Spray applicator for roofing and other surfaces

Information

  • Patent Grant
  • 6358344
  • Patent Number
    6,358,344
  • Date Filed
    Friday, September 1, 2000
    24 years ago
  • Date Issued
    Tuesday, March 19, 2002
    22 years ago
Abstract
A method and an industrial robotic device for uniformly applying coatings at appropriate thickness and pitch upon a surface moves a spray applicator foam dispenser between two parallel tracks. The uniform application of foam at each pass is assured, by accelerating the speed of the foam dispenser at the end of each pass, by providing respective curved uphill distal ends of the tracks, so that the spray applicator foam dispenser moves up the curved distal ends and returns quickly while changing speed tilt and direction at the end of each pass.
Description




FIELD OF THE INVENTION




The present invention relates to a new and useful method and industrial robotic device for applying coatings or other spray coated layers, in uniform thicknesses and at appropriate angles of pitch, in field applications, such as roofing applications or pavement applications.




BACKGROUND OF THE INVENTION




In the roofing applications, flat roofs are often made of polyurethane foam layers, which may be covered by various coatings, such as elastomeric coatings, such as silicone. It is difficult to maintain a uniform thickness when applying a foam or elastomeric material, which by its nature rises when applied to achieve a thickness above a roof base.




Furthermore, the faster that a foam applicator passes over a surface, the less volume of foam is applied, resulting in less of a thickness of the applied foam. To achieve thicker foam layers, a spray applicator is slowed down in velocity as it passes over the roof bases, so that more foam material is discharged per square unit of space of roof base being passed over by the spray applicator.




Various attempts have been made to apply foam uniformly, such as from an applicator moving at a uniform speed along a carriage track. However, at the end of each pass of an applicator over a portion of a roof base, the discharged foam is applied twice, i.e. once at the end of the pass to the edge, and again as it starts over above the previously applied foam, until the carriage can adjust to an unsprayed area.




Among prior art devices included U.S. Pat. No. 5,381,597 of Petrove which describes a wheeled robotic device for installing shingles on roofs. While it does not concern spraying of urethane foam upon a flat roof, it does describe a movable, wheeled carriage for use upon a roof.




U.S. Pat. No. 5,248,341 of Berry concerns the use of curved walls to accommodate spray paint applicators for curved surfaces, such as aircraft.




U.S. Pat. No. 5,141,363 of Stephens describes a mobile train which rides on parallel tracks for spraying the inside of a tunnel.




U.S. Pat. No. 5,098,024 of MacIntyre discloses a spray and effector which uses pivoting members to move an armature which holds a spray apparatus.




U.S. Pat. No. 4,983,426 of Jordan discloses a method for the application of an aqueous coating upon a flat roof by applying a tiecoat to a mastic coat.




U.S. Pat. No. 4,838,492 of Berry discloses a spray gun reciprocating device, wherein parallel tracks are used wherein each track is square in cross section, but further wherein each track guides a plurality of rollers thereon.




U.S. Pat. No. 4,630,567 of Bambousek discloses a spray system for automobile bodies, including a paint booth, a paint robot apparatus movable therein, and a rail mechanism for supporting the apparatus thereat.




U.S. Pat. No. 4,567,230 of Meyer describes a chemical composition for the application of a foam upon a flat roof.




U.S. Pat. No. 4,167,151 of Muraoka discloses a spray applicator wherein a discharge nozzle is moved transversally upon a frame placed adjacent and parallel to the surface having the foam being applied thereto. However, the applicator of Muraoka '151 does not solve the problem of excess foam being applied at the end of each transverse pass of the discharge nozzle.




U.S. Pat. No. 4,209,557 of Edwards describes a movable carriage for a nozzle applying adhesive to the back of a movably advancing sheet of carpeting. Similarly, Australian Patent no. 294,996 of Keith describes a movable carriage for a nozzle applying a polyurethane foam coating to a movably advancing sheet.




U.S. Pat. No. 4,016,323 of Volovsek also discloses the application of foam to a flat roof.




U.S. Pat. No. 3,786,965 and Canadian Patent no. 981,082, both of James et al, describe a self-contained trailer for environmentally containing a dispenser for uniformly dispensing urethane foam upon a terrestrial surface, wherein the problem of “skewing” occurs at the completion of each pass at the boundary edges of the surface to which are urethane foam is being applied. James '965 employs self-enclosed gantry robots to move the fluid discharge nozzle over the terrestrial surface.




U.S. Pat. No. 3,667,687 of Rivking discloses a foam applicator device.




U.S. Pat. No. 4,474,135 of Bellafiore discloses an apparatus for spraying a coating upon a spherical object supported by a post, which apparatus includes a curved track for providing orbital movement of a spray applicator about the exterior spherical surface of the sphere to be coated. While they are curved in nature, the curved tracks thereof are provided for orbital movement about the sphere, not to change the speed, tilt and direction of a linearly moving nozzle.




Another attempt to solve the problem of “double spraying” at a pass edge has been described in U.S. Pat. No. 4,333,973 of Bellafiore, which describes a similar spray applicator, such as that of Autofoam® Company. This spray applicator includes a wheeled, self-movable vehicle having a carriage portion with a horizontal linear track thereon. The spray applicator moves from one end of the track to the other, opposite end of the track at the end of one pass, of the applicator, above a portion of a roof base, and then the applicator reverses direction upon the track.




However, to avoid the “double spraying” problem noted above, the Autofoam® device has an on-off switch which turns the applicator off at an appropriate time at the end of a pass while the applicator is reversing direction, and re-starts the applicator a short time later when the applicator has started to move in the opposite direction.




Moreover, there are severe problems with this approach, as the constant “on-off” starting and re-starting of the applicator causes fatigue to the metal or other material parts of the applicator, and a detrimental effect to the end product. In addition, the Bellafiore '973 and Autofoam® devices are bulky and complicated to use.




OBJECTS OF THE INVENTION




Therefore, the objects of the present invention are as follows:




It is therefore an object of the present invention to provide a spray applicator for foam roofing which applies a coating of elastomeric foam of uniform thickness.




It is also an object of the present invention to provide a single yet efficient spray applicator for foam roofing.




It is also an object of the present invention to provide a spray applicator than can be disassembled into a few major parts for easy transport and reassembly on a roof without resorting to the use of a crane.




It is yet another object of this invention to provide a method for covering a large area of a roof with foam roofing using a continuous spray.




It is also an object of the present invention to provide a spray applicator with a nutating nozzle mount to minimize variations in coating thickness.




It is a further object of the present invention to provide a hand-held remote control to enable the spray applicator vehicle to operate without an on-board operator.




It is an object of the present invention to provide a method for continuous adhesive spraying and application of elastomeric sheet roofing material of a large strip areas of a roof.




It is a further object of the present invention to provide accessories for the spray applicator vehicle to permit its use for applying elastomeric sheet roofing material from a roll.




Yet another objective of this invention is to provide a method and apparatus to provide fabric reinforced foam roofing.




It is also an object of the present invention to improve over the disadvantages of the prior art.




SUMMARY OF THE INVENTION




In keeping with these objects and others which may become apparent, and to solve the problems inherent in the Bellafiore '973 and Autofoam® spraying devices, the present invention uses one or more track rails, such as a double linear track of round cross section, as shown in the drawings herein, wherein there is an arcuate uphill end portion of the track at each side, so that the spray applicator, which moves along the one or more linear tracks, will accelerate in speed and tilt the discharge nozzle outward as it rolls up the curved uphill portion, thereby reducing the amount of foam applied to the edge portion of the roof at the end of a pass of the applicator.




To obviate the complicated mechanisms of the Autofoam® device, the present invention uses simple mechanics to move the spray applicator. For example, a radially extending swinging arm is provided for the sideways movement of the applicator along the track. To eliminate arcuate movement of the pivoting arm, a telescoping mechanism is provided, so that the spray applicator moves linearly, instead of arcuately, as the swinging arm moves about a pivot fulcrum point.




To further insure uniform thickness, the present invention further comprises various speed controls, so that an appropriate thickness can be applied for each pass.




For example, a rheostat controls the speed of the movement of the spray applicator, and an LED readout tachometer has a display dial with appropriate readings for appropriate speeds for corresponding desired thicknesses. Since the rate of flow of foam-producing material emanating from the nozzle is fixed, the ground movement speed of the applicator determines the weight of the coating per unit area applied. This, in turn, determines the thickness.




When a slope is desired on a flat roof, such as toward a drainage line, the ground speed of the foam applicator can be reduced on each successive pass away and parallel to the drainage line. This will result in a stepwise slope approximating the desired contour.




It has been found that a nutating nozzle holder, which tilts the nozzle a small amount cyclically as it traverses the track, can be used to minimize the variations in foam thickness (in the form of rounded ridges) due to the hollow-cone pattern of the nozzle.




Accessories can be added to the spray applicator so that it can be adapted for spraying adhesive on a roof or for automatically laying an elastomeric sheet covering such as Sure-Seal™ Fleece Back 100 EPDM made by Carlisle SynTec Incorporated of Carlisle, Pa. over a polyurethane foam substrate. Accessories can also be added for imbedding reinforced fabric within the polyurethane foal substrate.




While the invention has been described for use in applying roofing materials on roofs, it is also usable for spray applications at ground level such as for pavement painting or sealing applications.











DESCRIPTION OF THE DRAWINGS




The present invention can best be described in conjunction with the accompanying drawings, in which:





FIG. 1

is a top plan view of a spray applicator vehicle of the present invention;





FIG. 2

is a side elevation of a spray applicator vehicle of the present invention;





FIG. 3

is a side cross section detail of a transverse rail and carriage;





FIG. 4

is an end elevation of a transverse rail and carriage;





FIG. 5

is a block diagram of a spray applicator electrical system;





FIG. 6

is an end cross section of a coated roof with a central drain ridge;





FIG. 7

is a block diagram of a spray applicator electrical system using a hand-held remote control;





FIGS. 8 and 8A

show a nozzle spray pattern and resultant foam cross section;





FIGS. 9A and 9B

show a nutating spray nozzle feature with details thereof; wherein





FIG. 9A

is a side elevation of a nozzle holder and an actuator cable; and,





FIG. 9B

is a top plan view of a cam and cam follower;





FIG. 10

is a side elevation of a spray applicator as adapted for laying elastomeric sheet roofing material; and,





FIG. 11

is a side elevation of a spray application vehicle as adapted for applying fabric or mesh reinforced foam coating.











DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT




As shown in

FIGS. 1-2

, spray applicator


1


is used for applying polyurethane foam coatings or other spray coated layers, in uniform thicknesses in field applications, such as roofing applications or pavement applications.




As shown in

FIGS. 1 and 2

, spray applicator vehicle


1


includes frame


2


, operator seat


5


, steerable powered single wheel


50


, two unpowered side wheels


4


, swinging boom


18


, transverse rail subassembly


23


and various associated parts of nozzle


62


attached to carriage plate


26


. Motor


6


drives sprocket


52


of chain


8


through gear reduction box


7


to provide vehicle motion via wheel sprocket


51


. The operator steers the vehicle


1


by steering wheel


9


, which moves steering linkage bar


57


, thereby rotating wheel flange


58


. Boom


18


is continuously reciprocated from pivot point


20


on tower


55


by crank arm


16


which is cyclically moved by reduction gear box


13


powered by motor


12


, via adjustable linkage arm


14


. Linkage arm


14


is attached to output shaft


17


and is rotated at a constant speed as determined by settings in control box


11


. Slot


15


permits adjustment of the lateral movement limits of telescoping end


19


of boom


18


. Rails


24


and


25


constrain the movement of carriage plate


26


to a linear path transverse to frame


2


.




Control box


11


also sets the ground speed of vehicle


1


. Hose


35


, which may consist of two or more separate hoses or individual lumens, carries liquid materials for spraying through nozzle


62


from a remote pressurized source. For polyurethane foam, two chemicals supplied from separate hoses


35


are mixed at the nozzle


62


just prior to discharge. The two liquids interact chemically causing an exothermic foaming and hardening reaction. Hose


35


is retained in boom bracket


37


and may also be attached in one or more places by hook and loop straps


36


. In normal use, a second (non-riding) work person guides hose


35


. Solenoid


38


, actuated by a switch in control unit


11


, operates the discharge valve at nozzle


62


.




It can be appreciated that vehicle


1


rolling at a constant speed with boom


18


reciprocating continuously is able to spray a continuous strip of coating on a surface. If the discharge rate at the nozzle is held constant, the amount of product sprayed on a surface per unit of sprayed area can be set by selecting ground speed.




Since the boom changes direction at the distal ends of its swings, a method is employed to limit the amount discharged to prevent “double coating” at the edges.




As noted before, prior art systems, such as described in Bellafoire '973 and of Autofoam® Company, shut the nozzle off at these portions of the cycle. However this action causes several problems.




For example, the on/off cycling has detrimental effects on spray material consistency from a chemical reaction point of view. The on/off cycling also causes mechanical wear and induces metal fatigue on brackets that must react to cyclic pressure loading.




In contrast to the devices of Bellafoire '973 and of the Autofoam® Company, the present invention uses a geometric arrangement and constant liquid product flow to prevent pattern edge build-up.




For example,

FIG. 3

shows a cross section of rails


24


and


25


in the middle of the transverse sweep. Carriage plate


26


, driven by end bushing


27


on telescoping extension


19


, is shown with brackets


65


and


66


attached. Brackets


65


secure top rollers


29


with concave “hourglass” contours. Similarly contoured bottom rollers


53


are secured by brackets


66


. Thus rollers


29


and


53


capture rails


24


and


25


constraining plate


26


to roll along these rails. Plate


26


also supports nozzle holder assembly


34


(not shown in this figure).





FIG. 4

shows an end view of rail subassembly


23


. Both rails


24


and


25


are curved at their distal ends in a constant radius. Nozzle assembly


34


is shown in a flat vertical spray location at “A” and at an oblique spray location at the extreme limit of travel on the curved portion at “B”. Top rollers


29


and bottom rollers


53


are offset from each other to facilitate easy rolling without binding on the curved portions. If boom


18


is reciprocated at an essentially constant rate, the carriage assembly is accelerated at the ends of travel due to the greater distance traveled per unit time on the curved end contour as well as the change in direction. Furthermore, the angle of nozzle


62


is tilted outward at the end so that the coverage area “BB” is larger than that of “AA”. These end factors combine to reduce the thickness of the sprayed layer so that the “double layering” at the edge of each applied band of foam can be controlled to result in an edge thickness essentially the same as that of the center portion of a pass. This can be adjusted empirically based on the particular batch, temperature and other field conditions. The adjustment is the end limit position of nozzle


62


relative to the track end curve as determined by the adjustment of crank arm


16


in slot


15


of linkage arm


14


.




Spray vehicle


1


is designed to be easily disassembled into four subassemblies for easy transport to the roof of a building on an elevator or by using a winch. Prior art systems require a crane. Booms


18


and


19


can be lifted off as a unit by removing spring pin


22


from upright link


54


, spring pin


21


from pivot shaft


20


and spring pin


28


from carriage plate


26


coupling.




A front subassembly including of track subassembly


23


with uprights


3


can be removed by removing two spring pins


30


from frame member


2


.




Central frame


2


subassembly including wheels


4


can be separated from the driven wheel subassembly (including seat


5


and steering wheel


9


by removing large spring pin


60


from socket member


59


on the frame subassembly. Then back chassis


10


can be lifted free. Electrical connections tying the various subassemblies have connectors which must be disconnected. The four subassemblies can then be reassembled on the rooftop.





FIG. 5

shows a block diagram of the electrical system largely housed in control box


11


. The spray applicator vehicle


1


is electrically operated by connection to standard AC mains (typically 115 VAC at 60 HZ) via plug


40


and extension cord


39


. A portable engine operated generator can supply this power as an alternative. Although two separate modular AC/DC converters


76


and


83


are depicted, a single converter can supply current to all DC loads.




An AC power switch


75


controls power to the entire spray applicator vehicle


1


. Converter


76


supplies DC to a unidirectional speed control


77


with digital speed indicator


78


and speed set control


79


. For maximum consistency of application, speed control


77


is preferable a PID type of feedback servo control which maintains output speed of motor


12


(for swinging of boom


18


) constant via feedback from encoder


80


mounted on motor


12


.




Switch


81


controls power to a solenoid


82


which opens the discharge valve at nozzle


62


. Converter


83


supplies DC power to a bi-directional PID speed control


84


with digital speed indicator


85


and speed set control


86


. This control accurately and repeatedly maintains the ground speed in either direction of spray applicator vehicle


1


as set even under varying load conditions by virtue of feedback encoder


87


mounted on motor


6


.




This operation is used during the spraying operation and determines the thickness of the resulting sprayed layer. Control switch


89


determines the direction of movement as forward or reverse.




A second manual bi-directional speed control


90


is used to quickly select the desired ground speed via alternate manual control


91


when it is desired to maneuver spray applicator vehicle


1


prior or after a spray application.




In this manner, the carefully selected “automatic” setting for spraying is not altered. Either automatic speed control


84


or manual speed control


90


is actively enable at any one time via selector switch


88


.




The repeatable application of a desired amount of coating per pass permits the type of roof foam surfacing depicted in FIG.


6


. This is an exaggerated cross section of the end of a roof


61


surface with a central drain


96


ditch with grate cover


95


. If the roof


61


had a flat pitch, it would be desirable to create a pitch toward the drainage ditch for more effective drainage. This can be approximated by a stepped foam layer as shown, starting from lowest strip “A” and rising in thickness to strip “E” of the thickest cross section farthest from central drain


96


. These strips can be applied in a single pass or in multiple passes by spray applicator vehicle


1


where the ground speed for layer “A” is fastest and the speed is reduced for each successive layer “B”, “C”, “D”, “E” and “F”.




For safety reasons, federal OSHA occupational safety regulations stipulate that a powered vehicle cannot be ridden by a workperson within ten feet of the edge of a roof. Also, a workperson is required to guide hose


35


while the operator rides and guides spray applicator vehicle


1


. For these reasons, it would be desirable to operate spray applicator vehicle remotely. In this manner, a single workperson controls spray applicator vehicle


1


and guide hose


35


.





FIG. 7

shows such a remote control configuration. Control box


11


is replaced by a hand-held remote control box


100


with a face plate and several vehicle mounted functional units. Since the operator is no longer physically on spray applicator vehicle


1


, electric steering ram


102


replaces the steering wheel. Electric steeling ram


102


is controlled by positional steering control


101


, which sets the position of steered wheel


50


to match that of steering control wheel


106


on remote control box


100


.




Communications between remote control box


100


and spray applicator vehicle


1


is via coiled cable


105


, although a fail-safe radio communications channel can be used as well. To limit the number of individual conductors in cable


105


, a multiplexor/demultiplexor module


103


and


104


is used at each end of cable


105


to facilitate the two way communications. The function of similarly numbered components is the same as that explained above in reference to FIG.


5


.




Hollow-cone nozzle


62


sprays a pattern


110


that impinges on the ground as shown in FIG.


8


. As this pattern is swept sideways in a single pass, it will lay material that is denser toward the top and bottom edges resulting in a cross section with ridges


111


and valley


112


in the “Y” direction from roof surface


61


.




While multiple sweeps by boom


18


mitigate this effect somewhat, ridges in the final sprayed surface still persist. This problem is eliminated by nutating or cyclically rocking the nozzle amount


34


slightly at right angles to rails


24


and


25


several times during each sweep to even out the coverage of hollow-cone nozzle


62


over multiple sweeps.





FIG. 9

shows optional modifications to accomplish this. The detail of

FIG. 9A

shows modified bracket


120


with pivot


121


holding nozzle mount


34


. Bracket


120


is fastened to carriage plate


26


. A push-pull cable assembly including armored housing sleeve


123


with cable


122


within is used to actuate the cyclic motion illustrated by the phantom representation (shown in broken lines) of nozzle holder


34


at the extreme outward position. The detail of

FIG. 9B

shows the powering end of cable


122


. Bracket


126


, attached to the frame of vehicle spray applicator


1


in the vicinity of gear box


13


, retains sleeve


123


. Cam follower


130


is pivoted at pivot point


128


within adjustment slot


127


and is biased toward multiple lobe cam


131


by spring


129


. The stroke of wire


122


(and therefore the amount of cyclic tilt of nozzle holder


34


) is determined by the dimensions and geometry of can follower


130


and the depth of lobes on multiple lobe cam


131


.




The proper centering of the motion of holder


34


is adjusted by moving pivot


128


within slot


127


. Multiple lobe cam


131


is attached to the output shaft of gear box


13


under arm


14


. It can be appreciated that cable wire


122


is cycled by each cam lobe as multiple lobe cam rotates.




By moving cam follower


130


out of contact with multiple lobe cam


131


and tightening it in a locked position, to defeat the pivoting, nozzle holder


34


can be locked in a vertical position to defeat the nutating feature.




Alternatively, a separate small gear motor and crank coupling (not shown) mounted right on bracket


120


can be used to actuate the nutating action without need of cable


122


.




Spray applicator vehicle


1


is easily modified to adhesively bond sheet elastomeric roofing material. As shown in

FIG. 10

, side arms


141


are pivoted at pivot point


140


from side extensions (not shown) which are attached to frame


2


. These arms


141


have telescoping extensions


142


which are locked with hand screws


143


. A roll of elastomeric sheet


144


is pivoted at the end of arms


142


at pivot point


148


, with sheet end


145


trailing roll


144


as vehicle spray applicator


1


moves in the direction of arrow


149


. Also pivoted at pivot point


148


are side arms


146


which trail a weighted roller


147


, which weighted roller


147


applies even pressure to sheet layer


145


. Nozzle


62


sprays a layer of bonding adhesive which bonds sheet


145


to roof surface


61


.




Alternatively, roll


144


can be adjusted to apply a skin coating of rolled material over the solidified foam layer applied from nozzle


62


to a surface, such as a roof.




Adjustment of extensions


142


determine the distance X between the sheet contact and the sprayed roof surface a fixed distance from the center of the spray cone. Since the vehicle moves at a predetermined constant speed, distance X can be used to match the optimal delay from adhesive application to contact of the sheet roofing material.




A method for applying reinforced foam roofing involves the use of a reinforcing fabric or open fabric mesh. The fabric can be manufactured of a variety of fibers such as nylon, fiberglass, aramid, etc. The method involves spraying a foaming mixture and immediately imbedding the reinforcing fabric in the mixture before the foam rises so that the reinforcing fabric rises with the foam and is embedded in the foam layer.





FIG. 11

shows modifications of the spraying applicator vehicle


1


for accomplishing this task. Side arms


160


are rigidly attached to frame


2


and uprights


3


; they flare out at the distal end to lie outside of the spray pattern on each side. Roll


164


of lightweight reinforcing fabric is pivotly attached at the end of arms


160


. The free end of fabric


165


is fed under light roller


162


, which contacts surface


61


just at the edge of the foam adhesive spray pattern. Spring plunger


161


supported by brace


163


forces roller


162


into contact with roof surface


61


. Foam spray


168


, prior to rising, is contacted with fabric


165


, which rises with foam


166


to embed itself in the foam layer as shown by the broken line.




It is further noted that other modifications may be made to the present invention without departing from the scope as noted in the appended claims.



Claims
  • 1. A method of making an in situ, filed applied surface membrane upon a roof surface comprising the steps of:applying by a spray a first layer of spontaneously rising and curable polyurethane foam upon a roof surface; during said spontaneously rising and curing of said polyurethane foam, applying a second layer of a reinforced open mesh layer having fibers therein over said polyurethane foam; permitting said polyurethane foam to rise through and over said fibers of said reinforced open mesh layer, thereby imbedding said mesh therebetween; applying a coating over said first and second layers; and, allowing said curable polyurethane foam to cure into a hardened state and become inseparable and monolithic.
  • 2. The method of making an in situ, filed applied surface membrane upon a roof surface as in claim 1 further comprising the step of applying said reinforced open mesh layer from a continuous roll, wherein a free end of said second layer of reinforced open mesh is fed from said continuous roll under a rotating roller which contacts an upper portion of said spray applied first layer of spontaneously rising and curable polyurethane foam upon said roof surface.
Parent Case Info

This application is a continuation of application Ser. No. 09/267,755 filed Mar. 11, 1999, now U.S. Pat. No. 6,117,256. This application is based in part upon Disclosure Document No. 373320 dated Mar. 8, 1995 and Provisional Patent Application, Serial No. 60/030,914, filed on Nov. 14, 1996.

US Referenced Citations (82)
Number Name Date Kind
1835402 Juers Dec 1931 A
2176891 Crom Oct 1939 A
2770216 Schock Nov 1956 A
3027095 Paasche Mar 1962 A
3096225 Carr Jul 1963 A
3411256 Best Nov 1968 A
3548453 Garis Dec 1970 A
3583118 Lowery Jun 1971 A
3607972 Kiles Sep 1971 A
3641720 Berrie Feb 1972 A
3667687 Rivkind Jun 1972 A
3705821 Breer Dec 1972 A
3741482 Eliason Jun 1973 A
3786965 James Jan 1974 A
3823525 Bruun Jul 1974 A
3867494 Rood Feb 1975 A
3885066 Schwenninger May 1975 A
3923937 Piccioli Dec 1975 A
3954544 Hooker May 1976 A
3971184 Van Wagoner Jul 1976 A
4016323 Volovsek Apr 1977 A
4073998 O'Connor Feb 1978 A
4087296 Hooker May 1978 A
4096303 Doerfling Jun 1978 A
4167151 Muraoka Sep 1979 A
4194282 Byrd, Jr. Mar 1980 A
4209557 Edwards Jun 1980 A
4210098 Harrison Jul 1980 A
4244151 Seem Jan 1981 A
4282697 Spielau et al. Aug 1981 A
4333973 Bellafiore Jun 1982 A
4379103 Doerfling Apr 1983 A
4474135 Bellafiore Oct 1984 A
4486994 Fisher et al. Dec 1984 A
4521458 Nelson Jun 1985 A
4521478 Hageman Jun 1985 A
4558550 Marchais Dec 1985 A
4567230 Meyer Jan 1986 A
4572857 Bekaert Feb 1986 A
4630567 Bambousek Dec 1986 A
4641468 Slater Feb 1987 A
4651494 Van Wagoner Mar 1987 A
4659018 Shulman Apr 1987 A
4736552 Ward et al. Apr 1988 A
4748781 Wencley Jun 1988 A
4754583 Jenn Jul 1988 A
4774794 Grieb Oct 1988 A
4788803 Seitz Dec 1988 A
4837095 Hageman Jun 1989 A
4838492 Berry Jun 1989 A
4903446 Richards et al. Feb 1990 A
4944127 Clear Jul 1990 A
4983426 Jordan Jan 1991 A
5070670 Alderson Dec 1991 A
5072569 VanTassel Dec 1991 A
5098024 MacIntyre Mar 1992 A
5141363 Stephens Aug 1992 A
5215805 Pavia Jun 1993 A
5231813 Drawdy Aug 1993 A
5248341 Berry Sep 1993 A
5253461 Janoski Oct 1993 A
5269109 Gulur Dec 1993 A
5279088 Heydon Jan 1994 A
5344700 McGrath et al. Sep 1994 A
5381597 Petrove Jan 1995 A
5381638 Andersson Jan 1995 A
5457917 Palmersten Oct 1995 A
5509242 Rechsteiner et al. Apr 1996 A
5620554 Venable Apr 1997 A
5670178 West Sep 1997 A
5771649 Zweig Jun 1998 A
5815989 Bennenk et al. Oct 1998 A
5872203 Wen Feb 1999 A
5921046 Hammond, Jr. Jul 1999 A
5950397 Ginn et al. Sep 1999 A
5987835 Santarossa Nov 1999 A
5992110 Clear Nov 1999 A
6006480 Rook Dec 1999 A
6061995 Menchetti May 2000 A
6167624 Lanahan et al. Jan 2001 B1
6193826 Starr et al. Feb 2001 B1
6205728 Sutelan Mar 2001 B1
Foreign Referenced Citations (4)
Number Date Country
294996 May 1967 AU
981082 Jan 1976 CA
813311 May 1959 GB
2055326 Mar 1981 GB
Non-Patent Literature Citations (2)
Entry
STEPANFOAM® Stepan Co. 1998 one Internet.
STEPANPOL® Stepan Co. 1998 one Internet.
Provisional Applications (1)
Number Date Country
60/030914 Nov 1996 US
Continuations (1)
Number Date Country
Parent 09/267755 Mar 1999 US
Child 09/653772 US