STIMULATING WELLS USING CO2, WATER BLOCK REMOVING AGENTS, AND/OR BREAKERS TO IMPROVE WELL PRODUCTION

Information

  • Patent Application
  • 20200140744
  • Publication Number
    20200140744
  • Date Filed
    October 16, 2019
    5 years ago
  • Date Published
    May 07, 2020
    4 years ago
  • Inventors
    • Gerstner; Michael J. (Midland, TX, US)
    • Lee; George J. (Midland, TX, US)
  • Original Assignees
    • Cudd Pumping Services, Inc. (The Woodlands, TX, US)
Abstract
In an embodiment, the present disclosure relates generally to a method for well stimulation. In some embodiments, the method includes pumping a treatment fluid into a well. In some embodiments, the treatment fluid includes carbon dioxide (CO2) and a breaker, and the method further includes treating at least one of a reservoir and a wellbore of the well with the treatment fluid. In some embodiments, the breaker is a solution of stabilized chlorine dioxide (ClO2). In some embodiments, the method further includes commingling the CO2 with water and forming, as a result of the commingling, carbonic acid. In some embodiments, the method includes activating the stabilized ClO2 to form activated ClO2. In some embodiments, the activated ClO2 is formed as a result of a lowering of pH in the treatment fluid by the carbonic acid.
Description
TECHNICAL FIELD

The present disclosure relates generally to stimulating wells and more particularly, but not by way of limitation, to stimulating wells using carbon dioxide (CO2), water block removing agents, and/or breakers to improve well production.


BACKGROUND

This section provides background information to facilitate a better understanding of the various aspects of the disclosure. It should be understood that the statements in this section of this document are to be read in this light, and not as admissions of prior art.


During the life of a well, various materials may be injected, or pumped, into the well to improve hydrocarbon production or extend the life of the well. For example, but not by way of limitation, water, clay control agents, fluid loss agents, friction reducers, gelling agents, crosslinkers, proppants, polymers, surfactants, scale-reducing agents, corrosion inhibitors, or combinations of the same and like may be injected, or pumped, into the well. In some instances, it may be desirable to stimulate the well after drilling to improve well productivity or, in the case of currently producing wells, to extend the life of the well or enhance existing production. Furthermore, in certain instances, in the life of the well, it is desirable to re-stimulate the well after previous stimulation operations, for example, after hydraulic fracturing, have occurred. In some instances, carbon dioxide (CO2) can be utilized for well stimulation and re-stimulation.


SUMMARY OF THE INVENTION

This summary is provided to introduce a selection of concepts that are further described below in the Detailed Description. This summary is not intended to identify key or essential features of the claimed subject matter, nor is it to be used as an aid in limiting the scope of the claimed subject matter.


In an embodiment, the present disclosure relates generally to a method for well stimulation. In some embodiments, the method includes pumping a treatment fluid into a well. In some embodiments, the treatment fluid includes carbon dioxide (CO2) and a breaker, and the method further includes treating at least one of a reservoir and a wellbore of the well with the treatment fluid.


In some embodiments, the breaker can include, without limitation, guar breakers, friction reducer breakers, slickwater breakers, oxidative breakers, enzyme breakers, gel breakers, ammonium persulfate, polyacrylamide breakers, or combinations thereof. In some embodiments, the breaker is a solution. In some embodiments, the solution includes stabilized chlorine dioxide (ClO2). In some embodiments, the solution has a concentration of 5% v/v of the stabilized ClO2.


In some embodiments, the method further includes commingling the CO2 with water and forming, as a result of the commingling, carbonic acid. In some embodiments, the method includes activating the stabilized ClO2 to form activated ClO2. In some embodiments, the activated ClO2 is formed as a result of a lowering of pH in the treatment fluid by the carbonic acid. In some embodiments, the lowering of pH results in the treatment fluid having a pH between about 4 to about 5. In some embodiments, the activated ClO2 is formed at a predetermined depth in the well based, at least in part, on a concentration of the CO2 and the stabilized ClO2 in the treatment fluid. In some embodiments, the breaker is in a range of about 20% to about 75% total volume of the treatment fluid.


In some embodiments, the method includes pumping a treated spacer into the well. In some embodiments, the treated spacers include a diverter agent to divert the treatment fluid to a particular zone of interest. In some embodiments, the treatment fluid further includes a water block removing agent that can include, without limitation, stimulation surfactants, ethoxylated surfactants, sulfonated surfactants, citrus terpenes, alcohols, ionic surfactants, nonionic surfactants, cationic surfactants, anionic surfactants, amphoteric surfactants, flow-back enhancers, emulsifiers, dispersants, oil-wetters, water-wetters, foamers, defoamers, or combinations thereof. In some embodiments, the water block removing agent is in a range of about 20% to about 75% total volume of the treatment fluid. In some embodiments, the CO2 is in a range of about 20% to about 75% total volume of the treatment fluid.


In some embodiments, the method further includes shutting-in the well for a predetermined period of time and flowing back the well after the predetermined period of time. In some embodiments, the treating includes at least one of mobilizing hydrocarbons in the reservoir, freeing hydrocarbons in the reservoir, lowering surface tension of residual fluids in the reservoir, and removing damage caused by residual material from previous fluids introduced into the well. In some embodiments, the treatment fluid further includes at least one of clay control agents, surfactants, foaming agents, fluid loss additives, scale reducing agents, corrosion inhibitors, biocides, and pH control additives.


In an additional embodiment, the present disclosure pertains to a method for well stimulation. In some embodiments, the method includes pumping a treatment fluid into a well, where the treatment fluid includes CO2, stabilized ClO2, and a water block removing agent that includes, without limitation, stimulation surfactants, ethoxylated surfactants, sulfonated surfactants, citrus terpenes, alcohols, ionic surfactants, nonionic surfactants, cationic surfactants, anionic surfactants, amphoteric surfactants, flow-back enhancers, emulsifiers, dispersants, oil-wetters, water-wetters, foamers, defoamers, or combinations thereof. In some embodiments, the method also includes commingling the CO2 with water, forming, as a result of the commingling, carbonic acid, lowering pH of the treatment fluid with the carbonic acid, activating the stabilized ClO2 to form activated ClO2, where the activating occurs at a predetermined depth based, at least in part, on a concentration of the CO2 and the stabilized ClO2 in the treatment fluid, and where the activated ClO2 is formed due to a lowering of pH in the treatment fluid by the carbonic acid. In some embodiments, the method further includes treating at least one of a reservoir and a wellbore of the well with the treatment fluid.





BRIEF DESCRIPTION OF THE DRAWINGS

A more complete understanding of the subject matter of the present disclosure may be obtained by reference to the following Detailed Description when taken in conjunction with the accompanying Drawings wherein:



FIG. 1 illustrates wellhead rate, pressure, slurry rate, and CO2 rate during execution of a planned well treatment; and



FIG. 2 illustrates net bottom-hole pressure during the executed treatment.





DETAILED DESCRIPTION

It is to be understood that the following disclosure provides many different embodiments, or examples, for implementing different features of various embodiments. Specific examples of components and arrangements are described below to simplify the disclosure. These are, of course, merely examples and are not intended to be limiting. The section headings used herein are for organizational purposes and are not to be construed as limiting the subject matter described.


In general, the present disclosure relates to well stimulation. Well stimulation generally refers to a well intervention process performed on an oil or gas well to increase, restore, or enhance the productivity of the well by improving the flow of hydrocarbons from the reservoir into the wellbore. In various instances, well stimulation can involve a method in which carbon dioxide (CO2) is injected into the reservoir of the well to increase production by reducing hydrocarbon viscosity and improving miscible, or partially miscible, displacement of hydrocarbons into the wellbore. CO2 stimulation can be used as a first stimulation operation or any subsequent stimulation operation (re-stimulation) on a well.


However, standard CO2 injections can have limitations, such as, for example: (i) failing to lower surface tension of certain fluids in the reservoir that impede hydrocarbon flow into the wellbore (e.g. treatment fluids after hydraulic fracturing); and (ii) failing to remove damage caused by added materials in various fluids introduced into the reservoir (e.g. during hydraulic fracturing). In some instances, these fluids or materials are introduced into the reservoir as a result of drilling operations, completion operations, well stimulation operations, such as, for example, hydraulic fracturing or acidizing, well intervention operations, such as, for example, fishing, milling, remedial work, or fluid swaps, and combinations of the same and like.


In instances where a well is subjected to hydraulic fracturing, treatment fluids are pumped at a high pressure and high rate into a zone, or area of interest, of the reservoir to be treated, causing a fracture to form in the formation of the rock matrix within the zone. Typically, the fractures extend away from the wellbore in opposing directions according to the natural stresses within the formation. During hydraulic fracturing, proppant (e.g. sand) is mixed with the treatment fluids to keep the fracture open when the hydraulic fracturing is completed and the pressure acting against the formation has subsided. While hydraulic fracturing creates high-conductivity communication with a large area of the formation, during the life of the well, the formation may need to undergo re-stimulation, and in these instances, CO2 stimulations (e.g. CO2 injections) can be utilized as re-stimulation efforts.


However, once hydraulic fracturing has occurred in a particular well, conventional CO2 stimulations become less productive as the formation has been exposed to various treatment, or fracturing, fluids and materials contained therein. As discussed above, standard CO2 injections have limitations, and these limitations are often exacerbated by the use of treatment fluids used in hydraulic fracturing. For example, in standard re-stimulation of a well, conventional CO2 stimulations fail to lower the surface tension of the treatment fluids left in the reservoir (e.g. guar-based gels), and additionally, fail to remove damage caused by added materials (e.g. friction reducers) in the treatment fluids.


As such, in view of the foregoing, an embodiment of the present disclosure relates generally to a stimulation method utilizing CO2 to stimulate a well. In some embodiments, the stimulation method utilizes CO2 and water to stimulate the well. In some embodiments, the stimulation method further utilizes a water block removing agent to stimulate the well. In some embodiments, the stimulation method further utilizes a breaker to stimulate the well. In some embodiments, the stimulation method utilizes a combination of one or more of the CO2, the water, the water block removing agent, and the breaker to stimulate the well.


Furthermore, an additional embodiment of the present disclosure relates to a treatment fluid including CO2 for well stimulation. In some embodiments, the treatment fluid includes CO2 and water for well stimulation. In some embodiments, the treatment fluid further includes a water block removing agent for well stimulation. In some embodiments, the treatment fluid further includes a breaker for well stimulation. In some embodiments, the treatment fluid includes a combination of one or more of the CO2, the water, the water block removing agent, and the breaker for well stimulation.


In some embodiments, the CO2 can be in a range of about 20% to about 75% total volume of fluid. In some embodiments, the water block removing agent can be in a range of about 0% to about 75% total volume of fluid. In some embodiments, the breaker can be in a range of about 0% to about 75% total volume of fluid. In some embodiments, the water block removing agent can be in a range of about 20% to about 75% total volume of fluid. In some embodiments, the breaker can be in a range of about 20% to about 75% total volume of fluid.


In some embodiments, the well can be a hydrocarbon well. In some embodiments, the well can be a gas well. In some embodiments, the well can be an oil well. In some embodiments, the well can be a vertical well. In some embodiments, the well can be a horizontal well. In some embodiments, the well formation can be oil forming, natural gas forming, or combinations thereof. In some embodiments, the well can have a shale formation that can include, without limitation, Bakken shale formation, Barnett shale formation, Eagle Ford shale formation, Fayetteville shale formation, Haynesville shale formation, Marcellus shale formation, Niobrara shale formation, Permian Basin shale formation, Utica shale formation, Wolfcamp shale formation, or Woodford shale formation. In some embodiments, the well can be an offshore or land based well. In some embodiments, the well can be a shallow, deep, or ultra-deep well.


In some embodiments, the water block removing agent can decrease interfacial tension and shift reservoir wettability. In some embodiments, the water block removing agent can a surfactant. In some embodiments, the water block removing agent can include, without limitation, stimulation surfactants, ethoxylated surfactants, sulfonated surfactants, citrus terpenes, alcohols, ionic surfactants, nonionic surfactants, cationic surfactants, anionic surfactants, amphoteric surfactants, flow-back enhancers, emulsifiers, dispersants, oil-wetters, water-wetters, foamers, defoamers, or combinations of the same and like.


In some embodiments, the breaker breaks down gels or other chemicals, scales, or corrosion within the reservoir or in the wellbore. In some embodiments, the breaker can include, without limitation, guar breakers, friction reducer breakers, slickwater breakers, oxidative breakers, enzyme breakers, gel breakers, ammonium persulfate, polyacrylamide breakers, or combinations of the same and like.


Chlorine dioxide (ClO2) is a powerful and highly selective oxidizer that can be used, without limitation, to eliminate sulfide deposits, eliminate biofilm and polymer residues, neutralize hydrogen sulfide, and dissolve plugging agents, such as, but not limited to, iron sulfide and polymers. As such, in some embodiments, the breaker can be ClO2. In some embodiments, the ClO2 is a stabilized ClO2. In some embodiments, the ClO2 is a 5% v/v solution of stabilized ClO2. In embodiments where the breaker is stabilized ClO2, the combination of CO2, water, and stabilized ClO2 allows for the commingling of each constituent part in order to form activated ClO2 downhole allowing for improved well stimulation by removing damage caused by added materials from various fluids introduced into the reservoir or wellbore. In some embodiments, generation of carbonic acid, as a result of mixing water and CO2 during stimulation treatment, activates the stabilized ClO2 downhole. In some embodiments, concentrations of the CO2, the water, or the stabilized ClO2 can allow for the activation of the stabilized ClO2 at a particular depth. For example, the CO2, the water, and the stabilized ClO2 can have concentrations chosen such that the commingling forms carbonic acid in concentrations adequate to convert the stabilized ClO2 to activated ClO2 at a desired depth in the well.


In some embodiments, the stabilized ClO2 becomes activated upon reduction in pH of the treatment fluid. For example, in some embodiments, the reduction in pH occurs in the treatment fluid when CO2 commingles with water to form carbonic acid. In this example, the carbonic acid causes a decrease in pH of the treatment fluid. In this manner, the activation of the stabilized ClO2 can be controlled by a treatment schedule created for the stimulation method. In some embodiments, the controlled activation can be utilized to allow for various activation percentages of the ClO2 activated from the stabilized ClO2. This allows for the controlled activation of the stabilized ClO2 at a desired depth in the well. As such, based on wellbore conditions and a desired activation percent at a zone of interest, the treatment scheduled can be designed to allow for optimal activated ClO2 to enter into formation. This type of controlled activation allows for the stabilized ClO2 to be activated near, or at, the zone of interest. In this manner, the ClO2 does not unnecessarily react with components in the wellbore before reaching the desired depth, as is typical with conventional stimulation methods utilizing breakers. This further allows for the control of percent-activated ClO2 at desired depths. For instance, stabilized ClO2 can be converted to 1 to 100% activated ClO2 at any desired depth by controlling the CO2, the water, and the stabilized ClO2 concentrations.


In some embodiments, the pH range of the treatment fluid can be lowered to about 4 to about 5 in order to activate the stabilized ClO2. In some embodiments, upon activation of the stabilized ClO2, the ClO2 forms dissolved, activated, ClO2 solution that can be injected, or pumped, into the reservoir of the well. This downhole activation of stabilized ClO2 is notable because ClO2 is a true gas dissolved in water, and thus, will behave as a nano-fluid allowing it to permeate into the rock matrix in a unique manner. As such, activated ClO2 downhole allows for better permeability compared to traditional breakers into the rock matrix of the reservoir than conventional CO2 stimulation methods. This allows for the enhanced removal of damages caused by added materials, such as friction reducers or gels, introduced into the reservoir.


In some embodiments, the CO2 utilized in stimulation methods can be in a range of about 20% to about 75% total volume of fluid. In some embodiments, the stabilized ClO2 utilized in stimulation methods can be in a range of about 0% to about 75% total volume of fluid. In some embodiments, the water block removing agent utilized in stimulation methods can be in a range of about 0% to about 75% total volume of fluid. In some embodiments, the stabilized ClO2 utilized in stimulation methods can be in a range of about 20% to about 75% total volume of fluid. In some embodiments, the water block removing agent utilized in stimulation methods can be in a range of about 20% to about 75% total volume of fluid.


In some embodiments, the activation of the stabilized ClO2 can be delayed. In some embodiments, the activation of the stabilized ClO2 can be immediate or near immediate, for example, in shallow wells or in wells in which near-surface areas needs to undergo a treatment to remove excess buildup of gels, friction reducing agents, sulfides, such as iron sulfide, polymers, scale, or combinations of the same and like.


In such embodiments where immediate or near immediate activation of the stabilized ClO2 is desired, the stabilized ClO2 can be combined with mineral acid to partially, or fully, activate the stabilized ClO2 to 1% to 100% activated ClO2. In some embodiments, the stabilized ClO2 is combined with an organic acid to partially, or fully, activate the stabilized ClO2 to 1% to 100% activated ClO2.


In some embodiments, the mineral acid can include, without limitation, hydrochloric acid, nitric acid, phosphoric acid, sulfuric acid, boric acid, hydrofluoric acid, hydrobromic acid, perchloric acid, hydroiodic acid, or combinations of the same and like. In some embodiments, the organic acid can include, without limitation, lactic acid, acetic acid, formic acid, citric acid, oxalic acid, uric acid, malic acid, glyoxylic acid, glycolic acid, or combinations of the same and like.


In some embodiments, the breaker can be sodium chlorite (NaClO2). In this particular embodiment, the combination of CO2, water, and NaClO2 allows for the commingling of each constituent part in order to form ClO2 downhole allowing for improved well stimulation by removing damage caused by added materials in from various fluids introduced into the reservoir. In some embodiments, generation of carbonic acid, as a result of mixing water and CO2 during stimulation treatment, converts the NaClO2 to ClO2 downhole in a similar manner to that of the conversion of stabilized ClO2 to activated ClO2 as described above.


In some embodiments, generation of carbonic acid, as a result of mixing water and CO2 during stimulation treatment, converts the NaClO2 to ClO2 downhole. In some embodiments, concentrations of the CO2, the water, or the NaClO2 can allow for the conversion of the NaClO2 to ClO2 at a particular depth. For example, the CO2, the water, and the NaClO2 can have concentrations chosen such that the commingling forms carbonic acid in concentrations adequate to convert the NaClO2 to ClO2 at a desired depth in the well.


In some embodiments, the NaClO2 converts to ClO2 upon reduction in pH of the treatment fluid. For example, in some embodiments, the reduction in pH occurs in the treatment fluid when CO2 commingles with water to form carbonic acid. In this example, the carbonic acid causes a decrease in pH of the treatment fluid. In this manner, the conversion of NaClO2 to ClO2 can be controlled by a treatment schedule created for the stimulation method. In some embodiments, the controlled conversion can be utilized to allow for various percentages of the ClO2 to be converted from the NaClO2. This allows for the controlled conversion of the NaClO2 at a desired depth in the well. As such, based on wellbore conditions and a desired ClO2 amounts at a zone of interest, the treatment scheduled can be designed to allow for optimal ClO2 to enter into formation. This type of controlled activation allows for the NaClO2 to be converted near, or at, the zone of interest to ClO2. In this manner, the ClO2 does not unnecessarily react with components in the wellbore before reaching the desired depth, as is typical with conventional stimulation methods using breakers. This further allows for the control of percentage of the ClO2 at desired depths. For instance, NaClO2 can be converted to 1% to 100% ClO2 at any desired depth by controlling the CO2, the water, and the NaClO2 concentrations.


The downhole generation of ClO2, similar to the activation of ClO2 from stabilized ClO2, is notable as well, as ClO2 is a true gas dissolved in water, and thus, will behave as a nano-fluid allowing it to permeate into the rock matrix in a unique manner similar to that of ClO2 activated from stabilized ClO2. As such, the addition of NaClO2 to form ClO2 downhole allows for better permeability of a breaker into the rock matrix of the reservoir than conventional CO2 stimulation methods. This allows for the enhanced removal of damages caused by added materials, such as friction reducers or gels, introduced into the reservoir.


In some embodiments, the CO2 utilized in stimulation methods can be in a range of about 20% to about 75% total volume of fluid. In some embodiments, the NaClO2 utilized in stimulation methods can be in a range of about 0% to about 75% total volume of fluid. In some embodiments, the water block removing agent utilized in stimulation methods can be in a range of about 0% to about 75% total volume of fluid. In some embodiments, the NaClO2 utilized in stimulation methods can be in a range of about 20% to about 75% total volume of fluid. In some embodiments, the water block removing agent utilized in stimulation methods can be in a range of about 20% to about 75% total volume of fluid.


In some embodiments, the NaClO2 is a partially activated NaClO2. In some embodiments, the NaClO2 is combined with mineral acid, such as those described above, to partially activate the NaClO2 to 1% to 100% ClO2. In some embodiments, the NaClO2 is combined with an organic acid, such as those described above, to partially activate the NaClO2 to 1% to 100% ClO2. In some embodiments, the stimulation method utilizing a combination of CO2, water, and NaClO2 can further include a buffering system, for example, but not limited to, a combination of pH buffers, to allow for a smooth and controlled reaction for conversion of NaClO2 to ClO2.


In some embodiments, the stimulation methods and compositions disclosed herein can further include, without limitation, clay control agents, surfactants, foaming agents, fluid loss additives, scale reducing agents, corrosion inhibitors, biocides, pH control additives, or combinations of the same and like.


In a particular embodiment, the stimulation method can include injecting, or pumping, a treatment fluid including CO2, water, for example, fresh water, a water block removing agent, and a breaker into the formation of a well thereby improving hydrocarbon production. In some embodiments, the water block removing agent can be the water block removing agent as discussed above. In some embodiments, the breaker can be the breaker as discussed above. In some embodiments, the breaker can be stabilized ClO2. In some embodiments, the breaker can be NaClO2. In some embodiments, diverters can be utilized during the injection process to direct the treatment fluid to a particular zone, or area, of interest in the well. In these embodiments, diverters can, for example, isolate perforation zones of interest in the well such that the treatment fluid bypasses other perforation zones.


In some embodiments, the diverters can include, without limitation, degradable ball plugs, biodegradable ball plugs, ball plugs, frac plugs, composite plugs, bridge plugs, drillable plugs, drillable composite plugs, drillable frac plugs, or combinations of the same and like. In some embodiments, the diverters can be a part of the treatment fluid. In some embodiments, the diverters can be added on an intermittent basis to the treatment fluid, for example, during certain intervals of a treatment schedule, as illustrated below. In certain embodiments, such as those with drillable plugs, diverters can be added before the stimulation method in order to isolate a zone of interest.


In some embodiments, a buffering system, for example, but not limited to, a combination of pH buffers, can be utilized in the stimulation method in order to allow for a smooth and controlled reaction of NaClO2 to ClO2 in embodiments where the breaker is NaClO2. In some embodiment, the well undergoing the treatment method disclosed herein may be subsequently shut-in for an extended, predetermined, period of time to maximize the benefits of the treatment fluid on the formation. In some embodiments, after shut-in, the well can then be flown back and placed back into production.


In some embodiments, the CO2, the water, the water block removing agent, and the breaker can be injected, or pumped, into the well together. In some embodiments, the CO2, the water, the water block removing agent, and the breaker can be each, individually, be injected, or pumped, at different stages of the stimulation treatment. In some embodiments, the CO2, the water, the ClO2, and the water block removing agent can be injected, or pumped, into the well together. In some embodiments, the CO2, the water, the ClO2, and the water block removing agent can be each, individually, injected, or pumped, at different stages of the stimulation treatment. In embodiments where a mineral acid or an organic acid is utilized to partially, or fully, activate or convert the ClO2, the mineral acid or the organic acid can be injected, or pumped, into the well with the treatment fluid or be injected, or pumped, at different stages of the stimulation treatment.


In some embodiments, the CO2, the water, the NaClO2, and the water block removing can be injected, or pumped, into the well together. In some embodiments, the CO2, the water, the NaClO2, and the water block removing agent can be each, individually, be injected, or pumped, at different stages of the stimulation treatment. In embodiments where a mineral acid or an organic acid is utilized to partially, or fully, convert the NaClO2, the mineral acid or the organic acid can be injected, or pumped, into the well with the treatment fluid or be injected, or pumped, at different stages of the stimulation treatment.


As illustrated in the non-limiting example provided herein below, in some embodiments, breakers can be injected, or pumped, into the well during various stages of the stimulation treatment. Moreover, in some embodiments, water block removing agents can be periodically injected, or pumped, into the well during various stages of the stimulation treatment. Furthermore, in some embodiments, diverters can be periodically injected, or pumped, during various stages of the stimulation treatment. In some embodiments, CO2 can also be injected, or pumped, together with at least one of the breakers, the water block removing agents, and the diverters. Additionally, in some embodiments, additional breakers, such as, for example, ammonium persulfate, and additional water block removing agents can also be injected, or pumped, into the well during various stages of the stimulation treatment.


Without being bound by theory, it is believed the CO2 will disperse throughout the formation and mobilize hydrocarbons in the reservoir, thereby freeing the hydrocarbons to be able to flow into the wellbore. In addition, the water block removing agents lower the surface tension of residual treatment, or fracturing, fluids, thereby removing them from being an impediment for hydrocarbons to flow into the wellbore. Moreover, the various breakers remove any damage caused by residuals from adding materials to the treatment, or fracturing, fluids during a previous hydraulic fracturing operation.


Working Examples

Reference will now be made to more specific embodiments of the present disclosure and data that provides support for such embodiments. However, it should be noted that the disclosure below is for illustrative purposes only and is not intended to limit the scope of the claimed subject matter in any way.


Below illustrates a planned treatment schedule utilizing an embodiment of the stimulation methods and compositions, as presented above. The illustrative example below was planned for a well with a measured depth of approximately 18,080 ft, with perforations ranging from a measured depth of 11,890 ft (10,520 ft true vertical depth) to 17,981 ft (10,520 ft true vertical depth). The well had a bottom-hole fracture pressure of 8,942 psi having a 0.850 psi/ft fracture gradient (Wolfcamp formation), and a reservoir temperature of approximated 160° F. with an estimated surface temperature of 80° F. Treatment injection were to be conducted through 7 in outer diameter 26.0 lbs/ft casing (6.276 in inner diameter) from 0 to 9,717 ft, following 4 in outer diameter 11.6 lbs/ft casing (3.428 in inner diameter) to 18,080 ft. The perforation count was 612 having approximate hole sizes of about 0.410 in.


Table 1, shown below, illustrates the planned treatment schedule of the well. As can be seen below, after pumping rate is established with treated water, ClO2 treatment and treated spacers are to be alternately pumped at approximately 30 bpm. After each ClO2 treatment, diverters are to be injected into the well via treated spacers to force treatment fluid to the next zone, with the exception of the last ClO2 treatment, in which the well is to be flushed with CO2. A total of 17 stages are to be conducted over the span of 132.7 min via a treatment of 69 steps.

















TABLE 1








Cln.
Cln.
Ttl.
Stg.
Cum.
Time





Vol.
Vol.
Rate
Time
Time
Remaining


Step #
Fluid
Stage Type
(bbls)
(gals)
(bpm)
(mins)
(mins)
(mins)























1
Treated Water
Establish
119.0
5,000
30.0
4.0
4.0
132.7




Rate








2
ClO2 Treatment
Stage 1
95.2
4,000
30.0
3.2
7.1
128.8


3
Treated Spacer
Drop 18
6.0
250
30.0
0.2
7.3
125.6




Diverters








4
ClO2 Treatment

95.2
4,000
30.0
3.2
10.5
125.4


5
Treated Spacer
Drop 18
6.0
250
30.0
0.2
10.7
122.2




Diverters








6
ClO2 Treatment
Stage 2
83.3
3,500
30.0
2.8
13.5
122.0


7
Treated Spacer
Drop 18
6.0
250
30.0
0.2
13.7
119.2




Diverters








8
ClO2 Treatment

83.3
3,500
30.0
2.8
16.5
119.0


9
Treated Spacer
Drop 18
6.0
250
30.0
0.2
16.7
116.3




Diverters








10
ClO2 Treatment
Stage 3
83.3
3,500
30.0
2.8
19.4
116.1


11
Treated Spacer
Drop 18
6.0
250
30.0
0.2
19.6
113.3




Diverters








12
ClO2 Treatment

83.3
3,500
30.0
2.8
22.4
113.1


13
Treated Spacer
Drop 18
6.0
250
30.0
0.2
22.6
110.3




Diverters








14
ClO2 Treatment
Stage 4
83.3
3,500
30.0
2.8
25.4
110.1


15
Treated Spacer
Drop 18
6.0
250
30.0
0.2
25.6
107.3




Diverters








16
ClO2 Treatment

83.3
3,500
30.0
2.8
28.4
107.1


17
Treated Spacer
Drop 18
6.0
250
30.0
0.2
28.6
104.4




Diverters








18
ClO2 Treatment
Stage 5
83.3
3,500
30.0
2.8
31.3
104.2


19
Treated Spacer
Drop 18
6.0
250
30.0
0.2
31.5
101.4




Diverters








20
ClO2 Treatment

83.3
3,500
30.0
2.8
34.3
101.2


21
Treated Spacer
Drop 18
6.0
250
30.0
0.2
34.5
98.4




Diverters








22
ClO2 Treatment
Stage 6
95.2
4,000
30.0
3.2
37.7
98.2


23
Treated Spacer
Drop 18
6.0
250
30.0
0.2
37.9
95.0




Diverters








24
ClO2 Treatment

95.2
4,000
30.0
3.2
41.1
94.8


25
Treated Spacer
Drop 18
6.0
250
30.0
0.2
41.3
91.7




Diverters








26
ClO2 Treatment
Stage 7
95.2
4,000
30.0
3.2
44.4
91.5


27
Treated Spacer
Drop 18
6.0
250
30.0
0.2
44.6
88.3




Diverters








28
ClO2 Treatment

95.2
4,000
30.0
3.2
47.8
88.1


29
Treated Spacer
Drop 18
6.0
250
30.0
0.2
48.0
84.9




Diverters








30
ClO2 Treatment
Stage 8
95.2
4,000
30.0
3.2
51.2
84.7


31
Treated Spacer
Drop 18
6.0
250
30.0
0.2
51.4
81.5




Diverters








32
ClO2 Treatment

95.2
4,000
30.0
3.2
54.6
81.3


33
Treated Spacer
Drop 18
6.0
250
30.0
0.2
54.8
78.2




Diverters








34
ClO2 Treatment
Stage 9
95.2
4,000
30.0
3.2
57.9
78.0


35
Treated Spacer
Drop 18
6.0
250
30.0
0.2
58.1
74.8




Diverters








36
ClO2 Treatment

95.2
4,000
30.0
3.2
61.3
74.6


37
Treated Spacer
Drop 18
6.0
250
30.0
0.2
61.5
71.4




Diverters








38
ClO2 Treatment
Stage 10
95.2
4,000
30.0
3.2
64.7
71.2


39
Treated Spacer
Drop 18
6.0
250
30.0
0.2
64.9
68.1




Diverters








40
ClO2 Treatment

95.2
4,000
30.0
3.2
68.1
67.9


41
Treated Spacer
Drop 18
6.0
250
30.0
0.2
68.3
64.7




Diverters








42
ClO2 Treatment
Stage 11
95.2
4,000
30.0
3.2
71.4
64.5


43
Treated Spacer
Drop 18
6.0
250
30.0
0.2
71.6
61.3




Diverters








44
ClO2 Treatment

95.2
4,000
30.0
3.2
74.8
61.1


45
Treated Spacer
Drop 18
6.0
250
30.0
0.2
75.0
57.9




Diverters








46
ClO2 Treatment
Stage 12
95.2
4,000
30.0
3.2
78.2
57.7


47
Treated Spacer
Drop 18
6.0
250
30.0
0.2
78.4
54.6




Diverters








48
ClO2 Treatment

95.2
4,000
30.0
3.2
81.5
54.4


49
Treated Spacer
Drop 18
6.0
250
30.0
0.2
81.7
51.2




Diverters








50
ClO2 Treatment
Stage 13
83.3
3,500
30.0
2.8
84.5
51.0


51
Treated Spacer
Drop 18
6.0
250
30.0
0.2
84.7
48.2




Diverters








52
ClO2 Treatment

83.3
3,500
30.0
2.8
87.5
48.0


53
Treated Spacer
Drop 18
6.0
250
30.0
0.2
87.7
45.2




Diverters








54
ClO2 Treatment
Stage 14
131.0
5,500
30.0
4.4
92.1
45.0


55
Treated Spacer
Drop 18
6.0
250
30.0
0.2
92.3
40.7




Diverters








56
ClO2 Treatment

131.0
5,500
30.0
4.4
96.6
40.5


57
Treated Spacer
Drop 18
6.0
250
30.0
0.2
96.8
36.1




Diverters








58
ClO2 Treatment
Stage 15
131.0
5,500
30.0
4.4
101.2
35.9


59
Treated Spacer
Drop 18
6.0
250
30.0
0.2
101.4
31.5




Diverters








60
ClO2 Treatment

131.0
5,500
30.0
4.4
105.8
31.3


61
Treated Spacer
Drop 18
6.0
250
30.0
0.2
106.0
27.0




Diverters








62
ClO2 Treatment
Stage 16
83.3
3,500
30.0
2.8
108.7
26.8


63
Treated Spacer
Drop 18
6.0
250
30.0
0.2
108.9
24.0




Diverters








64
ClO2 Treatment

83.3
3,500
30.0
2.8
111.7
23.8


65
Treated Spacer
Drop 18
6.0
250
30.0
0.2
111.9
21.0




Diverters








66
ClO2 Treatment
Stage 17
71.4
3,000
30.0
2.4
114.3
20.8


67
Treated Spacer
Drop 18
6.0
250
30.0
0.2
114.5
18.5




Diverters








68
ClO2 Treatment

71.4
3,000
30.0
2.4
116.9
18.3


69
CO2
Flush
476.2
20,000
30.0
15.9
132.7
15.9









Table 2, shown below, illustrates a planned blender schedule for the stimulation of the well.

















TABLE 2






Clean
Stg.
Cum.
Blender
Slurry
Stg.
Cum.
Stg.



Rate
Clean.
Clean
Conc.
Rate
Slurry
Slurry
Time


Step #
(bpm)
(bbls)
(bbls)
(lb/gal)
(bpm)
(bbls)
(bbls)
(mins)























1
15.00
59.5
59.5
0.00
15.00
59.5
59.5
4.0


2
15.00
47.6
107.1
0.00
15.00
47.6
107.1
3.2


3
15.00
3.0
110.1
0.00
15.00
3.0
110.1
0.2


4
15.00
47.6
157.7
0.00
15.00
47.6
157.7
3.2


5
15.00
3.0
160.7
0.00
15.00
3.0
160.7
0.2


6
15.00
41.7
202.4
0.00
15.00
41.7
202.4
2.8


7
15.00
3.0
205.4
0.00
15.00
3.0
205.4
0.2


8
15.00
41.7
247.0
0.00
15.00
41.7
247.0
2.8


9
15.00
3.0
250.0
0.00
15.00
3.0
250.0
0.2


10
15.00
41.7
291.7
0.00
15.00
41.7
291.7
2.8


11
15.00
3.0
294.6
0.00
15.00
3.0
294.6
0.2


12
15.00
41.7
336.3
0.00
15.00
41.7
336.3
2.8


13
15.00
3.0
339.3
0.00
15.00
3.0
339.3
0.2


14
15.00
41.7
381.0
0.00
15.00
41.7
381.0
2.8


15
15.00
3.0
383.9
0.00
15.00
3.0
383.9
0.2


16
15.00
41.7
425.6
0.00
15.00
41.7
425.6
2.8


17
15.00
3.0
428.6
0.00
15.00
3.0
428.6
0.2


18
15.00
41.7
470.2
0.00
15.00
41.7
470.2
2.8


19
15.00
3.0
473.2
0.00
15.00
3.0
473.2
0.2


20
15.00
41.7
514.9
0.00
15.00
41.7
514.9
2.8


21
15.00
3.0
517.9
0.00
15.00
3.0
517.9
0.2


22
15.00
47.6
565.5
0.00
15.00
47.6
565.5
3.2


23
15.00
3.0
568.5
0.00
15.00
3.0
568.5
0.2


24
15.00
47.6
616.1
0.00
15.00
47.6
616.1
3.2


25
15.00
3.0
619.0
0.00
15.00
3.0
619.0
0.2


26
15.00
47.6
666.7
0.00
15.00
47.6
666.7
3.2


27
15.00
3.0
669.6
0.00
15.00
3.0
669.6
0.2


28
15.00
47.6
717.3
0.00
15.00
47.6
717.3
3.2


29
15.00
3.0
720.2
0.00
15.00
3.0
720.2
0.2


30
15.00
47.6
767.9
0.00
15.00
47.6
767.9
3.2


31
15.00
3.0
770.8
0.00
15.00
3.0
770.8
0.2


32
15.00
47.6
818.5
0.00
15.00
47.6
818.5
3.2


33
15.00
3.0
821.4
0.00
15.00
3.0
821.4
0.2


34
15.00
47.6
869.0
0.00
15.00
47.6
869.0
3.2


35
15.00
3.0
872.0
0.00
15.00
3.0
872.0
0.2


36
15.00
47.6
919.6
0.00
15.00
47.6
919.6
3.2


37
15.00
3.0
922.6
0.00
15.00
3.0
922.6
0.2


38
15.00
47.6
970.2
0.00
15.00
47.6
970.2
3.2


39
15.00
3.0
973.2
0.00
15.00
3.0
973.2
0.2


40
15.00
47.6
1,020.8
0.00
15.00
47.6
1,020.8
3.2


41
15.00
3.0
1,023.8
0.00
15.00
3.0
1,023.8
0.2


42
15.00
47.6
1,071.4
0.00
15.00
47.6
1,071.4
3.2


43
15.00
3.0
1,074.4
0.00
15.00
3.0
1,074.4
0.2


44
15.00
47.6
1,122.0
0.00
15.00
47.6
1,122.0
3.2


45
15.00
3.0
1,125.0
0.00
15.00
3.0
1,125.0
0.2


46
15.00
47.6
1,172.6
0.00
15.00
47.6
1,172.6
3.2


47
15.00
3.0
1,175.6
0.00
15.00
3.0
1,175.6
0.2


48
15.00
47.6
1,223.2
0.00
15.00
47.6
1,223.2
3.2


49
15.00
3.0
1,226.2
0.00
15.00
3.0
1,226.2
0.2


50
15.00
41.7
1,267.9
0.00
15.00
41.7
1,267.9
2.8


51
15.00
3.0
1,270.8
0.00
15.00
3.0
1,270.8
0.2


52
15.00
41.7
1,312.5
0.00
15.00
41.7
1,312.5
2.8


53
15.00
3.0
1,315.5
0.00
15.00
3.0
1,315.5
0.2


54
15.00
65.5
1,381.0
0.00
15.00
65.5
1,381.0
4.4


55
15.00
3.0
1,383.9
0.00
15.00
3.0
1,383.9
0.2


56
15.00
65.5
1,449.4
0.00
15.00
65.5
1,449.4
4.4


57
15.00
3.0
1,452.4
0.00
15.00
3.0
1,452.4
0.2


58
15.00
65.5
1,517.9
0.00
15.00
65.5
1,517.9
4.4


59
15.00
3.0
1,520.8
0.00
15.00
3.0
1,520.8
0.2


60
15.00
65.5
1,586.3
0.00
15.00
65.5
1,586.3
4.4


61
15.00
3.0
1,589.3
0.00
15.00
3.0
1,589.3
0.2


62
15.00
41.7
1,631.0
0.00
15.00
41.7
1,631.0
2.8


63
15.00
3.0
1,633.9
0.00
15.00
3.0
1,633.9
0.2


64
15.00
41.7
1,675.6
0.00
15.00
41.7
1,675.6
2.8


65
15.00
3.0
1,678.6
0.00
15.00
3.0
1,678.6
0.2


66
15.00
35.7
1,714.3
0.00
15.00
35.7
1,714.3
2.4


67
15.00
3.0
1,717.3
0.00
15.00
3.0
1,717.3
0.2


68
15.00
35.7
1,753.0
0.00
15.00
35.7
1,753.0
2.4


69
0.00
0.0
1,753.0
0.00
0.00
0.0
1,753.0
15.9









Table 3, shown below, illustrates a planned CO2 schedule for the stimulation of the well. During treatment, CO2 is to be pumped at a rate of approximately 13.9 bpm at 50% CIP and approximately a 28.0 bpm foam rate.


















TABLE 3







CO2
Stg. CO2
Cum. CO2
Stg. CO2
Cum. CO2
Foam
Stg.
Cum.



CO2 %
Rate
Surface
Surface
Surface
Surface
Rate
Foam
Foam


Step #
(CIP)
(bpm)
(tons)
(tons)
(bbls)
(bbls)
(bpm)
(bbls)
(bbls)
























1
50
13.9
9.8
9.8
55.1
55.1
28.9
115
115


2
50
13.9
7.9
17.7
44.1
99.1
28.9
92
206


3
50
13.9
0.5
18.2
2.8
101.9
28.9
6
212


4
50
13.9
7.9
26.1
44.1
145.9
28.9
92
304


5
50
13.9
0.5
26.6
2.8
148.7
28.9
6
309


6
50
13.9
6.9
33.5
38.5
187.2
28.9
80
390


7
50
13.9
0.5
33.9
2.8
190.0
28.9
6
395


8
50
13.9
6.9
40.8
38.5
228.5
28.9
80
476


9
50
13.9
0.5
41.3
2.8
231.3
28.9
6
481


10
50
13.9
6.9
48.2
38.5
269.8
28.9
80
561


11
50
13.9
0.5
48.7
2.8
272.6
28.9
6
567


12
50
13.9
6.9
55.6
38.5
311.1
28.9
80
647


13
50
13.9
0.5
56.1
2.8
313.9
28.9
6
653


14
50
13.9
6.9
63.0
38.5
352.4
28.9
80
733


15
50
13.9
0.5
63.5
2.8
355.2
28.9
6
739


16
50
13.9
6.9
70.4
38.5
393.7
28.9
80
819


17
50
13.9
0.5
70.9
2.8
396.5
28.9
6
825


18
50
13.9
6.9
77.7
38.5
435.0
28.9
80
905


19
50
13.9
0.5
78.2
2.8
437.8
28.9
6
911


20
50
13.9
6.9
85.1
38.5
476.3
28.9
80
991


21
50
13.9
0.5
85.6
2.8
479.1
28.9
6
997


22
50
13.9
7.9
93.5
44.1
523.1
28.9
92
1,089


23
50
13.9
0.5
94.0
2.8
525.9
28.9
6
1,094


24
50
13.9
7.9
101.8
44.1
569.9
28.9
92
1,186


25
50
13.9
0.5
102.3
2.8
572.7
28.9
6
1,192


26
50
13.9
7.9
110.2
44.1
616.7
28.9
92
1,283


27
50
13.9
0.5
110.7
2.8
619.5
28.9
6
1,289


28
50
13.9
7.9
118.6
44.1
663.5
28.9
92
1,381


29
50
13.9
0.5
119.1
2.8
666.3
28.9
6
1,387


30
50
13.9
7.9
126.9
44.1
710.3
28.9
92
1,478


31
50
13.9
0.5
127.4
2.8
713.1
28.9
6
1,484


32
50
13.9
7.9
135.3
44.1
757.1
28.9
92
1,576


33
50
13.9
0.5
135.8
2.8
759.9
28.9
6
1,581


34
50
13.9
7.9
143.7
44.1
803.9
28.9
92
1,673


35
50
13.9
0.5
144.2
2.8
806.7
28.9
6
1,679


36
50
13.9
7.9
152.0
44.1
850.7
28.9
92
1,770


37
50
13.9
0.5
152.5
2.8
853.5
28.9
6
1,776


38
50
13.9
7.9
160.4
44.1
897.5
28.9
92
1,868


39
50
13.9
0.5
160.9
2.8
900.3
28.9
6
1,874


40
50
13.9
7.9
168.8
44.1
944.3
28.9
92
1,965


41
50
13.9
0.5
169.3
2.8
947.1
28.9
6
1,971


42
50
13.9
7.9
177.1
44.1
991.1
28.9
92
2,063


43
50
13.9
0.5
177.6
2.8
993.9
28.9
6
2,068


44
50
13.9
7.9
185.5
44.1
1,037.9
28.9
92
2,160


45
50
13.9
0.5
186.0
2.8
1,040.7
28.9
6
2,166


46
50
13.9
7.9
193.9
44.1
1,084.7
28.9
92
2,257


47
50
13.9
0.5
194.3
2.8
1,087.5
28.9
6
2,263


48
50
13.9
7.9
202.2
44.1
1,131.6
28.9
92
2,355


49
50
13.9
0.5
202.7
2.8
1,134.3
28.9
6
2,360


50
50
13.9
6.9
209.6
38.5
1,172.8
28.9
80
2,441


51
50
13.9
0.5
210.1
2.8
1,175.6
28.9
6
2,446


52
50
13.9
6.9
217.0
38.5
1,214.1
28.9
80
2,527


53
50
13.9
0.5
217.5
2.8
1,216.9
28.9
6
2,532


54
50
13.9
10.8
228.3
60.6
1,277.5
28.9
126
2,658


55
50
13.9
0.5
228.8
2.8
1,280.2
28.9
6
2,664


56
50
13.9
10.8
239.6
60.6
1,340.8
28.9
126
2,790


57
50
13.9
0.5
240.1
2.8
1,343.5
28.9
6
2,796


58
50
13.9
10.8
250.9
60.6
1,404.1
28.9
126
2,922


59
50
13.9
0.5
251.4
2.8
1,406.9
28.9
6
2,928


60
50
13.9
10.8
262.2
60.6
1,467.4
28.9
126
3,054


61
50
13.9
0.5
262.7
2.8
1,470.2
28.9
6
3,059


62
50
13.9
6.9
269.6
38.5
1,508.7
28.9
80
3,140


63
50
13.9
0.5
270.1
2.8
1,511.5
28.9
6
3,145


64
50
13.9
6.9
277.0
38.5
1,550.0
28.9
80
3,226


65
50
13.9
0.5
277.5
2.8
1,552.8
28.9
6
3,231


66
50
13.9
5.9
283.4
33.0
1,585.8
28.9
69
3,300


67
50
13.9
0.5
283.9
2.8
1,588.6
28.9
6
3,306


68
50
13.9
5.9
289.8
33.0
1,621.6
28.9
69
3,375


69
100
27.8
78.7
368.5
440.5
2,062.1
27.8
441
3,815









Table 4, shown below, illustrates planned cumulative treatment requirements for the stimulation of the well.









TABLE 4





Treatment Requirements (All Stages)







Fluids








67,000
gals ClO2 Treatment







Additives per 1000 Gallons:








2.00
gal Broad-Spectrum Demulsifier


1,000.00
gal Stabilized ClO2


4.00
gal Corrosion Inhibitor


4,125
gals Treated Spacer







Additives per 1000 Gallons:








2.00
gal Broad-Spectrum Demulsifier


594.00
each Diverting Agents


2,500
gals Treated Water







Additives per 1000 Gallons:








2.00
gal Broad-Spectrum Demulsifier


CO2:
368.5 tons









Table 5, shown below, illustrates the planned pipe friction for the stimulation of the well.
















TABLE 5







ID
OD
ID

Fric.
Fric.



Outer
Inner
Inner
Length
Gradient
PSI























6.276
0.000
0.000
9,717
21.298
207



3.428
0.000
0.000
2,173
218.627
475










Table 6, shown below, illustrates the various planned parameters for the stimulation of the well.












TABLE 6







Rate:
30.00
Perfs Top:
TVD: 10,520.00





 MD: 11,890.00


Perfs Bottom:
TVD: 10,520.00
Frac Gradient:
0.850



 MD: 17,981.00




Fluid Gradient:
0.438
BHFP:
8,942


Hit:
4,606
Total Perf
0




Friction Pressure:



Total Restriction
0
Total Pipe
682


Friction Pressure:

Friction Pressure:



Surface Line
0
STP:
5,018


Friction

Pressure:



Hydraulic
3,690
Average Friction
57.362


Horsepower:

Gradient:









Below illustrates an executed treatment log for the planned treatment schedule as presented above and executed on a well. Table 7, shown below, illustrates pressure testing performed prior to the execution of the planned treatment schedule.
















TABLE 7














Barrels/Linear



Depth
OD
Weight
ID

Volume
Feet


















Tubing 1 Length (ft):





0.00
bbl
0.00000


Tubing 2 Length (ft):





0.00
bbl
0.00000


Casing 1 Length (ft):
9,717
7
26.00
6.276

225.82
bbl
0.02324


Casing 2 Length (ft):
18,080
4
11.6
3.428

0.00
bbl
0.00000


Open Hole Length (ft):

N/A
N/A


0.00
bbl
0.00000


Combined Depth (ft):




Annular Vol.
236.40
bbl
0.00000
















Depth
Vol.








Top Perf/Open Hole:
9,717

Maximum Pressure:
ISIP:



Bottom Perf/Open Hole:
18,080

Average Pressure:
 5 min:
N/A


Number of Perfs:
612

Maximum Rate:
10 min:
N/A


Perf Size:
0.41

Average Rate:
15 min:
N/A


Packer Depth:
N/A

Fluid to Recover:
Proppant Total:
















STP
Net PSI
Rate
Stage
Total
Comments










Arrive on Location







Rig-Up Safety Meeting







Rig-Up Equipment







Test Lines


4500




Test Backside Pop-Off







Changing Rubber Seal in Iron


9500




Testing Lines







Leak on Iron


9500




Test Manuel Pop-Off







Turning Off Equipment







Leaving Location









Table 8, shown below, illustrates the executed treatment log for the planned treatment schedule as presented above. FIG. 1 illustrates wellhead rate, pressure, slurry rate, and CO2 rate during the executed treatment. FIG. 2 illustrates net bottom-hole pressure during the executed treatment.















TABLE 8













Barrels/Linear



Depth
OD
Weight
ID
Volume
Feet


















Tubing 1 Length (ft):





0.00
bbl
0.00000


Tubing 2 Length (ft):





0.00
bbl
0.00000


Casing 1 Length (ft):
9,717
7
26.00
6.276

371.77
bbl
0.03826


Casing 2 Length (ft):
18,080
4
11.6
3.428

467.28
bbl
0.01142


Open Hole Length (ft):

N/A
N/A


0.00
bbl
0.00000


Combined Depth (ft):




Annular Vol.
236.40
bbl
0.00000

















Depth
Vol.









Top Perf/Open Hole:
11,890
396.59
Maximum Pressure:
5,004
ISIP:
1,508


Bottom Perf/Open Hole:
17,981
466.15
Average Pressure:
2,773
 5 min:
398


Number of Perfs:
612

Max Slurry Rate:
30
10 min:
388


Perf Size:
0.41

Average Slurry Rate:
17
15 min:
380


Frac Grad:
0.58

Max CO2 Rate:
13




Packer Depth:
N/A

Average CO2 Rate:
12







Max Wellhead Rate:
36







Average Wellhead Rate
29
Fluid to
2067







Recover















STP
Net PSI
Rate
Stage
Total
Comments










Arrive on Location







Operation Safety Meeting







Warming up Equipment


9500




Test Lines


2500




Test Backside Pop-Off







Leak on Iron







Venting Testing Hoses







Opening Wellhead


612
0
8.0
97.0
0.0
Establish Rate Break @ (3,530 psi)


2656
0
17.9
115.0
97.0
Start ClO2 Treatment Stage 1


1886
985
16.1
6.0
212.0
Start Spacer/Drop 36 Diverters


2336
1049
16.0
171.0
218.0
Start ClO2 Treatment Stage 2


2110
814
16.0
0.0
389.0
Establish Rate on Formation


21487
898
16.0
25.0
389.0
Start Spacer/Drop 36 Diverters


2200
931
16.0
166.0
414.0
Start ClO2 Treatment Stage 3


2294
928
16.0
0.0
580.0
ClO2 Treatment Stage 1 on Formation


2630
1212
16.0
13.0
580.0
Start Spacer/Drop 36 Diverters


2675
1335
16.0
0.0
593.0
Spacer/Drop 36 Diverters on Formation


2695
1374
16.5
0.0
593.0
ClO2 Treatment Stage 2 on Formation


2800
1439
16.3
166.0
593.0
Start ClO2 Treatment Stage 4


23149
1058
16.0
0.0
759.0
Spacer/Drop 36 Diverters on Formation


2315
1020
16.0
0.0
759.0
ClO2 Treatment Stage 3 on Formation


2253
1046
16.5
0.0
759.0
Spacer/Drop 36 Diverters on Formation


2541
1339
16.3
8.0
759.0
Start Spacer/Drop 36 Diverters


2638
1436
16.4
97.0
767.0
Start ClO2 Treatment Stage 5


2420
1620
16.0
6.0
864.0
Start Spacer/Drop 36 Diverters


2611
1529
16.0
97.0
870.0
Start ClO2 Treatment Stage 6


2463
1336
16.0
0.0
967.0
ClO2 Treatment Stage 4 on Formation


2461
1339
16.0
0.0
967.0
Spacer/Drop 36 Diverters on Formation


2475
1342
16.0
0.0
967.0
ClO2 Treatment Stage 5 on Formation


2605
1344
16.0
0.0
967.0
Spacer/Drop 36 Diverters on Formation


30064
1804
17.0
6.0
967.0
Start Spacer/Drop 36 Diverters


3257
1994
17.0
160.0
973.0
Start ClO2 Treatment Stage 7


2629
1500
16.0
10.0
1133.0
Start Spacer/Drop 36 Diverters


2622
1485
16.0
110.0
1143.0
Start ClO2 Treatment Stage 8


2617
1477
16.0
0.0
1253.0
ClO2 Treatment Stage 6 on Formation


3087
1948
16.0
8.0
1253.0
Start Spacer/Drop 36 Diverters


1660
1460
17.0
110.0
1261.0
Start ClO2 Treatment Stage 9


2647
1443
16.0
0.0
1371.0
Spacer/Drop 36 Diverters on Formation


2646
1447
16.0
0.0
1371.0
ClO2 Treatment Stage 7 on Formation


3132
1935
16.0
6.0
1371.0
Start Spacer/Drop 36 Diverters


3188
1985
16.0
0.0
1377.0
Spacer/Drop 36 Diverters on Formation


3188
1985
16.0
103.0
1377.0
Start ClO2 Treatment Stage 10


2696
1481
17.0
0.0
1480.0
ClO2 Treatment Stage 8 on Formation


2978
1899
10.0
6.0
1480.0
Start Spacer/Drop 36 Diverters


2254
1084
17.0
91.0
1486.0
Start ClO2 Treatment Stage 11


2694
1434
16.0
0.0
1577.0
Spacer/Drop 36 Diverters on Formation


2695
1423
16.0
0.0
1577.0
ClO2 Treatment Stage 9 on Formation


3002
1800
16
8.0
1577.0
Start Spacer/Drop 36 Diverters


3202
1975
16
60.0
1585.0
Start ClO2 Treatment Stage 12


3925
2689
16.0
0.0
1645.0
Spacer/Drop 36 Diverters on Formation


4069
2845
16.0
0.0
1645.0
ClO2 Treatment Stage 10 on Formation


3934
268
16
5.0
1645.0
Start Spacer/Drop 36 Diverters


3681
2492
16
60.0
1650.0
Start ClO2 Treatment Stage 13


4199
2993
16
5.0
1710.0
Start Spacer/Drop 36 Diverters


4004
2863
16
103.0
1715.0
Start ClO2 Treatment Stage 14


4243
3050
16.0
0.0
1818.0
Spacer/Drop 36 Diverters on Formation


4250
3049
16
0.0
1818.0
ClO2 Treatment Stage 11 on Formation


4809
3611
16
6.0
1818.0
Start Spacer/Drop 36 Diverters


4622
3485
16
84.0
1824.0
Start ClO2 Treatment Stage 15


4432
3236
16
0.0
1908.0
Spacer/Drop 36 Diverters on Formation


4433
3245
16
0.0
1908.0
ClO2 Treatment Stage 12 on Formation


4669
3418
16
5.0
1908.0
Start Spacer/Drop 36 Diverters


4775
3519
16
70.0
1913.0
Start ClO2 Treatment Stage 16


7780
3256
17
0.0
1983.0
Spacer/Drop 36 Diverters on Formation


4470
3248
16
0.0
1983.0
ClO2 Treatment Stage 13 on Formation


3389
4243
16
8.0
1983.0
Start Spacer/Drop 36 Diverters


1831
2578
14
70.0
1991.0
Start ClO2 Treatment Stage 17


1410
1927
14
6.0
2061.0
Start Spacer/Drop 36 Diverters


1377
1816
14
98.0
2067.0
Start CO2 Flush







Shutdown


380




5, 10, 15







Start Rigging Down







Leave Location









Although various embodiments of the present disclosure have been described in the foregoing Detailed Description, it will be understood that the present disclosure is not limited to the embodiments disclosed herein, but is capable of numerous rearrangements, modifications, and substitutions without departing from the spirit of the disclosure as set forth herein.


The term “substantially” is defined as largely but not necessarily wholly what is specified, as understood by a person of ordinary skill in the art. In any disclosed embodiment, the terms “substantially”, “approximately”, “generally”, and “about” may be substituted with “within [a percentage] of” what is specified, where the percentage includes 0.1, 1, 5, and 10 percent.


The foregoing outlines features of several embodiments so that those skilled in the art may better understand the aspects of the disclosure. Those skilled in the art should appreciate that they may readily use the disclosure as a basis for designing or modifying other processes and structures for carrying out the same purposes and/or achieving the same advantages of the embodiments introduced herein. Those skilled in the art should also realize that such equivalent constructions do not depart from the spirit and scope of the disclosure, and that they may make various changes, substitutions, and alterations herein without departing from the spirit and scope of the disclosure. The scope of the invention should be determined only by the language of the claims that follow. The term “comprising” within the claims is intended to mean “including at least” such that the recited listing of elements in a claim are an open group. The terms “a”, “an”, and other singular terms are intended to include the plural forms thereof unless specifically excluded.

Claims
  • 1. A method for well stimulation, the method comprising: pumping a treatment fluid into a well, wherein the treatment fluid comprises carbon dioxide (CO2) and a breaker; andtreating at least one of a reservoir and a wellbore of the well with the treatment fluid.
  • 2. The method of claim 1, wherein the breaker is selected from the group consisting of guar breakers, friction reducer breakers, slickwater breakers, oxidative breakers, enzyme breakers, gel breakers, ammonium persulfate, polyacrylamide breakers, or combinations thereof.
  • 3. The method of claim 1, wherein the breaker is a solution.
  • 4. The method of claim 3, wherein the solution comprises stabilized chlorine dioxide (ClO2).
  • 5. The method of claim 4, wherein the solution has a concentration of 5% v/v of the stabilized ClO2.
  • 6. The method of claim 4, comprising: commingling the CO2 with water; andforming, as a result of the commingling, carbonic acid.
  • 7. The method of claim 6, comprising activating the stabilized ClO2 to form activated ClO2.
  • 8. The method of claim 7, wherein the activated ClO2 is formed as a result of a lowering of pH in the treatment fluid by the carbonic acid.
  • 9. The method of claim 8, wherein the lowering of pH results in the treatment fluid having a pH between about 4 to about 5.
  • 10. The method of claim 7, wherein the activated ClO2 is formed at a predetermined depth in the well based, at least in part, on a concentration of the CO2 and the stabilized ClO2 in the treatment fluid.
  • 11. The method of claim 1, wherein the breaker is in a range of about 20% to about 75% total volume of the treatment fluid.
  • 12. The method of claim 1, comprising pumping a treated spacer into the well.
  • 13. The method of claim 12, wherein the treated spacer comprises a diverter agent to divert the treatment fluid to a particular zone of interest.
  • 14. The method of claim 1, wherein the treatment fluid comprises a water block removing agent selected from the group consisting of stimulation surfactants, ethoxylated surfactants, sulfonated surfactants, citrus terpenes, alcohols, ionic surfactants, nonionic surfactants, cationic surfactants, anionic surfactants, amphoteric surfactants, flow-back enhancers, emulsifiers, dispersants, oil-wetters, water-wetters, foamers, defoamers, or combinations thereof.
  • 15. The method of claim 14, wherein the water block removing agent is in a range of about 20% to about 75% total volume of the treatment fluid.
  • 16. The method of claim 1, wherein the CO2 is in a range of about 20% to about 75% total volume of the treatment fluid.
  • 17. The method of claim 1, comprising: shutting-in the well for a predetermined period of time; andflowing back the well after the predetermined period of time.
  • 18. The method of claim 1, wherein the treating comprises at least one of mobilizing hydrocarbons in the reservoir, freeing hydrocarbons in the reservoir, lowering surface tension of residual fluids in the reservoir, and removing damage caused by residual material from previous fluids introduced into the well.
  • 19. The method of claim 1, wherein the treatment fluid comprises at least one of clay control agents, surfactants, foaming agents, fluid loss additives, scale reducing agents, corrosion inhibitors, biocides, and pH control additives.
  • 20. A method for well stimulation, the method comprising: pumping a treatment fluid into a well, wherein the treatment fluid comprises carbon dioxide (CO2), stabilized chlorine dioxide (ClO2), and a water block removing agent selected from the group consisting of stimulation surfactants, ethoxylated surfactants, sulfonated surfactants, citrus terpenes, alcohols, ionic surfactants, nonionic surfactants, cationic surfactants, anionic surfactants, amphoteric surfactants, flow-back enhancers, emulsifiers, dispersants, oil-wetters, water-wetters, foamers, defoamers, or combinations thereof;commingling the CO2 with water;forming, as a result of the commingling, carbonic acid;lowering pH of the treatment fluid with the carbonic acid;activating the stabilized ClO2 to form activated ClO2, wherein the activating occurs at a predetermined depth based, at least in part, on a concentration of the CO2 and the stabilized ClO2 in the treatment fluid, andwherein the activated ClO2 is formed due to a lowering of pH in the treatment fluid by the carbonic acid; andtreating at least one of a reservoir and a wellbore of the well with the treatment fluid.
CROSS-REFERENCE TO RELATED APPLICATIONS

This patent application claims priority from, and incorporates by reference the entire disclosure of, U.S. Provisional Patent Application No. 62/746,291 filed on Oct. 16, 2018 and U.S. Provisional Patent Application No. 62/806,260 filed on Feb. 15, 2019.

Provisional Applications (2)
Number Date Country
62746291 Oct 2018 US
62806260 Feb 2019 US