
b
. Accordingly, the spinnerette assembly
200
can be attached to the same spinning machine to produce twice as many fibers. One skilled in the art can envision additional embodiments to spin fibers in multiples greater than two (e.g., 3, 4, 5) based on the above embodiments.
FIG. 5
illustrates a third preferred embodiment of the invention adapted to make hollow fibers of three components. For illustrative purposes and clarity, the numeration used in
FIG. 5
for corresponding components in
FIGS. 1
,
2
, and
3
is 200 greater than that in
FIGS. 1
,
2
, and
3
). Spinnerette assembly
300
comprises spinnerette body
310
, bottom plate
320
, plural needles
330
(one of which is visible in FIG.
5
), and middle plate
360
disposed between spinnerette body
310
and bottom plate
320
. Shim
340
a
is disposed between spinnerette body
310
and middle plate
360
, and shim
340
b
is disposed between middle plate
360
and bottom plate
320
. Spinnerette body
310
, middle plate
360
, bottom plate
320
, and shims
340
a
and
340
b
are assembled into a unitary body during use as described in detail below. A proximal end of each needle
330
is secured, e.g., by a pressure fit, in a respective needle mounting hole
311
formed in spinnerette body
310
by drilling or another machining process. Bottom plate
320
and middle plate
360
are secured to spinnerette body
310
by fasteners
331
, such as bolts or the like threaded through holes
332
, with shim
340
a
defining a gap
341
a
. Additionally, shim
340
b
defines a gap
341
b
between middle plate
360
and bottom plate
320
.
Apertures corresponding to annular passages
353
,
363
, and
354
are formed in spinnerette body, middle plate, and bottom plate respectively through which a core forming material, a core material plus a first sheath forming material, and a core forming material plus a first and second sheath forming material are extruded respectively. This nascent three-component hollow-fiber ultimately exits the spinnerette assembly through extrusion orifice
355
. Flared recesses
356
are formed in a bottom surface of the bottom plate
320
to permit each extruded fiber to exit spinnerette assembly
300
without interference for further processing by a spinning machine on which spinnerette assembly
300
is mounted. Channels
344
a
and
345
a
are formed in a bottom surface of spinnerette body
310
, and are in communication with gap
341
a
. Channels
344
b
and
345
b
are formed in a top surface of bottom plate
320
, and are in communication with gap
341
b.
Core forming material passages
350
are formed in spinnerette body
310
through which a core forming material, such as a polymer material, is introduced into each extrusion orifice. Each core forming material passage
350
includes core forming material inlet port
351
which is a hole extending in a direction that is substantially parallel to the extrusion orifice. Each core forming material passage
350
also includes transverse passage
352
which extends from core forming material inlet port
351
to a top portion of annular passage
353
which defines an upper portion of the extrusion orifice. Transverse passage
352
is defined by a backcut portion formed in spinnerette body
310
by a tool inserted through core forming material inlet port
350
and extends entirely around needle
330
to permit the core forming material to be evenly introduced into annular passage
353
.
Bore forming fluid inlet port
313
and bore forming fluid passages
312
and
314
are formed in spinnerette body
310
to be in open communication with needle mounting hole
311
. This arrangement permits a bore forming fluid to be introduced into an extruded fiber to maintain the hollow structure of the extruded fiber in the manner described below.
A first sheath forming material inlet port
342
a
is formed in spinnerette body
310
to be in communication with channels
344
a
to permit a first sheath forming material, such as a polymer material, to be introduced into the first sheath forming material inlet port
342
a
, through first sheath forming material passage
343
a
, into channels
344
a
and
345
a
, through gap
341
a
, and into annular passage
363
.
Similarly, a second sheath forming material inlet port
342
b
is formed in bottom plate
320
to be in communication with channel
344
b
to permit a second sheath forming material, such as a polymer material, to be introduced into the second sheath forming material inlet port
342
b
, through second sheath forming material passage
343
b
, into channels
344
b
and
345
b
, through gap
341
b
, and into annular passage
354
. Other aspects of the third preferred embodiment are similar to the first preferred embodiment and like elements are labeled with similar numerals having a prefix of “3”.
Operation of the third preferred embodiment is similar to the first preferred embodiment. However, the second sheath forming material travels through second sheath forming material inlet port
342
b
, through second sheath forming material passage
343
b
, into channels
344
b
and
345
b
, through gap
341
b
, and into annular passage
354
. As second sheath forming material enters annular passage
354
, it is deposited uniformly around the material flowing from annular passage
363
(e.g., core forming material coated with first sheath forming material) into annular passage
354
. Accordingly, a hollow fiber having a core, a first sheath deposited uniformly on the core, and a second sheath deposited uniformly on the first sheath plus core, all in a concentric manner, is formed.
The various ports, channels, and passages in the spinnerette assemblies described above can be formed in any manner and can be of any number to produce fibers having plural sheaths and core. For example, the core forming material passage can be of any shape or configuration and can comprise plural channels or a single channel. The spinnerette assemblies can be machined using any known techniques such as drilling, electronic discharge machining (EDM), or any other suitable process or processes. There can be any number of extrusion orifices. The invention can be used to make hollow fibers of any type and of any material amenable to extrusion. The various angles and dimensions can be varied to suit the particular application. The spinnerette assemblies can be manufactured of any suitable material such as steel, monel, titanium, aluminum, or alloys thereof. The core forming material and the sheath forming material(s) can be of any type amenable to extrusion such as polymer melts or solutions, ceramic pastes, and the like. The bore forming fluid can be an inert gas or liquid for example.
The invention has been described through preferred embodiments. However, various modifications can be made without departing from the scope of the invention as defined in the appended claims.
Claims
- 1. A spinnerette assembly for forming one or more composite hollow fibers comprising:a unitary spinnerette body; at least one extrusion orifice formed in said unitary spinnerette body; a hollow needle being affixed in a needle mounting hole formed in said unitary spinnerette body and wherein said needle mounting hole receives a portion of said hollow needle, said hollow needle extending through each said at least one extrusion orifice in a concentric manner to define at least one annular passage around said needle in said at least one extrusion orifice; a bore forming fluid passage formed in said unitary spinnerette body, said bore forming fluid passage communicating with the interior of each said hollow needle; at least one core forming material passage formed in said unitary spinnerette body, wherein each said at least one core forming material passage comprises a core forming material inlet port extending from a surface of said spinnerette body to an interior of said unitary spinnerette body and at least one transverse passage extending form said core forming material port to each said at least one annular passage; and a sheath forming material passage formed in said unitary spinnerette body wherein said sheath forming material passage comprises a sheath forming material port extending from a surface of said unitary spinnerette body to each said annular passage.
- 2. A spinnerette assembly as recited in claim 1, wherein said at least one transverse passage is a backcut portion of said at least one core forming material passage that entirely surrounds said hollow needle in a continuous manner and is in communication with said at least one extrusion orifice.
- 3. A spinnerette assembly as recited in claim 1, wherein each said core forming material port extends substantially parallel to said at least one extrusion orifice and said at least one transverse passage extends substantially perpendicular to said core forming material port.
- 4. A spinnerette assembly as recited in claim 1, wherein said spinnerette assembly comprises said unitary spinnerette body and a bottom plate separated from each other by a shim disposed between said unitary spinnerette body and said bottom plate.
- 5. A spinnerette assembly as recited in claim 4 wherein each said needle mounting hole is in communication with said bore forming fluid inlet port at a surface of said unitary spinnerette body via said bore forming fluid passage.
- 6. A spinnerette as recited in claim 5, wherein said bore forming fluid passage comprises a first bore forming fluid conduit coaxial with said needle and in communication with said needle and a second bore forming fluid conduit that extends at an angle with respect to said first bore forming fluid conduit from said bore forming fluid conduit to a surface of said unitary spinnerette body.
- 7. A spinnerette assembly as recited in claim 4, wherein said extrusion orifice extends through portions of said unitary spinnerette body and said bottom plate.
- 8. A spinnerette assembly as recited in claim 4, wherein said core forming material passage is formed in said unitary spinnerette body.
- 9. A spinnerette assembly as recited in claim 4, wherein a gap between said unitary spinnerette body and said bottom plate defines a portion of said sheath forming material passage.
- 10. A spinnerette assembly for forming one or more multiple-sheath composite hollow fibers comprising:a unitary spinnerette body, at least one extrusion orifice formed in said unitary spinnerette body; a hollow needle being affixed in a needle mounting hole formed in said unitary spinnerette body and wherein said needle mounting hole receives a portion of said needle, said hollow needle extending through each said at least one extrusion orifice in a concentric manner to define at least one annular passage around said needle in said at least one extrusion orifice; a bore forming fluid passage formed in said unitary spinnerette body, said bore forming fluid passage communicating with the interior of each said needle; at least one core forming material passage formed in said unitary spinnerette body, wherein each said at least one core forming material passage comprises a core forming material inlet port extending from a surface of said unitary spinnerette body to an interior of said unitary spinnerette body and at least one transverse passage extending from said core forming material port to each said at least one annular passage; and a first sheath forming material passage, wherein said first sheath forming material passage comprises a first sheath forming material port extending from a surface of said unitary spinnerette body to each said at least one annular passage a second sheath forming material passage, wherein said second sheath forming material passage comprises a second sheath forming material port extending from a surface of said spinnerette assembly to each said annular passage.
- 11. A spinnerette assembly as recited in claim 10, wherein said transverse passage is a backcut portion of said core forming material passage that entirely surrounds said needle in a continuous manner and is in communication with said extrusion orifice.
- 12. A spinnerette assembly as recited in claim 10, wherein each said core forming material port extends substantially parallel to said extrusion orifice and said transverse passage extends substantially perpendicular to said core forming material port.
- 13. A spinnerette assembly as recited in claim 10, wherein said spinnerette assembly comprises a unitary spinnerette body, a middle plate, and a bottom plate separated by a first shim disposed between said unitary spinnerette body and said middle plate, and a second shim disposed between said middle plate and said bottom plate.
- 14. A spinnerette assembly as recited in claim 13 wherein each said needle mounting hole is in communication with said bore forming fluid inlet port at a surface of said unitary spinnerette body via a bore forming fluid passage.
- 15. A spinnerette as recited in claim 14, wherein said bore forming fluid passage comprises a first bore forming fluid conduit coaxial with said needle and in communication with said needle and a second bore forming fluid conduit that extends at an angle with respect to said first bore forming fluid conduit from said bore forming fluid conduit to a surface of said unitary spinnerette body.
- 16. A spinnerette assembly as recited in claim 13, wherein said extrusion orifice extends through portions of said unitary spinnerette body, said middle plate, and said bottom plate.
- 17. A spinnerette assembly as recited in claim 13, wherein a gap between said unitary spinnerette body and said middle plate defines a portion of said first sheath forming material passage, and the gap between said middle plate and said bottom plate defines a portion of said second sheath forming material passage.
- 18. A spinnerette assembly as recited in claim 17 wherein said second sheath forming material passage comprises said second sheath forming material inlet port situated at an exterior surface of said bottom plate in communication with a channel formed in said bottom plate, said channel being in communication with the gap defined between said bottom plate and said middle plate.
- 19. A spinnerette assembly as recited in claims 1 or 10 comprising multiple transverse passages and extrusion orifices for each core forming material port.
US Referenced Citations (5)