The disclosure relates to a stripping method for removing undesired flavoring substances from wort and a device for carrying out the method.
A plurality of stripping systems for removing undesired flavoring substances that form due to reaction kinetics during the manufacturing process at temperatures above 80° C. is available on the market. A well-known undesired flavoring substance is, for example, dimethylsulphide (DMS mainly formed from the precursor S-methylmethione (SMM) which is formed when malt is kilned). When the reaction product is not sufficiently stripped or the wort is kept hot for an insufficient period and the precursor is thus not sufficiently split, an undesired, vegetable-like taste will form in subsequent fermentation. Therefore, the standard value of 100 μg/l should not be exceeded. Many brewers meanwhile strive for values below 50 μg/l. In optimal wort boiling, the precursor product is sufficiently split, and in boiling systems with atmospheric circulation, the formed DMS is largely stripped.
In subsequent hot break removal, however, the undesired DMS is reproduced and cannot be stripped again. Manufacturing processes with malts of bad quality and/or shortened boiling times and/or insufficient boiling rely on subsequent stripping processes to achieve the desired wort quality. However, desired substances, such as hop aromas, will inevitably also be stripped in the stripping process. Several common systems have established for stripping which are, for example, based on the supply of thermal energy, the application of a vacuum, or the creation of large surfaces.
There are systems, for example, which guide hot wort over a heated screen for thermal stripping. The injection of hot water vapor flowing through a wort column is also known for stripping undesired flavoring substances.
As a consequence of all these systems, energy must be subsequently introduced and further wort reaction occurs by the action of heat. Apart from the supply of thermal energy, methods are known which cool down wort to a temperature uncritical for the forming of DMS upstream of the whirlpool rest. However, due to the higher viscosity of the wort resulting from cooler temperatures, this will lead to a deterioration of hot break separation.
Apart from thermal stripping, systems working with vacuum have established on the market. This step can also be achieved by multiple expansion evaporation resulting in a strong boiling movement with a corresponding surface having an advantageous effect on the stripping of flavoring substances. In all expansion evaporations, a clearly worse depletion of undesired flavoring substances is disadvantageously obtained, compared to, for example, atmospheric stripping. Moreover, for the generation of a vacuum, additional energy and water consumptions are necessary.
As a third process group with respect to wort stripping, the generation of large surfaces utilizing the hot wort's own energy can be mentioned. In this case, the wort is guided into a vessel where it runs downwards, for example at the container wall.
Systems which are exclusively based on the distribution of hot wort have the disadvantage of reducing their effectiveness as the wort inlet temperatures decrease. At low temperatures, only a small amount of water vapor and undesired flavoring substances will pass over into the gaseous phase under atmospheric conditions, despite an effective surface of a maximum size.
Starting from this situation, one aspect the present disclosure is to provide a stripping method and a stripping device which reliably permit to remove undesired flavoring substances and prevent their reproduction without using high quantities of energy.
So, according to the present disclosure, wort is first introduced into a stripping vessel and a falling film flowing downwards is created. Falling film here means a film that flows down towards the outlet at an inner wall of a container. Here, the falling film is formed underneath a distribution device, preferably essentially rotationally symmetrical to the central axis of the stripping container. The falling film can be introduced then, for example, into a liquid reservoir in the lower zone of the stripping container whose surface does not exceed a maximum filling level. By generating the falling film, the surface of the wort can be essentially enlarged, so that water vapor and undesired flavoring substances, for example DMS, can be depleted via the interface to the internal gas chamber.
By blowing stripping gas into the stripping container, the exsorption or stripping of undesired flavoring substances and water vapor can be promoted. Here, the total pressure in the stripping container corresponds to the sum of all partial pressures of the different gases in the stripping container. In a balance condition, the partial pressure of a dissolved gas over the falling film is proportional to its concentration in the falling film. If now the partial pressure (that means the concentration) of the stripping gas in the stripping container is increased by introducing the stripping gas, the partial pressure of the water vapor or the undesired flavoring substances is simultaneously decreased, so that by this partial pressure shift, for example water vapor and flavoring substances are increasingly stripped from the falling film. For this, it is not necessary to heat the stripping gas, so that stripping is possible with a very low amount of energy. The depleted flavoring substances and the water vapor can then be discharged with the flow of stripping gas.
So, by blowing in the stripping gas into the external stripping container, the reduction of undesired flavoring substances, such as DMS, in the hot wort can be influenced, so that stripping can be kept at a constantly high level, even with low wort inlet temperatures or different wort volume flows.
Particularly advantageously, the method is employed for wort freed from hot break which is further cooled after stripping. If the stripping process is carried out after hot break separation, undesired flavoring substances which are reproduced in hot break separation can be effectively removed. Since in the method according to the disclosure, no further thermal energy is supplied, their reproduction during and after the stripping process can be prevented. If the wort is already freed from hot break in the stripping process, the falling film can be better and more uniformly formed.
It is particularly advantageous if the outlet temperature of the wort is lower than the inlet temperature of the wort. This means that the wort flowing down in the falling film is cooled by the stripping gas. This means that by the stripping gas, on the one hand more water and flavoring substances pass over into the gaseous phase due to the partial pressure shift, but on the other hand, a new formation of undesired flavoring substances is also prevented by the temperature reduction of the wort. Since no additional energy must be supplied, the stripping gas can be unheated and thus e.g. have ambient temperature. The stripping gas can thus preferably have room temperature or expansion temperature, that means a temperature<40° C.
According to a preferred embodiment of the present disclosure, the volume flow rate of the stripping gas is adjusted or controlled, respectively, so that, independent of the wort inlet temperature, a constant amount of water vapor and undesired flavoring components can be stripped.
In particular, the volume flow rate of the stripping gas is adjusted depending on the temperature difference ΔT between the inlet temperature and the outlet temperature of the wort, and it is advantageously automatically controlled. Since the temperature decrease ΔT is proportional to the forming water vapor or the flavoring components that have passed over into the gaseous phase, i.e. the amount of stripping gas, the stripping amount can be exactly adjusted by the adjustment or control of the volume flow rate of the stripping gas.
One can react to lower wort inlet temperatures with a higher amount of stripping gas. Such a method can be easily and inexpensively realized. So, a constant amount of stripping gas can also be adjusted at different wort inlet temperatures, and also independent of the volume flow rate of the wort. The temperature difference can be determined by measuring the inlet and outlet temperatures of the wort and by subtraction. Such a control is particularly simple. However, it is also possible to adjust the stripping gas volume in response to a value proportional to the temperature difference, which is determined, for example, on the basis of the inlet temperature of the wort and the volume flow rate of the wort when the falling film surface is known.
Advantageously, the volume flow rate of the stripping gas is adjusted or controlled such that a predetermined temperature difference ΔT results which is within a range of 0.1 to 10° C., in particular 0.1-5° C. In this range, the undesired flavoring substances can be particularly well stripped. This means that a desired ΔT is determined for various sorts, and thus a certain amount of undesired flavoring components can be stripped.
Advantageously, at least one of the following group is used as stripping gas: inert gas, air, CO2, N2, O2. Preferably, the stripping gas is sterile and free from water vapor. If N2 is used, it can be generated particularly inexpensively from ambient air by a nitrogen generator.
By introducing the stripping gas, a slight overpressure can prevail in the stripping container, compared to atmospheric pressure. This overpressure, however, is maximally 250 mbar in addition to atmospheric pressure.
It is advantageous to introduce the stripping gas into the gas chamber of the stripping container in particular centrally via an inflow opening directed upwards or downwards, and/or to directly blow it into the filling level of the wort. If the stripping gas is guided into the gas chamber via an inflow opening directed downwards, one will have the advantage that also the minor surface of the wort in the lower zone of the stripping gas container is “blown off”, whereby here, too, the temperature is effectively further reduced and hydrogen and flavoring components pass over into the gaseous phase.
In a particularly preferred embodiment, the stripping gas will rise to the top in a reverse current to the falling film guided downwards.
The inventive device for carrying out the method comprises a stripping container, a wort feed, a distributor device for generating a falling film, a wort drain and stripping gas supply and discharge lines which generate a flow of stripping gas in the stripping container.
As stripping gas, a wort copper, a mash vessel, a whirlpool or other containers occurring in a brewery can also be employed apart from an external container.
A corresponding device can be manufactured relatively easily and inexpensively. Advantageously, the device comprises a temperature sensor for measuring the inlet temperature of the wort, and a temperature sensor for measuring the outlet temperature of the wort. The device can equally comprise a control valve for adjusting the volume flow rate of the stripping gas. With such an arrangement, the volume flow rate of the stripping gas can be adjusted e.g. in response to a temperature difference ΔT of the inlet and outlet temperatures.
To be able to also allow for thermal fluctuations of the wort, the volume flow rate of the gas is advantageously not only adjusted to a certain ΔT, but a control device is also provided which controls the volume flow rate of the stripping gas in response to the temperature difference ΔT between the inlet temperature and the outlet temperature of the wort.
To realize a uniform flow of stripping gas, the stripping gas supply line is advantageously designed such that it comprises an inflow opening located centrally in the container, preferably facing downwards.
Different distributor devices can be provided for generating the falling film. It is possible, for example, to provide a swirl inlet nozzle which makes the wort rotate such that it will flow down the container's inner wall as a falling film from an upper zone of the container. However, it is also possible to provide a wort directional screen, in particular a double screen which sprays the wort in a thin film towards the container's inner wall, so that a falling film will flow down the container's inner wall. It is finally also possible to provide an annular conduit in the upper zone of the container which comprises either several openings arranged at its circumference or an annular gap which directs the wort to the container's inner wall, such that the wort can flow down the container's inner wall as a falling film.
It is particularly advantageous to provide a brewhouse arrangement wherein the stripping device according to the disclosure is arranged between the apparatus for hot break separation and the apparatus for wort cooling. Then, the inlet temperature of the wort into the stripping container has a temperature within a range of 80-100° C.
It is advantageous for the stripping container to comprise a bottom whose diameter diminishes downwards and which preferably has a conical design and/or a sensor for level control. By the conical bottom, in the outlet zone of the stripping container, a high filling level with a simultaneously small volume is possible which ensures sufficient admission pressure for the subsequent wort pump. By the sensor for level control, a desired filling level can be determined.
The disclosure will be illustrated below with reference to the following figures.
The inlet 2 is provided with a distributor device 4 which is designed such that it forms a falling film 19 at an internal surface of the container. Falling film here means a film that flows down at an inner wall of a container towards the wort drain 3. The falling film is here formed underneath the distributor device 4, preferably rotationally symmetric to the central axis M of the stripping container. The falling film can then flow, for example, into a liquid reservoir 42 in the lower zone of the stripping container 1. The thickness of the falling film is within a range of 0.1-1 mm. The falling film has two interfaces, one being directed to the container's inner wall and the other one being directed to the inner gas chamber 40. Thus, a large surface of the wort is efficiently produced.
In this embodiment, a swirl inlet nozzle is provided as distributor device 4. Such a swirl inlet nozzle is shown more in detail in
The use of this swirl element is particularly advantageous. However, it is also possible to use other distributor devices, for example the double screen shown in
While it is not represented, it is, for example, also possible to provide an annular conduit in the upper zone of the stripping container which comprises either several openings arranged at the circumference or an annular gap guiding the wort to the container's inner wall, such that the wort can flow down at the container's inner wall as a falling film.
Apart from the wort feed and drain 2, 3, the container also comprises a stripping gas supply line 5 in the lower zone of the container and a stripping gas discharge line 6, preferably in the upper zone of the container. By the stripping gas supply and discharge lines, a flow of stripping gas 21 can be generated. In this embodiment, the stripping gas discharge line is disposed at the upper end of the container and extends through the inner inset 26 of the nozzle 4. As can be taken from
The embodiment shown in
So, the stripping gas, e.g. an inert gas, sterile air, CO2, O2 or N2, can flow to the top via the stripping gas supply line 5 in a reverse current to the flowing down falling film 19.
By blowing in the stripping gas into the stripping container 1, the stripping of undesired flavoring substances and water vapor 20 can be controlled.
Here, the total pressure pg in the stripping container corresponds to the sum of all partial pressures pi of the different gases in the gas chamber 40 of the stripping container.
p
g
=Σp
i
p
g=(pair+pDMS+presidual components)+pH
wherein e.g. pg=1000 mbar; pair+pDMS+presidual components=150 mbar; pH
The partial pressures act as the corresponding volumes. The partial pressure of a dissolved gas over the falling film, i.e. in the gas chamber 40, is proportional to its concentration in the falling film in balance. If now the partial pressure of the stripping gas in the stripping container is increased by introducing the stripping gas 21, the partial pressure of the water vapor or the undesired flavoring substances 20, respectively, is simultaneously reduced, so that by this partial pressure shift, for example water vapor and DMS, and also the other flavoring components are increasingly exorbed. For this, it is not necessary to heat the stripping gas, so that stripping is possible with a very low amount of energy. The depleted flavoring substances and the water vapor can then be discharged with the flow of stripping gas.
So, by blowing in the stripping gas into the external stripping container 1, the reduction of undesired flavoring substances in the hot wort can be selectively influenced in response to the volume flow rate of the stripping gas, so that stripping can be kept at a constantly high level, even with low wort inlet temperatures or different wort volume flow rates.
The wort cools down as it is flowing down as a falling film. The temperature decrease is proportional to the volume flow rate of the stripping gas and thus also to the amount of stripped water or flavoring components, respectively, the stripping gas amount maintaining—corresponding to an efficiency—the driving gradient between the water vapor and flavoring substances at the falling film to the interior of the container 40.
Thus, the volume flow rate of the stripping gas can be adjusted, in particular automatically controlled, in response to the temperature difference ΔT between the inlet temperature and the outlet temperature of the wort to thus adjust a constant amount of stripped water or flavoring components, independent of the wort inlet temperature or the wort volume flow rate. Since the outlet temperature of the wort is lower than the inlet temperature of the wort, the stripping gas can have room temperature or expansion temperature, but normally a temperature of <40° C., and is therefore unheated, but neither cooled. It showed that it is advantageous, as will be illustrated more in detail below, to adjust the volume flow rate of the stripping gas such that a predetermined temperature difference ΔT is within a range of 0.1 to 10° C., in particular 0.1-5° C. A certain ΔT can be determined for different wort sorts by experiments (e.g. by the quantitative analysis of DMS), so that the water vapor formation and the amount of stripped flavoring components also proportional to ΔT, respectively, can be adjusted.
The next diagram shows the content of free DMS in wort, which was stripped with the above described device, in response to ΔT. As can be seen in the graph of
As can be taken from
Finally, the line 14 for the stripping gas, e.g. CO2, is provided. The control valve 11 is located in this line, by which the volume flow rate of the stripping gas which is supplied to the container 1 can be adjusted. Moreover, the arrangement comprises a temperature sensor 8 which is here provided in the wort line 9 to measure the temperature of the incoming wort. Finally, a further temperature sensor 7 is provided in the outlet zone of the container 1 which determines the outlet temperature of the wort. The temperature sensor 7 is here disposed in the lower conical end of the container 1, but it could also be arranged, for example, in the line 15. The temperature sensors 8 and 7 are connected with a controller 24 which controls the volume flow rate of the stripping gas via the control valve 11 in response to the temperature difference ΔT.
In the upper zone of the container 1, here a condensate return protection 50 as well as a condensate line 12 via which the condensate can be discarded via the drain 23 are moreover shown. Via the line 13, the stripped water vapor and the other stripped components can be discharged and condensed and discarded. The energy of the condensed water vapor can here be recovered and reused.
Between the lines 14 and 9, a valve 16 is provided for rinsing purposes.
Between the lines 9 and 15, a valve 17 for bypassing the stripping is provided.
Below, a method according to the disclosure will be illustrated more in detail with reference to
First, a desired ΔT is determined in advance for a certain wort type, as was explained in connection with
Here, the wort can be conducted via the line 9 to the feed 2, in particular after hot break separation, e.g. from the whirlpool. The temperature of the incoming wort is, for example, 80 to 100° C. As described above, a certain volume flow rate is adjusted via the control valve 10 such that a certain filling level of the wort 41 in the container 1 can be adjusted. The discharge valve 22 is correspondingly adjusted. The volume flow rate of the wort is e.g. 5-60 m3/h. The wort flowing in via the feed 2 is distributed by the distributor device 4, so that a falling film 19 flowing downwards is produced (see also
Via the line 14, stripping gas 21 is introduced via the stripping gas inlet 5 into the container 1. The stripping gas 21 flows to the top in a reverse current to the falling film 19 (also see
During stripping, a slight overpressure can be formed, depending on the air pressure of the ambient atmosphere. The wort cools down during stripping, and the temperature of the introduced wort is determined by the temperature sensor 8, and that of the cooled wort is determined by the temperature sensor 7. If now, for example, ΔT is smaller than ΔTnominal, the stripping gas flow is increased such that ΔT corresponds to a desired value or value range. In the process, the controller 24 correspondingly activates the control valve 11. If ΔT is greater than ΔTnominal, the volume flow rate of the stripping gas is reduced by the control valve 11 until ΔT reaches again a corresponding nominal value or lies within a corresponding nominal value range. By adjusting the stripping gas flow in response to the temperature difference ΔT, thus a constant desired amount of undesired flavoring substances 20 can be stripped at all times. The stripped wort can be supplied to a wort cooler (32) via the wort pump 18 and line 15 (see
In the above described embodiments, the temperature difference was determined by measuring the inlet and outlet temperatures of the wort via the corresponding sensors. However, it is also possible to adjust or control the stripping gas volume in response to a value proportional to the temperature difference, which is determined, for example, on the basis of the inlet temperature of the wort and the volume flow rate of the wort with a known falling film surface.
Number | Date | Country | Kind |
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10 2010 028 980.9 | May 2010 | DE | national |
The present application is the United States national phase of priority of International Patent Application No. PCT/EP2011/001873, filed Apr. 13, 2011, which application claims priority of German Application No. 102010028980.9, filed May 14, 2010. The entire text of the priority application is incorporated herein by reference.
Filing Document | Filing Date | Country | Kind | 371c Date |
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PCT/EP2011/001873 | 4/13/2011 | WO | 00 | 12/11/2012 |