Stirrer

Information

  • Patent Grant
  • 5141327
  • Patent Number
    5,141,327
  • Date Filed
    Friday, July 26, 1991
    33 years ago
  • Date Issued
    Tuesday, August 25, 1992
    32 years ago
Abstract
A stirrer for stirring a liquid in a container, which includes a stator; a rotor disposed in the container and provided with stirring vanes; and a cylindrical housing of nonmagnetic material having a peripheral wall thereof interposed between the stator and rotor and rotatably supporting the rotor through intervention of the liquid. This arrangement provides a stirrer of simple and compact construction, which can stir the liquid in a container completely in a closed state free of sliding portions of rotary components or shaft seal portions.
Description

BACKGROUND OF THE INVENTION
1. Field of the Invention
This invention relates to a stirrer which is useful particularly in pharmaceutical, food and chemical industries for mixing, dissolving, kneading and diffusing a liquid or other material in a container.
2. Discussion of the Background
Illustrated in FIG. 30 is a known mixer which is provided with a stirring vessel a, a rotational transmission c located externally under the bottom wall of the stirring vessel a and driven from an electric motor b, and an impeller shaft e which protrudes from below into a lower portion of the vessel a and having impeller vanes d. The impeller shaft e and the transmission c are coupled to each other through a magnetic coupling f to rotate the impeller wheel d.
This sort of conventional stirrer is required to separately provide a rotational drive like the motor b for rotating the impeller vanes d which invariably have drawbacks in that they are of complex in construction and are large in size.
SUMMARY OF THE INVENTION
It is an object of the present invention to provide a stirrer which is capable of stirring a liquid in a container in a completely closed state with no slide portions of rotary components nor a shaft seal portion being required.
It is another object of the invention to provide a stirrer which is of compact construction and is reduced in size.
In accordance with the present invention, the foregoing objects are achieved by the provision of a stirrer for stirring a liquid in a container, which essentially includes a cylindrical housing of nonmagnetic material having the peripheral wall portion thereof interposed between a stator and a rotor with stirring vanes for supporting the rotor rotatably through intervention of the liquid from the container.





BRIEF DESCRIPTION OF THE DRAWINGS
A more complete appreciation of the invention and many of the attendant advantages thereof will be readily obtained as the same becomes better understood by reference t the following detailed description when considered in connection with the accompanying drawings, wherein:
FIG. 1 is a plan view of a first embodiment of the invention;
FIG. 2 is a front view of the embodiment of FIG. 1;
FIG. 3 is a cross-sectional view taken on line III--III of FIG. 2;
FIG. 4 is a perspective view of a rotor;
FIG. 5 is a plan view of a second embodiment of the invention;
FIG. 6 is a partly cutaway front view of the embodiment of FIG. 5;
FIG. 7 is a partly cutaway plan view of a third embodiment of the invention;
FIG. 8 is a partly cutaway front view of the embodiment of FIG. 7;
FIG. 9 is a plan view of a fourth embodiment of the invention;
FIG. 10 is a vertical section of a fifth embodiment of the invention;
FIG. 11 is a sectional view taken on line XI--XI of FIG. 10;
FIG. 12 is a sectional view taken on line XII--XII of FIG. 11;
FIG. 13 is a view similar to FIG. 12 but showing a sixth embodiment of the invention;
FIG. 14 is a vertical section of a rotor of a seventh embodiment of the invention;
FIG. 15 is a vertical section of a rotor of an eighth embodiment of the invention;
FIG. 16 is a vertical section of a ninth embodiment of the invention;
FIG. 17 is a vertical section of a tenth embodiment of the invention;
FIG. 18 is an enlarged sectional view taken on line XVIII--XVIII of FIG. 17;
FIG. 19 is a vertical section of a rotor;
FIG. 20 is a vertical section of a modification of the stirrer of the tenth embodiment arranged in the fashion of the ninth embodiment;
FIG. 21 is a partly cutaway sectional view of an eleventh embodiment of the invention;
FIG. 22 is a partly cutaway sectional view of a twelfth embodiment of the invention;
FIG. 23 is a partly cutaway sectional view of a thirteenth embodiment of the invention;
FIG. 24 is a vertical section of a fourteenth embodiment of the invention;
FIG. 25 is a partly cutaway sectional view of a fifteenth embodiment of the invention;
FIG. 26(a) and (b) are diagrammatic views explanatory of the operation of the rotor in the fifth to fifteenth embodiments;
FIG. 27 is a vertical section of a sixteenth embodiment of the invention;
FIG. 28 is a cross-sectional view of a stator;
FIG. 29(a) -29(e) are diagrammatic views explanatory of the operation of the rotor; and
FIG. 30 is a partly cutaway elevation of a conventional stirrer.





DESCRIPTION OF THE PREFERRED EMBODIMENTS
Now, the invention will be described more particularly, firstly by way of the first embodiment shown in FIGS. 1 through 4.
In these figures, indicated at 10 is a rectangular liquid container and at 1 is a cylindrical housing of a nonmagnetic material which is projectingly provided in a lower portion of one side wall of the liquid container 10. The housing 1 is hermetically closed at opposite ends thereof, and provided with first communication ports 11a at opposite end portions of the peripheral wall thereof and a second communication port 11b in a center portion of the peripheral wall. Thus, the housing 1 is communicable with the liquid container 10 through the just-mentioned first and second housing 1 is a hollow cylindrical rotor 3 which is open at the opposite ends and which leaves a small clearance or gap g therearound as shown in FIG. 3. The rotor 3 has cylindrical opposite end portions 3a which comprise a coated magnetic material such as SS41 or the like and a conductive body of copper, aluminum or the like, as well as a cylindrical center portion 3b which is constituted by stainless steel, engineering plastics or the like. As shown in FIGS. 3 and 4, a large number of inclined openings or slots 3c are provided in the center portion 3c to function as a stirring portion. The rotor 3 as a whole is coated with Teflon or other corrosion-resistant material.
Rotating field devices, namely, stators 2, are located on the outer side of the housing 1 opposingly to the cylindrical end portions 3a of the rotor 3. In this instance, each one of the stators 2 is constituted by a multi-layered iron core of silicon steel sheets or the like and a winding wound around the core.
With the above-described arrangement, rotating fields are induced in the cylindrical portions 3a of the rotor 3 as soon as current is conducted through the stator 2, whereupon the liquid is drawn into the gap g by the rotor 3 to produce a bearing effect, rotating the rotor 3 smoothly in a noncontacting state in the direction of arrow A in FIG. 3 by the balancing action between the attraction of the rotating fields and gravity acting on the rotor 3. At this time, since the rotor 3 is provided with the slots 3c in the center portion 3b, the liquid which flows in through the first communicating ports 11a of the housing 1 is sucked into the rotor 3 through the openings at the opposite ends thereof, while the liquid in the rotor 3 is stirred as it is discharged through the slots 3c to return to the container 10 through the second communication port 11b. This is repeated to stir the liquid in the container 10.
Referring now to FIGS. 5 and 6, there is shown a second embodiment of the invention which employs a vertical type cylindrical liquid container 10 with a rectangular open frame 11c projecting from a lower portion of its side wall, and a cylindrical housing 1 fixedly connected in a hermetically sealed state to the frame 11c along the edges of a rectangular opening formed on one side of the housing 1. In the same manner as in the foregoing first embodiment, upon rotating the rotor 3 by supplying current to the stator 2, the liquid flowing toward the opposite end portions of the open frame 11c from the container 10 is sucked into the openings at the opposite ends of the rotor 3 and then discharged through the slots 3c into the center portion of the open frame 11c to return to the container 10. The liquid in the container 10 is thus stirred by repeated circulation through the rotor 3. This embodiment has an advantage in that the housing 1 is easily detachable from the container 10 to facilitate their transportation or maintenance and service.
FIGS. 7 and 8 illustrate a third embodiment of the invention, which employs a vertical type cylindrical liquid container 10 with a housing 1 hermetically and integrally connected to an opening in the side wall of the container 10 for effective use of the installation space. This embodiment is suitable for application, particularly in a case where only a limited floor space is available, and can perform the stirring operation in substantially the same manner as the foregoing second embodiment.
Shown in FIG. 4 is a fourth embodiment of the invention, wherein a housing 1 is spaced more from a container 10 than in the above-described second embodiment and communicated with the latter through three ducts 11d, more specifically, a couple of side ducts 11d and a center duct 11d. The stirring operation is substantially the same as in the first embodiment. With this fourth embodiment, the stator 2 can circumvent the rotor 3 to a greater degree to enhance the rotational efficiency.
Referring to FIGS. 10 to 12, there is shown a fifth embodiment of the invention, which is of a type having a housing 1 formed within an indented bottom wall portion of a stirring container 10. More specifically, the housing 1 is formed of a nonmagnetic material at least in those portions which oppose the rotor 3 as will be described hereinafter, and in this case formed by an indented portion which is provided in a center portion of the bottom wall of the container 10 in such a manner as to circumvent the stator 2. Denoted at 3 is a rotor which is formed in a cap-like shape and which has its peripheral wall portion formed of a magnetic material such as SS41 or the like and a conducting body of copper, aluminum or the like. The top wall of the rotor 3 is formed of stainless steel, engineering plastics or the like. The rotor 3 as a whole is coated with a corrosion-proof material sold under the TEFLON trademark. The rotor 3 is fitted on the housing 1 which circumvents the stator 2, and is provided with an aperture 3d at the center of its top wall and with a plurality of stirring vanes 3e on the peripheral and top wall surfaces. As shown particularly in FIGS. 11 and 12, a plurality radial of strip-like grooves 4 are cut into the inner surface 3f of the top wall of the rotor 3 at uniform angular intervals in the circumferential direction. Each groove 4 is connected to stepped surfaces 5a to 5c of a sectoral shape. Indicated at 6 is a fixed base for mounting the housing 1 and stator 2.
This embodiment operates as follows.
Upon supplying current to the stator 2 to produce shifting fields, the rotor 3 is rotationally driven in the direction of arrow X for stirring the liquid A with the vanes 3e on the rotor 3.
In this instance, since the rotor 3 is provided with aperture 3d at the center of its top wall, the liquid A which is urged to flow into the grooves 4 through the aperture 3d by rotation of the rotor 3 is firstly supplied to the peripheral portions of the respective grooves 4. As the liquid proceeds successively from the first to third sectoral stepped surfaces 5a to 5c, the liquid pressure is increased stepwise, producing a pressure which acts upwardly on the rotor 3 to float the same upward, while part of the liquid A is forced to flow downward through the small gap g between the housing 1 and rotor 3.
In this manner, the gap g is constantly maintained and the rotor 3 is rotated smoothly in a balanced state with the reaction forces of the top stirring vanes 3e and circumferential stirring vanes 3e.
As is clear from the foregoing description, the stirring apparatus of this embodiment employs a noncontacting rotor for the stirring operation, so that it can be applied to either a sealed or nonsealed type container and facilitates stirring operations under high pressure or in a vacuum, free of abrasive wear as would result from sliding movements and free from the generation of vibrations. Moreover, the liquid A in the container 10 can be discharged more easily after stirring operation.
Referring to FIG. 13, there is illustrated a sixth embodiment of the invention, in which the stepped surfaces 5a to 5c of the foregoing fifth embodiment are replaced by an infinite number of stepped surfaces, namely, by a linearly inclined surface 5c to obtain the same effects as in the fifth embodiment.
Illustrated in FIG. 14 is a seventh embodiment of the invention, in which stepped surfaces 5e to 5g are formed on the rotor 3 in the circumferential direction and concentrically in a manner so as to minimize the gap toward the outer periphery. FIG. 15 shows an eighth embodiment in which the number of the stepped surfaces 5e to 5g is increased infinitely to present a linearly inclined surface 5h. In the seventh and eighth embodiments, the liquid which is urged to flow into the aperture 3d by rotation of the rotor 3 is forced outward in the gap between the top wall of the rotor 3 and the top surface of the housing 1 under the influence of the centrifugal force. Since the gap is narrowed toward the outer periphery, the liquid pressure is increased outwardly, generating a pressure which pushes up the rotor 3 into a floating state for smooth rotation.
Although the grooves and stepped surfaces are formed on part of the rotor 3 in the fifth to eighth embodiments, they may be formed on the top surface of the housing 1 if desired.
Shown in FIG. 16 is a ninth embodiment of the invention, in which a closed type housing 1 of a nonmagnetic material is formed separately from the container 10 for the liquid A, and receives therein a stator 2. A rotor 3 is fitted on the housing 1, and grooves and stepped surfaces or a linearly inclined surface are formed on the inner surface of the top wall of the rotor or on the top surface of the housing 1 as in the fifth to eighth embodiments. This stirrer can be placed in an ordinary container. Reference number 7 indicates a lead wire.
Referring to FIGS. 17 to 19, there is illustrated a tenth embodiment of the invention, wherein pumping vanes 3g which are curved in the circumferential direction are projectingly provided on the inner surface of the top wall of a rotor 3 as shown particularly in FIGS. 18 and 19. In addition, a number of labyrinths 8 are formed on the inner periphery at the lower end of the peripheral wall of the rotor 3.
Thus, supplying current to the stator 2 to generate shifting fields which drive the rotor 3 to rotate in the direction of arrow X, the liquid A which is urged to flow into the gap between the opposing surfaces of the rotor 3 and the housing 1 through the aperture 3d is forcibly pushed outward by the pumping vanes 3g on the inner surface 3f of the top wall of the rotor 3 with an outwardly increasing liquid pressure to push up the rotor 3 before flowing down through the gap between the opposing peripheral wall surfaces of the housing 1 and rotor 3. Due to the existence of the labyrinths 8 at the lower end of the rotor 3, downward flow of the liquid A is blocked there to a substantial degree so as to float the rotor 3 upward securely while in rotation. Accordingly, the rotor 3 is rotated smoothly, balancing with the reaction forces of the stirring vanes 3e on its peripheral wall, and consequently the liquid A is stirred by the vanes of the rotor 3.
Although the pumping vanes 3g are provided on part of the rotor 3 in this embodiment, of course they may be formed on the top wall of the housing 1.
Further, the labyrinths 8 which are formed on the inner peripheral surface at the lower end of the rotor 3 may be provided at an intermediate portion on the inner periphery of the rotor 3 or on the outer peripheral surface of the housing 1 if desired.
Moreover, instead of forming the housing 1 by part of the container 10 as in the present embodiment, a closed type housing 1 may be formed separately from the container 10 as shown in FIG. 20 in a manner similar to the ninth embodiment, receiving a stator 2 in the housing 1 and fitting a rotor 3 over the housing 1. In this case, pumping vanes 3g are provided either on part of the rotor 3 or on the opposing surface of the top wall of the housing 1. Further, labryinths 8 may be provided on the rotor 3 or on the opposing peripheral surface of the housing 1.
Referring to FIG. 21, there is shown an eleventh embodiment of the invention, in which a housing 1 is fixed by screws to a lower portion of a stirring container 10 through an O-ring 9a of other suitable seal member. Indicated at B is a incompressible fluid which is filled in the housing 1 and in the gap space around a stator 2. Lead wire 7 from the stator 2 is passed through a seal 9b. Thus, when the container 10 is under high pressure, the compressive force which acts on the housing through the liquid A is sustained by the incompressible fluid B filled in the housing 1. It follows that the wall thickness of the housing 1, particularly, the thickness of the peripheral wall portion can be reduced to enhance the efficiency of the motor.
Illustrated in FIG. 22 is a twelfth embodiment of the invention, in which a housing 1 is suspended from the top wall of a stirring container 10 by means of a hollow cylindrical support member 12. The housing 1 is in communication with the cylindrical support member 12 which is filled with a incompressible fluid B. A seal 9b is provided at the upper end of the support member 12. In this embodiment, the rotor 3 is formed in C-shape in section.
The incompressible fluid B may be filled in the housing 1 alone, locating the seal 9b in the position indicated by broken line in FIG. 22.
FIG. 23 shows a thirteenth embodiment of the invention, in which a communication hole 13 is formed in an upper portion of a hollow cylindrical support member 12 and the fluid B is filled in a housing 1 and only in a lower portion of the support member 12, leaving an empty space thereabove. Accordingly, when stirring the container 10 under high pressure, the upper empty space in the support member 12 is raised to the same pressure level by communication with the upper empty space in the container 10 through the communication hole 13, as a result zeroing or equalizing the pressure difference between inside and outside of the housing 1 and the cylindrical support member 12. This permits a reduction of their wall thicknesses so as to enhance the motor efficiency.
Alternatively, the hollow spaces in the casing 1 and support member 12 may be entirely emptied and filled with the high pressure gas in the upper space of the container 10 by communication therewith through the communication port 13, instead of the fluid B.
Although a situation where a high pressure prevails in the container 10 has been described as an example in each one of the foregoing eleventh to thirteenth embodiments, there occurs almost no pressure difference between inside and outside of the housing 1 even under low pressure or vacuum condition, permitting a reduction in the wall thickness of the housing 1. The housing 1 which has been shown as being fixed in the container 10 in the eleventh to thirteenth embodiments may be provided as an independent closed type which can be set in an arbitrary position within an existing container.
Referring to FIG. 24, there is illustrated a fourteenth embodiment of the invention, wherein a pipe 14 is inserted in a center aperture of a stator 2 to form an air passage 15. The lower end of the pipe 14 is passed through and fixed to a support plate 16 which supports the container 10, the side walls of the pipe 14 being spread into a trumpet-like shape under the support plate 16 to accommodate a fan 17. Indicated at 18 are openings which are formed in the support plate 16, namely, in the bottom wall of the housing 1 beneath the peripheral wall portions of the stator 2, and indicated at 19 are legs which support the container 10.
Upon generating shifting fields by supplying current to the stator 2, the rotor 3 is rotated on the liquid bearing which is formed in the small clearance between the rotor 3 and the housing 1, stirring the liquid A with the vanes 3e which are provided on the rotor 3. As the fan 17 is actuated, the air which is drawn by the fan 17 is sent into the air passage 15 and circulated through the housing 1 and along the peripheral wall portions of the stator 2 before being discharged through the openings 18. As a result of this air circulation, the housing 1 is cooled and the stator is smoothly rotated so as to stir the liquid A efficiently.
By reversing the rotation of the fan 17, the air circulation can be changed so as to draw air through the openings 18 and discharge it through the air passage 15.
Shown in FIG. 25 is a fifteenth embodiment of the invention, in which a housing 1 is provided in an upper portion of a container 10 and supported on a tubular support member 20 which is pendant from the top wall of the container 10. A pipe 14 is inserted centrally in the support member 20. The lower end of the pipe 14 is fitted in the center hole of the stator 2, while the upper end is spread into a trumpet-like shape to accommodate a fan 17. This embodiment operates in the same manner as the foregoing fourteenth embodiment.
Instead of employing an air-cooled type stator 2 as in the fourteenth and fifteenth embodiments, arrangements may be made to cool the stator by feeding thereto cooling water or other cooling liquid with the use of a pump.
In any of the foregoing fifth to fifteenth embodiments, there may arise the following problem in a situation where the winding is wrapped around the entire circumference of the stator 2.
Namely, as power is supplied to the winding of the stator 2, an attracting force F.sub.1 is generated in a certain direction by the magnetic field of the winding as shown in FIG. 26a, exerting a pulling force on the rotor 3 and producing on the outer side of the housing 1 a liquid film of a wedge-like shape in the direction of rotation. As a result, the liquid between the rotor 3 and housing 1 is pulled in due to its viscosity and generates a liquid pressure with an overall reaction force F.sub.2 in the opposite direction. By vector addition of the attracting force F.sub.1 and the reaction force F.sub.2, a combined force F.sub.3 acts on the peripheral wall in the rotational direction. Consequently, as shown in FIG. 26b, the rotor is pulled in the direction of the combined force F.sub.3, and in this state the attracting force F.sub.1 and overall reaction force F.sub.2 of the liquid pressure occur in the manner as described hereinabove. Therefore, next the rotor 3 is pulled in the direction of the combined force of the attracting force F.sub.1 and overall reaction force F.sub.2. Since the stator 2 has the winding wrapped 360.degree. around its entire circumference, the position where the rotor 3 approaches the housing 1 is shifted sequentially, putting the rotor 3 into eccentric rotational motions and sometimes causing the rotor 3 to hit against the circumference of the housing 1. This makes it difficult to ensure smooth rotation of the rotor.
In order to overcome this problem, the sixteenth embodiment shown in FIGS. 27 and 28 has stator windings 2A, 2A'; 2B, 2B' and 2C, 2C' wrapped over an angle of 150.degree. in slots 2a, 2a'; 2b, 2b' and 2c, 2c'. Upon supplying current to the windings 2A, 2A'; 2B, 2B' and 2C, 2C', shifting fields are generated in the stator 2 and thereby the rotor 3 on the opposite side of the housing 1 is urged to rotate in the direction of arrow W and at the same time pulled toward stator 2. As a result, the rotor 3 is moved into an eccentric position as shown in FIG. 29a, forming a small gap g.sub.0 between the rotor 3 and housing 1 with a fluid bearing constituted by the inflowing liquid film. The overall force Phd 1 of the attracting forces Pa.sub.1 to Pz.sub.1 of the stator windings acts on the rotor 3 across the small gap g.sub.0 in the direction of <.alpha. short of the small gap position. At this time, pressures Pa.sub.2 to Pz.sub.2 of the wedge-shaped liquid film act on the rotor 3 and housing 1, and their overall pressure P.sub.2 acts as shown in FIG. 29b. Accordingly, the combined vector force P.sub.3 of the overall attracting force P.sub.1 and the overall pressure P.sub.2 acts on the rotor 3 as shown in FIG. 29c, shifting the small gap g.sub.0 through an angle of .theta. to g'.sub.0. In this state, the small gap g'.sub.0 is located in the vicinity of the end of the stator windings where the attracting forces P'a.sub.1 to P'z.sub.1 of the windings are interrupted in the direction of the rotation as shown in FIG. 29d. Therefore, the overall attracting force P'.sub.1 is maintained substantially in the same direction as the aforementioned overall force P.sub.1. However, as a result of the shift of the small gap from g.sub.0 to g'.sub.0, the overall pressure P'.sub.2 is shifted in the direction of rotation as shown in FIG. 29e. Therefore, the combined vector P'.sub.3 of the overall attracting force P'.sub.1 and the overall pressure P'.sub.2 are almost extinguished as shown in FIG. 29c to maintain a constant small gap g'.sub.0, while the rotor 3 is rotated by the shifting fields of the stator windings. Thus, the rotor 3 tends to move into the eccentric position to form a narrow gap g.sub.0 only through a rotational angle of 150.degree. where it is associated with the windings 2A, 2A' to 2C, 2C', and the eccentric displacement does not occur through the remaining angle of rotation. Namely, as the rotor 3 continues its rotation, the eccentric circular movements due to the eccentric displacement are extinguished so as to allow the rotor to smoothly rotate while keeping a constant gap g'.sub.0 and from the housing and efficiently stirring the liquid A with the vanes 3e.
The stator windings 2A, 2A' to 2C, 2C' may be increased or reduced suitably to cover an arbitrary rotational angle, for example, to cover an angle of 180.degree. or 120.degree. if desired.
Needless to say, the rotor can be more smoothly rotated in the fifth to fifteenth embodiments by adopting the partial wrapping of the windings as in the sixteenth embodiment.
Obviously, numerous modifications and variations of the present invention are possible in light of the above teachings. It is therefore to be understood that within the scope of the appended claims, the invention may be practiced otherwise than as specifically described herein
Claims
  • 1. A stirrer for stirring a liquid, which comprises:
  • a container within which said liquid is housed, said container being mounted on a base;
  • a stator positioned on said base and circumvented by said container;
  • a rotor disposed in said container and provided with stirring vanes; and
  • a cylindrically shaped housing of nonmagnetic material having a peripheral wall thereof interposed between said stator and said rotor and fluidically rotatively supporting said rotor by said liquid wherein said stator and rotor are located on inner and outer sides of said housing, respectively, and said rotor is of a hollow cylindrical shape open at one end and provided at an opposite end with an aperture centrally in a peripheral wall thereof to stir streams of said liquid from an inside portion to an outside portion of said peripheral wall.
  • 2. A stirrer as defined in claim 1, wherein said aperture comprises a plurality of stepped surfaces.
Priority Claims (5)
Number Date Country Kind
1-59150 Mar 1989 JPX
1-62685 Mar 1989 JPX
1-84098 Apr 1989 JPX
1-86044 Apr 1989 JPX
1-47738 Apr 1989 JPX
Parent Case Info

This is a division of application Ser. No. 07/491,596filed on Mar. 12, 1990, now U.S. Pat. No. 5,061,079.

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3172645 Price Mar 1965
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3554497 Zipperer Jan 1971
3730488 Gardner, Jr. May 1973
3929320 Haller Dec 1975
3995835 Cichy et al. Dec 1976
4162855 Bender Jul 1979
4199265 Sanderson et al. Apr 1980
4209259 Rains et al. Jun 1980
4465377 Bruyne Aug 1984
4568195 Harz et al. Feb 1986
4691725 Parisi Sep 1987
Divisions (1)
Number Date Country
Parent 491596 Mar 1990