Patent Application
20140099515
The present invention is relating to a steel cord, particular for reinforcing rubber product.
The present invention is relating to a rubber product reinforced by steel cord.
A steel cord with different bending stiffness in different directions, i.e. lateral bending stiffness in horizontal plane and radial bending stiffness in vertical axis, has a good advantage in comparison with a normal steel cord with same bending stiffness in the different directions. While applying such steel cord in rubber product, i.e. rubber tyre, the different bending stiffness in different direction leads to a good handling, riding comfort or driving stability. In a direction perpendicular to the horizontal axis of the steel cord, there is a decreased radial bending stiffness and an increased flexibility so that any obstacles such as cobble stones on the road can be taken easily. In the direction of the horizontal axis of the steel cord, there is an increased lateral bending stiffness and a decreased flexibility leading to an improved stability when taking a bend.
Normally the present steel cord with different bending stiffness in different direction is produced as the steel cord with oval cross-section or rectangular cross-section.
U.S. Pat. No. 4,544,603 discloses a steel cord having a lateral bending stiffness in a horizontal plane different from the radial bending stiffness in a vertical plane. This steel cord has several steel filaments overlapped with each other. The steel filaments are flat wires having substantially rectangular cross-section with round edges. Because the steel filaments have the same cross-section dimension, the steel cord has a cross-section of rectangular form. While embedding the steel cord into rubber for reinforcing rubber product, this rectangular cross-section has a disadvantage. When the steel cord is embedded into the rubber, use is made of an extruding or calendaring operation. This extruding of calendaring operation makes use of an extrusion die which is mostly round. In other words, the cross-section of hole in the extrusion die is round. Now, the steel cord with a rectangular cross-section can not fit the extrusion die with round cross-section. As a result, the steel cord will turn over or twist during the extrusion or calendaring process, and the rigid edges of the steel cord will damage the extrusion die. An optional solution is using other extrusion die with a rectangular cross-section. Because this rectangular extrusion die is not a normal or general die, it is more expensive than round die, the solution of using extrusion die with a rectangular cross-section will increase the production cost.
U.S. Pat. No. 4,606,392 also discloses a steel cord for reinforcing element comprising several flat wires twisted together. Because of this twisting of the steel cord, the steel cord has a substantially round cross-section. The steel cord can fit the normal extrusion die with round cross-section, but the difference between the lateral bending stiffness and radial bending stiffness is not existing. While using the rubber tyre with such steel cord, the handling and riding comfort is not different from other steel cords with round cross-section.
It is an object of the present invention to overcome the drawbacks of the prior arts.
It is also an object of the present invention to provide a steel cord with substantially round cross-section.
It is a further object of the present invention to provide a rubber product reinforced by the steel cord.
According to the present invention, a steel cord comprises a plurality of steel filaments arranged in parallel without twisting. The steel cord further comprises a wrapping filament twisted around the steel filaments. The steel filaments are flat wires having flat surfaces and preferably round edges. The steel filaments are contacted with each other along the flat surfaces. The cross-section of the steel cord is substantially round. The lateral bending stiffness (in a horizontal plane) is greater than the radial bending stiffness (in a vertical plane).
The cross-section of the steel cord is substantially round. While embedding the steel cord into rubber, the steel cord with substantially round cross-section fits the normal extrusion die with round cross-section well, and the extrusion die would not be damaged by the steel cord. It is not necessary to make special extrusion die to adapt for the steel cord. The additional cost for special extrusion die is saved. So the steel cord according to the invention combines the advantages of a round cross-section with the advantages of having a different radial and lateral stiffness.
According to the present invention, ‘substantially round’ is a cross-section being nearly round but not round, and the arc line in the cross-section is nearly round. In any one cross-section along the length of steel cord, because of the non-round cross-section, the diameter has a maximum value to be maximum diameter, a minimum value to be minimum value, and an average value to be average diameter. To the present invention, ‘substantially round’ means that, the ratio of the difference between maximum diameter and minimum diameter to the average diameter ranges from 5% to 15%. For example, to a steel cord with an average diameter being 1 mm, the difference between maximum diameter and minimum value is between 0.05 and 0.15 mm, such steel cord has substantially round cross-section. All these make the shape of cross-section of the steel cord to be nearly round but not round.
The lateral bending stiffness (in a horizontal plane) is greater than the radial bending stiffness (in a vertical plane). Preferably the ratio of the lateral bending stiffness to the radial bending stiffness is not less than 1.8. More preferably the ratio of the lateral bending stiffness to the radial bending stiffness is not less than 2.0. The steel cord with different bending stiffness in different plane is quite adapting for reinforcing rubber ply in tyre. The steel cord will take good advantages on handling and riding comfort to the rubber tyre.
In the context of the present invention, a horizontal plane is the plane which is parallel to the flat surface of the steel filament, and a vertical plane is the plane which is perpendicular to the flat surface of the steel filament.
According to the present invention, the steel filaments in the steel cord are flat wires. Flat wire here means a wire with flat cross-section having a pair of flat surface and, preferably, a pair of round edges.
To obtain a steel cord with substantially round cross-section, the flat wires are laid to overlap with each other along the flat surface to make a strand, and then bundle the strand by twisting a wrapping wire around it.
The flat wires are laid according to the following geometry. The wider flat wire is laid in the center of the steel cord, and the narrower flat wire is laid away from the center of the steel cord. In other words, the steel filament near the centre of the steel cord has the bigger width, and the steel filament away from the centre of the steel cord has the smaller width. As a result, a steel cord with a substantially round cross-section is obtained.
The steel filaments in the steel cord may have the same cross-section area or different cross-sectional area.
Preferably, the steel filament near the centre of the steel cord has the bigger thickness, and the steel filament away from the centre of the steel cord has the smaller thickness, and thereby the steel filament near the centre of the steel cord has the bigger cross-sectional area, and the steel filament away from the centre of the steel cord has the smaller cross-sectional area.
The number of the steel filaments in the steel cord preferably ranges from 3 to 9.
To obtain a stable steel cord, the strand consisting of a plurality steel filaments with flat cross-section is twisted by a wrapping filament. The wrapping filament can be any one of the prior existing warp filaments with various cross-sections or various materials. The wrapping filament may be a wire with round, flat or rectangular cross-section. And the wrapping filament can be made from metal, metal alloy or nylon.
Preferably the wrapping filament can be made of steel. For the wrapping filament made from nylon, while being embedded into rubber, the nylon wrapping filament will disperse into rubber, as a result there is no wrapping filament twisted around the steel stand in the final rubber product. In this case, the definition of substantially round is also applied to the strand of steel filaments.
According to the size of the steel filament, preferably the steel cord has a diameter ranging from 0.2 mm to 15 mm.
The steel cord in the present invention can be embedded into rubber as a reinforcing element for rubber product. According to the diameter of the steel cord, the steel cord can be applied to various applications. For the steel cord with a diameter ranging from 0.2 mm to 5.0 mm, the steel cord can be applied to reinforce rubber belt in tyre for passenger car or rubber track tyre. For the steel cord with a diameter ranging from 0.2 mm to 1.2 mm, the steel cord can be used for reinforcing timing belt. For the steel cord with large diameter ranging from 4.0 mm to 13 mm, the steel cord can be applied to reinforcing the rubber belt for elevator.
The steel cord comprises a plurality of steel filaments and a wrapping filament. In the present invention, both the steel filaments and wrapping filament can be manufactured from a wire rod in the following process.
The wire rod is firstly cleaned by mechanical descaling and/or by chemical pickling in a H2SO4 or HCl solution in order to remove the oxides present on the surface. The wire rod is then rinsed in water and is dried. The dried wire rod is then subjected to a first series of dry drawing operations in order to reduce the diameter until a first intermediate diameter.
At this first intermediate diameter d1, e.g. at about 3.0 to 3.5 mm, the dry drawn steel wire is subjected to a first intermediate heat treatment, called patenting. Patenting means first austenitizing until a temperature of about 1000° C. followed by a transformation phase from austenite to pearlite at a temperature of about 600° C.-650° C. The steel wire is then ready for further mechanical deformation.
Thereafter the steel wire is further dry drawn from the first intermediate diameter dl until a second intermediate diameter d2 in a second number of diameter reduction steps. The second diameter d2 typically ranges from 1.0 mm to 2.5 mm.
At this second intermediate diameter d2, the steel wire is subjected to a second patenting treatment, i.e. austenitizing again at a temperature of about 1000° C. and thereafter quenching at a temperature of 600° C. to 650° C. to allow for transformation to pearlite.
If the total reduction in the first and 2nd dry drawing step is not too big a direct drawing operation can be done from wire rod till diameter d2.
After this second patenting treatment the steel wire is usually provided with a brass coating: copper is plated on the steel wire and zinc is plated on the copper. A thermo-diffusion treatment is applied to form the brass coating.
The brass-coated steel wire is then subjected to a final series of cross-section reductions by means of wet drawing machines. The final product is a steel filament with a carbon content above 0.60 percent by weight, with a tensile strength typically above 2000 MPa and adapted for the reinforcement of elastomeric products.
Steel filaments adapted for the reinforcement of tyres typically have filaments with a final diameter ranging from 0.05 mm to 0.60 mm, e.g. from 0.10 mm to 0.40 mm. Examples of filament diameters are 0.10 mm, 0.12 mm, 0.15 mm, 0.175 mm, 0.18 mm, 0.20 mm, 0.22 mm, 0.245 mm, 0.28 mm, 0.30 mm, 0.32 mm, 0.35 mm, 0.38 mm, 0.40 mm.
Of course, the steel filaments may have big diameters like 4 mm to 13 mm for other applications such as belt for elevator.
Then steel filaments are rolled by a pair of rollers to change the cross-section from round to flat. Thus flat wires are obtained. The flat wires have a pair of flat surfaces and a pair of round edges.
For a wrapping filament, it can be a steel filament having round cross-section or flat cross-section.
A comparison test between the invention steel cord 20 and prior steel cord 44 is carried out, and the following Table 1 summarizes the result.
According to table 1, although the prior art steel cord 44 has the same tensile strength as the invention steel cord 20, the invention steel cord has a greater improvement on the difference between lateral bending stiffness and radial bending stiffness. The ratio of lateral bending stiffness to radial bending stiffness in invention steel cord 20 is nearly two times more of it in prior steel cord 44. While keeping the same tensile strength, the invention steel cord has a greater advantage than the prior art steel cord, the invention steel cord is more suitable for reinforcing rubber product which requires different bending stiffness in different direction. Furthermore, the invention steel cord has substantially round cross-section which is quite fitting for the normal round extrusion die in the further process.
Another prior art steel cord A has the same structure with prior art steel cord 44 being consisting of two flat wires and a wrapping filament. The two flat wires have the same width of 0.42 mm and same thickness of 0.28 mm. In a cross-section of the steel cord A, the maximum diameter is 0.95 mm, the minimum diameter is 0.67 mm, the average diameter is 0.81 mm, and the ratio of diameter difference between maximum value and minimum value to the average diameter is 34.6%. The cross-section of the prior steel cord A is not substantially round.
A comparison test between the steel cord 20 and prior steel cord A is carried out, and the following Table 2 summarizes the result.
According to table 2, the tensile strength of the invention steel cord 20 is two times of the tensile strength of the prior art steel cord A, although the ratio of lateral bending stiffness to radial bending stiffness in invention steel cord 20 is similar with it in prior art steel cord A. While keeping the same ratio of lateral bending stiffness to radial bending stiffness, the invention steel cord has a greater advantage than the prior art steel cord on tensile strength, the invention steel cord is more suitable to be a reinforcing element. Furthermore, the invention steel cord has substantially round cross-section which is quite fitting for the normal round extrusion die in the further process.
Both table 1 and table 2 show that the invention steel cord has a great improvement on the difference between lateral bending stiffness and radial bending stiffness or on tensile strength compared with the prior art steel cords. Furthermore, the invention steel cord has substantially round cross-section. As a result, the invention steel cord fits for the existing round extrusion die well, and the invention steel cord is quite suitable for reinforcing rubber product, especially for reinforcing rubber tyre.
To a rubber tyre which has rubber belt 60, a good handling, riding comfort and driving stability are obtained.
| Number | Date | Country | Kind |
|---|---|---|---|
| PCT/CN2011/075573 | Jun 2011 | CN | national |
| Filing Document | Filing Date | Country | Kind | 371c Date |
|---|---|---|---|---|
| PCT/EP2012/058074 | 5/3/2012 | WO | 00 | 12/9/2013 |
