Structural reinforcements

Information

  • Patent Grant
  • 6311452
  • Patent Number
    6,311,452
  • Date Filed
    Friday, October 13, 2000
    24 years ago
  • Date Issued
    Tuesday, November 6, 2001
    23 years ago
Abstract
A composite structural reinforcement has a keyed reinforcement member in which a thermally expandable resin strip is mechanically retained. The mechanical interlock permits the resin to be secured to the member without heat or an adhesive.
Description




TECHNICAL FIELD




The present invention relates generally to the reinforcement of hollow structures and more specifically to the use of rigid reinforcements which utilize expandable resins.




BACKGROUND OF THE INVENTION




There has been an increase in the need for selective reinforcement of automotive structures in order to meet various government test standards. To that end, structural foams and carriers have been developed for the purpose of reinforcing specific locations in vehicles. The primary focus of these reinforcements is to add strength or stiffness to a structure.




As will be appreciated by those skilled in the art, the three factors of greatest general importance in the evaluation of reinforcement effectiveness are stiffness, weight, and cost. With most prior art techniques, increasing stiffness results in a corresponding penalty of weight increase and/or cost increase. For example, while using thicker gages of metal increases strength, it results in an unwanted increase in weight. Similarly, the use of exotic high-strength alloys is effective to increase strength, but this adds considerably to the cost of the vehicle. Finally, it will be recognized that the cost of resins is also a concern and thus structural foams must be used sparingly.




Another concern in the use of structural foams is the problem associated with fully curing material that is very thick. That is, in some prior art applications the materials required to satisfactorily reinforce are so thick that it is difficult to achieve full cure. Therefore, it will be recognized that techniques for reinforcing hollow structures which do not cause a substantial weight and cost or curing problems have the potential to provide significant advantages.




It is therefore an object of the present invention to provide a structural reinforcement which utilizes structural foam in a manner which conserves resin.




It is a further object of the invention to provide such a reinforcement which can be fully cured in a short time.




It is still a further object to provide a low-cost, light-weight structural reinforcement which provides significant strength and stiffness to the reinforced region.




It is still a further object to provide a structural reinforcement which can be transported easily to the site of installation.




SUMMARY OF THE INVENTION




In one aspect the present invention provides a keyed reinforcing member having a rigid body and an attached uncured resin portion. The rigid body includes a surface having a geometry that mates with the uncured resin to form a purely mechanical interlock between the rigid body and the resin. In one aspect the rigid member has an interlocking channel in which a strip of uncured resin is disposed. In one aspect the rigid member is linear, in other applications the member is non-linear with the resin strip being disposed circumferentially. In still another aspect the rigid member has attachment sites and locator pins which facilitate its location and attachment to the hollow structural body to be reinforced.




In another aspect the present invention provides a method of reinforcing a structure comprising the steps of providing a rigid member having a surface adapted to receive and mechanically retain an uncured resin body having a preselected shape. An uncured resin body having the mating geometry is inserted in the interlocking portion of the rigid member. The composite keyed reinforcement is then placed in the appropriate location of the structural body to be reinforced. The composite keyed reinforcement is then heated to a temperature sufficient to foam (expand) and cure the resin. Typically, the foam will then bond to the surrounding structural body.




Thus, the invention provides a way to reduce cost, improve stiffness, and increase the possibility of achieving full cure of the structural foam all through the use of a composite construction. The keying of the surface of the reinforcement member permits uncured resin to be applied such that mechanical interlocking between the member and the applied uncured resin occurs. This interlocking permits the resin to be positioned on the reinforcement member without the necessity of heating the reinforcement member, using a secondary adhesive, heating the uncured structural foam, or using a pressure sensitive uncured structural foam. In addition to processing ease, the keyed surface produces a structure that is strongly resistant to damage during shipping or handling in an assembly plant. In one aspect the primary uncured heat expandable material attached to the keyed reinforcing member is not pressure sensitive. This enables packaging such that adjacent preformed parts do not adhere to each other during shipping (i.e. the material does not behave as a pressure sensitive adhesive).




These features and others will be more fully explained herein in connection with the drawings.











BRIEF DESCRIPTION OF THE DRAWINGS





FIG. 1

is a cross sectional view of a rigid linear member of the keyed reinforcement of the present invention, prior to attachment of the resin strip.





FIG. 2

is a cross section of a group of resin strips prior to insertion into the linear member of FIG.


1


.





FIG. 3

is a cross sectional view of keyed reinforcement depicted in

FIG. 1

after attachment of the resin strips of FIG.


1


and with insertion of a locator pin.





FIG. 4

is a side view of the keyed reinforcement member depicted in

FIG. 1

of the drawings.





FIG. 5

is a cross section of a linear keyed reinforcement in another embodiment.





FIG. 6

is a perspective view of a portion of a non-linear keyed reinforcement in one aspect of the invention.





FIG. 7

is a cross section along lines


7





7


of

FIG. 6

but with the resin strip inserted into the channel.





FIG. 8

is a plan view of the complete ring structure partially depicted in FIG.


6


.











DESCRIPTION




Referring now to

FIGS. 1 through 4

of the drawings, multi-walled keyed member


20


is depicted as a linear extrusion having opposed walls


22


,


24


and opposed walls


26


,


28


. Keyed member


20


serves not only to provide stiffness and strength to composite structural reinforcement member


30


(FIG.


3


), but also as a mechanically interlocking carrier for thermally expandable resin strips


32


. Keyed member


20


may be formed of a number of materials such as aluminum, light-weight steel and high-strength plastics. Most preferably, keyed member


20


is an aluminum extrusion, but can also be done effectively using injection molded, compression molded, blow molded, extruded, or rotational molded plastic or stamped or roll formed steel as well as other forming methods known to those skilled in the art of material use and forming. In this particular embodiment, keyed member


20


has an internal partition or wall


34


which defines two chambers,


36


and


38


. Partition


34


provides additional strength and rigidity to member


20


.




In the embodiment of

FIGS. 1-4

each wall of keyed member


20


is provided with at least one channel


40


which is adapted to retain one resin strip


42


. In more detail, and referring now to

FIG. 1

of the drawings, wall


22


of keyed member


20


has channel


40


which will generally be coextensive along the entire length of keyed member


20


. In this particular embodiment channel


40


is provided with lips or flanges


44


which extend partially over the opening or cavity of channel


40


. As shown in

FIG. 3

, resin strips


42


have a shape which mates with channels


40


to provide a mechanical interlock as shown best in

FIG. 3

of the drawings. It is to be understood that the precise mating shapes or geometries of the keyed member and the interlocking strip are not critical to the practice of the invention. It is important, however, that the two (member


20


and strips


42


) have shapes which achieve the desired mechanical interlock, i.e. resin strips


42


are held in place by member


20


without the need for an adhesive bond or external additional locking parts. Thus, in the example shown in

FIGS. 2 and 3

of the drawings lower edges


46


of resin strips


42


extend to engage lips


44


of channels


40


. In

FIG. 4

of the drawings, the linear nature of keyed member


20


and strip


42


are shown more clearly. It will be appreciated that strips


42


(which will also preferably be extruded) can be easily slipped into channels


40


for assembly of composite reinforcement structure


30


or may be formed in place as will be more fully described herein.




In order to locate composite reinforcement


30


in a structure to be reinforced, such as a motor vehicle body, and referring now to

FIG. 3

of the drawings locator pin


48


may be provided. The nature of locator pins will be well known to those skilled in the art. In addition, in the most preferred embodiment of the invention at least two walls of keyed member


20


(in terms of area) are each at least 25% covered (this is total coverage and coverage may be interrupted) by their respective resin strips.




Referring now to

FIG. 5

of the drawings in another embodiment composite reinforcement


50


has keyed member


52


with a central web


54


that forms channels


56


in which resin strips


58


are mechanically held in T-shaped locking configuration. This illustrates the variable nature of the interlocking surfaces of the keyed member and the resin strips; here, strip


58


has a convex surface


60


that is received in a concave depression


62


. As in the previously described embodiment strips


64


are provided such that all sides of keyed member


52


have an associated resin strip. Locator pin


66


is also shown.




The construction of the present invention enables a number of different options for installation in a hollow structural part of a motor vehicle. One possibility is to attach end caps (not shown) to the reinforcing structure. These end caps may have an integral fastener or be spring loaded to enable installation and positioning in a vehicle. Another option is to form a part that has the near net shape of the structure that it is intended to reinforce such that when installed into a hollow cavity it becomes trapped and is thereby positioned. This would typically be a vehicle area that requires a reinforcement that is not linear and involves laying a part into a partial cavity that is later capped with another piece of sheet metal. An additional method of installation is to apply a pressure sensitive adhesive to some surface of the composite reinforcing structure. Depending on goals of the reinforcement, the pressure sensitive adhesive may or may not also have structural characteristics following cure.




As stated above, in one embodiment of the invention composite keyed reinforcement


30


is linear; that is, preferably its length is at least twice its width or height. In another preferred embodiment, however, and referring now to

FIGS. 6 through 8

of the drawings, composite reinforcement


70


is in the nature of a ring or continuous wall structure. Each face


72


has a channel


74


into which a resin strip


76


is disposed by mechanical interlock as in the previously described embodiments. (In addition, as best shown in

FIG. 7

, in a preferred embodiment of the invention at least 50% by weight of resin strip


76


resides outside of channel


74


although it is not necessary that any material reside outside in some applications.) Accordingly, the structures of

FIGS. 1-5

would typically be used if increased bending resistance is required. If reinforcement for so-called breathing or oil canning is required, circumferential material of FIGS.


6


through may be used.




Resin strips


42


,


64


and


76


are thermally expandable. That is, upon the application of heat they will expand, typically by a foaming reaction, and preferably to at least 50% the volume of the unexpanded state, but more preferably twice (the unexpanded state being depicted in the drawings). In a preferred embodiment, the resin used to form the resin strips is an epoxy-based material.




Resin preferably forms from about 5% to about 75% by weight and more preferably from about 15% to 65% by weight of the resin strip. Filler preferably forms from about 0% to about 70% by weight and more preferably from about 20% to about 50% by weight of the resin strip. Blowing agent preferably forms from about 0% to about 10% by weight and more preferably from about 0.2% to 5% by weight of the resin strip. Curing agent preferably forms from about 0% to about 10% by weight and more preferably from about 0.5% to 5% by weight of the resin strip. Accelerator preferably forms from about 0% to about 10% by weight and more preferably from about 0.3% to 5% by weight of the resin strip. One preferred formulation is set forth in Table I below.



















Ingredient




% by Weight













Epoxy Resin




15% to 65%







Ethylene Copolymer




 0% to 20%







Blowing Agent




0.2% to 5%  







Curing Agent




0.5% to 5%  







Accelerator




0.3% to 5%  







Filler




20% to 50%















As stated, the heat expandable material is most preferably a heat-activated, substantially epoxy-based material. However, other suitable materials may also be suitable. These include polyolefin materials, copolymers and terpolymers with at least one monomer type an alpha-olefin, phenol/formaldehyde materials, phenoxy materials, polyurethane materials with a high glass transition and others. In general the desired characteristics of this heat expandable material will be high stiffness, high strength, high glass transition temperature, good corrosion resistance, ability to adhere to contaminated metallic and polymer surfaces, fast cure upon activation, good handing characteristics, low cured density, low cost, and long shelf life.




As stated, composite keyed reinforcement part


30


is most preferably intended to be placed in a hollow vehicle cavity for the purpose of structural reinforcement. When the vehicle is heated, the heat expandable material (structural foam) expands to contact the surface of the hollow cavity that it is intended to reinforce. It is not necessary that the space between the member and the inner surface of the hollow cavity or other surface being reinforced be fully filled with expanded heat expandable material for substantial reinforcement to occur. If full filling is required, it is possible to space the distance between pieces of uncured heat expandable material and/or adjust the quantity of heat expandable material such that the heat expandable material knits together during the expansion process.




A particular benefit of the present invention is that it permits large sections to be reinforced with full confidence that the structural foam material will fully cure. Because the material must be heated to cure, it is important that full cure occur to obtain optimum properties. If very large sections are filled with structural foam alone, then the difficulty of obtaining sufficient heat transfer through the material can be difficult. Use of a keyed composite reinforcing member greatly increases the probability that full cure will occur. This is possible both because it permits the possibility of using less heat activated foam and the rigid reinforcement provides a heat transfer conduit to the inner surface of the heat activated material. An additional benefit is that a reinforcement with less weight and lower cost can be provided for certain design types. A further additional benefit is that it permits the possibility of producing a part that is highly resistant to damage during transport owing to the support that the keyed reinforcing member provides to the heat expandable material.




Keyed reinforcing member


20


can be produced in many different ways which facilitates production of a keyed indentation that permits mechanical interlocking. It is possible to make a keyed reinforcing member by aluminum extrusion, steel roll forming, pultruded polymer composites, extruded polymers, blow molded polymers, thermoformed extruded polymers, and compression molded powder metals. Many other methods can be envisioned as well. The type of reinforcement is dictated by desired part shape, performance characteristics, and cost.




Composite reinforcing structure


30


may be constructed by dispensing heat activated expandable material onto the keyed reinforcing member using an extruder, including an extruder that is articulated by a robot. This process relies on the extruder being positioned such that molten heat expandable material is dispensed into the keyed section of the keyed reinforcement member. Upon cooling, the heat expandable material will stiffen and resist deformation while being transported. Upon sufficient reheating (a temperature necessarily higher than the temperature used to shape the heat expandable material), the heat expandable material will be activated such that it will expand and cure in the hollow vehicle cavity and thereby provide the desired reinforcement. A particularly preferred way of dispensing material onto a keyed reinforcing member is to use a robot articulated extruder to press the molten heat expandable material into the keyed sections. An additional method is to insert injection mold this material onto the keyed reinforcing structure. Another way of constructing this kind of reinforcement is to separately extrude the heat expandable material into a shape that mimics the section of a keyed location and then slide or snap the heat expandable material into the keyed section of a keyed reinforcing member. A further additional way of making the composite construction is to press molten of deformable heat expandable material into the keyed section of the reinforcing member.



Claims
  • 1. A structural reinforcement system for structurally reinforcing a hollow member, said reinforcement member comprising:(a) a member having at least one longitudinal channel incorporated about its periphery, said member adapted for placement in a cavity defined in an automotive vehicle frame; and (b) an expandable material disposed within at least one of said channels over at least a portion of said member.
  • 2. The system as claimed in claim 1, wherein said member is a metal alloy.
  • 3. The system as claimed in claim 1, wherein said member is injection molded.
  • 4. The system as claimed in claim 1, wherein said member is aluminum.
  • 5. The system as claimed in claim 1, wherein said member is a formed steel.
  • 6. The system as claimed in claim 1, wherein said expandable material is a heat activated expandable polymeric material having foamable characteristics when exposed to heat.
  • 7. The system as claimed in claim 1, wherein said member has at least two longitudinal channels disposed substantially over the entire length of said member.
  • 8. The system as claimed in claim 1, wherein said member includes ribs for retaining said expandable material in said channels.
  • 9. The system as claimed in claim 1, wherein said member is adapted for reinforcing a hollow structural member of a motor vehicle.
  • 10. The system as claimed in claim 1, wherein said expandable material is suitable for placement within and along said plurality of channels of said members.
  • 11. A reinforcement system for hollow members of an automotive vehicle, comprising:(a) a hollow member adapted for insertion in a cavity of an automotive vehicle, said member having a plurality of longitudinal channels defined about its periphery; and (b) an expandable material disposed within at least one of said channels in sealing contact with at least a portion of said member and at least one of said plurality of channels.
  • 12. The system as claimed in claim 11, wherein said hollow member includes at least two longitudinal passageways separated by a partition.
  • 13. The system as claimed in claim 11, wherein said member is a metal alloy.
  • 14. The system as claimed in claim 11, wherein said member is injection molded.
  • 15. The system as claimed in claim 11, wherein said member is aluminum.
  • 16. The system as claimed in claim 11, wherein said member is a formed steel.
  • 17. The member as claimed in claim 11, wherein said expandable material is a polymeric material having structurally adhering properties when exposed to heat.
  • 18. The member as claimed in claim 11, wherein said expandable material is an epoxy-based polymeric material.
  • 19. The member as claimed in claim 11, wherein said expandable material is a heat activated material having foamable characteristics when exposed to heat.
  • 20. The member as claimed in claim 11, wherein said expandable material is a structurally adhering polymeric material that is generally free of tack to the touch.
  • 21. A reinforcement member for structurally reinforcing a hollow member of an automotive vehicle, said reinforcement member comprising:(a) a rigid member having a plurality of channels configured about its periphery for receiving and mechanically retaining an expandable material inserted therein, said member being adapted for placement in a cavity defined in an automotive vehicle frame; and (b) an expandable material disposed in at least one of said channels and over at least a portion of the surface adjacent said channel of said member, said expandable material being suitable for foaming upon activation through heat and adhering to said member.
  • 22. The member as claimed in claim 21, wherein said member is a metal alloy.
  • 23. The member as claimed in claim 21, wherein said member is injection molded.
  • 24. The member as claimed in claim 21, wherein said member is aluminum.
  • 25. The member as claimed in claim 21, wherein said member is a formed steel.
  • 26. A reinforcement system for a hollow member of an automotive vehicle, comprising:(a) an automotive vehicle body member, said body member having a wall structure defining an internal passageway therein; and (b) a rigidifying member having a channel defined on an outer surface thereof, and (c) an expandable material disposed in said channel over at least a portion of the exterior of said member, said expandable member being suitable for foaming upon activation and adhering said member to said wall structure of said vehicle body.
  • 27. The system as claimed in claim 26, wherein said member is a metal alloy.
  • 28. The system as claimed in claim 26, wherein said member is injection molded.
  • 29. The system as claimed in claim 26, wherein said member is aluminum.
  • 30. A The system as claimed in claim 26, wherein said member is a formed steel.
Parent Case Info

This application is a continuation of application number 09/268,810 filed on Mar. 10, 1999 now U.S. Pat. No. 6,131,897.

US Referenced Citations (110)
Number Name Date Kind
3054636 Wessels, III Sep 1962
3123170 Bryant Mar 1964
3493257 Fitzgerald et al. Feb 1970
3665968 DePutter May 1972
3746387 Schwenk Jul 1973
3757559 Welsh Sep 1973
3890108 Welsh Jun 1975
4019301 Fox Apr 1977
4082825 Puterbaugh Apr 1978
4090734 Inami et al. May 1978
4238540 Yates et al. Dec 1980
4378395 Asoshina et al. Mar 1983
4397490 Evans et al. Aug 1983
4440434 Celli Apr 1984
4457555 Draper Jul 1984
4559274 Kloppe et al. Dec 1985
4610836 Wycech Sep 1986
4613177 Loren et al. Sep 1986
4705716 Tang Nov 1987
4732806 Wycech Mar 1988
4751249 Wycech Jun 1988
4762352 Enomoto Aug 1988
4803108 Leuchten et al. Feb 1989
4836516 Wycech Jun 1989
4853270 Wycech Aug 1989
4861097 Wycech Aug 1989
4898630 Kitoh et al. Feb 1990
4901500 Wycech Feb 1990
4908930 Wycech Mar 1990
4917435 Bonnett et al. Apr 1990
4922596 Wycech May 1990
4923902 Wycech May 1990
4978562 Wycech Dec 1990
4989913 Moore, III Feb 1991
4995545 Wycech Feb 1991
5102188 Yamane Apr 1992
5122398 Seiler et al. Jun 1992
5124186 Wycech Jun 1992
5213391 Takagi May 1993
5255487 Wieting et al. Oct 1993
5266133 Hanley et al. Nov 1993
5344208 Bien et al. Sep 1994
5373027 Hanley et al. Dec 1994
5395135 Lim et al. Mar 1995
5506025 Otto et al. Apr 1996
5560672 Lim et al. Oct 1996
5575526 Wycech Nov 1996
5580120 Nees et al. Dec 1996
5642914 Takabatake Jul 1997
5648401 Czaplicki et al. Jul 1997
5649400 Miwa Jul 1997
5652039 Tremain et al. Jul 1997
5707098 Uchida et al. Jan 1998
5725272 Jones Mar 1998
5731069 Delle Donne et al. Mar 1998
5755486 Wycech May 1998
5766719 Rimkus Jun 1998
5785376 Nees et al. Jul 1998
5786394 Slaven Jul 1998
5803533 Schulz et al. Sep 1998
5804608 Nakazato et al. Sep 1998
5806915 Takabatake Sep 1998
5806919 Davies Sep 1998
5855094 Baudisch et al. Jan 1999
5866052 Muramatsu Feb 1999
5884960 Wycech Mar 1999
5885688 McLaughlin Mar 1999
5888600 Wycech Mar 1999
5888642 Meteer et al. Mar 1999
5901528 Richardson May 1999
5904024 Miwa May 1999
5932680 Heider Aug 1999
5934737 Abouzahr Aug 1999
5941597 Horiuchi et al. Aug 1999
5984389 Nuber Nov 1999
5985435 Czaplicki et al. Nov 1999
5988734 Longo et al. Nov 1999
5992923 Wycech Nov 1999
5994422 Born et al. Nov 1999
6003274 Wycech Dec 1999
6004425 Born et al. Dec 1999
6022066 Tremblay et al. Feb 2000
6033300 Schneider Mar 2000
6050630 Hochet Apr 2000
6058673 Wycech May 2000
6059342 Kawai et al. May 2000
6068424 Wycech May 2000
6077884 Hess et al. Jun 2000
6079180 Wycech Jun 2000
6082811 Yoshida Jul 2000
6090232 Seeliger et al. Jul 2000
6092864 Wycech et al. Jul 2000
6094798 Seeliger et al. Aug 2000
6096403 Wycech et al. Aug 2000
6096791 Born et al. Aug 2000
6099948 Paver, Jr. Aug 2000
6102379 Ponslet et al. Aug 2000
6102473 Steininger et al. Aug 2000
6103341 Barz et al. Aug 2000
6103784 Hilborn et al. Aug 2000
6110982 Russick et al. Aug 2000
6129410 Kosaraju et al. Oct 2000
6131897 Barz et al. Oct 2000
6135542 Emmelmann et al. Oct 2000
6149227 Wycech Nov 2000
6150428 Hanley, IV et al. Nov 2000
6152260 Eipper et al. Nov 2000
6153709 Xiao et al. Nov 2000
6165588 Wycech Dec 2000
6168226 Wycech Jan 2001
Foreign Referenced Citations (65)
Number Date Country
2919046 May 1979 DE
G9011147.8 Sep 1990 DE
G9320333.0 Jun 1994 DE
82102135.9 Mar 1982 EP
90202150.0 Aug 1990 EP
91104546.6 Mar 1991 EP
94101343.5 Jan 1994 EP
95913082.4 Mar 1995 EP
0 893 331 A1 Jan 1999 EP
0 893 332 A1 Jan 1999 EP
0 891 918 A1 Jan 1999 EP
628863 Mar 1947 GB
8028960 Sep 1980 GB
8725028 Oct 1987 GB
64-69308 Mar 1989 JP
64-69309 Mar 1989 JP
2-206537 Aug 1990 JP
5-38992 Feb 1993 JP
PCTJP8800029 Jan 1988 WO
PCTAU9200468 Sep 1992 WO
PCTEP9500896 Mar 1995 WO
PCTUS9505749 May 1995 WO
PCTUS9611155 Jul 1996 WO
PCTUS9710693 Jun 1997 WO
PCTUS9719981 Nov 1997 WO
PCTUS9707644 Nov 1997 WO
PCTUS9808980 May 1998 WO
PCTUS9816461 Aug 1998 WO
PCTUS9817994 Sep 1998 WO
PCTUS9900770 Jan 1999 WO
PCTUS9900035 Jan 1999 WO
PCTUS9901855 Feb 1999 WO
PCTUS9901865 Feb 1999 WO
PCTUS9816461 Feb 1999 WO
PCTUS9904279 Mar 1999 WO
PCTUS9904263 Mar 1999 WO
PCTUS9911195 May 1999 WO
PCTUS9911194 May 1999 WO
PCTUS9911110 May 1999 WO
PCTUS9911109 May 1999 WO
PCTUS9910441 May 1999 WO
PCTCA9900424 May 1999 WO
PCTEP9903832 Jun 1999 WO
PCTUS9918820 Aug 1999 WO
PCTEP9906112 Aug 1999 WO
PCTEP9907143 Sep 1999 WO
PCTUS9918832 Sep 1999 WO
PCTUS9924795 Oct 1999 WO
PCTEP9909541 Dec 1999 WO
PCTEP9909732 Dec 1999 WO
PCTEP9909909 Dec 1999 WO
PCTUS9929987 Dec 1999 WO
PCTUS9929991 Dec 1999 WO
PCTUS9929986 Dec 1999 WO
PCTUS9929990 Dec 1999 WO
PCTUS9929992 Dec 1999 WO
PCTDE9904103 Dec 1999 WO
PCTEP9910151 Dec 1999 WO
PCTEP0000021 Jan 2000 WO
PCTUS0001644 Jan 2000 WO
PCTUS0000497 Jan 2000 WO
PCTUS0000010 Jan 2000 WO
PCTEP0001474 Feb 2000 WO
PCTUS0002631 Feb 2000 WO
PCTAT0000123 May 2000 WO
Non-Patent Literature Citations (11)
Entry
Co-pending Application Ser. No. 09/524,960, filed Mar. 14, 2000.
Co-pending Application Ser. No. 09/524,961, filed Mar. 14, 2000.
Co-pending Application Ser. No. 09/428,243; filed Oct. 27, 1999.
Co-pending Application Ser. No. 09/460,322; filed Dec. 10, 1999.
Co-pending Application Ser. No. 09/459,756; filed Dec. 10, 1999.
Co-pending Application Ser. No. 9/524,298; filed Mar. 14, 2000.
Co-pending Application Ser. No. 09/502,686; filed Feb. 11, 2000.
Co-pending Application Ser. No. 09/631,211; filed Aug. 3, 2000.
Co-pending Application Ser. No. 09/676,443; filed Sep. 29, 2000.
Co-pending Application Ser. No. 09/591,877; filed Jun. 12, 2000.
Co-pending Application Ser. No. 09/676,725; filed Sep. 29, 2000.
Continuations (1)
Number Date Country
Parent 09/268810 Mar 1999 US
Child 09/687398 US