Patent Grant
8359823
The present invention relates to a steel cord comprising a core layer with one or more preformed filaments and an outer layer. The steel cord can be adapted for reinforcement such as a belt or breaker structure of tire.
Steel cord comprising preformed filaments are known in the art. The 4+6 structure of the steel cord is also disclosed.
EP0301776A1 provides a cord structure of 4+6. It discloses a low profile radial tire reinforced with steel cords composed of two layers of a core and an outer layer, the core comprising 3 or 4 filaments and the outer layer comprising a number of filaments equal to or less than the number of the core filaments, the filaments being substantially equal in diameter, the core filaments and the outer filaments having a twist of the same hand but a different pitch, the aspect ratio of the tire being at most 0.85. The patent document also discloses the cord structure can be 4+6. However the steel cord according to the patent document has no full rubber penetration. As a consequence humidity may reach the individual steel filaments during use, which may drastically decrease the life time of the steel cord and of the reinforced tire.
Full rubber penetration means that rubber must be able to penetrate into the cord between the composing elements and fill all possible interstices in order to reduce fretting and tensions between the elements and to avoid moisture from traveling along the cord, which would cause a lot of corrosion and which would considerably reduce the life of the cord and the rubber product.
WO02/088459A1 provides a steel cord comprising a first group and a second group. The first group comprises 4 filaments and the second group comprises 6 filaments. The first group is helically twisted around the second group. The first filaments have a twisting step greater than 300 mm. The second filaments are polygonally preformed. The first steel filaments have a spatial wave form. It discloses the spatial wave is not a planar wave, and it has a first crimp and a second crimp. The first crimp lies in a plane which is substantially different from the plane of the second crimp. Due to process of spatial wave, e.g. two subsequent crimps in different planes, high tensions are introduced in the first filaments and the residual stress of the first filaments is very high. It causes high sequential breaking rate of the cord. According to this the breaking load of the cord can not up to requirement. Also due to the process of spatial wave, the wear of the crimp device is high.
It is an object of the present invention to overcome the problem of the prior art.
It is a further object of the present invention to provide a steel cord with full rubber penetration and high breaking load.
It is yet another object of the present invention to provide a steel cord which can be made in an economical way.
According to the present invention, a steel cord comprises a core layer and an outer layer. The core layer comprises a first number of first steel filaments. The first number ranges from 3 to 8. And first steel filaments have a twist pitch greater than 310 mm. The outer layer comprises a second number of second steel filaments. The second number ranges from 3 to 10. At least one of the second steel filaments is polygonally preformed. The outer layer is helically twisted around the core layer with a core twist pitch, and the core twist pitch ranges from 15 Rf to 150 Rf when the average diameter of the second steel filaments is Rf mm. At least one of said first steel filaments is preformed into wavy form in one plane. The wave height ranges from 1.2 Df mm to 2.4 Df mm when the average diameter of the first steel filaments is Df mm, and the wave length ranges from 10 Df mm to 25 Df mm.
The technique of polygonal preforming is disclosed in WO95/16816.
Polygonal preforming is different from spiral preforming. Although both of them are three dimensionally preforming or spatial preforming, to the persons skilled in the art, polygonal preforming and spiral preforming are different types of preforming.
Polygonal preforming is a preforming which gives the steel filament projections on a plane perpendicular to the longitudinal central axis. The projections are in the form of curves which are convex curves with a radius of curvature alternating between a maximum and a minimum. The radius of the curvature of the preformed steel filament alternates between two extremes: a minimum at the point where the highest bending has been given and a maximum at the point where the smallest bending has been given. As a consequence of the rotating of the filament around its own longitudinal axis, the radius of curvature of the steel filament always points in the direction of a central axis of the steel wire. It means that the polygon has a convex form. In other words, the zone of plastical tension of the steel filament always lies radially inward while the zone of plastical compression lies radially outward.
JP 06108387 describes a steel cord with a two dimensional preforming on core wires and a spirally preforming on outer wires. In the art spiral preforming without special description means that a preforming in the form of curves which are circular curves with a radius of the curvature is a fixed value or a continuous monotonic function. It means that the curves of spiral preformed steel filament are rather circular curves.
Preferably the wave height ranges from 1.6 Df mm to 2.0 Df mm. Most preferably the wave height ranges from 1.7 Df mm to 1.9 Df mm.
Preferably the wave length ranges from 12 Df mm to 20 Df mm. Most preferably the wave length ranges from 14 Df mm to 16 Df mm.
According to the present invention Df is the average diameters of the first steel filament. Df ranges from 0.06 mm to 1.0 mm. Preferably Df ranges from 0.2 mm to 0.5 mm. Most preferably Df ranges from 0.3 mm to 0.4 mm. The Df may be 0.35 mm or 0.38 mm.
According to the present invention the core twist pitch ranges from 15 Rf to 150 Rf. Preferably the core twist pitch ranges from 40 Rf to 70 Rf.
The outer layer can be twisted around each other with an outer twist pitch. The outer twist pitch ranges from 15 Rf to 150 Rf. Preferably the outer twist pitch ranges from 40 Rf to 70 Rf. Most preferably the outer twist pitch is equal to the core twist pitch.
According to the present invention Rf is the average diameter of the second steel filaments. Rf ranges from 0.06 mm to 1.0 mm. Preferably Rf ranges from 0.2 mm to 0.5 mm. Most preferably Rf ranges from 0.3 mm to 0.4 mm. The Rf can be 0.35 mm or 0.38 mm.
According to the present invention, Rf can be different from Df or not. Preferably Rf is equal to Df.
Preferably the first number ranges from 3 to 5. Most preferably the first number is 4.
Preferably the second number ranges from 5 to 8. Most preferably the second number is 6.
The second number can be equal to the first number. Preferably the second number is greater than the first number.
The structure of the steel cord can be 3+3, 3+4, 3+5, 3+6, 3+7, 3+8, 3+9, 3+10, 4+4, 4+5, 4+6, 4+7, 4+8, 4+9, 4+10, 5+5, 5+6, 5+7, 5+8, 5+9, 5+10, 6+6, 6+7, 6+8, 6+9, 6+10, 7+7, 7+8, 7+9, 7+10, 8+8, 8+9, or 8+10.
According to the present invention at least one of the first steel filaments is wavy preformed in one single plane. Preferably all the first steel filaments are wavy preformed in one single plane. No other performing is imposed on the first filaments.
As the steel filament is preformed into wavy form in one plane, compared with the spatial wave form, the steel filament has lower strength loss. The sequential breaking rate of the steel cord comprising such preformed steel filament is much lower. The breaking load of the steel cord is same as the prior steel cord or even higher. Also the wear of the crimp device is lower.
According to the present invention at least one of the second steel filaments is polygonally preformed. Preferably all the second steel filaments are polygonally preformed.
The polygonal preforming of the second steel filaments gives an open structure to the steel cord which allows rubber or other matrix material to penetrate until the first steel filaments.
According to the present invention the first steel filaments have a twist pitch greater than 310 mm. Preferably the first steel filaments are untwisted.
The sequential breaking rate of the steel cord is less than 20%, and even less than 10%. The breaking load is more than 2965N while the steel cord has full rubber penetration.
According to the present invention, the steel cord can be used as reinforcement such as the belt layer or breaker structure to reinforce tires intended for industrial vehicles selected from subway trains, buses, road transport machinery, off load machinery, aircraft and other transport or handling vehicles.
The invention will now be described into more detail with reference to the accompanying drawings wherein
A first preferred embodiment is shown in
The four first steel filaments 10 are wavy preformed in one single plane and untwisted, i.e. they are parallel to each other.
The six second steel filaments 20 are polygonally preformed and twisted around each other with the outer twist pitch of 23 mm.
The process for manufacturing the embodiment comprises follow steps:
(i) the four first steel filaments 10 are guided towards a pair of toothed wheels which give the filaments a crimp preforming in one plane;
(ii) the bundle of first steel filaments is guided towards the first flyer of a double twisting apparatus where the bundle of first steel filaments is receiving two twists in a first twisting direction, e.g. in Z-direction;
(iii) inside the rotating flyers of the double-twisting apparatus, the six second steel filaments 20 are guided towards a preforming device which gives the second steel filaments a polygonal preforming;
(iv) than the bundles of first steel filaments and second steel filaments are guided towards the second flyer of the double twisting apparatus together, where they are receiving another two twists, however now in a second opposite twisting direction, e.g. in S-direction; therefore the core layer comprising the first steel filaments is untwisted—the twists in Z-direction are compensated by the twists in S-direction—and the outer layer comprising the second steel filaments is twisted, e.g. in S-direction.
A second preferred embodiment is shown in
A third preferred embodiment is shown in
Compared with the steel cord S with the structure of 4+6 mentioned in the WO02/088459A1, some properties of the present invention are measured. The table 1 hereunder summarizes the result.
The steel filament adapted for the steel cord comprises a carbon content more than 0.70%, preferably more than 0.80%, or more than 90%. It can also contain: manganese (content ranging from 0.20% to 1.00%), sulphur and phosphorus (contents being limited to 0.05%), and/or silicon (content ranging from 0.10% to 0.90%). Additionally chromium, nickel, boron, nickel, vanadium, molybdenum, niobium, copper, calcium, aluminum, titanium and/or nitrogen may be added.
The steel filament is preferably coated with a metallic coating. The coating may be a corrosion resistant coating that promotes the adhesion to the matrix material such as zinc-copper alloy (either low copper −63.5% Cu or high copper −67.5% Cu), or a ternary brass such as zinc-copper-nickel or zinc-copper-cobalt.
The tensile strength of the steel filament may dependent upon the steel filament composition, the degree of the preforming and the diameter of the filament. Preferably the steel filament has a high tensile strength. Most preferably the steel filament has a tensile strength up to 4000 MPa.
The diameter of one steel filament may be different from the others inside the core layer of first steel filaments and/or the diameter of one steel filament may be different from the others inside the layer of second steel filaments.
| Number | Date | Country | Kind |
|---|---|---|---|
| 09150269 | Jan 2009 | EP | regional |
| Filing Document | Filing Date | Country | Kind | 371c Date |
|---|---|---|---|---|
| PCT/EP2009/066670 | 12/9/2009 | WO | 00 | 7/5/2011 |
| Publishing Document | Publishing Date | Country | Kind |
|---|---|---|---|
| WO2010/079034 | 7/15/2010 | WO | A |
| Number | Name | Date | Kind |
|---|---|---|---|
| 5321941 | Bollen et al. | Jun 1994 | A |
| 5606852 | Yanagisawa | Mar 1997 | A |
| 5802830 | Kawatani | Sep 1998 | A |
| 5878564 | De Vos et al. | Mar 1999 | A |
| 5911675 | Obana | Jun 1999 | A |
| 6016647 | Kawatani et al. | Jan 2000 | A |
| 6109017 | Kawatani | Aug 2000 | A |
| 6405774 | Komatsu | Jun 2002 | B1 |
| 6695026 | Miyazaki et al. | Feb 2004 | B2 |
| 6745806 | Miyazaki et al. | Jun 2004 | B2 |
| 6829880 | Noferi | Dec 2004 | B2 |
| 7131257 | Miyazaki et al. | Nov 2006 | B2 |
| Number | Date | Country |
|---|---|---|
| 0 301 776 | Oct 1992 | EP |
| 4-308287 | Oct 1992 | JP |
| 6-108387 | Apr 1994 | JP |
| 10-298880 | Nov 1998 | JP |
| 11-36182 | Feb 1999 | JP |
| 2000-80578 | Mar 2000 | JP |
| 2005-23494 | Jan 2005 | JP |
| 2006-225801 | Aug 2006 | JP |
| WO 9516816 | Jun 1995 | WO |
| WO 02088459 | Nov 2002 | WO |
| Entry |
|---|
| “Polygonally Preformed Steel Elements”, Research Disclosure, Mason Publications, No. 323, Jul. 1, 1994, pp. 359-365. |
| Number | Date | Country | |
|---|---|---|---|
| 20110268954 A1 | Nov 2011 | US |
