The present invention relates to a spray dryer absorber which is operative for removing gaseous pollutants from a hot process gas and comprises a spray dryer chamber and at least two dispersers mounted at a roof of the spray dryer chamber, each such disperser being operative for dispersing a portion of the hot process gas around a respective atomizer which is operative for atomizing an absorption liquid, each disperser being provided with a flow directing device, which is operative for providing the respective portion of the hot process gas with a rotary movement around the atomizer, as seen from the top of the spray dryer chamber.
The present invention further relates to a method of removing gaseous pollutants from a hot process gas by means of a spray dryer absorber.
In the combustion of a fuel, such as coal, oil, peat, waste, etc., in a combustion plant, such as a power plant, a hot process gas is generated, such a hot process gas, often referred to as a flue gas, containing pollutants, including acid gases, such as sulphur dioxide, SO2. It is necessary to remove as much as possible of the acid gases from the flue gas before the flue gas may be emitted to the ambient air. A spray dryer absorber may be utilized for removing acid gases, including sulphur dioxide, from a flue gas.
An example of a spray dryer absorber can be found in U.S. Pat. No. 4,755,366. The spray dryer absorber comprises a chamber which is provided with a rotary atomizer having an atomizer wheel. The rotary atomizer is supplied with an aqueous suspension, sometimes referred to as a slurry, which comprises an absorbent, such as limestone. The atomizer wheel spins at a high rpm and atomizes the aqueous suspension, such that very small droplets are formed. The small droplets absorb acid gas components from the flue gas, and then form a solid residue thanks to the drying effect of the spray dryer absorber.
A problem of the spray dryer absorber of U.S. Pat. No. 4,755,366 is that it is difficult to increase the capacity of a single spray dryer absorber with respect to the flue gas flow rate. One reason for this difficulty is that the very high rpm of the atomizer wheel poses mechanical obstacles to up-scaling its size. Thus, it often becomes necessary to build two, three, or more, parallel spray dryer absorber chambers for coping with higher flue gas flow rates.
An object of the present invention is to provide a spray dryer absorber which can be designed for a higher flue gas flow rate than the spray dryer absorbers of the prior art.
This object is achieved by means of a spray dryer absorber which is operative for removing gaseous pollutants from a hot process gas and comprises a spray dryer chamber and at least two dispersers mounted at a roof of the spray dryer chamber, each such disperser being operative for dispersing a portion of the hot process gas around a respective atomizer which is operative for atomizing an absorption liquid, each disperser being provided with a flow directing device, which is operative for providing the respective portion of the hot process gas with a rotary movement around the atomizer, as seen from the top of the spray dryer chamber, the spray dryer absorber being characterised in said at least two dispersers being located at substantially the same distance from the periphery of the spray dryer chamber, the flow directing device of at least one specific disperser of said at least two dispersers being operative for providing said portion of the hot process gas passing through that specific disperser with a rotary movement in a direction, which is opposite to the direction of the rotary movement of the respective portion of the hot process gas dispersed by at least one other disperser being located closest to said at least one specific disperser, as seen along the periphery of the spray dryer chamber.
An advantage of this spray dryer absorber is that two or more dispersers can be arranged in one and the same spray dryer chamber, without such dispersers affecting each other in a negative way. Hence, the capacity with respect to the flue gas flow, and with respect to the absorption liquid flow, of one spray dryer absorber can be increased, still maintaining an efficient drying of liquid droplets, and an efficient removal of gaseous pollutants.
According to one embodiment the spray dryer absorber comprises at least three dispersers, maximum two consecutive dispersers of said at least three dispersers, as seen along the periphery of the spray dryer chamber, being operative for providing the flue gas supplied thereto with a rotary movement in the same direction. An advantage of this embodiment is that adverse effects on the mixing between the process gas and the liquid droplets that might be caused by neighbouring dispersers providing the gas supplied thereto with the same direction of rotary movement is minimized. Preferably, when the total number of dispersers is even, such as in a spray dryer absorber with totally 4, 6 or 8 dispersers, each specific disperser provides the process gas supplied thereto with a direction of rotary movement which is opposite to the direction of rotary movement provided to the respective portions of process gas supplied to the closest neighbouring dispersers of that specific disperser. When the total number of dispersers is not even, such as a spray dryer absorber with totally 3, 5, 7, or 9 dispersers, the occurrences of two consecutive dispersers providing the process gas supplied thereto with the same direction of rotary movement is preferably minimized to have only one occurrence in that spray dryer absorber of two consecutive dispersers providing the process gas with the same direction of rotary movement.
According to one embodiment the spray dryer chamber is circular as seen from above. An advantage of this embodiment is that adverse effects related to flow of gas in corners of the absorber can be avoided. Furthermore, a circular spray dryer chamber makes it easier to locate the dispersers in suitable positions relative to each other, with respect to gas flow properties.
According to one embodiment the total number of dispersers is 2 to 9. Such a number has been found to provide a spray dryer absorber which is efficient both with respect to investment cost, and with respect to removal of gaseous pollutants.
A further object of the present invention is to provide a method of removing gaseous pollutants from large volumes of hot process gas by means of a spray dryer absorber, such method being more efficient with respect to investment cost and removal efficiency than the prior art methods.
This object is achieved by means of a method of removing gaseous pollutants from a hot process gas by means of a spray dryer absorber comprising a spray dryer chamber and at least two dispersers mounted at a roof of the spray dryer chamber, each such disperser being operative for dispersing a portion of the hot process gas around a respective atomizer which is operative for atomizing an absorption liquid, each disperser being provided with a flow directing device, which is operative for providing the respective portion of the hot process gas with a rotary movement around the atomizer, as seen from the top of the spray dryer chamber, the method being characterised in causing the respective portion of the hot process gas passing through at least one specific disperser of said at least two dispersers to obtain a rotary movement in a direction, which is opposite to the direction of the rotary movement of the respective portion of the hot process gas dispersed by at least one other disperser being located closest to said at least one specific disperser, as seen along the periphery of the spray dryer chamber.
An advantage of this method is that the risk of obtaining unwanted effects, such as the forming of large droplets, reduction of rotary movement, etc., is reduced in the areas where flow fields of dispersers being located adjacent to each other interact. This improves the efficiency of removing gaseous pollutants from the hot process gas and of drying the absorption liquid droplets.
According to one embodiment of the method said spray dryer absorber comprises at least three dispersers, maximum two consecutive dispersers of said at least three dispersers, as seen along the periphery of the spray dryer chamber, providing the flue gas supplied thereto with a rotary movement in the same direction.
Further objects and features of the present invention will be apparent from the description and the claims.
The invention will now be described in more detail with reference to the appended drawings in which:
a is a three-dimensional view of a spray dryer absorber in accordance with the prior art.
b is a top view of the spray dryer absorber of
a is a three-dimensional view of a spray dryer absorber in accordance with a first embodiment of the present invention.
b is a top view of the spray dryer absorber of
The flue gas, from which most of the dust particles have been removed, is forwarded to a spray dryer absorber 8 via a duct 10. The spray dryer absorber 8 comprises a spray dryer chamber 12 and four dispersers 14, 16, 18, 20 that are mounted at a roof 22 of the spray dryer chamber 12. Each disperser 14, 16, 18, 20 comprises an atomizer 24. The atomizers 24 could be of the so-called rotary atomizer type, in which a wheel spinning at a high velocity is operative for atomizing an absorption liquid. In this regard, reference may be had, by way of exemplification and not limitation, to, for example, the rotary atomizer described in U.S. Pat. No. 4,755,366, the teachings of which are hereby incorporated herein by virtue of this reference thereto. A further alternative is to utilize as the atomizers 24 atomizing nozzles which atomizes an absorption liquid which is supplied thereto under pressure.
Each disperser 14, 16, 18, 20 is provided with a flow directing device 26, 28, 30, 32. A dividing duct 34 is operative for supplying each of the dispersers 14, 16, 18, 20 with a portion of the flue gas, supplied via the duct 10. Each of the flow directing devices 26, 28, 30, 32 is operative for providing the respective portion of the flue gas with a rotary movement around the atomizer 24 of the respective disperser 14, 16, 18, 20. Two of the flow directing devices, namely the flow directing devices 26 and 30 of the dispersers 14, 18, are operative for providing the respective portion of the flue gas supplied thereto with a rotary movement around the respective atomizer 24 in the clockwise direction, as seen from the top of the spray dryer chamber 12. Two of the flow directing devices, namely the flow directing devices 28 and 32 of the dispersers 16, 20, are operative for providing the respective portion of the flue gas supplied thereto with a rotary movement around the respective atomizer 24 in the counter-clockwise direction, as seen from the top of the spray dryer chamber 12.
A tank 36 is operative for supplying each of the atomizers 24 with a flow of an absorption liquid, via a distributing pipe 38, such absorption liquid comprising, for example, a limestone slurry.
The action of the respective dispersers 14, 16, 18, 20 result in the mixing of flue gas with absorption liquid. The result is that the absorption liquid absorbs gaseous pollutants, such as sulphur dioxide, SO2, from the flue gas. At the same time the absorption liquid is dried by the hot flue gas, resulting in a dry end product being collected at the bottom 40 of the spray dryer chamber 12. The dry product is removed for disposal via a pipe 42. The flue gas, from which most of the gaseous pollutants are being removed, travels substantially vertically downwards from the dispersers 14, 16, 18, 20 in the spray dryer chamber 12 and leaves the spray dryer absorber 8 via a duct 44. The flue gas is forwarded, by means of the duct 44, to a second filter, which may, for example, be an electrostatic precipitator 46. As alternative the second filter may be a bag house or any other suitable filtering device. The second filter 46 removes most of the remaining dust particles, and any dried residues of the absorption liquid. A cleaned flue gas may then be admitted to the ambient air via a clean gas duct 48.
It will be appreciated that the disperser 20 will have a similar design as the disperser 16 illustrated in
a illustrates a spray dryer absorber 108 in accordance with a prior art design. This spray dryer absorber 108 has a spray dryer chamber 112 and a roof 122. At its roof 122, the spray dryer absorber 108 is provided with three dispersers 116. Each of those dispersers 116 will have a similar design as the disperser 16 described hereinbefore with reference to
b illustrates the spray dryer absorber 108 in accordance with the prior art design as seen from above. Since the three dispersers 116 each have a similar design as the disperser 16, illustrated hereinbefore with reference to
a illustrates the spray dryer absorber 8 in accordance with a first embodiment of the present invention, as previously illustrated with reference to
b illustrates the spray dryer absorber 8 as seen from above. As described hereinbefore, with reference to
Each of the dispersers 14, 16, 18, 20 is located at substantially the same distance D from the periphery P of the spray dryer chamber 12. Looking at the disperser 16, the flow directing device, denoted 50 and 52 and illustrated in detail in
As an example, at the point N1 where the dispersers 14 and 16 are located closest to each other, the flow fields from both dispersers 14, 16 will have the same direction. A similar flow behaviour will be present at the points N2, N3 and N4. Hence, for all four points N1, N2, N3, N4 where the flow fields of two adjacent dispersers 14, 16, 18, 20 may interact, the flow fields of those two dispersers will always have the same direction, contrary to the prior art design, illustrated in
The design illustrated in
Hence, with the design of
In
Trajectories T indicate the calculated paths of the liquid droplets for one second after leaving the respective atomizer 24 of the respective disperser 614 and 616, after which one second almost all of the liquid has been dried by the flue gas. As can be seen from
From
Furthermore, the prior art spray dryer absorber 108, having three dispersers 116 as illustrated in
Furthermore, calculations were also made for a prior art spray dryer absorber 708 having four dispersers. The prior art spray dryer absorber 708 is not illustrated in detail, but had a similar design as the spray dryer absorber 8 illustrated with reference to
Finally, the prior art spray dryer absorber 208, having five dispersers 216 as illustrated in
Hence, for each specific number of dispersers of a spray dryer absorber, it is surprisingly much better to arrange those dispersers in accordance with the principles of the present invention compared to arranging them according to the prior art, as regards the risk of aggregates forming on the walls of the spray dryer chamber.
It will be appreciated that numerous modifications of the embodiments described above are possible within the scope of the appended claims.
Above it has been described that a spray dryer absorber 8, 308, 408, 608 may be provided with 2, 3, 4 or 5 dispersers. It will be appreciated that the same effect could be achieved with other numbers of dispersers, being two or more, located at the same distance D from the periphery P of the spray dryer chamber 12. Typically, a spray dryer absorber designed in accordance with the present invention would be provided with 2 to 9 dispersers located at substantially the same distance D from the periphery P of the spray dryer chamber.
Above it has been described that in a spray dryer absorber having at least three dispersers, it is preferable that maximum two consecutive dispersers of those at least three dispersers are operative for providing the flue gas supplied thereto with a rotary movement in the same direction. Hence, in a spray dryer absorber having five dispersers and being designed in accordance with a further embodiment of the present invention it would be possible, as an example, to have four of these dispersers providing the gas with a counter-clockwise rotation, FCC, and just one disperser providing the gas with a clockwise rotation, FC, or, as a further example, to have three consecutive dispersers providing the gas with a counter-clockwise rotation, FCC, and two consecutive dispersers providing the gas with a clockwise rotation, FC. However, those alternative embodiments are generally less preferred than what is illustrated in
To summarize, a spray dryer absorber is operative for removing gaseous pollutants from a hot process gas and comprises at least two dispersers. Each such disperser is operative for dispersing a portion of the hot process gas around a respective atomizer, and for providing the respective portion of the hot process gas with a rotary movement around the atomizer. At least one specific disperser is operative for providing the hot process gas passing through that specific disperser with a rotary movement in a direction, which is opposite to the direction of the rotary movement of the respective portion of the hot process gas dispersed by at least one other disperser being located closest to that specific disperser.
While the invention has been described with reference to a number of preferred embodiments, it will be understood by those skilled in the art that various changes may be made and equivalents may be substituted for elements thereof without departing from the scope of the invention. In addition, many modifications may be made to adapt a particular situation or material to the teachings of the invention without departing from the essential scope thereof. Therefore, it is intended that the invention not be limited to the particular embodiments disclosed as the best mode contemplated for carrying out this invention, but that the invention will include all embodiments falling within the scope of the appended claims. Moreover, the use of the terms first, second, etc. do not denote any order or importance, but rather the terms first, second, etc. are used to distinguish one element from another.
Number | Date | Country | Kind |
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08151663.5 | Feb 2008 | EP | regional |
Filing Document | Filing Date | Country | Kind | 371c Date |
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PCT/EP09/00638 | 1/30/2009 | WO | 00 | 8/13/2010 |