Split hybrid insulation structure for an appliance

Information

  • Patent Grant
  • 10345031
  • Patent Number
    10,345,031
  • Date Filed
    Thursday, August 23, 2018
    6 years ago
  • Date Issued
    Tuesday, July 9, 2019
    5 years ago
Abstract
An insulation structure for an appliance includes a first vacuum insulated structure having a top and downward sides extending from the top and defining a lower connection surface. A second vacuum insulated structure having a bottom and upward sides extending from the bottom and defining an upper connection surface, and an intermediate insulation structure having a top surface and a bottom surface, wherein the top surface engages the lower connection surface of the first vacuum insulated structure to define the first insulated interior, wherein the bottom surface engages the upper connection surface of the second vacuum insulated structure to define the second insulated interior, and wherein the intermediate insulation structure includes an appliance utility path within which at least one utility for the appliance is disposed.
Description
SUMMARY OF THE DISCLOSURE

In at least one aspect, an insulation structure for an appliance includes a first vacuum insulated structure having a top and at least one downward side extending from the top, a lower portion of the at least one downward side defining a lower connection surface. The top and the at least one downward side at least partially define a first insulated interior. A second vacuum insulated structure includes a bottom and at least one upward side extending from the bottom, an upper portion of the at least one upward side defining an upper connection surface. The bottom and the at least one upward side at least partially define a second insulated interior. An intermediate insulation structure includes a top surface and a bottom surface, wherein the top surface engages the lower connection surface of the first vacuum insulated structure to further define the first insulated interior, wherein the bottom surface engages the upper connection surface of the second vacuum insulated structure to further define the second insulated interior, and wherein the intermediate insulation structure includes an appliance utility path within which at least one utility for the appliance is disposed, and wherein the appliance utility path is in communication with the first and second insulated interiors.


In at least another aspect, a first vacuum insulated structure includes a plurality of continuous sides that define an open front, an open end and an engagement surface proximate the open end, wherein the continuous sides at least partially define a first insulated interior, and wherein the plurality of continuous sides is free of internal apertures through the first vacuum insulated structure. An intermediate insulation structure includes a first surface and a second surface, wherein one of the first and second surfaces receives the engagement surface to further define the first insulated interior. The intermediate insulation structure includes an appliance utility path within which at least one utility for the appliance is disposed, and wherein the appliance utility path is in communication with the first insulated interior.


In at least another aspect, a method for forming an insulation structure for an appliance includes disposing at least one utility system within the appliance utility path of the intermediate insulation structure, and engaging the lower connection surface of the first vacuum insulated structure with the top surface of the intermediate insulation structure to define the first insulated interior. The first insulated interior is in communication with the appliance utility path and the at least one utility. The method also includes engaging the upper connection surface of the second vacuum insulation structure with the bottom surface of the intermediate insulation structure to define the second insulated interior. The second insulated interior is in communication with the appliance utility path and the at least one utility. The engagement of the first and second vacuum insulated structures with the intermediate insulation structure forms a split hybrid insulation structure.


These and other features, advantages, and objects of the present device will be further understood and appreciated by those skilled in the art by reference to the following specification, claims, and appended drawings.





BRIEF DESCRIPTION OF THE DRAWINGS

The foregoing summary, as well as the following detailed description of the device, will be better understood when read in conjunction with the appended drawings. For the purpose of illustrating the device, there are shown in the drawings, certain embodiment(s) which are presently preferred. It should be understood, however, that the device is not limited to the precise arrangements and instrumentalities shown. Drawings are not necessary to scale.


Certain features of the device may be exaggerated in scale or shown in schematic form in the interest of clarity and conciseness.



FIG. 1 is a front perspective view of a refrigerated appliance incorporating an embodiment of the split hybrid insulation structure and shown with the doors in an open position;



FIG. 2 is an exploded perspective view of an aspect of the split hybrid insulation structure;



FIG. 3 is a cross-sectional view of the appliance of FIG. 1 taken along line III-III and illustrated with the doors in a closed position;



FIG. 4 is an enlarged cross-sectional view of the refrigerating appliance of FIG. 3 taken at area IV;



FIG. 5 is a top plan view of an aspect of an intermediate insulation structure for the split hybrid insulation system;



FIG. 6 is a cross-sectional view of an appliance incorporating an aspect of the split hybrid insulation structure and including a second intermediate insulation structure for defining a pantry compartment;



FIG. 7 is an enlarged cross-sectional view of the refrigerating appliance of FIG. 6 taken at area VII; and



FIG. 8 is a schematic flow diagram illustrating a method for forming a split hybrid insulation structure for an appliance.





DETAILED DESCRIPTION

Before the subject device is described further, it is to be understood that the device is not limited to the particular embodiments of the device described below, as variations of the particular embodiments may be made and still fall within the scope of the appended claims. It is also to be understood that the terminology employed is for the purpose of describing particular embodiments or aspects of embodiments, and is not intended to be limiting. Instead, the scope of the present device will be established by the appended claims.


Where a range of values is provided, it is understood that each intervening value, to the tenth of the unit of the lower limit unless the context clearly dictates otherwise, between the upper and lower limit of that range, and any other stated or intervening value in that stated range, is encompassed within the device. The upper and lower limits of these smaller ranges may independently be included in the smaller ranges, and are also encompassed within the device, subject to any specifically excluded limit in the stated range. Where the stated range includes one or both of the limits, ranges excluding either or both of those included limits are also included in the device.


In this specification and the appended claims, the singular forms “a,” “an” and “the” include plural reference unless the context clearly dictates otherwise.


As illustrated in FIGS. 1-4, reference numeral 10 generally refers to a split hybrid insulation structure to be disposed within an insulation cavity 12 of an appliance 14 where the insulation cavity 12 is defined between an inner liner 16 and an outer wrapper 18 of the appliance 14. An insulation structure 10 for the appliance 14 includes a first vacuum insulated structure 20 having a top side 22 and at least one downward side 24 extending from the top side 22. A lower portion 26 of the at least one downward side 24 defines a lower connection surface 28. The top side 22 and the at least one downward side 24 at least partially define a first insulated interior 30. A second vacuum insulated structure 40 includes a bottom side 42 and at least one upward side 44 extending from the bottom side 42. An upper portion 46 of the at least one upward side 44 defines an upper connection surface 48, wherein the bottom side 42 and the at least one upward side 44 at least partially define a second insulated interior 50. An intermediate insulation structure 60 includes top and bottom surfaces 62, 64. The top surface 62 is configured to engage the lower connection surface 28 of the first vacuum insulated structure 20 to further define the first insulated interior 30. The bottom surface 64 of the intermediate insulation structure 60 is configured to engage the upper connection surface 48 of the second vacuum insulated structure 40 to further define the second insulated interior 50. The intermediate insulation structure 60 includes an appliance utility path 66 within which at least one utility system 68 for the appliance 14 is disposed. The appliance utility path 66 is configured to be in communication with the first and second insulated interiors 30, 50.


Referring again to FIGS. 2-5, the first and second vacuum insulated structures 20, 40 can be formed from an insulation material 80 disposed within a barrier film 82 and evacuated to create an at least partial, or more typically, substantially complete or complete vacuum within the barrier film 82. The outer surface 84 of the first and second vacuum insulated structures 20, 40 are hermetically sealed such that the at least partial vacuum or greater vacuum level defined within the interior 86 of the first and second vacuum insulated structures 20, 40 can be maintained throughout manufacture, assembly and use of the appliance 14. It is contemplated that the first and second vacuum insulated structures 20, 40 are manufactured such that the components of the first and second vacuum insulated structures 20, 40 are free or substantially free of apertures, openings, perforations, or other punctures defined through any of the surfaces of the first and second vacuum insulated structures 20, 40. Accordingly, the top and downward sides 22, 24 of the first vacuum insulated structure 20 and the connecting joints 88 therebetween and the bottom and upward sides 42, 44 of the second vacuum insulated structure 40 and connecting joints 88 therebetween form a continuous surface 90 that, as discussed above, is free of punctures, openings, apertures, and other discontinuities defined within the first and second vacuum insulated structures 20, 40.


According to the various alternate aspects of the disclosure, the at least one downward side 24 can include one or more downward sides 24, and typically, three sides. Similarly, the at least one upward side 44 can include one or more upward sides 44, and typically, three upward sides 44. Additional upward and/or downward sides 44, 24 may be included to provide for various utility systems 68 of the appliance 14.


Referring again to FIGS. 2-4, the intermediate insulation structure 60 can be formed from a conventional rigid foam insulation that is free of any outer wrapper 18 or other container. Accordingly, in various alternate aspects of the disclosure, it is contemplated that the lower connection surface 28 of the first vacuum insulated structure 20 and the upper connection surface 48 of the second vacuum insulated structure 40 directly engage the top and bottom surfaces 62, 64, respectively, of the intermediate insulation structure 60.


According to the various alternate aspects of the disclosure, the engagement between the intermediate insulating structure 60 and the first and second vacuum insulated structures 20, 40 can be a surface-to-surface engagement that is substantially free or free of fasteners, adhesives, welding or other connecting method. It is also contemplated that the lower connection surface 28 of the first vacuum-insulated structure 20 and/or the upper connection surface 48 of the second vacuum insulated structure 40 with the top and bottom surfaces 62, 64, respectively, of the intermediate insulating structure 60 can optionally include adhesives, fasteners, mechanical fastening mechanisms, interference mechanisms or other connecting methods beyond a surface-to-surface connection.


According to various alternate aspects of the disclosure, as exemplified in FIG. 5, the intermediate insulation structure 60 can include an intermediate cover member 100 that defines an internal mullion volume 102. In such an aspect of the disclosure, it is contemplated that an insulating material is disposed within the internal mullion volume 102. As will be described more fully below, the appliance utility path 66 is disposed within the intermediate insulation structure 60 such that the various utility systems 68 of the appliance 14 can be run through portions of the intermediate insulation structure 60. In this manner, the internal mullion volume 102 of the intermediate insulation structure 60 is made to be free or substantially free of any vacuum and is not, typically, hermetically sealed. Accordingly, the appliance utility path 66 defined within the intermediate insulation structure 60 provides a path through which the various utility systems 68 can be delivered to the first and second insulated interiors 30, 50 without having to pass through either the first and/or second vacuum insulated structures 20, 40. Therefore, the first and second vacuum insulated structures 20, 40 can be maintained in a continuous or substantially continuous configuration and free of internal openings, holes, or other punctures. In this manner, the first and second vacuum insulated structures 20, 40 are free, or substantially free, of direct engagement with the appliance utility path 66.


According to the various alternate aspects of the disclosure, manufacturing the first and second vacuum insulated structures 20, 40 to be free of openings, apertures, or other punctures can serve to simplify the process of making the first and second vacuum insulated structures 20, 40. Additionally, because the first and second vacuum insulated structures 20, 40 are made to be substantially free or free of discontinuous surfaces, the occurrence of imperfections in the hermetic seal of the barrier film 82 can be lessened, as fewer corners, edges, and interconnections are included within the first and second vacuum insulated structures 20, 40. It is also contemplated that the absence of openings, apertures, or other punctures within the first and second vacuum insulated structures 20, 40 can serve to increase the insulating performance of the first and second vacuum insulated structures 20, 40, thereby increasing the energy efficiency of the first and second insulated interiors 30, 50 in the appliance 14 as a whole.


According to various alternate aspects of the disclosure, the intermediate insulation structure 60 can include a non-vacuum insulated member through which the appliance utility path 66 can be run. It is also contemplated that at least a portion of the intermediate insulation structure 60 can be made from a vacuum insulated member to form an intermediate insulating structure 60 made from a plurality of components to form a composite structure. In such an aspect of the disclosure, the appliance utility path 66 can be run through a portion of the intermediate insulation structure 60 that is not placed under a vacuum. Such a composite construction can serve to minimize the amount of the split hybrid insulation structure 10 that is not placed under an at least partial or greater vacuum, while also minimizing the occurrence of apertures, openings, and other punctures within the various vacuum insulated structures of the split hybrid insulation structure 10.


Referring again to FIGS. 2-4, the upward sides 44 of the second vacuum insulated structure 40 can include a lower back wall 110 that extends upward from the bottom side 42 of the second vacuum insulated structure 40. It is contemplated that the lower back wall 110 can be set forward a predetermined distance relative to an upper back wall 112 of the first vacuum insulated structure 20. In such an aspect of the disclosure, a rear portion 114 of the intermediate insulation structure 60 extends rearward of the lower back wall 110 to define an interstitial space 116 defined between the lower back wall 110 and an outer wrapper 18 of the appliance 14. At least a portion of the appliance utility path 66 can be positioned within the rear portion 114 of the intermediate insulation structure 60 such that the appliance utility path 66 is in communication with the interstitial space 116. It is contemplated that at least a portion of the interstitial space 116 can include a machine compartment 118 for housing various mechanical features of the refrigerating appliance 14. Such mechanical features can include, but are not limited to, compressors, condensors, expansion devices, electrical features, water delivery systems, air handling units, and other similar mechanical fixtures. Accordingly, the various utility systems 68 of the appliance 14 can include at least one of an electrical system, a data system, a wireless communication system, a refrigeration system, a water or other liquid(s) system, an air handling system and other similar systems. It is contemplated that the interstitial space 116 defined between the lower back wall 110 and the outer wrapper 18 of the appliance 14 can extend downward from a portion of the bottom surface 64 of the intermediate insulation structure 60.


Referring again to FIGS. 2-4, the downward sides 24 of the first vacuum insulated structure 20 can include an upper back wall 112 that can engage or substantially engage the outer wrapper 18 of the appliance 14, such that the interstitial space 116 does not extend above or does not substantially extend above the intermediate insulation structure 60. According to various alternate aspects of the disclosure, the interstitial space 116 can extend both above and below the intermediate insulation structure 60 such that the upper back wall 112 and the lower back wall 110 of the first and second vacuum insulated structures 20, 40, respectively, can be at least partially offset from the outer wrapper 18 to define portions of the interstitial space 116 for housing the various utility systems 68 of the appliance 14.


Referring again to FIGS. 3 and 4, it is contemplated that the appliance utility path 66 of the intermediate insulation structure 60 can include a plurality of conduits that extend through portions of the intermediate insulation structure 60. In this manner, first and second conduits 130, 132 of the plurality of conduits can be placed in communication with the first and second insulated interiors 30, 50, respectively. According to the various alternate aspects of the disclosure, it is also contemplated that the first and second conduits 130, 132 of the appliance utility path 66 can be used to house various portions of the utility systems 68 of the appliance 14. In this manner, the utility systems 68 can be delivered from the machine compartment 118 within the interstitial space 116 and through the appliance utility path 66 for delivery to positions at least proximate the first and second insulated interiors 30, 50.


Referring again to FIGS. 3 and 4, it is contemplated that the inner liner 16 of the appliance 14 can be offset from portions of the first vacuum insulated structure 20, the second vacuum insulated structure 40, and/or the intermediate insulation structure 60. In this manner, the utility spaces 140 can be defined between the inner liner 16 and portions of the split hybrid insulation structure 10 for housing other portions of the various utility systems 68 of the appliance 14. By way of example, and not limitation, one or more of the utility spaces 140 defined between the inner liner 16 and the split hybrid insulation structure 10 can be used to house one or more evaporators and air handlers for delivering cooling to one of the first and second insulated interiors 30, 50. Such utility spaces 140 can also be used to house one or more water filters, ice makers, air handling ducts, user interface controls, electrical wiring, refrigeration lines, and other support systems and fixtures of the various utility systems 68 of the appliance 14.


As exemplified in FIGS. 2-4, it is contemplated that portions of the first and second vacuum insulated structures 20, 40 proximate the interstitial space 116 and the utility spaces 140 can be at least partially protected through the use of a cover member 160 that extends over a portion of the first and/or second vacuum insulated structures 20, 40 to prevent damage to the first and second vacuum insulated structures 20, 40 that may affect the at least partial vacuum formed therein. Such a cover member 160 may be applied to prevent punctures of the barrier film 82 that might affect the insulated performance of the split hybrid insulation structure 10.


According to various alternate aspects of the disclosure, instead of the utility spaces 140 being incorporated between the inner liner 16 and portions of a split hybrid insulation structure 10, various components of utility systems 68 can be set within recesses 170 defined within or along the intermediate insulation structure 60. Accordingly, such recesses 170 can be placed in communication with the appliance utility path 66 such that components of the various utility systems 68 of the appliance 14 can be delivered to the recess 170 for operating the fixtures disposed therein. It is also contemplated that the various fixtures of the utility systems 68 of the appliance 14 that are disposed in the location of the intermediate insulation structure 60 can be positioned in a predetermined setting and the foam insulation of the intermediate insulation structure 60 can be sprayed or otherwise disposed around the various fixtures of the utility systems 68 of the appliance 14. In this manner, the intermediate insulation structure 60 with the various components of the utility systems 68 of the appliance 14 can be pre-made for installation within the split hybrid insulation structure 10 for manufacture within the desired appliance 14.


According to the various alternate aspects of the disclosure, a split hybrid insulation structure 10 can be used for various appliances 14 that can include, but are not limited to, refrigerators, coolers, freezers, warmers, ovens, cleaning appliances, electrical equipment, and other similar appliances 14. It is also contemplated that an appliance 14 incorporating an aspect of the split hybrid insulation structure 10 may have only a first insulated interior 30. It is also contemplated that such an appliance 14 may have more than first and second insulated interiors 30, 50.


Referring now to FIGS. 6 and 7, an appliance 14 incorporating an aspect of the split hybrid insulation structure 10 can include a first vacuum insulated structure 20 having a plurality of continuous sides 180 that define an open front 182, an open end 184, and an engagement surface 186 proximate the open end 184. The continuous sides 180 of the first vacuum insulated structure 20 can at least partially define a first insulated interior 30. As discussed above, the plurality of continuous sides 180 of the first vacuum insulated structure 20 are configured to be free of internal apertures, or other punctures or openings, through the first vacuum insulated structure 20. The intermediate insulation structure 60 can include first and second surfaces that may correspond to the top and bottom surfaces 62, 64. One of the first and second surfaces is configured to receive the engagement surface 186 of the vacuum insulated structure to further define the first insulated interior 30. The intermediate insulation structure 60 can include the appliance utility path 66 within which at least one of the utility systems 68 for the appliance 14 can be disposed. The appliance utility path 66 is configured to be in communication with the first insulated interior 30 such that the utility systems 68 are delivered through the intermediate insulation structure 60 and not through the first vacuum insulated structure 20.


Referring again to FIGS. 6 and 7, it is contemplated that the split hybrid insulation structure 10 can include a second vacuum insulated structure 40 having a second plurality of continuous sides 190 that define a second open front 192 and a second open end 194 and a second engagement surface 196. The second plurality of continuous sides 190 of the second vacuum insulated structure 40 can be free of internal apertures, openings, and other punctures extending through the second vacuum insulated structure 40. The second engagement surface 196 of the second vacuum insulated structure 40 is configured to engage the other of the first and second surfaces of the intermediate insulation structure 60 to define a second insulated interior 50. As noted above, the first and second surfaces can correspond to the top and bottom surfaces 62, 64. As with the first insulated interior 30, the appliance utility path 66 is placed in communication with the second insulated interior 50.


It is also contemplated that a third vacuum insulated structure 210 having a third plurality of continuous sides 212, a third open front 214, at least one third open end 216 and at least one third engagement surface 218 can be disposed within the appliance 14. The first, second and third vacuum insulated structures 20, 40, 210 can define any one or more of a refrigerating compartment 220, freezing compartment 222 and a pantry compartment 224 within a refrigerating appliance. In such an aspect of the disclosure, a second intermediate insulation structure 226 can be disposed between the third vacuum insulated structure 210 and one of the first and second vacuum insulated structures 20, 40 to define a third insulated interior 208 that can define a pantry compartment 224 of the refrigerating appliance. It is also contemplated that each of the intermediate insulation structure 60 and the second intermediate insulation structure 226 can include a portion of the appliance utility path 66 for delivering various portions of the utility systems 68 of the appliance 14 to the first, second and third insulated interiors 30, 50, 208. In this manner, the first, second and third vacuum insulated structures 20, 40, 210 of the split hybrid insulation structure 10 can remain undisturbed or substantially undisturbed while the utility systems 68 of the appliance 14 are delivered through the intermediate insulation structure 60 and the second intermediate insulation structure 226.


It is contemplated that an area behind the third vacuum insulated structure 210 can also include a portion of the interstitial space 116 for housing at least a portion of utility systems 68 of the appliance 14, which can also provide for delivery of resources by the various utility systems 68 of the appliance 14 to the first, second and third insulated interiors 30, 50, 208. In this manner, a portion of the intermediate insulation structure 60 and/or the second intermediate insulation structure 226 can include an interstitial portion 240 that can define a boundary of the interstitial space 116. In such an aspect of the disclosure, the appliance utility path 66 can be in communication with the interstitial space 116 through the interstitial portion 240 of the intermediate insulation structure 60 and/or the second intermediate insulation structure 226.


According to the various alternate aspects of the disclosure, where the split hybrid insulation structure 10 is used within a refrigerating appliance, the refrigerating appliance can take the form of any one of several refrigerator configurations. Such configurations can include, but are not limited to, French door bottom mount, side-by-side, coffin, single cavity refrigerator, single cavity freezer, and other various multi-compartment configurations that can incorporate one or both of heating and cooling functions.


Referring now to FIG. 5, the intermediate insulation structure 60 of the split hybrid insulation structure 10 can include various configurations of the appliance utility path 66. The appliance utility path 66 can be one or more conduits that extend through the material of the intermediate insulation structure 60. It is also contemplated that the appliance utility path 66 can incorporate a cutout 250 from a portion of the intermediate insulation structure 60. Where a cutout 250 is implemented, various foam insulation material 80 can be used to fill in portions of the insulation cavity 12 defined between the outer wrapper 18 and the inner liner 16 to increase the insulating performance of the split hybrid insulation structure 10.


Referring now to FIGS. 1-4 and 8, having described the split hybrid insulation structure 10, a method is disclosed for forming a split hybrid insulation structure 10 for an appliance 14. This method 400 can include the step of disposing at least one utility system 68 within an appliance utility path 66 of the intermediate insulation structure 60 (step 402). By placing components of the utility systems 68 of the appliance 14 within the appliance utility path 66, before installing the first, second and/or third vacuum insulated structures 20, 40, 210, damage to the first, second and/or third vacuum insulated structures 20, 40, 210 may be minimized through the process of locating the positions of the components of the utility systems 68 prior to adding the vacuum insulated structures. The method can also include engaging the lower connection surface 28 of the first vacuum insulated structure 20 with the top surface 62 of the intermediate insulation structure 60 to define the first insulated interior 30 (step 404). In this manner, the first insulated interior 30 can be placed in communication with the appliance utility path 66 and one or more of the utility systems 68 of the appliance 14. The upper connection surface 48 of the second vacuum insulated structure 40, according to the method 400, is also moved into engagement with the bottom surface 64 of the intermediate insulation structure 60 to define the second insulated interior 50 (step 406). As with the first insulated interior 30, the second insulated interior 50 is placed in communication with the appliance utility path 66 and at least one of the utility systems 68 of the appliance 14. It is contemplated that the engagement of the first and second vacuum insulated structures 20, 40 with the intermediate insulation structure 60 forms or substantially forms the split hybrid insulation structure 10.


According to various alternate aspects of the disclosure, it is contemplated that the one or more utility systems 68 of the appliance 14 can be installed through the intermediate insulation structure 60 after the first and second vacuum insulated structures 20, 40 are engaged with the intermediate insulation structure 60. The installation of the components of the utility systems 68 can be installed after formation of the split hybrid insulation structure 10 so long as substantial damage to the first and/or second vacuum insulated structures 20, 40 that may damage the vacuum formed therein or negatively affect the insulating performance of the structures can be avoided.


Referring again to FIGS. 1-4 and 8, the method 400 also includes providing an outer wrapper 18 and an inner liner 16 for the appliance 14 (step 408). It is contemplated that the split hybrid insulation structure 10 can be disposed between the inner liner 16 and the outer wrapper 18 (step 410). The method 400 also includes the step of connecting the inner liner 16 to the outer wrapper 18 to form the insulating cavity therebetween (step 412). In this manner, the split hybrid insulation structure 10 is disposed within the insulation cavity 12 and an interstitial space 116 can be defined between the first and/or second vacuum insulated structures 20, 40 in the outer wrapper 18. As discussed above, the interstitial space 116 can at least partially define the machine compartment 118 of the appliance 14.

Claims
  • 1. A method for forming a split hybrid insulation structure for an appliance, the method including: engaging a first engagement surface of a first vacuum insulated structure with one of first and second surfaces of an intermediate insulation structure to define a first insulated interior, wherein the first vacuum insulated structure includes a plurality of continuous sides that are free of internal apertures therethrough;disposing at least one utility within an interstitial space at least partially defined by an outer surface of the first vacuum insulated structure, wherein the first vacuum insulated structure separates the first insulated interior from the interstitial space;connecting the at least one utility to the first insulated interior via an appliance utility path that extends through the intermediate insulation structure and traverses around the first engagement surface of the first vacuum insulated structure, wherein a rear portion of the intermediate insulation structure includes an interstitial portion, wherein one of the first and second surfaces within the interstitial portion defines a boundary of the interstitial space, and wherein the appliance utility path communicates with the interstitial space through the interstitial portion of the intermediate insulation structure; anddisposing the at least one utility within the appliance utility path of the intermediate insulation structure.
  • 2. The method of claim 1, further including a step of: engaging a second vacuum insulated structure having a second plurality of continuous sides that are free of internal apertures therethrough, wherein a second engagement surface of the second vacuum insulated structure engages the other of the first and second surfaces of the intermediate insulation structure to define a second insulated interior, and wherein the appliance utility path places the interstitial space in communication with the second insulated interior via the intermediate insulation structure.
  • 3. The method of claim 2, wherein the appliance utility path extends through the intermediate insulation structure and traverses around the second engagement surface of the second vacuum insulated structure.
  • 4. The method of claim 2, wherein the appliance utility path includes a plurality of conduits that extends through portions of the intermediate insulation structure, wherein first and second conduits of the plurality of conduits are in communication with the first and second insulated interiors, respectively.
  • 5. The method of claim 1, further including steps of: disposing the first vacuum insulated structure and the intermediate insulation structure having the appliance utility path between an inner liner and an outer wrapper; andconnecting the inner liner to the outer wrapper to form an insulating cavity therebetween, wherein the first vacuum insulated structure and the intermediate insulation structure are disposed within the insulating cavity, and wherein the interstitial space is defined between the first vacuum insulated structure and the outer wrapper.
  • 6. The method of claim 5, wherein the interstitial space at least partially defines a machine compartment.
  • 7. The method of claim 6, wherein the interstitial space includes a cover member that at least partially separates the first vacuum insulated structure from the machine compartment, wherein a portion of the first vacuum insulated structure is disposed between the inner liner and the cover member.
  • 8. The method of claim 5, wherein the intermediate insulation structure is defined by a foam insulation material that directly engages the first vacuum insulated structure and the inner liner.
  • 9. The method of claim 1, wherein the appliance utility path includes at least one conduit that extends through portions of the intermediate insulation structure, wherein the at least one conduit is in communication with the first insulated interior, and wherein the first vacuum insulated structure is free of direct engagement with the appliance utility path.
  • 10. The method of claim 1, wherein the intermediate insulation structure includes an internal mullion volume and an insulating material disposed within the internal mullion volume, and wherein the internal mullion volume is free of a vacuum.
  • 11. The method of claim 10, wherein the insulating material is a foamed-in insulation, and wherein at least one of an ice maker and a water filter are disposed within the internal mullion volume and are at least partially surrounded by the foamed-in insulation.
  • 12. A method for forming a split hybrid insulation structure for an appliance, the method including: disposing an engagement surface of a vacuum insulated structure in direct engagement with an intermediate insulation structure to cooperatively define an insulated interior and separate an interstitial space from the insulated interior, wherein the vacuum insulated structure includes a plurality of continuous sides that are free of internal apertures therethrough;disposing at least one utility conduit within the intermediate insulation structure and extending from the interstitial space to the insulated interior via an appliance utility path that extends from the interstitial space through the intermediate insulation structure and traverses around the engagement surface of the vacuum insulated structures;disposing at least one utility within the interstitial space that is at least partially defined by an outer surface of the vacuum insulated structure, wherein the vacuum insulated structure separates the insulated interior from the interstitial space;connecting the at least one utility to the insulated interior via the at least one utility conduit;disposing the at least one utility within the at least one utility conduit of the intermediate insulation structure; anddisposing the vacuum insulated structure and the intermediate insulation structure having the at least one utility conduit between an inner liner and an outer wrapper; andconnecting the inner liner to the outer wrapper to form an insulating cavity therebetween, wherein the vacuum insulated structure and the intermediate insulation structure are disposed within the insulating cavity, and wherein the interstitial space is defined between the vacuum insulated structure and the outer wrapper.
  • 13. The method of claim 12, wherein the interstitial space at least partially defines a machine compartment.
  • 14. The method of claim 13, wherein the interstitial space includes a cover member that at least partially separates the vacuum insulated structure from the machine compartment, wherein a portion of the vacuum insulated structure is disposed between the inner liner and the cover member.
  • 15. The method of claim 12, wherein the intermediate insulation structure is defined by a foam insulation material that directly engages the vacuum insulated structure and the inner liner.
  • 16. A method for forming a split hybrid insulation structure for an appliance, the method including: disposing an engagement surface of a vacuum insulated structure in direct engagement with an intermediate insulation structure to cooperatively define an insulated interior and separate an interstitial space from the insulated interior, wherein the vacuum insulated structure includes a plurality of continuous sides that are free of internal apertures therethrough;disposing a utility conduit within the intermediate insulation structure, the utility conduit extending from the interstitial space to the insulated interior via an appliance utility path that extends from the interstitial space through the intermediate insulation structure and traverses around the engagement surface of the vacuum insulated structure, wherein the interstitial space is partially defined by a cover member that at least partially separates the vacuum insulated structure from the interstitial space;disposing the vacuum insulated structure and the intermediate insulation structure having the utility conduit between an inner liner and an outer wrapper; andconnecting the inner liner to the outer wrapper to form an insulating cavity therebetween, wherein the vacuum insulated structure and the intermediate insulation structure are disposed within the insulating cavity, and wherein the interstitial space is defined between the vacuum insulated structure and the outer wrapper.
CROSS-REFERENCE TO RELATED APPLICATIONS

The present application is a divisional of U.S. patent application Ser. No. 15/254,519 filed Sep. 1, 2016, entitled SPLIT HYBRID INSULATION STRUCTURE FOR AN APPLIANCE, which is a continuation of U.S. patent application Ser. No. 14/789,303 filed Jul. 1, 2015, entitled SPLIT HYBRID INSULATION STRUCTURE FOR AN APPLIANCE, now U.S. Pat. No. 9,441,779, the entire disclosures of which are hereby incorporated herein by reference. The device is in the field of insulation structures for appliances, more specifically, a multi-component hybrid insulation structure incorporating multiple insulation structures.

US Referenced Citations (449)
Number Name Date Kind
948541 Coleman Feb 1910 A
1275511 Welch Aug 1918 A
1849369 Frost Mar 1932 A
1921576 Muffly Aug 1933 A
2108212 Schellens Feb 1938 A
2128336 Torstensson Aug 1938 A
2164143 Munters Jun 1939 A
2191659 Hintze Feb 1940 A
2318744 Brown May 1943 A
2356827 Coss Aug 1944 A
2432042 Richard Dec 1947 A
2439602 Heritage Apr 1948 A
2439603 Heritage Apr 1948 A
2451884 Stelzer Oct 1948 A
2538780 Hazard Jan 1951 A
2559356 Hedges Jul 1951 A
2729863 Kurtz Jan 1956 A
2768046 Evans Oct 1956 A
2817123 Jacobs Dec 1957 A
2942438 Schmeling Jun 1960 A
2985075 Knutsson-Hall May 1961 A
3086830 Malia Apr 1963 A
3125388 Costantini et al. Mar 1964 A
3137900 Carbary Jun 1964 A
3218111 Steiner Nov 1965 A
3258883 Louis et al. Jul 1966 A
3290893 Haldopoulos Dec 1966 A
3338451 Kesling Aug 1967 A
3353301 Heilweil et al. Nov 1967 A
3353321 Heilweil et al. Nov 1967 A
3358059 Snyder Dec 1967 A
3379481 Fisher Apr 1968 A
3408316 Mueller et al. Oct 1968 A
3471416 Fijal Oct 1969 A
3597850 Jenkins Aug 1971 A
3607169 Coxe Sep 1971 A
3632012 Kitson Jan 1972 A
3633783 Aue Jan 1972 A
3634971 Kesling Jan 1972 A
3635536 Lackey et al. Jan 1972 A
3670521 Dodge, III et al. Jun 1972 A
3688384 Mizushima et al. Sep 1972 A
3769770 Deschamps et al. Nov 1973 A
3862880 Feldman Jan 1975 A
3868829 Mann et al. Mar 1975 A
3875683 Waters Apr 1975 A
3910658 Lindenschmidt Oct 1975 A
3933398 Haag Jan 1976 A
3935787 Fisher Feb 1976 A
4005919 Hoge et al. Feb 1977 A
4006947 Haag et al. Feb 1977 A
4043624 Lindenschmidt Aug 1977 A
4050145 Benford Sep 1977 A
4067628 Sherbum Jan 1978 A
4170391 Bottger Oct 1979 A
4242241 Rosen et al. Dec 1980 A
4260876 Hochheiser Apr 1981 A
4303730 Torobin Dec 1981 A
4303732 Torobin Dec 1981 A
4325734 Burrage et al. Apr 1982 A
4330310 Tate, Jr. et al. May 1982 A
4332429 Frick Jun 1982 A
4396362 Thompson et al. Aug 1983 A
4417382 Schilf Nov 1983 A
4492368 DeLeeuw et al. Jan 1985 A
4529368 Makansi Jul 1985 A
4548196 Torobin Oct 1985 A
4583796 Nakajima et al. Apr 1986 A
4660271 Lenhardt Apr 1987 A
4671909 Torobin Jun 1987 A
4671985 Rodrigues et al. Jun 1987 A
4681788 Barito et al. Jul 1987 A
4745015 Cheng et al. May 1988 A
4777154 Torobin Oct 1988 A
4781968 Kellerman Nov 1988 A
4805293 Buchser Feb 1989 A
4865875 Kellerman Sep 1989 A
4870735 Jahr et al. Oct 1989 A
4914341 Weaver et al. Apr 1990 A
4917841 Jenkins Apr 1990 A
5007226 Nelson Apr 1991 A
5018328 Cur et al. May 1991 A
5033636 Jenkins Jul 1991 A
5066437 Barito et al. Nov 1991 A
5082335 Cur et al. Jan 1992 A
5084320 Barito et al. Jan 1992 A
5094899 Rusek, Jr. Mar 1992 A
5118174 Benford et al. Jun 1992 A
5121593 Forslund Jun 1992 A
5157893 Benson et al. Oct 1992 A
5168674 Molthen Dec 1992 A
5171346 Hallett Dec 1992 A
5175975 Benson et al. Jan 1993 A
5212143 Torobin May 1993 A
5221136 Hauck et al. Jun 1993 A
5227245 Brands et al. Jul 1993 A
5231811 Andrepont et al. Aug 1993 A
5248196 Lynn et al. Sep 1993 A
5251455 Cur et al. Oct 1993 A
5252408 Bridges et al. Oct 1993 A
5263773 Gable et al. Nov 1993 A
5273801 Barry et al. Dec 1993 A
5318108 Benson et al. Jun 1994 A
5340208 Hauck et al. Aug 1994 A
5353868 Abbott Oct 1994 A
5359795 Mawby et al. Nov 1994 A
5375428 LeClear et al. Dec 1994 A
5397759 Torobin Mar 1995 A
5418055 Chen et al. May 1995 A
5433056 Benson et al. Jul 1995 A
5477676 Benson et al. Dec 1995 A
5500287 Henderson Mar 1996 A
5500305 Bridges et al. Mar 1996 A
5505810 Kirby et al. Apr 1996 A
5507999 Cospey et al. Apr 1996 A
5509248 Dellby et al. Apr 1996 A
5512345 Tsutsumi et al. Apr 1996 A
5532034 Kirby et al. Jul 1996 A
5533311 Tirrell et al. Jul 1996 A
5562154 Benson et al. Oct 1996 A
5586680 Dellby et al. Dec 1996 A
5599081 Revlett et al. Feb 1997 A
5600966 Valence et al. Feb 1997 A
5632543 McGrath et al. May 1997 A
5640828 Reeves et al. Jun 1997 A
5643485 Potter et al. Jul 1997 A
5652039 Tremain et al. Jul 1997 A
5716581 Tirrell Feb 1998 A
5768837 Sjoholm Jun 1998 A
5792801 Tsuda et al. Aug 1998 A
5813454 Potter Sep 1998 A
5826780 Nesser et al. Oct 1998 A
5827385 Meyer et al. Oct 1998 A
5834126 Sheu Nov 1998 A
5843353 De Vos et al. Dec 1998 A
5866228 Awata Feb 1999 A
5866247 Klatt et al. Feb 1999 A
5868890 Fredrick Feb 1999 A
5900299 Wynne May 1999 A
5918478 Bostic et al. Jul 1999 A
5924295 Park Jul 1999 A
5950395 Takemasa et al. Sep 1999 A
5952404 Simpson et al. Sep 1999 A
5966963 Kovalaske Oct 1999 A
5985189 Lynn et al. Nov 1999 A
6013700 Asano et al. Jan 2000 A
6063471 Dietrich et al. May 2000 A
6094922 Ziegler Aug 2000 A
6109712 Haworth et al. Aug 2000 A
6128914 Tamaoki et al. Oct 2000 A
6132837 Boes et al. Oct 2000 A
6158233 Cohen et al. Dec 2000 A
6163976 Tada et al. Dec 2000 A
6164030 Dietrich Dec 2000 A
6164739 Schultz et al. Dec 2000 A
6187256 Aslan et al. Feb 2001 B1
6209342 Banicevic et al. Apr 2001 B1
6210625 Matsushita et al. Apr 2001 B1
6220473 Lehman et al. Apr 2001 B1
6221456 Pogorski et al. Apr 2001 B1
6224179 Wenning May 2001 B1
6244458 Frysinger et al. Jun 2001 B1
6260377 Tamaoki et al. Jul 2001 B1
6266970 Nam et al. Jul 2001 B1
6294595 Tyagi et al. Sep 2001 B1
6305768 Nishimoto Oct 2001 B1
6485122 Wolf et al. Jan 2002 B2
6390378 Briscoe, Jr. et al. May 2002 B1
6406449 Moore et al. Jun 2002 B1
6408841 Hirath et al. Jun 2002 B1
6415623 Jennings et al. Jul 2002 B1
6428130 Banicevic et al. Aug 2002 B1
6430780 Kim et al. Aug 2002 B1
6460955 Vaughan et al. Oct 2002 B1
6519919 Takenouchi et al. Feb 2003 B1
6623413 Wynne Sep 2003 B1
6629429 Kawamura et al. Oct 2003 B1
6655766 Hodges Dec 2003 B2
6689840 Eustace et al. Feb 2004 B1
6716501 Kovalchuk et al. Apr 2004 B2
6736472 Banicevic May 2004 B2
6749780 Tobias Jun 2004 B2
6773082 Lee Aug 2004 B2
6858280 Allen et al. Feb 2005 B2
6860082 Yamamoto et al. Mar 2005 B1
6938968 Tanimoto et al. Sep 2005 B2
7008032 Chekal et al. Mar 2006 B2
7026054 Ikegawa et al. Apr 2006 B2
7197792 Moon Apr 2007 B2
7197888 LeClear et al. Apr 2007 B2
7207181 Murray et al. Apr 2007 B2
7210308 Tanimoto et al. May 2007 B2
7234247 Maguire Jun 2007 B2
7263744 Kim et al. Sep 2007 B2
7284390 Van Meter et al. Oct 2007 B2
7296423 Müller et al. Nov 2007 B2
7316125 Uekado Jan 2008 B2
7343757 Egan et al. Mar 2008 B2
7360371 Feinauer et al. Apr 2008 B2
7449227 Echigoya et al. Nov 2008 B2
7475562 Jackovin Jan 2009 B2
7517031 Laible Apr 2009 B2
7614244 Venkatakrishnan et al. Nov 2009 B2
7625622 Teckoe et al. Dec 2009 B2
7641298 Hirath et al. Jan 2010 B2
7665326 LeClear et al. Feb 2010 B2
7703217 Tada et al. Apr 2010 B2
7703824 Kittelson et al. Apr 2010 B2
7757511 LeClear et al. Jul 2010 B2
7762634 Tenra et al. Jul 2010 B2
7794805 Aumaugher et al. Sep 2010 B2
7815269 Wenning et al. Oct 2010 B2
7842269 Schachtely et al. Nov 2010 B2
7845745 Gorz et al. Dec 2010 B2
7861538 Welle et al. Jan 2011 B2
7886559 Hell Feb 2011 B2
7893123 Luisi Feb 2011 B2
7908873 Cur et al. Mar 2011 B1
7930892 Vonderhaar Apr 2011 B1
7938148 Carlier et al. May 2011 B2
7992257 Kim Aug 2011 B2
8049518 Wern et al. Nov 2011 B2
8074469 Hamel et al. Dec 2011 B2
8079652 Laible et al. Dec 2011 B2
8108972 Bae et al. Feb 2012 B2
8113604 Olson et al. Feb 2012 B2
8117865 Allard et al. Feb 2012 B2
8157338 Seo et al. Apr 2012 B2
8162415 Hagele et al. Apr 2012 B2
8163080 Meyer et al. Apr 2012 B2
8176746 Allard et al. May 2012 B2
8182051 Laible et al. May 2012 B2
8197019 Kim Jun 2012 B2
8202599 Henn Jun 2012 B2
8211523 Fujimori et al. Jul 2012 B2
8266923 Bauer et al. Sep 2012 B2
8281558 Hiemeyer et al. Oct 2012 B2
8299656 Allard et al. Oct 2012 B2
8343395 Hu et al. Jan 2013 B2
8353177 Adamski et al. Jan 2013 B2
8382219 Hottmann et al. Feb 2013 B2
8434317 Besore May 2013 B2
8439460 Laible et al. May 2013 B2
8456040 Allard et al. Jun 2013 B2
8491070 Davis et al. Jul 2013 B2
8516845 Wuesthoff et al. Aug 2013 B2
8528284 Aspenson et al. Sep 2013 B2
8590992 Lim et al. Nov 2013 B2
8717029 Chae et al. May 2014 B2
8739568 Allard et al. Jun 2014 B2
8752918 Kang Jun 2014 B2
8752921 Gorz et al. Jun 2014 B2
8763847 Mortarotti Jul 2014 B2
8764133 Park et al. Jul 2014 B2
8770682 Lee et al. Jul 2014 B2
8776390 Hanaoka et al. Jul 2014 B2
8840204 Bauer et al. Sep 2014 B2
8852708 Kim et al. Oct 2014 B2
8881398 Hanley et al. Nov 2014 B2
8905503 Sahasrabudhe et al. Dec 2014 B2
8943770 Sanders et al. Feb 2015 B2
8944541 Allard et al. Feb 2015 B2
9009969 Choi et al. Apr 2015 B2
RE45501 Maguire May 2015 E
9056952 Eilbracht et al. Jun 2015 B2
9074811 Korkmaz Jul 2015 B2
9080808 Choi et al. Jul 2015 B2
9102076 Doshi et al. Aug 2015 B2
9103482 Fujimori et al. Aug 2015 B2
9125546 Kleemann et al. Sep 2015 B2
9140480 Kuehl et al. Sep 2015 B2
9140481 Cur et al. Sep 2015 B2
9170045 Oh et al. Oct 2015 B2
9170046 Jung et al. Oct 2015 B2
9188382 Kim et al. Nov 2015 B2
8955352 Lee et al. Dec 2015 B2
9221210 Wu et al. Dec 2015 B2
9228386 Thielmann et al. Jan 2016 B2
9267727 Lim et al. Feb 2016 B2
9303915 Kim et al. Apr 2016 B2
9328951 Shin et al. May 2016 B2
9353984 Kim et al. May 2016 B2
9410732 Choi et al. Aug 2016 B2
9423171 Betto et al. Aug 2016 B2
9429356 Kim et al. Aug 2016 B2
9441779 Alshourbagy Sep 2016 B1
9448004 Kim et al. Sep 2016 B2
9463917 Wu et al. Oct 2016 B2
9482463 Choi et al. Nov 2016 B2
9506689 Carbajal et al. Nov 2016 B2
9518777 Lee et al. Dec 2016 B2
9568238 Kim et al. Feb 2017 B2
D781641 Incukur Mar 2017 S
D781642 Incukur Mar 2017 S
9605891 Lee et al. Mar 2017 B2
9696085 Seo et al. Jul 2017 B2
9702621 Cho et al. Jul 2017 B2
9759479 Ramm et al. Sep 2017 B2
9777958 Choi et al. Oct 2017 B2
9791204 Kim et al. Oct 2017 B2
9833942 Wu et al. Dec 2017 B2
10088220 Alshourbagy Oct 2018 B2
20020004111 Matsubara et al. Jan 2002 A1
20020114937 Albert et al. Aug 2002 A1
20020144482 Henson et al. Oct 2002 A1
20020168496 Morimoto et al. Nov 2002 A1
20030008100 Horn Jan 2003 A1
20030041612 Piloni et al. Mar 2003 A1
20030056334 Finkelstein Mar 2003 A1
20030157284 Tanimoto et al. Aug 2003 A1
20030167789 Tanimoto et al. Sep 2003 A1
20030173883 Koons Sep 2003 A1
20040144130 Jung Jul 2004 A1
20040178707 Avendano et al. Sep 2004 A1
20040180176 Rusek Sep 2004 A1
20040226141 Yates et al. Nov 2004 A1
20040253406 Hayashi et al. Dec 2004 A1
20050042247 Gomoll et al. Feb 2005 A1
20050229614 Ansted Oct 2005 A1
20050235682 Hirai et al. Oct 2005 A1
20060064846 Espendola et al. Mar 2006 A1
20060076863 Echigoya et al. Apr 2006 A1
20060201189 Adamski et al. Sep 2006 A1
20060261718 Miseki et al. Nov 2006 A1
20060263571 Tsunetsugu et al. Nov 2006 A1
20060266075 Itsuki et al. Nov 2006 A1
20070001563 Park et al. Jan 2007 A1
20070099502 Ferinauer et al. May 2007 A1
20070176526 Gomoll et al. Aug 2007 A1
20070266654 Noale Nov 2007 A1
20080044488 Zimmer et al. Feb 2008 A1
20080048540 Kim Feb 2008 A1
20080138458 Ozasa et al. Jun 2008 A1
20080196441 Ferreira et al. Aug 2008 A1
20080300356 Meyer et al. Dec 2008 A1
20080309210 Luisi et al. Dec 2008 A1
20090032541 Rogala et al. Feb 2009 A1
20090056367 Nuemann Mar 2009 A1
20090058244 Cho et al. Mar 2009 A1
20090113925 Korkmaz May 2009 A1
20090131571 Fraser et al. May 2009 A1
20090179541 Smith et al. Jul 2009 A1
20090205357 Lim et al. Aug 2009 A1
20090302728 Rotter et al. Dec 2009 A1
20090322470 Yoo et al. Dec 2009 A1
20090324871 Henn Dec 2009 A1
20100170279 Aoki Jul 2010 A1
20100206464 Heo et al. Aug 2010 A1
20100218543 Ducharme Sep 2010 A1
20100231109 Matzke et al. Sep 2010 A1
20100287843 Oh Nov 2010 A1
20100287974 Cur et al. Nov 2010 A1
20100293984 Adamski et al. Nov 2010 A1
20100295435 Kendall et al. Nov 2010 A1
20110011119 Kuehl et al. Jan 2011 A1
20110023527 Kwon et al. Feb 2011 A1
20110030894 Tenra et al. Feb 2011 A1
20110095669 Moon et al. Apr 2011 A1
20110146325 Lee Jun 2011 A1
20110146335 Jung et al. Jun 2011 A1
20110165367 Kojima et al. Jul 2011 A1
20110215694 Fink et al. Sep 2011 A1
20110220662 Kim et al. Sep 2011 A1
20110241513 Nomura et al. Oct 2011 A1
20110241514 Nomura et al. Oct 2011 A1
20110260351 Corradi et al. Oct 2011 A1
20110290808 Bai et al. Dec 2011 A1
20110309732 Horil et al. Dec 2011 A1
20110315693 Cur et al. Dec 2011 A1
20120000234 Adamski et al. Jan 2012 A1
20120011879 Gu Jan 2012 A1
20120060544 Lee et al. Mar 2012 A1
20120099255 Lee et al. Apr 2012 A1
20120103006 Jung et al. May 2012 A1
20120104923 Jung et al. May 2012 A1
20120118002 Kim et al. May 2012 A1
20120137501 Allard et al. Jun 2012 A1
20120152151 Meyer et al. Jun 2012 A1
20120196059 Fujimori et al. Aug 2012 A1
20120231204 Jeon et al. Sep 2012 A1
20120237715 McCraken Sep 2012 A1
20120240612 Wusthoff et al. Sep 2012 A1
20120273111 Nomura et al. Nov 2012 A1
20120279247 Katu et al. Nov 2012 A1
20120280608 Park et al. Nov 2012 A1
20120285971 Junge et al. Nov 2012 A1
20120297813 Hanley et al. Nov 2012 A1
20120324937 Adamski et al. Dec 2012 A1
20130026900 Oh et al. Jan 2013 A1
20130033163 Kang Feb 2013 A1
20130043780 Ootsuka et al. Feb 2013 A1
20130068990 Eilbracht et al. Mar 2013 A1
20130111941 Yu et al. May 2013 A1
20130221819 Wing Aug 2013 A1
20130255304 Cur et al. Oct 2013 A1
20130256318 Kuehl et al. Oct 2013 A1
20130256319 Kuehl et al. Oct 2013 A1
20130257256 Allard et al. Oct 2013 A1
20130257257 Cur et al. Oct 2013 A1
20130264439 Allard et al. Oct 2013 A1
20130270732 Wu et al. Oct 2013 A1
20130285527 Choi et al. Oct 2013 A1
20130293080 Kim et al. Nov 2013 A1
20130305535 Cur et al. Nov 2013 A1
20130328472 Shim et al. Dec 2013 A1
20140009055 Cho et al. Jan 2014 A1
20140097733 Seo et al. Apr 2014 A1
20140132144 Kim et al. May 2014 A1
20140166926 Lee et al. Jun 2014 A1
20140171578 Meyer et al. Jun 2014 A1
20140190978 Bowman et al. Jul 2014 A1
20140196305 Smith Jul 2014 A1
20140216706 Melton et al. Aug 2014 A1
20140232250 Kim et al. Aug 2014 A1
20140260332 Wu Sep 2014 A1
20140346942 Kim et al. Nov 2014 A1
20140364527 Wintermantel et al. Dec 2014 A1
20150011668 Kolb et al. Jan 2015 A1
20150015133 Carbajal et al. Jan 2015 A1
20150017386 Kolb et al. Jan 2015 A1
20150027628 Cravens et al. Jan 2015 A1
20150059399 Hwang et al. Mar 2015 A1
20150115790 Ogg Apr 2015 A1
20150147514 Shinohara et al. May 2015 A1
20150159936 Oh et al. Jun 2015 A1
20150168050 Cur et al. Jun 2015 A1
20150176888 Cur et al. Jun 2015 A1
20150184923 Jeon Jul 2015 A1
20150190840 Muto et al. Jul 2015 A1
20150224685 Amstutz Aug 2015 A1
20150241115 Strauss et al. Aug 2015 A1
20150241118 Wu Aug 2015 A1
20150285551 Aiken et al. Oct 2015 A1
20160084567 Fernandez et al. Mar 2016 A1
20160116100 Thiery et al. Apr 2016 A1
20160123055 Ueyama May 2016 A1
20160161175 Benold et al. Jun 2016 A1
20160178267 Hao et al. Jun 2016 A1
20160178269 Hiemeyer et al. Jun 2016 A1
20160235201 Soot Aug 2016 A1
20160240839 Umeyama et al. Aug 2016 A1
20160258671 Allard et al. Sep 2016 A1
20160290702 Sexton et al. Oct 2016 A1
20160348957 Hitzelberger et al. Dec 2016 A1
20170038126 Lee et al. Feb 2017 A1
20170157809 Deka et al. Jun 2017 A1
20170176086 Kang Jun 2017 A1
20170184339 Liu et al. Jun 2017 A1
20170191746 Seo Jul 2017 A1
Foreign Referenced Citations (211)
Number Date Country
626838 May 1961 CA
1320631 Jul 1993 CA
2259665 Jan 1998 CA
2640006 Aug 2007 CA
1158509 Sep 1997 CN
1970185 May 2007 CN
100359272 Jan 2008 CN
101437756 May 2009 CN
201680116 Dec 2010 CN
201748744 Feb 2011 CN
102296714 Dec 2011 CN
102452522 May 2012 CN
102717578 Oct 2012 CN
102720277 Oct 2012 CN
103072321 May 2013 CN
202973713 Jun 2013 CN
203331442 Dec 2013 CN
104816478 Aug 2015 CN
105115221 Dec 2015 CN
204963379 Jan 2016 CN
1150190 Jun 1963 DE
4110292 Oct 1992 DE
4409091 Sep 1995 DE
19818890 Nov 1999 DE
19914105 Sep 2000 DE
19915311 Oct 2000 DE
102008026528 Dec 2009 DE
102009046810 May 2011 DE
102010024951 Dec 2011 DE
102011051178 Dec 2012 DE
102012223536 Jun 2014 DE
102012223541 Jun 2014 DE
0480451 Apr 1992 EP
0645576 Mar 1995 EP
0691518 Jan 1996 EP
0260699 Mar 1998 EP
0860669 Aug 1998 EP
1087186 Mar 2001 EP
1200785 May 2002 EP
1243880 Sep 2002 EP
1484563 Dec 2004 EP
1496322 Jan 2005 EP
1505359 Feb 2005 EP
1602425 Dec 2005 EP
1624263 Aug 2006 EP
2342511 Jul 2011 EP
2543942 Jan 2013 EP
2607073 Jun 2013 EP
2789951 Oct 2014 EP
2878427 Jun 2015 EP
2980963 Apr 2013 FR
2991698 Dec 2013 FR
837929 Jun 1960 GB
1214548 Dec 1970 GB
S4828353 Aug 1973 JP
S5157777 May 1976 JP
S59191588 Dec 1984 JP
04165197 Jun 1992 JP
04165197 Oct 1992 JP
04309778 Nov 1992 JP
H06159922 Jun 1994 JP
H071479 Jan 1995 JP
H07167377 Jul 1995 JP
H08300052 Nov 1996 JP
H08303686 Nov 1996 JP
H09166271 Jun 1997 JP
H10113983 May 1998 JP
11159693 Jun 1999 JP
H11311395 Nov 1999 JP
H11336990 Dec 1999 JP
2000097390 Apr 2000 JP
20000117334 Apr 2000 JP
2000320958 Nov 2000 JP
2001038188 Feb 2001 JP
2001116437 Apr 2001 JP
2001336691 Dec 2001 JP
2001343176 Dec 2001 JP
2002068853 Mar 2002 JP
3438948 Aug 2003 JP
3478771 Dec 2003 JP
2004303695 Oct 2004 JP
2005069596 Mar 2005 JP
2005098637 Apr 2005 JP
2005114015 Apr 2005 JP
2005164193 Jun 2005 JP
2005256849 Sep 2005 JP
2006-77792 Mar 2006 JP
2006161834 Jun 2006 JP
2006161945 Jun 2006 JP
3792801 Jul 2006 JP
2006200685 Aug 2006 JP
2007263186 Oct 2007 JP
4111096 Jul 2008 JP
2008157431 Jul 2008 JP
2008190815 Aug 2008 JP
2009063064 Mar 2009 JP
2009162402 Jul 2009 JP
2009524570 Jul 2009 JP
2010017437 Jan 2010 JP
2010071565 Apr 2010 JP
2010108199 May 2010 JP
2010145002 Jul 2010 JP
4545126 Sep 2010 JP
2010236770 Oct 2010 JP
2010276309 Dec 2010 JP
2011002033 Jan 2011 JP
2011069612 Apr 2011 JP
4779684 Sep 2011 JP
2011196644 Oct 2011 JP
2012026493 Feb 2012 JP
4897473 Mar 2012 JP
2012063029 Mar 2012 JP
2012087993 May 2012 JP
2012163258 Aug 2012 JP
2012189114 Oct 2012 JP
2012242075 Dec 2012 JP
2013002484 Jan 2013 JP
2013050242 Mar 2013 JP
2013050267 Mar 2013 JP
2013076471 Apr 2013 JP
2013088036 May 2013 JP
2013195009 Sep 2013 JP
20020057547 Jul 2002 KR
20020080938 Oct 2002 KR
20030083812 Nov 2003 KR
20040000126 Jan 2004 KR
20050095357 Sep 2005 KR
100620025 Sep 2006 KR
20070044024 Apr 2007 KR
1020070065743 Jun 2007 KR
20080103845 Nov 2008 KR
20090026045 Mar 2009 KR
101017776 Feb 2011 KR
20120007241 Jan 2012 KR
20120046621 May 2012 KR
20120051305 May 2012 KR
20150089495 Aug 2015 KR
2061925 Jun 1996 RU
2077411 Apr 1997 RU
2081858 Jun 1997 RU
2132522 Jun 1999 RU
2162576 Jan 2001 RU
2166158 Apr 2001 RU
2187433 Aug 2002 RU
2234645 Aug 2004 RU
2252377 May 2005 RU
2253792 Jun 2005 RU
2349618 Mar 2009 RU
2414288 Mar 2011 RU
2422598 Jun 2011 RU
142892 Jul 2014 RU
2529525 Sep 2014 RU
2571031 Dec 2015 RU
203707 Dec 1967 SU
00476407 Jul 1975 SU
547614 May 1977 SU
648780 Feb 1979 SU
01307186 Apr 1987 SU
9614207 May 1996 WO
9721767 Jun 1997 WO
1998049506 Nov 1998 WO
9920961 Apr 1999 WO
9920964 Apr 1999 WO
200160598 Aug 2001 WO
200202987 Jan 2002 WO
2002052208 Apr 2002 WO
02060576 Aug 2002 WO
03072684 Sep 2003 WO
2003089729 Oct 2003 WO
2004010042 Jan 2004 WO
2006045694 May 2006 WO
2006073540 Jul 2006 WO
2007033836 Mar 2007 WO
2007085511 Aug 2007 WO
2007106067 Sep 2007 WO
2008065453 Jun 2008 WO
2008077741 Jul 2008 WO
2008118536 Oct 2008 WO
2008122483 Oct 2008 WO
2009013106 Jan 2009 WO
2009112433 Sep 2009 WO
2009147106 Dec 2009 WO
2010007783 Jan 2010 WO
2010029730 Mar 2010 WO
2010043009 Apr 2010 WO
2010092627 Aug 2010 WO
2010127947 Nov 2010 WO
2010127947 Nov 2010 WO
2011003711 Jan 2011 WO
2011058678 May 2011 WO
2011058678 May 2011 WO
2011081498 Jul 2011 WO
2012023705 Feb 2012 WO
2012026715 Mar 2012 WO
2012031885 Mar 2012 WO
2012043990 Apr 2012 WO
2012044001 Apr 2012 WO
2012085212 Jun 2012 WO
2012119892 Sep 2012 WO
2012152646 Nov 2012 WO
2013116103 Aug 2013 WO
2013116302 Aug 2013 WO
2014038150 Mar 2014 WO
2014038150 Mar 2014 WO
2014095542 Jun 2014 WO
2014121893 Aug 2014 WO
2014184393 Nov 2014 WO
2014184393 Nov 2014 WO
2013140816 Aug 2015 WO
2016082907 Jun 2016 WO
2017029782 Feb 2017 WO
Non-Patent Literature Citations (2)
Entry
Cai et al., “Generation of Metal Nanoparticles by Laser Ablation of Microspheres,” J. Aerosol Sci., vol. 29, No. 5/6 (1998), pp. 627-636.
Raszewski et al., “Methods for Producing Hollow Glass Microspheres,” Powerpoint, cached from Google, Jul. 2009, 6 pages.
Related Publications (1)
Number Date Country
20180363973 A1 Dec 2018 US
Divisions (1)
Number Date Country
Parent 15254519 Sep 2016 US
Child 16110553 US
Continuations (1)
Number Date Country
Parent 14789303 Jul 2015 US
Child 15254519 US