Patent Application
20060115697
1. Field of the Invention
The present invention relates to a substance shutoff device for shutting down communication of an inflammable substance or oxidizer, and to a fuel cell provided with means for shutting down communication of a fuel or oxidizer.
2. Related Background Art
A conventional leak detection/shutoff device for an inflammable gas is constructed with: a detection mechanism for detecting gas leak; a control mechanism for giving an order to shut down the gas based on detection signals; and shutoff means for shutting down the gas. The mechanisms and the means are each driven by receiving energy such as electricity supplied from outside of the device.
Meanwhile, an example of an inflammable gas detection mechanism is a device employing a semiconductor device. Another example thereof is a device disclosed in Japanese Patent Application Laid-Open No. 2004-028749, in which a heat generated by combustion of an inflammable gas in a catalyst portion is converted into a voltage signal through a thermoelectric conversion effect, which is used as a detection signal. Further, as a gas shutoff means, there is often employed a method providing a valve which opens/closes by using electricity such as an electromagnetic valve, while a method is also employed which operates by heat. Examples of a gas shutoff method which operates by heat include: a fuse mechanism disclosed in Japanese Patent Application Laid-Open No. 2000-002354, in which a bearing member loses a bearing power by heat so that a valve member seats on a valve seat; and a device disclosed in Japanese Patent Application Laid-Open No. H07-071634, in which a substance which has softened to deform or has become a viscous fluid by heat fills in pores of a heat resistant porous material to close a gas flow path. Japanese Patent Application Laid-Open No. 2000-046219 discloses a pressure regulator provided with a thermal fuse. Further, an example of a device, which uses heat of catalytic combustion to operate shutoff means for a gas flow path, is a catalytic combustion hot air device disclosed in Japanese Patent Application Laid-Open No. H06-154022.
Meanwhile, as disclosed in Japanese Patent Application Laid-Open No. H08-315847, a fuel cell is provided with a fuel detection sensor as safety measures against fuel leak. The fuel cell is provided with: shutoff means for shutting down supply of a fuel to a fuel cell body when the fuel leaks; or discharge means for discharging the fuel out of a case. Further, examples of fuel detection means for a fuel cell which have been attempted include: a method involving fuel detection by deterioration in power generation characteristics of a fuel cell; and a method involving mixing of an odorant substance or a detecting substance such as helium in a gaseous fuel. In addition, an electromagnetic valve or the like is used for fuel shutoff means.
However, the conventional detection means for an inflammable substance involves conversion of a detection signal into an electrical signal for processing, and thus requires a processing circuit and a power source for driving the processing circuit. Further, the shutoff means employing an electromagnetic valve or the like requires a power source for driving the valve. Further, the shutoff means which operates by heat is mostly used for preventing heating of a system, and no shutoff means is directly connected to a detection mechanism for a leaking substance. Moreover, those systems each have problems in a complicated structure and a large size.
Hitherto, no fuel cell has utilized heat generation associated with catalytic combustion, for detection of fuel leak. Further, no fuel cell has utilized heat generation associated with catalytic combustion in a power generation cell of a fuel cell, for detection of fuel leak. Moreover, no fuel cell has utilized a shutoff means driven by heat for shutting down a leaking substance.
It is, therefore, an object of the present invention to provide an inflammable substance shutoff device with a simple structure which is driven without use of a drive energy such as electricity to shut down communication of an inflammable substance or oxidizer.
It is another object of the present invention to provide a fuel cell that can shut down communication of a fuel or an oxidizer without use of a drive energy such as electricity.
That is, according to one aspect of the present invention, there is provided a substance shutoff device for shutting down communication of at least one of an inflammable substance and an oxidizer when the inflammable substance and the oxidizer are brought into contact with each other, thereby preventing continuation of the contact between the inflammable substance and the oxidizer, the substance shutoff device comprising:
a catalyst portion provided in one of an inflammable substance flow path and an oxidizer flow path; and
a shutoff means which operates by heat generated accompanying a reaction between the inflammable substance and the oxidizer in the catalyst portion to shut down communication of at least one of the inflammable substance and the oxidizer.
Incidentally, the catalyst portion may be provided in the inflammable substance flow path or the oxidizer flow path, or may be provided in contact with a wall surface of one of the inflammable substance flow path and the oxidizer flow path. Further, the expression “prevent continuation of contact between an inflammable substance and an oxidizer” herein employed is intended to encompass not only a case where the contact is immediately cut off (or broken) but also a case where the contact is cut off (or broken) after a certain time lag.
According to another aspect of the present invention, there is provided a fuel cell comprising:
a cell portion comprising a fuel electrode for being supplied with a fuel, an oxidizer electrode for being supplied with an oxidizer, and an ionic conductor provided between the fuel electrode and the oxidizer electrode;
a fuel flow path;
an oxidizer flow path;
a detection means which generates heat by contact between the oxidizer and the fuel; and
a shutoff means provided in at least one of the fuel flow path and the oxidizer flow path and thermally coupled to the detection means, for shutting down communication of at least one of the fuel and the oxidizer based on the heat generation of the detection means.
The inflammable substance shutoff device of the present invention is capable of detecting and shutting down leak of an inflammable substance, and can therefore be utilized for a fuel cell, for example.
The present invention can provide an inflammable substance shutoff device capable of reducing use of a drive source such as electricity and shutting down leak of an inflammable substance or oxidizer with a simple construction.
Further, the present invention can provide a small and highly safe fuel cell provided with means for shutting down leak of a fuel or oxidizer.
The substance shutoff device of the present invention is for shutting down communication of at least one of an inflammable substance and an oxidizer when the inflammable substance and the oxidizer are brought into contact with each other, thereby preventing continuation of the contact between the inflammable substance and the oxidizer, and is characterized by having a catalyst portion provided in one of an inflammable substance flow path and an oxidizer flow path; and a shutoff means which operates by heat generated accompanying a reaction between the inflammable substance and the oxidizer in the catalyst portion to shut down communication of at least one of the inflammable substance and the oxidizer. In other words, the substance shutoff device of the present invention can be described as a substance shut off device for shutting down at least one of an inflammable substance and an oxidizer when the inflammable substance and the oxidizer are brought into contact with each other to thereby prevent (or cut off) the contact, which comprises a catalyst portion provided so as to be brought into contact with one of an inflammable substance and an oxidizer; and a shut off means which operates by heating through a reaction between the inflammable substance and the oxidizer in the catalyst portion to shut down communication of at least one of the inflammable substance and the oxidizer.
Further, the fuel cell of the present invention is characterized by having a cell portion comprising a fuel electrode for being supplied with a fuel, an oxidizer electrode for being supplied with an oxidizer, and an ionic conductor provided between the fuel electrode and the oxidizer electrode; a fuel flow path; an oxidizer flow path; a detection means which generates heat by contact between the oxidizer and the fuel; and a shutoff means provided in at least one of the fuel flow path and the oxidizer flow path and thermally coupled to the detection means, for shutting down communication of at least one of the fuel and the oxidizer based on the heat generation of the detection means.
Incidentally, the term “communication” as herein employed is intended to embrace any action of one of the inflammable substance (or fuel) and the oxidizer to come into contact with the other, including flow or movement.
Further, the term “oxidizer flow path” as herein employed is intended to embrace not only a space enclosed by a wall such as of rectangular parallelepiped shape but also an open space such as the atmosphere (ambient air) existing outside of the substance shutoff device or outside of the fuel cell.
Further, the shutoff means of the present invention operates without use of electrical signals.
The present invention has been accomplished on the assumption of use in a system provided with an inflammable substance flow path or a fuel flow path (alternatively, an inflammable substance flow path or a fuel flow path, and an oxidizer flow path) such that the inflammable substance or fuel and the oxidizer are not brought into contact with each other in a normal state.
In the present invention, it is preferred that the shutoff means for the fuel cell shuts down communication of an inflammable substance.
Further, in the present invention, it is preferred that the shutoff means for the fuel cell shuts down communication of a fuel.
Hereinafter, preferable embodiments of the shutoff device and fuel cell of the present invention will be enumerated.
It is preferred that the inflammable substance comprises hydrogen.
It is preferred that the oxidizer comprises oxygen.
It is preferred that the catalyst portion comprises platinum.
It is preferred that a heat transfer means is provided between the catalyst portion and the shutoff means.
It is preferred that the shutoff means comprises a material which softens, becomes a viscous fluid, or foams by heat.
It is preferred that the material which softens, becomes a viscous fluid, or foams by heat of the shutoff means is porous.
It is preferred that the shutoff means comprises a member comprising a first material which softens, becomes a viscous fluid, or foams by heat, and a surface of the member is covered with a second material having a composition different from the composition of the first material.
It is preferred that the shutoff means comprises a bimetal or a shape memory alloy. The term “bimetal” herein employed refers to a material made by bonding together two kinds of thin metal sheets having different coefficients of thermal expansion.
It is preferred that the shutoff means comprises a valve member which loses a bearing power by heat to seat on a valve seat.
It is preferred that the shutoff means comprises a porous member.
Hereinafter, preferable embodiments of the fuel cell of the present invention will be enumerated.
It is preferred that the substance shutoff device is provided in a catalyst layer of the fuel cell, and the shutoff means of the substance shutoff device comprises a material which softens, becomes a viscous fluid, or foams by heat.
It is preferred that the shutoff means comprises a material having electronic conductivity.
It is preferred that the shutoff means has a fuel cell catalyst on a surface thereof
It is preferred that the shutoff means comprises a material having ionic conductivity.
Substance shutoff devices in accordance with the present invention will be described with reference to the accompanying drawings.
The following substance shutoff devices are capable of shutting down communication of an inflammable substance or oxidizer.
The term “inflammable substance” herein employed refers to an inflammable gas such as hydrogen or hydrocarbon and an inflammable liquid such as methanol or ether.
Further, examples of the oxidizer include oxygen-containing substances such as air and oxygen.
In the present example, the description is made of the case where an inflammable gas (hydrogen) is used as the inflammable substance, and air is used as the oxidizer. However, the present invention is not limited to use of hydrogen and air.
In a case where a catalyst portion for leak detection is provided in an inflammable substance flow path of the substance shutoff device of the present invention, air diffusing and entering through a leak portion of the inflammable gas is mixed with the inflammable gas, thereby causing a catalytic combustion reaction in the catalyst portion. Alternatively, in a case where a catalyst portion for leak detection is provided outside of the inflammable substance flow path of the substance shutoff device of the present invention, the leaked inflammable gas is mixed with air, thereby causing a catalytic combustion reaction in the catalyst portion. Platinum may be used as a catalyst. In a case where a gas is used which contains a substance which poisons platinum such as carbon monoxide, a catalyst comprising ruthenium is effectively used. When a catalytic combustion reaction takes place, the catalyst portion generates heat. The heat generation causes the shutoff means (means for shutting down communication of a gas in this example, which is hereinafter referred to as “gas shutoff means”) to operate.
Examples of the gas shutoff means include the following.
First, as shown in
As a method of ensuring the gas flow, there may be included a method of forming the material which softens to deform or becomes a viscous fluid by heat into a porous member and providing the porous member in the flow path; or a method of partly providing the material which softens to deform or becomes a viscous fluid in the flow path, as shown in
Secondly, when a heat resistant porous material 112 is provided adjacent to a material 111 which softens to deform or becomes a viscous fluid by heat as shown in
Moreover, as shown in
Moreover, as shown in
Further, as shown in
By adopting the above-described construction, when an inflammable gas leaks, the gas shutoff means can be operated by using heat of a catalyst reaction to shut down the gas leakage.
Description is made of the case where the shutoff means of the present invention is provided in a fuel flow path or oxidizer flow path of a fuel cell.
First, a construction of a fuel cell is described by taking a polymer electrolyte fuel cell as an example.
Hereinafter, the description is made of the case where hydrogen is used as the fuel, and air is used as the oxidizer. However, the present invention is not limited to use of hydrogen and air.
The fuel and the oxidizer pass through diffusion layer 271 and 272 respectively, and the fuel reacts at a catalyst provided in the fuel electrode 213 while the oxidizer reacts at a catalyst provided in the oxidizer electrode 211. During the reaction, ions pass through a (polymer) electrolyte membrane 212, and electrons are guided to the electrode 25 and are taken out as electricity. In the reactions, the fuel and the oxidizer generally do not mix, and undergo reactions at the respective electrodes. However, if the electrolyte membrane breaks to cause fuel leak, the fuel and the oxidizer may cause a catalytic combustion reaction on the catalyst. Further, other components may break to cause leak of the fuel to the outside. The fuel cell generates heat during power generation, and generally reaches a temperature of about 40 to 80° C. in room-temperature environment. Meanwhile, heat generation caused by mixing of the fuel and the oxidizer for catalytic combustion may raise the temperature of the fuel cell to above 100° C. although depending on the mixing ratio of the fuel and the oxidizer.
In the present example, the substance shutoff means described in Example 1 is provided in at least one of a fuel flow path and an oxidizer flow path. Further, the substance shutoff means may be disposed at a valve or the like provided in a flow path, thus enabling the valve to be closed to thereby shut down the gas. As the detection means for detecting fuel leak, a member may be employed which generates heat by contact between the oxidizer and the fuel. For example, a catalyst portion which generates heat upon reaction between the oxidizer and the fuel may be used. In a case where the catalyst portion is used as the detection means, a catalyst layer of a fuel cell may be used as the catalyst portion, or another catalyst portion may be provided separately from the catalyst layer of the fuel cell. The detection means and the shutoff means are thermally bonded by bringing the detection means and the shutoff means into contact with each other, or using a heat transfer means which connects the detection means and the shutoff means. In a case where the catalyst portion for leak detection and the gas shutoff portion as the shutoff means are provided distant from each other, the catalyst portion and the gas shutoff portion are preferably connected through a member having a high thermal conductivity. When the fuel leaks, a mixture of the fuel and the oxidizer are brought into contact with a catalyst portion for leak detection to thereby cause a catalytic combustion reaction. The gas shutoff means operates by heat generation associated with the catalytic combustion reaction, thereby shutting down the fuel.
In a case where the shutoff means is provided in a fuel flow path, if the catalyst portion is provided outside of the fuel flow path, the shutoff means operates based on heat generation of the catalyst portion by a reaction between the fuel leaked to the outside of the fuel flow path and the oxidizer to thereby shut down communication of the fuel. Alternatively, if the catalyst portion is provided in the fuel flow path, the shutoff means operates based on heat generation of the catalyst portion by a reaction between the fuel and the oxidizer entering into the fuel flow path to thereby shut down communication of the fuel. In this way, continuation of fuel leak to the outside of the fuel flow path can be prevented. Meanwhile, in a case where the shutoff means is provided in an oxidizer flow path, when fuel leaks from the fuel flow path and enters into the oxidizer flow path, the shutoff means operates based on heat generation of the catalyst portion by a reaction between the leaked fuel and the oxidizer, to thereby shut down communication of the oxidizer. In this way, the oxidizer flow path is shut down, to thereby prevent continuation of inflow of the fuel into the oxidizer flow path.
Further, there are sometimes cases where in order to improve power generation characteristics of a fuel cell, an oxidizer gas is partly mixed into a fuel gas to operate the fuel cell. However, because the heat of catalytic combustion generated by fuel leak causes an operation at higher temperatures than that for a normal operation, an operation involving fuel leak and a normal operation can be detected distinguishably, so that the present invention is effective to this case as well.
Description is made of the case where an inflammable substance shutoff device of the present invention is provided in a diffusion layer of a fuel cell.
As shown in
In the present example, as shown in
The material which softens to deform or becomes a viscous fluid by heat may be subjected to surface coating, to thereby impart conductivity or electrical insulating property to the surface thereof. Further, the surface coating allows control of wettability. As a catalyst for detecting gas leak, a catalyst layer of a fuel cell may be used, or another catalyst layer may be provided separately from the catalyst layer of the fuel cell. If fuel leakage occurs due to breakage of an electrolyte membrane or the like, air and the fuel may react at a catalyst portion for detecting fuel leak, to thereby cause catalytic combustion. A diffusion member made of the low melting point material melts by heat generation associated with the catalytic combustion to clog the diffusion layer. This realizes at least one of shut down of the leakage of the fuel and prevention of contact of a mixed gas of the leaked fuel and ambient air with the fuel cell catalyst.
Description is made of the case where an inflammable substance shutoff device of the present invention is provided in a catalyst layer of a fuel cell.
As shown in
In the present example, catalyst fine particles are mixed with a member made of a material which softens to deform or becomes a viscous fluid by heat, to thereby form a catalyst layer. If the electrolyte membrane breaks to cause fuel leakage, a catalytic combustion reaction will take place at the fuel cell catalyst. This raises the temperature of the catalyst layer, so that the above member softens or becomes a viscous fluid to cover the catalyst layer. Thus, the catalytic combustion will stop.
The material which softens to deform or becomes a viscous fluid by heat may have at least one of electronic conductivity and ionic conductivity, to thereby further improve the catalytic performance. In a case where the material which softens to deform or becomes a viscous fluid by heat has electronic conductivity, there may be used as the material an elemental metal such as tin, indium, selenium, lead, or bismuth, or an alloy containing these. Further, there may also be used a material prepared by mixing a conductive substance into a thermoplastic resin or a material prepared by coating a surface of a thermoplastic resin with a conductive layer. The material may be subjected to coating with a corrosion resistant material for preventing corrosion. Examples of the corrosion resistant material include carbon; noble metals such as gold, silver, and platinum; ceramics; and organic materials. In particular, in a case where platinum is used as a coating material, the resultant may also be used as a catalyst for leak detection.
In a case where the material which softens or becomes a viscous fluid by heat has electronic conductivity on the surface as described above, the material may be used as a catalyst carrier 51 as shown in
This application claims priority from Japanese Patent Application No. 2004-194790 filed Jun. 30, 2004, which is hereby incorporated by reference herein.
| Number | Date | Country | Kind |
|---|---|---|---|
| 2004-194790 | Jun 2004 | JP | national |
This application is a continuation of International Application No. PCT/JP2005/012167 filed Jun. 24, 2005, which claims the benefit of Japanese Patent Application No. 2004-194790 filed Jun. 30, 2004.
| Number | Date | Country | |
|---|---|---|---|
| Parent | PCT/JP05/12167 | Jun 2005 | US |
| Child | 11329028 | Jan 2006 | US |
