Embodiments of the present disclosure are in the field of renewable energy and, in particular, include approaches for fabricating interconnects for solar cells, and the resulting solar cells.
Photovoltaic cells, commonly known as solar cells, are well known devices for direct conversion of solar radiation into electrical energy. Generally, solar cells are fabricated on a semiconductor wafer or substrate using semiconductor processing techniques to form a p-n junction near a surface of the substrate. Solar radiation impinging on the surface of, and entering into, the substrate creates electron and hole pairs in the bulk of the substrate. The electron and hole pairs migrate to p-doped and n-doped regions in the substrate, thereby generating a voltage differential between the doped regions. The doped regions are connected to conductive regions on the solar cell to direct an electrical current from the cell to an external circuit coupled thereto.
Efficiency is an important characteristic of a solar cell as it is directly related to the capability of the solar cell to generate power. Likewise, efficiency in producing solar cells is directly related to the cost effectiveness of such solar cells. Accordingly, techniques for increasing the efficiency of solar cells, or techniques for increasing the efficiency in the manufacture of solar cells, are generally desirable. Some embodiments of the present disclosure allow for increased solar cell manufacture efficiency by providing novel processes for fabricating solar cell structures. Some embodiments of the present disclosure allow for increased solar cell efficiency by providing novel solar cell structures.
The following detailed description is merely illustrative in nature and is not intended to limit the embodiments of the subject matter or the application and uses of such embodiments. As used herein, the word “exemplary” means “serving as an example, instance, or illustration.” Any implementation described herein as exemplary is not necessarily to be construed as preferred or advantageous over other implementations. Furthermore, there is no intention to be bound by any expressed or implied theory presented in the preceding technical field, background, brief summary or the following detailed description.
This specification includes references to “one embodiment” or “an embodiment.” The appearances of the phrases “in one embodiment” or “in an embodiment” do not necessarily refer to the same embodiment. Particular features, structures, or characteristics may be combined in any suitable manner consistent with this disclosure.
Terminology. The following paragraphs provide definitions and/or context for terms found in this disclosure (including the appended claims):
“Comprising.” This term is open-ended. As used in the appended claims, this term does not foreclose additional structure or steps.
“Configured To.” Various units or components may be described or claimed as “configured to” perform a task or tasks. In such contexts, “configured to” is used to connote structure by indicating that the units/components include structure that performs those task or tasks during operation. As such, the unit/component can be said to be configured to perform the task even when the specified unit/component is not currently operational (e.g., is not on/active). Reciting that a unit/circuit/component is “configured to” perform one or more tasks is expressly intended not to invoke 35 U.S.C. §112, sixth paragraph, for that unit/component.
“First,” “Second,” etc. As used herein, these terms are used as labels for nouns that they precede, and do not imply any type of ordering (e.g., spatial, temporal, logical, etc.). For example, reference to a “first” solar cell does not necessarily imply that this solar cell is the first solar cell in a sequence; instead the term “first” is used to differentiate this solar cell from another solar cell (e.g., a “second” solar cell).
“Coupled”—The following description refers to elements or nodes or features being “coupled” together. As used herein, unless expressly stated otherwise, “coupled” means that one element/node/feature is directly or indirectly joined to (or directly or indirectly communicates with) another element/node/feature, and not necessarily mechanically.
In addition, certain terminology may also be used in the following description for the purpose of reference only, and thus are not intended to be limiting. For example, terms such as “upper”, “lower”, “above”, and “below” refer to directions in the drawings to which reference is made. Terms such as “front”, “back”, “rear”, “side”, “outboard”, and “inboard” describe the orientation and/or location of portions of the component within a consistent but arbitrary frame of reference which is made clear by reference to the text and the associated drawings describing the component under discussion. Such terminology may include the words specifically mentioned above, derivatives thereof, and words of similar import.
“Inhibit”—As used herein, inhibit is used to describe a reducing or minimizing effect. When a component or feature is described as inhibiting an action, motion, or condition it may completely prevent the result or outcome or future state completely. Additionally, “inhibit” can also refer to a reduction or lessening of the outcome, performance, and/or effect which might otherwise occur. Accordingly, when a component, element, or feature is referred to as inhibiting a result or state, it need not completely prevent or eliminate the result or state.
Approaches for fabricating spot-welded and adhesive bonded interconnects for solar cells, and the resulting solar cells, are described herein. In the following description, numerous specific details are set forth, such as specific paste compositions and process flow operations, in order to provide a thorough understanding of embodiments of the present disclosure. It will be apparent to one skilled in the art that embodiments of the present disclosure may be practiced without these specific details. In other instances, well-known fabrication techniques, such as lithography and patterning techniques, are not described in detail in order to not unnecessarily obscure embodiments of the present disclosure. Furthermore, it is to be understood that the various embodiments shown in the figures are illustrative representations and are not necessarily drawn to scale.
Disclosed herein are solar cells. In one embodiment, a solar cell includes a substrate having a back surface and an opposing light-receiving surface. A plurality of alternating N-type and P-type semiconductor regions is disposed in or above the back surface of the substrate. A conductive contact structure is disposed on the plurality of alternating N-type and P-type semiconductor regions. An interconnect structure is electrically connected to the conductive contact structure. The interconnect structure includes a plurality of protrusions in contact with the conductive contact structure. Each of the plurality of protrusions is spot-welded to the conductive contact structure and is surrounded by an adhesive material.
Also disclosed herein are methods of fabricating solar cells. In one embodiment, a method of fabricating a solar cell involves providing a solar cell including a substrate having a back surface and an opposing light-receiving surface, a plurality of alternating N-type and P-type semiconductor regions formed in or above the back surface of the substrate, and a conductive contact structure formed on the plurality of alternating N-type and P-type semiconductor regions. The method also includes forming a plurality of regions of an adhesive material on the conductive contact structure of the solar cell. The method also includes electrically connecting an interconnect structure to the conductive contact structure of the solar cell by spot-welding a plurality of protrusions of the interconnect structure to the conductive contact structure at locations corresponding to the plurality of region of the adhesive material.
In another embodiment, a method of fabricating a solar cell involves providing a solar cell including a substrate having a back surface and an opposing light-receiving surface, a plurality of alternating N-type and P-type semiconductor regions formed in or above the back surface of the substrate, and a conductive contact structure formed on the plurality of alternating N-type and P-type semiconductor regions. The method also includes providing an interconnect structure having a plurality of protrusions. The method also includes forming a plurality of regions of an adhesive material on the plurality of protrusions of the interconnect structure. The method also includes electrically connecting the interconnect structure to the conductive contact structure of the solar cell by spot-welding the plurality of protrusions of the interconnect structure to the conductive contact structure.
One or more embodiments described herein are directed to hybrid laser-adhesive weld-bonding for back contact solar cell interconnection structures. In an embodiment, spot welding of electrical interconnects is used to reduce certain critical reliability functions of joints formed between an interconnect structure and a solar cell (e.g., primarily mechanical stability under loading and corrosion resistance). A hybrid weld-bonding approach is used based on a combined resistance spot welding with adhesive bonding to overcome the above described limitations and produce a superior joint versus joints fabricated from a single approach. Since weld-bonding as typically practiced may not be feasible for interconnecting solar cells, some embodiments of the present disclosure involve use of a preformed interconnect with a dimpled region that overcomes the limitations of weld-bonding on the backside of solar cells. Advantages may include, but are not limited to, the implementation of controlled area and heights that dictate the precise location for both welding and adhesive boding. Embodiments described herein may be compatible with laser spot welding and/or with foil-based approaches for solar cell metallization structures.
To provide context, while spot welding of interconnects is sufficient from an electrical stand point, it has the potential to greatly reduce the mechanical reliability of the interconnection region. Spot welding can also lead to micro-gap regions that may be susceptible to crevice corrosion during service of a solar module, especially if the interconnection and backside metallization is fabricated from aluminum. Hybrid adhesive-welding may overcome such performance and reliability issues but may be incompatible with thinner and more delicate silicon wafers, and with laser spot welding processing which may be used to pattern metal foil-based solar cell metallization regions.
In accordance with one or more embodiments of the present disclosure, a prefabricated interconnect is provided with a predefined dimpled region. When placed during a solar cell stringing process, only a small amount of pressure distal from the joint is needed to squeeze an associated adhesive region out from under a corresponding weld area. The weld area remains open from the top side to allow for a laser spot welding process inside the dimpled region. The limited contact area may further confine heat dissipation during welding and may improve the quality and speed of the welding process. In an embodiment, the height of the dimpled region is selected to provide a consistent adhesive bond height, thus providing for an improved manufacturing process that ensures proper joint construction.
More specific embodiments include the use of an adhesive region to provide a tackiness to the cell during the stringing process such that pick-n-place processing can be decoupled from an actual welding step. It is to be appreciated that when no adhesive is used, such processes cannot be separated since there is no way to keep the interconnect structure from moving during indexing. In some embodiments, the adhesive fills in a micro-gap region between an interconnect structure and a cell pad area that is not welded. Such fill with the adhesive material may eliminate a crevice corrosion risk that may otherwise occur if spot welding alone is used. Furthermore, in an embodiment, overall joint strength is improved by implementing processes described herein since a relatively larger adhesion region is used and since the elastic properties of the adhesive impart improved fatigue and stress reduction. It is to be appreciated that solder is currently implemented in state-of-the-art processing as a stress reducer in for interconnect design. However, such a solder approach may not be needed if a welding process is implemented, as described below.
In order to provide visual context for embodiments described herein
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As a reference for one or more embodiments of the present disclosure,
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As another reference for one or more embodiments of the present disclosure,
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As exemplary implementations of one or more embodiments of the present disclosure,
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In an embodiment, the conductive contact structure 504 includes a metal foil, and each of the plurality of protrusions 508 of the interconnect structure 506A or 506B is spot-welded to the metal foil. In an embodiment, the conductive contact structure 504 further includes a metal seed layer disposed between the plurality of alternating N-type and P-type semiconductor regions and the metal foil. In an embodiment, the substrate 502 is a monocrystalline silicon substrate, and the plurality of alternating N-type and P-type semiconductor regions is a plurality of N-type and P-type diffusion regions formed in the silicon substrate 502. In another embodiment, however, the plurality of alternating N-type and P-type semiconductor regions is a plurality of N-type and P-type polycrystalline silicon regions formed above the back surface of the substrate 502.
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It is to be appreciated that structures described in association with
Referring to operation 702 of flowchart 700 and corresponding
Referring to operation 704 of flowchart 700 and again to corresponding
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In an embodiment, spot-welding 620 the plurality of protrusions 608 of the interconnect structure 606 to the conductive contact structure 604 involves laser-welding the plurality of protrusions 608 of the interconnect structure 606 to the conductive contact structure 604. In another embodiment, spot-welding 620 the plurality of protrusions 608 of the interconnect structure 606 to the conductive contact structure 604 involves resistive-welding the plurality of protrusions 608 of the interconnect structure 606 to the conductive contact structure 604. In an embodiment, the conductive contact structure 604 includes a metal foil, and electrically connecting the interconnect structure 606 to the conductive contact structure 604 involves electrically connecting each of the plurality of protrusions 608 of the interconnect structure 606 to the metal foil.
Referring again to
As another exemplary processing scheme,
Referring to operation 802 of flowchart 800, a method of fabricating a solar cell involves providing a solar cell including a substrate having a back surface and an opposing light-receiving surface, a plurality of alternating N-type and P-type semiconductor regions formed in or above the back surface of the substrate, and a conductive contact structure formed on the plurality of alternating N-type and P-type semiconductor regions.
Referring to operation 804 of flowchart 800, the method also includes providing an interconnect structure having a plurality of protrusions. The method also includes forming a plurality of regions of an adhesive material on the plurality of protrusions of the interconnect structure, as depicted in operation 806 of flowchart 800.
In an embodiment, forming the plurality of regions of the adhesive material involves forming a plurality of regions of a material such as, but not limited to, an epoxy, an aliphatic urethane, an acrylic, a modified polyolefin, a polyimide, or a silicone. In an embodiment, forming the plurality of regions of the adhesive material involves forming a plurality of regions of the adhesive material having a thickness approximately in the range of 30-130 microns.
Referring to operation 806 of flowchart 800, the method also includes electrically connecting the interconnect structure to the conductive contact structure of the solar cell by spot-welding the plurality of protrusions of the interconnect structure to the conductive contact structure.
In an embodiment, spot-welding the plurality of protrusions of the interconnect structure to the conductive contact structure involves laser-welding the plurality of protrusions of the interconnect structure to the conductive contact structure. In an embodiment, spot-welding the plurality of protrusions of the interconnect structure to the conductive contact structure involves resistive-welding the plurality of protrusions of the interconnect structure to the conductive contact structure. In an embodiment, the conductive contact structure includes a metal foil, and electrically connecting the interconnect structure to the conductive contact structure involves electrically connecting each of the plurality of protrusions of the interconnect structure to the metal foil.
In an embodiment, spot-welding the plurality of protrusions of the interconnect structure to the conductive contact structure involves spot-welding a plurality of protrusions each having a corresponding indentation in the interconnect structure (as described in association with
In an embodiment, as applicable to embodiments described above, alternating N-type and P-type semiconductor regions described herein are formed from polycrystalline silicon. In one such embodiment, the N-type polycrystalline silicon emitter regions are doped with an N-type impurity, such as phosphorus. The P-type polycrystalline silicon emitter regions are doped with a P-type impurity, such as boron. The alternating N-type and P-type semiconductor regions may have trenches formed there between, the trenches extending partially into the substrate. Additionally, although not depicted, in one embodiment, a bottom anti-reflective coating (BARC) material or other protective layer (such as a layer amorphous silicon) may be formed on the alternating N-type and P-type semiconductor regions. The alternating N-type and P-type semiconductor regions may be formed on a thin dielectric tunneling layer formed on the back surface of the substrate.
In an embodiment, as applicable to embodiments described above, a light receiving surface of a solar cell described herein may be a texturized light-receiving surface. In one embodiment, a hydroxide-based wet etchant is employed to texturize the light receiving surface of the substrate. In an embodiment, a texturized surface may be one which has a regular or an irregular shaped surface for scattering incoming light, decreasing the amount of light reflected off of the light receiving surface of the solar cell. Additional embodiments can include formation of a passivation and/or anti-reflective coating (ARC) layers on the light-receiving surface.
In an embodiment, as applicable to embodiments described above, an M1 layer, if included, is a plurality of metal seed material regions. In a particular such embodiment, the metal seed material regions are aluminum regions each having a thickness approximately in the range of 0.3 to 20 microns and composed of aluminum in an amount greater than approximately 97% and silicon in an amount approximately in the range of 0-2%.
In an embodiment, as applicable to embodiments described above, an M2 layer as described herein is a conductive layer formed through electroplating or electroless plating. In another embodiment, an M2 layer as described herein is a metal foil layer. In one such embodiment, the metal foil is an aluminum (Al) foil having a thickness approximately in the range of 5-100 microns and, preferably, a thickness approximately in the range of 30-100 microns. In one embodiment, the Al foil is an aluminum alloy foil including aluminum and second element such as, but not limited to, copper, manganese, silicon, magnesium, zinc, tin, lithium, or combinations thereof. In one embodiment, the Al foil is a temper grade foil such as, but not limited to, F-grade (as fabricated), O-grade (full soft), H-grade (strain hardened) or T-grade (heat treated). In another embodiment, a copper foil, or a copper layer supported on a carrier, is used the “metal foil.” In some embodiments, a protective layer such as a zincate layer is included on one or both sides of the metal foil.
Although certain materials are described specifically with reference to above described embodiments, some materials may be readily substituted with others with other such embodiments remaining within the spirit and scope of embodiments of the present disclosure. For example, in an embodiment, a different material substrate, such as a group III-V material substrate, can be used instead of a silicon substrate. Additionally, although reference is made significantly to back contact solar cell arrangements, it is to be appreciated that approaches described herein may have application to front contact solar cells as well. In other embodiments, the above described approaches can be applicable to manufacturing of other than solar cells. For example, manufacturing of light emitting diode (LEDs) may benefit from approaches described herein.
Thus, approaches for fabricating spot-welded and adhesive bonded interconnects for solar cells, and the resulting solar cells, have been disclosed.
Although specific embodiments have been described above, these embodiments are not intended to limit the scope of the present disclosure, even where only a single embodiment is described with respect to a particular feature. Examples of features provided in the disclosure are intended to be illustrative rather than restrictive unless stated otherwise. The above description is intended to cover such alternatives, modifications, and equivalents as would be apparent to a person skilled in the art having the benefit of this disclosure.
The scope of the present disclosure includes any feature or combination of features disclosed herein (either explicitly or implicitly), or any generalization thereof, whether or not it mitigates any or all of the problems addressed herein. Accordingly, new claims may be formulated during prosecution of this application (or an application claiming priority thereto) to any such combination of features. In particular, with reference to the appended claims, features from dependent claims may be combined with those of the independent claims and features from respective independent claims may be combined in any appropriate manner and not merely in the specific combinations enumerated in the appended claims.