Patent Application
20110016742
This application is based on the Provisional specification filed in relation to New Zealand Patent Application Number 550563, the entire contents of which are incorporated herein by reference.
The invention relates to improvements in spray freeze drying.
Spray freeze drying is discussed in the applicant's co-pending patent, NZ 529594/529595 (also published as WO 2005/105253) incorporated herein by reference. As mentioned in these specifications, freeze drying materials is well known in the art, for example to remove an aqueous component from a solid suspension leaving a dry solid which may have various uses such as for forming tablets and capsules.
In the applicants co-pending patent, methods and apparatus are described to produce a dried solid from a freeze dryer whereby the solid may be produced on a continuous basis. A key improvement in the previous apparatus and methods was to spray the inlet material and subsequent collection on a conveyed collection surface.
Further improvements on the methods and apparatus disclosed in the co-pending patent applications are now disclosed.
It is an object of the present invention to at least to provide the public with a useful choice.
All references, including any patents or patent applications cited in this specification are hereby incorporated by reference. No admission is made that any reference constitutes prior art. The discussion of the references states what their authors assert, and the applicants reserve the right to challenge the accuracy and pertinency of the cited documents. It will be clearly understood that, although a number of prior art publications are referred to herein, this reference does not constitute an admission that any of these documents form part of the common general knowledge in the art, in New Zealand or in any other country.
It is acknowledged that the term ‘comprise’ may, under varying jurisdictions, be attributed with either an exclusive or an inclusive meaning. For the purpose of this specification, and unless otherwise noted, the term ‘comprise’ shall have an inclusive meaning—i.e. that it will be taken to mean an inclusion of not only the listed components it directly references, but also other non-specified components or elements. This rationale will also be used when the term ‘comprised’ or ‘comprising’ is used in relation to one or more steps in a method or process.
Further aspects and advantages of the present invention will become apparent from the ensuing description which is given by way of example only.
According to a first aspect of the present invention there is provided an apparatus for drying or concentrating a raw material which at ambient conditions has a solid and aqueous portion including:
According to a further aspect of the present invention there is provided a method of drying or concentrating a raw material which at ambient conditions has a solid and an aqueous portion by the steps of:
Preferably, the thickness of the layer collected on the collection surface is also controlled by the rate of conveyance of the collection surface.
The inventors have found that several critical features are involved in forming a frozen layer on the collection surface beyond just the rate of conveyance. Forming a layer that is smooth, continuous and fine (termed for the purposes of this specification as a ‘monolayer’) is critical in achieving a uniformly dried product from the dryer. Preferably, the frozen layer on the collection surface is characterised by being smooth, continuous and a fine width. For the purposes of this specification, the term ‘fine width’ refers to the layer being less than 10 mm in width. In preferred embodiments, the width is less than 5 mm.
For the purposes of this disclosure and ease of reading, the collection surface may be referred to interchangeably as a conveyer belt. This should not be seen as limiting as other conveying methods such as those described in NZ 529594/529595 are also envisaged.
Preferably, the raw material is a solid suspended in or dissolved in the aqueous portion. More preferably, the raw material includes up to 50% solid material. Still more preferably, the raw material includes less than 30% solid material. As should be appreciated by those skilled in the art, these parameters equate to various dairy products such as milk to be dried, nutraceutical extracts and other products. It is envisaged that the raw material could also be a frozen solid material containing an aqueous portion. For example, the dryer assembly may be used for continuous drying of solid materials such as frozen vegetables. Further reference will be made to drying of solid/aqueous mixtures however this should not be seen as limiting.
Preferably, the raw material inlet flow rate is tailored to the collection surface size at a ratio of 1 kg/hour of raw material per 0.25 to 1.5 metres of collection surface width. As noted above, a key parameter found to achieve formation of a monolayer on the collection surface is use of an inlet rate tailored to the conveyer belt width. In one embodiment, the inlet rate is approximately 10 kg/hour of raw material to be dried on an approximately 0.5 m wide and 9 metre long conveyer belt. If the rate is increased above this level, product collected on the belt may be too thick to dry sufficiently and may also not fully freeze on formation of a monolayer resulting in small explosions as described further below.
A further key parameter found by the inventors is that the raw material is pumped into the vacuum chamber using a positive pressure rather than relying on the vacuum in the chamber alone to drive the dispersion of raw material into the chamber. In preferred embodiments, the back pressure ranges from approximately 20 to 40 psi. One problem noted by having insufficient back pressure is that discrete snow-like crystals are deposited on the conveyer belt surface rather than formation of a monolayer. The crystals also tend to blow around the chamber, not staying in one position (a monolayer) during drying.
The inventors have found that, once vacuum pressure and inlet pressure are stabilised, the inlet nozzle applies the raw material as a flat sheet monolayer on a continuous basis for hours at a time without need to adjust any parameters.
In preferred embodiments as described in NZ 529594/529595, the raw material is dispersed into the vacuum chamber using a nozzle or nozzles that atomise the raw material into small particles.
A further key parameter in achieving the desired size of particle as well as achieving a monolayer of material on the conveyer belt is nozzle selection. Preferably, the inlet nozzle or nozzles are selected based on injecting sufficient quantities of raw material such that:
It is the inventors' experience that atomiser nozzle choice is a critical variable. Preferred nozzle types are those that are relatively small and spray a half cone shaped arrangement. Full cone nozzle types may be used but the inlet flow of raw material must then be carefully regulated to ensure that liquid material does not become frozen under a solid cap on the conveyer belt resulting in sublimation and small explosions (see below). Nozzles are preferably sized to account for material viscosity. For example, materials with higher viscosity require larger nozzle sizes in order to ensure a smooth flow and full atomisation of the raw material.
A yet further key parameter in the inventors experience is the distance between the inlet nozzle and the collection surface. In preferred embodiments, the distance between the inlet nozzle or nozzles and the collection surface or surfaces varies from between 70 and 120 mm. In a particularly preferred embodiment, this distance is approximately 90 mm, although, it should be appreciated that this may vary depending on at least the raw material and nozzle configuration.
Preferably, the inlet nozzle or nozzles move across the collection surface during operation. In a preferred embodiment, the inlet nozzle is attached to a pivotal arm. Preferably, the arm is attached to an actuator which moves the arm through a pre-set course such that the inlet nozzle sprays an arc of raw material onto the collection surface. For the purposes of this specification, this arc pivot is referred to as a ‘swinging arm’. In one embodiment, a swinging arm is used to spray raw material onto a conveyer belt where the arc tracks the inlet nozzle across the width of the belt. In an alternative embodiment, multiple swinging arms are used on one belt to cover a belt surface and the swinging arms may be arranged in parallel beside each other or in series after each other. Whilst the above description is made with respect to a pivot producing a spray arc, other moving nozzle patterns are envisaged such as straight line back and forth patterns across the belt. An arc pattern should not be seen as limiting.
Preferably, the vacuum pressure in the chamber remains at an approximately steady level of less than or equal to 4.0 mbar. The inventors have found that the vacuum chamber must operate at a pressure below the triple point of the aqueous portion of the raw material to be separated from the solid material. In preferred embodiments, this pressure for water containing raw materials ranges from approximately 0.3 to 4.0 mbar.
In addition to the parameters discussed above, vacuum pressure has been found to be a key variable. For example, if the vacuum pressure is greater than 4 mbar, the raw material tends to fully freeze only after being collected on the conveyer belt. This is not desirable as uneven layer formation results and even small explosions may occur from trapped liquid under an outer solid cap subliming and flashing off breaking open the cap. Opportunities for product deterioration may also result from higher vacuum pressures delaying freezing.
A further factor found important by the inventors has been that it is important that the vacuum pressure remain at an approximately steady level and if changing, that the change occurs at a relatively slow rate. In preferred embodiments, any fluctuations in pressure in the vacuum chamber are less than 0.5 to 1.5 mbar above or below the set vacuum pressure. Fluctuations greater than this, particularly if they occur quickly, may result in uneven layering and potentially sublimation problems such as small explosions noted above.
In a further embodiment, particle size reducing devices may also be incorporated into the design of the dryer. In one preferred embodiment, the vacuum chamber includes a granulator to reduce the product particle size as the dried material leaves the conveyer belt. Preferably, the granulator is a rotor and cutter house configuration.
Preferably, the collection surface or surfaces is or are conveyer belt(s).
Preferably, the belt or belts include at least one inlet nozzle per belt.
In one embodiment, the raw material is injected onto a first upper most conveyer belt and through gravity, the material drops onto at least one further conveyer belt located underneath the first belt until being collected after being dried.
In preferred embodiments, the dryer includes at least two condensing chambers including coils onto which vaporised water or other aqueous substances condense so that in use, one chamber may be used in operation and the other chamber isolated from the vacuum chamber to allow alternate defrosting. It should be appreciated that by having two or more chambers, one chamber may be used in operation and the other chamber isolated from the vacuum chamber to allow alternate defrosting without disrupting processing.
According to a further aspect of the present invention there is provided a dried product produced using the apparatus substantially as described above.
According to a further aspect of the present invention there is provided a dried product produced by the method substantially as described above.
From the above description it should be appreciated that there are provided improved methods and apparatus for drying a raw material having a solid and aqueous portion. Key advantages from the method and apparatus include:
Further aspects of the present invention will become apparent from the ensuing description which is given by way of example only and with reference to the accompanying drawings in which:
Reference is made to the applicant's co-pending patent applications NZ 529594/529595 and WO 2005/105253 incorporated herein by reference for a detailed description of the method and apparatus. Alternative embodiments described above are now further described in more detail below.
Referring to
Raw material 3 is located in a tank T. In this embodiment the raw material contains less than 50% solids dispersed within an aqueous solution.
The raw material is pumped using inlet pump 17 via airlock valves 18A and inlet nozzle 10 into the vacuum chamber 2. The nozzle 10 disperses the raw material 3 as a fine spray and the evaporated portions 5A and 5B vaporises on entry to the chamber 2 and subsequently condenses out on condensing coils 6.
Frozen portion 4 is collected on a conveyer belt 8 as a fine monolayer of frozen material 7. The monolayer 7 is conveyed along the belt 8 and further evaporated portion 5A and 5B sublimes off the frozen portion 4 due to heating panels 11 underneath the belt 8. The dried material 12 is collected 18B via outlet airlock valve 14. A scraper device 13 may be used to remove dried material 12 from the belt 8.
The inventors have found that a critical step in achieving a dried product 12 is the production of a smooth monolayer 7 when the raw material 3 is sprayed into the chamber and collected on the belt 8.
Critical parameters in achieving this monolayer include the rate of conveyance of the belt 8 but also other parameters including the raw material 3 inlet rate; the use of positive pressure from the inlet pump(s) 18A; inlet nozzle 10 size and configuration; and the distance between the inlet nozzle 10 and conveyer belt 8.
In this example the inlet rate is approximately 10 kg/hour of inlet material 3 based on an approximately 9 metre long conveyer belt 8. If the inlet rate is increased above this level, the layer 7 collected on the belt 8 may be too thick to dry sufficiently and may also not fully freeze on forming of a monolayer 7 resulting in small explosions where liquid phase is trapped beneath a solid phase on the monolayer. This liquid phase subsequently boils off and explodes the upper solid layer.
In the example shown in
In the example shown in
In the embodiment shown in
To ensure formation of a smooth, continuous and fine monolayer on the belt 8, the vacuum pressure in the embodiment of
The chamber also includes a rotor and cutter house configuration granulator (not shown) inside the vacuum chamber 2, which reduces the particle size of the dried material 12 before it leaves the vacuum chamber 2.
Referring to
Referring to
In a further arrangement not shown, the condensing coils are located in one or more adjacent chambers. These chambers may be alternately sealed whereby one chamber may be operated and the other chamber isolated from the vacuum chamber to allow alternate defrosting and cleaning without disrupting processing.
From the above description it should be appreciated that there is provided improved methods and apparatus for drying a solid material containing an aqueous component with improved identification of critical parameters to assist in forming a smooth, continuous and fine layer on the collection surface. The fine layer results in effective drying.
Aspects of the present invention have been described by way of example only and it should be appreciated that modifications and additions may be made thereto without departing from the scope thereof as defined in the appended claims.
| Number | Date | Country | Kind |
|---|---|---|---|
| 550563 | Oct 2006 | NZ | national |
| Filing Document | Filing Date | Country | Kind | 371c Date |
|---|---|---|---|---|
| PCT/NZ07/00305 | 10/16/2007 | WO | 00 | 10/13/2010 |
