Patent Grant
10487448
The invention relates to a steel cord adapted to reinforce a breaker or belt ply in a rubber tire. The invention also relates to a twisting equipment and to a method to make such a steel cord.
Steel cords for reinforcing breaker or belt plies in a rubber tire are well known in the art.
U.S. Pat. No. 4,408,444 discloses a M+N construction, and more particularly a 2+2 construction. This cord has two groups of filaments, a first group with M, preferably two filaments and a second group with N, preferably two filaments. This cord, at least in its 2+2 embodiment, has the advantage of full rubber penetration whether brought under tension or not. However, this cord construction suffers from the drawback of having a relatively poor fatigue limit and too great a cord diameter.
In an attempt to mitigate these drawbacks, EP-B1-0 466 720 proposes a similar but different M+N construction. The difference is that the filaments of one group have a filament diameter which differs from the filaments of the other group. The result is an increase in fatigue limit and, sometimes, a decrease in cord diameter for the same reinforcing effect.
M+N constructions with difference in filament diameters are, however, difficult to process during tire manufacturing, particularly in an automated system. Filaments with a difference in diameter have different saturation levels of residual torsions. The resulting cords are subject to flare. The cords are less stable and the integration of such cords in rubber plies leads to tip rise of the rubber plies, i.e. one or more edges are lifting up.
When applying torsions to a steel cord or a steel filament, the first observed phenomenon is linear, i.e. the number of residual torsions is equal to the number of applied torsions. Further increasing the number of applied torsions leads to an increase of residual torsions but not to the same degree: in decreasing amounts. In other words, a saturation phenomenon is observed. As soon as there is no increase anymore of residual torsions, the saturation level of residual torsions has been reached.
The saturation level of residual torsions of a steel filament is dependent upon the material of the steel filament, the tensile strength of the steel filament and, especially, upon the diameter of the steel filament.
In order to cope with the problem of tip rise, WO-A1-2012/128372 proposes a 2xdc+Nxds construction where the filament diameter of the core group dc is greater than the filament diameter of the sheath group ds and where the two core filaments are plastically deformed to such a degree that they form a wave with such an amplitude that the core steel filaments get well anchored by the rubber in the ultimate rubber ply. This anchorage hinders any negative effect of residual torsions and lowers the tip rise of any reinforced rubber ply.
However, the 2xdc+Nxds of WO-A1-2012/128372 suffers from flare and risks to become a less robust or less stable construction.
The term ‘flare’ refers to the phenomenon of spreading of the filaments ends or the strand ends after cutting of the steel cord or steel strand. A steel cord without flare does not exhibit this spreading, the filaments or strands remain more or less in their position after cutting.
Patent applications JP-A-2013199194, JP-A-2013199193, JP-A-2013199191, JP-A-2013199717, JP-A-2013199195, JP-A-2013199190, JP-A-2013199189 all disclose 2xdc+Nxds steel cord constructions but they do not offer a solution of the problem of flare and neither a solution for the too great a wave of the core steel filaments.
JP-A-06-306784 discloses a way of manufacturing a 2 (core)+2 (sheath) steel cord construction by means of a double-twister where used is made of a turbine or false twister. The core steel filaments and the sheath steel filaments have the same diameter.
U.S. Pat. No. 5,487,262 discloses a method and device for making a steel cord where use is made of two false twisters in sequence.
A general object of the invention is to avoid the drawbacks of the prior art.
A particular object of the invention is to provide a steel cord without flare.
Another object of the invention is to provide a steel cord with reduced plastic deformation.
Yet another object of the invention is to provide a steel cord with an improved robustness.
Still another object of the invention is to keep the tip rise of a rubber ply reinforced with a steel cord according to the invention low or zero.
According to a first aspect of the invention there is provided a steel cord adapted to reinforce a breaker or belt ply in a rubber tire.
The terms “adapted to reinforce a breaker or belt ply in a rubber tire” refer to steel cords where the steel filaments are made from a plain carbon steel (see example hereafter), have a filament diameter ranging from 0.10 mm to 0.40 mm, e.g. ranging from 0.12 mm to 0.35 mm, have a sufficient tensile strength (tensile strength Rm ranging from 1500 MPa to 4000 MPa and higher) and are provided with a coating promoting adhesion with rubber such as a binary brass coating or a ternary zinc-cobalt-copper or zinc-copper-nickel coating.
The steel cord comprises a core group and a sheath group. Preferably the steel cord only consists of a core group and a sheath group.
The core group has two to four core steel filaments with a first diameter dc, for example two core steel filaments with a diameter dc. Preferably the core steel filaments have about the same tensile strength and the same steel composition.
The sheath group has one to six sheath steel filaments with a second diameter ds, for example two to four sheath filaments with a second diameter ds. Preferably the sheath steel filaments have about the same tensile strength and the same steel composition.
The first diameter dc is greater than the second diameter ds. Preferably the diameter ratio dc/ds ranges from 1.10 to 1.70, preferably from 1.10 to 1.50. The two to four core steel filaments are untwisted or have a twisting step greater than 300 mm. The sheath group and the core group are twisted around each other with a cord twisting step in a cord twisting direction.
The ratio of the absolute value of the difference in residual torsions of the core group and the sheath group to the absolute value of the difference in saturation level between the core group and the sheath group ranges from 0.15 to 0.65, preferably from 0.15 to 0.60, for example from 0.15 to 0.55, for example from 0.25 to 0.50. This is valid in case the total cord has no residual torsions.
The saturation level is expressed in number of revolutions per meter.
The amount of residual torsions is also expressed in number of revolutions per meter.
The residual torsions of a steel cord or of a steel filament are determined as follows: One end of the steel cord or steel filament of a particular length is allowed to turn freely, the other end is hold fixed. The number or revolutions is counted and their direction is noted.
The way how residual torsions of a core group or of a sheath group are determined will be explained hereinafter.
The saturation level of a steel filament is the maximum number of elastic torsions (expressed as number of revolutions per meter) one can apply to a steel filament. The saturation level of a group of equal steel filaments, i.e. equal diameter, composition and tensile strength, is equal to the saturation level of an individual steel filament of that group. In practice, the saturation level is determined or measured before the twisting process.
For applied torsions in the S-direction, residual torsions which make the twisting step or twist pitch shorter have a positive sign, residual torsions which make the twisting step or twist pitch longer have a negative sign. For applied torsions in the Z-direction, the opposite is valid.
The invention is particularly suited for steel cord constructions made by means of a double twister since with a double twister the individual steel filaments may be subjected to a twist on themselves, which is not the case with steel cords made by means of a tubular strander in the normal way. In the present invention, the sheath steel filaments are preferably twisted on themselves. This individual twisting of the steel filaments, next to the twisting of groups and cord, may increase the amount of residual torsions of the sheath group.
The characterizing feature of a steel cord according to the invention can be written in following formula:
0.10≤ρ=|RTc−RTs|/|SLc−SLs|≤0.65
The ratio ρ is the ratio of the torsion gap as measured to the (maximum) torsion gap which could be obtained in case a double false twister would not be used. Due to the use of a double false twister the ratio ρ can be kept between the mentioned limits. This reduced level of difference in residual torsions between the core group and the sheath group contributes to a more robust steel cord with reduced or even total avoidance of flare and without the necessity of high levels of plastic deformation and great amplitudes of waves of the steel core filaments. Due to the reduced level of difference in residual torsions, the need for anchorage of the core filaments in the rubber ply is less prominent.
There is no need to bring the residual torsions of the core group and/or the sheath group individually or separately to zero in order to reach the advantages of absence of flare and increase in robustness. On the contrary bringing the residual torsions to zero would require too much energy in the twisting process.
According to another preferable embodiment, the amount of residual torsions of the core group is substantially different from the amount of residual torsions of the sheath group.
According to a preferable embodiment, the one to six sheath steel filaments of the steel cord of the invention are twisted around each other with a cord twisting step and in a cord twisting direction.
A preferable cord construction according to the first aspect of the invention has a core group with two core steel filaments and a sheath group with three sheath steel filaments. So a preferable cord construction is 2xdc+3xds.
As mentioned, due to the low levels of residual torsions in both the core steel filaments and the sheath steel filaments, the plastic deformation of the individual steel filaments may be reduced.
As a result of such a reduced plastic deformation, each of the core steel filaments may have a wave height hc ranging from 2.2xdc to 2.7xdc.
Similarly, each of the sheath filaments may have a wave height hs ranging from 2.2xds to 3.9xds.
Due to the reduced plastic deformation of the individual steel filaments, the linear density of the resulting invention cord is also reduced, e.g. by more than one percent. Eventually this leads to a reinforced rubber ply and tire with a reduced weight.
Preferably the steel cord according to the first aspect of the invention has no flare.
Also preferably the steel cord has a tensile strength exceeding 2500 MPa, e.g. exceeding 2700 MPa.
The steel cord preferably has a breaking load exceeding 450 Newton, e.g. exceeding 500 Newton.
According a second aspect of the invention, there is provided a rubber ply comprising a plurality of steel cords according to the first aspect of the invention. The steel cords are arranged in parallel next to each other with a density ranging from 6 ends per cm to 12 ends per cm, e.g. from 6.5 ends per cm to 11 ends per cm. The thickness of the rubber ply ranges from 0.65 mm to 1.6 mm, e.g. from 0.7 mm to 1.5 mm and is e.g. 1.2 mm. The rubber ply has a tip rise lower than 10 mm, e.g. lower than 5 mm. This reduction in tip rise facilitates the automated processing of the rubber plies in the manufacturing of tires.
Before integrating into the belt or breaker of a tyre, rubber reinforced by steel cords is cut into a ply with the form of a parallelogram, i.e. with two sharp angles and two obtuse angles. The tip rise is the phenomenon that the sharp angle of the ply may show a rise, i.e a distance to the base. The tip rise is the vertical distance in mm between a base and a sharp angle of the ply. The amount of tip rise is mainly due to the residual torsions of the individual cords. As the tip rise only concerns one corner of the ply, its amount is independent of the length and width of the rubber ply.
According to a third aspect of the present invention, there is provided equipment for manufacturing an m+n cord according to the first aspect of the invention. This equipment comprises a double-twister and supply spools positioned at a first side of the double-twister for supplying the two to four core steel filaments to the double-twister.
In case of less supply spools than the number of core filaments, some core filaments are multiple wound in parallel on the spool.
The double-twister comprises a stationary cradle. The cradle bears supply spools for supplying one to six sheath steel filaments to an assembly point inside the double-twister.
As is the case with the number of supply spools outside the double twister, there can also be less supply spools than the number of sheath filaments, namely when multiple winding has been applied.
The equipment further comprises a cord spool for receiving a twisted steel cord leaving the double-twister. This cord spool is positioned at a second side of the double-twister, preferably opposite to the first side.
The equipment further comprises a first false twister and a second false twister. The first false twister and the second false twister are both positioned between the double-twister and the cord spool.
It is due to the second false twister which rotates in a direction opposite to the first false twister, that the level of the residual torsions of both the core group and the sheath group is brought to an acceptable low level.
The terms “false twister” refer to a device that applies a number of twists in a first direction (e.g. S) to a filament or a cord, immediately followed by the same number of twist in an opposite direction (e.g. Z). The effect on the number of applied torsions is zero, but the false twister has an effect on the number of residual torsions.
According to a fourth aspect of the present invention, there is provided a method of manufacturing an m+n cord according to the first aspect of the invention.
This method comprises the following steps:
A steel cord according to the first aspect of the invention may be made in the following way.
Starting material may be a steel wire rod with a minimum carbon content of 0.65%, e.g. a minimum carbon content of 0.75%, a manganese content ranging from 0.40% to 0.70%, a silicon content ranging from 0.15% to 0.30%, a maximum sulfur content of 0.03%, a maximum phosphorus content of 0.30%, all percentages being percentages by weight. Micro-alloying elements such as chromium and copper, with percentages going from 0.10% up to 0.40% are not excluded, but are not needed.
The wire rod is firstly cleaned by mechanical descaling and/or by chemical pickling in a H2SO4 or HCl solution in order to remove the oxides present on the surface. The wire rod is then rinsed in water and is dried. The dried wire rod is then subjected to a first series of dry drawing operations in order to reduce the diameter until a first intermediate diameter.
At this first intermediate diameter d1, e.g. at about 3.0 to 3.5 mm, the dry drawn steel wire is subjected to a first intermediate heat treatment, called patenting. Patenting means first austenitizing until a temperature of about 1000° C. followed by a transformation phase from austenite to pearlite at a temperature of about 600° C.-650° C. The steel wire is then ready for further mechanical deformation.
Thereafter the steel wire is further dry drawn from the first intermediate diameter d1 until a second intermediate diameter d2 in a second number of diameter reduction steps. The second diameter d2 typically ranges from 1.0 mm to 2.5 mm.
At this second intermediate diameter d2, the steel wire is subjected to a second patenting treatment, i.e. austenitizing again at a temperature of about 1000° C. and thereafter quenching at a temperature of 600° C. to 650° C. to allow for transformation to pearlite.
If the total reduction in the first and second dry drawing step is not too big a direct drawing operation can be done from wire rod till diameter d2.
After this second patenting treatment the steel wire is usually provided with a brass coating: copper is plated on the steel wire and zinc is plated on the copper. A thermo-diffusion treatment is applied to form the brass coating.
The brass-coated steel wire is then subjected to a final series of cross-section reductions by means of wet drawing machines. The final product is a steel filament with a carbon content above 0.65 percent by weight (e.g. above 0.75 percent by weight), with a tensile strength typically above 2000 MPa (e.g. above 2500 MPa) and adapted for the reinforcement of elastomer products.
For the manufacture of a steel cord according to the present invention two different steel filament diameters are required, e.g. 0.16, 0.17 or 0.20 mm steel filaments and 0.22, 0.24 and 0.265 mm steel filaments.
Starting from the left side of
Three sheath steel filaments 116 with a filament diameter of ds are drawn from three supply spools 118 which are located in a stationary cradle (not shown) inside the double-twister 106. The three sheath steel filaments 116 are brought together with the three twisted core steel filaments 102 at the assembly point 113. At the level of the second stationary reversing pulley 114, both the core steel filaments 102 and the sheath steel filaments 116 receive a twist in the S-direction. This means that the three core steel filaments 102 are partially untwisted (from 2xZ-twists to one Z-twist) while the sheath steel filaments 116 are twisted. The assembly of two core steel filaments 102 and three sheath steel filaments 116 is guided over a second flyer 120 to a second stationary guiding pulley 122. At the level of the second stationary guiding pulley 122 the assembly receives a second twist in the S-direction. This means that the three core steel filaments 102 are now completely untwisted (from one Z-twist to zero) and that the three sheath steel filaments 116 have now been twisted twice in S-direction.
The resulting product leaving the double-twister 106 is a steel cord with a core group and a sheath group. The core group consists of three untwisted core steel filaments 102. The sheath group has three S-twisted sheath steel filaments 116. The sheath group is twisted in S-direction around the core group. This is a complete steel cord but not yet with all the features according to the invention.
The steel cord leaves the double-twister 106 and is led through a first false twister 124 which rotates in a direction 126 opposite to the rotation direction of the double-twister 106. The effect of this first false twister 124 will be explained with reference to
Subsequently the steel cord is also led to a second false twister 128 which rotates in a direction 130 opposite to the rotation direction of the first double-twister 124. The effect of this second false twister 128 will be explained with reference to
Finally a steel cord 132 possessing all the features of a steel cord according to the invention leaves the second false twister 128 and is wound upon a cord spool 134.
The abscissa shows the applied torsions (number of revolutions per meter): S in the right direction, Z in the left direction.
The ordinate shows the residual torsions (number of revolutions per meter): Z in direction upwards, S in direction downwards.
Dash line 204 shows the torsion saturation level (number of revolutions per meter) of a core steel filament 102.
Dot and dash line 206 shows the torsion saturation level (number of revolutions per meter) of a sheath steel filament 116.
The torsion saturation level 204 of a core steel filament is lower than the torsion saturation level 206 of a sheath steel filament, since the core steel filament is thicker and reaches quicker the plastic deformation zone.
Still referring to
Still referring only to
With one false twister 124, the difference in residual torsions between a core steel filament 102 and a sheath steel filament 116 is 7.5 residual revolutions per meter.
This high difference in residual torsions per meter causes instability in the steel cord and requires a high deformation degree of the core steel filaments in order to anchor the steel cord in a rubber ply and to prevent tip rise of a rubber ply reinforced with this steel cord.
The improvement of the invention is explained with reference to
Curve 208-210 is the torsion curve of a core steel filament 102. Part 208 is the part with only one false twister 124, the dash part 210 is the part with an additional second false twister 128.
Core steel filament 102 receives a first Z-twist at position a and a second Z-twist at position b. At position c the core steel filament 102 is partially untwisted because of a first S-twist. At position d, the core steel filament leaves the double-twister untwisted, i.e. with zero applied twists, because of a second S-twist. The core steel filament 102 is then sent to a first false twister 124, where it receives first twists in S-direction—point e—and immediately thereafter a first series of twists in Z-direction because of first false twister 124 and a second series of twists in Z-direction because of second false twister 128—points f-g. Finally the second series of twists in Z-direction are compensated by twists in S-direction (action of second false twister 128) to arrive at point h with zero applied twists and—only −+1.8 residual revolutions per meter.
Curve 212-214 is the torsion curve of a sheath steel filament 116. Part 212 is the part with only one false twister 124, the dash part 214 is the part with an additional second false twister 128.
Sheath steel filament 116 receives a first S-twist at c′ and a second S-twist at d′ when leaving the double-twister 106. Sheath steel filament 116 is then guided to false twister 124 where it receives first additional twists in S-direction—point e′. Thereafter, sheath steel filament 116 receives a first series of Z-twists (action of first false twister 124) and a second series of Z-twists (action of second false twister 128)—points f′-g′. Finally the second series of Z-twists are compensated by a series of S-twists (action of second false twister 128) to arrive at point h′, with a number of applied twists corresponding to the desired lay length or cord twisting step and with −2.5 residual revolutions per meter.
The number of residual torsions is determined per group, i.e. the number of residual torsions is determined for the core group as a whole and—separately—for the sheath group as a whole.
To determine the number of residual torsions per group a 4 meter length steel cord sample is taken. All residual cord torsions are first released. This 4 meter sample is fixed between two clamps which have an interdistance of 100 cm. The clamps have a rubber path in contact with the steel cord to avoid damage to the steel cord.
The purpose is to determine the number of residual torsions over this 100 cm length.
Outside the clamps, the steel cord is cut but leaving a length of about 10 cm. At one end, outside the clamps, the steel cord is plastically bent so that a length of about 5 cm points vertically upwards. The number of rotations of this bent part will indicate the number of residual torsions per meter.
For the determination of the residual torsions of the core group, one end of the steel cord is unclamped. The sheath steel filaments are unravelled by means of a gripper until past the clamp, while the bent part of the core group is kept vertical. Thereafter the core group is clamped again and the sheath steel filaments are unravelled until the second clamp. Now one is ready to determine the residual torsions in revolutions per meter of the core group: the first clamp is released again while holding the bent part of the core group vertical and thereafter the bent part is released and its number of rotations is counted.
For the determination of the residual torsions of the sheath group, one end of the steel cord is unclamped. The sheath steel filaments are unravelled by means of a gripper not only until past the first clamp but until the second clamp, while the gripper is kept horizontal so that the bent part of the sheath steel filaments is also kept stable. Once the unravelling has been done until the second clamp, one is ready to determine the residual torsions of the sheath group in revolutions per meter: the gripper releases the sheath group and the number of rotations of the bent part of the sheath group is counted.
With two false twisters 124, 128 the difference in residual torsions between the core group and the sheath group has been reduced to 4.3 residual revolutions per meter. This is a much more stable cord without flare and causing no tip rise in a rubber ply without having to deform the core steel filaments heavily.
As a matter of example, the tip rise T can be limited to 10 mm with a wave height hc of 2.7xdc and a rotation speed ω of 35%. Increasing the rotation speed ω to 75% may reduce the wave height hc to 0.36 mm without increase of tip rise T.
Referring to
As a result of the double-twisting process in the double-twister 106, the sheath steel filaments 116 are not only twisted around each other but each sheath steel filament 116, as such, also shows a twist in the same direction and to the same degree around its own longitudinal axis.
As has been explained hereabove, thanks to the action of the double false twister 128, the difference in residual torsions between the core steel filaments 102 and the sheath steel filaments 116 can be reduced. As a result of this reduction the wave height hc can also be reduced leading to a more stable and closed structure and without causing flare or tip rise.
Comparison of Prior Art Cords Versus Invention Cords
m: number of filaments in core group
n: number of filaments in sheath group
dc: diameter of core steel filaments
ds: diameter of sheath steel filaments
Rm: tensile strength of steel filaments
No DFT: prior art process without double false twister
DFT: invention process with double false twister
Factor φ: depends upon tensile strength level
Ratio ρ: ratio of difference in torsion gap measured to difference in sauration level
SLc: saturation level core group
SLs: saturation level sheath group
RTc: Residual torsions of core group
RTs: residual torsions of sheath group
HT: high-tensile strength
ST: super-high-tensile strength
UT: ultra-high-tensile strength
A high-tensile (HT) strength means a steel filament with a tensile strength between 3800-2000×d MPa and 4000-2000×d MPa, where d is the filament diameter and is expressed in mm.
A super-high-tensile (ST) strength means a steel filament with a tensile strength between 4000-2000×d MPa and 4400-2000×d MPa, where d is the filament diameter and is expressed in mm.
An ultra-high-tensile (UT) strength means a steel filament with a tensile strength above 4400-2000×d MPa.
| Number | Date | Country | Kind |
|---|---|---|---|
| 14167476 | May 2014 | EP | regional |
| Filing Document | Filing Date | Country | Kind |
|---|---|---|---|
| PCT/EP2015/057490 | 4/7/2015 | WO | 00 |
| Publishing Document | Publishing Date | Country | Kind |
|---|---|---|---|
| WO2015/169521 | 11/12/2015 | WO | A |
| Number | Name | Date | Kind |
|---|---|---|---|
| 1960426 | Zundorf | May 1934 | A |
| 3771304 | Taketomi et al. | Nov 1973 | A |
| 4408444 | Baillievier | Oct 1983 | A |
| 5285623 | Baillievier | Feb 1994 | A |
| 5487262 | De Waegenaere et al. | Jan 1996 | A |
| 5512380 | De Vos | Apr 1996 | A |
| 5581990 | Van Giel | Dec 1996 | A |
| 5743078 | Doornaert | Apr 1998 | A |
| 6365273 | Baillievier | Apr 2002 | B1 |
| 20030188525 | Kobayashi | Oct 2003 | A1 |
| 20100005774 | Fukuda | Jan 2010 | A1 |
| 20100200143 | Okamoto | Aug 2010 | A1 |
| 20110268954 | Qi | Nov 2011 | A1 |
| Number | Date | Country |
|---|---|---|
| 0466720 | Nov 1993 | EP |
| 0635597 | Jan 1995 | EP |
| 2060673 | May 2009 | EP |
| 2689939 | Jan 2014 | EP |
| H04-266441 | Sep 1992 | JP |
| H06-306784 | Nov 1994 | JP |
| 2008025040 | Feb 2008 | JP |
| 2013199189 | Oct 2013 | JP |
| 2013199190 | Oct 2013 | JP |
| 2013199191 | Oct 2013 | JP |
| 2013199193 | Oct 2013 | JP |
| 2013199194 | Oct 2013 | JP |
| 2013199195 | Oct 2013 | JP |
| 2013199717 | Oct 2013 | JP |
| 2012128372 | Sep 2012 | WO |
| Entry |
|---|
| International Search Report (ISR) dated Jun. 25, 2016, for PCT/EP2015/057490. |
| Number | Date | Country | |
|---|---|---|---|
| 20170073888 A1 | Mar 2017 | US |
