Claims
- 1. A heat sterilizable stress-free container made in accordance with the method comprising the steps of:
- forming first and second film members, each having at least two integral layers, the first of the layers formed of a material which is cross-linkable and free or essentially free of leachable plasticizers and which has a heat distortion temperature at or below 110.degree. C., the first layer material being selectively cross-linkable to obtain the desired resistance to distortion at heat sterilization temperatures, the second of the layers formed of a material which, when compared to the first layer material, is not cross-linkable and which has a heat distortion temperature above 110.degree. C.;
- positioning the first and second film members in overlapping relationship with corresponding first layers of each adjacent one another so as to form inner surfaces of the container;
- melting a peripheral region of the overlapping, adjacent first layers of the container using heat sealing elements without pre-stressing said film members to form a peripheral seal between the inner first layers of the container;
- irradiating the container so as to cross-link the first layers to obtain the desired resistance to melting; and
- sterilizing the container by exposure to heat at or above 110.degree. C. without pre-stressing the material, to form a non-stressed, non-heat shrinkable container.
- 2. A container as in claim 1 wherein said first layer has a thickness in a range of 0.005-0.010 inch and wherein said second layer has a thickness in a range of 0.002-0.004 inch.
- 3. A container as in claim 2 wherein said first layer has a thickness substantially equal to 0.006-0.008 inch.
- 4. A container as in claim 3 wherein said second layer has a thickness substantially equal to 0.002-0.004 inch.
- 5. A container as in claim 1 wherein said first layer is formed of poly(ethylene vinyl acetate).
- 6. A container as in claim 1 wherein said second layer is formed from a group consisting essentially of polyethylene, polypropylene, or copolymers, blends, and alloys thereof.
- 7. A container as in claim 6 wherein said first layer is formed of poly(ethylene vinyl acetate).
- 8. A container as in claim 7 wherein said poly(ethylene vinyl acetate) contains 10 to 35 weight percent of vinyl acetate units.
- 9. A container as in claim 1 wherein said film has an integral third layer bonded to said first layer with said third layer positioned as said inner layer of said container to prevent contact between the contents of said container and said first layer.
- 10. A container as in claim 9 with said third layer formed from material selected from a group consisting essentially of polyethylene, polypropylene, or copolymers, blends, and alloys thereof.
- 11. A container as in claim 10 wherein said third layer has a thickness in a range of 0.0001 to 0.001 inch.
- 12. A container as in claim 9 wherein said film has a fourth layer positioned between said first and said second layers to serve as an integral gas and water vapor barrier for said container.
- 13. A container as in claim 12 wherein said fourth layer is formed of poly(ethylene vinyl alcohol).
- 14. A container as in claim 12 wherein said fourth layer has a thickness in a range of 0.0001 to 0.005 inch.
- 15. A container as in claim 9 wherein said film has a fourth layer positioned within said first layer to serve as an integral gas and water vapor barrier for said container.
- 16. A container as in claim 15 wherein said fourth layer is formed of poly(ethylene vinyl alcohol) or poly (vinylidine chloride).
- 17. A container as in claim 15 wherein said fourth layer has a thickness in the range of 0.001 to 0.005 inch.
- 18. A container as in claim 1 wherein said film includes a layer positioned between said first and second layer to serve as an integral gas and water vapor barrier of said container.
- 19. A container as in claim 18 wherein said gas vapor barrier layer has a thickness in a range of 0.001 to 0.005 inch.
- 20. A container as in claim 18 wherein said second layer also serves as a water vapor barrier.
- 21. A container as in claim 1 wherein said film includes a layer positioned within said first layer to serve as an integral gas and water vapor barrier of said container.
- 22. A container as in claim 21 wherein said gas and water vapor barrier layer has a thickness in a range of 0.001 to 0.005 inch.
- 23. A container as in claim 21 wherein said second layer also serves as a water vapor barrier.
Parent Case Info
This is a divisional of copending application Ser. No. 07/143,295 now U.S. Pat. No. 4,892,604 filed on 1-7-88 which is a continuation application of now abandoned application Ser. No. 059,132, filed on June 1, 1987 which was a continuation of abandoned application Ser. No. 827,847 filed Feb. 7, 1986.
US Referenced Citations (7)
Divisions (1)
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Number |
Date |
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Parent |
143295 |
Jan 1988 |
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Continuations (2)
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Number |
Date |
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Parent |
59132 |
Jun 1987 |
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Parent |
827847 |
Feb 1986 |
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