Stretchable composite fiber

Abstract

An integral composite fiber is formed by integrally joining a stretchable fiber and unstretchable fibers. The stretchable fiber has longitudinally extending first exposed surfaces that are circumferentially spaced from each other. The unstretchable fibers has longitudinally extending second exposed surfaces each disposed between a circumferentially adjacent pair of the first exposed surfaces. One of the first exposed surfaces has a larger surface area than the other or others of the first exposed surfaces. Said other or each of the others of the first exposed surfaces has a surface area ratio of less than 0.8 with respect to the surface area of said one of the first exposed surfaces. By longitudinally stretching this integral composite fiber, because shear stress is large due to a large difference in shrinkage stress between said one of the first exposed surfaces and the other or others of the first exposed surfaces, the unstretchable fibers easily separate from the stretchable fiber, and are three-dimensionally crimped. The unshrinkable fibers are thus helically wrapped around and covers the shrinkable fiber, which has a rubber-like feel to the touch. Thus, the composite fiber obtained is bulky and feels good to the touch.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

Other features and objects of the present invention will become apparent from the following description made with reference to the accompanying drawings, in which:

FIG. 1 shows an entire stretchable nonwoven fabric embodying the present invention;

FIG. 2 shows the production steps of the stretchable nonwoven fabric;

FIGS. 3A to 3C are enlarged views of die openings;

FIGS. 4A to 4C are sectional views of composite fibers;

FIG. 5 is a sectional view of a composite fiber;

FIGS. 6A to 6C are photos of sections of composite fibers according to Examples of the invention.

FIGS. 7A and 7B are photos of sections of composite fibers according to Comparative Examples;

FIG. 8 is an enlarged photo of a nonwoven fabric of Example of the invention;

FIG. 9 is an enlarged photo of a nonwoven fabric of Comparative Example;

FIGS. 10A and 10B are sectional views of conventional composite fibers; and

FIG. 11 is a plan view of a conventional stretchable composite fiber.

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

Now the embodiment of the present invention is described with reference to the drawings.

The stretchable nonwoven fabric 1 according to the embodiment of FIG. 1 is formed from material A comprising an elastic thermoplastic polymer, and material B comprising an inelastic thermoplastic polymer. Materials A and B are insoluble in each other.

Material A is preferably one of elastic thermoplastic polymers of the urethane, styrene, ester, ethylene, vinyl chloride and nylon families, or a mixture thereof. On condition that such elastic thermoplastic polymer or polymers constitute a major portion of material A, material A may additionally contain several percent of inelastic thermoplastic polymers.

Material B is preferably one of inelastic thermoplastic polymers of the polyester, polyolefin, nylon and polyvinyl alcohol families, or a mixture thereof. On condition that such inelastic thermoplastic polymer or polymers constitute a major portion of material B, material B may additionally contain several percent of elastic thermoplastic polymers.

Hydrophilic agents, antimicrobials, deodorants, etc. may be kneaded into either of materials A and B. Such hydrophilic agents include water-soluble polymers such as stearates, sodium sulfonates and polyethylene oxide, and are preferably added to one or each of materials A and B by about 0.2 to 7.0% by weight. The above antimicrobials and deodorants include titanium oxide, white carbon, silver compounds, zeolite and bamboo extracts, and are preferably added to one or each of materials A and B by about 0.2 to 2.0% by weight.

The stretchable nonwoven fabric 1 is formed from materials A and B following the steps shown in FIG. 2. As shown, materials A and B are first put into hopers 21 and 22, respectively, heated and melted in respective extruders 23 and 24, and fed into a die 25. Materials A and B flow through vertical passages formed in the die 25. In the bottom of the die 25, substantially circular minute nozzle openings 25a are formed so as to be arranged in rows and columns.

The nozzle openings 25a may be shaped as shown in FIGS. 3A to 3C. The nozzle opening 25a shown in FIG. 3A comprises a substantially dovetail-shaped central portion 25b and substantially oval side portions 25c disposed on both sides of the central portion 25b and having pointed tips at both ends of their major axes. The nozzle opening shown in FIG. 3B comprises a substantially square central portion 25b having three arcuate concave sides and one arcuate convex side, and three substantially oval side portions 25c each provided along one of the arcuate concave sides of the central portion 25b and having pointed tips at both ends of its major axis. The nozzle opening shown in FIG. 3C comprises a substantially ginkgo leaf-shaped central portion 25b, and a bilobed side portion 25c provided along the bottom edge of the central portion 25b.

Molten material A is fed into the central portion 25b of each nozzle opening 25a from the extruder 23, while molten material B is fed into the side portion or portions 25c of each nozzle opening 25a from the extruder 24. Thus, stretchable fibers 11 made of an elastic thermoplastic polymer are spun from the central portions 25b of the nozzle openings 25a, while unstretchable fibers 12 made of an inelastic thermoplastic polymer are spun from the side portions 25c of the nozzle openings 25a. As soon as the fibers 11 and 12 are spun, they are joined together in a molten state.

With the fibers 11 and 12 joined together, because materials A and B are insoluble in each other, they never melt into each other or mix with each other. Thus, according to the shape of the nozzle openings 25a of the die 25, composite fibers 10 as shown in FIGS. 4A to 4C are formed, of which the stretchable and unstretchable fibers 11 and 12 are alternately exposed to the surface.

The stretchable fiber 11 of FIG. 4A has two separate portions 11a and 11c that are exposed to the surface of the composite fiber 11. The stretchable fiber of FIG. 4B has three such exposed portions 11b, 11d and 11e, and the stretchable fiber of FIG. 4C has one such exposed portion 11f. The ratio of materials A and B, and the like are adjusted so that the content of the stretchable fiber 11 is 30 to 90% by weight based on 100% by weight of the entire composite fiber 10.

As shown in FIGS. 4A and 4B, of the exposed portions 11a to 11e of the stretchable fibers 11 of FIGS. 4A and 4B, the surface area ratios between the exposed portions 11a and 11b, i.e. the exposed portions having the largest surface areas of the respective fibers 11, and the other exposed portions 11c, 11d and 11e are determined so as to satisfy the following relations:

S(11c)/S(11a)<0.8

S(11d)/S(11b)<0.8

S(11e)/S(11b)<0.8

where S(11a) to S(11d) represent surface areas of the exposed portions 11a to 11d, respectively.

In the arrangement of FIG. 4C, of which the stretchable fiber 11 has only one exposed portion 11f, it can be considered that the stretchable fiber 11 has a second exposed portion having a zero surface area. Thus, the surface area ratio of the second exposed portion to the exposed portion 11f is 0/S(11f)=0<0.8.

As shown in FIG. 2, the composite fibers 10 pass through a cooling chamber 26 provided under the die. From an air blower 27 connected to the cooling chamber 26, air is continuously blown into the chamber 26, thereby cooling the composite fibers 10 when they pass through the chamber 26.

As shown in FIG. 2, a collecting conveyor 28 is provided under the cooling chamber 26. The collecting conveyor 28 comprises a pulley 28a and a net-like endless belt 28b driven by the pulley 28a. The conveyor 28 contains a suction box 29 to which a suction blower 30 is connected so that a suction force is applied to the endless belt 28b by the suction box 29. Thus, after passing through the cooling chamber 26, the composite fibers 10 are sucked to and deposited on the collecting conveyor 28. The fibers 10 are thus formed into a fiber web on the conveyor, which is fed toward the discharge end of the conveyer 28 by the moving endless belt 28b.

After being discharged from the discharge end of the conveyor 28, the fiber web is guided by guide rollers 31 into between a pair of heated embossing rollers 32. The fiber web is point-bonded when sandwiched between the heated embossing rollers 32a and formed into a fiber sheet.

The fiber sheet is then fed into between two pairs of nip rollers 33. The fiber sheet is stretched by a predetermined amount, preferably by 70% or more, when sandwiched between the nip rollers 33, and then released.

When the sheet is stretched, due to the above-described difference in surface area, large shear stress is produced at the interface between the stretchable fibers 11 and the unstretchable fibers 12, so that the fibers 11 and 12 are smoothly separated from each other. Also, as shown in FIG. 5, the unstretchable fibers 12 are three-dimensionally crimped, so that the fibers 12 are helically twisted around the stretchable fiber 11. The stretchable nonwoven fabric 1 thus obtained is therefore sufficiently bulky and voluminous, highly stretchable, and feels good to the touch with no rubber-like feel to the touch.

The stretchable nonwoven fabric 1 is wound onto a winder roller 34, cut, if necessary, and used.

In this embodiment, the composite fibers 10 are formed into the nonwoven fabric 1. But instead, a composite fiber 10 which is also formed from molten spun yarn may be formed into a stretchable composite fiber by e.g. directly feeding the fiber 10 into between two pairs of nip rollers to stretch it in the longitudinal direction, thereby splitting the fiber into a stretchable fiber 11 and an unstretchable fiber or fibers 12. By twisting together such stretchable composite fibers alone or such stretchable composite fibers and other fibers, a stretchable yarn is obtained. Further, a woven fabric can also be produced by weaving such yarns on a loom.

In the embodiment, the composite fiber 10 has a circular cross-section. But its cross-section is not limited to circular but may be polygonal or doughnut-shaped. The composite fiber 10 according to the present invention, which comprises the stretchable fiber 11 and the unstretchable fiber or fibers 12, is not limited in structure to those of the embodiment but may be designed freely, provided the above-mentioned relations of surface areas, weight ratios, etc. are met.

EXAMPLES

More detailed Examples of the invention and Comparative Examples are described to further clarify the present invention.

As the elastic thermoplastic polymer, a polyurethane resin having a hardness of about 80 was prepared, and as the inelastic thermoplastic polymer, a polypropylene resin having a melt flow rate (MFR) of about 30 was prepared.

From these resins, composite fibers of about 4 deniers according to Examples 1, 2 and 3, which have the cross-sections shown in FIGS. 6A, 6B and 6C, were formed in the manner outlined in the description of the embodiment. Composite fibers of about 4 deniers as Comparative Examples 1 and 2, which have the cross-sections shown in FIGS. 7A and 7B, were also formed.

The structures of the composite fibers of Examples of the invention and Comparative Examples are shown in Table 1. Each figure in the column of Rw in the table is the weight ratio (%) of the fiber made of the polyurethane resin to the entire composite fiber. Each figure in the column of Rs in the table is the ratio (%) of the surface area of one of the portions of the polyurethane resin fiber exposed to the surface of the composite fiber and having the largest surface area to the surface area of the other exposed portion or each of the other exposed portions. Each figure in the column of St in the table is the residual strain (%) in the composite fiber. As is apparent from the table, the composite fibers according to Examples of the invention are extremely small in residual strain compared to those of Comparative Examples.

	TABLE 1
	Rw	Rs	Sl
	Example 1 of the invention	60	23	5.7
	Example 2 of the invention	75	15, 13	3.9
	Example 3 of the invention	50	0	4.7
	Comparative Example 1	60	92	67.8
	Comparative Example 2	75	78, 82, 85	32.5

The composite fibers of Examples of the invention and Comparative Examples were laminated on belt conveyors to form fiber webs, as in the embodiment. The webs were point-bonded together with heated embossing rollers to obtain fiber sheets that weigh 80 grams per square meter. The thus obtained fiber sheets were guided into between two pairs of nip rollers to stretch them by 150%, thereby forming stretchable nonwoven fabrics of Examples of the invention and Comparative Examples.

FIG. 8 shows an enlarged photo of a thus obtained stretchable nonwoven fabric of Example of the invention, and FIG. 9 shows an enlarged photo of a thus obtained stretchable nonwoven fabric of Comparative Example.

As is apparent from FIG. 8, in the stretchable nonwoven fabrics of Examples of the invention, the polypropylene fibers are three-dimensionally crimped, and helically wrapped around the polyurethane fibers.

Because the polypropylene fibers are three-dimensionally crimped, the fabrics are bulky and voluminous, and feel good to the touch with no rubber-like feel to the touch because the polypropylene fibers are helically wrapped around the polyurethane fibers. Because the fibers are substantially completely separated from each other, they were stretched to a high degree.

On the other hand, in the stretchable nonwoven fabrics of Comparative Examples, as shown in FIG. 9, the polypropylene fibers are only two-dimensionally crimped, so that the fabrics are less voluminous because the polypropylene fibers are not wrapped around the polyurethane fibers. Also, as is apparent from FIG. 9, the polypropylene fibers and polyurethane fibers are not sufficiently separated from each other but they are partially joined together, so that the fabrics were not stretched sufficiently.

From these results, it was discovered that the stretchable nonwoven fabrics of Examples of the invention were superior to conventional such fabrics in voluminousness, feel to the touch and degree of expansion.

Claims

1. A stretchable composite fiber formed: by forming an integral composite fiber comprising a stretchable fiber and unstretchable fibers that are integrally joined together, said stretchable fiber having longitudinally extending first exposed surfaces that are circumferentially spaced from each other, said unstretchable fibers having longitudinally extending second exposed surfaces each disposed between a circumferentially adjacent pair of said first exposed surfaces;wherein one of said first exposed surfaces has a larger surface area than the other or others of said first exposed surfaces, said other or each of said others of said first exposed surfaces having a surface area ratio of less than 0.8 with respect to the surface area of said one of said first exposed surfaces; andby stretching said integral composite fiber in the longitudinal direction thereof, thereby separating said stretchable fiber and said unstretchable fibers from each other, and causing said unstretchable fibers to be three-dimensionally crimped and helically twisted around said stretchable fiber.

2. A stretchable composite fiber formed: by forming an integral composite fiber comprising a stretchable fiber and an unstretchable fiber that are integrally joined together, said stretchable fiber having a single longitudinally extending first exposed surface, said unstretchable fiber having a longitudinally extending second exposed surface disposed circumferentially adjacent to said first exposed surface; andby stretching said integral composite fiber in the longitudinal direction thereof, thereby separating said stretchable fiber and said unstretchable fibers from each other, and causing said unstretchable fibers to be three-dimensionally crimped and helically twisted around said stretchable fiber.

3. The stretchable composite fiber of claim 1 wherein said stretchable fiber accounts for 30 to 90% by weight of the entire stretchable composite fiber.

4. The stretchable composite fiber of claim 2 wherein said stretchable fiber accounts for 30 to 90% by weight of the entire stretchable composite fiber.

5. The stretchable composite fiber of claim 1 which contains at least one of hydrophilic components, antimicrobial components and deodorant components.

6. The stretchable composite fiber of claim 2 which contains at least one of hydrophilic components, antimicrobial components and deodorant components.

7. A stretchable yarn formed of a plurality of the stretchable composite fibers of claim 1 that are twisted together.

8. A stretchable yarn formed of a plurality of the stretchable composite fibers of claim 2 that are twisted together.

9. A nonwoven fabric comprising a plurality of the stretchable composite fibers of claim 1.

10. A nonwoven fabric comprising a plurality of the stretchable composite fibers of claim 2.