Coating of substrates with a thin material layer or with several thin material layers plays an important role in numerous technical fields.
For example CD disks can be provided with a protective layer or clock housings with a ceramic layer. Coating glass with layers which permit only certain wavelengths to pass or reflect them has gained considerable significance. Large glass facades are installed on buildings with so-called architectural glass provided with thin layers. The coating can also serve for the purpose of making synthetic films or synthetic bottles gas-tight.
The method very often employed for coating the listed materials is the sputtering method. In the sputtering method a plasma is generated in an evacuated chamber. By plasma is understood a mixture of positive and negative charge carriers at relatively high density and of neutral particles as well as photons. The positive ions of the plasma are attracted by the negative potential of the cathode, which is provided with a so-called target. When the positive ions of the plasma impinge on the target, they knock small particles out of it, which, in turn, can be deposited on the substrate disposed opposite the target. This knocking-out of particles is referred to as “sputtering”. One differentiates here between reactive and non-reactive sputtering. In non-reactive sputtering the work proceeds with inert gases, which serve as working gas and their positive gas ions knock particles out of the target. The reactive sputtering additionally employs reactive gases, for example oxygen, which form a compound with the particles of the target before they are deposited on a substrate.
The ions required for the sputtering process are generated by the collisions of gas atoms and electrons, for example in a glow discharge, and with the aid of an electric field accelerated into the target forming the cathode.
The free electrons are primarily responsible for the ionization. These can be densified in front of a target with the aid of magnets and therewith intensify the ionization. The combination of cathode and magnets is referred to as a magnetron.
A problem encountered in magnetrons lies therein that the target material is only eroded non-uniformly since the magnetic field is not homogeneous. For example, in the proximity of the pole lines of the magnetic fields no erosion of the target material occurs. As pole lines are denoted those zones in which the magnetic field lines penetrate perpendicularly the target surface on the sputter side. As a consequence of the non-uniform erosion of the target material, the substrate is also coated non-uniformly.
The aim is therefore to eliminate the disadvantage of the non-uniform erosion.
A magnetron is already known in which a magnet system is moved parallel to the target material (EP 1 120 811 A2). The magnet system involves several magnets, which are moved on a path relative to and parallel with the target surface. Through this magnet system the magnetic field becomes more homogeneous and the uniform erosion of the target material is ensured.
A high target utilization can also be attained thereby that a tubular target is employed. In this target is located a magnet system, which is moved relative to the target, or the magnet system is stationary while the tubular target is moved about the magnet system (DE 41 17 367 C2).
Lastly is also known a planar magnetron comprising several magnets, which define a magnetic field in the form of a closed loop in order to generate a plasma tube over a target (EP 0 918 351 A1). Herein devices are provided which cause a cyclical movement between the magnets and the surface of the target. One of these movements is circular.
Problem
The invention addresses the problem of improving the utilization of a planar and rectangular target in the sputter process.
Resolution of the Problem
The problem is solved according to the characteristics of patent claim 1.
The invention consequently relates to a magnetron with a planar target and a planar magnet system. The planar magnet system comprises a bar-shaped first magnetic pole with enlarged ends and a frame-shaped second magnetic pole and a relative movement between the magnetic poles and the target proceeds in such a manner that, in the case of a stationary target, each moving point of the magnetic system moves on a circular path. If the magnet system is stationary, each point of the target moves on such a circular path. During the relative movement with respect to one another the magnet system and the target are in parallel planes. The diameter of the circular path corresponds to the mean distance between two parallel arms of a plasma tube, which develops between the first and the second magnetic pole during the sputtering operation. Thereby that the magnets in the curve region of the plasma tube are disposed such that the pole lines form in this region a circular arc or a circular area, holes in the target are avoided.
The advantage attained with the invention comprises in particular that the target is also sputtered at those sites at which the magnetic field lines in static operation penetrate perpendicularly through the target surface. In particular the increased erosion rates occurring on a narrow side of a rectangular target are avoided.
Embodiment examples of the invention are shown in the drawing and will be described in further detail in the following. In the drawing depict:
The magnet configuration 1 is comprised of a first magnet pole, for example a north pole 2 and a second magnet pole, for example a south pole 3. The north pole 2 has the form of a rectangular frame encompassing the bar-shaped south pole 3.
The north pole 2 is comprised of two long sides 4, 5 and two short sides 6, 7. The south pole 3 also has two long sides 8, 9 and two short sides 10, 11, the short sides 10, 11, however, being considerable shorter than the short sides 6, 7 of the north pole 2.
Between the north pole 2 and the south pole 3 is evident a plasma tube 12, which occupies nearly the entire interspace between north pole 2 and south pole 3. This plasma tube 12 results from the magnetic field of the magnet configuration 1 in connection with a voltage applied on a cathode not shown in
The target, also not shown in
The plasma tube 12 can be subdivided into four regions. Two regions 13, 14 extend parallel to the long sides 4, 5 of the north pole 2, while two other regions 15, 16 encompass semi-elliptically the ends of the south pole 3.
D denotes the distance between the center lines of the parallel regions 13, 14 of the plasma tube 12.
If the magnet configuration 1 is employed in a magnetron, during static operation substantially sputtered off are those portions of the target which are located directly opposite to the plasma tube 12. The remaining areas are substantially not eroded.
To make the sputtering of the target 20 more uniform, an imaginary axis 21 through the south pole-north pole configuration is rotated on a circle 22 with the diameter D.
The magnet system 1 consequently is moved such that each of its points describes a circle with the same diameter D. The magnet system 1 and the target 20 are located in planes which are oriented parallel to one another.
If a voltage is applied on the, not shown, cathode, a plasma is ignited. Hereby the plasma tube 12, depicted in
When moving the magnet configuration 1 relative to target 20 the plasma tube 12 is also moved and thus guided over a large portion of the target surface which herein is stationary. The plasma tube 12 consequently also sweeps over areas of target 20 which in static operation would not be sputtered.
To avoid the redeposition of the eroded target material onto the target surface, each site of the surface of target 20 should be covered for a certain length of time by the plasma tube 12.
The magnet configuration 1 depicted in
To avoid this hole, the inner magnet pole is modified in the manner shown in
In the case of the magnet configuration 25 depicted in
However, the inner magnet 26 has a different form. While it also comprises a bar with two long sides 27, 28 and two short sides 24, 30, the long sides 27, 28 are shorter than is the case with the inner magnets 3 according to
The short sides 24, 30 are adjoined in each instance by five small bar magnets 31 to 35 or 36 to 40, respectively, which together form essentially a circular body, such that the inner magnet pole has approximately the form of a bone. The small bar magnets 33 and 38 extend parallel to the short sides 7, 6 of the outer magnet pole, while the small bar magnets 32, 34 or 37, 39 extend parallel to the long sides 4, 5 of the outer magnet pole. The small bar magnets 31, 35 or 36, 40 establish a connection between the bar magnets 32, 34 or 37, 39 and the short sides 24, 30 of the inner magnet pole 26. They are approximately disposed at an angle of 45 degrees relative to the longitudinal axis of the inner magnet 26.
The plasma tube 45 resulting due to the magnet configuration 25 is once again depicted in
The illustration of
For this purpose along a circular path 46 with diameter D the plasma density is mathematically integrated (cf. in this connection Shunji Ido, Koji Nakamura: Computational Studies on the Shape and Control of Plasmas in Magnetron Sputtering Systems, Jpn. J. Appl. Phys. 32; 5698-5702, 1993). A closed contour path integral is formed therein. For the circular path 46 this integration yields the value zero since no plasma is found within the circular path 46.
In the case of the circular path 47 a certain positive value results for the plasma density since here the plasma tube 45 penetrates into the circular path 47. For the circular path 48 results again, as was the case with the circular path 46, the value zero.
Thereby that the plasma in the curve region 49, 50 is constricted, the holes in the target 20 are avoided, which occur when utilizing a magnet configuration 1 according to
The constriction should be large enough for the plasma tube 45 to be guided on the circular path 46 around the curve, wherein the inner side of the plasma tube 45 describes a circular path with diameter D, which corresponds to the distance D shown in
Such a constriction can be attained through a very wide magnet or through several narrow magnets arranged next to one another.
The central magnet 55 or 60 is in each case the largest, while the laterally succeeding magnets 54, 53; 56, 57 or 58, 59; 61, 62 become increasingly shorter toward the outside.
In the variant of
In
If the pin 77 is disposed at a distance D/2 from the center of the driving wheel 76 and the motor 79 is started up, the yoke plate 75 moves with the magnet system in the manner already described, i.e. such that each point of the yoke and of the magnet system moves on a circular path. The pin 77 is herein not rigidly connected with the yoke plate 75 but rather inserted into a hole of this yoke plate 75 where it can rotate and in this way prevents that the yoke plate 75 rotates as a whole about the shaft 78. The geometric orientation (x-, y-axis) of the short and long sides of the yoke plate 75 remains unchanged during the rotational movement.
It is not necessary for the pin 77 to project into an opening in the yoke plate 75 itself. It is also feasible to provide for this purpose an additional plate connected with the yoke plate 75. Any other drive, which effects the desired movement of the magnet configuration relative to the target (cf. EP 0 918 351 A1, FIG. 6) can also be utilized. It is only essential that each point on the magnet configuration describes a movement on a circumference with diameter D.
The magnets, which form the ends of the bar-shaped inner magnet pole 26, are preferably implemented such that their magnetic field lines form relative to the surface of the target 20 an angle greater than 20 degrees.
Filing Document | Filing Date | Country | Kind | 371c Date |
---|---|---|---|---|
PCT/EP2005/006032 | 6/4/2005 | WO | 00 | 2/19/2008 |