Spray texture material compositions, systems, and methods with accelerated dry times

Information

  • Patent Grant
  • 9382060
  • Patent Number
    9,382,060
  • Date Filed
    Tuesday, August 5, 2014
    10 years ago
  • Date Issued
    Tuesday, July 5, 2016
    8 years ago
Abstract
A system for dispensing texture material in an orange peel pattern has an aerosol dispenser and a contained material. The aerosol dispenser is a container assembly, a valve assembly, and an outlet assembly. The contained material is texture material and propellant material. The texture material is approximately 24-34% water, 4.1-6.1% latex binder, 48-58% fillers, and 4.8-8.8% drier accelerant by weight. The contained material comprises approximately 10-15% by weight of the propellant material. The outlet assembly alters the cross-sectional of the outlet opening to correspond to a desired orange peel texture pattern. The valve assembly allows the propellant material to force at least a portion of the texture material out of the outlet opening in a spray pattern corresponding to the desired orange peel texture pattern. The drier accelerant promotes drying of the dispensed texture material.
Description
TECHNICAL FIELD

The present invention relates to texture material compositions, systems, and methods and, more particularly, texture material compositions adapted to be dispensed using an aerosol dispensing system.


BACKGROUND

The surfaces of drywall materials defining wall and ceiling surfaces are commonly coated with texture materials. Texture materials are coatings that are deposited in discrete drops that dry to form a bumpy, irregular texture on the destination surface. Texture materials are commonly applied using a hopper gun connected to a source of pressurized air. However, when only a small area is to be coated or an existing textured surface is repaired, texture materials are typically applied using an aerosol dispensing system.


An aerosol dispensing system for dispensing texture material typically comprises a container assembly, a valve assembly, and an outlet assembly. The container assembly contains the texture material and a propellant material. The propellant material pressurizes the texture material within the container assembly. The valve assembly is mounted to the container assembly in a normally closed configuration but can be placed in an open configuration to define a dispensing path along which the pressurized texture material is forced out of the container assembly by the propellant material. Displacement of the outlet assembly places the valve assembly in the open configuration. The outlet assembly defines a portion of the outlet path and is configured such that the texture material is applied to the destination surface in an applied texture pattern.


The propellant used by aerosol dispensing systems for texture materials may simply be a compressed inert gas such as air or nitrogen. More typically, the propellant used by aerosol dispensing systems is a bi-phase propellant material, including mixtures of volatile hydrocarbons such as propane, n-butane, isobutane, dimethyl ether (DME), and methylethyl ether.


At room temperature, bi-phase propellant materials typically exist in both liquid and vapor states within the container assembly. Prior to use, the vapor portion of the bi-phase propellant material is pressurized to an equilibrium pressure. When the valve assembly is placed in its open configuration, the vapor portion of the bi-phase propellant material forces the texture material out of the container assembly along the dispensing path.


When the valve assembly returns to its closed position, part of the liquid portion of the bi-phase propellant material changes to the vapor state because of the drop in pressure within the container assembly. The vapor portion of the propellant material returns the pressure within the container assembly to the equilibrium value in preparation for the next time texture material is to be dispensed from the aerosol dispensing system.


The texture material dispensed by an aerosol dispensing system may employ a solvent base, a water base, or a base containing a combination of water and water soluble solvents. A solvent based texture material dries quickly but can be malodorous and may require the use of complementary solvent cleaners for clean up. A water based texture material is typically not malodorous and can be cleaned using water but can take significantly longer to dry. A water/solvent based texture material can be cleaned using water, is typically not unacceptably malodorous, and has a dry time somewhere between solvent based and water based texture materials.


The need exists for formulations of water/solvent based texture materials that may be used to form an orange peel texture pattern.


SUMMARY

The present invention may be embodied as a system for dispensing texture material in an orange peel pattern comprising an aerosol dispenser and a contained material. The aerosol dispenser comprises a container assembly formed at least in part of tin-plated steel, a valve assembly that controls flow of pressurized fluid out of the container assembly, and an outlet assembly that alters a cross-sectional area of an outlet opening through which pressurized fluid flowing out of the container assembly through the valve assembly passes. The contained material comprises texture material and propellant material. The texture material comprises by weight approximately 24-34% water, approximately 4.1-6.1% latex binder, approximately 48-58% fillers, and approximately 4.8-8.8% drier accelerant. The contained material comprises approximately 10-15% by weight of the propellant material. The contained material is disposed within the container assembly. The outlet assembly is operated to alter the cross-sectional of the outlet opening such that the cross-sectional area of the outlet opening corresponds to a desired orange peel texture pattern. The valve assembly is operated to allow the propellant material to force at least a portion of the texture material out of the outlet opening in a spray pattern corresponding to the desired orange peel texture pattern. The drier accelerant promotes drying of the dispensed texture material in the desired orange peel texture pattern.


The present invention may also be embodied as a method of dispensing texture material in an orange peel pattern comprising the following steps. An aerosol dispenser is provided. The aerosol dispenser comprises a container assembly formed at least in part of tin-plated steel, a valve assembly that controls flow of pressurized fluid out of the container assembly, and an outlet assembly that alters a cross-sectional area of an outlet opening through which pressurized fluid flowing out of the container assembly through the valve assembly passes. A contained material is formed by combining texture material and propellant material. The texture material comprises by weight approximately 24-34% water, approximately 4.1-6.1% latex binder, approximately 48-58% fillers, and approximately 4.8-8.8% drier accelerant. The contained material comprises approximately 10-15% by weight of the propellant material. The contained material is arranged within the container assembly. The outlet assembly is operated to alter the cross-sectional of the outlet opening such that the cross-sectional area of the outlet opening corresponds to a desired orange peel texture pattern. Operating the valve assembly to allow the propellant material to force at least a portion of the texture material out of the outlet opening in a spray pattern corresponding to the desired orange peel texture pattern such that the drier accelerant promotes drying of the dispensed texture material in the desired orange peel texture pattern.





BRIEF DESCRIPTION OF THE DRAWINGS


FIG. 1 is a section view of a first example aerosol dispensing system for texture material of the present invention; and



FIGS. 2A-2B are side elevation views depicting the process of using the aerosol dispensing system of FIG. 1 to apply texture material to a destination wall surface.





DETAILED DESCRIPTION

Referring initially to FIG. 1 of the drawing, depicted therein is an aerosol dispensing system 20 constructed in accordance with, and embodying, the principles of the present invention. The aerosol dispensing system 20 comprises a container assembly 22, a valve assembly 24, and an outlet assembly 26. The container assembly 22 and valve assembly 24 define a main chamber 28.


The main chamber 28 contains a liquid material 30 and a vapor material 32. The liquid material 30 comprises propellant material in liquid form and an orange peel texture material concentrate. The vapor material 32 comprises propellant material in vapor form. The combination of the liquid material 30 and the vapor material 32 in the container assembly 22 will be referred to as the contained material 34.


When the valve assembly 24 is in a closed configuration, the flow of fluid out of the main chamber 28 is substantially prevented. However, the vapor material 32 pressurizes the liquid material 30 within the main chamber 28 such that, when the valve assembly 24 is in an open configuration, the vapor material 32 forces the liquid material 30 out of the main chamber 28.


As perhaps best shown in FIG. 1, the example container assembly 22 comprises a main member 40, a bottom cap 42, and an end cap 44 formed of tin-plated steel. The tin-plated steel used to form the main member 40, bottom cap 42, and end cap 44 comprises a thin sheet of steel coated on one side by an even thinner layer (approximately 0.5 microns) of tin.


The main member 40 is a rectangular sheet that is rolled into a cylinder and welded along a seam 50 to define first and second end openings 52 and 54. The bottom cap 42 is a shaped tin-plated steel member that is crimped onto the cylindrical main member 40 to seal the first end opening 52. The end cap 44 is also a shaped tin-plated steel member defining a mounting opening 56; the end cap 44 is crimped onto the main member 40 such that fluid may not flow through the second opening 54 between the end cap 44 and the main member 40. The main member 40, bottom cap 42, and end cap 44 define an interior metal surface 58 of the container assembly 22.


With the bottom cap 42 covering the first opening 52, the end cap 44 covering the second opening 54, and the valve assembly 24 supported by the end cap 44, the aerosol dispensing system 20 defines the main chamber 28.


Alternatively, the container assembly 22 may be made of aluminum, in which case the bottom cap portion and the end cap portion may be integrally formed with the main member portion.


The example texture material concentrate is generally formulated as follows.












EXAMPLE OF ORANGE PEEL TEXTURE MATERIAL


CONCENTRATE












FIRST
SECOND



FIRST
PREFERRED
PREFERRED


COMPONENT
EXAMPLE
RANGE
RANGE





solvent/carrier (water)
29.28%
24-34%
19-39%


resin/binder (latex)
 5.13%
4.1-6.1%
 2-10%


fillers (cellulosic
53.09%
48-58%
43-63%


thickener, clay, talc,





calcium carbonate)





additives (biocide,
 0.53%
0.2-1.0%
0-3%


dispersant, defoamer)





drier accelerant
 6.79%
4.8-8.8%
 2-12%


(isopropyl alcohol)









The texture material concentrate described in the table set forth above is combined in the container assembly 22 with the propellant material to obtain the contained material 34. The preferred amount of propellant material used to form the example dispensing system 20 is approximately 12.6% of the texture material concentrate by weight and is preferably within a first preferred range of substantially between 10% and 15% and is in any event preferably within a second preferred range of substantially between 5% and 20%. The propellant material is typically dimethyl ether (DME).


The solvent/carrier of the example formulation set forth in the table above is water. The resin/binder is or may be a conventional latex binder. The fillers may comprise any conventional pigments, extenders, and thickeners. If used, the additives forming part of the formulation described in the table set forth above typically comprise conventional biocides, dispersants, and defoamers.


The drier accelerant may be any water soluble solvent such as such as tetrahydrofuran, acetone, methanol, iso-propanol, ethanol, N-propanol, propylene glycol monomethylether, propylene glycol n-propyl ether, diethylene glycol monomethyl ether, diacetone alcohol, ethylene glycol monobutyl ether, N-methyl pyrrolidone, dipropylene glycol methyl ether, diethanolamine, diethylene glycol monoethyl ether, diethylene glycol, methyl ethyl ketone, and methyl acetate.


In the context of the example container assembly 22 comprising tin-plated steel components, the texture material concentrate may be formulated to have anti-corrosion properties. In this case, the texture material concentrate may further comprise first and second anti-corrosion materials are included to promote passive corrosion behavior of the metal interior surface 58 of the container assembly 22 in contact with the texture material concentrate. Passive corrosion behavior occurs when the interaction between a metal structure and the environment forms a thin protective film on the surface of the metal structure. Passive corrosion produces essentially no corrosion of the metal structure and thus is very desirable.


In the example texture material concentrate, the first anti-corrosion material is an aninonic, phosphate ester. The example first anti-corrosion material is Elfugin, a proprietary product sold by Clariant Paper Chemicals as an antistatic for application to paper products. In the general example described above, approximately 1.00% (±5%) of the first anti-corrosion material is preferably used. The second anti-corrosion material of the example texture material concentrate is sodium nitrite. In the general example described above, approximately 0.100% (±5%) or 0.250% (±5%) of the first anti-corrosion material is preferably used, depending upon the nature of the remaining components of the texture material concentrate and propellant.


Generally speaking, the first anti-corrosion material should be within a first preferred range of substantially between 0.5% and 2% and in any event should be within a second preferred range of substantially between 0.1 and 5.0%. The second anti-corrosion material should be within a first preferred range of substantially between 0.05% and 1.0% and in any event should be within a second preferred range of substantially between 0.025% and 2.0%. The amount of water set forth in the foregoing table should be reduced by the amount of the first and second anti-corrosion materials used.


If the anti-corrosion materials are used, the texture material concentrate is preferably formulated and combined with propellant material as follows. The first and second anti-corrosion materials are initially dissolved in the water. The remaining materials are then mixed with the water solution to obtain the texture material concentrate.


If the container assembly is formed of tin-plated steel, the bottom cap 42 is crimped onto the main member 40 to form a container subassembly 22a. The valve assembly 24 is combined with the end cap 44 to form a cap subassembly 22b. The texture material concentrate is placed within the container subassembly 22a. The cap subassembly 22b is crimped onto the container subassembly 22a to form the container assembly 22. The propellant material is then introduced into the container assembly 22 through the valve assembly 24. The outlet assembly 26 is then engaged with the valve assembly to form the aerosol dispensing system 20.


With the foregoing general understanding of the present invention, the details of several example formulations of the texture material concentrate and the construction and use of the example aerosol dispensing system 20 will now be described in further detail with reference to FIG. 1.


The example valve assembly 24 comprises a valve housing 60, a valve seat 62, a valve member 64, and a valve spring 66. The end cap 44 supports the valve housing 60 and the valve seat 62 adjacent to the mounting opening 56. The valve housing 60 supports the valve spring 66 such that the valve spring 66 biases the valve member 64 against the valve seat 62 in a normally closed position. An intake tube 68 extends from the valve housing 60 to the end of the main member 40 closed by the bottom cap 42.


The outlet assembly 26 comprises an actuator member 70, a resilient member 72, and a clamp member 74. The actuator member defines a stem portion 76 and a plurality of finger portions 78. The stem portion 76 extends through the mounting opening 56 and engages the valve member 64. The actuator member 70 supports the resilient member 72 such that the resilient member 72 is held within the finger portions 78. The clamp member 74 engages the actuator member 70 such that displacement of the clamp member 74 relative to the actuator member 70 bends the finger portions 78 towards each other to deform the resilient member 72.


A dispensing path 80 extends between an inlet opening 82 defined by the intake tube 68 and an outlet opening 84 defined by the resilient member 72. Fluid is prevented from flowing along the dispensing path 80 when the valve assembly 24 is in the closed configuration as defined above. Fluid may flow along the dispensing path 80 when the valve assembly 24 is in the open configuration. The spray pattern of liquid flowing out of the main chamber 28 through the outlet opening 84 may be varied by deforming the resilient member 72 as described above.


More specifically, the valve spring 66 normally biases the valve member 64 against the valve seat 62 to close the dispensing path 80. When the actuator member 70 is displaced towards the container assembly 22, the valve member 64 is displaced away from the valve seat 62 against the force of the valve spring 66 to place the valve assembly 24 in its open configuration. In this open configuration, the example dispensing path 80 extends through a first passageway 90 defined by the intake tube 68, a valve chamber 92 defined by the valve housing 60, a gap 94 between valve member 64 and the valve seat 62, a second passageway 96 defined by the actuator member 70, and a third passageway 98 defined by the resilient member 72.


Turning now to FIGS. 2A-2B of the drawing, depicted therein is an example of use of the example dispensing system 20 described above. The example dispensing system 20 is used to apply texture material to a wall member 120 defining a target surface portion 122. In the case of a repair to the wall member 120, existing spray texture material 124 typically surrounds the target surface portion 122.


Initially, the dispensing system 20 is arranged such that the outlet opening 84 faces the target surface portion 122. The actuator member 70 is then displaced to place the valve assembly 24 in its open configuration. The pressurized propellant material causes a portion of the contained material 34 to be dispensed from the container assembly 22 through the dispensing path 80.


Because of the formulation of the contained material 34 and the geometry of the resilient member 72, the contained material exits the container assembly 22 in a spray 130 comprising discrete droplets 132. The droplets 132 are deposited onto the target surface 122 to form a texture coating 134 in an applied texture pattern. The texture coating 134 is initially wet but dries when exposed to air.


By appropriately selecting the cross-sectional area of the outlet opening 84, the applied texture pattern of the texture coating 134 can be formed such that the applied texture pattern substantially matches the existing pattern of the existing texture material 124.


In the example dispensing system 20 described above, the outlet opening 84 is varied using the collar 74 to deform the fingers 78 and thus the resilient member 72. Alternatively, the outlet opening of the dispensing system 20 may be varied using any of the structures described, for example, in U.S. Pat. No. 6,536,633, and the teachings of that patent are incorporated herein by reference.


The scope of the present invention should be determined by the claims appended hereto and not the foregoing detailed description of the invention.

Claims
  • 1. A system for dispensing texture material in an orange peel pattern, comprising: an aerosol dispenser comprising a container assembly formed at least in part of tin-plated steel,a valve assembly that controls flow of pressurized fluid out of the container assembly, andan outlet assembly that alters a cross-sectional area of an outlet opening through which pressurized fluid flowing out of the container assembly through the valve assembly passes;a contained material comprising texture material, where the texture material comprises by weight approximately 24-34% water,approximately 4.1-6.1% latex binder,approximately 48-58% fillers, andapproximately 4.8-8.8% drier accelerant;a propellant material, where the contained material comprises approximately 10-15% by weight of the propellant material;whereinthe contained material is disposed within the container assembly;the outlet assembly is operated to alter the cross-sectional of the outlet opening such that the cross-sectional area of the outlet opening corresponds to a desired orange peel texture pattern;the valve assembly is operated to allow the propellant material to force at least a portion of the texture material out of the outlet opening in a spray pattern corresponding to the desired orange peel texture pattern; andthe drier accelerant promotes drying of the dispensed texture material in the desired orange peel texture pattern.
  • 2. A system as recited in claim 1, in which the drier accelerant comprises at least one material selected from the group of materials comprising tetrahydrofuran, acetone, methanol, iso-propanol, ethanol, N-propanol, propylene glycol monomethylether, propylene glycol n-propyl ether, diethylene glycol monomethyl ether, diacetone alcohol, ethylene glycol monobutyl ether, N-methyl pyrrolidone, dipropylene glycol methyl ether, diethanolamine, diethylene glycol monoethyl ether, diethylene glycol, methyl ethyl ketone, and methyl acetate.
  • 3. A system as recited in claim 1, further comprising: a first anti-corrosion material; anda second anti-corrosion material; whereinthe amount of the first anti-corrosion material is selected with respect to the second anti-corrosion material to promote formation of a thin protective film on any portion of the container assembly made of tin-plated steel.
  • 4. A system as recited in claim 3, in which: the first anti-corrosion material comprises approximately 0.1-5% by weight of the texture material, where the first anti-corrosion material is a phosphate ester, anda second anti-corrosion material comprises approximately 0.025-2.0% by weight of the texture material, where the second anti-corrosion material is sodium nitrite.
  • 5. A system as recited in claim 1, further comprising at least one additive selected from the group of additives consisting of a biocide, a defoamer, and a dispersant.
  • 6. A method dispensing texture material in an orange peel pattern, comprising the steps of: an aerosol dispenser comprising a container assembly formed at least in part of tin-plated steel,a valve assembly that controls flow of pressurized fluid out of the container assembly, andan outlet assembly that alters a cross-sectional area of an outlet opening through which pressurized fluid flowing out of the container assembly through the valve assembly passes;forming a contained material by combining texture material, where the texture material comprises by weight approximately 24-34% water,approximately 4.1-6.1% latex binder,approximately 48-58% fillers, andapproximately 4.8-8.8% drier accelerant; anda propellant material, where the contained material comprises approximately 10-15% by weight of the propellant material;whereinarranging the contained material within the container assembly;operating the outlet assembly to alter the cross-sectional of the outlet opening such that the cross-sectional area of the outlet opening corresponds to a desired orange peel texture pattern;operating the valve assembly to allow the propellant material to force at least a portion of the texture material out of the outlet opening in a spray pattern corresponding to the desired orange peel texture pattern such that the drier accelerant promotes drying of the dispensed texture material in the desired orange peel texture pattern.
  • 7. A method as recited in claim 6, in which the step of forming the texture material comprises the step of selecting at least one material from the group of materials comprising tetrahydrofuran, acetone, methanol, iso-propanol, ethanol, N-propanol, propylene glycol monomethylether, propylene glycol n-propyl ether, diethylene glycol monomethyl ether, diacetone alcohol, ethylene glycol monobutyl ether, N-methyl pyrrolidone, dipropylene glycol methyl ether, diethanolamine, diethylene glycol monoethyl ether, diethylene glycol, methyl ethyl ketone, and methyl acetate to form the drier accelerant.
  • 8. A method as recited in claim 6, in which the step of forming the contained material further comprises the steps of: adding first and second anti-corrosion materials to the texture material; andselecting amounts of the first and second anti-corrosion material with respect to each other such that the first and second anti-corrosion materials form a thin protective film on any portion of the container assembly made of tin-plated steel.
  • 9. A method as recited in claim 8, in which: the first anti-corrosion material comprises approximately 0.1-5% by weight of the texture material, where the first anti-corrosion material is a phosphate ester, anda second anti-corrosion material comprises approximately 0.025-2.0% by weight of the texture material, where the second anti-corrosion material is sodium nitrite.
  • 10. A method as recited in claim 6, further comprising the steps of: selecting at least one additive selected from the group of additives consisting of a biocide, a defoamer, and a dispersant; andadding the at least one selected additive to the texture material.
RELATED APPLICATIONS

This application is a continuation of U.S. patent application Ser. No. 13/562,033 filed Jul. 30, 2012, currently pending. U.S. patent application Ser. No. 13/562,033 is a continuation of U.S. patent application Ser. No. 12/080,671 filed Apr. 4, 2008, now abandoned. U.S. patent application Ser. No. 12/080,671 claims benefit of U.S. Provisional Patent Application Ser. No. 60/922,117 filed Apr. 5, 2007. The contents of all related applications are incorporated herein by reference.

US Referenced Citations (517)
Number Name Date Kind
208330 Palmer Sep 1878 A
351968 Derrick Nov 1886 A
D25916 Woods Aug 1896 S
568876 Regan Oct 1896 A
579418 Bookwalter Mar 1897 A
582397 Shone May 1897 A
658586 Reiling Sep 1900 A
930095 Seagrave Aug 1909 A
931757 Harmer Aug 1909 A
941671 Campbell Nov 1909 A
1093907 Birnbaum Apr 1914 A
1154974 Custer Sep 1915 A
1486156 Needham Mar 1924 A
2127188 Schellin et al. Aug 1938 A
2149930 Plastaras Mar 1939 A
D134562 Murphy Dec 1942 S
2307014 Becker et al. Jan 1943 A
2320964 Yates Jun 1943 A
2353318 Scheller Jul 1944 A
2388093 Smith Oct 1945 A
2530808 Cerasi Nov 1950 A
2565954 Dey Aug 1951 A
2612293 Michel Sep 1952 A
2686652 Carlson et al. Aug 1954 A
2723200 Pyenson Nov 1955 A
2763406 Countryman Sep 1956 A
2764454 Edelstein Sep 1956 A
2785926 Lataste Mar 1957 A
2790680 Rosholt Apr 1957 A
2831618 Soffer et al. Apr 1958 A
2839225 Soffer et al. Jun 1958 A
2908446 Strouse Oct 1959 A
2932434 Abplanalp Apr 1960 A
2965270 Soffer et al. Dec 1960 A
2968441 Holcomb Jan 1961 A
2976897 Beckworth Mar 1961 A
2997243 Kolb Aug 1961 A
3083872 Meshberg Apr 1963 A
3107059 Frechette Oct 1963 A
3167525 Thomas Jan 1965 A
3191809 Schultz et al. Jun 1965 A
3196819 Lechner et al. Jul 1965 A
3198394 Lefer Aug 1965 A
3216628 Fergusson Nov 1965 A
3246850 Bourke Apr 1966 A
3258208 Greenebaum, II Jun 1966 A
3284007 Clapp Nov 1966 A
3314571 Greenebaum, II Apr 1967 A
3317140 Smith May 1967 A
3342382 Huling Sep 1967 A
3346195 Groth Oct 1967 A
3373908 Crowell Mar 1968 A
3377028 Bruggeman Apr 1968 A
3390121 Burford Jun 1968 A
3405845 Cook et al. Oct 1968 A
3414171 Grisham et al. Dec 1968 A
3415425 Knight et al. Dec 1968 A
3425600 Abplanalp Feb 1969 A
3428224 Eberhardt et al. Feb 1969 A
3433391 Krizka et al. Mar 1969 A
3450314 Gross Jun 1969 A
3467283 Kinnavy Sep 1969 A
3472457 McAvoy Oct 1969 A
3482738 Bartels Dec 1969 A
3513886 Easter et al. May 1970 A
3514042 Freed May 1970 A
3544258 Presant et al. Dec 1970 A
3548564 Bruce et al. Dec 1970 A
3550861 Teson Dec 1970 A
3575319 Safianoff Apr 1971 A
3592359 Marraffino Jul 1971 A
3596835 Smith et al. Aug 1971 A
3608822 Berthoud Sep 1971 A
3613954 Bayne Oct 1971 A
3648932 Ewald et al. Mar 1972 A
3653558 Shay Apr 1972 A
3698645 Coffey Oct 1972 A
3700136 Ruekberg Oct 1972 A
3703994 Nigro Nov 1972 A
3704811 Harden, Jr. Dec 1972 A
3704831 Clark Dec 1972 A
3705669 Cox et al. Dec 1972 A
3711030 Jones Jan 1973 A
3764067 Coffey et al. Oct 1973 A
3770166 Marand Nov 1973 A
3773706 Dunn, Jr. Nov 1973 A
3776470 Tsuchiya Dec 1973 A
3776702 Chant Dec 1973 A
3777981 Probst et al. Dec 1973 A
3788521 Laauwe Jan 1974 A
3795366 McGhie et al. Mar 1974 A
3799398 Morane et al. Mar 1974 A
3806005 Prussin et al. Apr 1974 A
3811369 Ruegg May 1974 A
3813011 Harrison et al. May 1974 A
3814326 Bartlett Jun 1974 A
3819119 Coffey et al. Jun 1974 A
3828977 Borchert Aug 1974 A
3848778 Meshberg Nov 1974 A
3862705 Beres et al. Jan 1975 A
3871553 Steinberg Mar 1975 A
3891128 Smrt Jun 1975 A
3912132 Stevens Oct 1975 A
3913803 Laauwe Oct 1975 A
3913804 Laauwe Oct 1975 A
3913842 Singer Oct 1975 A
3932973 Moore Jan 1976 A
3936002 Geberth, Jr. Feb 1976 A
3938708 Burger Feb 1976 A
3975554 Kummins et al. Aug 1976 A
3982698 Anderson Sep 1976 A
3989165 Shaw et al. Nov 1976 A
3991916 Del Bon Nov 1976 A
3992003 Visceglia et al. Nov 1976 A
4010134 Braunisch et al. Mar 1977 A
4032064 Giggard Jun 1977 A
4036673 Murphy et al. Jul 1977 A
4045860 Winckler Sep 1977 A
4089443 Zrinyi May 1978 A
4096974 Haber et al. Jun 1978 A
4117951 Winckler Oct 1978 A
4129448 Greenfield et al. Dec 1978 A
4147284 Mizzi Apr 1979 A
4148416 Gunn-Smith Apr 1979 A
4154378 Paoletti et al. May 1979 A
4164492 Cooper Aug 1979 A
RE30093 Burger Sep 1979 E
4171757 Diamond Oct 1979 A
4173558 Beck Nov 1979 A
4185758 Giggard Jan 1980 A
4187959 Pelton Feb 1980 A
4187985 Goth Feb 1980 A
4198365 Pelton Apr 1980 A
4202470 Fujii May 1980 A
4238264 Pelton Dec 1980 A
4240940 Vasishth et al. Dec 1980 A
4258141 Jarre et al. Mar 1981 A
4275172 Barth et al. Jun 1981 A
4293353 Pelton et al. Oct 1981 A
4308973 Irland Jan 1982 A
4310108 Motoyama et al. Jan 1982 A
4322020 Stone Mar 1982 A
4346743 Miller Aug 1982 A
4354638 Weinstein Oct 1982 A
4358388 Daniel et al. Nov 1982 A
4370930 Strasser et al. Feb 1983 A
4372475 Goforth et al. Feb 1983 A
4401271 Hansen Aug 1983 A
4401272 Merton et al. Aug 1983 A
4411387 Stern et al. Oct 1983 A
4417674 Giuffredi Nov 1983 A
4420575 Rapaport Dec 1983 A
4438221 Fracalossi et al. Mar 1984 A
4442959 Del Bon et al. Apr 1984 A
4460719 Danville Jul 1984 A
4482662 Rapaport et al. Nov 1984 A
4496081 Farrey Jan 1985 A
4546905 Nandagiri et al. Oct 1985 A
4595127 Stoody Jun 1986 A
4609608 Solc Sep 1986 A
4641765 Diamond Feb 1987 A
4683246 Davis et al. Jul 1987 A
4702400 Corbett Oct 1987 A
4728007 Samuelson et al. Mar 1988 A
4744495 Warby May 1988 A
4761312 Koshi et al. Aug 1988 A
4792062 Goncalves Dec 1988 A
4793162 Emmons Dec 1988 A
4804144 Denman Feb 1989 A
4815414 Duffy et al. Mar 1989 A
4819838 Hart, Jr. Apr 1989 A
4830224 Brison May 1989 A
4839393 Buchanan et al. Jun 1989 A
4854482 Bergner Aug 1989 A
4870805 Morane Oct 1989 A
4878599 Greenway Nov 1989 A
4887651 Santiago Dec 1989 A
4893730 Bolduc Jan 1990 A
4896832 Howlett Jan 1990 A
D307649 Henry May 1990 S
4940171 Gilroy Jul 1990 A
4948054 Mills Aug 1990 A
4949871 Flanner Aug 1990 A
4951876 Mills Aug 1990 A
4953759 Schmidt Sep 1990 A
4954544 Chandaria Sep 1990 A
4955545 Stern et al. Sep 1990 A
4961537 Stern Oct 1990 A
4969577 Werding Nov 1990 A
4969579 Behar Nov 1990 A
4988017 Schrader et al. Jan 1991 A
4991750 Moral Feb 1991 A
5007556 Lover Apr 1991 A
5009390 McAuliffe, Jr. et al. Apr 1991 A
5037011 Woods Aug 1991 A
5038964 Bouix Aug 1991 A
5052585 Bolduc Oct 1991 A
5059187 Sperry et al. Oct 1991 A
5065900 Scheindel Nov 1991 A
5069390 Stern et al. Dec 1991 A
5083685 Amemiya et al. Jan 1992 A
5100055 Rokitenetz et al. Mar 1992 A
5115944 Nikolich May 1992 A
5126086 Stoffel Jun 1992 A
5169037 Davies et al. Dec 1992 A
5182316 DeVoe et al. Jan 1993 A
5188263 Woods Feb 1993 A
5188295 Stern et al. Feb 1993 A
5211317 Diamond et al. May 1993 A
5219609 Owens Jun 1993 A
5250599 Swartz Oct 1993 A
5277336 Youel Jan 1994 A
5297704 Stollmeyer Mar 1994 A
5307964 Toth May 1994 A
5310095 Stern et al. May 1994 A
5312888 Nafziger et al. May 1994 A
5314097 Smrt et al. May 1994 A
5323963 Ballu Jun 1994 A
5341970 Woods Aug 1994 A
5342597 Tunison, III Aug 1994 A
5368207 Cruysberghs Nov 1994 A
5374434 Clapp et al. Dec 1994 A
5405051 Miskell Apr 1995 A
5409148 Stern et al. Apr 1995 A
5417357 Yquel May 1995 A
D358989 Woods Jun 1995 S
5421519 Woods Jun 1995 A
5425824 Marwick Jun 1995 A
5450983 Stern et al. Sep 1995 A
5467902 Yquel Nov 1995 A
5476879 Woods et al. Dec 1995 A
5489048 Stern et al. Feb 1996 A
5498282 Miller et al. Mar 1996 A
5501375 Nilson Mar 1996 A
5505344 Woods Apr 1996 A
5523798 Hagino et al. Jun 1996 A
5524798 Stern et al. Jun 1996 A
5544783 Conigliaro Aug 1996 A
5548010 Franer Aug 1996 A
5549228 Brown Aug 1996 A
5558247 Caso Sep 1996 A
5562235 Cruysberghs Oct 1996 A
5570813 Clark, II Nov 1996 A
5573137 Pauls Nov 1996 A
5583178 Oxman et al. Dec 1996 A
5597095 Ferrara, Jr. Jan 1997 A
5615804 Brown Apr 1997 A
5639026 Woods Jun 1997 A
5641095 de Laforcade Jun 1997 A
5645198 Stern et al. Jul 1997 A
5655691 Stern et al. Aug 1997 A
5695788 Woods Dec 1997 A
5715975 Stern et al. Feb 1998 A
5727736 Tryon Mar 1998 A
5752631 Yabuno et al. May 1998 A
5775432 Burns et al. Jul 1998 A
5792465 Hagarty Aug 1998 A
5799879 Ottl et al. Sep 1998 A
5865351 De Laforcade Feb 1999 A
5868286 Mascitelli Feb 1999 A
5887756 Brown Mar 1999 A
5894964 Barnes et al. Apr 1999 A
5915598 Yazawa et al. Jun 1999 A
5921446 Stern Jul 1999 A
5934518 Stern et al. Aug 1999 A
5941462 Sandor Aug 1999 A
5957333 Losenno et al. Sep 1999 A
5975356 Yquel et al. Nov 1999 A
5988575 Lesko Nov 1999 A
6000583 Stern et al. Dec 1999 A
6027042 Smith Feb 2000 A
6032830 Brown Mar 2000 A
6039306 Pericard et al. Mar 2000 A
6062494 Mills May 2000 A
6070770 Tada et al. Jun 2000 A
6092698 Bayer Jul 2000 A
6095435 Greer, Jr. et al. Aug 2000 A
6112945 Woods Sep 2000 A
6113070 Holzboog Sep 2000 A
6116473 Stern et al. Sep 2000 A
6129247 Thomas et al. Oct 2000 A
6131777 Warby Oct 2000 A
6139821 Fuerst et al. Oct 2000 A
6152335 Stern et al. Nov 2000 A
6161735 Uchiyama et al. Dec 2000 A
6168093 Greer, Jr. et al. Jan 2001 B1
6170717 Di Giovanni et al. Jan 2001 B1
D438111 Woods Feb 2001 S
D438786 Ghali Mar 2001 S
6225393 Woods May 2001 B1
6254015 Abplanalp Jul 2001 B1
6257503 Baudin Jul 2001 B1
6261631 Lomasney et al. Jul 2001 B1
6265459 Mahoney et al. Jul 2001 B1
6276570 Stern et al. Aug 2001 B1
6283171 Blake Sep 2001 B1
6284077 Lucas et al. Sep 2001 B1
6290104 Bougamont et al. Sep 2001 B1
6291536 Taylor Sep 2001 B1
6296155 Smith Oct 2001 B1
6296156 Lasserre et al. Oct 2001 B1
6299679 Montoya Oct 2001 B1
6299686 Mills Oct 2001 B1
6315152 Kalisz Nov 2001 B1
6325256 Liljeqvist et al. Dec 2001 B1
6328185 Stern et al. Dec 2001 B1
6328197 Gapihan Dec 2001 B1
6333365 Lucas et al. Dec 2001 B1
6352184 Stern et al. Mar 2002 B1
6362302 Boddie Mar 2002 B1
6375036 Woods Apr 2002 B1
6382474 Woods et al. May 2002 B1
6386402 Woods May 2002 B1
6394321 Bayer May 2002 B1
6394364 Abplanalp May 2002 B1
6395794 Lucas et al. May 2002 B2
6398082 Clark et al. Jun 2002 B2
6399687 Woods Jun 2002 B2
6414044 Taylor Jul 2002 B2
6415964 Woods Jul 2002 B2
6439430 Gilroy, Sr. et al. Aug 2002 B1
6446842 Stern et al. Sep 2002 B2
D464395 Huang Oct 2002 S
6474513 Burt Nov 2002 B2
6478198 Haroian Nov 2002 B2
6478561 Braun et al. Nov 2002 B2
6482392 Zhou et al. Nov 2002 B1
D468980 Woods Jan 2003 S
6510969 Di Giovanni et al. Jan 2003 B2
6520377 Yquel Feb 2003 B2
6531528 Kurp Mar 2003 B1
6536633 Stern et al. Mar 2003 B2
6581807 Mekata Jun 2003 B1
6588628 Abplanalp et al. Jul 2003 B2
6595393 Loghman-Adham et al. Jul 2003 B1
6613186 Johnson Sep 2003 B2
6615827 Greenwood et al. Sep 2003 B2
6637627 Liljeqvist et al. Oct 2003 B1
6641005 Stern et al. Nov 2003 B1
6641864 Woods Nov 2003 B2
6652704 Green Nov 2003 B2
6659312 Stern et al. Dec 2003 B1
6666352 Woods Dec 2003 B1
6688492 Jaworski et al. Feb 2004 B2
6712238 Mills Mar 2004 B1
6726066 Woods Apr 2004 B2
6736288 Green May 2004 B1
6758373 Jackson et al. Jul 2004 B2
6797051 Woods Sep 2004 B2
6802461 Schneider Oct 2004 B2
6831110 Ingold et al. Dec 2004 B2
6832704 Smith Dec 2004 B2
6837396 Jaworski et al. Jan 2005 B2
6843392 Walker Jan 2005 B1
D501538 Zeng Feb 2005 S
D501914 Chen Feb 2005 S
6848601 Greer, Jr. Feb 2005 B2
6851575 van't Hoff Feb 2005 B2
D502533 Chen Mar 2005 S
6880733 Park Apr 2005 B2
6883688 Stern et al. Apr 2005 B1
6894095 Russo et al. May 2005 B2
6905050 Stern et al. Jun 2005 B1
6910608 Greer, Jr. et al. Jun 2005 B2
6913407 Greer et al. Jul 2005 B2
6926178 Anderson Aug 2005 B1
6929154 Grey et al. Aug 2005 B2
6932244 Meshberg Aug 2005 B2
6966467 Di Giovanni et al. Nov 2005 B2
D512309 Geier Dec 2005 S
6971353 Heinze et al. Dec 2005 B2
6971553 Brennan et al. Dec 2005 B2
6978916 Smith Dec 2005 B2
6978947 Jin Dec 2005 B2
6981616 Loghman-Adham et al. Jan 2006 B2
7014073 Stern et al. Mar 2006 B1
7014127 Valpey, III et al. Mar 2006 B2
7036685 Green May 2006 B1
7045008 Langford May 2006 B2
7059497 Woods Jun 2006 B2
7059546 Ogata et al. Jun 2006 B2
7063236 Greer, Jr. et al. Jun 2006 B2
7104424 Kolanus Sep 2006 B2
7104427 Pericard Sep 2006 B2
7121434 Caruso Oct 2006 B1
7163962 Woods Jan 2007 B2
7182227 Poile et al. Feb 2007 B2
7189022 Greer, Jr. et al. Mar 2007 B1
7192985 Woods Mar 2007 B2
7204393 Strand Apr 2007 B2
7226001 Stern et al. Jun 2007 B1
7226232 Greer, Jr. et al. Jun 2007 B2
7232047 Greer, Jr. et al. Jun 2007 B2
7237697 Dunne Jul 2007 B2
7240857 Stern et al. Jul 2007 B1
7249692 Walters et al. Jul 2007 B2
7261225 Rueschhoff et al. Aug 2007 B2
7267248 Yerby et al. Sep 2007 B2
7278590 Greer, Jr. et al. Oct 2007 B1
7303152 Woods Dec 2007 B2
7307053 Tasz et al. Dec 2007 B2
7337985 Greer, Jr. et al. Mar 2008 B1
7341169 Bayer Mar 2008 B2
7350676 Di Giovanni et al. Apr 2008 B2
7374068 Greer, Jr. May 2008 B2
7383970 Anderson Jun 2008 B2
7445166 Williams Nov 2008 B2
7448517 Shieh et al. Nov 2008 B2
7481338 Stern et al. Jan 2009 B1
7487891 Yerby et al. Feb 2009 B2
7487893 Greer, Jr. et al. Feb 2009 B1
7494075 Schneider Feb 2009 B2
7500621 Tryon et al. Mar 2009 B2
7510102 Schmitt Mar 2009 B2
7556841 Kimball et al. Jul 2009 B2
7597274 Stern et al. Oct 2009 B1
7600659 Greer, Jr. et al. Oct 2009 B1
7624932 Greer, Jr. et al. Dec 2009 B1
7631785 Paas et al. Dec 2009 B2
7641079 Lott et al. Jan 2010 B2
7673816 Stern et al. Mar 2010 B1
7677420 Greer, Jr. et al. Mar 2010 B1
7744299 Greer, Jr. et al. Jun 2010 B1
7766196 Sugano et al. Aug 2010 B2
7775408 Yamamoto et al. Aug 2010 B2
7784647 Tourigny Aug 2010 B2
7784649 Greer, Jr. Aug 2010 B2
7845523 Greer, Jr. et al. Dec 2010 B1
7854356 Eberhardt Dec 2010 B2
7886995 Togashi Feb 2011 B2
7891529 Paas et al. Feb 2011 B2
7913877 Neuhalfen Mar 2011 B2
7922041 Gurrisi et al. Apr 2011 B2
7926741 Laidler et al. Apr 2011 B2
7947753 Greer, Jr. May 2011 B2
7971800 Combs et al. Jul 2011 B2
7984834 McBroom et al. Jul 2011 B2
8016163 Behar et al. Sep 2011 B2
8028864 Stern et al. Oct 2011 B2
8033432 Pardonge et al. Oct 2011 B2
8033484 Tryon et al. Oct 2011 B2
8038077 Greer, Jr. et al. Oct 2011 B1
8042713 Greer, Jr. et al. Oct 2011 B2
8087552 Fazekas et al. Jan 2012 B2
8132697 Finlay et al. Mar 2012 B2
8146782 Gross et al. Apr 2012 B2
8157135 Stern et al. Apr 2012 B2
8172113 Greer, Jr. May 2012 B2
8187574 Mekata et al. May 2012 B2
8201757 Suzuki Jun 2012 B2
8215862 Greer, Jr. et al. Jul 2012 B2
8221019 Greer, Jr. et al. Jul 2012 B2
8251255 Greer, Jr. et al. Aug 2012 B1
8281958 Matthews et al. Oct 2012 B2
8313011 Greer, Jr. et al. Nov 2012 B2
8317065 Stern et al. Nov 2012 B2
8336742 Greer, Jr. et al. Dec 2012 B2
8342421 Greer, Jr. et al. Jan 2013 B2
8353465 Tryon et al. Jan 2013 B2
8420705 Greer, Jr. Apr 2013 B2
8505786 Stern et al. Aug 2013 B2
8561840 Greer, Jr. et al. Oct 2013 B2
8573451 Tryon Nov 2013 B2
8584898 Greer, Jr. et al. Nov 2013 B2
8622255 Greer, Jr. Jan 2014 B2
8647006 Greer, Jr. et al. Feb 2014 B2
8701944 Tryon Apr 2014 B2
8784942 Tait et al. Jul 2014 B2
8844765 Tryon Sep 2014 B2
20010002676 Woods Jun 2001 A1
20020003147 Corba Jan 2002 A1
20020100769 McKune Aug 2002 A1
20020119256 Woods Aug 2002 A1
20030102328 Abplanalp et al. Jun 2003 A1
20030134973 Chen et al. Jul 2003 A1
20030183651 Greer, Jr. Oct 2003 A1
20030205580 Yahav Nov 2003 A1
20040012622 Russo et al. Jan 2004 A1
20040099697 Woods May 2004 A1
20040141797 Garabedian et al. Jul 2004 A1
20040154264 Colbert Aug 2004 A1
20040157960 Rowe Aug 2004 A1
20040195277 Woods Oct 2004 A1
20050121474 Lasserre et al. Jun 2005 A1
20050236436 Woods Oct 2005 A1
20050256257 Betremieux et al. Nov 2005 A1
20060049205 Green Mar 2006 A1
20060079588 Greer, Jr. Apr 2006 A1
20060180616 Woods Aug 2006 A1
20060219808 Woods Oct 2006 A1
20060219811 Woods Oct 2006 A1
20060273207 Woods Dec 2006 A1
20070117916 Anderson et al. May 2007 A1
20070119984 Woods May 2007 A1
20070125879 Khamenian Jun 2007 A1
20070142260 Tasz et al. Jun 2007 A1
20070155892 Gharapetian et al. Jul 2007 A1
20070178243 Houck et al. Aug 2007 A1
20070194040 Tasz et al. Aug 2007 A1
20070219310 Woods Sep 2007 A1
20070228086 Delande et al. Oct 2007 A1
20070272765 Kwasny Nov 2007 A1
20080033099 Bosway Feb 2008 A1
20080041887 Scheindel Feb 2008 A1
20120064249 Greer, Jr. et al. Mar 2012 A1
20120132670 Finlay et al. May 2012 A1
20130022747 Greer, Jr. et al. Jan 2013 A1
20130102696 Greer, Jr. et al. Apr 2013 A1
20130122200 Greer, Jr. et al. May 2013 A1
20130230655 Greer, Jr. Sep 2013 A1
20140050853 Greer, Jr. et al. Feb 2014 A1
20140061335 Tryon Mar 2014 A1
20140079882 Greer, Jr. et al. Mar 2014 A1
20140113076 Greer, Jr. et al. Apr 2014 A1
20140120260 Greer, Jr. May 2014 A1
20140162023 Greer, Jr. et al. Jun 2014 A1
20140248428 Tryon Sep 2014 A1
Foreign Referenced Citations (35)
Number Date Country
770467 Oct 1967 CA
976125 Oct 1975 CA
1191493 Aug 1985 CA
1210371 Aug 1986 CA
2145129 Sep 1995 CA
2090185 Oct 1998 CA
2224042 Jun 1999 CA
2291599 Jun 2000 CA
2381994 Feb 2001 CA
2327903 Jun 2001 CA
2065534 Aug 2003 CA
2448794 May 2004 CA
2504509 Oct 2005 CA
2504513 Oct 2005 CA
680849 Nov 1992 CH
210449 May 1909 DE
1926796 Mar 1970 DE
3808438 Apr 1989 DE
3806991 Sep 1989 DE
463476 Feb 1914 FR
84727 Sep 1965 FR
1586067 Dec 1969 FR
2659847 Sep 1991 FR
867713 May 1961 GB
970766 Sep 1964 GB
977860 Dec 1964 GB
1144385 Mar 1969 GB
2418959 Apr 2006 GB
461392 Jan 1971 JP
55142073 Nov 1980 JP
8332414 Dec 1996 JP
9418094 Aug 1994 WO
2005087617 Sep 2005 WO
2005108240 Nov 2005 WO
2006090229 Aug 2006 WO
Non-Patent Literature Citations (5)
Entry
ATSM, “Standard Test Method for Conducting Cyclic Potentiodynamic Polarization Measurements for Localized Corrosion Susceptibility of Iron-Nickel, or Cobalt-Based Alloys,” 1993, 5 pages.
Homax Products, Inc., “Easy Touch Spray Texture Brochure”, Mar. 1992, 1 page.
Newman-Green, Inc., “Aerosol Valves, Sprayheads & Accessories Catalog”, Apr. 1, 1992, pp. 14, 20, and 22.
Tait, “An Introduction to Electrochemical Corrosion Testing for Practicing Engineers and Scientists,” 1994, 17 pages.
Chadwick, “Controlling Particle Size in Self-Pressurized Aerosol Packages,” Metal Finishing, Jul./Aug. 2004, 3 pages, vol. 102, No. 7/8.
Provisional Applications (1)
Number Date Country
60922117 Apr 2007 US
Continuations (2)
Number Date Country
Parent 13562033 Jul 2012 US
Child 14452254 US
Parent 12080671 Apr 2008 US
Child 13562033 US