TREA

Substituted 1,2,5-oxadiazole compounds and their use as herbicides

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Information

  • Patent Application
  • 20160280696
  • Publication Number
    20160280696
  • Date Filed
    October 07, 2014
    9 years ago
  • Date Published
    September 29, 2016
    7 years ago
Information
Abstract
The present invention relates to a compound of formula I, wherein the variables are defined as in the specification. The invention further refers to a composition comprising such compound and to the use thereof for controlling unwanted vegetation.
Description

The present invention relates to substituted 1,2,5-oxadiazole compounds and the N-oxides and salts thereof and to compositions comprising the same. The invention also relates to the use of the 1,2,5-oxadiazole compounds or of the compositions comprising such compounds for controlling unwanted vegetation. Furthermore, the invention relates to methods of applying such compounds.


For the purposes of controlling unwanted vegetation, especially in crops, there is an ongoing need for new herbicides which have high activities and selectivities together with a substantial lack of toxicity for humans and animals.


EP 0 173 657 A1 describes N-(1,2,5-oxadiazol-3-yl) carboxamides, herbicidal compositions comprising them and the use of such compositions for controlling the growth of weeds. WO 2011/035874 describes N-(1,2,5-oxadiazol-3-yl) benzamides carrying 3 substituents in the 2-, 3- and 4-positions of the phenyl ring and their use as herbicides.


The N-(1,2,5-oxadiazol-3-yl) carboxamides of the prior art often suffer form insufficient herbicidal activity in particular at low application rates and/or unsatisfactory selectivity resulting in a low compatibility with crop plants.


Accordingly, it is an object of the present invention to provide further 1,2,5-oxadiazole compounds having a strong herbicidal activity, in particular even at low application rates, a sufficiently low toxicity for humans and animals and/or a high compatibility with crop plants. The 1,2,5-oxadiazole compounds should also show a broad activity spectrum against a large number of different unwanted plants.


These and further objectives are achieved by the compounds of formula I defined below and their N-oxides and also their agriculturally suitable salts.


It has been found that the above objectives can be achieved by substituted 1,2,5-oxadiazole compounds of the general formula I, as defined below, including their N-oxides and their salts, in particular their agriculturally suitable salts.


Therefore, in a first aspect the present invention relates to compounds of formula I,




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an N-oxide or an agriculturally suitable salt thereof,


wherein

  • R1 is selected from the group consisting of halogen, C1-C8-alkyl, C1-C8-haloalkyl, nitro, C1-C4-alkoxy-C1-C4-alkyl, cyano-Z1, C2-C8-alkenyl, C2-C8-alkynyl, C3-C10-cycloalkyl-Z1, C2-C8-haloalkenyl, C3-C8-haloalkynyl, C1-C8-alkoxy, C1-C4-alkoxy-C1-C4-alkoxy-Z1, C1-C4-alkylthio-C1-C4-alkyl, C1-C4-alkylthio-C1-C4-alkylthio-Z1, C2-C6-alkenyloxy, C2-C6-alkynyloxy, C1-C6-haloalkoxy, C1-C4-haloalkoxy-C1-C4-alkyl, C1-C4-haloalkoxy-C1-C4-alkoxy-Z1, R1b—S(O)k—Z1, phenoxy-Z1 and heterocyclyloxy-Z1, where heterocyclyloxy is an oxygen bound 5- or 6-membered monocyclic or 8-, 9- or 10-membered bicyclic saturated, partially unsaturated or aromatic heterocycle, which contains 1, 2, 3 or 4 heteroatoms as ring members, which are selected from the group consisting of O, N and S, where the cyclic groups in phenoxy and heterocyclyloxy are unsubstituted or substituted by 1, 2, 3 or 4 groups R11, which are identical or different;
  • X is N or CR2;
  • R2 is selected from the group consisting of hydrogen, halogen, hydroxy-Z2, nitro, C1-C4-nitroalkyl, cyano, C1-C4-cyanoalkyl, C1-C6-alkyl, C2-C8-alkenyl, C2-C8-alkynyl, C3-C10-cycloalkyl-Z2, C3-C10-cycloalkoxy-Z2, where the C3-C10-cycloalkyl groups in the two aforementioned radicals are unsubstituted or partially or completely halogenated, C1-C8-haloalkyl, C2-C8-haloalkenyl, C3-C8-haloalkynyl, C1-C8-alkoxy-Z2, C1-C8-haloalkoxy-Z2, C3-C10-cycloalkyl-C1-C2-alkoxy, C1-C4-alkoxy-C1-C4-alkoxy-Z2, C1-C4-alkylthio-C1-C4-alkylthio-Z2, C2-C8-alkenyloxy-Z2, C2-C8-alkynyloxy-Z2, C2-C8-haloalkenyloxy-Z2, C3-C8-haloalkynyloxy-Z2, C1-C4-haloalkoxy-C1-C4-alkoxy-Z2, (tri-C1-C4-alkyl)silyl-Z2, R2b—S(O)k—Z2, R2c—C(═O)—Z2, R2dO—C(═O)—Z2, R2dO—N═CH—Z2, R2dO—N═CC1-C4-alkyl-Z2, R2dO—N═CC1-C4-haloalkyl-Z2, R2cR2dC═N—O—C1-C4-alkyl, R2eR2fN—C(═O)—Z2, R2gR2hN—Z2, phenyl-Z2a, hetero-cyclyl-Z2a, where heterocyclyl is a 3-, 4-, 5- or 6-membered monocyclic or 8-, 9- or 10-membered bicyclic saturated, partially unsaturated or aromatic heterocycle, which contains 1, 2, 3 or 4 heteroatoms as ring members, which are selected from the group consisting of O, N and S, where the cyclic groups in phenyl-Z2a and heterocyclyl-Z2a are unsubstituted or substituted by 1, 2, 3 or 4 groups R21, which are identical or different, rhodano, C3-C6-cycloalkenyl, OC(O)OR22, OC(O)N(R22)2, ONC(R23)2, OSO2R25, SO2OR22, SO2N(R22)2, N(R22)C(O)OR22, N(R22)C(O)N(R22)2, C(O)N(R22)OR22, P(O)(O—C1-C4-alkyl)2, C1-C6-alkyl-OC(O)R22, C1-C6-alkyl-OSO2R25, C1-C6-alkyl-SO2OR22, C1-C6-alkyl-SO2N(R22)2, C1-C6-alkyl-P(O)(O—C1-C4-alkyl)2,




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  • R3 is selected from the group consisting of hydrogen, halogen, hydroxy-Z2, nitro, C1-C4-nitroalkyl, cyano, C1-C4-cyanoalkyl, C1-C6-alkyl, C2-C8-alkenyl, C2-C8-alkynyl, C3-C10-cycloalkyl-Z2, C3-C10-cycloalkoxy-Z2, where the C3-C10-cycloalkyl groups in the two aforementioned radicals are unsubstituted or partially or completely halogenated, C1-C8-haloalkyl, C2-C8-haloalkenyl, C3-C8-haloalkynyl, C1-C8-alkoxy-Z2, C1-C8-haloalkoxy-Z2, C3-C10-cycloalkyl-C1-C2-alkoxy, C1-C4-alkoxy-C1-C4-alkoxy-Z2, C1-C4-alkylthio-C1-C4-alkylthio-Z2, C2-C8-alkenyloxy-Z2, C2-C8-alkynyloxy-Z2, C2-C8-haloalkenyloxy-Z2, C3-C8-haloalkynyloxy-Z2, C1-C4-haloalkoxy-C1-C4-alkoxy-Z2, (tri-C1-C4-alkyl)silyl-Z2, R2b—S(O)k—Z2, R2c—C(═O)—Z2, R2dO—C(═O)—Z2, R2dO—N═CH—Z2, R2cR2dC═N—O—C1-C4-alkyl, R2eR2fN—C(═O)—Z2, R2gR2hN—Z2, phenyl-Z2a, heterocyclyl-Z2a, where heterocyclyl is a 3-, 4-, 5- or 6-membered monocyclic or 8-, 9- or 10-membered bicyclic saturated, partially unsaturated or aromatic heterocycle, which contains 1, 2, 3 or 4 heteroatoms as ring members, which are selected from the group consisting of O, N and S, where the cyclic groups in phenyl-Z2a and heterocyclyl-Z2a are unsubstituted or substituted by 1, 2, 3 or 4 groups R21, which are identical or different,

  •  rhodano, C3-C6-cycloalkenyl, C3-C6-halocycloalkenyl, C3-C6-cycloalkenyl-C1-C6-alkyl, C3-C6-halocycloalkenyl-C1-C6-alkyl, OC(O)R22, OC(O)OR25, OC(O)N(R22)2, OSO2R25, SO2OR22, SO2N(R22)2, SO2N(R22)C(O)R22, SO2N(R22)C(O)OR25, SO2N(R22)C(O)N(R22)2, N(R22)C(O)OR25, N(R22)C(O)N(R22)2, N(R22)S(O)2OR22, N(R22)S(O)2N(R22)2, C(O)N(R22)OR22, C(O)N(R22)N(R22)2, C(O)N(R22)C(O)R22, C(O)N(R22)C(O)OR25, C(O)N(R22)C(O)N(R22)2, C(O)N(R22)SO2R25, C(O)N(R22)SO2OR22, C(O)N(R22)SO2N(R22)2, P(O)(OH)2, P(O)(O—C1-C4-alkyl)2, C1-C6-alkyl-OC(O)R22, C1-C6-alkyl-OC(O)OR25, C1-C6-alkyl-OC(O)N(R22)2, C1-C6-alkyl-OSO2R25, C1-C6-alkyl-SO2OR22, C1-C6-alkyl-SO2N(R22)2, C1-C6-alkyl-SO2N(R22)C(O)R22, C1-C6-alkyl-SO2N(R22)C(O)OR25, C1-C6-alkyl-SO2N(R22)C(O)N(R22)2, C1-C6-alkyl-N(R22)C(O)OR25, C1-C6-alkyl-N(R22)C(O)N(R22)2, C1-C6-alkyl-N(R22)S(O)2OR22, C1-C6-alkyl-N(R22)S(O)2N(R22)2, C1-C6-alkyl-C(O)N(R22)OR22, C1-C6-alkyl-C(O)N(R22)N(R22)2, C1-C6-alkyl-C(O)N(R22)C(O)R22, C1-C6-alkyl-C(O)N(R22)C(O)OR25, C1-C6-alkyl-C(O)N(R22)C(O)N(R22)2, C1-C6-alkyl-C(O)N(R22)SO2R25, C1-C6-alkyl-C(O)N(R22)SO2OR22, C1-C6-alkyl-C(O)N(R22)SO2N(R22)2, C1-C6-alkyl-P(O)(OH)2 and C1-C6-alkyl-P(O)(O—C1-C4-alkyl)2;

  • R4 is selected from the group consisting of hydrogen, halogen, C1-C8-alkyl, cyano-Z1, nitro, C3-C7-cycloalkyl, C3-C7-cycloalkyl-C1-C4-alkyl, where the C3-C7-cycloalkyl groups in the two aforementioned radicals are unsubstituted or partially or completely halogenated, C2-C8-alkenyl, C2-C8-alkynyl, C1-C8-haloalkyl, C1-C3-alkylamino, C1-C3-dialkylamino, C1-C3-alkylamino-S(O)k, C1-C3-alkylcarbonyl, C1-C8-alkoxy, C1-C4-alkoxy-C1-C4-alkyl, C1-C4-alkoxy-C1-C4-alkoxy-Z1, C1-C4-alkylthio-C1-C4-alkyl, C1-C4-alkylthio-C1-C4-alkylthio-Z1, C2-C6-alkenyloxy, C2-C6-alkynyloxy, C1-C6-haloalkoxy, C1-C4-haloalkoxy-C1-C4-alkyl, C1-C4-haloalkoxy-C1-C4-alkoxy-Z1, R1b—S(O)k—Z1, phenoxy-Z1 and heterocyclyloxy-Z1, where heterocyclyloxy is an oxygen bound 5- or 6-membered monocyclic or 8-, 9- or 10-membered bicyclic saturated, partially unsaturated or aromatic heterocycle, which contains 1, 2, 3 or 4 heteroatoms as ring members, which are selected from the group consisting of O, N and S, where the cyclic groups in phenoxy and heterocyclyloxy are unsubstituted or substituted by 1, 2, 3 or 4 groups R11, which are identical or different;

  • R5 is selected from the group consisting of halogen, cyano-Z1, nitro, C1-C8-alkyl, C3-C7-cycloalkyl, C3-C7-cycloalkyl-C1-C4-alkyl, where the C3-C7-cycloalkyl groups in the two aforementioned radicals are unsubstituted or partially or completely halogenated, C2-C8-alkenyl, C2-C8-alkynyl, C1-C8-haloalkyl, C1-C3-alkylamino, C1-C3-dialkylamino, C1-C3-alkylamino-S(O)k, C1-C3-alkylcarbonyl, C1-C8-alkoxy, C1-C4-alkoxy-C1-C4-alkyl, C1-C4-alkoxy-C1-C4-alkoxy-Z1, C1-C4-alkylthio-C1-C4-alkyl, C1-C4-alkylthio-C1-C4-alkylthio-Z1, C2-C6-alkenyloxy, C2-C6-alkynyloxy, C1-C6-haloalkoxy, C1-C4-haloalkoxy-C1-C4-alkyl, C1-C4-haloalkoxy-C1-C4-alkoxy-Z, R1b—S(O)k—Z1, phenoxy-Z1 and heterocyclyloxy-Z, where heterocyclyloxy is an oxygen bound 5- or 6-membered monocyclic or 8-, 9- or 10-membered bicyclic saturated, partially unsaturated or aromatic heterocycle, which contains 1, 2, 3 or 4 heteroatoms as ring members, which are selected from the group consisting of O, N and S, where the cyclic groups in phenoxy and heterocyclyloxy are unsubstituted or substituted by 1, 2, 3 or 4 groups R11, which are identical or different;

  • R6 is selected from the group consisting of cyano, nitro, hydroxy, amino, C1-C6-alkyl, C1-C6-cyano-alkyl, C3-C7-cycloalkyl, C3-C7-cycloalkyl-C1-C4-alkyl, where the C3-C7-cycloalkyl groups in the two aforementioned radicals are unsubstituted or partially or completely halogenated, C1-C6-haloalkyl, C1-C6-alkoxy, C1-C6-alkylcarbonyl, C1-C6-alkyaminocarbonyl, C1-C6-dialkyl-aminocarbonyl, C1-C6-alkyamino, C1-C6-dialkyl-amino, C2-C6-alkenyl, C2-C6-haloalkenyl, C2-C6-alkynyl, C2-C6-haloalkynyl, C1-C4-alkoxy-C1-C4-alkyl, C1-C4-haloalkoxy-C1-C4-alkyl, RbRbN—S(O)n—Z, RbO—S(O)n—Z, Rb—S(O)n—Z, RcRcN—C1-C3-alkyl-S(O)n—C1- C3-alkyl, Rc—C(═O)—C1-C3-alkyl, Rd—C(═O)O—C1-C3-alkyl, Rd—O—C(═O)O—C1-C3-alkyl, RdO—C(═O)—C1-C3-alkyl, ReRfN—C(═O)—C1-C3-alkyl, Rc—C(═O)ReN—C1-C3-alkyl, Rb—S(O)n—ReN—C1-C3-alkyl, RcRcN—C1-C3-alkyl, phenyl-Z and heterocyclyl-Z, where heterocyclyl is a 5- or 6-membered monocyclic or 8-, 9- or 10-membered bicyclic saturated, partially unsaturated or aromatic heterocycle, which contains 1, 2, 3 or 4 heteroatoms as ring members, which are selected from the group consisting of O, N and S, where phenyl and heterocyclyl are unsubstituted or substituted by 1, 2, 3 or 4 groups R′, which are identical or different;

  • R7 is selected from the group consisting of hydrogen, cyano, nitro, halogen, C1-C6-alkyl, C3-C7-cycloalkyl, C3-C7-cycloalkyl-C1-C4-alkyl, where the C3-C7-cycloalkyl groups in the two aforementioned radicals are unsubstituted or partially or completely halogenated, C1-C6-haloalkyl, C2-C6-alkenyl, C2-C6-haloalkenyl, C2-C6-alkynyl, C2-C6-haloalkynyl, C1-C4-alkoxy-C1-C4-alkyl, C1-C4-haloalkoxy-C1-C4-alkyl, O—Ra, Z—S(O)n—Rb, Z—C(═O)—Rc, Z—C(═O)—ORd, Z—C(═O)—NReRf, Z—NRgRh, Z-phenyl and Z-heterocyclyl, where heterocyclyl is a 5- or 6-membered monocyclic or 8-, 9- or 10-membered bicyclic saturated, partially unsaturated or aromatic heterocycle, which contains 1, 2, 3 or 4 heteroatoms as ring members, which are selected from the group consisting of O, N and S, where phenyl and heterocyclyl are unsubstituted or substituted by 1, 2, 3 or 4 groups R′, which are identical or different;

  • R′, R11, R21 independently of each other are selected from the group consisting of halogen, NO2, ON, C1-C6-alkyl, C3-C7-cycloalkyl, C3-C7-halocycloalkyl, C1-C6-haloalkyl, C2-C6-alkenyl, C2-C6-haloalkenyl, C2-C6-alkynyl, C2-C6-haloalkynyl, C1-C6-alkoxy, C1-C4-alkoxy-C1-C4-alkyl, C1-C4-alkylthio-C1-C4-alkyl, C1-C4-haloalkoxy-C1-C4-alkyl, C1-C4-alkoxy-C1-C4-alkoxy, C3-C7-cycloalkoxy and C1-C6-haloalkyloxy, or two vicinal radicals R′, R11 or R21 together may form a group ═O;

  • Z, Z1, Z2 independently of each other are selected from the group consisting of a covalent bond and C1-C4-alkanediyl;

  • Z2a is s Z2a elected from the group consisting of a covalent bond, C1-C4-alkanediyl, O—C1-C4-alkanediyl, C1-C4-alkanediyl-O and

  •  C1-C4-alkanediyl-O—C1-C4-alkanediyl;

  • Ra is selected from the group consisting of hydrogen, C1-C6-alkyl, C3-C7-cycloalkyl, C3-C7-cycloalkyl-C1-C4-alkyl, where the C3-C7-cycloalkyl groups in the two aforementioned radicals are unsubstituted or partially or completely halogenated, C1-C6-haloalkyl, C2-C6-alkenyl, C2-C6-haloalkenyl, C2-C6-alkynyl, C2-C6-haloalkynyl, C1-C4-alkoxy-C1-C4-alkyl, phenyl and benzyl, where phenyl and benzyl are unsubstituted or substituted by 1, 2, 3 or 4 groups, which are identical or different and selected from the group consisting of halogen, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy and C1-C4-haloalkoxy;

  • Rb, R1b, R2b independently of each other are selected from the group consisting of C1-C6-alkyl, C3-C7-cycloalkyl, C1-C6-haloalkyl, C2-C6-alkenyl, C2-C6-haloalkenyl, C2-C6-alkynyl, C2-C6-haloalkynyl, phenyl and heterocyclyl, where heterocyclyl is a 5- or 6-membered monocyclic saturated, partially unsaturated or aromatic heterocycle, which contains 1, 2, 3 or 4 heteroatoms as ring members, which are selected from the group consisting of O, N and S, where phenyl and heterocyclyl are unsubstituted or substituted by 1, 2, 3 or 4 groups, which are identical or different and selected from the group consisting of halogen, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy and C1-C4-haloalkoxy;

  • Rc, R2c independently of each other are selected from the group consisting of hydrogen, C1-C6-alkyl, C3-C7-cycloalkyl, C3-C7-cycloalkyl-C1-C4-alkyl, where the C3-C7-cycloalkyl groups in the two aforementioned radicals are unsubstituted or partially or completely halogenated, C1-C6-haloalkyl, C2-C6-alkenyl, C2-C6-haloalkenyl, C2-C6-alkynyl, C2-C6-haloalkynyl, C1-C4-alkoxy-C1-C4-alkyl, phenyl, benzyl and heterocyclyl, where heterocyclyl is a 5- or 6-membered monocyclic saturated, partially unsaturated or aromatic heterocycle, which contains 1, 2, 3 or 4 heteroatoms as ring members, which are selected from the group consisting of O, N and S, where phenyl, benzyl and heterocyclyl are unsubstituted or substituted by 1, 2, 3 or 4 groups, which are identical or different and selected from the group consisting of halogen, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy and C1-C4-haloalkoxy;

  • Rd, R2d independently of each other are selected from the group consisting of C1-C6-alkyl, C3-C7-cycloalkyl, C3-C7-cycloalkyl-C1-C4-alkyl, where the C3-C7-cycloalkyl groups in the two aforementioned radicals are unsubstituted or partially or completely halogenated, C1-C6-haloalkyl, C2-C6-alkenyl, C2-C6-haloalkenyl, C2-C6-alkynyl, C2-C6-haloalkynyl, C1-C4-alkoxy-C1-C4-alkyl, phenyl and benzyl, where phenyl and benzyl are unsubstituted or substituted by 1, 2, 3 or 4 groups, which are identical or different and selected from the group consisting of halogen, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy and C1-C4-haloalkoxy;

  • Re, Rf independently of each other are selected from the group consisting of hydrogen, C1-C6-alkyl, C3-C7-cycloalkyl, C3-C7-cycloalkyl-C1-C4-alkyl, where the C3-C7-cycloalkyl groups in the two aforementioned radicals are unsubstituted or partially or completely halogenated, C1-C6-haloalkyl, C2-C6-alkenyl, C2-C6-haloalkenyl, C2-C6-alkynyl, C2-C6-haloalkynyl, C1-C4-alkoxy-C1-C4-alkyl, phenyl and benzyl, where phenyl and benzyl are unsubstituted or substituted by 1, 2, 3 or 4 groups, which are identical or different and selected from the group consisting of halogen, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy and C1-C4-haloalkoxy, or

  • Re, Rf together with the nitrogen atom, to which they are bound may form a 5-, 6 or 7-membered, saturated or unsaturated N-bound heterocyclic radical, which may carry as a ring member a further heteroatom selected from O, S and N and which is unsubstituted or may carry 1, 2, 3 or 4 groups, which are identical or different and selected from the group consisting of halogen, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy and C1-C4-haloalkoxy;

  • R2e, R2f independently of each other have the meanings given for Re, Rf;

  • Rg is selected from the group consisting of hydrogen, C1-C6-alkyl, C3-C7-cycloalkyl, C3-C7-cycloalkyl-C1-C4-alkyl, where the C3-C7-cycloalkyl groups in the two aforementioned radicals are unsubstituted or partially or completely halogenated, C1-C6-haloalkyl, C2-C6-alkenyl, C2-C6-haloalkenyl, C2-C6-alkynyl, C2-C6-haloalkynyl, C1-C4-alkoxy-C1-C4-alkyl, C1-C4-alkylsulfonyl, C1-C4-alkylcarbonyl, phenyl and benzyl, where phenyl and benzyl are unsubstituted or substituted by 1, 2, 3 or 4 groups, which are identical or different and selected from the group consisting of halogen, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy and C1-C4-haloalkoxy;

  • Rh is selected from the group consisting of hydrogen, C1-C6-alkyl, C3-C7-cycloalkyl, C3-C7-cycloalkyl-C1-C4-alkyl, where the C3-C7-cycloalkyl groups in the two aforementioned radicals are unsubstituted or partially or completely halogenated, C1-C6-haloalkyl, C2-C6-alkenyl, C2-C6-haloalkenyl, C2-C6-alkynyl, C2-C6-haloalkynyl, C1-C4-alkoxy-C1-C4-alkyl, C1-C4-alkylsulfonyl, C1-C4-alkylcarbonyl, a radical C(═O)—Rk, phenyl and benzyl, where phenyl and benzyl are unsubstituted or substituted by 1, 2, 3 or 4 groups, which are identical or different and selected from the group consisting of halogen, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy and C1-C4-haloalkoxy, or

  • Rg, Rh together with the nitrogen atom, to which they are bound may form a 5-, 6 or 7-membered, saturated or unsaturated N-bound heterocyclic radical, which may carry as a ring member a further heteroatom selected from O, S and N and which is unsubstituted or may carry 1, 2, 3 or 4 groups, which are identical or different and selected from the group consisting of ═O, halogen, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy and C1-C4-haloalkoxy;

  • R2g, R2h independently of each other have the meanings given for Rg, Rh;

  • Rk has the meanings given for Rc;

  • R22 is selected from the group consisting of hydrogen, C1-C6-alkyl, C1-C6-haloalkyl, C2-C6-alkenyl, C2-C6-haloalkenyl, C2-C6-alkynyl, C3-C6-haloalkynyl, C3-C6-cycloalkyl, C3-C6-cycloalkenyl, C3-C6-halocycloalkyl, C3-C6-cycloalkyl-C1-C6-alkyl, C1-C6-alkoxy-C1-C6-alkyl, C3-C6-cycloalkyl-C1-C6-alkoxy-C1-C6-alkyl,

  •  phenyl, phenyl-C1-C6-alkyl, heteroaryl, heteroaryl-C1-C6-alkyl, heterocyclyl, heterocyclyl-C1-C6-alkyl, phenyl-O—C1-C6-alkyl, heteroaryl-O—C1-C6-alkyl, heterocyclyl-O—C1-C6-alkyl, phenyl-N(R23)—C1-C6-alkyl, heteroaryl-N(R23)—C1-C6-alkyl, heterocyclyl-N(R23)—C1-C6-alkyl, phenyl-S(O)n—C1-C6-alkyl, heteroaryl-S(O)n—C1-C6-alkyl, heterocyclyl-S(O)n—C1-C6-alkyl, where the 15 aforementioned radicals are substituted by s residues selected from the group consisting of nitro, halogen, cyano, rhodano, C1-C6-alkyl, C1-C6-haloalkyl, C3-C6-cycloalkyl, C(O)OR23, C(O)N(R23)2, OR23, N(R23)2, S(O)nR24, S(O)2OR23, S(O)2N(R23)2 and R23O—C1-C6-alkyl, and where heterocyclyl bears 0, 1 or 2 oxo groups;

  • R23 is selected from the group consisting of hydrogen, C1-C6-alkyl, C1-C6-haloalkyl, C2-C6-alkenyl, C2-C6-alkynyl, C3-C6-cycloalkyl, C3-C6-cycloalkyl-C1-C6-alkyl and phenyl;

  • R24 is selected from the group consisting of C1-C6-alkyl, C1-C6-haloalkyl, C2-C6-alkenyl, C2-C6-alkynyl, C3-C6-cycloalkyl, C3-C6-cycloalkyl-C1-C6-alkyl and phenyl;

  • R25 is selected from the group consisting of C1-C6-alkyl, C1-C6-haloalkyl, C2-C6-alkenyl, C2-C6-haloalkenyl, C2-C6-alkynyl, C3-C6-haloalkynyl, C3-C6-cycloalkyl, C3-C6-cycloalkenyl, C3-C6-halocycloalkyl, C3-C6-cycloalkyl-C1-C6-alkyl, C1-C6-alkoxy-C1-C6-alkyl, C3-C6-cycloalkyl-C1-C6-alkoxy-C1-C6-alkyl,

  •  phenyl, phenyl-C1-C6-alkyl, heteroaryl, heteroaryl-C1-C6-alkyl, heterocyclyl, heterocyclyl-C1-C6-alkyl, phenyl-O—C1-C6-alkyl, heteroaryl-O—C1-C6-alkyl, heterocyclyl-O—C1-C6-alkyl, phenyl-N(R23)—C1-C6-alkyl, heteroaryl-N(R23)—C1-C6-alkyl, heterocyclyl-N(R23)—C1-C6-alkyl, phenyl-S(O)n—C1-C6-alkyl, heteroaryl-S(O)n—C1-C6-alkyl, heterocyclyl-S(O)n—C1-C6-alkyl, where the 15 aforementioned radicals are substituted by s residues selected from the group consisting of nitro, halogen, cyano, rhodano, C1-C6-alkyl, C1-C6-haloalkyl, C3-C6-cycloalkyl, C(O)OR23, C(O)N(R23)2, OR23, N(R23)2, S(O)nR24, S(O)2OR23, S(O)2N(R23)2 and R23O—C1-C6-alkyl, and where heterocyclyl bears 0, 1 or 2 oxo groups;

  • R26 is C1-C6-alkyl or C1-C4-alkoxy-C1-C4-alkyl;

  • R27 is selected from the group consisting of hydrogen, cyano and C1-C4-haloalkylcarbonyl;

  • R28, R29 independently of each other are C1-C6-alkyl, or

  • R28, R29 together with the sulfur atom, to which they are bound may form a 5- or 6-membered saturated ring, which may carry as a ring member 1 oxygen atom;



k is 0, 1 or 2;


n is 0, 1 or 2;


s is 0, 1, 2 or 3;


t is 0 or 1.


The compounds of the present invention, i.e. the compounds of formula I, their N-oxides, or their salts are particularly useful for controlling unwanted vegetation. Therefore, the invention also relates to the use of a compound of the present invention, an N-oxide or a salt thereof or of a composition comprising at least one compound of the invention, an N-oxide or an agriculturally suitable salt thereof for combating or controlling unwanted vegetation.


The invention also relates to a composition comprising at least one compound according to the invention, including an N-oxide or a salt thereof, and at least one auxiliary. In particular, the invention relates to an agricultural composition comprising at least one compound according to the invention including an N-oxide or an agriculturally suitable salt thereof, and at least one auxiliary customary for crop protection formulations.


The present invention also relates to a method for combating or controlling unwanted vegetation, which method comprises allowing a herbicidally effective amount of at least one compound according to the invention, including an N-oxide or a salt thereof, to act on unwanted plants, their seed and/or their habitat.


Depending on the substitution pattern, the compounds of formula I may have one or more centers of chirality, in which case they are present as mixtures of enantiomers or diastereomers. The invention provides both the pure enantiomers or pure diastereomers of the compounds of formula I, and their mixtures and the use according to the invention of the pure enantiomers or pure diastereomers of the compound of formula I or its mixtures. Suitable compounds of formula I also include all possible geometrical stereoisomers (cis/trans isomers) and mixtures thereof. Cis/trans isomers may be present with respect to an alkene, carbon-nitrogen double-bond, nitrogen-sulfur double bond or amide group. The term “stereoisomer(s)” encompasses both optical isomers, such as enantiomers or diastereomers, the latter existing due to more than one center of chirality in the molecule, as well as geometrical isomers (cis/trans isomers).


Depending on the substitution pattern, the compounds of formula I may be present in the form of their tautomers. Hence the invention also relates to the tautomers of the formula I and the stereoisomers, salts and N-oxides of said tautomers.


The term “N-oxide” includes any compound of the present invention which has at least one tertiary nitrogen atom that is oxidized to an N-oxide moiety. N-oxides in compounds of formula I can in particular be prepared by oxidizing the ring nitrogen atom(s) of the heterocyclic ring with a suitable oxidizing agent, such as peroxo carboxylic acids or other peroxides, or the ring nitrogen atom(s) of a heterocyclic substituent R, R1, R2 or R3.


The present invention moreover relates to compounds as defined herein, wherein one or more of the atoms depicted in formula I have been replaced by its stable, preferably non-radioactive isotope (e.g., hydrogen by deuterium, 12C by 13O, 14N by 15N, 16O by 18O) and in particular wherein at least one hydrogen atom has been replaced by a deuterium atom. Of course, the compounds according to the invention contain more of the respective isotope than this naturally occurs and thus is anyway present in the compounds of formula I.


The compounds of the present invention may be amorphous or may exist in one ore more different crystalline states (polymorphs) which may have different macroscopic properties such as stability or show different biological properties such as activities. The present invention includes both amorphous and crystalline compounds of formula I, their enantiomers or diastereomers, mixtures of different crystalline states of the respective compound of formula I, its enantiomers or diastereomers, as well as amorphous or crystalline salts thereof.


Salts of the compounds of the present invention are preferably agriculturally suitable salts. They can be formed in a customary method, e.g. by reacting the compound with an acid if the compound of the present invention has a basic functionality or by reacting the compound with a suitable base if the compound of the present invention has an acidic functionality.


Useful agriculturally suitable salts are especially the salts of those cations or the acid addition salts of those acids whose cations and anions, respectively, do not have any adverse effect on the herbicidal action of the compounds according to the present invention. Suitable cations are in particular the ions of the alkali metals, preferably lithium, sodium and potassium, of the alkaline earth metals, preferably calcium, magnesium and barium, and of the transition metals, preferably manganese, copper, zinc and iron, and also ammonium (NH4+) and substituted ammonium in which one to four of the hydrogen atoms are replaced by C1-C4-alkyl, C1-C4-hydroxyalkyl, C1-C4-alkoxy, C1-C4-alkoxy-C1-C4-alkyl, hydroxy-C1-C4-alkoxy-C1-C4-alkyl, phenyl or benzyl. Examples of substituted ammonium ions comprise methylammonium, isopropylammonium, dimethylammonium, diisopropylammonium, trimethylammonium, tetramethylammonium, tetraethylammonium, tetrabutylammonium, 2-hydroxyethylammonium, 2-(2-hydroxyethoxy)ethylammonium, bis(2-hydroxyethyl)ammonium, benzyltrimethylammonium and benzyl-triethylammonium, furthermore phosphonium ions, sulfonium ions, preferably tri(C1-C4-alkyl)sulfonium, and sulfoxonium ions, preferably tri(C1-C4-alkyl)sulfoxonium.


Anions of useful acid addition salts are primarily chloride, bromide, fluoride, hydrogensulfate, sulfate, dihydrogenphosphate, hydrogenphosphate, phosphate, nitrate, bicarbonate, carbonate, hexafluorosilicate, hexafluorophosphate, benzoate, and the anions of C1-C4-alkanoic acids, preferably formate, acetate, propionate and butyrate. They can be formed by reacting compounds of the present invention with an acid of the corresponding anion, preferably with hydrochloric acid, hydrobromic acid, sulfuric acid, phosphoric acid or nitric acid.


The term “undesired vegetation” (“weeds”) is understood to include any vegetation growing in non-crop-areas or at a crop plant site or locus of seeded and otherwise desired crop, where the vegetation is any plant species, including their germinant seeds, emerging seedlings and established vegetation, other than the seeded or desired crop (if any). Weeds, in the broadest sense, are plants considered undesirable in a particular location.


The organic moieties mentioned in the above definitions of the variables are—like the term halogen—collective terms for individual listings of the individual group members. The prefix Cn-Cm indicates in each case the possible number of carbon atoms in the group.


The term “halogen” denotes in each case fluorine, bromine, chlorine or iodine, in particular fluorine, chlorine or bromine.


The term “partially or completely halogenated” will be taken to mean that 1 or more, e.g. 1, 2, 3, 4 or 5 or all of the hydrogen atoms of a given radical have been replaced by a halogen atom, in particular by fluorine or chlorine. A partially or completely halogenated radical is termed below also “halo-radical”. For example, partially or completely halogenated alkyl is also termed haloalkyl.


The term “alkyl” as used herein (and in the alkyl moieties of other groups comprising an alkyl group, e.g. alkoxy, alkylcarbonyl, alkoxycarbonyl, alkylthio, alkylsulfonyl and alkoxyalkyl) denotes in each case a straight-chain or branched alkyl group having usually from 1 to 10 carbon atoms, frequently from 1 to 6 carbon atoms, preferably 1 to 4 carbon atoms and in particular from 1 to 3 carbon atoms. Examples of C1-C4-alkyl are methyl, ethyl, n-propyl, iso-propyl, n-butyl, 2-butyl (sec-butyl), isobutyl and tert-butyl. Examples for C1-C6-alkyl are, apart those mentioned for C1-C4-alkyl, n-pentyl, 1-methylbutyl, 2-methylbutyl, 3-methylbutyl, 2,2-dimethylpropyl, 1-ethylpropyl, n-hexyl, 1,1-dimethylpropyl, 1,2-dimethylpropyl, 1-methylpentyl, 2-methylpentyl, 3-methylpentyl, 4-methylpentyl, 1,1-dimethylbutyl, 1,2-dimethylbutyl, 1,3-dimethylbutyl, 2,2-dimethylbutyl, 2,3-dimethylbutyl, 3,3-dimethylbutyl, 1-ethylbutyl, 2-ethylbutyl, 1,1,2-trimethylpropyl, 1,2,2-trimethylpropyl, 1-ethyl-1-methylpropyl and 1-ethyl-2-methylpropyl. Examples for C1-C10-alkyl are, apart those mentioned for C1-C6-alkyl, n-heptyl, 1-methylhexyl, 2-methylhexyl, 3-methylhexyl, 4-methylhexyl, 5-methylhexyl, 1-ethylpentyl, 2-ethylpentyl, 3-ethylpentyl, n-octyl, 1-methyloctyl, 2-methylheptyl, 1-ethylhexyl, 2-ethylhexyl, 1,2-dimethylhexyl, 1-propylpentyl, 2-propylpentyl, nonyl, decyl, 2-propylheptyl and 3-propylheptyl.


The term “alkylene” (or alkanediyl) as used herein in each case denotes an alkyl radical as defined above, wherein one hydrogen atom at any position of the carbon backbone is replaced by one further binding site, thus forming a bivalent moiety.


The term “haloalkyl” as used herein (and in the haloalkyl moieties of other groups comprising a haloalkyl group, e.g. haloalkoxy, haloalkylthio, haloalkylcarbonyl, haloalkylsulfonyl and haloalkylsulfinyl) denotes in each case a straight-chain or branched alkyl group having usually from 1 to 8 carbon atoms (“C1-C8-haloalkyl”), frequently from 1 to 6 carbon atoms (“C1-C6-haloalkyl”), more frequently 1 to 4 carbon atoms (“C1-C4-haloalkyl”), wherein the hydrogen atoms of this group are partially or totally replaced with halogen atoms. Preferred haloalkyl moieties are selected from C1-C4-haloalkyl, more preferably from C1-C2-haloalkyl, more preferably from halomethyl, in particular from C1-C2-fluoroalkyl. Halomethyl is methyl in which 1, 2 or 3 of the hydrogen atoms are replaced by halogen atoms. Examples are bromomethyl, chloromethyl, dichloromethyl, trichloromethyl, fluoromethyl, difluoromethyl, trifluoromethyl, chlorofluoromethyl, dichlorofluoromethyl, chlorodifluoromethyl and the like. Examples for C1-C2-fluoroalkyl are fluoromethyl, difluoromethyl, trifluoromethyl, 1-fluoroethyl, 2-fluoroethyl, 2,2-difluoroethyl, 2,2,2-trifluoroethyl, pentafluoroethyl, and the like. Examples for C1-C2-haloalkyl are, apart those mentioned for C1-C2-fluoroalkyl, chloromethyl, dichloromethyl, trichloromethyl, bromomethyl, chlorofluoromethyl, dichlorofluoromethyl, chlorodifluoromethyl, 1-chloroethyl, 2-chloroethyl, 2,2-dichloroethyl, 2,2,2-trichloroethyl, 2-chloro-2-fluoroethyl, 2-chloro-2,2-difluoroethyl, 2,2-dichloro-2-fluoroethyl, 1-bromoethyl, and the like. Examples for C1-C4-haloalkyl are, apart those mentioned for C1-C2-haloalkyl, 1-fluoropropyl, 2-fluoropropyl, 3-fluoropropyl, 3,3-difluoropropyl, 3,3,3-trifluoropropyl, heptafluoropropyl, 1,1,1-trifluoroprop-2-yl, 3-chloropropyl, 4-chlorobutyl and the like.


The term “cycloalkyl” as used herein (and in the cycloalkyl moieties of other groups comprising a cycloalkyl group, e.g. cycloalkoxy and cycloalkylalkyl) denotes in each case a mono- or bicyclic cycloaliphatic radical having usually from 3 to 10 carbon atoms (“C3-C10-cycloalkyl”), preferably 3 to 7 carbon atoms (“C3-C7-cycloalkyl”) or in particular 3 to 6 carbon atoms (“C3-C6-cycloalkyl”). Examples of monocyclic radicals having 3 to 6 carbon atoms comprise cyclopropyl, cyclobutyl, cyclopentyl and cyclohexyl. Examples of monocyclic radicals having 3 to 7 carbon atoms comprise cyclopropyl, cyclobutyl, cyclopentyl, cyclohexyl and cycloheptyl. Examples of bicyclic radicals having 7 or 8 carbon atoms comprise bicyclo[2.1.1]hexyl, bicyclo[2.2.1]heptyl, bicyclo[3.1.1]heptyl, bicyclo[2.2.1]heptyl, bicyclo[2.2.2]octyl and bicyclo[3.2.1]octyl.


The term “halocycloalkyl” as used herein (and in the halocycloalkyl moieties of other groups comprising an halocycloalkyl group, e.g. halocycloalkylmethyl) denotes in each case a mono- or bicyclic cycloaliphatic radical having usually from 3 to 10 carbon atoms, preferably 3 to 7 carbon atoms or in particular 3 to 6 carbon atoms, wherein at least one, e.g. 1, 2, 3, 4 or 5 of the hydrogen atoms are replaced by halogen, in particular by fluorine or chlorine. Examples are 1- and 2-fluorocyclopropyl, 1,2-, 2,2- and 2,3-difluorocyclopropyl, 1,2,2-trifluorocyclopropyl, 2,2,3,3-tetrafluorocyclopropyl, 1- and 2-chlorocyclopropyl, 1,2-, 2,2- and 2,3-dichlorocyclopropyl, 1,2,2-trichlorocyclopropyl, 2,2,3,3-tetrachlorocyclopropyl, 1-, 2- and 3-fluorocyclopentyl, 1,2-, 2,2-, 2,3-, 3,3-, 3,4-, 2,5-difluorocyclopentyl, 1-, 2- and 3-chlorocyclopentyl, 1,2-, 2,2-, 2,3-, 3,3-, 3,4-, 2,5-dichlorocyclopentyl and the like.


The term “cycloalkyl-alkyl” used herein denotes a cycloalkyl group, as defined above, which is bound to the remainder of the molecule via an alkylene group. The term “C3-C7-cycloalkyl-C1-C4-alkyl” refers to a C3-C7-cycloalkyl group as defined above which is bound to the remainder of the molecule via a C1-C4-alkyl group, as defined above. Examples are cyclo-propylmethyl, cyclopropylethyl, cyclopropylpropyl, cyclobutylmethyl, cyclobutylethyl, cyclobutylpropyl, cyclopentylmethyl, cyclopentylethyl, cyclopentylpropyl, cyclohexylmethyl, cyclohexylethyl, cyclohexylpropyl, and the like.


The term “alkenyl” as used herein denotes in each case a monounsaturated straight-chain or branched hydrocarbon radical having usually 2 to 8 (“C2-C8-alkenyl”), preferably 2 to 6 carbon atoms (“C2-C6-alkenyl”), in particular 2 to 4 carbon atoms (“C2-C4-alkenyl”), and a double bond in any position, for example C2-C4-alkenyl, such as ethenyl, 1-propenyl, 2-propenyl, 1-methylethenyl, 1-butenyl, 2-butenyl, 3-butenyl, 1-methyl-1-propenyl, 2-methyl-1-propenyl, 1-methyl-2-propenyl or 2-methyl-2-propenyl; C2-C6-alkenyl, such as ethenyl, 1-propenyl, 2-propenyl, 1-methylethenyl, 1-butenyl, 2-butenyl, 3-butenyl, 1-methyl-1-propenyl, 2-methyl-1-propenyl, 1-methyl-2-propenyl, 2-methyl-2-propenyl, 1-pentenyl, 2-pentenyl, 3-pentenyl, 4-pentenyl, 1-methyl-1-butenyl, 2-methyl-1-butenyl, 3-methyl-1-butenyl, 1-methyl-2-butenyl, 2-methyl-2-butenyl, 3-methyl-2-butenyl, 1-methyl-3-butenyl, 2-methyl-3-butenyl, 3-methyl-3-butenyl, 1,1-dimethyl-2-propenyl, 1,2-dimethyl-1-propenyl, 1,2-dimethyl-2-propenyl, 1-ethyl-1-propenyl, 1-ethyl-2-propenyl, 1-hexenyl, 2-hexenyl, 3-hexenyl, 4-hexenyl, 5-hexenyl, 1-methyl-1-pentenyl, 2-methyl-1-pentenyl, 3-methyl-1-pentenyl, 4-methyl-1-pentenyl, 1-methyl-2-pentenyl, 2-methyl-2-pentenyl, 3-methyl-2-pentenyl, 4-methyl-2-pentenyl, 1-methyl-3-pentenyl, 2-methyl-3-pentenyl, 3-methyl-3-pentenyl, 4-methyl-3-pentenyl, 1-methyl-4-pentenyl, 2-methyl-4-pentenyl, 3-methyl-4-pentenyl, 4-methyl-4-pentenyl, 1,1-dimethyl-2-butenyl, 1,1-dimethyl-3-butenyl, 1,2-dimethyl-1-butenyl, 1,2-dimethyl-2-butenyl, 1,2-dimethyl-3-butenyl, 1,3-dimethyl-1-butenyl, 1,3-dimethyl-2-butenyl, 1,3-dimethyl-3-butenyl, 2,2-dimethyl-3-butenyl, 2,3-dimethyl-1-butenyl, 2,3-dimethyl-2-butenyl, 2,3-dimethyl-3-butenyl, 3,3-dimethyl-1-butenyl, 3,3-dimethyl-2-butenyl, 1-ethyl-1-butenyl, 1-ethyl-2-butenyl, 1-ethyl-3-butenyl, 2-ethyl-1-butenyl, 2-ethyl-2-butenyl, 2-ethyl-3-butenyl, 1,1,2-trimethyl-2-propenyl, 1-ethyl-1-methyl-2-propenyl, 1-ethyl-2-methyl-1-propenyl, 1-ethyl-2-methyl-2-propenyl and the like, or C2-C8-alkenyl, such as the radicals mentioned for C2-C6-alkenyl and additionally 1-heptenyl, 2-heptenyl, 3-heptenyl, 1-octenyl, 2-octenyl, 3-octenyl, 4-octenyl and the positional isomers thereof.


The term “haloalkenyl” as used herein, which may also be expressed as “alkenyl which is substituted by halogen”, and the haloalkenyl moieties in haloalkenyloxy and the like refers to unsaturated straight-chain or branched hydrocarbon radicals having 2 to 8 (“C2-C8-haloalkenyl”) or 2 to 6 (“C2-C6-haloalkenyl”) or 2 to 4 (“C2-C4-haloalkenyl”) carbon atoms and a double bond in any position, where some or all of the hydrogen atoms in these groups are replaced by halogen atoms as mentioned above, in particular fluorine, chlorine and bromine, for example chlorovinyl, chloroallyl and the like.


The term “alkynyl” as used herein denotes unsaturated straight-chain or branched hydrocarbon radicals having usually 2 to 8 (“C2-C8-alkynyl”), frequently 2 to 6 (“C2-C6-alkynyl”), preferably 2 to 4 carbon atoms (“C2-C4-alkynyl”) and a triple bond in any position, for example C2-C4-alkynyl, such as ethynyl, 1-propynyl, 2-propynyl, 1-butynyl, 2-butynyl, 3-butynyl, 1-methyl-2-propynyl and the like, C2-C6-alkynyl, such as ethynyl, 1-propynyl, 2-propynyl, 1-butynyl, 2-butynyl, 3-butynyl, 1-methyl-2-propynyl, 1-pentynyl, 2-pentynyl, 3-pentynyl, 4-pentynyl, 1-methyl-2-butynyl, 1-methyl-3-butynyl, 2-methyl-3-butynyl, 3-methyl-1-butynyl, 1,1-dimethyl-2-propynyl, 1-ethyl-2-propynyl, 1-hexynyl, 2-hexynyl, 3-hexynyl, 4-hexynyl, 5-hexynyl, 1-methyl-2-pentynyl, 1-methyl-3-pentynyl, 1-methyl-4-pentynyl, 2-methyl-3-pentynyl, 2-methyl-4-pentynyl, 3-methyl-1-pentynyl, 3-methyl-4-pentynyl, 4-methyl-1-pentynyl, 4-methyl-2-pentynyl, 1,1-dimethyl-2-butynyl, 1,1-dimethyl-3-butynyl, 1,2-dimethyl-3-butynyl, 2,2-dimethyl-3-butynyl, 3,3-dimethyl-1-butynyl, 1-ethyl-2-butynyl, 1-ethyl-3-butynyl, 2-ethyl-3-butynyl, 1-ethyl-1-methyl-2-propynyl and the like.


The term “haloalkynyl” as used herein, which is also expressed as “alkynyl which is substituted by halogen”, refers to unsaturated straight-chain or branched hydrocarbon radicals having usually 2 to 8 carbon atoms (“C2-C8-haloalkynyl”), frequently 2 to 6 (“C2-C6-haloalkynyl”), preferably 2 to 4 carbon atoms (“C2-C4-haloalkynyl”), and a triple bond in any position (as mentioned above), where some or all of the hydrogen atoms in these groups are replaced by halogen atoms as mentioned above, in particular fluorine, chlorine and bromine.


The term “alkoxy” as used herein denotes in each case a straight-chain or branched alkyl group usually having from 1 to 8 carbon atoms (“C1-C8-alkoxy”), frequently from 1 to 6 carbon atoms (“C1-C6-alkoxy”), preferably 1 to 4 carbon atoms (“C1-C4-alkoxy”), which is bound to the remainder of the molecule via an oxygen atom. C1-C2-Alkoxy is methoxy or ethoxy. C1-C4-Alkoxy is additionally, for example, n-propoxy, 1-methylethoxy (isopropoxy), butoxy, 1-methylpropoxy (sec-butoxy), 2-methylpropoxy (isobutoxy) or 1,1-dimethylethoxy (tert-butoxy). C1-C6-Alkoxy is additionally, for example, pentoxy, 1-methylbutoxy, 2-methylbutoxy, 3-methylbutoxy, 1,1-dimethylpropoxy, 1,2-dimethylpropoxy, 2,2-dimethylpropoxy, 1-ethylpropoxy, hexoxy, 1-methylpentoxy, 2-methylpentoxy, 3-methylpentoxy, 4-methylpentoxy, 1,1-dimethylbutoxy, 1,2-dimethylbutoxy, 1,3-dimethylbutoxy, 2,2-dimethylbutoxy, 2,3-dimethylbutoxy, 3,3-dimethylbutoxy, 1-ethylbutoxy, 2-ethylbutoxy, 1,1,2-trimethylpropoxy, 1,2,2-trimethylpropoxy, 1-ethyl-1-methylpropoxy or 1-ethyl-2-methylpropoxy. C1-C8-Alkoxy is additionally, for example, heptyloxy, octyloxy, 2-ethylhexyloxy and positional isomers thereof.


The term “haloalkoxy” as used herein denotes in each case a straight-chain or branched alkoxy group, as defined above, having from 1 to 8 carbon atoms (“C1-C8-haloalkoxy”), frequently from 1 to 6 carbon atoms (“C1-C6-haloalkoxy”), preferably 1 to 4 carbon atoms (“C1-C4-haloalkoxy”), more preferably 1 to 3 carbon atoms (“C1-C3-haloalkoxy”), wherein the hydrogen atoms of this group are partially or totally replaced with halogen atoms, in particular fluorine atoms. C1-C2-Haloalkoxy is, for example, OCH2F, OCHF2, OCF3, OCH2Cl, OCHCl2, OCCl3, chlorofluoromethoxy, dichlorofluoromethoxy, chlorodifluoromethoxy, 2-fluoroethoxy, 2-chloroethoxy, 2-bromoethoxy, 2-iodoethoxy, 2,2-difluoroethoxy, 2,2,2-trifluoroethoxy, 2-chloro-2-fluoroethoxy, 2-chloro-2,2-difluoroethoxy, 2,2-dichloro-2-fluoroethoxy, 2,2,2-trichloroethoxy or OC2F5. C1-C4-Haloalkoxy is additionally, for example, 2-fluoropropoxy, 3-fluoropropoxy, 2,2-difluoropropoxy, 2,3-difluoropropoxy, 2-chloropropoxy, 3-chloropropoxy, 2,3-dichloropropoxy, 2-bromopropoxy, 3-bromopropoxy, 3,3,3-trifluoropropoxy, 3,3,3-trichloropropoxy, OCH2—C2F5, OCF2—C2F5, 1-(CH2F)-2-fluoroethoxy, 1-(CH2Cl)-2-chloroethoxy, 1-(CH2Br)-2-bromoethoxy, 4-fluorobutoxy, 4-chlorobutoxy, 4-bromobutoxy or nonafluorobutoxy. C1-C6-Haloalkoxy is additionally, for example, 5-fluoropentoxy, 5-chloropentoxy, 5-bromopentoxy, 5-iodopentoxy, undecafluoropentoxy, 6-fluorohexoxy, 6-chlorohexoxy, 6-bromohexoxy, 6-iodohexoxy or dodecafluorohexoxy.


The term “alkoxyalkyl” as used herein denotes in each case alkyl usually comprising 1 to 6 carbon atoms, preferably 1 to 4 carbon atoms, wherein 1 carbon atom carries an alkoxy radical usually comprising 1 to 8, frequently 1 to 6, in particular 1 to 4, carbon atoms as defined above. “C1-C6-alkoxy-C1-C6-alkyl” is a C1-C6-alkyl group, as defined above, in which one hydrogen atom is replaced by a C1-C6-alkoxy group, as defined above. Examples are CH2OCH3, CH2—OC2H5, n-propoxymethyl, CH2—OCH(CH3)2, n-butoxymethyl, (1-methylpropoxy)-methyl, (2-methylpropoxy)methyl, CH2—OC(CH3)3, 2-(methoxy)ethyl, 2-(ethoxy)ethyl, 2-(n-propoxy)-ethyl, 2-(1-methylethoxy)-ethyl, 2-(n-butoxy)ethyl, 2-(1-methylpropoxy)-ethyl, 2-(2-methylpropoxy)-ethyl, 2-(1,1-dimethylethoxy)-ethyl, 2-(methoxy)-propyl, 2-(ethoxy)-propyl, 2-(n-propoxy)-propyl, 2-(1-methylethoxy)-propyl, 2-(n-butoxy)-propyl, 2-(1-methylpropoxy)-propyl, 2-(2-methylpropoxy)-propyl, 2-(1,1-dimethylethoxy)-propyl, 3-(methoxy)-propyl, 3-(ethoxy)-propyl, 3-(n-propoxy)-propyl, 3-(1-methylethoxy)-propyl, 3-(n-butoxy)-propyl, 3-(1-methylpropoxy)-propyl, 3-(2-methylpropoxy)-propyl, 3-(1,1-dimethylethoxy)-propyl, 2-(methoxy)-butyl, 2-(ethoxy)-butyl, 2-(n-propoxy)-butyl, 2-(1-methylethoxy)-butyl, 2-(n-butoxy)-butyl, 2-(1-methylpropoxy)-butyl, 2-(2-methyl-propoxy)-butyl, 2-(1,1-dimethylethoxy)-butyl, 3-(methoxy)-butyl, 3-(ethoxy)-butyl, 3-(n-propoxy)-butyl, 3-(1-methylethoxy)-butyl, 3-(n-butoxy)-butyl, 3-(1-methylpropoxy)-butyl, 3-(2-methylpropoxy)-butyl, 3-(1,1-dimethylethoxy)-butyl, 4-(methoxy)-butyl, 4-(ethoxy)-butyl, 4-(n-propoxy)-butyl, 4-(1-methylethoxy)-butyl, 4-(n-butoxy)-butyl, 4-(1-methylpropoxy)-butyl, 4-(2-methylpropoxy)-butyl, 4-(1,1-dimethylethoxy)-butyl and the like.


The term “haloalkoxy-alkyl” as used herein denotes in each case alkyl as defined above, usually comprising 1 to 6 carbon atoms, preferably 1 to 4 carbon atoms, wherein 1 carbon atom carries an haloalkoxy radical as defined above, usually comprising 1 to 8, frequently 1 to 6, in particular 1 to 4, carbon atoms as defined above. Examples are fluoromethoxymethyl, difluoromethoxymethyl, trifluoromethoxymethyl, 1-fluoroethoxymethyl, 2-fluoroethoxymethyl, 1,1-difluoroethoxymethyl, 1,2-difluoroethoxymethyl, 2,2-difluoroethoxymethyl, 1,1,2-trifluoroethoxymethyl, 1,2,2-trifluoroethoxymethyl, 2,2,2-trifluoroethoxymethyl, pentafluoroethoxymethyl, 1-fluoroethoxy-1-ethyl, 2-fluoroethoxy-1-ethyl, 1,1-difluoroethoxy-1-ethyl, 1,2-difluoroethoxy-1-ethyl, 2,2-difluoroethoxy-1-ethyl, 1,1,2-trifluoroethoxy-1-ethyl, 1,2,2-trifluoroethoxy-1-ethyl, 2,2,2-trifluoroethoxy-1-ethyl, pentafluoroethoxy-1-ethyl, 1-fluoroethoxy-2-ethyl, 2-fluoroethoxy-2-ethyl, 1,1-difluoroethoxy-2-ethyl, 1,2-difluoroethoxy-2-ethyl, 2,2-difluoroethoxy-2-ethyl, 1,1,2-trifluoroethoxy-2-ethyl, 1,2,2-trifluoroethoxy-2-ethyl, 2,2,2-trifluoroethoxy-2-ethyl, pentafluoroethoxy-2-ethyl, and the like.


The term “alkylthio” (also alkylsulfanyl, “alkyl-S” or “alkyl-S(O)k” (wherein k is 0)) as used herein denotes in each case a straight-chain or branched saturated alkyl group as defined above, usually comprising 1 to 8 carbon atoms (“C1-C8-alkylthio”), frequently comprising 1 to 6 carbon atoms (“C1-C6-alkylthio”), preferably 1 to 4 carbon atoms (“C1-C4-alkylthio”), which is attached via a sulfur atom at any position in the alkyl group. C1-C2-Alkylthio is methylthio or ethylthio. C1-C4-Alkylthio is additionally, for example, n-propylthio, 1-methylethylthio (iso-propylthio), butylthio, 1-methylpropylthio (sec-butylthio), 2-methylpropylthio (isobutylthio) or 1,1-dimethylethylthio (tert-butylthio). C1-C6-Alkylthio is additionally, for example, pentylthio, 1-methylbutylthio, 2-methylbutylthio, 3-methylbutylthio, 1,1-dimethylpropylthio, 1,2-dimethylpropylthio, 2,2-dimethylpropylthio, 1-ethylpropylthio, hexylthio, 1-methylpentylthio, 2-methylpentylthio, 3-methylpentylthio, 4-methylpentylthio, 1,1-dimethylbutylthio, 1,2-dimethylbutylthio, 1,3-dimethylbutylthio, 2,2-dimethylbutylthio, 2,3-dimethylbutylthio, 3,3-dimethylbutylthio, 1-ethylbutylthio, 2-ethylbutylthio, 1,1,2-trimethylpropylthio, 1,2,2-trimethylpropylthio, 1-ethyl-1-methylpropylthio or 1-ethyl-2-methylpropylthio. C1-C8-Alkylthio is additionally, for example, heptylthio, octylthio, 2-ethylhexylthio and positional isomers thereof.


The term “haloalkylthio” as used herein refers to an alkylthio group as defined above wherein the hydrogen atoms are partially or completely substituted by fluorine, chlorine, bromine and/or iodine. C1-C2-Haloalkylthio is, for example, SCH2F, SCHF2, SCF3, SCH2Cl, SCHCl2, SCCl3, chlorofluoromethylthio, dichlorofluoromethylthio, chlorodifluoromethylthio, 2-fluoroethylthio, 2-chloroethylthio, 2-bromoethylthio, 2-iodoethylthio, 2,2-difluoroethylthio, 2,2,2-trifluoroethylthio, 2-chloro-2-fluoroethylthio, 2-chloro-2,2-difluoroethylthio, 2,2-dichloro-2-fluoroethylthio, 2,2,2-trichloroethylthio or SC2F5. C1-C4-Haloalkylthio is additionally, for example, 2-fluoropropylthio, 3-fluoropropylthio, 2,2-difluoropropylthio, 2,3-difluoropropylthio, 2-chloropropylthio, 3-chloropropylthio, 2,3-dichloropropylthio, 2-bromopropylthio, 3-bromopropylthio, 3,3,3-trifluoropropylthio, 3,3,3-trichloropropylthio, SCH2—C2F5, SCF2—C2F5, 1-(CH2F)-2-fluoroethylthio, 1-(CH2Cl)-2-chloroethylthio, 1-(CH2Br)-2-bromoethylthio, 4-fluorobutylthio, 4-chlorobutylthio, 4-bromobutylthio or nonafluorobutylthio. C1-C6-Haloalkylthio is additionally, for example, 5-fluoropentylthio, 5-chloropentylthio, 5-brompentylthio, 5-iodopentylthio, undecafluoropentylthio, 6-fluorohexylthio, 6-chlorohexylthio, 6-bromohexylthio, 6-iodohexylthio or dodecafluorohexylthio.


The terms “alkylsulfinyl” and “alkyl-S(O)k” (wherein k is 1) are equivalent and, as used herein, denote an alkyl group, as defined above, attached via a sulfinyl [S(O)] group. For example, the term “C1-C2-alkylsulfinyl” refers to a C1-C2-alkyl group, as defined above, attached via a sulfinyl [S(O)] group. The term “C1-C4-alkylsulfinyl” refers to a C1-C4-alkyl group, as defined above, attached via a sulfinyl [S(O)] group. The term “C1-C6-alkylsulfinyl” refers to a C1-C6-alkyl group, as defined above, attached via a sulfinyl [S(O)] group. C1-C2-alkylsulfinyl is methylsulfinyl or ethylsulfinyl. C1-C4-alkylsulfinyl is additionally, for example, n-propylsulfinyl, 1-methylethylsulfinyl (isopropylsulfinyl), butylsulfinyl, 1-methylpropylsulfinyl (sec-butylsulfinyl), 2-methylpropylsulfinyl (isobutylsulfinyl) or 1,1-dimethylethylsulfinyl (tert-butylsulfinyl). C1-C6-alkylsulfinyl is additionally, for example, pentylsulfinyl, 1-methylbutylsulfinyl, 2-methylbutylsulfinyl, 3-methylbutylsulfinyl, 1,1-dimethylpropylsulfinyl, 1,2-dimethylpropylsulfinyl, 2,2-dimethylpropylsulfinyl, 1-ethylpropylsulfinyl, hexylsulfinyl, 1-methylpentylsulfinyl, 2-methylpentylsulfinyl, 3-methylpentylsulfinyl, 4-methylpentylsulfinyl, 1,1-dimethylbutylsulfinyl, 1,2-dimethylbutylsulfinyl, 1,3-dimethylbutylsulfinyl, 2,2-dimethylbutylsulfinyl, 2,3-dimethylbutylsulfinyl, 3,3-dimethylbutylsulfinyl, 1-ethylbutylsulfinyl, 2-ethylbutylsulfinyl, 1,1,2-trimethylpropylsulfinyl, 1,2,2-trimethylpropylsulfinyl, 1-ethyl-1-methylpropylsulfinyl or 1-ethyl-2-methylpropylsulfinyl.


The terms “alkylsulfonyl” and “alkyl-S(O)k” (wherein k is 2) are equivalent and, as used herein, denote an alkyl group, as defined above, attached via a sulfonyl [S(O)2] group. The term “C1-C2-alkylsulfonyl” refers to a C1-C2-alkyl group, as defined above, attached via a sulfonyl [S(O)2] group. The term “C1-C4-alkylsulfonyl” refers to a C1-C4-alkyl group, as defined above, attached via a sulfonyl [S(O)2] group. The term “C1-C6-alkylsulfonyl” refers to a C1-C6-alkyl group, as defined above, attached via a sulfonyl [S(O)2] group. C1-C2-alkylsulfonyl is methylsulfonyl or ethylsulfonyl. C1-C4-alkylsulfonyl is additionally, for example, n-propylsulfonyl, 1-methylethylsulfonyl (isopropylsulfonyl), butylsulfonyl, 1-methylpropylsulfonyl (sec-butylsulfonyl), 2-methylpropylsulfonyl (isobutylsulfonyl) or 1,1-dimethylethylsulfonyl (tert-butylsulfonyl). C1-C6-alkylsulfonyl is additionally, for example, pentylsulfonyl, 1-methylbutylsulfonyl, 2-methylbutylsulfonyl, 3-methylbutylsulfonyl, 1,1-dimethylpropylsulfonyl, 1,2-dimethylpropylsulfonyl, 2,2-dimethylpropylsulfonyl, 1-ethylpropylsulfonyl, hexylsulfonyl, 1-methylpentylsulfonyl, 2-methylpentylsulfonyl, 3-methylpentylsulfonyl, 4-methylpentylsulfonyl, 1,1-dimethylbutylsulfonyl, 1,2-dimethylbutylsulfonyl, 1,3-dimethylbutylsulfonyl, 2,2-dimethylbutylsulfonyl, 2,3-dimethylbutylsulfonyl, 3,3-dimethylbutylsulfonyl, 1-ethylbutylsulfonyl, 2-ethylbutylsulfonyl, 1,1,2-trimethylpropylsulfonyl, 1,2,2-trimethylpropylsulfonyl, 1-ethyl-1-methylpropylsulfonyl or 1-ethyl-2-methylpropylsulfonyl.


The term “alkylamino” as used herein denotes in each case a group R*HN—, wherein R* is a straight-chain or branched alkyl group usually having from 1 to 6 carbon atoms (“C1-C6-alkylamino”), preferably 1 to 4 carbon atoms (“C1-C4-alkylamino”). Examples of C1-C6-alkylamino are methylamino, ethylamino, n-propylamino, isopropylamino, n-butylamino, 2-butylamino, isobutyl-amino, tert-butylamino, and the like.


The term “dialkylamino” as used herein denotes in each case a group R*RoN—, wherein R* and Ro, independently of each other, are a straight-chain or branched alkyl group each usually having from 1 to 6 carbon atoms (“di-(C1-C6-alkyl)-amino”), preferably 1 to 4 carbon atoms (“di-(C1-C4-alkyl)-amino”). Examples of a di-(C1-C6-alkyl)-amino group are dimethylamino, diethylamino, dipropylamino, dibutylamino, methyl-ethyl-amino, methyl-propyl-amino, methyl-isopropylamino, methyl-butyl-amino, methyl-isobutyl-amino, ethyl-propyl-amino, ethyl-isopropylamino, ethyl-butyl-amino, ethyl-isobutyl-amino, and the like.


The suffix “-carbonyl” in a group denotes in each case that the group is bound to the remainder of the molecule via a carbonyl C═O group. This is the case e.g. in alkylcarbonyl, haloalkylcarbonyl, aminocarbonyl, alkylaminocarbonyl, dialkylaminocarbonyl, alkoxycarbonyl, haloalkoxycarbonyl.


The term “aryl” as used herein refers to a mono-, bi- or tricyclic aromatic hydrocarbon radical such as phenyl or naphthyl, in particular phenyl.


The term “het(ero)aryl” as used herein refers to a mono-, bi- or tricyclic heteroaromatic hydrocarbon radical, preferably to a monocyclic heteroaromatic radical, such as pyridyl, pyrimidyl and the like.


The term “3-, 4-, 5- or 6-membered monocyclic or 8-, 9- or 10-membered bicyclic saturated, unsaturated or aromatic heterocycle containing 1, 2, 3 or 4 heteroatoms as ring members selected from the groups consisting of N, O and S” as used herein denotes monocyclic or bicyclic radicals, the monocyclic or bicyclic radicals being saturated, unsaturated or aromatic where N can optionally be oxidized, i.e. in the form of an N-oxide, and S can also optionally be oxidized to various oxidation states, i.e. as SO or SO2. An unsaturated heterocycle contains at least one C—C and/or C—N and/or N—N double bond(s). A fully unsaturated heterocycle contains as many conjugated C—C and/or C—N and/or N—N double bonds as allowed by the size(s) of the ring(s). An aromatic monocyclic heterocycle is a fully unsaturated 5- or 6-membered monocyclic heterocycle. An aromatic bicyclic heterocycle is an 8-, 9- or 10-membered bicyclic heterocycle consisting of a 5- or 6-membered heteroaromatic ring which is fused to a phenyl ring or to another 5- or 6-membered heteroaromatic ring. The heterocycle may be attached to the remainder of the molecule via a carbon ring member or via a nitrogen ring member. As a matter of course, the heterocyclic ring contains at least one carbon ring atom. If the ring contains more than one O ring atom, these are not adjacent.


Examples of a 3-, 4-, 5- or 6-membered monocyclic saturated heterocycle include: oxirane-2-yl, aziridine-1-yl, aziridine-2-yl, oxetan-2-yl, azetidine-1-yl, azetidine-2-yl, azetidine-3-yl, thietane-1-yl, thietan-2-yl, thietane-3-yl, tetrahydrofuran-2-yl, tetrahydrofuran-3-yl, tetrahydrothien-2-yl, tetrahydrothien-3-yl, pyrrolidin-1-yl, pyrrolidin-2-yl, pyrrolidin-3-yl, pyrazolidin-1-yl, pyrazolidin-3-yl, pyrazolidin-4-yl, pyrazolidin-5-yl, imidazolidin-1-yl, imidazolidin-2-yl, imidazolidin-4-yl, oxazolidin-2-yl, oxazolidin-3-yl, oxazolidin-4-yl, oxazolidin-5-yl, isoxazolidin-2-yl, isoxazolidin-3-yl, isoxazolidin-4-yl, isoxazolidin-5-yl, thiazolidin-2-yl, thiazolidin-3-yl, thiazolidin-4-yl, thiazolidin-5-yl, isothiazolidin-2-yl, isothiazolidin-3-yl, isothiazolidin-4-yl, isothiazolidin-5-yl, 1,2,4-oxadiazolidin-3-yl, 1,2,4-oxadiazolidin-5-yl, 1,2,4-thiadiazolidin-3-yl, 1,2,4-thiadiazolidin-5-yl, 1,2,4-triazolidin-3-yl, 1,3,4-oxadiazolidin-2-yl, 1,3,4-thiadiazolidin-2-yl, 1,3,4-triazolidin-1-yl, 1,3,4-triazolidin-2-yl, 2-tetrahydropyranyl, 4-tetrahydropyranyl, 1,3-dioxan-5-yl, 1,4-dioxan-2-yl, piperidin-1-yl, piperidin-2-yl, piperidin-3-yl, piperidin-4-yl, hexahydropyridazin-3-yl, hexahydropyridazin-4-yl, hexahydropyrimidin-2-yl, hexahydropyrimidin-4-yl, hexahydropyrimidin-5-yl, piperazin-1-yl, piperazin-2-yl, 1,3,5-hexahydrotriazin-1-yl, 1,3,5-hexahydrotriazin-2-yl and 1,2,4-hexahydrotriazin-3-yl, morpholin-2-yl, morpholin-3-yl, morpholin-4-yl, thiomorpholin-2-yl, thiomorpholin-3-yl, thiomorpholin-4-yl, 1-oxothiomorpholin-2-yl, 1-oxothiomorpholin-3-yl, 1-oxothiomorpholin-4-yl, 1,1-dioxothiomorpholin-2-yl, 1,1-dioxothiomorpholin-3-yl, 1,1-dioxothiomorpholin-4-yl and the like.


Examples of a 5- or 6-membered monocyclic partially unsaturated heterocycle include: 2,3-dihydrofur-2-yl, 2,3-dihydrofur-3-yl, 2,4-dihydrofur-2-yl, 2,4-dihydrofur-3-yl, 2,3-dihydrothien-2-yl, 2,3-dihydrothien-3-yl, 2,4-dihydrothien-2-yl, 2,4-dihydrothien-3-yl, 2-pyrrolin-2-yl, 2-pyrrolin-3-yl, 3-pyrrolin-2-yl, 3-pyrrolin-3-yl, 2-isoxazolin-3-yl, 3-isoxazolin-3-yl, 4-isoxazolin-3-yl, 2-isoxazolin-4-yl, 3-isoxazolin-4-yl, 4-isoxazolin-4-yl, 2-isoxazolin-5-yl, 3-isoxazolin-5-yl, 4-isoxazolin-5-yl, 2-isothiazolin-3-yl, 3-isothiazolin-3-yl, 4-isothiazolin-3-yl, 2-isothiazolin-4-yl, 3-isothiazolin-4-yl, 4-isothiazolin-4-yl, 2-isothiazolin-5-yl, 3-isothiazolin-5-yl, 4-isothiazolin-5-yl, 2,3-dihydropyrazol-1-yl, 2,3-dihydropyrazol-2-yl, 2,3-dihydropyrazol-3-yl, 2,3-dihydropyrazol-4-yl, 2,3-dihydropyrazol-5-yl, 3,4-dihydropyrazol-1-yl, 3,4-dihydropyrazol-3-yl, 3,4-dihydropyrazol-4-yl, 3,4-dihydropyrazol-5-yl, 4,5-dihydropyrazol-1-yl, 4,5-dihydropyrazol-3-yl, 4,5-dihydropyrazol-4-yl, 4,5-dihydropyrazol-5-yl, 2,3-dihydrooxazol-2-yl, 2,3-dihydrooxazol-3-yl, 2,3-dihydrooxazol-4-yl, 2,3-dihydrooxazol-5-yl, 3,4-dihydrooxazol-2-yl, 3,4-dihydrooxazol-3-yl, 3,4-dihydrooxazol-4-yl, 3,4-dihydrooxazol-5-yl, 3,4-dihydrooxazol-2-yl, 3,4-dihydrooxazol-3-yl, 3,4-dihydrooxazol-4-yl, 2-, 3-, 4-, 5- or 6-di- or tetrahydropyridinyl, 3-di- or tetrahydropyridazinyl, 4-di- or tetrahydropyridazinyl, 2-di- or tetrahydropyrimidinyl, 4-di- or tetrahydropyrimidinyl, 5-di- or tetrahydropyrimidinyl, di- or tetrahydropyrazinyl, 1,3,5-di- or tetrahydrotriazin-2-yl and 1,2,4-di- or tetrahydrotriazin-3-yl.


A 5- or 6-membered monocyclic fully unsaturated (including aromatic) heterocyclic ring is e.g. a 5- or 6-membered monocyclic fully unsaturated (including aromatic) heterocyclic ring. Examples are: 2-furyl, 3-furyl, 2-thienyl, 3-thienyl, 1-pyrrolyl, 2-pyrrolyl, 3-pyrrolyl, 1-pyrazolyl, 3-pyrazolyl, 4-pyrazolyl, 5-pyrazolyl, 2-oxazolyl, 4-oxazolyl, 5-oxazolyl, 2-thiazolyl, 4-thiazolyl, 5-thiazolyl, 1-imidazolyl, 2-imidazolyl, 4-imidazolyl, 1,3,4-triazol-1-yl, 1,3,4-triazol-2-yl, 2-pyridinyl, 3-pyridinyl, 4-pyridinyl, 1-oxopyridin-2-yl, 1-oxopyridin-3-yl, 1-oxopyridin-4-yl, 3-pyridazinyl, 4-pyridazinyl, 2-pyrimidinyl, 4-pyrimidinyl, 5-pyrimidinyl and 2-pyrazinyl.


Examples of a 5- or 6-membered heteroaromatic ring fused to a phenyl ring or to a 5- or 6-membered heteroaromatic radical include benzofuranyl, benzothienyl, indolyl, indazolyl, benzimidazolyl, benzoxathiazolyl, benzoxadiazolyl, benzothiadiazolyl, benzoxazinyl, chinolinyl, isochinolinyl, purinyl, 1,8-naphthyridyl, pteridyl, pyrido[3,2-d]pyrimidyl or pyridoimidazolyl and the like.


If two radicals bound on the same nitrogen atom (for example Re and Rf or R2e and R2f or Rg and Rh or R2g and R2h) together with the nitrogen atom, to which they are bound, form a 5-, 6 or 7-membered, saturated or unsaturated N-bound heterocyclic radical, which may carry as a ring member a further heteroatom selected from O, S and N, this is for example pyrrolidine-1-yl, pyrazolidin-1-yl, imidazolidin-1-yl, oxazolidin-3-yl, thiazolidin-3-yl, isoxazolidin-2-yl, isothiazolin-2-yl, [1,2,3]-triazolidin-1-yl, [1,2,3]-triazolidin-2-yl, [1,2,4]-triazolidin-1-yl, [1,2,4]-triazolidin-4-yl, [1,2,3]-oxadiazolidin-2-yl, [1,2,3]-oxadiazolidin-3-yl, [1,2,5]-oxadiazolidin-2-yl, [1,2,4]-oxadiazolidin-2-yl, [1,2,4]-oxadiazolidin-4-yl, [1,3,4]-oxadiazolidin-3-yl, [1,2,3]-thiadiazolidin-2-yl, [1,2,3]-thiadiazolidin-3-yl, [1,2,5]-thiadiazolidin-2-yl, [1,2,4]-thiadiazolidin-2-yl, [1,2,4]-thiadiazolidin-4-yl, [1,3,4]-thiadiazolidin-3-yl, piperidin-1-yl, piperazine-1-yl, morpholin-1-yl, thiomorpholin-1-yl, 1-oxothiomorpholin-1-yl, 1,1-dioxothiomorpholin-1-yl, azepan-1-yl, 1,4-diazepan-1-yl, pyrrolin-1-yl, pyrazolin-1-yl, imidazolin-1-yl, oxazolin-3-yl, isoxazolin-2-yl, thiazolin-3-yl, isothiazolin-1-yl, 1,2-dihydropyridin-1-yl, 1,2,3,4-tetrahydropyridin-1-yl, 1,2,5,6-tetrahydropyridin-1-yl, 1,2-dihydropyridazin, 1,6-dihydropyridazin, 1,2,3,4-tetrahydropyridazin-1-yl, 1,2,5,6-tetrahydropyridazin-1-yl, 1,2-dihydropyrimidin, 1,6-dihydropyrimidin, 1,2,3,4-tetrahydropyrimidin-1-yl, 1,2,5,6-tetrahydropyrimidin-1-yl, 1,2-dihydropyrazin-1-yl, 1,2,3,4-tetrahydropyrazin-1-yl, 1,2,5,6-tetrahydropyrazin-1-yl, pyrrol-1-yl, pyrazol-1-yl, imidazol-1-yl, [1,2,3]-1H-triazol-1-yl, [1,2,3]-2H-triazol-2-yl, [1,2,4]-1H-triazol-1-yl and [1,2,4]-4H-triazol-4-yl.







The remarks made below as to preferred embodiments of the variables (substituents) of the compounds of formula I are valid on their own as well as preferably in combination with each other, as well as in combination with the stereoisomers, salts, tautomers or N-oxides thereof.


The remarks made below concerning preferred embodiments of the variables further are valid on their own as well as preferably in combination with each other concerning the compounds of formulae I, where applicable, as well as concerning the uses and methods according to the invention and the composition according to the invention.


Preferred compounds according to the invention are compounds of formula I or a stereoisomer, salt or N-oxide thereof, wherein the salt is an agriculturally suitable salt. Further preferred compounds according to the invention are compounds of formula I or an N-oxide or salt thereof, especially an agriculturally suitable salt. Particularly preferred compounds according to the invention are compounds of formula I or a salt thereof, especially an agriculturally suitable salt thereof.


According to one embodiment of the invention the variable X in the compounds of formula I is N.


According to another embodiment of the invention the variable X in the compounds of formula I is CR2.


Preferred compounds according to the invention are compounds of formula I, wherein R1 is selected from the group consisting of cyano, halogen, nitro, C1-C6-alkyl, C3-C6-cycloalkyl, C2-C6-alkenyl, C2-C6-alkynyl, C1-C6-haloalkyl, C1-C6-alkoxy, C1-C4-alkoxy-C1-C4-alkyl, C1-C4-haloalkoxy-C1-C4-alkyl, C1-C4-alkoxy-C1-C4-alkoxy-Z1, C1-C4-alkylthio-C1-C4-alkyl, C1-C4-alkylthio-C1-C4-alkylthio-Z1, C2-C6-alkenyloxy, C2-C6-alkynyloxy, C1-C6-haloalkoxy, C1-C4-haloalkoxy-C1-C4-alkoxy and R1b—S(O)k, where Z1 is as defined in claim 1, where k is 0, 1 or 2 and where R1b is selected from C1-C4-alkyl and C1-C4-haloalkyl.


In a more preferred embodiment, in the compound of formula I, R1 is selected from the group consisting of halogen, cyano, nitro, C1-C4-alkyl, C3-C6-cycloalkyl, C1-C4-haloalkyl, C1-C4-alkoxy-C1-C4-alkyl, C1-C4-haloalkoxy-C1-C4-alkyl, C1-C4-alkoxy-C1-C4-alkoxy-C1-C4-alkyl, C1-C4-alkylthio-C1-C4-alkyl, C1-C4-alkylthio-C1-C4-alkylthio-C1-C4-alkyl, C1-C4-alkoxy, C1-C4-haloalkoxy, C3-C4-alkenyloxy, C3-C4-alkynyloxy, C1-C4-alkoxy-C1-C4-alkoxy, C1-C4-haloalkoxy-C1-C4-alkoxy, C1-C4-alkyl-S(O)k and C1-C4-haloalkyl-S(O)k, where k is 0 or 2.


In a highly preferred embodiment, in the compound of formula I, R1 is selected from the group consisting of halogen, nitro, C1-C4-alkyl, C3-C6-cycloalkyl, C1-C4-haloalkyl, C1-C4-alkoxy-C1-C4-alkyl, C1-C4-alkoxy-C1-C4-alkoxy-C1-C4-alkyl, C1-C4-alkoxy, C1-C4-haloalkoxy, C1-C4-alkylthio, C1-C4-haloalkylthio and C1-C4-alkylsulfonyl.


In one preferred embodiment of the present invention, X as used in the context of formula I is N (nitrogen).


In an alternative group of embodiments of the present invention, where X is CR2, the variable R2 is hydrogen.


In another group of embodiments of the invention, where X is CR2, the variable R2 of the compounds of formula I has any one of the meanings given above for R2 with the exception of hydrogen.


According to a preferred embodiment of the invention the variable R2 is 5- or 6-membered heterocyclyl, where heterocyclyl is a saturated, partially unsaturated or aromatic heterocyclic radical, which contains as a ring member 1 heteroatom selected from the group consisting of O, N and S and 0, 1, 2 or 3 further nitrogen atoms, where heterocyclyl is unsubstituted or carries 1, 2 or 3 radicals R21 which are identical or different.


According to an even more preferred embodiment of the invention, the variable R2 is 5- or 6-membered heterocyclyl selected from the group consisting of isoxazolinyl, 1,2-dihydrotetrazolonyl, 1,4-dihydrotetrazolonyl, tetrahydrofuryl, dioxolanyl, piperidinyl, morpholinyl, piperazinyl, isoxazolyl, pyrazolyl, thiazolyl, oxazolyl, furyl, pyridinyl, pyrimidinyl and pyrazinyl, where heterocyclyl is unsubstituted or carries 1, 2 or 3 radicals R21 which are identical or different and selected from the group consisting of C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy, C1-C4-alkoxy-C1-C4-alkyl and C1-C4-alkylthio-C1-C4-alkyl.


According to a particular embodiment of the invention the variable R2 is selected from the group consisting of hydrogen, halogen, C1-C6-alkyl, C3-C6-cycloalkyl-C1-C4-alkoxy, C1-C4-alkoxy-C1-C4-alkyl, C1-C4-haloalkoxy-C1-C4-alkyl, C2-C6-alkenyl, C2-C6-alkynyl, C1-C4-alkoxy, C1-C4-haloalkoxy, C3-C6-alkenyloxy, C3-C6-alkynyloxy, C3-C6-haloalkenyloxy, C3-C6-haloalkynyloxy, C1-C4-alkoxy-C1-C4-alkoxy, C1-C4-alkoxycarbonyl, C1-C4-alkyl-S(O)k and C1-C4-haloalkyl-S(O)k, where k is 0, 1 or 2, N(C1-C4-alkyl)SO2(C1-C4-alkyl), isoxazolyl and isoxazolinyl, where the last two mentioned radicals may be unsubstituted or carry 1 or 2 radicals selected from halogen and C1-C4-alkyl.


In another particular embodiment of the invention, the variable R2 in formula I is




embedded image


where


R26 is selected from the group consisting of methyl, ethyl and methoxyethyl,


R27 is selected from the group consisting of hydrogen, cyano and trifluoroacetyl,


t is 0 or 1;


or




embedded image


where


R28 is ethyl and R29 is ethyl, or


R28 and R29 together are —(CH2)5— or —(CH2)2—O—(CH2)2—.


According to a more preferred embodiment of the invention the variable R2 in the compounds of formula I is a radical of the following formula:




embedded image


in which # denotes the bond through which the group R2 is attached and:

  • RP1 is hydrogen or halogen, preferably hydrogen, Cl, Br or F, and in particular H or F;
  • RP2 is hydrogen, halogen or C1-C2-alkoxy, preferably hydrogen, Cl, Br, F, OCH3 or OCH2CH3, and in particular H, F, Cl or OCH3; and
  • RP3 is hydrogen, halogen, C1-C2-alkyl, C1-C2-haloalkyl, C1-C2-alkoxy, C1-C2-alkoxy-C1-C2-alkoxy, preferably hydrogen, Cl, Br, F, CH3, C2H5, CF3, CHF2, CH2F, CCl2F, CF2Cl, CH2CF3, CH2CHF2, CF2CF3, OCH3, OCH2CH3, OCH2OCH3, OCH2CH2OCH2CH3, OCH2OCH2CH3 or OCH2CH2OCH3, and in particular is H, F, Cl, CH3, CF3, OCH3, OCH2CH3, OCH2OCH3 or OCH2CH2OCH3.


According to a particular embodiment of the invention the variable R2 in the compounds of formula I is phenyl which is unsubstituted or carries one radical R21, where R21 is preferably attached to position 4 of the phenyl group and is as defined above and in particular selected from C1-C2-alkyl, C1-C2-alkoxy, C1-C2-haloalkyl and C1-C2-alkoxy-C1-C2-alkoxy, preferably form CH3, C2H5, OCH3, OC2H5, CHF2, CF3, OCH2OCH3 and OCH2CH2OCH3, and specifically from OCH3 and OC2H5.


According to a preferred embodiment of the invention the variable R2 in the compounds of formula I is selected from the group consisting of hydrogen, halogen, C1-C6-alkyl, C1-C4-alkoxy-C1-C4-alkyl, C1-C4-haloalkoxy-C1-C4-alkyl, C2-C6-alkenyl, C2-C6-alkynyl, C1-C4-alkoxy, C1-C4-haloalkoxy, C3-C6-alkenyloxy, C3-C6-alkynyloxy, C3-C6-haloalkenyloxy, C3-C6-haloalkynyloxy, C1-C4-alkoxycarbonyl, C1-C4-alkyl-S(O)k and C1-C4-haloalkyl-S(O)k, where k is 0, 1 or 2, isoxazolyl and isoxazolinyl, where the last two mentioned radicals may be unsubstituted or carry 1 or 2 radicals selected from halogen and C1-C4-alkyl.


According to another preferred embodiment of the invention the variable R2 in the compounds of formula I is selected from the group consisting of halogen, C1-C6-alkyl, C1-C4-alkoxy-C1-C4-alkyl, C1-C4-haloalkoxy-C1-C4-alkyl, C2-C6-alkenyl, C2-C6-alkynyl, C1-C4-alkoxy, C1-C4-haloalkoxy, C3-C6-alkenyloxy, C3-C6-alkynyloxy, C3-C6-haloalkenyloxy, C3-C6-haloalkynyloxy, C1-C4-alkoxycarbonyl, C1-C4-alkyl-S(O)k and C1-C4-haloalkyl-S(O)k, where k is 0, 1 or 2, isoxazolyl and isoxazolinyl, where the last two mentioned radicals may be unsubstituted or carry 1 or 2 radicals selected from halogen and C1-C4-alkyl.


According to a more preferred embodiment of the invention the variable R2 in the compounds of formula I is selected from C2-C4-alkenyl, C2-C4-alkynyl, C1-C4-alkoxy, C1-C2-haloalkoxy-C1-C2-alkyl, C3-C4-alkenyloxy, C3-C4-alkynyloxy, C1-C4-alkoxycarbonyl and C1-C4-alkyl-S(O2), and in particular from CH═CH2, CH═CHCH3, CH2OCH2CF3, OC2H5, OCH2CH═CH2, OCH2C≡CH, C(O)OCH3, C(O)OC2H5, SO2CH3, SO2C2H5 and SO2CH(CH3)2.


According to a specifically preferred embodiment of the invention the variable R2 in the compounds of formula I is selected from the group consisting of hydrogen, 4,5-dihydroisoxazol-3-yl, which is unsubstituted or substituted in position 5 with CH3, CH2F or CHF2, 4,5-dihydroisoxazol-5-yl, which is unsubstituted or substituted in position 3 with CH3, OCH3, CH2OCH3, CH2SCH3, 1-methyl-5-oxo-1,5-dihydrotetrazol-2-yl, 4-methyl-5-oxo-4,5-dihydrotetrazol-1-yl, morpholin-4-yl, isoxazol-3-yl, 5-methyl-isoxazol-3-yl, isoxazol-5-yl, 3-methyl-isoxazol-5-yl, 1-methyl-1H-pyrazol-3-yl, 2-methyl-2H-pyrazol-3-yl, thiazol-2-yl, 4-CH3-phenyl, 4-C2H5-phenyl, 4-OCH3-phenyl, 4-OC2H5-phenyl, 4-CHF2-phenyl, 4-CF3-phenyl, 4-OCH2OCH3-phenyl, 4-OCH2CH2OCH3-phenyl, CH═CH2, CH═CHCH3, CH2OCH2CF3, OC2H5, OCH2CH═CH2, OCH2C═CH, C(O)OCH3, C(O)OC2H5, SO2CH3, SO2C2H5 and SO2CH(CH3)2, in particular selected from hydrogen, halogen, methyl, CH2OCH2CF3, methylsulfonyl, ethylsulfonyl, methylsulfanyl, ethylsulfanyl, 3-isoxazolinyl, 5-methyl-3-isoxazolinyl, 5-isoxazolinyl, 3-methyl-5-isoxazolinyl, 3-isoxazolyl, 5-methyl-3-isoxazolyl, 5-isoxazolyl and 3-methyl-5-isoxazolyl, and specifically selected from hydrogen, chlorine, methylsulfonyl, methylsulfanyl, CH2OCH2CF3, 3-isoxazolinyl, 5-methyl-3-isoxazolinyl, 3-methyl-5-isoxazolinyl, 3-isoxazolyl, 5-methyl-3-isoxazolyl and 3-methyl-5-isoxazolyl.


In a highly preferred embodiment, R2 is selected from the group consisting of hydrogen, halogen, C1-C4-alkyl, C1-C4-alkoxy, C1-C4-haloalkoxy, C3-C6-cycloalkyl-C1-C2-alkoxy, C1-C2-alkoxy-C1-C2-alkyl, C1-C2-haloalkoxy-C1-C2-alkyl, C1-C2-alkoxy-C1-C2-alkoxy, C1-C4-alkyl-S(O)k, where k is 0, 1 or 2, N(C1-C4-alkyl)SO2(C1-C4-alkyl), isoxazolyl and isoxazolinyl, where the last two mentioned radicals may be unsubstituted or carry 1 or 2 radicals selected from halogen and C1-C4-alkyl.


In a particularly preferred embodiment, R2 in formula I is selected from the group consisting of hydrogen, chlorine, fluorine, methyl, methoxy, ethoxy, OCH2(cyclo-C3H5), OCHF2, OCH2CF3, OCH2CH2OCH3, methoxymethyl, CH2OCH2CF3, methylsulfonyl, ethylsulfonyl, methylsulfinyl, ethylsulfinyl, methylsulfanyl, ethylsulfanyl, NCH3SO2CH3, 3-isoxazolinyl, 5-methyl-3-isoxazolinyl, 5-isoxazolinyl, 3-methyl-5-isoxazolinyl, 3-isoxazolyl, 5-methyl-3-isoxazolyl, 5-isoxazolyl and 3-methyl-5-isoxazolyl, in particular selected from the group consisting of hydrogen, chlorine, fluorine, methyl, CH2OCH2CF3, methylsulfonyl, ethylsulfonyl, methylsulfanyl, ethylsulfanyl, 3-isoxazolinyl, 5-methyl-3-isoxazolinyl, 5-isoxazolinyl, 3-methyl-5-isoxazolinyl, 3-isoxazolyl, 5-methyl-3-isoxazolyl, 5-isoxazolyl and 3-methyl-5-isoxazolyl.


Preferred compounds according to the invention are compounds of formula I, wherein R3 is selected from the group consisting of hydrogen, halogen, cyano, nitro, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy, C1-C4-haloalkoxy, C2-C4-alkenyl, C2-C4-alkynyl, C3-C4-alkenyloxy, C3-C4-alkynyloxy or R2b—S(O)k, where k is 0, 1 or 2 and where R2b is selected from C1-C4-alkyl and C1-C4-haloalkyl.


More preferably, R3 is selected from R3 is selected from the group consisting of hydrogen, halogen, cyano, nitro, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy, C1-C4-haloalkoxy, C1-C4-alkylthio, C1-C4-haloalkylthio, C1-C4-alkyl-S(O)2 and C1-C4-haloalkyl-S(O)2.


In particular, R3 is selected from the group consisting of chlorine, fluorine, CF3, SO2CH3, cyano, nitro, hydrogen and CH3.


Preferred compounds according to the invention are compounds of formula I, wherein R4 is selected from the group consisting of hydrogen, cyano, halogen, nitro, C1-C2-alkyl and C1-C2-haloalkyl, in particular from the group consisting of hydrogen, CHF2, CF3, CN, NO2, CH3 and halogen, and specifically from hydrogen, CHF2, CF3, CN, NO2, CH3, Cl, Br and F.


In particular, R4 is selected from the group consisting of hydrogen, CHF2, CF3, CN, NO2, CH3 and halogen.


Preferred compounds according to the invention are compounds of formula I, wherein R5 is selected from the group consisting of halogen, C1-C2-alkyl and C1-C2-haloalkyl, and in particular from the group consisting of CHF2, CF3 and halogen.


According to a particular embodiment of the invention R5 is selected from the group consisting of CHF2, CF3 and halogen.


According to a particular embodiment of the invention, R4 is hydrogen and R5 is chlorine or fluorine.


According to a preferred embodiment of the invention, R6 in the compounds formula I is selected from the group consisting of cyano, C1-C6-alkyl, C1-C6-cyano-alkyl, C1-C6-alkoxy, C2-C6-alkenyl, C2-C6-haloalkenyl, C2-C6-alkynyl, C2-C6-haloalkynyl, C1-C4-alkoxy-C1-C4-alkyl, C1-C4-haloalkoxy-C1-C4-alkyl, RbRbN—S(O)n—Z, RbO—S(O)n—Z, Rb—S(O)n—Z, Rd—C(═O)O—C1-C3-alkyl, Rd—O—C(═O)O—C1-C3-alkyl, RdO—C(═O)—C1-C3-alkyl, ReRfN—C(═O)—C1-C3-alkyl, phenyl-Z and where phenyl is unsubstituted or substituted by 1, 2, 3 or 4 groups R′, which are identical or different.


Preferred compounds according to the invention are compounds of formula I, wherein R6 is selected from the group consisting of C1-C4-alkyl, C2-C6-alkenyl, C2-C6-alkynyl, C1-C4-alkoxy-C1-C4-alkyl, C3-C7-cycloalkyl, C1-C4-haloalkyl, Rc—C(═O)—C1-C2-alkyl, RdO—C(═O)—C1-C2-alkyl, ReRfN—C(═O)—C1-C2-alkyl, Rk—C(═O)NH—C1-C2-alkyl and benzyl, where


Rc is C1-C4-alkyl or C1-C4-haloalkyl,


Rd is C1-C4-alkyl,


Re is hydrogen or C1-C4-alkyl,


Rf is hydrogen or C1-C4-alkyl, or


Re, Rf together with the nitrogen atom, to which they are bound may form a 5-, 6 or 7-membered, saturated N-bound heterocyclic radical, which may carry as a ring member a further heteroatom selected from O, S and N and which is unsubstituted or may carry 1, 2, 3 or 4 methyl groups,


Rk is C1-C4-alkyl.


Further preferred compounds according to the invention are compounds of formula I, wherein

    • R6 is selected from the group consisting of C1-C6-alkyl, C2-C6-alkenyl, C2-C6-alkynyl, C1-C4-alkoxy-C1-C4-alkyl, RdO—C(═O)—C1-C3-alkyl, phenyl-Z and where phenyl is unsubstituted or substituted by 1, 2, 3 or 4 groups R′, which are identical or different.


More preferred compounds according to the invention are compounds of formula I, wherein R6 is selected from the group consisting of cyano, C1-C6-alkyl, C1-C6-cyano-alkyl, C1-C6-alkoxy, C2-C6-alkenyl, C2-C6-haloalkenyl, C2-C6-alkynyl, C2-C6-haloalkynyl, C1-C4-alkoxy-C1-C4-alkyl, C1-C4-haloalkoxy-C1-C4-alkyl, RbRbN—S(O)n—Z, RbO—S(O)n—Z, Rb—S(O)n—Z, Rd—C(═O)O—C1-C3-alkyl, Rd—O—C(═O)O—C1-C3-alkyl, RdO—C(═O)—C1-C3-alkyl, ReRfN—C(═O)—C1-C3-alkyl, phenyl-Z and where phenyl is unsubstituted or substituted by 1, 2, 3 or 4 groups R′, which are identical or different.


Highly preferably, R6 is selected from the group consisting of C1-C6-alkyl, C2-C6-alkenyl, C2-C6-alkynyl, C1-C4-alkoxy-C1-C4-alkyl, RdO—C(═O)—C1-C3-alkyl, phenyl-Z and where phenyl is unsubstituted or substituted by 1, 2, 3 or 4 groups R′, which are identical or different.


Particularly, R6 is selected from the group consisting of methyl, ethyl, methoxymethyl, ethoxymethyl, prop-2-ynyl and methoxycarbonylmethyl;


According to one embodiment, preferred compounds according to the invention are compounds of formula I, wherein R7 is selected from the group consisting of hydrogen, C1-C4-alkyl, C2-C6-alkenyl, C2-C6-alkynyl, C1-C4-alkoxy-C1-C4-alkyl, C3-C7-cycloalkyl, C1-C4-haloalkyl, Rc—C(═O)—C1-C2-alkyl, RdO—C(═O)—C1-C2-alkyl, ReRfN—C(═O)—C1-C2-alkyl, Rk—C(═O)NH—C1-C2- alkyl and benzyl, where


Rc is C1-C4-alkyl or C1-C4-haloalkyl,


Rd is C1-C4-alkyl,


Re is hydrogen or C1-C4-alkyl,


Rf is hydrogen or C1-C4-alkyl, or


Re, Rf together with the nitrogen atom, to which they are bound may form a 5-, 6 or 7-membered, saturated N-bound heterocyclic radical, which may carry as a ring member a further heteroatom selected from O, S and N and which is unsubstituted or may carry 1, 2, 3 or 4 methyl groups,


Rk is C1-C4-alkyl.


According to a highly preferred embodiment, R7 is selected from the group consisting of C1-C4-alkyl, C3-C7-cycloalkyl, C1-C4-haloalkyl, C2-C6-alkenyl, C2-C6-alkynyl, C1-C4-alkoxy and C1-C4-alkoxy-C1-C4-alkyl.


Even more preferably R7 is selected from the group consisting of methyl, ethyl, propyl, methoxy, ethoxy, methoxymethyl, methoxyethyl and ethoxymethyl, in particular selected from the group consisting of methyl, ethyl and methoxy.


In this context, the variables R′, R11, R21, R22, R23, R24, R25, R26, R27, R28, Z, Z1, Z2, Z2a, Ra, Rb, R1b, R2b, Rc, R2c, Rd, R2d, Re, R2e, Rf, R2f, Rg, R2g, Rh, R2h, Rk, n and k, independently of each other, preferably have one of the following meanings:


R′, R11, R21 independently of each other are selected from halogen, C1-C4-alkyl, C3-C6-cycloalkyl, C3-C6-halocycloalkyl, C1-C4-haloalkyl, C1-C4-alkoxy, C1-C4-alkoxy-C1-C4-alkyl, C1-C4-alkylthio-C1-C4-alkyl, C1-C4-alkoxy-C1-C4-alkoxy and C1-C6-haloalkyloxy, more preferably from halogen, C1-C4-alkyl, C3-C6-cycloalkyl, C1-C4-haloalkyl and C1-C4-alkoxy.


More preferably R′, R11, R21 independently of each other are selected from the group consisting of halogen, C1-C4-alkyl, C3-C6-cycloalkyl, C1-C4-haloalkyl, C1-C4-alkoxy, C1-C4-alkoxy-C1-C4-alkyl, C1-C4-alkylthio-C1-C4-alkyl and C1-C4-alkoxy-C1-C4-alkoxy; in particular selected from halogen, C1-C4-alkyl, C1-C4-alkoxy, C1-C4-haloalkyl, C1-C4-alkoxy-C1-C4-alkyl and C1-C4-alkoxy-C1-C4-alkoxy; and specifically from Cl, F, Br, methyl, ethyl, methoxy and trifluoromethyl.


R22 is selected from the group consisting of hydrogen, C1-C6-alkyl, C1-C6-haloalkyl, C2-C6-alkenyl, C2-C6-haloalkenyl, C2-C6-alkynyl, C3-C6-haloalkynyl, C3-C6-cycloalkyl, C3-C6-cycloalkenyl, C3-C6-halocycloalkyl, C3-C6-cycloalkyl-C1-C6-alkyl, C1-C6-alkoxy-C1-C6-alkyl, C3-C6-cycloalkyl-C1-C6-alkoxy-C1-C6-alkyl, phenyl, phenyl-C1-C6-alkyl, heteroaryl, heteroaryl-C1-C6-alkyl, heterocyclyl, heterocyclyl-C1-C6-alkyl, phenyl-O—C1-C6-alkyl, heteroaryl-O—C1-C6-alkyl, heterocyclyl-O—C1-C6-alkyl, phenyl-N(R23)—C1-C6-alkyl, heteroaryl-N(R23)—C1-C6-alkyl, heterocyclyl-N(R23)—C1-C6-alkyl, phenyl-S(O)n—C1-C6-alkyl, heteroaryl-S(O)n—C1-C6-alkyl, heterocyclyl-S(O)n—C1-C6-alkyl, where the 15 aforementioned radicals are substituted by s residues selected from the group consisting of nitro, halogen, cyano, rhodano, C1-C6-alkyl, C1-C6-haloalkyl, C3-C6-cycloalkyl, C(O)OR23, C(O)N(R23)2, OR23, N(R23)2, S(O)nR24, S(O)2OR23, S(O)2N(R23)2 and R23O—C1-C6-alkyl, and where heterocyclyl bears 0, 1 or 2 oxo groups;


R23 is selected from the group consisting of hydrogen, C1-C6-alkyl, C1-C6-haloalkyl, C2-C6-alkenyl, C2-C6-alkynyl, C3-C6-cycloalkyl, C3-C6-cycloalkyl-C1-C6-alkyl and phenyl;


R24 is selected from the group consisting of C1-C6-alkyl, C1-C6-haloalkyl, C2-C6-alkenyl, C2-C6-alkynyl, C3-C6-cycloalkyl, C3-C6-cycloalkyl-C1-C6-alkyl and phenyl;


R25 is selected from the group consisting of C1-C6-alkyl, C1-C6-haloalkyl, C2-C6-alkenyl, C2-C6-haloalkenyl, C2-C6-alkynyl, C3-C6-haloalkynyl, C3-C6-cycloalkyl, C3-C6-cycloalkenyl, C3-C6-halocycloalkyl, C3-C6-cycloalkyl-C1-C6-alkyl, C1-C6-alkoxy-C1-C6-alkyl, C3-C6-cycloalkyl-C1-C6-alkoxy-C1-C6-alkyl, phenyl, phenyl-C1-C6-alkyl, heteroaryl, heteroaryl-C1-C6-alkyl, heterocyclyl, heterocyclyl-C1-C6-alkyl, phenyl-O—C1-C6-alkyl, heteroaryl-O—C1-C6-alkyl, heterocyclyl-O—C1-C6-alkyl, phenyl-N(R23)—C1-C6-alkyl, heteroaryl-N(R23)—C1-C6-alkyl, heterocyclyl-N(R23)—C1-C6-alkyl, phenyl-S(O)n—C1-C6-alkyl, heteroaryl-S(O)n—C1-C6-alkyl, heterocyclyl-S(O)n—C1-C6-alkyl, where the 15 aforementioned radicals are substituted by s residues selected from the group consisting of nitro, halogen, cyano, rhodano, C1-C6-alkyl, C1-C6-haloalkyl, C3-C6-cycloalkyl, C(O)OR23, C(O)N(R23)2, OR23, N(R23)2, S(O)nR24, S(O)2OR23, S(O)2N(R23)2 and R23O—C1-C6-alkyl, and where heterocyclyl bears 0, 1 or 2 oxo groups;


R26 is C1-C6-alkyl or C1-C4-alkoxy-C1-C4-alkyl;


R27 is selected from the group consisting of hydrogen, cyano and C1-C4-haloalkylcarbonyl;


R28, R29 independently of each other are C1-C6-alkyl, or


R28, R29 together with the sulfur atom, to which they are bound may form a 5- or 6-membered saturated ring, which may carry as a ring member 1 oxygen atom;


Z, Z1, Z2 independently of each other are selected from a covalent bond, methanediyl and ethanediyl, and in particular are a covalent bond.


Z2a is selected from a covalent bond, C1-C2-alkanediyl, O—C1-C2-alkanediyl, C1-C2-alkanediyl-O and C1-C2-alkanediyl-O—C1-C2-alkanediyl; more preferably from a covalent bond, methanediyl, ethanediyl, O-methanediyl, O-ethanediyl, methanediyl-O, and ethanediyl-O; and in particular from a covalent bond, methanediyl and ethanediyl.


Ra is selected from the group consisting of hydrogen, C1-C6-alkyl, C3-C7-cycloalkyl, C3-C7-cycloalkyl-C1-C4-alkyl, where the C3-C7-cycloalkyl groups in the two aforementioned radicals are unsubstituted or partially or completely halogenated, C1-C6-haloalkyl, C2-C6-alkenyl, C2-C6-haloalkenyl, C2-C6-alkynyl, C2-C6-haloalkynyl, C1-C4-alkoxy-C1-C4-alkyl, phenyl and benzyl, where phenyl and benzyl are unsubstituted or substituted by 1, 2, 3 or 4 groups, which are identical or different and selected from the group consisting of halogen, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy and C1-C4-haloalkoxy;


Rb, R1b, R2b independently of each other are selected from C1-C6-alkyl, C3-C7-cycloalkyl, C1-C6-haloalkyl, C2-C6-alkenyl, C2-C6-haloalkenyl, C2-C6-alkynyl, C2-C6-haloalkynyl, phenyl and heterocyclyl, where heterocyclyl is a 5- or 6-membered monocyclic saturated, partially unsaturated or aromatic heterocycle, which contains 1, 2 or 3 heteroatoms as ring members, which are selected from the group consisting of O, N and S, where phenyl and heterocyclyl are unsubstituted or substituted by 1, 2 or 3 groups, which are identical or different and selected from the group consisting of halogen, C1-C4-alkyl, C1-C2-haloalkyl and C1-C2-alkoxy.


More preferably Rb, R1b, R2b independently of each other are selected from the group consisting of C1-C4-alkyl, C2-C4-alkenyl, C2-C4-alkynyl, C1-C4-haloalkyl, C2-C4-haloalkenyl, C2-C4-haloalkynyl, C3-C6-cycloalkyl, phenyl and heterocyclyl, where heterocyclyl is a 5- or 6-membered monocyclic saturated, partially unsaturated or aromatic heterocycle, which contains 1, 2 or 3 heteroatoms as ring members, which are selected from the group consisting of O, N and S.


In particular, Rb, R1b, R2b independently of each other are selected from C1-C4-alkyl, C1-C4-haloalkyl, C2-C4-alkenyl, C2-C4-haloalkenyl, C2-C4-alkynyl, C3-C6-cycloalkyl, phenyl and heterocyclyl, where heterocyclyl is a 5- or 6-membered aromatic heterocyclic radical having 1 or 2 nitrogen atoms as ring members.


Rc, R2c, Rk independently of each other are selected from hydrogen, C1-C6-alkyl, C3-C7-cycloalkyl, which is unsubstituted or partly or completely halogenated, C1-C6-haloalkyl, C2-C6-alkenyl, C2-C6-haloalkenyl, C2-C6-alkynyl, C2-C6-haloalkynyl, C1-C4-alkoxy-C1-C4-alkyl, phenyl, benzyl and heterocyclyl, where heterocyclyl is a 5- or 6-membered monocyclic saturated, partially unsaturated or aromatic heterocycle, which contains 1, 2 or 3 heteroatoms as ring members, which are selected from the group consisting of O, N and S, where phenyl, benzyl and heterocyclyl are unsubstituted or substituted by 1, 2 or 3 groups, which are identical or different and selected from the group consisting of halogen, C1-C4-alkyl, C1-C4-haloalkyl and C1-C4-alkoxy.


More preferably Rc, R2c, Rk independently of each other are selected from hydrogen, C1-C4-alkyl, C1-C4-haloalkyl, C2—C-alkenyl, C2—C-haloalkenyl, C2—C-alkynyl, C3-C6-cycloalkyl, phenyl and heterocyclyl, where heterocyclyl is a 5- or 6-membered monocyclic saturated, partially unsaturated or aromatic heterocycle, which contains 1, 2 or 3 heteroatoms as ring members, which are selected from the group consisting of O, N and S.


In particular, Rc, R2c, Rk independently of each other are selected from hydrogen, C1-C4-alkyl, C1-C4-haloalkyl, C2-C4-alkenyl, C2-C4-haloalkenyl, C3-C6-cycloalkyl, phenyl and heterocyclyl, where heterocyclyl is a 5- or 6-membered aromatic heterocyclic radical having 1 or 2 nitrogen atoms as ring members.


Rd, R2d independently of each other are selected from C1-C6-alkyl, C3-C7-cycloalkyl, which is unsubstituted or partly or completely halogenated, C1-C6-haloalkyl, C2-C6-alkenyl, C2-C6-haloalkenyl, C2-C6-alkynyl, C2-C6-haloalkynyl, C1-C4-alkoxy-C1-C4-alkyl, phenyl and benzyl.


More preferably Rd, R2d independently of each other are selected from C1-C6-alkyl, C1-C6-haloalkyl, C2-C6-alkenyl, C2-C6-haloalkenyl, C2-C6-alkynyl, C1-C4-alkoxy-C1-C4-alkyl and C3-C7-cycloalkyl, which is unsubstituted or partly or completely halogenated, and in particular selected from C1-C4-alkyl, C1-C4-haloalkyl, C2-C4-alkenyl, C2-C4-haloalkenyl, C2-C4-alkynyl and C3-C6-cycloalkyl.


Re, Rf, R2e, R2f independently of each other are selected from the group consisting of hydrogen, C1-C6-alkyl, C3-C7-cycloalkyl, which is unsubstituted or partially or completely halogenated, C1-C6-haloalkyl, C2-C6-alkenyl, C2-C6-haloalkenyl, C1-C4-alkoxy-C1-C4-alkyl, phenyl and benzyl, where phenyl and benzyl are unsubstituted or substituted by 1, 2 or 3 groups, which are identical or different and selected from the group consisting of halogen, C1-C4-alkyl, C1-C4-haloalkyl and C1-C4-alkoxy, or Re and Rf or R2e and R2f together with the nitrogen atom, to which they are bound may form a 5-, 6 or 7-membered, saturated or unsaturated N-bound heterocyclic radical, which may carry as a ring member a further heteroatom selected from O, S and N and which is unsubstituted or may carry 1, 2, 3 or 4 groups, which are identical or different and selected from the group consisting of halogen, C1-C4-alkyl, C1-C4-haloalkyl and C1-C4-alkoxy.


More preferably Re, Rf, R2e, R2f independently of each other are selected from hydrogen, C1-C6-alkyl, C1-C6-haloalkyl and benzyl, or Re and Rf or R2e and R2f together with the nitrogen atom, to which they are bound may form a 5- or 6-membered, saturated or unsaturated N-bound heterocyclic radical, which may carry as a ring member a further heteroatom selected from O, S and N and which is unsubstituted or may carry 1, 2 or 3 groups, which are identical or different and selected from the group consisting of halogen, C1-C4-alkyl and C1-C4-haloalkyl.


In particular, Re, Rf, R2e, R2f independently of each other are selected from hydrogen and C1-C4-alkyl, or Re and Rf or R2e and R2f together with the nitrogen atom, to which they are bound may form a 5- or 6-membered, saturated N-bound heterocyclic radical, which may carry as a ring member a further heteroatom selected from O, S and N and which is unsubstituted or may carry 1, 2 or 3 methyl groups.


Rg, R2g independently of each other are selected from hydrogen, C1-C6-alkyl, C3-C7-cycloalkyl, which is unsubstituted or partly or completely halogenated, C1-C6-haloalkyl, C2-C6-alkenyl, C2-C6-haloalkenyl, C2-C6-alkynyl, C2-C6-haloalkynyl, C1-C4-alkoxy-C1-C4-alkyl, C1-C4-alkylsulfonyl, C1-C4-alkylcarbonyl, phenyl and benzyl.


More preferably Rg, R2g independently of each other are selected from hydrogen, C1-C6-alkyl, C1-C6-haloalkyl, C2-C6-alkenyl, C2-C6-haloalkenyl, benzyl, C1-C4-alkoxy-C1-C4-alkyl and C3-C7-cycloalkyl, which is unsubstituted or partly or completely halogenated, and in particular selected from hydrogen, C1-C4-alkyl, C1-C4-haloalkyl, C2-C4-alkenyl, C2-C4-haloalkenyl, benzyl and C3-C6-cycloalkyl.


Rh, R2h independently of each other are selected from hydrogen, C1-C6-alkyl, C3-C7-cycloalkyl, which is unsubstituted or partly or completely halogenated, C1-C6-haloalkyl, C2-C6-alkenyl, C2-C6-haloalkenyl, C2-C6-alkynyl, C2-C6-haloalkynyl, C1-C4-alkoxy-C1-C4-alkyl, C1-C4-alkylsulfonyl, C1-C4-alkylcarbonyl, phenyl, benzyl and a radical C(═O)—Rk, where Rk is H, C1-C4-alkyl, C1-C4-haloalkyl or phenyl.


More preferably Rh, R2h independently of each other are selected from hydrogen, C1-C6-alkyl, C1-C6-haloalkyl, C2-C6-alkenyl, C2-C6-haloalkenyl, benzyl, C1-C4-alkoxy-C1-C4-alkyl and C3-C7-cycloalkyl, which is unsubstituted or partly or completely halogenated, and in particular selected from hydrogen, C1-C4-alkyl, C1-C4-haloalkyl, C2-C4-alkenyl, C2-C4-haloalkenyl, benzyl and C3-C6-cycloalkyl; or


Rg and Rh or R2g and R2h together with the nitrogen atom, to which they are bound may form a 5-, 6 or 7-membered, saturated or unsaturated N-bound heterocyclic radical, which may carry as a ring member a further heteroatom selected from O, S and N and which is unsubstituted or may carry 1, 2, 3 or 4 groups, which are identical or different and selected from the group consisting of ═O, halogen, C1-C4-alkyl and C1-C4-haloalkyl and C1-C4-alkoxy;


more preferably Rg and Rh or R2g and R2h together with the nitrogen atom, to which they are bound may form a 5- or 6-membered, saturated or unsaturated N-bound heterocyclic radical, which may carry as a ring member a further heteroatom selected from O, S and N and which is unsubstituted or may carry 1, 2 or 3 groups, which are identical or different and selected from the group consisting of halogen, C1-C4-alkyl and C1-C4-haloalkyl; and in particular, Rg and Rh or R2g and R2h together with the nitrogen atom, to which they are bound may form a 5- or 6-membered, saturated N-bound heterocyclic radical, which may carry as a ring member a further heteroatom selected from O, S and N and which is unsubstituted or may carry 1, 2 or 3 methyl groups.


n and k independently of each other are 0 or 2, and in particular 2.


s is 0, 1, 2 or 3.


t is 0 or 1.


Particularly preferably, the variables have the following meanings:


R22 is selected from hydrogen, C1-C6-alkyl, C1-C6-haloalkyl, C3-C6-cycloalkyl, C3-C6-halocycloalkyl, C3-C6-cycloalkyl-C1-C6-alkyl, C1-C6-alkoxy-C1-C6-alkyl, C3-C6-cycloalkyl-C1-C6-alkoxy-C1-C6-alkyl, phenyl, phenyl-C1-C6-alkyl, heteroaryl, heteroaryl-C1-C6-alkyl, heterocyclyl, heterocyclyl-C1-C6-alkyl, phenyl-O—C1-C6-alkyl, heteroaryl-O—C1-C6-alkyl, heterocyclyl-O—C1-C6-alkyl, where the 9 aforementioned radicals are substituted by s residues selected from the group consisting of nitro, halogen, C1-C6-alkyl, C1-C6-haloalkyl, C(O)OR23, C(O)N(R23)2, OR23, N(R23)2, S(O)nR24 and R23O—C1-C6-alkyl, and where heterocyclyl bears 0, 1 or 2 oxo groups.


More preferably R22 is selected from hydrogen, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy-C1-C4-alkyl, C3-C6-cycloalkyl, C3-C6-cycloalkyl-C1-C2-alkyl, phenyl and phenyl-C1-C2-alkyl. In particular, R22 is hydrogen or C1-C4-alkyl.


R23 is selected from hydrogen, C1-C4-alkyl, C1-C4-haloalkyl and C3-C6-cycloalkyl. In particular, R23 is hydrogen or C1-C4-alkyl.


R24 is selected from C1-C4-alkyl, C1-C4-haloalkyl and C3-C6-cycloalkyl. In particular, R24 is C1-C4-alkyl.


R25 is selected from C1-C6-alkyl, C1-C6-haloalkyl, C3-C6-cycloalkyl, C3-C6-halocycloalkyl, C3-C6-cycloalkyl-C1-C6-alkyl, C1-C6-alkoxy-C1-C6-alkyl, C3-C6-cycloalkyl-C1-C6-alkoxy-C1-C6-alkyl, phenyl, phenyl-C1-C6-alkyl, heteroaryl, heteroaryl-C1-C6-alkyl, heterocyclyl, heterocyclyl-C1-C6-alkyl, phenyl-O—C1-C6-alkyl, heteroaryl-O—C1-C6-alkyl, heterocyclyl-O—C1-C6-alkyl, where the 9 aforementioned radicals are substituted by s residues selected from the group consisting of nitro, halogen, C1-C6-alkyl, C1-C6-haloalkyl, C(O)OR23, C(O)N(R23)2, OR23, N(R23)2, S(O)nR24 and R23O—C1-C6-alkyl, and where heterocyclyl bears 0, 1 or 2 oxo groups.


More preferably R25 is selected from C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy-C1-C4-alkyl, C3-C6-cycloalkyl, C3-C6-cycloalkyl-C1-C2-alkyl, phenyl and phenyl-C1-C2-alkyl. In particular, R25 is C1-C4-alkyl.


R26 is selected from the group consisting of methyl, ethyl and methoxyethyl.


R27 is selected from the group consisting of hydrogen, cyano and trifluoroacetyl.


R28 is ethyl and R29 is ethyl, or R28 and R29 together are —(CH2)5— or —(CH2)2—O—(CH2)2—.


s is 0, 1, 2 or 3. In one particular embodiment of the invention, s is 0. In another particular embodiment of the invention, s is 1, 2 or 3.


t is 0 or 1. In one particular embodiment of the invention, t is 0. In another particular embodiment of the invention, t is 1.


According to one embodiment, preferred compounds according to the invention are compounds of formula I, where

    • R1 is selected from the group consisting of halogen, nitro, C1-C4-alkyl, C3-C6-cycloalkyl, C1-C4-haloalkyl, C1-C4-alkoxy-C1-C4-alkyl, C1-C4-alkoxy-C1-C4-alkoxy-C1-C4-alkyl, C1-C4-alkoxy, C1-C4-haloalkoxy, C1-C4-alkylthio, C1-C4-haloalkylthio and C1-C4-alkylsulfonyl; and
    • R3 is selected from the group consisting of hydrogen, halogen, cyano, nitro, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy, C1-C4-haloalkoxy, C1-C4-alkylthio, C1-C4-haloalkylthio and C1-C4-alkylsulfonyl.


According to an even more preferred embodiment, compounds according to the invention are compounds of formula I, where X is CR2 and the variables R1, R2, R3, R4, R5, R6 and R7 have the following meanings:

    • R1 is selected from the group consisting of halogen, nitro, cyclopropyl, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy-C1-C4-alkyl, C1-C4-alkoxy-C1-C4-alkoxy-C1-C4-alkyl and C1-C4-alkyl-S(O)2;
    • R2 is selected from the group consisting of hydrogen, halogen, C1-C4-alkyl, C1-C4-alkoxy, C1-C4-haloalkoxy, C3-C6-cycloalkyl-C1-C2-alkoxy, C1-C2-alkoxy-C1-C2-alkyl, C1-C2-haloalkoxy-C1-C2-alkyl, C1-C2-alkoxy-C1-C2-alkoxy, C1-C4-alkyl-S(O)k, where k is 0, 1 or 2, N(C1-C4-alkyl)SO2(C1-C4-alkyl), isoxazolyl and isoxazolinyl, where the last two mentioned radicals may be unsubstituted or carry 1 or 2 radicals selected from halogen and C1-C4-alkyl;
    • R3 is selected from the group consisting of hydrogen, halogen, cyano, nitro, C1-C4-alkyl, C1-C4-haloalkyl and C1-C4-alkyl-S(O)2;
    • R4 is selected from the group consisting of hydrogen, cyano, methyl and halogen;
    • R5 is selected from the group consisting of halogen, CHF2 and CF3;
    • R6 is selected from the group consisting of C1-C4-alkyl, C1-C2-alkoxy-C1-C2-alkyl, C2-C4-alkenyl, C2-C4-alkynyl, C1-C4-alkoxycarbonyl-C1-C4-alkyl and phenyl-C1-C2-alkyl;
    • R7 is selected from the group consisting of C1-C4-alkyl, C1-C4-alkoxy and C1-C2-alkoxy-C1-C2-alkyl.


In a preferred embodiment, X is CR2 and the variables R1, R2, R3, R4, R5, R6 and R7 have the following meanings:

    • R1 is selected from the group consisting of chlorine, nitro, methyl, cyclopropyl, trifluoromethyl, methoxymethyl, CH2OCH2CH2OOH3 and methylsulfonyl;
    • R2 is selected from the group consisting of hydrogen, chlorine, fluorine, methyl, methoxy, ethoxy, OCH2(cyclo-C3H5), OCHF2, OCH2CF3, OCH2CH2OCH3, methoxymethyl, CH2OCH2CF3, methylsulfonyl, ethylsulfonyl, methylsulfinyl, ethylsulfinyl, methylsulfanyl, ethylsulfanyl, NCH3SO2CH3, 3-isoxazolinyl, 5-methyl-3-isoxazolinyl, 5-isoxazolinyl, 3-methyl-5-isoxazolinyl, 3-isoxazolyl, 5-methyl-3-isoxazolyl, 5-isoxazolyl and 3-methyl-5-isoxazolyl;
    • R3 is selected from the group consisting of hydrogen, fluorine, chlorine, bromine, cyano, nitro, methyl, trifluoromethyl and methylsulfonyl;
    • R4 is selected from the group consisting of hydrogen, cyano, methyl, chlorine and fluorine;
    • R5 is selected from the group consisting of chlorine and fluorine;
    • R6 is selected from the group consisting of methyl, ethyl, methoxymethyl, ethoxymethyl, prop-2-enyl, prop-2-ynyl, methoxycarbonylmethyl and benzyl;
    • R7 is selected from the group consisting of methyl, ethyl, propyl, methoxy, ethoxy, methoxymethyl, methoxyethyl and ethoxymethyl.


In another preferred embodiment of the present invention, X is N and the variables R1, R3, R4, R5, R6 and R7 have the following meanings:

    • R1 is selected from the group consisting of halogen, nitro, cyclopropyl, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy-C1-C4-alkyl, C1-C4-alkoxy-C1-C4-alkoxy-C1-C4-alkyl and C1-C4-alkyl-S(O)2;
    • R3 is selected from the group consisting of hydrogen, halogen, cyano, nitro, C1-C4-alkyl, C1-C4-haloalkyl and C1-C4-alkyl-S(O)2;
    • R4 is selected from the group consisting of hydrogen, cyano, methyl and halogen;
    • R5 is selected from the group consisting of halogen, CHF2 and CF3;
    • R6 is selected from the group consisting of C1-C4-alkyl, C1-C2-alkoxy-C1-C2-alkyl, C2-C4-alkenyl, C2-C4-alkynyl, C1-C4-alkoxycarbonyl-C1-C4-alkyl and phenyl-C1-C2-alkyl;
    • R7 is selected from the group consisting of C1-C4-alkyl, C1-C4-alkoxy and C1-C2-alkoxy-C1-C2-alkyl.


In a more preferred embodiment of the present invention, X is N and the variables R1, R3, R4, R5, R6 and R7 have the following meanings:

    • R1 is selected from the group consisting of chlorine, nitro, methyl, cyclopropyl, trifluoromethyl, methoxymethyl, CH2OCH2CH2OCH3 and methylsulfonyl;
    • R3 is selected from the group consisting of hydrogen, fluorine, chlorine, bromine, cyano, nitro, methyl, trifluoromethyl and methylsulfonyl;
    • R4 is selected from the group consisting of hydrogen, cyano, methyl, chlorine and fluorine;
    • R5 is selected from the group consisting of chlorine and fluorine;
    • R6 is selected from the group consisting of methyl, ethyl, methoxymethyl, ethoxymethyl, prop-2-enyl, prop-2-ynyl, methoxycarbonylmethyl and benzyl;
    • R7 is selected from the group consisting of methyl, ethyl, propyl, methoxy, ethoxy, methoxymethyl, methoxyethyl and ethoxymethyl.


In another preferred embodiment of the present invention, X is CR2 and the variables R1, R2, R3, R4, R5, R6 and R7 have the following meanings:

    • R1 is selected from the group consisting of chlorine, nitro, methyl, cyclopropyl, trifluoromethyl, methoxymethyl, CH2OCH2CH2OOH3 and methylsulfonyl;
    • R2 is selected from the group consisting of hydrogen, chlorine, fluorine, methyl, CH2OCH2CF3, methylsulfonyl, ethylsulfonyl, methylsulfanyl, ethylsulfanyl, 3-isoxazolinyl, 5-methyl-3-isoxazolinyl, 5-isoxazolinyl, 3-methyl-5-isoxazolinyl, 3-isoxazolyl, 5-methyl-3-isoxazolyl, 5-isoxazolyl and 3-methyl-5-isoxazolyl;
    • R3 is selected from the group consisting of hydrogen, fluorine, chlorine, cyano, nitro, methyl, trifluoromethyl and methylsulfonyl;
    • R4 is selected from the group consisting of hydrogen, cyano, methyl, chlorine and fluorine;
    • R5 is selected from the group consisting of chlorine and fluorine;
    • R6 is selected from the group consisting of methyl, ethyl, methoxymethyl, ethoxymethyl, prop-2-ynyl and methoxycarbonylmethyl;
    • R7 is selected from the group consisting of methyl, ethyl and methoxy.


In a still further embodiment of the present invention, X is CR2 and the variable R3 are not hydrogen, in particular X is CR2 and the variables R2 and R3 are not hydrogen.


A second aspect of the present invention relates to a composition comprising at least one compound, an N-oxide or an agriculturally suitable salt thereof, according to the present invention and at least one auxiliary, which is customary for formulating crop protection compounds.


A further aspect of the present invention refers to the use of a compound, an N-oxide or an agriculturally suitable salt thereof, or a composition according to the present invention for controlling unwanted vegetation.


A still further aspect of the present invention relates to a method for controlling unwanted vegetation which comprises allowing a herbicidally effective amount of at least one compound, an N-oxide or an agriculturally suitable salt thereof, or a composition according to the present invention to act on plants, their seed and/or their habitat.


According to another preferred embodiment of the invention, where X is CR2, the variables R1, R2, R3, R4 and R5 together form one of the following substitution patterns on the phenyl ring of compounds of formula I, provided that position 1 is the attachment point of the phenyl ring to the remainder of the molecule:


2-Br-4,6-Cl2, 2,6-Cl2-4-CN, 2,4,6-Cl3, 2,6-Cl2-4-F, 2,6-Cl2-4-CF3, 2,6-Cl2-4-S(O)2CH3, 2-CF3-4-CN-6-Cl, 2-CF3-4,6-Cl2, 2-CF3-4-CF3-6-Cl, 2-CF3-4-S(O)2CH3-6-Cl, 2-CF3- 4-F-6-Cl, 2-CH3—CN-6-Cl, 2-CH3-4,6-Cl2, 2-CH3-4-CF3-6-Cl, 2-CH3-4-S(O)2CH3-6-Cl, 2-CH3-4-F-6-Cl, 2-S(O)2CH3-4-CN-6-Cl, 2-S(O)2CH3-4,6-Cl2, 2-S(O)2CH3-4-CF3-6-Cl, 2-S(O)2CH3-4-S(O)2CH3-6-Cl, 2-S(O)2CH3-4-F-6-Cl, 2-Cl-4-CN-6-F, 2-Cl-4-CF3-6-F, 2-Cl-4-S(O)2CH3-6-F, 2,4-Cl2-6-F, 2-Cl-4,6-F2, 2-CF3-4-CN-6-F, 2-CF3-4-CF3-6-F, 2-CF3-4-S(O)2CH3-6-F, 2-CF3-4-Cl-6- F, 2-CF3-4,6-F2, 2-CH3-4-CN-6-F, 2-CH3-4-CF3-6-F, 2-CH3-4-S(O)2CH3-6-F, 2-CH3-4-Cl-6-F, 2-CH3-4,6-F2, 2-S(O)2CH3-4-CN-6-F, 2-S(O)2CH3-4-CF3-6-F, 2-S(O)2CH3-4-S(O)2CH3-6-F, 2-S(O)2CH3-4-Cl-6-F or 2-S(O)2CH3-4,6-F2.


According to another preferred embodiment of the invention the variables R1, R2, R3, R4 and R5 together form one of the following substitution patterns on the phenyl ring of compounds of formula I, provided that position 1 is the attachment point of the phenyl ring to the remainder of the molecule:


2,6-Cl2-3-(3-isoxazolinyl)-4-CN, 2,4,6-Cl3-3-(3-isoxazolinyl), 2,6-Cl2-3-(3-isoxazolinyl)-4-F, 2,6-Cl2-3-(3-isoxazolinyl)-4-CF3, 2,6-Cl2-3-(3-isoxazolinyl)-4-S(O)2CH3, 2-CF3-3-(3-isoxazolinyl)-4-CN-6-Cl, 2-CF3-3-(3-isoxazolinyl)-4,6-Cl2, 2-CF3-3-(3-isoxazolinyl)-4-CF3-6-Cl, 2-CF3-3-(3-isoxazolinyl)-4-S(O)2CH3-6-Cl, 2-CF3-3-(3-isoxazolinyl)-4-F-6-Cl, 2-CH3-3-(3-isoxazolinyl)-4-CN-6-Cl, 2-CH3-3-(3-isoxazolinyl)-4,6-Cl2, 2-CH3-3-(3-isoxazolinyl)-4-CF3-6-Cl, 2-CH3-3-(3-isoxazolinyl)-4-S(O)2CH3-6-Cl, 2-CH3-3-(3-isoxazolinyl)-4-F-6-Cl, 2-S(O)2CH3-3-(3-isoxazolinyl)-4-CN-6-Cl, 2-S(O)2CH3-3-(3-isoxazolinyl)-4,6-Cl2, 2-S(O)2CH3-3-(3-isoxazolinyl)-4-CF3-6-Cl, 2-S(O)2CH3-3-(3-isoxazolinyl)-4-S(O)2CH3-6-Cl, 2-S(O)2CH3-3-(3-isoxazolinyl)-4-F-6-Cl, 2-Cl-3-(3-isoxazolinyl)-4-CN-6-F, 2-Cl-3-(3-isoxazolinyl)-4-CF3-6-F, 2-Cl-3-(3-isoxazolinyl)-4-S(O)2CH3-6-F, 2,4-Cl2-3-(3-isoxazolinyl)-6-F, 2-Cl-3-(3-isoxazolinyl)-4,6-F2, 2-CF3-3-(3-isoxazolinyl)-4-CN-6-F, 2-CF3-3-(3-isoxazolinyl)-4-CF3-6-F, 2-CF3-3-(3-isoxazolinyl)-4-S(O)2CH3-6-F, 2-CF3-3- (3-isoxazolinyl)-4-Cl-6-F, 2-CF3-3-(3-isoxazolinyl)-4,6-F2, 2-CH3-3-(3-isoxazolinyl)-4-CN-6-F, 2-CH3-3-(3-isoxazolinyl)-4-CF3-6-F, 2-CH3-3-(3-isoxazolinyl)-4-S(O)2CH3-6-F, 2-CH3-3-(3-isoxazolinyl)-4-Cl-6-F, 2-CH3-3-(3-isoxazolinyl)-4,6-F2, 2-S(O)2CH3-3-(3-isoxazolinyl)-4-CN-6-F, 2-S(O)2CH3-3-(3-isoxazolinyl)-4-CF3-6-F, 2-S(O)2CH3-3-(3-isoxazolinyl)-4-S(O)2CH3-6-F, 2-S(O)2CH3-3-(3-isoxazolinyl)-4-Cl-6-F, 2-S(O)2CH3-3-(3-isoxazolinyl)-4,6-F2, 2,6-Cl2-3-(CH2—O—CH2CF3)-4-CN, 2,4,6-Cl3-3-(3-isoxazolinyl), 2,6-Cl2-3-(CH2—O—CH2CF3)-4-F, 2,6-Cl2-3- (CH2—O—CH2CF3)-4-CF3, 2,6-Cl2-3-(CH2—O—CH2CF3)-4-S(O)2CH3, 2-CF3-3-(CH2—O—CH2CF3)-4-CN-6-Cl, 2-CF3-3-(CH2—O—CH2CF3)-4,6-Cl2, 2-CF3-3-(CH2—O—CH2CF3)-4-CF3-6-Cl, 2-CF3-3-(CH2—O—CH2CF3)-4-S(O)2CH3-6-Cl, 2-CF3-3-(CH2—O—CH2CF3)-4-F-6-Cl, 2-CH3-3-(CH2—O—CH2CF3)-4-CN-6-Cl, 2-CH3-3-(CH2—O—CH2CF3)-4,6-Cl2, 2-CH3-3-(CH2—O—CH2CF3)-4-CF3-6-Cl, 2- CH3-3-(CH2—O—CH2CF3)-4-S(O)2CH3-6-Cl, 2-CH3-3-(CH2—O—CH2CF3)-4-F-6-Cl, 2-S(O)2CH3-3-(CH2—O—CH2CF3)-4-CN-6-Cl, 2-S(O)2CH3-3-(CH2—O—CH2CF3)-4,6-Cl2, 2-S(O)2CH3-3-(CH2—O—CH2CF3)-4-CF3-6-Cl, 2-S(O)2CH3-3-(CH2—O—CH2CF3)-4-S(O)2CH3-6-Cl, 2-S(O)2CH3-3-(CH2—O—CH2CF3)- 4-F-6-Cl, 2-Cl-3-(CH2—O—CH2CF3)-4-CN-6-F, 2-Cl-3-(CH2—O—CH2CF3)-4-CF3-6-F, 2-Cl-3-(CH2—O—CH2CF3)-4-S(O)2CH3-6-F, 2,4-Cl2-3-(CH2—O—CH2CF3)-6-F, 2-Cl-3-(CH2—O—CH2CF3)-4,6-F2, 2- CF3-3-(CH2—O—CH2CF3)-4-CN-6-F, 2-CF3-3-(CH2—O—CH2CF3)-4-CF3-6-F, 2-CF3-3-(CH2—O—CH2CF3)-4-S(O)2CH3-6-F, 2-CF3-3-(CH2—O—CH2CF3)-4-Cl-6-F, 2-CF3-3-(CH2—O—CH2CF3)-4,6-F2, 2-CH3- 3-(CH2—O—CH2CF3)-4-CN-6-F, 2-CH3-3-(CH2—O—CH2CF3)-4-CF3-6-F, 2-CH3-3-(CH2—O—CH2CF3)-4-S(O)2CH3-6-F, 2-CH3-3-(CH2—O—CH2CF3)-4-Cl-6-F, 2-CH3-3-(CH2—O—CH2CF3)-4,6- F2, 2-S(O)2CH3-3-(CH2—O—CH2CF3)-4-CN-6-F, 2-S(O)2CH3-3-(CH2—O—CH2CF3)-4-CF3-6- F, 2-S(O)2CH3-3-(CH2—O—CH2CF3)-4-S(O)2CH3-6-F, 2-S(O)2CH3-3-(CH2—O—CH2CF3)-4-Cl-6-F or 2- S(O)2CH3-3-(CH2—O—CH2CF3)-4,6-F2.


Examples of preferred compounds I.A, where X is N, are the individual compounds compiled in Tables 1 to 10 below. Moreover, the meanings mentioned below for the individual variables in the Tables are per se, independently of the combination in which they are mentioned, a particularly preferred embodiment of the substituents in question.




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Table 1: compounds of formula I.A (I.A-1.1-I.A-1.2880) in which R4 is H and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 2: compounds of formula I.A (I.A-2.1-I.A-2.2880) in which R4 is H and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 3: compounds of formula I.A (I.A-3.1-I.A-3.2880) in which R4 is F and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 4: compounds of formula I.A (I.A-4.1-I.A-4.2880) in which R4 is F and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 5: compounds of formula I.A (I.A-5.1-I.A-5.2880) in which R4 is Cl and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 6: compounds of formula I.A (I.A-6.1-I.A-6.2880) in which R4 is Cl and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 7: compounds of formula I.A (I.A-7.1-I.A-7.2880) in which R4 is CN and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 8: compounds of formula I.A (I.A-8.1-I.A-8.2880) in which R4 is CN and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 9: Compounds of formula I.A (I.A-9.1-I.A-9.2880) in which R4 is CH3 and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 10: compounds of formula I.A (I.A-10.1-I.A-10.2880) in which R4 is CH3 and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;














TABLE A







R1
R3
R6
R7




















A-1
Cl
H
CH3
CH3


A-2
Cl
H
CH3
CH2CH3


A-3
Cl
H
CH3
CH2CH2CH3


A-4
Cl
H
CH3
CH2CH2OCH3


A-5
Cl
H
CH3
OCH3


A-6
Cl
H
CH2CH3
CH3


A-7
Cl
H
CH2CH3
CH2CH3


A-8
Cl
H
CH2CH3
CH2CH2CH3


A-9
Cl
H
CH2CH3
CH2CH2OCH3


A-10
Cl
H
CH2CH3
OCH3


A-11
Cl
H
CH2OCH3
CH3


A-12
Cl
H
CH2OCH3
CH2CH3


A-13
Cl
H
CH2OCH3
CH2CH2CH3


A-14
Cl
H
CH2OCH3
CH2CH2OCH3


A-15
Cl
H
CH2OCH3
OCH3


A-16
Cl
H
CH2OCH2CH3
CH3


A-17
Cl
H
CH2OCH2CH3
CH2CH3


A-18
Cl
H
CH2OCH2CH3
CH2CH2CH3


A-19
Cl
H
CH2OCH2CH3
CH2CH2OCH3


A-20
Cl
H
CH2OCH2CH3
OCH3


A-21
Cl
H
CH2(CO)OCH3
CH3


A-22
Cl
H
CH2(CO)OCH3
CH2CH3


A-23
Cl
H
CH2(CO)OCH3
CH2CH2CH3


A-24
Cl
H
CH2(CO)OCH3
CH2CH2OCH3


A-25
Cl
H
CH2(CO)OCH3
OCH3


A-26
Cl
H
CH2CHCH2
CH3


A-27
Cl
H
CH2CHCH2
CH2CH3


A-28
Cl
H
CH2CHCH2
CH2CH2CH3


A-29
Cl
H
CH2CHCH2
CH2CH2OCH3


A-30
Cl
H
CH2CHCH2
OCH3


A-31
Cl
H
CH2CCH
CH3


A-32
Cl
H
CH2CCH
CH2CH3


A-33
Cl
H
CH2CCH
CH2CH2CH3


A-34
Cl
H
CH2CCH
CH2CH2OCH3


A-35
Cl
H
CH2CCH
OCH3


A-36
Cl
H
CH2C6H5
CH3


A-37
Cl
H
CH2C6H5
CH2CH3


A-38
Cl
H
CH2C6H5
CH2CH2CH3


A-39
Cl
H
CH2C6H5
CH2CH2OCH3


A-40
Cl
H
CH2C6H5
OCH3


A-41
Cl
F
CH3
CH3


A-42
Cl
F
CH3
CH2CH3


A-43
Cl
F
CH3
CH2CH2CH3


A-44
Cl
F
CH3
CH2CH2OCH3


A-45
Cl
F
CH3
OCH3


A-46
Cl
F
CH2CH3
CH3


A-47
Cl
F
CH2CH3
CH2CH3


A-48
Cl
F
CH2CH3
CH2CH2CH3


A-49
Cl
F
CH2CH3
CH2CH2OCH3


A-50
Cl
F
CH2CH3
OCH3


A-51
Cl
F
CH2OCH3
CH3


A-52
Cl
F
CH2OCH3
CH2CH3


A-53
Cl
F
CH2OCH3
CH2CH2CH3


A-54
Cl
F
CH2OCH3
CH2CH2OCH3


A-55
Cl
F
CH2OCH3
OCH3


A-56
Cl
F
CH2OCH2CH3
CH3


A-57
Cl
F
CH2OCH2CH3
CH2CH3


A-58
Cl
F
CH2OCH2CH3
CH2CH2CH3


A-59
Cl
F
CH2OCH2CH3
CH2CH2OCH3


A-60
Cl
F
CH2OCH2CH3
OCH3


A-61
Cl
F
CH2(CO)OCH3
CH3


A-62
Cl
F
CH2(CO)OCH3
CH2CH3


A-63
Cl
F
CH2(CO)OCH3
CH2CH2CH3


A-64
Cl
F
CH2(CO)OCH3
CH2CH2OCH3


A-65
Cl
F
CH2(CO)OCH3
OCH3


A-66
Cl
F
CH2CHCH2
CH3


A-67
Cl
F
CH2CHCH2
CH2CH3


A-68
Cl
F
CH2CHCH2
CH2CH2CH3


A-69
Cl
F
CH2CHCH2
CH2CH2OCH3


A-70
Cl
F
CH2CHCH2
OCH3


A-71
Cl
F
CH2CCH
CH3


A-72
Cl
F
CH2CCH
CH2CH3


A-73
Cl
F
CH2CCH
CH2CH2CH3


A-74
Cl
F
CH2CCH
CH2CH2OCH3


A-75
Cl
F
CH2CCH
OCH3


A-76
Cl
F
CH2C6H5
CH3


A-77
Cl
F
CH2C6H5
CH2CH3


A-78
Cl
F
CH2C6H5
CH2CH2CH3


A-79
Cl
F
CH2C6H5
CH2CH2OCH3


A-80
Cl
F
CH2C6H5
OCH3


A-81
Cl
Cl
CH3
CH3


A-82
Cl
Cl
CH3
CH2CH3


A-83
Cl
Cl
CH3
CH2CH2CH3


A-84
Cl
Cl
CH3
CH2CH2OCH3


A-85
Cl
Cl
CH3
OCH3


A-86
Cl
Cl
CH2CH3
CH3


A-87
Cl
Cl
CH2CH3
CH2CH3


A-88
Cl
Cl
CH2CH3
CH2CH2CH3


A-89
Cl
Cl
CH2CH3
CH2CH2OCH3


A-90
Cl
Cl
CH2CH3
OCH3


A-91
Cl
Cl
CH2OCH3
CH3


A-92
Cl
Cl
CH2OCH3
CH2CH3


A-93
Cl
Cl
CH2OCH3
CH2CH2CH3


A-94
Cl
Cl
CH2OCH3
CH2CH2OCH3


A-95
Cl
Cl
CH2OCH3
OCH3


A-96
Cl
Cl
CH2OCH2CH3
CH3


A-97
Cl
Cl
CH2OCH2CH3
CH2CH3


A-98
Cl
Cl
CH2OCH2CH3
CH2CH2CH3


A-99
Cl
Cl
CH2OCH2CH3
CH2CH2OCH3


A-100
Cl
Cl
CH2OCH2CH3
OCH3


A-101
Cl
Cl
CH2(CO)OCH3
CH3


A-102
Cl
Cl
CH2(CO)OCH3
CH2CH3


A-103
Cl
Cl
CH2(CO)OCH3
CH2CH2CH3


A-104
Cl
Cl
CH2(CO)OCH3
CH2CH2OCH3


A-105
Cl
Cl
CH2(CO)OCH3
OCH3


A-106
Cl
Cl
CH2CHCH2
CH3


A-107
Cl
Cl
CH2CHCH2
CH2CH3


A-108
Cl
Cl
CH2CHCH2
CH2CH2CH3


A-109
Cl
Cl
CH2CHCH2
CH2CH2OCH3


A-110
Cl
Cl
CH2CHCH2
OCH3


A-111
Cl
Cl
CH2CCH
CH3


A-112
Cl
Cl
CH2CCH
CH2CH3


A-113
Cl
Cl
CH2CCH
CH2CH2CH3


A-114
Cl
Cl
CH2CCH
CH2CH2OCH3


A-115
Cl
Cl
CH2CCH
OCH3


A-116
Cl
Cl
CH2C6H5
CH3


A-117
Cl
Cl
CH2C6H5
CH2CH3


A-118
Cl
Cl
CH2C6H5
CH2CH2CH3


A-119
Cl
Cl
CH2C6H5
CH2CH2OCH3


A-120
Cl
Cl
CH2C6H5
OCH3


A-121
Cl
Br
CH3
CH3


A-122
Cl
Br
CH3
CH2CH3


A-123
Cl
Br
CH3
CH2CH2CH3


A-124
Cl
Br
CH3
CH2CH2OCH3


A-125
Cl
Br
CH3
OCH3


A-126
Cl
Br
CH2CH3
CH3


A-127
Cl
Br
CH2CH3
CH2CH3


A-128
Cl
Br
CH2CH3
CH2CH2CH3


A-129
Cl
Br
CH2CH3
CH2CH2OCH3


A-130
Cl
Br
CH2CH3
OCH3


A-131
Cl
Br
CH2OCH3
CH3


A-132
Cl
Br
CH2OCH3
CH2CH3


A-133
Cl
Br
CH2OCH3
CH2CH2CH3


A-134
Cl
Br
CH2OCH3
CH2CH2OCH3


A-135
Cl
Br
CH2OCH3
OCH3


A-136
Cl
Br
CH2OCH2CH3
CH3


A-137
Cl
Br
CH2OCH2CH3
CH2CH3


A-138
Cl
Br
CH2OCH2CH3
CH2CH2CH3


A-139
Cl
Br
CH2OCH2CH3
CH2CH2OCH3


A-140
Cl
Br
CH2OCH2CH3
OCH3


A-141
Cl
Br
CH2(CO)OCH3
CH3


A-142
Cl
Br
CH2(CO)OCH3
CH2CH3


A-143
Cl
Br
CH2(CO)OCH3
CH2CH2CH3


A-144
Cl
Br
CH2(CO)OCH3
CH2CH2OCH3


A-145
Cl
Br
CH2(CO)OCH3
OCH3


A-146
Cl
Br
CH2CHCH2
CH3


A-147
Cl
Br
CH2CHCH2
CH2CH3


A-148
Cl
Br
CH2CHCH2
CH2CH2CH3


A-149
Cl
Br
CH2CHCH2
CH2CH2OCH3


A-150
Cl
Br
CH2CHCH2
OCH3


A-151
Cl
Br
CH2CCH
CH3


A-152
Cl
Br
CH2CCH
CH2CH3


A-153
Cl
Br
CH2CCH
CH2CH2CH3


A-154
Cl
Br
CH2CCH
CH2CH2OCH3


A-155
Cl
Br
CH2CCH
OCH3


A-156
Cl
Br
CH2C6H5
CH3


A-157
Cl
Br
CH2C6H5
CH2CH3


A-158
Cl
Br
CH2C6H5
CH2CH2CH3


A-159
Cl
Br
CH2C6H5
CH2CH2OCH3


A-160
Cl
Br
CH2C6H5
OCH3


A-161
Cl
CN
CH3
CH3


A-162
Cl
CN
CH3
CH2CH3


A-163
Cl
CN
CH3
CH2CH2CH3


A-164
Cl
CN
CH3
CH2CH2OCH3


A-165
Cl
CN
CH3
OCH3


A-166
Cl
CN
CH2CH3
CH3


A-167
Cl
CN
CH2CH3
CH2CH3


A-168
Cl
CN
CH2CH3
CH2CH2CH3


A-169
Cl
CN
CH2CH3
CH2CH2OCH3


A-170
Cl
CN
CH2CH3
OCH3


A-171
Cl
CN
CH2OCH3
CH3


A-172
Cl
CN
CH2OCH3
CH2CH3


A-173
Cl
CN
CH2OCH3
CH2CH2CH3


A-174
Cl
CN
CH2OCH3
CH2CH2OCH3


A-175
Cl
CN
CH2OCH3
OCH3


A-176
Cl
CN
CH2OCH2CH3
CH3


A-177
Cl
CN
CH2OCH2CH3
CH2CH3


A-178
Cl
CN
CH2OCH2CH3
CH2CH2CH3


A-179
Cl
CN
CH2OCH2CH3
CH2CH2OCH3


A-180
Cl
CN
CH2OCH2CH3
OCH3


A-181
Cl
CN
CH2(CO)OCH3
CH3


A-182
Cl
CN
CH2(CO)OCH3
CH2CH3


A-183
Cl
CN
CH2(CO)OCH3
CH2CH2CH3


A-184
Cl
CN
CH2(CO)OCH3
CH2CH2OCH3


A-185
Cl
CN
CH2(CO)OCH3
OCH3


A-186
Cl
CN
CH2CHCH2
CH3


A-187
Cl
CN
CH2CHCH2
CH2CH3


A-188
Cl
CN
CH2CHCH2
CH2CH2CH3


A-189
Cl
CN
CH2CHCH2
CH2CH2OCH3


A-190
Cl
CN
CH2CHCH2
OCH3


A-191
Cl
CN
CH2CCH
CH3


A-192
Cl
CN
CH2CCH
CH2CH3


A-193
Cl
CN
CH2CCH
CH2CH2CH3


A-194
Cl
CN
CH2CCH
CH2CH2OCH3


A-195
Cl
CN
CH2CCH
OCH3


A-196
Cl
CN
CH2C6H5
CH3


A-197
Cl
CN
CH2C6H5
CH2CH3


A-198
Cl
CN
CH2C6H5
CH2CH2CH3


A-199
Cl
CN
CH2C6H5
CH2CH2OCH3


A-200
Cl
CN
CH2C6H5
OCH3


A-201
Cl
CH3
CH3
CH3


A-202
Cl
CH3
CH3
CH2CH3


A-203
Cl
CH3
CH3
CH2CH2CH3


A-204
Cl
CH3
CH3
CH2CH2OCH3


A-205
Cl
CH3
CH3
OCH3


A-206
Cl
CH3
CH2CH3
CH3


A-207
Cl
CH3
CH2CH3
CH2CH3


A-208
Cl
CH3
CH2CH3
CH2CH2CH3


A-209
Cl
CH3
CH2CH3
CH2CH2OCH3


A-210
Cl
CH3
CH2CH3
OCH3


A-211
Cl
CH3
CH2OCH3
CH3


A-212
Cl
CH3
CH2OCH3
CH2CH3


A-213
Cl
CH3
CH2OCH3
CH2CH2CH3


A-214
Cl
CH3
CH2OCH3
CH2CH2OCH3


A-215
Cl
CH3
CH2OCH3
OCH3


A-216
Cl
CH3
CH2OCH2CH3
CH3


A-217
Cl
CH3
CH2OCH2CH3
CH2CH3


A-218
Cl
CH3
CH2OCH2CH3
CH2CH2CH3


A-219
Cl
CH3
CH2OCH2CH3
CH2CH2OCH3


A-220
Cl
CH3
CH2OCH2CH3
OCH3


A-221
Cl
CH3
CH2(CO)OCH3
CH3


A-222
Cl
CH3
CH2(CO)OCH3
CH2CH3


A-223
Cl
CH3
CH2(CO)OCH3
CH2CH2CH3


A-224
Cl
CH3
CH2(CO)OCH3
CH2CH2OCH3


A-225
Cl
CH3
CH2(CO)OCH3
OCH3


A-226
Cl
CH3
CH2CHCH2
CH3


A-227
Cl
CH3
CH2CHCH2
CH2CH3


A-228
Cl
CH3
CH2CHCH2
CH2CH2CH3


A-229
Cl
CH3
CH2CHCH2
CH2CH2OCH3


A-230
Cl
CH3
CH2CHCH2
OCH3


A-231
Cl
CH3
CH2CCH
CH3


A-232
Cl
CH3
CH2CCH
CH2CH3


A-233
Cl
CH3
CH2CCH
CH2CH2CH3


A-234
Cl
CH3
CH2CCH
CH2CH2OCH3


A-235
Cl
CH3
CH2CCH
OCH3


A-236
Cl
CH3
CH2C6H5
CH3


A-237
Cl
CH3
CH2C6H5
CH2CH3


A-238
Cl
CH3
CH2C6H5
CH2CH2CH3


A-239
Cl
CH3
CH2C6H5
CH2CH2OCH3


A-240
Cl
CH3
CH2C6H5
OCH3


A-241
Cl
CF3
CH3
CH3


A-242
Cl
CF3
CH3
CH2CH3


A-243
Cl
CF3
CH3
CH2CH2CH3


A-244
Cl
CF3
CH3
CH2CH2OCH3


A-245
Cl
CF3
CH3
OCH3


A-246
Cl
CF3
CH2CH3
CH3


A-247
Cl
CF3
CH2CH3
CH2CH3


A-248
Cl
CF3
CH2CH3
CH2CH2CH3


A-249
Cl
CF3
CH2CH3
CH2CH2OCH3


A-250
Cl
CF3
CH2CH3
OCH3


A-251
Cl
CF3
CH2OCH3
CH3


A-252
Cl
CF3
CH2OCH3
CH2CH3


A-253
Cl
CF3
CH2OCH3
CH2CH2CH3


A-254
Cl
CF3
CH2OCH3
CH2CH2OCH3


A-255
Cl
CF3
CH2OCH3
OCH3


A-256
Cl
CF3
CH2OCH2CH3
CH3


A-257
Cl
CF3
CH2OCH2CH3
CH2CH3


A-258
Cl
CF3
CH2OCH2CH3
CH2CH2CH3


A-259
Cl
CF3
CH2OCH2CH3
CH2CH2OCH3


A-260
Cl
CF3
CH2OCH2CH3
OCH3


A-261
Cl
CF3
CH2(CO)OCH3
CH3


A-262
Cl
CF3
CH2(CO)OCH3
CH2CH3


A-263
Cl
CF3
CH2(CO)OCH3
CH2CH2CH3


A-264
Cl
CF3
CH2(CO)OCH3
CH2CH2OCH3


A-265
Cl
CF3
CH2(CO)OCH3
OCH3


A-266
Cl
CF3
CH2CHCH2
CH3


A-267
Cl
CF3
CH2CHCH2
CH2CH3


A-268
Cl
CF3
CH2CHCH2
CH2CH2CH3


A-269
Cl
CF3
CH2CHCH2
CH2CH2OCH3


A-270
Cl
CF3
CH2CHCH2
OCH3


A-271
Cl
CF3
CH2CCH
CH3


A-272
Cl
CF3
CH2CCH
CH2CH3


A-273
Cl
CF3
CH2CCH
CH2CH2CH3


A-274
Cl
CF3
CH2CCH
CH2CH2OCH3


A-275
Cl
CF3
CH2CCH
OCH3


A-276
Cl
CF3
CH2C6H5
CH3


A-277
Cl
CF3
CH2C6H5
CH2CH3


A-278
Cl
CF3
CH2C6H5
CH2CH2CH3


A-279
Cl
CF3
CH2C6H5
CH2CH2OCH3


A-280
Cl
CF3
CH2C6H5
OCH3


A-281
Cl
SO2CH3
CH3
CH3


A-282
Cl
SO2CH3
CH3
CH2CH3


A-283
Cl
SO2CH3
CH3
CH2CH2CH3


A-284
Cl
SO2CH3
CH3
CH2CH2OCH3


A-285
Cl
SO2CH3
CH3
OCH3


A-286
Cl
SO2CH3
CH2CH3
CH3


A-287
Cl
SO2CH3
CH2CH3
CH2CH3


A-288
Cl
SO2CH3
CH2CH3
CH2CH2CH3


A-289
Cl
SO2CH3
CH2CH3
CH2CH2OCH3


A-290
Cl
SO2CH3
CH2CH3
OCH3


A-291
Cl
SO2CH3
CH2OCH3
CH3


A-292
Cl
SO2CH3
CH2OCH3
CH2CH3


A-293
Cl
SO2CH3
CH2OCH3
CH2CH2CH3


A-294
Cl
SO2CH3
CH2OCH3
CH2CH2OCH3


A-295
Cl
SO2CH3
CH2OCH3
OCH3


A-296
Cl
SO2CH3
CH2OCH2CH3
CH3


A-297
Cl
SO2CH3
CH2OCH2CH3
CH2CH3


A-298
Cl
SO2CH3
CH2OCH2CH3
CH2CH2CH3


A-299
Cl
SO2CH3
CH2OCH2CH3
CH2CH2OCH3


A-300
Cl
SO2CH3
CH2OCH2CH3
OCH3


A-301
Cl
SO2CH3
CH2(CO)OCH3
CH3


A-302
Cl
SO2CH3
CH2(CO)OCH3
CH2CH3


A-303
Cl
SO2CH3
CH2(CO)OCH3
CH2CH2CH3


A-304
Cl
SO2CH3
CH2(CO)OCH3
CH2CH2OCH3


A-305
Cl
SO2CH3
CH2(CO)OCH3
OCH3


A-306
Cl
SO2CH3
CH2CHCH2
CH3


A-307
Cl
SO2CH3
CH2CHCH2
CH2CH3


A-308
Cl
SO2CH3
CH2CHCH2
CH2CH2CH3


A-309
Cl
SO2CH3
CH2CHCH2
CH2CH2OCH3


A-310
Cl
SO2CH3
CH2CHCH2
OCH3


A-311
Cl
SO2CH3
CH2CCH
CH3


A-312
Cl
SO2CH3
CH2CCH
CH2CH3


A-313
Cl
SO2CH3
CH2CCH
CH2CH2CH3


A-314
Cl
SO2CH3
CH2CCH
CH2CH2OCH3


A-315
Cl
SO2CH3
CH2CCH
OCH3


A-316
Cl
SO2CH3
CH2C6H5
CH3


A-317
Cl
SO2CH3
CH2C6H5
CH2CH3


A-318
Cl
SO2CH3
CH2C6H5
CH2CH2CH3


A-319
Cl
SO2CH3
CH2C6H5
CH2CH2OCH3


A-320
Cl
SO2CH3
CH2C6H5
OCH3


A-321
Cl
NO2
CH3
CH3


A-322
Cl
NO2
CH3
CH2CH3


A-323
Cl
NO2
CH3
CH2CH2CH3


A-324
Cl
NO2
CH3
CH2CH2OCH3


A-325
Cl
NO2
CH3
OCH3


A-326
Cl
NO2
CH2CH3
CH3


A-327
Cl
NO2
CH2CH3
CH2CH3


A-328
Cl
NO2
CH2CH3
CH2CH2CH3


A-329
Cl
NO2
CH2CH3
CH2CH2OCH3


A-330
Cl
NO2
CH2CH3
OCH3


A-331
Cl
NO2
CH2OCH3
CH3


A-332
Cl
NO2
CH2OCH3
CH2CH3


A-333
Cl
NO2
CH2OCH3
CH2CH2CH3


A-334
Cl
NO2
CH2OCH3
CH2CH2OCH3


A-335
Cl
NO2
CH2OCH3
OCH3


A-336
Cl
NO2
CH2OCH2CH3
CH3


A-337
Cl
NO2
CH2OCH2CH3
CH2CH3


A-338
Cl
NO2
CH2OCH2CH3
CH2CH2CH3


A-339
Cl
NO2
CH2OCH2CH3
CH2CH2OCH3


A-340
Cl
NO2
CH2OCH2CH3
OCH3


A-341
Cl
NO2
CH2(CO)OCH3
CH3


A-342
Cl
NO2
CH2(CO)OCH3
CH2CH3


A-343
Cl
NO2
CH2(CO)OCH3
CH2CH2CH3


A-344
Cl
NO2
CH2(CO)OCH3
CH2CH2OCH3


A-345
Cl
NO2
CH2(CO)OCH3
OCH3


A-346
Cl
NO2
CH2CHCH2
CH3


A-347
Cl
NO2
CH2CHCH2
CH2CH3


A-348
Cl
NO2
CH2CHCH2
CH2CH2CH3


A-349
Cl
NO2
CH2CHCH2
CH2CH2OCH3


A-350
Cl
NO2
CH2CHCH2
OCH3


A-351
Cl
NO2
CH2CCH
CH3


A-352
Cl
NO2
CH2CCH
CH2CH3


A-353
Cl
NO2
CH2CCH
CH2CH2CH3


A-354
Cl
NO2
CH2CCH
CH2CH2OCH3


A-355
Cl
NO2
CH2CCH
OCH3


A-356
Cl
NO2
CH2C6H5
CH3


A-357
Cl
NO2
CH2C6H5
CH2CH3


A-358
Cl
NO2
CH2C6H5
CH2CH2CH3


A-359
Cl
NO2
CH2C6H5
CH2CH2OCH3


A-360
Cl
NO2
CH2C6H5
OCH3


A-361
NO2
H
CH3
CH3


A-362
NO2
H
CH3
CH2CH3


A-363
NO2
H
CH3
CH2CH2CH3


A-364
NO2
H
CH3
CH2CH2OCH3


A-365
NO2
H
CH3
OCH3


A-366
NO2
H
CH2CH3
CH3


A-367
NO2
H
CH2CH3
CH2CH3


A-368
NO2
H
CH2CH3
CH2CH2CH3


A-369
NO2
H
CH2CH3
CH2CH2OCH3


A-370
NO2
H
CH2CH3
OCH3


A-371
NO2
H
CH2OCH3
CH3


A-372
NO2
H
CH2OCH3
CH2CH3


A-373
NO2
H
CH2OCH3
CH2CH2CH3


A-374
NO2
H
CH2OCH3
CH2CH2OCH3


A-375
NO2
H
CH2OCH3
OCH3


A-376
NO2
H
CH2OCH2CH3
CH3


A-377
NO2
H
CH2OCH2CH3
CH2CH3


A-378
NO2
H
CH2OCH2CH3
CH2CH2CH3


A-379
NO2
H
CH2OCH2CH3
CH2CH2OCH3


A-380
NO2
H
CH2OCH2CH3
OCH3


A-381
NO2
H
CH2(CO)OCH3
CH3


A-382
NO2
H
CH2(CO)OCH3
CH2CH3


A-383
NO2
H
CH2(CO)OCH3
CH2CH2CH3


A-384
NO2
H
CH2(CO)OCH3
CH2CH2OCH3


A-385
NO2
H
CH2(CO)OCH3
OCH3


A-386
NO2
H
CH2CHCH2
CH3


A-387
NO2
H
CH2CHCH2
CH2CH3


A-388
NO2
H
CH2CHCH2
CH2CH2CH3


A-389
NO2
H
CH2CHCH2
CH2CH2OCH3


A-390
NO2
H
CH2CHCH2
OCH3


A-391
NO2
H
CH2CCH
CH3


A-392
NO2
H
CH2CCH
CH2CH3


A-393
NO2
H
CH2CCH
CH2CH2CH3


A-394
NO2
H
CH2CCH
CH2CH2OCH3


A-395
NO2
H
CH2CCH
OCH3


A-396
NO2
H
CH2C6H5
CH3


A-397
NO2
H
CH2C6H5
CH2CH3


A-398
NO2
H
CH2C6H5
CH2CH2CH3


A-399
NO2
H
CH2C6H5
CH2CH2OCH3


A-400
NO2
H
CH2C6H5
OCH3


A-401
NO2
F
CH3
CH3


A-402
NO2
F
CH3
CH2CH3


A-403
NO2
F
CH3
CH2CH2CH3


A-404
NO2
F
CH3
CH2CH2OCH3


A-405
NO2
F
CH3
OCH3


A-406
NO2
F
CH2CH3
CH3


A-407
NO2
F
CH2CH3
CH2CH3


A-408
NO2
F
CH2CH3
CH2CH2CH3


A-409
NO2
F
CH2CH3
CH2CH2OCH3


A-410
NO2
F
CH2CH3
OCH3


A-411
NO2
F
CH2OCH3
CH3


A-412
NO2
F
CH2OCH3
CH2CH3


A-413
NO2
F
CH2OCH3
CH2CH2CH3


A-414
NO2
F
CH2OCH3
CH2CH2OCH3


A-415
NO2
F
CH2OCH3
OCH3


A-416
NO2
F
CH2OCH2CH3
CH3


A-417
NO2
F
CH2OCH2CH3
CH2CH3


A-418
NO2
F
CH2OCH2CH3
CH2CH2CH3


A-419
NO2
F
CH2OCH2CH3
CH2CH2OCH3


A-420
NO2
F
CH2OCH2CH3
OCH3


A-421
NO2
F
CH2(CO)OCH3
CH3


A-422
NO2
F
CH2(CO)OCH3
CH2CH3


A-423
NO2
F
CH2(CO)OCH3
CH2CH2CH3


A-424
NO2
F
CH2(CO)OCH3
CH2CH2OCH3


A-425
NO2
F
CH2(CO)OCH3
OCH3


A-426
NO2
F
CH2CHCH2
CH3


A-427
NO2
F
CH2CHCH2
CH2CH3


A-428
NO2
F
CH2CHCH2
CH2CH2CH3


A-429
NO2
F
CH2CHCH2
CH2CH2OCH3


A-430
NO2
F
CH2CHCH2
OCH3


A-431
NO2
F
CH2CCH
CH3


A-432
NO2
F
CH2CCH
CH2CH3


A-433
NO2
F
CH2CCH
CH2CH2CH3


A-434
NO2
F
CH2CCH
CH2CH2OCH3


A-435
NO2
F
CH2CCH
OCH3


A-436
NO2
F
CH2C6H5
CH3


A-437
NO2
F
CH2C6H5
CH2CH3


A-438
NO2
F
CH2C6H5
CH2CH2CH3


A-439
NO2
F
CH2C6H5
CH2CH2OCH3


A-440
NO2
F
CH2C6H5
OCH3


A-441
NO2
Cl
CH3
CH3


A-442
NO2
Cl
CH3
CH2CH3


A-443
NO2
Cl
CH3
CH2CH2CH3


A-444
NO2
Cl
CH3
CH2CH2OCH3


A-445
NO2
Cl
CH3
OCH3


A-446
NO2
Cl
CH2CH3
CH3


A-447
NO2
Cl
CH2CH3
CH2CH3


A-448
NO2
Cl
CH2CH3
CH2CH2CH3


A-449
NO2
Cl
CH2CH3
CH2CH2OCH3


A-450
NO2
Cl
CH2CH3
OCH3


A-451
NO2
Cl
CH2OCH3
CH3


A-452
NO2
Cl
CH2OCH3
CH2CH3


A-453
NO2
Cl
CH2OCH3
CH2CH2CH3


A-454
NO2
Cl
CH2OCH3
CH2CH2OCH3


A-455
NO2
Cl
CH2OCH3
OCH3


A-456
NO2
Cl
CH2OCH2CH3
CH3


A-457
NO2
Cl
CH2OCH2CH3
CH2CH3


A-458
NO2
Cl
CH2OCH2CH3
CH2CH2CH3


A-459
NO2
Cl
CH2OCH2CH3
CH2CH2OCH3


A-460
NO2
Cl
CH2OCH2CH3
OCH3


A-461
NO2
Cl
CH2(CO)OCH3
CH3


A-462
NO2
Cl
CH2(CO)OCH3
CH2CH3


A-463
NO2
Cl
CH2(CO)OCH3
CH2CH2CH3


A-464
NO2
Cl
CH2(CO)OCH3
CH2CH2OCH3


A-465
NO2
Cl
CH2(CO)OCH3
OCH3


A-466
NO2
Cl
CH2CHCH2
CH3


A-467
NO2
Cl
CH2CHCH2
CH2CH3


A-468
NO2
Cl
CH2CHCH2
CH2CH2CH3


A-469
NO2
Cl
CH2CHCH2
CH2CH2OCH3


A-470
NO2
Cl
CH2CHCH2
OCH3


A-471
NO2
Cl
CH2CCH
CH3


A-472
NO2
Cl
CH2CCH
CH2CH3


A-473
NO2
Cl
CH2CCH
CH2CH2CH3


A-474
NO2
Cl
CH2CCH
CH2CH2OCH3


A-475
NO2
Cl
CH2CCH
OCH3


A-476
NO2
Cl
CH2C6H5
CH3


A-477
NO2
Cl
CH2C6H5
CH2CH3


A-478
NO2
Cl
CH2C6H5
CH2CH2CH3


A-479
NO2
Cl
CH2C6H5
CH2CH2OCH3


A-480
NO2
Cl
CH2C6H5
OCH3


A-481
NO2
Br
CH3
CH3


A-482
NO2
Br
CH3
CH2CH3


A-483
NO2
Br
CH3
CH2CH2CH3


A-484
NO2
Br
CH3
CH2CH2OCH3


A-485
NO2
Br
CH3
OCH3


A-486
NO2
Br
CH2CH3
CH3


A-487
NO2
Br
CH2CH3
CH2CH3


A-488
NO2
Br
CH2CH3
CH2CH2CH3


A-489
NO2
Br
CH2CH3
CH2CH2OCH3


A-490
NO2
Br
CH2CH3
OCH3


A-491
NO2
Br
CH2OCH3
CH3


A-492
NO2
Br
CH2OCH3
CH2CH3


A-493
NO2
Br
CH2OCH3
CH2CH2CH3


A-494
NO2
Br
CH2OCH3
CH2CH2OCH3


A-495
NO2
Br
CH2OCH3
OCH3


A-496
NO2
Br
CH2OCH2CH3
CH3


A-497
NO2
Br
CH2OCH2CH3
CH2CH3


A-498
NO2
Br
CH2OCH2CH3
CH2CH2CH3


A-499
NO2
Br
CH2OCH2CH3
CH2CH2OCH3


A-500
NO2
Br
CH2OCH2CH3
OCH3


A-501
NO2
Br
CH2(CO)OCH3
CH3


A-502
NO2
Br
CH2(CO)OCH3
CH2CH3


A-503
NO2
Br
CH2(CO)OCH3
CH2CH2CH3


A-504
NO2
Br
CH2(CO)OCH3
CH2CH2OCH3


A-505
NO2
Br
CH2(CO)OCH3
OCH3


A-506
NO2
Br
CH2CHCH2
CH3


A-507
NO2
Br
CH2CHCH2
CH2CH3


A-508
NO2
Br
CH2CHCH2
CH2CH2CH3


A-509
NO2
Br
CH2CHCH2
CH2CH2OCH3


A-510
NO2
Br
CH2CHCH2
OCH3


A-511
NO2
Br
CH2CCH
CH3


A-512
NO2
Br
CH2CCH
CH2CH3


A-513
NO2
Br
CH2CCH
CH2CH2CH3


A-514
NO2
Br
CH2CCH
CH2CH2OCH3


A-515
NO2
Br
CH2CCH
OCH3


A-516
NO2
Br
CH2C6H5
CH3


A-517
NO2
Br
CH2C6H5
CH2CH3


A-518
NO2
Br
CH2C6H5
CH2CH2CH3


A-519
NO2
Br
CH2C6H5
CH2CH2OCH3


A-520
NO2
Br
CH2C6H5
OCH3


A-521
NO2
CN
CH3
CH3


A-522
NO2
CN
CH3
CH2CH3


A-523
NO2
CN
CH3
CH2CH2CH3


A-524
NO2
CN
CH3
CH2CH2OCH3


A-525
NO2
CN
CH3
OCH3


A-526
NO2
CN
CH2CH3
CH3


A-527
NO2
CN
CH2CH3
CH2CH3


A-528
NO2
CN
CH2CH3
CH2CH2CH3


A-529
NO2
CN
CH2CH3
CH2CH2OCH3


A-530
NO2
CN
CH2CH3
OCH3


A-531
NO2
CN
CH2OCH3
CH3


A-532
NO2
CN
CH2OCH3
CH2CH3


A-533
NO2
CN
CH2OCH3
CH2CH2CH3


A-534
NO2
CN
CH2OCH3
CH2CH2OCH3


A-535
NO2
CN
CH2OCH3
OCH3


A-536
NO2
CN
CH2OCH2CH3
CH3


A-537
NO2
CN
CH2OCH2CH3
CH2CH3


A-538
NO2
CN
CH2OCH2CH3
CH2CH2CH3


A-539
NO2
CN
CH2OCH2CH3
CH2CH2OCH3


A-540
NO2
CN
CH2OCH2CH3
OCH3


A-541
NO2
CN
CH2(CO)OCH3
CH3


A-542
NO2
CN
CH2(CO)OCH3
CH2CH3


A-543
NO2
CN
CH2(CO)OCH3
CH2CH2CH3


A-544
NO2
CN
CH2(CO)OCH3
CH2CH2OCH3


A-545
NO2
CN
CH2(CO)OCH3
OCH3


A-546
NO2
CN
CH2CHCH2
CH3


A-547
NO2
CN
CH2CHCH2
CH2CH3


A-548
NO2
CN
CH2CHCH2
CH2CH2CH3


A-549
NO2
CN
CH2CHCH2
CH2CH2OCH3


A-550
NO2
CN
CH2CHCH2
OCH3


A-551
NO2
CN
CH2CCH
CH3


A-552
NO2
CN
CH2CCH
CH2CH3


A-553
NO2
CN
CH2CCH
CH2CH2CH3


A-554
NO2
CN
CH2CCH
CH2CH2OCH3


A-555
NO2
CN
CH2CCH
OCH3


A-556
NO2
CN
CH2C6H5
CH3


A-557
NO2
CN
CH2C6H5
CH2CH3


A-558
NO2
CN
CH2C6H5
CH2CH2CH3


A-559
NO2
CN
CH2C6H5
CH2CH2OCH3


A-560
NO2
CN
CH2C6H5
OCH3


A-561
NO2
CH3
CH3
CH3


A-562
NO2
CH3
CH3
CH2CH3


A-563
NO2
CH3
CH3
CH2CH2CH3


A-564
NO2
CH3
CH3
CH2CH2OCH3


A-565
NO2
CH3
CH3
OCH3


A-566
NO2
CH3
CH2CH3
CH3


A-567
NO2
CH3
CH2CH3
CH2CH3


A-568
NO2
CH3
CH2CH3
CH2CH2CH3


A-569
NO2
CH3
CH2CH3
CH2CH2OCH3


A-570
NO2
CH3
CH2CH3
OCH3


A-571
NO2
CH3
CH2OCH3
CH3


A-572
NO2
CH3
CH2OCH3
CH2CH3


A-573
NO2
CH3
CH2OCH3
CH2CH2CH3


A-574
NO2
CH3
CH2OCH3
CH2CH2OCH3


A-575
NO2
CH3
CH2OCH3
OCH3


A-576
NO2
CH3
CH2OCH2CH3
CH3


A-577
NO2
CH3
CH2OCH2CH3
CH2CH3


A-578
NO2
CH3
CH2OCH2CH3
CH2CH2CH3


A-579
NO2
CH3
CH2OCH2CH3
CH2CH2OCH3


A-580
NO2
CH3
CH2OCH2CH3
OCH3


A-581
NO2
CH3
CH2(CO)OCH3
CH3


A-582
NO2
CH3
CH2(CO)OCH3
CH2CH3


A-583
NO2
CH3
CH2(CO)OCH3
CH2CH2CH3


A-584
NO2
CH3
CH2(CO)OCH3
CH2CH2OCH3


A-585
NO2
CH3
CH2(CO)OCH3
OCH3


A-586
NO2
CH3
CH2CHCH2
CH3


A-587
NO2
CH3
CH2CHCH2
CH2CH3


A-588
NO2
CH3
CH2CHCH2
CH2CH2CH3


A-589
NO2
CH3
CH2CHCH2
CH2CH2OCH3


A-590
NO2
CH3
CH2CHCH2
OCH3


A-591
NO2
CH3
CH2CCH
CH3


A-592
NO2
CH3
CH2CCH
CH2CH3


A-593
NO2
CH3
CH2CCH
CH2CH2CH3


A-594
NO2
CH3
CH2CCH
CH2CH2OCH3


A-595
NO2
CH3
CH2CCH
OCH3


A-596
NO2
CH3
CH2C6H5
CH3


A-597
NO2
CH3
CH2C6H5
CH2CH3


A-598
NO2
CH3
CH2C6H5
CH2CH2CH3


A-599
NO2
CH3
CH2C6H5
CH2CH2OCH3


A-600
NO2
CH3
CH2C6H5
OCH3


A-601
NO2
CF3
CH3
CH3


A-602
NO2
CF3
CH3
CH2CH3


A-603
NO2
CF3
CH3
CH2CH2CH3


A-604
NO2
CF3
CH3
CH2CH2OCH3


A-605
NO2
CF3
CH3
OCH3


A-606
NO2
CF3
CH2CH3
CH3


A-607
NO2
CF3
CH2CH3
CH2CH3


A-608
NO2
CF3
CH2CH3
CH2CH2CH3


A-609
NO2
CF3
CH2CH3
CH2CH2OCH3


A-610
NO2
CF3
CH2CH3
OCH3


A-611
NO2
CF3
CH2OCH3
CH3


A-612
NO2
CF3
CH2OCH3
CH2CH3


A-613
NO2
CF3
CH2OCH3
CH2CH2CH3


A-614
NO2
CF3
CH2OCH3
CH2CH2OCH3


A-615
NO2
CF3
CH2OCH3
OCH3


A-616
NO2
CF3
CH2OCH2CH3
CH3


A-617
NO2
CF3
CH2OCH2CH3
CH2CH3


A-618
NO2
CF3
CH2OCH2CH3
CH2CH2CH3


A-619
NO2
CF3
CH2OCH2CH3
CH2CH2OCH3


A-620
NO2
CF3
CH2OCH2CH3
OCH3


A-621
NO2
CF3
CH2(CO)OCH3
CH3


A-622
NO2
CF3
CH2(CO)OCH3
CH2CH3


A-623
NO2
CF3
CH2(CO)OCH3
CH2CH2CH3


A-624
NO2
CF3
CH2(CO)OCH3
CH2CH2OCH3


A-625
NO2
CF3
CH2(CO)OCH3
OCH3


A-626
NO2
CF3
CH2CHCH2
CH3


A-627
NO2
CF3
CH2CHCH2
CH2CH3


A-628
NO2
CF3
CH2CHCH2
CH2CH2CH3


A-629
NO2
CF3
CH2CHCH2
CH2CH2OCH3


A-630
NO2
CF3
CH2CHCH2
OCH3


A-631
NO2
CF3
CH2CCH
CH3


A-632
NO2
CF3
CH2CCH
CH2CH3


A-633
NO2
CF3
CH2CCH
CH2CH2CH3


A-634
NO2
CF3
CH2CCH
CH2CH2OCH3


A-635
NO2
CF3
CH2CCH
OCH3


A-636
NO2
CF3
CH2C6H5
CH3


A-637
NO2
CF3
CH2C6H5
CH2CH3


A-638
NO2
CF3
CH2C6H5
CH2CH2CH3


A-639
NO2
CF3
CH2C6H5
CH2CH2OCH3


A-640
NO2
CF3
CH2C6H5
OCH3


A-641
NO2
SO2CH3
CH3
CH3


A-642
NO2
SO2CH3
CH3
CH2CH3


A-643
NO2
SO2CH3
CH3
CH2CH2CH3


A-644
NO2
SO2CH3
CH3
CH2CH2OCH3


A-645
NO2
SO2CH3
CH3
OCH3


A-646
NO2
SO2CH3
CH2CH3
CH3


A-647
NO2
SO2CH3
CH2CH3
CH2CH3


A-648
NO2
SO2CH3
CH2CH3
CH2CH2CH3


A-649
NO2
SO2CH3
CH2CH3
CH2CH2OCH3


A-650
NO2
SO2CH3
CH2CH3
OCH3


A-651
NO2
SO2CH3
CH2OCH3
CH3


A-652
NO2
SO2CH3
CH2OCH3
CH2CH3


A-653
NO2
SO2CH3
CH2OCH3
CH2CH2CH3


A-654
NO2
SO2CH3
CH2OCH3
CH2CH2OCH3


A-655
NO2
SO2CH3
CH2OCH3
OCH3


A-656
NO2
SO2CH3
CH2OCH2CH3
CH3


A-657
NO2
SO2CH3
CH2OCH2CH3
CH2CH3


A-658
NO2
SO2CH3
CH2OCH2CH3
CH2CH2CH3


A-659
NO2
SO2CH3
CH2OCH2CH3
CH2CH2OCH3


A-660
NO2
SO2CH3
CH2OCH2CH3
OCH3


A-661
NO2
SO2CH3
CH2(CO)OCH3
CH3


A-662
NO2
SO2CH3
CH2(CO)OCH3
CH2CH3


A-663
NO2
SO2CH3
CH2(CO)OCH3
CH2CH2CH3


A-664
NO2
SO2CH3
CH2(CO)OCH3
CH2CH2OCH3


A-665
NO2
SO2CH3
CH2(CO)OCH3
OCH3


A-666
NO2
SO2CH3
CH2CHCH2
CH3


A-667
NO2
SO2CH3
CH2CHCH2
CH2CH3


A-668
NO2
SO2CH3
CH2CHCH2
CH2CH2CH3


A-669
NO2
SO2CH3
CH2CHCH2
CH2CH2OCH3


A-670
NO2
SO2CH3
CH2CHCH2
OCH3


A-671
NO2
SO2CH3
CH2CCH
CH3


A-672
NO2
SO2CH3
CH2CCH
CH2CH3


A-673
NO2
SO2CH3
CH2CCH
CH2CH2CH3


A-674
NO2
SO2CH3
CH2CCH
CH2CH2OCH3


A-675
NO2
SO2CH3
CH2CCH
OCH3


A-676
NO2
SO2CH3
CH2C6H5
CH3


A-677
NO2
SO2CH3
CH2C6H5
CH2CH3


A-678
NO2
SO2CH3
CH2C6H5
CH2CH2CH3


A-679
NO2
SO2CH3
CH2C6H5
CH2CH2OCH3


A-680
NO2
SO2CH3
CH2C6H5
OCH3


A-681
NO2
NO2
CH3
CH3


A-682
NO2
NO2
CH3
CH2CH3


A-683
NO2
NO2
CH3
CH2CH2CH3


A-684
NO2
NO2
CH3
CH2CH2OCH3


A-685
NO2
NO2
CH3
OCH3


A-686
NO2
NO2
CH2CH3
CH3


A-687
NO2
NO2
CH2CH3
CH2CH3


A-688
NO2
NO2
CH2CH3
CH2CH2CH3


A-689
NO2
NO2
CH2CH3
CH2CH2OCH3


A-690
NO2
NO2
CH2CH3
OCH3


A-691
NO2
NO2
CH2OCH3
CH3


A-692
NO2
NO2
CH2OCH3
CH2CH3


A-693
NO2
NO2
CH2OCH3
CH2CH2CH3


A-694
NO2
NO2
CH2OCH3
CH2CH2OCH3


A-695
NO2
NO2
CH2OCH3
OCH3


A-696
NO2
NO2
CH2OCH2CH3
CH3


A-697
NO2
NO2
CH2OCH2CH3
CH2CH3


A-698
NO2
NO2
CH2OCH2CH3
CH2CH2CH3


A-699
NO2
NO2
CH2OCH2CH3
CH2CH2OCH3


A-700
NO2
NO2
CH2OCH2CH3
OCH3


A-701
NO2
NO2
CH2(CO)OCH3
CH3


A-702
NO2
NO2
CH2(CO)OCH3
CH2CH3


A-703
NO2
NO2
CH2(CO)OCH3
CH2CH2CH3


A-704
NO2
NO2
CH2(CO)OCH3
CH2CH2OCH3


A-705
NO2
NO2
CH2(CO)OCH3
OCH3


A-706
NO2
NO2
CH2CHCH2
CH3


A-707
NO2
NO2
CH2CHCH2
CH2CH3


A-708
NO2
NO2
CH2CHCH2
CH2CH2CH3


A-709
NO2
NO2
CH2CHCH2
CH2CH2OCH3


A-710
NO2
NO2
CH2CHCH2
OCH3


A-711
NO2
NO2
CH2CCH
CH3


A-712
NO2
NO2
CH2CCH
CH2CH3


A-713
NO2
NO2
CH2CCH
CH2CH2CH3


A-714
NO2
NO2
CH2CCH
CH2CH2OCH3


A-715
NO2
NO2
CH2CCH
OCH3


A-716
NO2
NO2
CH2C6H5
CH3


A-717
NO2
NO2
CH2C6H5
CH2CH3


A-718
NO2
NO2
CH2C6H5
CH2CH2CH3


A-719
NO2
NO2
CH2C6H5
CH2CH2OCH3


A-720
NO2
NO2
CH2C6H5
OCH3


A-721
CH3
H
CH3
CH3


A-722
CH3
H
CH3
CH2CH3


A-723
CH3
H
CH3
CH2CH2CH3


A-724
CH3
H
CH3
CH2CH2OCH3


A-725
CH3
H
CH3
OCH3


A-726
CH3
H
CH2CH3
CH3


A-727
CH3
H
CH2CH3
CH2CH3


A-728
CH3
H
CH2CH3
CH2CH2CH3


A-729
CH3
H
CH2CH3
CH2CH2OCH3


A-730
CH3
H
CH2CH3
OCH3


A-731
CH3
H
CH2OCH3
CH3


A-732
CH3
H
CH2OCH3
CH2CH3


A-733
CH3
H
CH2OCH3
CH2CH2CH3


A-734
CH3
H
CH2OCH3
CH2CH2OCH3


A-735
CH3
H
CH2OCH3
OCH3


A-736
CH3
H
CH2OCH2CH3
CH3


A-737
CH3
H
CH2OCH2CH3
CH2CH3


A-738
CH3
H
CH2OCH2CH3
CH2CH2CH3


A-739
CH3
H
CH2OCH2CH3
CH2CH2OCH3


A-740
CH3
H
CH2OCH2CH3
OCH3


A-741
CH3
H
CH2(CO)OCH3
CH3


A-742
CH3
H
CH2(CO)OCH3
CH2CH3


A-743
CH3
H
CH2(CO)OCH3
CH2CH2CH3


A-744
CH3
H
CH2(CO)OCH3
CH2CH2OCH3


A-745
CH3
H
CH2(CO)OCH3
OCH3


A-746
CH3
H
CH2CHCH2
CH3


A-747
CH3
H
CH2CHCH2
CH2CH3


A-748
CH3
H
CH2CHCH2
CH2CH2CH3


A-749
CH3
H
CH2CHCH2
CH2CH2OCH3


A-750
CH3
H
CH2CHCH2
OCH3


A-751
CH3
H
CH2CCH
CH3


A-752
CH3
H
CH2CCH
CH2CH3


A-753
CH3
H
CH2CCH
CH2CH2CH3


A-754
CH3
H
CH2CCH
CH2CH2OCH3


A-755
CH3
H
CH2CCH
OCH3


A-756
CH3
H
CH2C6H5
CH3


A-757
CH3
H
CH2C6H5
CH2CH3


A-758
CH3
H
CH2C6H5
CH2CH2CH3


A-759
CH3
H
CH2C6H5
CH2CH2OCH3


A-760
CH3
H
CH2C6H5
OCH3


A-761
CH3
F
CH3
CH3


A-762
CH3
F
CH3
CH2CH3


A-763
CH3
F
CH3
CH2CH2CH3


A-764
CH3
F
CH3
CH2CH2OCH3


A-765
CH3
F
CH3
OCH3


A-766
CH3
F
CH2CH3
CH3


A-767
CH3
F
CH2CH3
CH2CH3


A-768
CH3
F
CH2CH3
CH2CH2CH3


A-769
CH3
F
CH2CH3
CH2CH2OCH3


A-770
CH3
F
CH2CH3
OCH3


A-771
CH3
F
CH2OCH3
CH3


A-772
CH3
F
CH2OCH3
CH2CH3


A-773
CH3
F
CH2OCH3
CH2CH2CH3


A-774
CH3
F
CH2OCH3
CH2CH2OCH3


A-775
CH3
F
CH2OCH3
OCH3


A-776
CH3
F
CH2OCH2CH3
CH3


A-777
CH3
F
CH2OCH2CH3
CH2CH3


A-778
CH3
F
CH2OCH2CH3
CH2CH2CH3


A-779
CH3
F
CH2OCH2CH3
CH2CH2OCH3


A-780
CH3
F
CH2OCH2CH3
OCH3


A-781
CH3
F
CH2(CO)OCH3
CH3


A-782
CH3
F
CH2(CO)OCH3
CH2CH3


A-783
CH3
F
CH2(CO)OCH3
CH2CH2CH3


A-784
CH3
F
CH2(CO)OCH3
CH2CH2OCH3


A-785
CH3
F
CH2(CO)OCH3
OCH3


A-786
CH3
F
CH2CHCH2
CH3


A-787
CH3
F
CH2CHCH2
CH2CH3


A-788
CH3
F
CH2CHCH2
CH2CH2CH3


A-789
CH3
F
CH2CHCH2
CH2CH2OCH3


A-790
CH3
F
CH2CHCH2
OCH3


A-791
CH3
F
CH2CCH
CH3


A-792
CH3
F
CH2CCH
CH2CH3


A-793
CH3
F
CH2CCH
CH2CH2CH3


A-794
CH3
F
CH2CCH
CH2CH2OCH3


A-795
CH3
F
CH2CCH
OCH3


A-796
CH3
F
CH2C6H5
CH3


A-797
CH3
F
CH2C6H5
CH2CH3


A-798
CH3
F
CH2C6H5
CH2CH2CH3


A-799
CH3
F
CH2C6H5
CH2CH2OCH3


A-800
CH3
F
CH2C6H5
OCH3


A-801
CH3
Cl
CH3
CH3


A-802
CH3
Cl
CH3
CH2CH3


A-803
CH3
Cl
CH3
CH2CH2CH3


A-804
CH3
Cl
CH3
CH2CH2OCH3


A-805
CH3
Cl
CH3
OCH3


A-806
CH3
Cl
CH2CH3
CH3


A-807
CH3
Cl
CH2CH3
CH2CH3


A-808
CH3
Cl
CH2CH3
CH2CH2CH3


A-809
CH3
Cl
CH2CH3
CH2CH2OCH3


A-810
CH3
Cl
CH2CH3
OCH3


A-811
CH3
Cl
CH2OCH3
CH3


A-812
CH3
Cl
CH2OCH3
CH2CH3


A-813
CH3
Cl
CH2OCH3
CH2CH2CH3


A-814
CH3
Cl
CH2OCH3
CH2CH2OCH3


A-815
CH3
Cl
CH2OCH3
OCH3


A-816
CH3
Cl
CH2OCH2CH3
CH3


A-817
CH3
Cl
CH2OCH2CH3
CH2CH3


A-818
CH3
Cl
CH2OCH2CH3
CH2CH2CH3


A-819
CH3
Cl
CH2OCH2CH3
CH2CH2OCH3


A-820
CH3
Cl
CH2OCH2CH3
OCH3


A-821
CH3
Cl
CH2(CO)OCH3
CH3


A-822
CH3
Cl
CH2(CO)OCH3
CH2CH3


A-823
CH3
Cl
CH2(CO)OCH3
CH2CH2CH3


A-824
CH3
Cl
CH2(CO)OCH3
CH2CH2OCH3


A-825
CH3
Cl
CH2(CO)OCH3
OCH3


A-826
CH3
Cl
CH2CHCH2
CH3


A-827
CH3
Cl
CH2CHCH2
CH2CH3


A-828
CH3
Cl
CH2CHCH2
CH2CH2CH3


A-829
CH3
Cl
CH2CHCH2
CH2CH2OCH3


A-830
CH3
Cl
CH2CHCH2
OCH3


A-831
CH3
Cl
CH2CCH
CH3


A-832
CH3
Cl
CH2CCH
CH2CH3


A-833
CH3
Cl
CH2CCH
CH2CH2CH3


A-834
CH3
Cl
CH2CCH
CH2CH2OCH3


A-835
CH3
Cl
CH2CCH
OCH3


A-836
CH3
Cl
CH2C6H5
CH3


A-837
CH3
Cl
CH2C6H5
CH2CH3


A-838
CH3
Cl
CH2C6H5
CH2CH2CH3


A-839
CH3
Cl
CH2C6H5
CH2CH2OCH3


A-840
CH3
Cl
CH2C6H5
OCH3


A-841
CH3
Br
CH3
CH3


A-842
CH3
Br
CH3
CH2CH3


A-843
CH3
Br
CH3
CH2CH2CH3


A-844
CH3
Br
CH3
CH2CH2OCH3


A-845
CH3
Br
CH3
OCH3


A-846
CH3
Br
CH2CH3
CH3


A-847
CH3
Br
CH2CH3
CH2CH3


A-848
CH3
Br
CH2CH3
CH2CH2CH3


A-849
CH3
Br
CH2CH3
CH2CH2OCH3


A-850
CH3
Br
CH2CH3
OCH3


A-851
CH3
Br
CH2OCH3
CH3


A-852
CH3
Br
CH2OCH3
CH2CH3


A-853
CH3
Br
CH2OCH3
CH2CH2CH3


A-854
CH3
Br
CH2OCH3
CH2CH2OCH3


A-855
CH3
Br
CH2OCH3
OCH3


A-856
CH3
Br
CH2OCH2CH3
CH3


A-857
CH3
Br
CH2OCH2CH3
CH2CH3


A-858
CH3
Br
CH2OCH2CH3
CH2CH2CH3


A-859
CH3
Br
CH2OCH2CH3
CH2CH2OCH3


A-860
CH3
Br
CH2OCH2CH3
OCH3


A-861
CH3
Br
CH2(CO)OCH3
CH3


A-862
CH3
Br
CH2(CO)OCH3
CH2CH3


A-863
CH3
Br
CH2(CO)OCH3
CH2CH2CH3


A-864
CH3
Br
CH2(CO)OCH3
CH2CH2OCH3


A-865
CH3
Br
CH2(CO)OCH3
OCH3


A-866
CH3
Br
CH2CHCH2
CH3


A-867
CH3
Br
CH2CHCH2
CH2CH3


A-868
CH3
Br
CH2CHCH2
CH2CH2CH3


A-869
CH3
Br
CH2CHCH2
CH2CH2OCH3


A-870
CH3
Br
CH2CHCH2
OCH3


A-871
CH3
Br
CH2CCH
CH3


A-872
CH3
Br
CH2CCH
CH2CH3


A-873
CH3
Br
CH2CCH
CH2CH2CH3


A-874
CH3
Br
CH2CCH
CH2CH2OCH3


A-875
CH3
Br
CH2CCH
OCH3


A-876
CH3
Br
CH2C6H5
CH3


A-877
CH3
Br
CH2C6H5
CH2CH3


A-878
CH3
Br
CH2C6H5
CH2CH2CH3


A-879
CH3
Br
CH2C6H5
CH2CH2OCH3


A-880
CH3
Br
CH2C6H5
OCH3


A-881
CH3
CN
CH3
CH3


A-882
CH3
CN
CH3
CH2CH3


A-883
CH3
CN
CH3
CH2CH2CH3


A-884
CH3
CN
CH3
CH2CH2OCH3


A-885
CH3
CN
CH3
OCH3


A-886
CH3
CN
CH2CH3
CH3


A-887
CH3
CN
CH2CH3
CH2CH3


A-888
CH3
CN
CH2CH3
CH2CH2CH3


A-889
CH3
CN
CH2CH3
CH2CH2OCH3


A-890
CH3
CN
CH2CH3
OCH3


A-891
CH3
CN
CH2OCH3
CH3


A-892
CH3
CN
CH2OCH3
CH2CH3


A-893
CH3
CN
CH2OCH3
CH2CH2CH3


A-894
CH3
CN
CH2OCH3
CH2CH2OCH3


A-895
CH3
CN
CH2OCH3
OCH3


A-896
CH3
CN
CH2OCH2CH3
CH3


A-897
CH3
CN
CH2OCH2CH3
CH2CH3


A-898
CH3
CN
CH2OCH2CH3
CH2CH2CH3


A-899
CH3
CN
CH2OCH2CH3
CH2CH2OCH3


A-900
CH3
CN
CH2OCH2CH3
OCH3


A-901
CH3
CN
CH2(CO)OCH3
CH3


A-902
CH3
CN
CH2(CO)OCH3
CH2CH3


A-903
CH3
CN
CH2(CO)OCH3
CH2CH2CH3


A-904
CH3
CN
CH2(CO)OCH3
CH2CH2OCH3


A-905
CH3
CN
CH2(CO)OCH3
OCH3


A-906
CH3
CN
CH2CHCH2
CH3


A-907
CH3
CN
CH2CHCH2
CH2CH3


A-908
CH3
CN
CH2CHCH2
CH2CH2CH3


A-909
CH3
CN
CH2CHCH2
CH2CH2OCH3


A-910
CH3
CN
CH2CHCH2
OCH3


A-911
CH3
CN
CH2CCH
CH3


A-912
CH3
CN
CH2CCH
CH2CH3


A-913
CH3
CN
CH2CCH
CH2CH2CH3


A-914
CH3
CN
CH2CCH
CH2CH2OCH3


A-915
CH3
CN
CH2CCH
OCH3


A-916
CH3
CN
CH2C6H5
CH3


A-917
CH3
CN
CH2C6H5
CH2CH3


A-918
CH3
CN
CH2C6H5
CH2CH2CH3


A-919
CH3
CN
CH2C6H5
CH2CH2OCH3


A-920
CH3
CN
CH2C6H5
OCH3


A-921
CH3
CH3
CH3
CH3


A-922
CH3
CH3
CH3
CH2CH3


A-923
CH3
CH3
CH3
CH2CH2CH3


A-924
CH3
CH3
CH3
CH2CH2OCH3


A-925
CH3
CH3
CH3
OCH3


A-926
CH3
CH3
CH2CH3
CH3


A-927
CH3
CH3
CH2CH3
CH2CH3


A-928
CH3
CH3
CH2CH3
CH2CH2CH3


A-929
CH3
CH3
CH2CH3
CH2CH2OCH3


A-930
CH3
CH3
CH2CH3
OCH3


A-931
CH3
CH3
CH2OCH3
CH3


A-932
CH3
CH3
CH2OCH3
CH2CH3


A-933
CH3
CH3
CH2OCH3
CH2CH2CH3


A-934
CH3
CH3
CH2OCH3
CH2CH2OCH3


A-935
CH3
CH3
CH2OCH3
OCH3


A-936
CH3
CH3
CH2OCH2CH3
CH3


A-937
CH3
CH3
CH2OCH2CH3
CH2CH3


A-938
CH3
CH3
CH2OCH2CH3
CH2CH2CH3


A-939
CH3
CH3
CH2OCH2CH3
CH2CH2OCH3


A-940
CH3
CH3
CH2OCH2CH3
OCH3


A-941
CH3
CH3
CH2(CO)OCH3
CH3


A-942
CH3
CH3
CH2(CO)OCH3
CH2CH3


A-943
CH3
CH3
CH2(CO)OCH3
CH2CH2CH3


A-944
CH3
CH3
CH2(CO)OCH3
CH2CH2OCH3


A-945
CH3
CH3
CH2(CO)OCH3
OCH3


A-946
CH3
CH3
CH2CHCH2
CH3


A-947
CH3
CH3
CH2CHCH2
CH2CH3


A-948
CH3
CH3
CH2CHCH2
CH2CH2CH3


A-949
CH3
CH3
CH2CHCH2
CH2CH2OCH3


A-950
CH3
CH3
CH2CHCH2
OCH3


A-951
CH3
CH3
CH2CCH
CH3


A-952
CH3
CH3
CH2CCH
CH2CH3


A-953
CH3
CH3
CH2CCH
CH2CH2CH3


A-954
CH3
CH3
CH2CCH
CH2CH2OCH3


A-955
CH3
CH3
CH2CCH
OCH3


A-956
CH3
CH3
CH2C6H5
CH3


A-957
CH3
CH3
CH2C6H5
CH2CH3


A-958
CH3
CH3
CH2C6H5
CH2CH2CH3


A-959
CH3
CH3
CH2C6H5
CH2CH2OCH3


A-960
CH3
CH3
CH2C6H5
OCH3


A-961
CH3
CF3
CH3
CH3


A-962
CH3
CF3
CH3
CH2CH3


A-963
CH3
CF3
CH3
CH2CH2CH3


A-964
CH3
CF3
CH3
CH2CH2OCH3


A-965
CH3
CF3
CH3
OCH3


A-966
CH3
CF3
CH2CH3
CH3


A-967
CH3
CF3
CH2CH3
CH2CH3


A-968
CH3
CF3
CH2CH3
CH2CH2CH3


A-969
CH3
CF3
CH2CH3
CH2CH2OCH3


A-970
CH3
CF3
CH2CH3
OCH3


A-971
CH3
CF3
CH2OCH3
CH3


A-972
CH3
CF3
CH2OCH3
CH2CH3


A-973
CH3
CF3
CH2OCH3
CH2CH2CH3


A-974
CH3
CF3
CH2OCH3
CH2CH2OCH3


A-975
CH3
CF3
CH2OCH3
OCH3


A-976
CH3
CF3
CH2OCH2CH3
CH3


A-977
CH3
CF3
CH2OCH2CH3
CH2CH3


A-978
CH3
CF3
CH2OCH2CH3
CH2CH2CH3


A-979
CH3
CF3
CH2OCH2CH3
CH2CH2OCH3


A-980
CH3
CF3
CH2OCH2CH3
OCH3


A-981
CH3
CF3
CH2(CO)OCH3
CH3


A-982
CH3
CF3
CH2(CO)OCH3
CH2CH3


A-983
CH3
CF3
CH2(CO)OCH3
CH2CH2CH3


A-984
CH3
CF3
CH2(CO)OCH3
CH2CH2OCH3


A-985
CH3
CF3
CH2(CO)OCH3
OCH3


A-986
CH3
CF3
CH2CHCH2
CH3


A-987
CH3
CF3
CH2CHCH2
CH2CH3


A-988
CH3
CF3
CH2CHCH2
CH2CH2CH3


A-989
CH3
CF3
CH2CHCH2
CH2CH2OCH3


A-990
CH3
CF3
CH2CHCH2
OCH3


A-991
CH3
CF3
CH2CCH
CH3


A-992
CH3
CF3
CH2CCH
CH2CH3


A-993
CH3
CF3
CH2CCH
CH2CH2CH3


A-994
CH3
CF3
CH2CCH
CH2CH2OCH3


A-995
CH3
CF3
CH2CCH
OCH3


A-996
CH3
CF3
CH2C6H5
CH3


A-997
CH3
CF3
CH2C6H5
CH2CH3


A-998
CH3
CF3
CH2C6H5
CH2CH2CH3


A-999
CH3
CF3
CH2C6H5
CH2CH2OCH3


A-1000
CH3
CF3
CH2C6H5
OCH3


A-1001
CH3
SO2CH3
CH3
CH3


A-1002
CH3
SO2CH3
CH3
CH2CH3


A-1003
CH3
SO2CH3
CH3
CH2CH2CH3


A-1004
CH3
SO2CH3
CH3
CH2CH2OCH3


A-1005
CH3
SO2CH3
CH3
OCH3


A-1006
CH3
SO2CH3
CH2CH3
CH3


A-1007
CH3
SO2CH3
CH2CH3
CH2CH3


A-1008
CH3
SO2CH3
CH2CH3
CH2CH2CH3


A-1009
CH3
SO2CH3
CH2CH3
CH2CH2OCH3


A-1010
CH3
SO2CH3
CH2CH3
OCH3


A-1011
CH3
SO2CH3
CH2OCH3
CH3


A-1012
CH3
SO2CH3
CH2OCH3
CH2CH3


A-1013
CH3
SO2CH3
CH2OCH3
CH2CH2CH3


A-1014
CH3
SO2CH3
CH2OCH3
CH2CH2OCH3


A-1015
CH3
SO2CH3
CH2OCH3
OCH3


A-1016
CH3
SO2CH3
CH2OCH2CH3
CH3


A-1017
CH3
SO2CH3
CH2OCH2CH3
CH2CH3


A-1018
CH3
SO2CH3
CH2OCH2CH3
CH2CH2CH3


A-1019
CH3
SO2CH3
CH2OCH2CH3
CH2CH2OCH3


A-1020
CH3
SO2CH3
CH2OCH2CH3
OCH3


A-1021
CH3
SO2CH3
CH2(CO)OCH3
CH3


A-1022
CH3
SO2CH3
CH2(CO)OCH3
CH2CH3


A-1023
CH3
SO2CH3
CH2(CO)OCH3
CH2CH2CH3


A-1024
CH3
SO2CH3
CH2(CO)OCH3
CH2CH2OCH3


A-1025
CH3
SO2CH3
CH2(CO)OCH3
OCH3


A-1026
CH3
SO2CH3
CH2CHCH2
CH3


A-1027
CH3
SO2CH3
CH2CHCH2
CH2CH3


A-1028
CH3
SO2CH3
CH2CHCH2
CH2CH2CH3


A-1029
CH3
SO2CH3
CH2CHCH2
CH2CH2OCH3


A-1030
CH3
SO2CH3
CH2CHCH2
OCH3


A-1031
CH3
SO2CH3
CH2CCH
CH3


A-1032
CH3
SO2CH3
CH2CCH
CH2CH3


A-1033
CH3
SO2CH3
CH2CCH
CH2CH2CH3


A-1034
CH3
SO2CH3
CH2CCH
CH2CH2OCH3


A-1035
CH3
SO2CH3
CH2CCH
OCH3


A-1036
CH3
SO2CH3
CH2C6H5
CH3


A-1037
CH3
SO2CH3
CH2C6H5
CH2CH3


A-1038
CH3
SO2CH3
CH2C6H5
CH2CH2CH3


A-1039
CH3
SO2CH3
CH2C6H5
CH2CH2OCH3


A-1040
CH3
SO2CH3
CH2C6H5
OCH3


A-1041
CH3
NO2
CH3
CH3


A-1042
CH3
NO2
CH3
CH2CH3


A-1043
CH3
NO2
CH3
CH2CH2CH3


A-1044
CH3
NO2
CH3
CH2CH2OCH3


A-1045
CH3
NO2
CH3
OCH3


A-1046
CH3
NO2
CH2CH3
CH3


A-1047
CH3
NO2
CH2CH3
CH2CH3


A-1048
CH3
NO2
CH2CH3
CH2CH2CH3


A-1049
CH3
NO2
CH2CH3
CH2CH2OCH3


A-1050
CH3
NO2
CH2CH3
OCH3


A-1051
CH3
NO2
CH2OCH3
CH3


A-1052
CH3
NO2
CH2OCH3
CH2CH3


A-1053
CH3
NO2
CH2OCH3
CH2CH2CH3


A-1054
CH3
NO2
CH2OCH3
CH2CH2OCH3


A-1055
CH3
NO2
CH2OCH3
OCH3


A-1056
CH3
NO2
CH2OCH2CH3
CH3


A-1057
CH3
NO2
CH2OCH2CH3
CH2CH3


A-1058
CH3
NO2
CH2OCH2CH3
CH2CH2CH3


A-1059
CH3
NO2
CH2OCH2CH3
CH2CH2OCH3


A-1060
CH3
NO2
CH2OCH2CH3
OCH3


A-1061
CH3
NO2
CH2(CO)OCH3
CH3


A-1062
CH3
NO2
CH2(CO)OCH3
CH2CH3


A-1063
CH3
NO2
CH2(CO)OCH3
CH2CH2CH3


A-1064
CH3
NO2
CH2(CO)OCH3
CH2CH2OCH3


A-1065
CH3
NO2
CH2(CO)OCH3
OCH3


A-1066
CH3
NO2
CH2CHCH2
CH3


A-1067
CH3
NO2
CH2CHCH2
CH2CH3


A-1068
CH3
NO2
CH2CHCH2
CH2CH2CH3


A-1069
CH3
NO2
CH2CHCH2
CH2CH2OCH3


A-1070
CH3
NO2
CH2CHCH2
OCH3


A-1071
CH3
NO2
CH2CCH
CH3


A-1072
CH3
NO2
CH2CCH
CH2CH3


A-1073
CH3
NO2
CH2CCH
CH2CH2CH3


A-1074
CH3
NO2
CH2CCH
CH2CH2OCH3


A-1075
CH3
NO2
CH2CCH
OCH3


A-1076
CH3
NO2
CH2C6H5
CH3


A-1077
CH3
NO2
CH2C6H5
CH2CH3


A-1078
CH3
NO2
CH2C6H5
CH2CH2CH3


A-1079
CH3
NO2
CH2C6H5
CH2CH2OCH3


A-1080
CH3
NO2
CH2C6H5
OCH3


A-1081
cyclopropyl
H
CH3
CH3


A-1082
cyclopropyl
H
CH3
CH2CH3


A-1083
cyclopropyl
H
CH3
CH2CH2CH3


A-1084
cyclopropyl
H
CH3
CH2CH2OCH3


A-1085
cyclopropyl
H
CH3
OCH3


A-1086
cyclopropyl
H
CH2CH3
CH3


A-1087
cyclopropyl
H
CH2CH3
CH2CH3


A-1088
cyclopropyl
H
CH2CH3
CH2CH2CH3


A-1089
cyclopropyl
H
CH2CH3
CH2CH2OCH3


A-1090
cyclopropyl
H
CH2CH3
OCH3


A-1091
cyclopropyl
H
CH2OCH3
CH3


A-1092
cyclopropyl
H
CH2OCH3
CH2CH3


A-1093
cyclopropyl
H
CH2OCH3
CH2CH2CH3


A-1094
cyclopropyl
H
CH2OCH3
CH2CH2OCH3


A-1095
cyclopropyl
H
CH2OCH3
OCH3


A-1096
cyclopropyl
H
CH2OCH2CH3
CH3


A-1097
cyclopropyl
H
CH2OCH2CH3
CH2CH3


A-1098
cyclopropyl
H
CH2OCH2CH3
CH2CH2CH3


A-1099
cyclopropyl
H
CH2OCH2CH3
CH2CH2OCH3


A-1100
cyclopropyl
H
CH2OCH2CH3
OCH3


A-1101
cyclopropyl
H
CH2(CO)OCH3
CH3


A-1102
cyclopropyl
H
CH2(CO)OCH3
CH2CH3


A-1103
cyclopropyl
H
CH2(CO)OCH3
CH2CH2CH3


A-1104
cyclopropyl
H
CH2(CO)OCH3
CH2CH2OCH3


A-1105
cyclopropyl
H
CH2(CO)OCH3
OCH3


A-1106
cyclopropyl
H
CH2CHCH2
CH3


A-1107
cyclopropyl
H
CH2CHCH2
CH2CH3


A-1108
cyclopropyl
H
CH2CHCH2
CH2CH2CH3


A-1109
cyclopropyl
H
CH2CHCH2
CH2CH2OCH3


A-1110
cyclopropyl
H
CH2CHCH2
OCH3


A-1111
cyclopropyl
H
CH2CCH
CH3


A-1112
cyclopropyl
H
CH2CCH
CH2CH3


A-1113
cyclopropyl
H
CH2CCH
CH2CH2CH3


A-1114
cyclopropyl
H
CH2CCH
CH2CH2OCH3


A-1115
cyclopropyl
H
CH2CCH
OCH3


A-1116
cyclopropyl
H
CH2C6H5
CH3


A-1117
cyclopropyl
H
CH2C6H5
CH2CH3


A-1118
cyclopropyl
H
CH2C6H5
CH2CH2CH3


A-1119
cyclopropyl
H
CH2C6H5
CH2CH2OCH3


A-1120
cyclopropyl
H
CH2C6H5
OCH3


A-1121
cyclopropyl
F
CH3
CH3


A-1122
cyclopropyl
F
CH3
CH2CH3


A-1123
cyclopropyl
F
CH3
CH2CH2CH3


A-1124
cyclopropyl
F
CH3
CH2CH2OCH3


A-1125
cyclopropyl
F
CH3
OCH3


A-1126
cyclopropyl
F
CH2CH3
CH3


A-1127
cyclopropyl
F
CH2CH3
CH2CH3


A-1128
cyclopropyl
F
CH2CH3
CH2CH2CH3


A-1129
cyclopropyl
F
CH2CH3
CH2CH2OCH3


A-1130
cyclopropyl
F
CH2CH3
OCH3


A-1131
cyclopropyl
F
CH2OCH3
CH3


A-1132
cyclopropyl
F
CH2OCH3
CH2CH3


A-1133
cyclopropyl
F
CH2OCH3
CH2CH2CH3


A-1134
cyclopropyl
F
CH2OCH3
CH2CH2OCH3


A-1135
cyclopropyl
F
CH2OCH3
OCH3


A-1136
cyclopropyl
F
CH2OCH2CH3
CH3


A-1137
cyclopropyl
F
CH2OCH2CH3
CH2CH3


A-1138
cyclopropyl
F
CH2OCH2CH3
CH2CH2CH3


A-1139
cyclopropyl
F
CH2OCH2CH3
CH2CH2OCH3


A-1140
cyclopropyl
F
CH2OCH2CH3
OCH3


A-1141
cyclopropyl
F
CH2(CO)OCH3
CH3


A-1142
cyclopropyl
F
CH2(CO)OCH3
CH2CH3


A-1143
cyclopropyl
F
CH2(CO)OCH3
CH2CH2CH3


A-1144
cyclopropyl
F
CH2(CO)OCH3
CH2CH2OCH3


A-1145
cyclopropyl
F
CH2(CO)OCH3
OCH3


A-1146
cyclopropyl
F
CH2CHCH2
CH3


A-1147
cyclopropyl
F
CH2CHCH2
CH2CH3


A-1148
cyclopropyl
F
CH2CHCH2
CH2CH2CH3


A-1149
cyclopropyl
F
CH2CHCH2
CH2CH2OCH3


A-1150
cyclopropyl
F
CH2CHCH2
OCH3


A-1151
cyclopropyl
F
CH2CCH
CH3


A-1152
cyclopropyl
F
CH2CCH
CH2CH3


A-1153
cyclopropyl
F
CH2CCH
CH2CH2CH3


A-1154
cyclopropyl
F
CH2CCH
CH2CH2OCH3


A-1155
cyclopropyl
F
CH2CCH
OCH3


A-1156
cyclopropyl
F
CH2C6H5
CH3


A-1157
cyclopropyl
F
CH2C6H5
CH2CH3


A-1158
cyclopropyl
F
CH2C6H5
CH2CH2CH3


A-1159
cyclopropyl
F
CH2C6H5
CH2CH2OCH3


A-1160
cyclopropyl
F
CH2C6H5
OCH3


A-1161
cyclopropyl
Cl
CH3
CH3


A-1162
cyclopropyl
Cl
CH3
CH2CH3


A-1163
cyclopropyl
Cl
CH3
CH2CH2CH3


A-1164
cyclopropyl
Cl
CH3
CH2CH2OCH3


A-1165
cyclopropyl
Cl
CH3
OCH3


A-1166
cyclopropyl
Cl
CH2CH3
CH3


A-1167
cyclopropyl
Cl
CH2CH3
CH2CH3


A-1168
cyclopropyl
Cl
CH2CH3
CH2CH2CH3


A-1169
cyclopropyl
Cl
CH2CH3
CH2CH2OCH3


A-1170
cyclopropyl
Cl
CH2CH3
OCH3


A-1171
cyclopropyl
Cl
CH2OCH3
CH3


A-1172
cyclopropyl
Cl
CH2OCH3
CH2CH3


A-1173
cyclopropyl
Cl
CH2OCH3
CH2CH2CH3


A-1174
cyclopropyl
Cl
CH2OCH3
CH2CH2OCH3


A-1175
cyclopropyl
Cl
CH2OCH3
OCH3


A-1176
cyclopropyl
Cl
CH2OCH2CH3
CH3


A-1177
cyclopropyl
Cl
CH2OCH2CH3
CH2CH3


A-1178
cyclopropyl
Cl
CH2OCH2CH3
CH2CH2CH3


A-1179
cyclopropyl
Cl
CH2OCH2CH3
CH2CH2OCH3


A-1180
cyclopropyl
Cl
CH2OCH2CH3
OCH3


A-1181
cyclopropyl
Cl
CH2(CO)OCH3
CH3


A-1182
cyclopropyl
Cl
CH2(CO)OCH3
CH2CH3


A-1183
cyclopropyl
Cl
CH2(CO)OCH3
CH2CH2CH3


A-1184
cyclopropyl
Cl
CH2(CO)OCH3
CH2CH2OCH3


A-1185
cyclopropyl
Cl
CH2(CO)OCH3
OCH3


A-1186
cyclopropyl
Cl
CH2CHCH2
CH3


A-1187
cyclopropyl
Cl
CH2CHCH2
CH2CH3


A-1188
cyclopropyl
Cl
CH2CHCH2
CH2CH2CH3


A-1189
cyclopropyl
Cl
CH2CHCH2
CH2CH2OCH3


A-1190
cyclopropyl
Cl
CH2CHCH2
OCH3


A-1191
cyclopropyl
Cl
CH2CCH
CH3


A-1192
cyclopropyl
Cl
CH2CCH
CH2CH3


A-1193
cyclopropyl
Cl
CH2CCH
CH2CH2CH3


A-1194
cyclopropyl
Cl
CH2CCH
CH2CH2OCH3


A-1195
cyclopropyl
Cl
CH2CCH
OCH3


A-1196
cyclopropyl
Cl
CH2C6H5
CH3


A-1197
cyclopropyl
Cl
CH2C6H5
CH2CH3


A-1198
cyclopropyl
Cl
CH2C6H5
CH2CH2CH3


A-1199
cyclopropyl
Cl
CH2C6H5
CH2CH2OCH3


A-1200
cyclopropyl
Cl
CH2C6H5
OCH3


A-1201
cyclopropyl
Br
CH3
CH3


A-1202
cyclopropyl
Br
CH3
CH2CH3


A-1203
cyclopropyl
Br
CH3
CH2CH2CH3


A-1204
cyclopropyl
Br
CH3
CH2CH2OCH3


A-1205
cyclopropyl
Br
CH3
OCH3


A-1206
cyclopropyl
Br
CH2CH3
CH3


A-1207
cyclopropyl
Br
CH2CH3
CH2CH3


A-1208
cyclopropyl
Br
CH2CH3
CH2CH2CH3


A-1209
cyclopropyl
Br
CH2CH3
CH2CH2OCH3


A-1210
cyclopropyl
Br
CH2CH3
OCH3


A-1211
cyclopropyl
Br
CH2OCH3
CH3


A-1212
cyclopropyl
Br
CH2OCH3
CH2CH3


A-1213
cyclopropyl
Br
CH2OCH3
CH2CH2CH3


A-1214
cyclopropyl
Br
CH2OCH3
CH2CH2OCH3


A-1215
cyclopropyl
Br
CH2OCH3
OCH3


A-1216
cyclopropyl
Br
CH2OCH2CH3
CH3


A-1217
cyclopropyl
Br
CH2OCH2CH3
CH2CH3


A-1218
cyclopropyl
Br
CH2OCH2CH3
CH2CH2CH3


A-1219
cyclopropyl
Br
CH2OCH2CH3
CH2CH2OCH3


A-1220
cyclopropyl
Br
CH2OCH2CH3
OCH3


A-1221
cyclopropyl
Br
CH2(CO)OCH3
CH3


A-1222
cyclopropyl
Br
CH2(CO)OCH3
CH2CH3


A-1223
cyclopropyl
Br
CH2(CO)OCH3
CH2CH2CH3


A-1224
cyclopropyl
Br
CH2(CO)OCH3
CH2CH2OCH3


A-1225
cyclopropyl
Br
CH2(CO)OCH3
OCH3


A-1226
cyclopropyl
Br
CH2CHCH2
CH3


A-1227
cyclopropyl
Br
CH2CHCH2
CH2CH3


A-1228
cyclopropyl
Br
CH2CHCH2
CH2CH2CH3


A-1229
cyclopropyl
Br
CH2CHCH2
CH2CH2OCH3


A-1230
cyclopropyl
Br
CH2CHCH2
OCH3


A-1231
cyclopropyl
Br
CH2CCH
CH3


A-1232
cyclopropyl
Br
CH2CCH
CH2CH3


A-1233
cyclopropyl
Br
CH2CCH
CH2CH2CH3


A-1234
cyclopropyl
Br
CH2CCH
CH2CH2OCH3


A-1235
cyclopropyl
Br
CH2CCH
OCH3


A-1236
cyclopropyl
Br
CH2C6H5
CH3


A-1237
cyclopropyl
Br
CH2C6H5
CH2CH3


A-1238
cyclopropyl
Br
CH2C6H5
CH2CH2CH3


A-1239
cyclopropyl
Br
CH2C6H5
CH2CH2OCH3


A-1240
cyclopropyl
Br
CH2C6H5
OCH3


A-1241
cyclopropyl
CN
CH3
CH3


A-1242
cyclopropyl
CN
CH3
CH2CH3


A-1243
cyclopropyl
CN
CH3
CH2CH2CH3


A-1244
cyclopropyl
CN
CH3
CH2CH2OCH3


A-1245
cyclopropyl
CN
CH3
OCH3


A-1246
cyclopropyl
CN
CH2CH3
CH3


A-1247
cyclopropyl
CN
CH2CH3
CH2CH3


A-1248
cyclopropyl
CN
CH2CH3
CH2CH2CH3


A-1249
cyclopropyl
CN
CH2CH3
CH2CH2OCH3


A-1250
cyclopropyl
CN
CH2CH3
OCH3


A-1251
cyclopropyl
CN
CH2OCH3
CH3


A-1252
cyclopropyl
CN
CH2OCH3
CH2CH3


A-1253
cyclopropyl
CN
CH2OCH3
CH2CH2CH3


A-1254
cyclopropyl
CN
CH2OCH3
CH2CH2OCH3


A-1255
cyclopropyl
CN
CH2OCH3
OCH3


A-1256
cyclopropyl
CN
CH2OCH2CH3
CH3


A-1257
cyclopropyl
CN
CH2OCH2CH3
CH2CH3


A-1258
cyclopropyl
CN
CH2OCH2CH3
CH2CH2CH3


A-1259
cyclopropyl
CN
CH2OCH2CH3
CH2CH2OCH3


A-1260
cyclopropyl
CN
CH2OCH2CH3
OCH3


A-1261
cyclopropyl
CN
CH2(CO)OCH3
CH3


A-1262
cyclopropyl
CN
CH2(CO)OCH3
CH2CH3


A-1263
cyclopropyl
CN
CH2(CO)OCH3
CH2CH2CH3


A-1264
cyclopropyl
CN
CH2(CO)OCH3
CH2CH2OCH3


A-1265
cyclopropyl
CN
CH2(CO)OCH3
OCH3


A-1266
cyclopropyl
CN
CH2CHCH2
CH3


A-1267
cyclopropyl
CN
CH2CHCH2
CH2CH3


A-1268
cyclopropyl
CN
CH2CHCH2
CH2CH2CH3


A-1269
cyclopropyl
CN
CH2CHCH2
CH2CH2OCH3


A-1270
cyclopropyl
CN
CH2CHCH2
OCH3


A-1271
cyclopropyl
CN
CH2CCH
CH3


A-1272
cyclopropyl
CN
CH2CCH
CH2CH3


A-1273
cyclopropyl
CN
CH2CCH
CH2CH2CH3


A-1274
cyclopropyl
CN
CH2CCH
CH2CH2OCH3


A-1275
cyclopropyl
CN
CH2CCH
OCH3


A-1276
cyclopropyl
CN
CH2C6H5
CH3


A-1277
cyclopropyl
CN
CH2C6H5
CH2CH3


A-1278
cyclopropyl
CN
CH2C6H5
CH2CH2CH3


A-1279
cyclopropyl
CN
CH2C6H5
CH2CH2OCH3


A-1280
cyclopropyl
CN
CH2C6H5
OCH3


A-1281
cyclopropyl
CH3
CH3
CH3


A-1282
cyclopropyl
CH3
CH3
CH2CH3


A-1283
cyclopropyl
CH3
CH3
CH2CH2CH3


A-1284
cyclopropyl
CH3
CH3
CH2CH2OCH3


A-1285
cyclopropyl
CH3
CH3
OCH3


A-1286
cyclopropyl
CH3
CH2CH3
CH3


A-1287
cyclopropyl
CH3
CH2CH3
CH2CH3


A-1288
cyclopropyl
CH3
CH2CH3
CH2CH2CH3


A-1289
cyclopropyl
CH3
CH2CH3
CH2CH2OCH3


A-1290
cyclopropyl
CH3
CH2CH3
OCH3


A-1291
cyclopropyl
CH3
CH2OCH3
CH3


A-1292
cyclopropyl
CH3
CH2OCH3
CH2CH3


A-1293
cyclopropyl
CH3
CH2OCH3
CH2CH2CH3


A-1294
cyclopropyl
CH3
CH2OCH3
CH2CH2OCH3


A-1295
cyclopropyl
CH3
CH2OCH3
OCH3


A-1296
cyclopropyl
CH3
CH2OCH2CH3
CH3


A-1297
cyclopropyl
CH3
CH2OCH2CH3
CH2CH3


A-1298
cyclopropyl
CH3
CH2OCH2CH3
CH2CH2CH3


A-1299
cyclopropyl
CH3
CH2OCH2CH3
CH2CH2OCH3


A-1300
cyclopropyl
CH3
CH2OCH2CH3
OCH3


A-1301
cyclopropyl
CH3
CH2(CO)OCH3
CH3


A-1302
cyclopropyl
CH3
CH2(CO)OCH3
CH2CH3


A-1303
cyclopropyl
CH3
CH2(CO)OCH3
CH2CH2CH3


A-1304
cyclopropyl
CH3
CH2(CO)OCH3
CH2CH2OCH3


A-1305
cyclopropyl
CH3
CH2(CO)OCH3
OCH3


A-1306
cyclopropyl
CH3
CH2CHCH2
CH3


A-1307
cyclopropyl
CH3
CH2CHCH2
CH2CH3


A-1308
cyclopropyl
CH3
CH2CHCH2
CH2CH2CH3


A-1309
cyclopropyl
CH3
CH2CHCH2
CH2CH2OCH3


A-1310
cyclopropyl
CH3
CH2CHCH2
OCH3


A-1311
cyclopropyl
CH3
CH2CCH
CH3


A-1312
cyclopropyl
CH3
CH2CCH
CH2CH3


A-1313
cyclopropyl
CH3
CH2CCH
CH2CH2CH3


A-1314
cyclopropyl
CH3
CH2CCH
CH2CH2OCH3


A-1315
cyclopropyl
CH3
CH2CCH
OCH3


A-1316
cyclopropyl
CH3
CH2C6H5
CH3


A-1317
cyclopropyl
CH3
CH2C6H5
CH2CH3


A-1318
cyclopropyl
CH3
CH2C6H5
CH2CH2CH3


A-1319
cyclopropyl
CH3
CH2C6H5
CH2CH2OCH3


A-1320
cyclopropyl
CH3
CH2C6H5
OCH3


A-1321
cyclopropyl
CF3
CH3
CH3


A-1322
cyclopropyl
CF3
CH3
CH2CH3


A-1323
cyclopropyl
CF3
CH3
CH2CH2CH3


A-1324
cyclopropyl
CF3
CH3
CH2CH2OCH3


A-1325
cyclopropyl
CF3
CH3
OCH3


A-1326
cyclopropyl
CF3
CH2CH3
CH3


A-1327
cyclopropyl
CF3
CH2CH3
CH2CH3


A-1328
cyclopropyl
CF3
CH2CH3
CH2CH2CH3


A-1329
cyclopropyl
CF3
CH2CH3
CH2CH2OCH3


A-1330
cyclopropyl
CF3
CH2CH3
OCH3


A-1331
cyclopropyl
CF3
CH2OCH3
CH3


A-1332
cyclopropyl
CF3
CH2OCH3
CH2CH3


A-1333
cyclopropyl
CF3
CH2OCH3
CH2CH2CH3


A-1334
cyclopropyl
CF3
CH2OCH3
CH2CH2OCH3


A-1335
cyclopropyl
CF3
CH2OCH3
OCH3


A-1336
cyclopropyl
CF3
CH2OCH2CH3
CH3


A-1337
cyclopropyl
CF3
CH2OCH2CH3
CH2CH3


A-1338
cyclopropyl
CF3
CH2OCH2CH3
CH2CH2CH3


A-1339
cyclopropyl
CF3
CH2OCH2CH3
CH2CH2OCH3


A-1340
cyclopropyl
CF3
CH2OCH2CH3
OCH3


A-1341
cyclopropyl
CF3
CH2(CO)OCH3
CH3


A-1342
cyclopropyl
CF3
CH2(CO)OCH3
CH2CH3


A-1343
cyclopropyl
CF3
CH2(CO)OCH3
CH2CH2CH3


A-1344
cyclopropyl
CF3
CH2(CO)OCH3
CH2CH2OCH3


A-1345
cyclopropyl
CF3
CH2(CO)OCH3
OCH3


A-1346
cyclopropyl
CF3
CH2CHCH2
CH3


A-1347
cyclopropyl
CF3
CH2CHCH2
CH2CH3


A-1348
cyclopropyl
CF3
CH2CHCH2
CH2CH2CH3


A-1349
cyclopropyl
CF3
CH2CHCH2
CH2CH2OCH3


A-1350
cyclopropyl
CF3
CH2CHCH2
OCH3


A-1351
cyclopropyl
CF3
CH2CCH
CH3


A-1352
cyclopropyl
CF3
CH2CCH
CH2CH3


A-1353
cyclopropyl
CF3
CH2CCH
CH2CH2CH3


A-1354
cyclopropyl
CF3
CH2CCH
CH2CH2OCH3


A-1355
cyclopropyl
CF3
CH2CCH
OCH3


A-1356
cyclopropyl
CF3
CH2C6H5
CH3


A-1357
cyclopropyl
CF3
CH2C6H5
CH2CH3


A-1358
cyclopropyl
CF3
CH2C6H5
CH2CH2CH3


A-1359
cyclopropyl
CF3
CH2C6H5
CH2CH2OCH3


A-1360
cyclopropyl
CF3
CH2C6H5
OCH3


A-1361
cyclopropyl
SO2CH3
CH3
CH3


A-1362
cyclopropyl
SO2CH3
CH3
CH2CH3


A-1363
cyclopropyl
SO2CH3
CH3
CH2CH2CH3


A-1364
cyclopropyl
SO2CH3
CH3
CH2CH2OCH3


A-1365
cyclopropyl
SO2CH3
CH3
OCH3


A-1366
cyclopropyl
SO2CH3
CH2CH3
CH3


A-1367
cyclopropyl
SO2CH3
CH2CH3
CH2CH3


A-1368
cyclopropyl
SO2CH3
CH2CH3
CH2CH2CH3


A-1369
cyclopropyl
SO2CH3
CH2CH3
CH2CH2OCH3


A-1370
cyclopropyl
SO2CH3
CH2CH3
OCH3


A-1371
cyclopropyl
SO2CH3
CH2OCH3
CH3


A-1372
cyclopropyl
SO2CH3
CH2OCH3
CH2CH3


A-1373
cyclopropyl
SO2CH3
CH2OCH3
CH2CH2CH3


A-1374
cyclopropyl
SO2CH3
CH2OCH3
CH2CH2OCH3


A-1375
cyclopropyl
SO2CH3
CH2OCH3
OCH3


A-1376
cyclopropyl
SO2CH3
CH2OCH2CH3
CH3


A-1377
cyclopropyl
SO2CH3
CH2OCH2CH3
CH2CH3


A-1378
cyclopropyl
SO2CH3
CH2OCH2CH3
CH2CH2CH3


A-1379
cyclopropyl
SO2CH3
CH2OCH2CH3
CH2CH2OCH3


A-1380
cyclopropyl
SO2CH3
CH2OCH2CH3
OCH3


A-1381
cyclopropyl
SO2CH3
CH2(CO)OCH3
CH3


A-1382
cyclopropyl
SO2CH3
CH2(CO)OCH3
CH2CH3


A-1383
cyclopropyl
SO2CH3
CH2(CO)OCH3
CH2CH2CH3


A-1384
cyclopropyl
SO2CH3
CH2(CO)OCH3
CH2CH2OCH3


A-1385
cyclopropyl
SO2CH3
CH2(CO)OCH3
OCH3


A-1386
cyclopropyl
SO2CH3
CH2CHCH2
CH3


A-1387
cyclopropyl
SO2CH3
CH2CHCH2
CH2CH3


A-1388
cyclopropyl
SO2CH3
CH2CHCH2
CH2CH2CH3


A-1389
cyclopropyl
SO2CH3
CH2CHCH2
CH2CH2OCH3


A-1390
cyclopropyl
SO2CH3
CH2CHCH2
OCH3


A-1391
cyclopropyl
SO2CH3
CH2CCH
CH3


A-1392
cyclopropyl
SO2CH3
CH2CCH
CH2CH3


A-1393
cyclopropyl
SO2CH3
CH2CCH
CH2CH2CH3


A-1394
cyclopropyl
SO2CH3
CH2CCH
CH2CH2OCH3


A-1395
cyclopropyl
SO2CH3
CH2CCH
OCH3


A-1396
cyclopropyl
SO2CH3
CH2C6H5
CH3


A-1397
cyclopropyl
SO2CH3
CH2C6H5
CH2CH3


A-1398
cyclopropyl
SO2CH3
CH2C6H5
CH2CH2CH3


A-1399
cyclopropyl
SO2CH3
CH2C6H5
CH2CH2OCH3


A-1400
cyclopropyl
SO2CH3
CH2C6H5
OCH3


A-1401
cyclopropyl
NO2
CH3
CH3


A-1402
cyclopropyl
NO2
CH3
CH2CH3


A-1403
cyclopropyl
NO2
CH3
CH2CH2CH3


A-1404
cyclopropyl
NO2
CH3
CH2CH2OCH3


A-1405
cyclopropyl
NO2
CH3
OCH3


A-1406
cyclopropyl
NO2
CH2CH3
CH3


A-1407
cyclopropyl
NO2
CH2CH3
CH2CH3


A-1408
cyclopropyl
NO2
CH2CH3
CH2CH2CH3


A-1409
cyclopropyl
NO2
CH2CH3
CH2CH2OCH3


A-1410
cyclopropyl
NO2
CH2CH3
OCH3


A-1411
cyclopropyl
NO2
CH2OCH3
CH3


A-1412
cyclopropyl
NO2
CH2OCH3
CH2CH3


A-1413
cyclopropyl
NO2
CH2OCH3
CH2CH2CH3


A-1414
cyclopropyl
NO2
CH2OCH3
CH2CH2OCH3


A-1415
cyclopropyl
NO2
CH2OCH3
OCH3


A-1416
cyclopropyl
NO2
CH2OCH2CH3
CH3


A-1417
cyclopropyl
NO2
CH2OCH2CH3
CH2CH3


A-1418
cyclopropyl
NO2
CH2OCH2CH3
CH2CH2CH3


A-1419
cyclopropyl
NO2
CH2OCH2CH3
CH2CH2OCH3


A-1420
cyclopropyl
NO2
CH2OCH2CH3
OCH3


A-1421
cyclopropyl
NO2
CH2(CO)OCH3
CH3


A-1422
cyclopropyl
NO2
CH2(CO)OCH3
CH2CH3


A-1423
cyclopropyl
NO2
CH2(CO)OCH3
CH2CH2CH3


A-1424
cyclopropyl
NO2
CH2(CO)OCH3
CH2CH2OCH3


A-1425
cyclopropyl
NO2
CH2(CO)OCH3
OCH3


A-1426
cyclopropyl
NO2
CH2CHCH2
CH3


A-1427
cyclopropyl
NO2
CH2CHCH2
CH2CH3


A-1428
cyclopropyl
NO2
CH2CHCH2
CH2CH2CH3


A-1429
cyclopropyl
NO2
CH2CHCH2
CH2CH2OCH3


A-1430
cyclopropyl
NO2
CH2CHCH2
OCH3


A-1431
cyclopropyl
NO2
CH2CCH
CH3


A-1432
cyclopropyl
NO2
CH2CCH
CH2CH3


A-1433
cyclopropyl
NO2
CH2CCH
CH2CH2CH3


A-1434
cyclopropyl
NO2
CH2CCH
CH2CH2OCH3


A-1435
cyclopropyl
NO2
CH2CCH
OCH3


A-1436
cyclopropyl
NO2
CH2C6H5
CH3


A-1437
cyclopropyl
NO2
CH2C6H5
CH2CH3


A-1438
cyclopropyl
NO2
CH2C6H5
CH2CH2CH3


A-1439
cyclopropyl
NO2
CH2C6H5
CH2CH2OCH3


A-1440
cyclopropyl
NO2
CH2C6H5
OCH3


A-1441
CH2OCH3
H
CH3
CH3


A-1442
CH2OCH3
H
CH3
CH2CH3


A-1443
CH2OCH3
H
CH3
CH2CH2CH3


A-1444
CH2OCH3
H
CH3
CH2CH2OCH3


A-1445
CH2OCH3
H
CH3
OCH3


A-1446
CH2OCH3
H
CH2CH3
CH3


A-1447
CH2OCH3
H
CH2CH3
CH2CH3


A-1448
CH2OCH3
H
CH2CH3
CH2CH2CH3


A-1449
CH2OCH3
H
CH2CH3
CH2CH2OCH3


A-1450
CH2OCH3
H
CH2CH3
OCH3


A-1451
CH2OCH3
H
CH2OCH3
CH3


A-1452
CH2OCH3
H
CH2OCH3
CH2CH3


A-1453
CH2OCH3
H
CH2OCH3
CH2CH2CH3


A-1454
CH2OCH3
H
CH2OCH3
CH2CH2OCH3


A-1455
CH2OCH3
H
CH2OCH3
OCH3


A-1456
CH2OCH3
H
CH2OCH2CH3
CH3


A-1457
CH2OCH3
H
CH2OCH2CH3
CH2CH3


A-1458
CH2OCH3
H
CH2OCH2CH3
CH2CH2CH3


A-1459
CH2OCH3
H
CH2OCH2CH3
CH2CH2OCH3


A-1460
CH2OCH3
H
CH2OCH2CH3
OCH3


A-1461
CH2OCH3
H
CH2(CO)OCH3
CH3


A-1462
CH2OCH3
H
CH2(CO)OCH3
CH2CH3


A-1463
CH2OCH3
H
CH2(CO)OCH3
CH2CH2CH3


A-1464
CH2OCH3
H
CH2(CO)OCH3
CH2CH2OCH3


A-1465
CH2OCH3
H
CH2(CO)OCH3
OCH3


A-1466
CH2OCH3
H
CH2CHCH2
CH3


A-1467
CH2OCH3
H
CH2CHCH2
CH2CH3


A-1468
CH2OCH3
H
CH2CHCH2
CH2CH2CH3


A-1469
CH2OCH3
H
CH2CHCH2
CH2CH2OCH3


A-1470
CH2OCH3
H
CH2CHCH2
OCH3


A-1471
CH2OCH3
H
CH2CCH
CH3


A-1472
CH2OCH3
H
CH2CCH
CH2CH3


A-1473
CH2OCH3
H
CH2CCH
CH2CH2CH3


A-1474
CH2OCH3
H
CH2CCH
CH2CH2OCH3


A-1475
CH2OCH3
H
CH2CCH
OCH3


A-1476
CH2OCH3
H
CH2C6H5
CH3


A-1477
CH2OCH3
H
CH2C6H5
CH2CH3


A-1478
CH2OCH3
H
CH2C6H5
CH2CH2CH3


A-1479
CH2OCH3
H
CH2C6H5
CH2CH2OCH3


A-1480
CH2OCH3
H
CH2C6H5
OCH3


A-1481
CH2OCH3
F
CH3
CH3


A-1482
CH2OCH3
F
CH3
CH2CH3


A-1483
CH2OCH3
F
CH3
CH2CH2CH3


A-1484
CH2OCH3
F
CH3
CH2CH2OCH3


A-1485
CH2OCH3
F
CH3
OCH3


A-1486
CH2OCH3
F
CH2CH3
CH3


A-1487
CH2OCH3
F
CH2CH3
CH2CH3


A-1488
CH2OCH3
F
CH2CH3
CH2CH2CH3


A-1489
CH2OCH3
F
CH2CH3
CH2CH2OCH3


A-1490
CH2OCH3
F
CH2CH3
OCH3


A-1491
CH2OCH3
F
CH2OCH3
CH3


A-1492
CH2OCH3
F
CH2OCH3
CH2CH3


A-1493
CH2OCH3
F
CH2OCH3
CH2CH2CH3


A-1494
CH2OCH3
F
CH2OCH3
CH2CH2OCH3


A-1495
CH2OCH3
F
CH2OCH3
OCH3


A-1496
CH2OCH3
F
CH2OCH2CH3
CH3


A-1497
CH2OCH3
F
CH2OCH2CH3
CH2CH3


A-1498
CH2OCH3
F
CH2OCH2CH3
CH2CH2CH3


A-1499
CH2OCH3
F
CH2OCH2CH3
CH2CH2OCH3


A-1500
CH2OCH3
F
CH2OCH2CH3
OCH3


A-1501
CH2OCH3
F
CH2(CO)OCH3
CH3


A-1502
CH2OCH3
F
CH2(CO)OCH3
CH2CH3


A-1503
CH2OCH3
F
CH2(CO)OCH3
CH2CH2CH3


A-1504
CH2OCH3
F
CH2(CO)OCH3
CH2CH2OCH3


A-1505
CH2OCH3
F
CH2(CO)OCH3
OCH3


A-1506
CH2OCH3
F
CH2CHCH2
CH3


A-1507
CH2OCH3
F
CH2CHCH2
CH2CH3


A-1508
CH2OCH3
F
CH2CHCH2
CH2CH2CH3


A-1509
CH2OCH3
F
CH2CHCH2
CH2CH2OCH3


A-1510
CH2OCH3
F
CH2CHCH2
OCH3


A-1511
CH2OCH3
F
CH2CCH
CH3


A-1512
CH2OCH3
F
CH2CCH
CH2CH3


A-1513
CH2OCH3
F
CH2CCH
CH2CH2CH3


A-1514
CH2OCH3
F
CH2CCH
CH2CH2OCH3


A-1515
CH2OCH3
F
CH2CCH
OCH3


A-1516
CH2OCH3
F
CH2C6H5
CH3


A-1517
CH2OCH3
F
CH2C6H5
CH2CH3


A-1518
CH2OCH3
F
CH2C6H5
CH2CH2CH3


A-1519
CH2OCH3
F
CH2C6H5
CH2CH2OCH3


A-1520
CH2OCH3
F
CH2C6H5
OCH3


A-1521
CH2OCH3
Cl
CH3
CH3


A-1522
CH2OCH3
Cl
CH3
CH2CH3


A-1523
CH2OCH3
Cl
CH3
CH2CH2CH3


A-1524
CH2OCH3
Cl
CH3
CH2CH2OCH3


A-1525
CH2OCH3
Cl
CH3
OCH3


A-1526
CH2OCH3
Cl
CH2CH3
CH3


A-1527
CH2OCH3
Cl
CH2CH3
CH2CH3


A-1528
CH2OCH3
Cl
CH2CH3
CH2CH2CH3


A-1529
CH2OCH3
Cl
CH2CH3
CH2CH2OCH3


A-1530
CH2OCH3
Cl
CH2CH3
OCH3


A-1531
CH2OCH3
Cl
CH2OCH3
CH3


A-1532
CH2OCH3
Cl
CH2OCH3
CH2CH3


A-1533
CH2OCH3
Cl
CH2OCH3
CH2CH2CH3


A-1534
CH2OCH3
Cl
CH2OCH3
CH2CH2OCH3


A-1535
CH2OCH3
Cl
CH2OCH3
OCH3


A-1536
CH2OCH3
Cl
CH2OCH2CH3
CH3


A-1537
CH2OCH3
Cl
CH2OCH2CH3
CH2CH3


A-1538
CH2OCH3
Cl
CH2OCH2CH3
CH2CH2CH3


A-1539
CH2OCH3
Cl
CH2OCH2CH3
CH2CH2OCH3


A-1540
CH2OCH3
Cl
CH2OCH2CH3
OCH3


A-1541
CH2OCH3
Cl
CH2(CO)OCH3
CH3


A-1542
CH2OCH3
Cl
CH2(CO)OCH3
CH2CH3


A-1543
CH2OCH3
Cl
CH2(CO)OCH3
CH2CH2CH3


A-1544
CH2OCH3
Cl
CH2(CO)OCH3
CH2CH2OCH3


A-1545
CH2OCH3
Cl
CH2(CO)OCH3
OCH3


A-1546
CH2OCH3
Cl
CH2CHCH2
CH3


A-1547
CH2OCH3
Cl
CH2CHCH2
CH2CH3


A-1548
CH2OCH3
Cl
CH2CHCH2
CH2CH2CH3


A-1549
CH2OCH3
Cl
CH2CHCH2
CH2CH2OCH3


A-1550
CH2OCH3
Cl
CH2CHCH2
OCH3


A-1551
CH2OCH3
Cl
CH2CCH
CH3


A-1552
CH2OCH3
Cl
CH2CCH
CH2CH3


A-1553
CH2OCH3
Cl
CH2CCH
CH2CH2CH3


A-1554
CH2OCH3
Cl
CH2CCH
CH2CH2OCH3


A-1555
CH2OCH3
Cl
CH2CCH
OCH3


A-1556
CH2OCH3
Cl
CH2C6H5
CH3


A-1557
CH2OCH3
Cl
CH2C6H5
CH2CH3


A-1558
CH2OCH3
Cl
CH2C6H5
CH2CH2CH3


A-1559
CH2OCH3
Cl
CH2C6H5
CH2CH2OCH3


A-1560
CH2OCH3
Cl
CH2C6H5
OCH3


A-1561
CH2OCH3
Br
CH3
CH3


A-1562
CH2OCH3
Br
CH3
CH2CH3


A-1563
CH2OCH3
Br
CH3
CH2CH2CH3


A-1564
CH2OCH3
Br
CH3
CH2CH2OCH3


A-1565
CH2OCH3
Br
CH3
OCH3


A-1566
CH2OCH3
Br
CH2CH3
CH3


A-1567
CH2OCH3
Br
CH2CH3
CH2CH3


A-1568
CH2OCH3
Br
CH2CH3
CH2CH2CH3


A-1569
CH2OCH3
Br
CH2CH3
CH2CH2OCH3


A-1570
CH2OCH3
Br
CH2CH3
OCH3


A-1571
CH2OCH3
Br
CH2OCH3
CH3


A-1572
CH2OCH3
Br
CH2OCH3
CH2CH3


A-1573
CH2OCH3
Br
CH2OCH3
CH2CH2CH3


A-1574
CH2OCH3
Br
CH2OCH3
CH2CH2OCH3


A-1575
CH2OCH3
Br
CH2OCH3
OCH3


A-1576
CH2OCH3
Br
CH2OCH2CH3
CH3


A-1577
CH2OCH3
Br
CH2OCH2CH3
CH2CH3


A-1578
CH2OCH3
Br
CH2OCH2CH3
CH2CH2CH3


A-1579
CH2OCH3
Br
CH2OCH2CH3
CH2CH2OCH3


A-1580
CH2OCH3
Br
CH2OCH2CH3
OCH3


A-1581
CH2OCH3
Br
CH2(CO)OCH3
CH3


A-1582
CH2OCH3
Br
CH2(CO)OCH3
CH2CH3


A-1583
CH2OCH3
Br
CH2(CO)OCH3
CH2CH2CH3


A-1584
CH2OCH3
Br
CH2(CO)OCH3
CH2CH2OCH3


A-1585
CH2OCH3
Br
CH2(CO)OCH3
OCH3


A-1586
CH2OCH3
Br
CH2CHCH2
CH3


A-1587
CH2OCH3
Br
CH2CHCH2
CH2CH3


A-1588
CH2OCH3
Br
CH2CHCH2
CH2CH2CH3


A-1589
CH2OCH3
Br
CH2CHCH2
CH2CH2OCH3


A-1590
CH2OCH3
Br
CH2CHCH2
OCH3


A-1591
CH2OCH3
Br
CH2CCH
CH3


A-1592
CH2OCH3
Br
CH2CCH
CH2CH3


A-1593
CH2OCH3
Br
CH2CCH
CH2CH2CH3


A-1594
CH2OCH3
Br
CH2CCH
CH2CH2OCH3


A-1595
CH2OCH3
Br
CH2CCH
OCH3


A-1596
CH2OCH3
Br
CH2C6H5
CH3


A-1597
CH2OCH3
Br
CH2C6H5
CH2CH3


A-1598
CH2OCH3
Br
CH2C6H5
CH2CH2CH3


A-1599
CH2OCH3
Br
CH2C6H5
CH2CH2OCH3


A-1600
CH2OCH3
Br
CH2C6H5
OCH3


A-1601
CH2OCH3
CN
CH3
CH3


A-1602
CH2OCH3
CN
CH3
CH2CH3


A-1603
CH2OCH3
CN
CH3
CH2CH2CH3


A-1604
CH2OCH3
CN
CH3
CH2CH2OCH3


A-1605
CH2OCH3
CN
CH3
OCH3


A-1606
CH2OCH3
CN
CH2CH3
CH3


A-1607
CH2OCH3
CN
CH2CH3
CH2CH3


A-1608
CH2OCH3
CN
CH2CH3
CH2CH2CH3


A-1609
CH2OCH3
CN
CH2CH3
CH2CH2OCH3


A-1610
CH2OCH3
CN
CH2CH3
OCH3


A-1611
CH2OCH3
CN
CH2OCH3
CH3


A-1612
CH2OCH3
CN
CH2OCH3
CH2CH3


A-1613
CH2OCH3
CN
CH2OCH3
CH2CH2CH3


A-1614
CH2OCH3
CN
CH2OCH3
CH2CH2OCH3


A-1615
CH2OCH3
CN
CH2OCH3
OCH3


A-1616
CH2OCH3
CN
CH2OCH2CH3
CH3


A-1617
CH2OCH3
CN
CH2OCH2CH3
CH2CH3


A-1618
CH2OCH3
CN
CH2OCH2CH3
CH2CH2CH3


A-1619
CH2OCH3
CN
CH2OCH2CH3
CH2CH2OCH3


A-1620
CH2OCH3
CN
CH2OCH2CH3
OCH3


A-1621
CH2OCH3
CN
CH2(CO)OCH3
CH3


A-1622
CH2OCH3
CN
CH2(CO)OCH3
CH2CH3


A-1623
CH2OCH3
CN
CH2(CO)OCH3
CH2CH2CH3


A-1624
CH2OCH3
CN
CH2(CO)OCH3
CH2CH2OCH3


A-1625
CH2OCH3
CN
CH2(CO)OCH3
OCH3


A-1626
CH2OCH3
CN
CH2CHCH2
CH3


A-1627
CH2OCH3
CN
CH2CHCH2
CH2CH3


A-1628
CH2OCH3
CN
CH2CHCH2
CH2CH2CH3


A-1629
CH2OCH3
CN
CH2CHCH2
CH2CH2OCH3


A-1630
CH2OCH3
CN
CH2CHCH2
OCH3


A-1631
CH2OCH3
CN
CH2CCH
CH3


A-1632
CH2OCH3
CN
CH2CCH
CH2CH3


A-1633
CH2OCH3
CN
CH2CCH
CH2CH2CH3


A-1634
CH2OCH3
CN
CH2CCH
CH2CH2OCH3


A-1635
CH2OCH3
CN
CH2CCH
OCH3


A-1636
CH2OCH3
CN
CH2C6H5
CH3


A-1637
CH2OCH3
CN
CH2C6H5
CH2CH3


A-1638
CH2OCH3
CN
CH2C6H5
CH2CH2CH3


A-1639
CH2OCH3
CN
CH2C6H5
CH2CH2OCH3


A-1640
CH2OCH3
CN
CH2C6H5
OCH3


A-1641
CH2OCH3
CH3
CH3
CH3


A-1642
CH2OCH3
CH3
CH3
CH2CH3


A-1643
CH2OCH3
CH3
CH3
CH2CH2CH3


A-1644
CH2OCH3
CH3
CH3
CH2CH2OCH3


A-1645
CH2OCH3
CH3
CH3
OCH3


A-1646
CH2OCH3
CH3
CH2CH3
CH3


A-1647
CH2OCH3
CH3
CH2CH3
CH2CH3


A-1648
CH2OCH3
CH3
CH2CH3
CH2CH2CH3


A-1649
CH2OCH3
CH3
CH2CH3
CH2CH2OCH3


A-1650
CH2OCH3
CH3
CH2CH3
OCH3


A-1651
CH2OCH3
CH3
CH2OCH3
CH3


A-1652
CH2OCH3
CH3
CH2OCH3
CH2CH3


A-1653
CH2OCH3
CH3
CH2OCH3
CH2CH2CH3


A-1654
CH2OCH3
CH3
CH2OCH3
CH2CH2OCH3


A-1655
CH2OCH3
CH3
CH2OCH3
OCH3


A-1656
CH2OCH3
CH3
CH2OCH2CH3
CH3


A-1657
CH2OCH3
CH3
CH2OCH2CH3
CH2CH3


A-1658
CH2OCH3
CH3
CH2OCH2CH3
CH2CH2CH3


A-1659
CH2OCH3
CH3
CH2OCH2CH3
CH2CH2OCH3


A-1660
CH2OCH3
CH3
CH2OCH2CH3
OCH3


A-1661
CH2OCH3
CH3
CH2(CO)OCH3
CH3


A-1662
CH2OCH3
CH3
CH2(CO)OCH3
CH2CH3


A-1663
CH2OCH3
CH3
CH2(CO)OCH3
CH2CH2CH3


A-1664
CH2OCH3
CH3
CH2(CO)OCH3
CH2CH2OCH3


A-1665
CH2OCH3
CH3
CH2(CO)OCH3
OCH3


A-1666
CH2OCH3
CH3
CH2CHCH2
CH3


A-1667
CH2OCH3
CH3
CH2CHCH2
CH2CH3


A-1668
CH2OCH3
CH3
CH2CHCH2
CH2CH2CH3


A-1669
CH2OCH3
CH3
CH2CHCH2
CH2CH2OCH3


A-1670
CH2OCH3
CH3
CH2CHCH2
OCH3


A-1671
CH2OCH3
CH3
CH2CCH
CH3


A-1672
CH2OCH3
CH3
CH2CCH
CH2CH3


A-1673
CH2OCH3
CH3
CH2CCH
CH2CH2CH3


A-1674
CH2OCH3
CH3
CH2CCH
CH2CH2OCH3


A-1675
CH2OCH3
CH3
CH2CCH
OCH3


A-1676
CH2OCH3
CH3
CH2C6H5
CH3


A-1677
CH2OCH3
CH3
CH2C6H5
CH2CH3


A-1678
CH2OCH3
CH3
CH2C6H5
CH2CH2CH3


A-1679
CH2OCH3
CH3
CH2C6H5
CH2CH2OCH3


A-1680
CH2OCH3
CH3
CH2C6H5
OCH3


A-1681
CH2OCH3
CF3
CH3
CH3


A-1682
CH2OCH3
CF3
CH3
CH2CH3


A-1683
CH2OCH3
CF3
CH3
CH2CH2CH3


A-1684
CH2OCH3
CF3
CH3
CH2CH2OCH3


A-1685
CH2OCH3
CF3
CH3
OCH3


A-1686
CH2OCH3
CF3
CH2CH3
CH3


A-1687
CH2OCH3
CF3
CH2CH3
CH2CH3


A-1688
CH2OCH3
CF3
CH2CH3
CH2CH2CH3


A-1689
CH2OCH3
CF3
CH2CH3
CH2CH2OCH3


A-1690
CH2OCH3
CF3
CH2CH3
OCH3


A-1691
CH2OCH3
CF3
CH2OCH3
CH3


A-1692
CH2OCH3
CF3
CH2OCH3
CH2CH3


A-1693
CH2OCH3
CF3
CH2OCH3
CH2CH2CH3


A-1694
CH2OCH3
CF3
CH2OCH3
CH2CH2OCH3


A-1695
CH2OCH3
CF3
CH2OCH3
OCH3


A-1696
CH2OCH3
CF3
CH2OCH2CH3
CH3


A-1697
CH2OCH3
CF3
CH2OCH2CH3
CH2CH3


A-1698
CH2OCH3
CF3
CH2OCH2CH3
CH2CH2CH3


A-1699
CH2OCH3
CF3
CH2OCH2CH3
CH2CH2OCH3


A-1700
CH2OCH3
CF3
CH2OCH2CH3
OCH3


A-1701
CH2OCH3
CF3
CH2(CO)OCH3
CH3


A-1702
CH2OCH3
CF3
CH2(CO)OCH3
CH2CH3


A-1703
CH2OCH3
CF3
CH2(CO)OCH3
CH2CH2CH3


A-1704
CH2OCH3
CF3
CH2(CO)OCH3
CH2CH2OCH3


A-1705
CH2OCH3
CF3
CH2(CO)OCH3
OCH3


A-1706
CH2OCH3
CF3
CH2CHCH2
CH3


A-1707
CH2OCH3
CF3
CH2CHCH2
CH2CH3


A-1708
CH2OCH3
CF3
CH2CHCH2
CH2CH2CH3


A-1709
CH2OCH3
CF3
CH2CHCH2
CH2CH2OCH3


A-1710
CH2OCH3
CF3
CH2CHCH2
OCH3


A-1711
CH2OCH3
CF3
CH2CCH
CH3


A-1712
CH2OCH3
CF3
CH2CCH
CH2CH3


A-1713
CH2OCH3
CF3
CH2CCH
CH2CH2CH3


A-1714
CH2OCH3
CF3
CH2CCH
CH2CH2OCH3


A-1715
CH2OCH3
CF3
CH2CCH
OCH3


A-1716
CH2OCH3
CF3
CH2C6H5
CH3


A-1717
CH2OCH3
CF3
CH2C6H5
CH2CH3


A-1718
CH2OCH3
CF3
CH2C6H5
CH2CH2CH3


A-1719
CH2OCH3
CF3
CH2C6H5
CH2CH2OCH3


A-1720
CH2OCH3
CF3
CH2C6H5
OCH3


A-1721
CH2OCH3
SO2CH3
CH3
CH3


A-1722
CH2OCH3
SO2CH3
CH3
CH2CH3


A-1723
CH2OCH3
SO2CH3
CH3
CH2CH2CH3


A-1724
CH2OCH3
SO2CH3
CH3
CH2CH2OCH3


A-1725
CH2OCH3
SO2CH3
CH3
OCH3


A-1726
CH2OCH3
SO2CH3
CH2CH3
CH3


A-1727
CH2OCH3
SO2CH3
CH2CH3
CH2CH3


A-1728
CH2OCH3
SO2CH3
CH2CH3
CH2CH2CH3


A-1729
CH2OCH3
SO2CH3
CH2CH3
CH2CH2OCH3


A-1730
CH2OCH3
SO2CH3
CH2CH3
OCH3


A-1731
CH2OCH3
SO2CH3
CH2OCH3
CH3


A-1732
CH2OCH3
SO2CH3
CH2OCH3
CH2CH3


A-1733
CH2OCH3
SO2CH3
CH2OCH3
CH2CH2CH3


A-1734
CH2OCH3
SO2CH3
CH2OCH3
CH2CH2OCH3


A-1735
CH2OCH3
SO2CH3
CH2OCH3
OCH3


A-1736
CH2OCH3
SO2CH3
CH2OCH2CH3
CH3


A-1737
CH2OCH3
SO2CH3
CH2OCH2CH3
CH2CH3


A-1738
CH2OCH3
SO2CH3
CH2OCH2CH3
CH2CH2CH3


A-1739
CH2OCH3
SO2CH3
CH2OCH2CH3
CH2CH2OCH3


A-1740
CH2OCH3
SO2CH3
CH2OCH2CH3
OCH3


A-1741
CH2OCH3
SO2CH3
CH2(CO)OCH3
CH3


A-1742
CH2OCH3
SO2CH3
CH2(CO)OCH3
CH2CH3


A-1743
CH2OCH3
SO2CH3
CH2(CO)OCH3
CH2CH2CH3


A-1744
CH2OCH3
SO2CH3
CH2(CO)OCH3
CH2CH2OCH3


A-1745
CH2OCH3
SO2CH3
CH2(CO)OCH3
OCH3


A-1746
CH2OCH3
SO2CH3
CH2CHCH2
CH3


A-1747
CH2OCH3
SO2CH3
CH2CHCH2
CH2CH3


A-1748
CH2OCH3
SO2CH3
CH2CHCH2
CH2CH2CH3


A-1749
CH2OCH3
SO2CH3
CH2CHCH2
CH2CH2OCH3


A-1750
CH2OCH3
SO2CH3
CH2CHCH2
OCH3


A-1751
CH2OCH3
SO2CH3
CH2CCH
CH3


A-1752
CH2OCH3
SO2CH3
CH2CCH
CH2CH3


A-1753
CH2OCH3
SO2CH3
CH2CCH
CH2CH2CH3


A-1754
CH2OCH3
SO2CH3
CH2CCH
CH2CH2OCH3


A-1755
CH2OCH3
SO2CH3
CH2CCH
OCH3


A-1756
CH2OCH3
SO2CH3
CH2C6H5
CH3


A-1757
CH2OCH3
SO2CH3
CH2C6H5
CH2CH3


A-1758
CH2OCH3
SO2CH3
CH2C6H5
CH2CH2CH3


A-1759
CH2OCH3
SO2CH3
CH2C6H5
CH2CH2OCH3


A-1760
CH2OCH3
SO2CH3
CH2C6H5
OCH3


A-1761
CH2OCH3
NO2
CH3
CH3


A-1762
CH2OCH3
NO2
CH3
CH2CH3


A-1763
CH2OCH3
NO2
CH3
CH2CH2CH3


A-1764
CH2OCH3
NO2
CH3
CH2CH2OCH3


A-1765
CH2OCH3
NO2
CH3
OCH3


A-1766
CH2OCH3
NO2
CH2CH3
CH3


A-1767
CH2OCH3
NO2
CH2CH3
CH2CH3


A-1768
CH2OCH3
NO2
CH2CH3
CH2CH2CH3


A-1769
CH2OCH3
NO2
CH2CH3
CH2CH2OCH3


A-1770
CH2OCH3
NO2
CH2CH3
OCH3


A-1771
CH2OCH3
NO2
CH2OCH3
CH3


A-1772
CH2OCH3
NO2
CH2OCH3
CH2CH3


A-1773
CH2OCH3
NO2
CH2OCH3
CH2CH2CH3


A-1774
CH2OCH3
NO2
CH2OCH3
CH2CH2OCH3


A-1775
CH2OCH3
NO2
CH2OCH3
OCH3


A-1776
CH2OCH3
NO2
CH2OCH2CH3
CH3


A-1777
CH2OCH3
NO2
CH2OCH2CH3
CH2CH3


A-1778
CH2OCH3
NO2
CH2OCH2CH3
CH2CH2CH3


A-1779
CH2OCH3
NO2
CH2OCH2CH3
CH2CH2OCH3


A-1780
CH2OCH3
NO2
CH2OCH2CH3
OCH3


A-1781
CH2OCH3
NO2
CH2(CO)OCH3
CH3


A-1782
CH2OCH3
NO2
CH2(CO)OCH3
CH2CH3


A-1783
CH2OCH3
NO2
CH2(CO)OCH3
CH2CH2CH3


A-1784
CH2OCH3
NO2
CH2(CO)OCH3
CH2CH2OCH3


A-1785
CH2OCH3
NO2
CH2(CO)OCH3
OCH3


A-1786
CH2OCH3
NO2
CH2CHCH2
CH3


A-1787
CH2OCH3
NO2
CH2CHCH2
CH2CH3


A-1788
CH2OCH3
NO2
CH2CHCH2
CH2CH2CH3


A-1789
CH2OCH3
NO2
CH2CHCH2
CH2CH2OCH3


A-1790
CH2OCH3
NO2
CH2CHCH2
OCH3


A-1791
CH2OCH3
NO2
CH2CCH
CH3


A-1792
CH2OCH3
NO2
CH2CCH
CH2CH3


A-1793
CH2OCH3
NO2
CH2CCH
CH2CH2CH3


A-1794
CH2OCH3
NO2
CH2CCH
CH2CH2OCH3


A-1795
CH2OCH3
NO2
CH2CCH
OCH3


A-1796
CH2OCH3
NO2
CH2C6H5
CH3


A-1797
CH2OCH3
NO2
CH2C6H5
CH2CH3


A-1798
CH2OCH3
NO2
CH2C6H5
CH2CH2CH3


A-1799
CH2OCH3
NO2
CH2C6H5
CH2CH2OCH3


A-1800
CH2OCH3
NO2
CH2C6H5
OCH3


A-1801
CH2OCH2CH2OCH3
H
CH3
CH3


A-1802
CH2OCH2CH2OCH3
H
CH3
CH2CH3


A-1803
CH2OCH2CH2OCH3
H
CH3
CH2CH2CH3


A-1804
CH2OCH2CH2OCH3
H
CH3
CH2CH2OCH3


A-1805
CH2OCH2CH2OCH3
H
CH3
OCH3


A-1806
CH2OCH2CH2OCH3
H
CH2CH3
CH3


A-1807
CH2OCH2CH2OCH3
H
CH2CH3
CH2CH3


A-1808
CH2OCH2CH2OCH3
H
CH2CH3
CH2CH2CH3


A-1809
CH2OCH2CH2OCH3
H
CH2CH3
CH2CH2OCH3


A-1810
CH2OCH2CH2OCH3
H
CH2CH3
OCH3


A-1811
CH2OCH2CH2OCH3
H
CH2OCH3
CH3


A-1812
CH2OCH2CH2OCH3
H
CH2OCH3
CH2CH3


A-1813
CH2OCH2CH2OCH3
H
CH2OCH3
CH2CH2CH3


A-1814
CH2OCH2CH2OCH3
H
CH2OCH3
CH2CH2OCH3


A-1815
CH2OCH2CH2OCH3
H
CH2OCH3
OCH3


A-1816
CH2OCH2CH2OCH3
H
CH2OCH2CH3
CH3


A-1817
CH2OCH2CH2OCH3
H
CH2OCH2CH3
CH2CH3


A-1818
CH2OCH2CH2OCH3
H
CH2OCH2CH3
CH2CH2CH3


A-1819
CH2OCH2CH2OCH3
H
CH2OCH2CH3
CH2CH2OCH3


A-1820
CH2OCH2CH2OCH3
H
CH2OCH2CH3
OCH3


A-1821
CH2OCH2CH2OCH3
H
CH2(CO)OCH3
CH3


A-1822
CH2OCH2CH2OCH3
H
CH2(CO)OCH3
CH2CH3


A-1823
CH2OCH2CH2OCH3
H
CH2(CO)OCH3
CH2CH2CH3


A-1824
CH2OCH2CH2OCH3
H
CH2(CO)OCH3
CH2CH2OCH3


A-1825
CH2OCH2CH2OCH3
H
CH2(CO)OCH3
OCH3


A-1826
CH2OCH2CH2OCH3
H
CH2CHCH2
CH3


A-1827
CH2OCH2CH2OCH3
H
CH2CHCH2
CH2CH3


A-1828
CH2OCH2CH2OCH3
H
CH2CHCH2
CH2CH2CH3


A-1829
CH2OCH2CH2OCH3
H
CH2CHCH2
CH2CH2OCH3


A-1830
CH2OCH2CH2OCH3
H
CH2CHCH2
OCH3


A-1831
CH2OCH2CH2OCH3
H
CH2CCH
CH3


A-1832
CH2OCH2CH2OCH3
H
CH2CCH
CH2CH3


A-1833
CH2OCH2CH2OCH3
H
CH2CCH
CH2CH2CH3


A-1834
CH2OCH2CH2OCH3
H
CH2CCH
CH2CH2OCH3


A-1835
CH2OCH2CH2OCH3
H
CH2CCH
OCH3


A-1836
CH2OCH2CH2OCH3
H
CH2C6H5
CH3


A-1837
CH2OCH2CH2OCH3
H
CH2C6H5
CH2CH3


A-1838
CH2OCH2CH2OCH3
H
CH2C6H5
CH2CH2CH3


A-1839v
CH2OCH2CH2OCH3
H
CH2C6H5
CH2CH2OCH3


A-1840v
CH2OCH2CH2OCH3
H
CH2C6H5
OCH3


A-1841
CH2OCH2CH2OCH3
F
CH3
CH3


A-1842
CH2OCH2CH2OCH3
F
CH3
CH2CH3


A-1843
CH2OCH2CH2OCH3
F
CH3
CH2CH2CH3


A-1844
CH2OCH2CH2OCH3
F
CH3
CH2CH2OCH3


A-1845
CH2OCH2CH2OCH3
F
CH3
OCH3


A-1846
CH2OCH2CH2OCH3
F
CH2CH3
CH3


A-1847
CH2OCH2CH2OCH3
F
CH2CH3
CH2CH3


A-1848
CH2OCH2CH2OCH3
F
CH2CH3
CH2CH2CH3


A-1849
CH2OCH2CH2OCH3
F
CH2CH3
CH2CH2OCH3


A-1850
CH2OCH2CH2OCH3
F
CH2CH3
OCH3


A-1851
CH2OCH2CH2OCH3
F
CH2OCH3
CH3


A-1852
CH2OCH2CH2OCH3
F
CH2OCH3
CH2CH3


A-1853
CH2OCH2CH2OCH3
F
CH2OCH3
CH2CH2CH3


A-1854
CH2OCH2CH2OCH3
F
CH2OCH3
CH2CH2OCH3


A-1855
CH2OCH2CH2OCH3
F
CH2OCH3
OCH3


A-1856
CH2OCH2CH2OCH3
F
CH2OCH2CH3
CH3


A-1857
CH2OCH2CH2OCH3
F
CH2OCH2CH3
CH2CH3


A-1858
CH2OCH2CH2OCH3
F
CH2OCH2CH3
CH2CH2CH3


A-1859
CH2OCH2CH2OCH3
F
CH2OCH2CH3
CH2CH2OCH3


A-1860
CH2OCH2CH2OCH3
F
CH2OCH2CH3
OCH3


A-1861
CH2OCH2CH2OCH3
F
CH2(CO)OCH3
CH3


A-1862
CH2OCH2CH2OCH3
F
CH2(CO)OCH3
CH2CH3


A-1863
CH2OCH2CH2OCH3
F
CH2(CO)OCH3
CH2CH2CH3


A-1864
CH2OCH2CH2OCH3
F
CH2(CO)OCH3
CH2CH2OCH3


A-1865
CH2OCH2CH2OCH3
F
CH2(CO)OCH3
OCH3


A-1866
CH2OCH2CH2OCH3
F
CH2CHCH2
CH3


A-1867
CH2OCH2CH2OCH3
F
CH2CHCH2
CH2CH3


A-1868
CH2OCH2CH2OCH3
F
CH2CHCH2
CH2CH2CH3


A-1869
CH2OCH2CH2OCH3
F
CH2CHCH2
CH2CH2OCH3


A-1870
CH2OCH2CH2OCH3
F
CH2CHCH2
OCH3


A-1871
CH2OCH2CH2OCH3
F
CH2CCH
CH3


A-1872
CH2OCH2CH2OCH3
F
CH2CCH
CH2CH3


A-1873
CH2OCH2CH2OCH3
F
CH2CCH
CH2CH2CH3


A-1874
CH2OCH2CH2OCH3
F
CH2CCH
CH2CH2OCH3


A-1875
CH2OCH2CH2OCH3
F
CH2CCH
OCH3


A-1876
CH2OCH2CH2OCH3
F
CH2C6H5
CH3


A-1877
CH2OCH2CH2OCH3
F
CH2C6H5
CH2CH3


A-1878
CH2OCH2CH2OCH3
F
CH2C6H5
CH2CH2CH3


A-1879
CH2OCH2CH2OCH3
F
CH2C6H5
CH2CH2OCH3


A-1880
CH2OCH2CH2OCH3
F
CH2C6H5
OCH3


A-1881
CH2OCH2CH2OCH3
Cl
CH3
CH3


A-1882
CH2OCH2CH2OCH3
Cl
CH3
CH2CH3


A-1883
CH2OCH2CH2OCH3
Cl
CH3
CH2CH2CH3


A-1884
CH2OCH2CH2OCH3
Cl
CH3
CH2CH2OCH3


A-1885
CH2OCH2CH2OCH3
Cl
CH3
OCH3


A-1886
CH2OCH2CH2OCH3
Cl
CH2CH3
CH3


A-1887
CH2OCH2CH2OCH3
Cl
CH2CH3
CH2CH3


A-1888
CH2OCH2CH2OCH3
Cl
CH2CH3
CH2CH2CH3


A-1889
CH2OCH2CH2OCH3
Cl
CH2CH3
CH2CH2OCH3


A-1890
CH2OCH2CH2OCH3
Cl
CH2CH3
OCH3


A-1891
CH2OCH2CH2OCH3
Cl
CH2OCH3
CH3


A-1892
CH2OCH2CH2OCH3
Cl
CH2OCH3
CH2CH3


A-1893
CH2OCH2CH2OCH3
Cl
CH2OCH3
CH2CH2CH3


A-1894
CH2OCH2CH2OCH3
Cl
CH2OCH3
CH2CH2OCH3


A-1895
CH2OCH2CH2OCH3
Cl
CH2OCH3
OCH3


A-1896
CH2OCH2CH2OCH3
Cl
CH2OCH2CH3
CH3


A-1897
CH2OCH2CH2OCH3
Cl
CH2OCH2CH3
CH2CH3


A-1898
CH2OCH2CH2OCH3
Cl
CH2OCH2CH3
CH2CH2CH3


A-1899
CH2OCH2CH2OCH3
Cl
CH2OCH2CH3
CH2CH2OCH3


A-1900
CH2OCH2CH2OCH3
Cl
CH2OCH2CH3
OCH3


A-1901
CH2OCH2CH2OCH3
Cl
CH2(CO)OCH3
CH3


A-1902
CH2OCH2CH2OCH3
Cl
CH2(CO)OCH3
CH2CH3


A-1903
CH2OCH2CH2OCH3
Cl
CH2(CO)OCH3
CH2CH2CH3


A-1904
CH2OCH2CH2OCH3
Cl
CH2(CO)OCH3
CH2CH2OCH3


A-1905
CH2OCH2CH2OCH3
Cl
CH2(CO)OCH3
OCH3


A-1906
CH2OCH2CH2OCH3
Cl
CH2CHCH2
CH3


A-1907
CH2OCH2CH2OCH3
Cl
CH2CHCH2
CH2CH3


A-1908
CH2OCH2CH2OCH3
Cl
CH2CHCH2
CH2CH2CH3


A-1909
CH2OCH2CH2OCH3
Cl
CH2CHCH2
CH2CH2OCH3


A-1910
CH2OCH2CH2OCH3
Cl
CH2CHCH2
OCH3


A-1911
CH2OCH2CH2OCH3
Cl
CH2CCH
CH3


A-1912
CH2OCH2CH2OCH3
Cl
CH2CCH
CH2CH3


A-1913
CH2OCH2CH2OCH3
Cl
CH2CCH
CH2CH2CH3


A-1914
CH2OCH2CH2OCH3
Cl
CH2CCH
CH2CH2OCH3


A-1915
CH2OCH2CH2OCH3
Cl
CH2CCH
OCH3


A-1916
CH2OCH2CH2OCH3
Cl
CH2C6H5
CH3


A-1917
CH2OCH2CH2OCH3
Cl
CH2C6H5
CH2CH3


A-1918
CH2OCH2CH2OCH3
Cl
CH2C6H5
CH2CH2CH3


A-1919
CH2OCH2CH2OCH3
Cl
CH2C6H5
CH2CH2OCH3


A-1920
CH2OCH2CH2OCH3
Cl
CH2C6H5
OCH3


A-1921
CH2OCH2CH2OCH3
Br
CH3
CH3


A-1922
CH2OCH2CH2OCH3
Br
CH3
CH2CH3


A-1923
CH2OCH2CH2OCH3
Br
CH3
CH2CH2CH3


A-1924
CH2OCH2CH2OCH3
Br
CH3
CH2CH2OCH3


A-1925
CH2OCH2CH2OCH3
Br
CH3
OCH3


A-1926
CH2OCH2CH2OCH3
Br
CH2CH3
CH3


A-1927
CH2OCH2CH2OCH3
Br
CH2CH3
CH2CH3


A-1928
CH2OCH2CH2OCH3
Br
CH2CH3
CH2CH2CH3


A-1929
CH2OCH2CH2OCH3
Br
CH2CH3
CH2CH2OCH3


A-1930
CH2OCH2CH2OCH3
Br
CH2CH3
OCH3


A-1931
CH2OCH2CH2OCH3
Br
CH2OCH3
CH3


A-1932
CH2OCH2CH2OCH3
Br
CH2OCH3
CH2CH3


A-1933
CH2OCH2CH2OCH3
Br
CH2OCH3
CH2CH2CH3


A-1934
CH2OCH2CH2OCH3
Br
CH2OCH3
CH2CH2OCH3


A-1935
CH2OCH2CH2OCH3
Br
CH2OCH3
OCH3


A-1936
CH2OCH2CH2OCH3
Br
CH2OCH2CH3
CH3


A-1937
CH2OCH2CH2OCH3
Br
CH2OCH2CH3
CH2CH3


A-1938
CH2OCH2CH2OCH3
Br
CH2OCH2CH3
CH2CH2CH3


A-1939
CH2OCH2CH2OCH3
Br
CH2OCH2CH3
CH2CH2OCH3


A-1940
CH2OCH2CH2OCH3
Br
CH2OCH2CH3
OCH3


A-1941
CH2OCH2CH2OCH3
Br
CH2(CO)OCH3
CH3


A-1942
CH2OCH2CH2OCH3
Br
CH2(CO)OCH3
CH2CH3


A-1943
CH2OCH2CH2OCH3
Br
CH2(CO)OCH3
CH2CH2CH3


A-1944
CH2OCH2CH2OCH3
Br
CH2(CO)OCH3
CH2CH2OCH3


A-1945
CH2OCH2CH2OCH3
Br
CH2(CO)OCH3
OCH3


A-1946
CH2OCH2CH2OCH3
Br
CH2CHCH2
CH3


A-1947
CH2OCH2CH2OCH3
Br
CH2CHCH2
CH2CH3


A-1948
CH2OCH2CH2OCH3
Br
CH2CHCH2
CH2CH2CH3


A-1949
CH2OCH2CH2OCH3
Br
CH2CHCH2
CH2CH2OCH3


A-1950
CH2OCH2CH2OCH3
Br
CH2CHCH2
OCH3


A-1951
CH2OCH2CH2OCH3
Br
CH2CCH
CH3


A-1952
CH2OCH2CH2OCH3
Br
CH2CCH
CH2CH3


A-1953
CH2OCH2CH2OCH3
Br
CH2CCH
CH2CH2CH3


A-1954
CH2OCH2CH2OCH3
Br
CH2CCH
CH2CH2OCH3


A-1955
CH2OCH2CH2OCH3
Br
CH2CCH
OCH3


A-1956
CH2OCH2CH2OCH3
Br
CH2C6H5
CH3


A-1957
CH2OCH2CH2OCH3
Br
CH2C6H5
CH2CH3


A-1958
CH2OCH2CH2OCH3
Br
CH2C6H5
CH2CH2CH3


A-1959
CH2OCH2CH2OCH3
Br
CH2C6H5
CH2CH2OCH3


A-1960
CH2OCH2CH2OCH3
Br
CH2C6H5
OCH3


A-1961
CH2OCH2CH2OCH3
CN
CH3
CH3


A-1962
CH2OCH2CH2OCH3
CN
CH3
CH2CH3


A-1963
CH2OCH2CH2OCH3
CN
CH3
CH2CH2CH3


A-1964
CH2OCH2CH2OCH3
CN
CH3
CH2CH2OCH3


A-1965
CH2OCH2CH2OCH3
CN
CH3
OCH3


A-1966
CH2OCH2CH2OCH3
CN
CH2CH3
CH3


A-1967
CH2OCH2CH2OCH3
CN
CH2CH3
CH2CH3


A-1968
CH2OCH2CH2OCH3
CN
CH2CH3
CH2CH2CH3


A-1969
CH2OCH2CH2OCH3
CN
CH2CH3
CH2CH2OCH3


A-1970
CH2OCH2CH2OCH3
CN
CH2CH3
OCH3


A-1971
CH2OCH2CH2OCH3
CN
CH2OCH3
CH3


A-1972
CH2OCH2CH2OCH3
CN
CH2OCH3
CH2CH3


A-1973
CH2OCH2CH2OCH3
CN
CH2OCH3
CH2CH2CH3


A-1974
CH2OCH2CH2OCH3
CN
CH2OCH3
CH2CH2OCH3


A-1975
CH2OCH2CH2OCH3
CN
CH2OCH3
OCH3


A-1976
CH2OCH2CH2OCH3
CN
CH2OCH2CH3
CH3


A-1977
CH2OCH2CH2OCH3
CN
CH2OCH2CH3
CH2CH3


A-1978
CH2OCH2CH2OCH3
CN
CH2OCH2CH3
CH2CH2CH3


A-1979
CH2OCH2CH2OCH3
CN
CH2OCH2CH3
CH2CH2OCH3


A-1980
CH2OCH2CH2OCH3
CN
CH2OCH2CH3
OCH3


A-1981
CH2OCH2CH2OCH3
CN
CH2(CO)OCH3
CH3


A-1982
CH2OCH2CH2OCH3
CN
CH2(CO)OCH3
CH2CH3


A-1983
CH2OCH2CH2OCH3
CN
CH2(CO)OCH3
CH2CH2CH3


A-1984
CH2OCH2CH2OCH3
CN
CH2(CO)OCH3
CH2CH2OCH3


A-1985
CH2OCH2CH2OCH3
CN
CH2(CO)OCH3
OCH3


A-1986
CH2OCH2CH2OCH3
CN
CH2CHCH2
CH3


A-1987
CH2OCH2CH2OCH3
CN
CH2CHCH2
CH2CH3


A-1988
CH2OCH2CH2OCH3
CN
CH2CHCH2
CH2CH2CH3


A-1989
CH2OCH2CH2OCH3
CN
CH2CHCH2
CH2CH2OCH3


A-1990
CH2OCH2CH2OCH3
CN
CH2CHCH2
OCH3


A-1991
CH2OCH2CH2OCH3
CN
CH2CCH
CH3


A-1992
CH2OCH2CH2OCH3
CN
CH2CCH
CH2CH3


A-1993
CH2OCH2CH2OCH3
CN
CH2CCH
CH2CH2CH3


A-1994
CH2OCH2CH2OCH3
CN
CH2CCH
CH2CH2OCH3


A-1995
CH2OCH2CH2OCH3
CN
CH2CCH
OCH3


A-1996
CH2OCH2CH2OCH3
CN
CH2C6H5
CH3


A-1997
CH2OCH2CH2OCH3
CN
CH2C6H5
CH2CH3


A-1998
CH2OCH2CH2OCH3
CN
CH2C6H5
CH2CH2CH3


A-1999
CH2OCH2CH2OCH3
CN
CH2C6H5
CH2CH2OCH3


A-2000
CH2OCH2CH2OCH3
CN
CH2C6H5
OCH3


A-2001
CH2OCH2CH2OCH3
CH3
CH3
CH3


A-2002
CH2OCH2CH2OCH3
CH3
CH3
CH2CH3


A-2003
CH2OCH2CH2OCH3
CH3
CH3
CH2CH2CH3


A-2004
CH2OCH2CH2OCH3
CH3
CH3
CH2CH2OCH3


A-2005
CH2OCH2CH2OCH3
CH3
CH3
OCH3


A-2006
CH2OCH2CH2OCH3
CH3
CH2CH3
CH3


A-2007
CH2OCH2CH2OCH3
CH3
CH2CH3
CH2CH3


A-2008
CH2OCH2CH2OCH3
CH3
CH2CH3
CH2CH2CH3


A-2009
CH2OCH2CH2OCH3
CH3
CH2CH3
CH2CH2OCH3


A-2010
CH2OCH2CH2OCH3
CH3
CH2CH3
OCH3


A-2011
CH2OCH2CH2OCH3
CH3
CH2OCH3
CH3


A-2012
CH2OCH2CH2OCH3
CH3
CH2OCH3
CH2CH3


A-2013
CH2OCH2CH2OCH3
CH3
CH2OCH3
CH2CH2CH3


A-2014
CH2OCH2CH2OCH3
CH3
CH2OCH3
CH2CH2OCH3


A-2015
CH2OCH2CH2OCH3
CH3
CH2OCH3
OCH3


A-2016
CH2OCH2CH2OCH3
CH3
CH2OCH2CH3
CH3


A-2017
CH2OCH2CH2OCH3
CH3
CH2OCH2CH3
CH2CH3


A-2018
CH2OCH2CH2OCH3
CH3
CH2OCH2CH3
CH2CH2CH3


A-2019
CH2OCH2CH2OCH3
CH3
CH2OCH2CH3
CH2CH2OCH3


A-2020
CH2OCH2CH2OCH3
CH3
CH2OCH2CH3
OCH3


A-2021
CH2OCH2CH2OCH3
CH3
CH2(CO)OCH3
CH3


A-2022
CH2OCH2CH2OCH3
CH3
CH2(CO)OCH3
CH2CH3


A-2023
CH2OCH2CH2OCH3
CH3
CH2(CO)OCH3
CH2CH2CH3


A-2024
CH2OCH2CH2OCH3
CH3
CH2(CO)OCH3
CH2CH2OCH3


A-2025
CH2OCH2CH2OCH3
CH3
CH2(CO)OCH3
OCH3


A-2026
CH2OCH2CH2OCH3
CH3
CH2CHCH2
CH3


A-2027
CH2OCH2CH2OCH3
CH3
CH2CHCH2
CH2CH3


A-2028
CH2OCH2CH2OCH3
CH3
CH2CHCH2
CH2CH2CH3


A-2029
CH2OCH2CH2OCH3
CH3
CH2CHCH2
CH2CH2OCH3


A-2030
CH2OCH2CH2OCH3
CH3
CH2CHCH2
OCH3


A-2031
CH2OCH2CH2OCH3
CH3
CH2CCH
CH3


A-2032
CH2OCH2CH2OCH3
CH3
CH2CCH
CH2CH3


A-2033
CH2OCH2CH2OCH3
CH3
CH2CCH
CH2CH2CH3


A-2034
CH2OCH2CH2OCH3
CH3
CH2CCH
CH2CH2OCH3


A-2035
CH2OCH2CH2OCH3
CH3
CH2CCH
OCH3


A-2036
CH2OCH2CH2OCH3
CH3
CH2C6H5
CH3


A-2037
CH2OCH2CH2OCH3
CH3
CH2C6H5
CH2CH3


A-2038
CH2OCH2CH2OCH3
CH3
CH2C6H5
CH2CH2CH3


A-2039
CH2OCH2CH2OCH3
CH3
CH2C6H5
CH2CH2OCH3


A-2040
CH2OCH2CH2OCH3
CH3
CH2C6H5
OCH3


A-2041
CH2OCH2CH2OCH3
CF3
CH3
CH3


A-2042
CH2OCH2CH2OCH3
CF3
CH3
CH2CH3


A-2043
CH2OCH2CH2OCH3
CF3
CH3
CH2CH2CH3


A-2044
CH2OCH2CH2OCH3
CF3
CH3
CH2CH2OCH3


A-2045
CH2OCH2CH2OCH3
CF3
CH3
OCH3


A-2046
CH2OCH2CH2OCH3
CF3
CH2CH3
CH3


A-2047
CH2OCH2CH2OCH3
CF3
CH2CH3
CH2CH3


A-2048
CH2OCH2CH2OCH3
CF3
CH2CH3
CH2CH2CH3


A-2049
CH2OCH2CH2OCH3
CF3
CH2CH3
CH2CH2OCH3


A-2050
CH2OCH2CH2OCH3
CF3
CH2CH3
OCH3


A-2051
CH2OCH2CH2OCH3
CF3
CH2OCH3
CH3


A-2052
CH2OCH2CH2OCH3
CF3
CH2OCH3
CH2CH3


A-2053
CH2OCH2CH2OCH3
CF3
CH2OCH3
CH2CH2CH3


A-2054
CH2OCH2CH2OCH3
CF3
CH2OCH3
CH2CH2OCH3


A-2055
CH2OCH2CH2OCH3
CF3
CH2OCH3
OCH3


A-2056
CH2OCH2CH2OCH3
CF3
CH2OCH2CH3
CH3


A-2057
CH2OCH2CH2OCH3
CF3
CH2OCH2CH3
CH2CH3


A-2058
CH2OCH2CH2OCH3
CF3
CH2OCH2CH3
CH2CH2CH3


A-2059
CH2OCH2CH2OCH3
CF3
CH2OCH2CH3
CH2CH2OCH3


A-2060
CH2OCH2CH2OCH3
CF3
CH2OCH2CH3
OCH3


A-2061
CH2OCH2CH2OCH3
CF3
CH2(CO)OCH3
CH3


A-2062
CH2OCH2CH2OCH3
CF3
CH2(CO)OCH3
CH2CH3


A-2063
CH2OCH2CH2OCH3
CF3
CH2(CO)OCH3
CH2CH2CH3


A-2064
CH2OCH2CH2OCH3
CF3
CH2(CO)OCH3
CH2CH2OCH3


A-2065
CH2OCH2CH2OCH3
CF3
CH2(CO)OCH3
OCH3


A-2066
CH2OCH2CH2OCH3
CF3
CH2CHCH2
CH3


A-2067
CH2OCH2CH2OCH3
CF3
CH2CHCH2
CH2CH3


A-2068
CH2OCH2CH2OCH3
CF3
CH2CHCH2
CH2CH2CH3


A-2069
CH2OCH2CH2OCH3
CF3
CH2CHCH2
CH2CH2OCH3


A-2070
CH2OCH2CH2OCH3
CF3
CH2CHCH2
OCH3


A-2071
CH2OCH2CH2OCH3
CF3
CH2CCH
CH3


A-2072
CH2OCH2CH2OCH3
CF3
CH2CCH
CH2CH3


A-2073
CH2OCH2CH2OCH3
CF3
CH2CCH
CH2CH2CH3


A-2074
CH2OCH2CH2OCH3
CF3
CH2CCH
CH2CH2OCH3


A-2075
CH2OCH2CH2OCH3
CF3
CH2CCH
OCH3


A-2076
CH2OCH2CH2OCH3
CF3
CH2C6H5
CH3


A-2077
CH2OCH2CH2OCH3
CF3
CH2C6H5
CH2CH3


A-2078
CH2OCH2CH2OCH3
CF3
CH2C6H5
CH2CH2CH3


A-2079
CH2OCH2CH2OCH3
CF3
CH2C6H5
CH2CH2OCH3


A-2080
CH2OCH2CH2OCH3
CF3
CH2C6H5
OCH3


A-2081
CH2OCH2CH2OCH3
SO2CH3
CH3
CH3


A-2082
CH2OCH2CH2OCH3
SO2CH3
CH3
CH2CH3


A-2083
CH2OCH2CH2OCH3
SO2CH3
CH3
CH2CH2CH3


A-2084
CH2OCH2CH2OCH3
SO2CH3
CH3
CH2CH2OCH3


A-2085
CH2OCH2CH2OCH3
SO2CH3
CH3
OCH3


A-2086
CH2OCH2CH2OCH3
SO2CH3
CH2CH3
CH3


A-2087
CH2OCH2CH2OCH3
SO2CH3
CH2CH3
CH2CH3


A-2088
CH2OCH2CH2OCH3
SO2CH3
CH2CH3
CH2CH2CH3


A-2089
CH2OCH2CH2OCH3
SO2CH3
CH2CH3
CH2CH2OCH3


A-2090
CH2OCH2CH2OCH3
SO2CH3
CH2CH3
OCH3


A-2091
CH2OCH2CH2OCH3
SO2CH3
CH2OCH3
CH3


A-2092
CH2OCH2CH2OCH3
SO2CH3
CH2OCH3
CH2CH3


A-2093
CH2OCH2CH2OCH3
SO2CH3
CH2OCH3
CH2CH2CH3


A-2094
CH2OCH2CH2OCH3
SO2CH3
CH2OCH3
CH2CH2OCH3


A-2095
CH2OCH2CH2OCH3
SO2CH3
CH2OCH3
OCH3


A-2096
CH2OCH2CH2OCH3
SO2CH3
CH2OCH2CH3
CH3


A-2097
CH2OCH2CH2OCH3
SO2CH3
CH2OCH2CH3
CH2CH3


A-2098
CH2OCH2CH2OCH3
SO2CH3
CH2OCH2CH3
CH2CH2CH3


A-2099
CH2OCH2CH2OCH3
SO2CH3
CH2OCH2CH3
CH2CH2OCH3


A-2100
CH2OCH2CH2OCH3
SO2CH3
CH2OCH2CH3
OCH3


A-2101
CH2OCH2CH2OCH3
SO2CH3
CH2(CO)OCH3
CH3


A-2102
CH2OCH2CH2OCH3
SO2CH3
CH2(CO)OCH3
CH2CH3


A-2103
CH2OCH2CH2OCH3
SO2CH3
CH2(CO)OCH3
CH2CH2CH3


A-2104
CH2OCH2CH2OCH3
SO2CH3
CH2(CO)OCH3
CH2CH2OCH3


A-2105
CH2OCH2CH2OCH3
SO2CH3
CH2(CO)OCH3
OCH3


A-2106
CH2OCH2CH2OCH3
SO2CH3
CH2CHCH2
CH3


A-2107
CH2OCH2CH2OCH3
SO2CH3
CH2CHCH2
CH2CH3


A-2108
CH2OCH2CH2OCH3
SO2CH3
CH2CHCH2
CH2CH2CH3


A-2109
CH2OCH2CH2OCH3
SO2CH3
CH2CHCH2
CH2CH2OCH3


A-2110
CH2OCH2CH2OCH3
SO2CH3
CH2CHCH2
OCH3


A-2111
CH2OCH2CH2OCH3
SO2CH3
CH2CCH
CH3


A-2112
CH2OCH2CH2OCH3
SO2CH3
CH2CCH
CH2CH3


A-2113
CH2OCH2CH2OCH3
SO2CH3
CH2CCH
CH2CH2CH3


A-2114
CH2OCH2CH2OCH3
SO2CH3
CH2CCH
CH2CH2OCH3


A-2115
CH2OCH2CH2OCH3
SO2CH3
CH2CCH
OCH3


A-2116
CH2OCH2CH2OCH3
SO2CH3
CH2C6H5
CH3


A-2117
CH2OCH2CH2OCH3
SO2CH3
CH2C6H5
CH2CH3


A-2118
CH2OCH2CH2OCH3
SO2CH3
CH2C6H5
CH2CH2CH3


A-2119
CH2OCH2CH2OCH3
SO2CH3
CH2C6H5
CH2CH2OCH3


A-2120
CH2OCH2CH2OCH3
SO2CH3
CH2C6H5
OCH3


A-2121
CH2OCH2CH2OCH3
NO2
CH3
CH3


A-2122
CH2OCH2CH2OCH3
NO2
CH3
CH2CH3


A-2123
CH2OCH2CH2OCH3
NO2
CH3
CH2CH2CH3


A-2124
CH2OCH2CH2OCH3
NO2
CH3
CH2CH2OCH3


A-2125
CH2OCH2CH2OCH3
NO2
CH3
OCH3


A-2126
CH2OCH2CH2OCH3
NO2
CH2CH3
CH3


A-2127
CH2OCH2CH2OCH3
NO2
CH2CH3
CH2CH3


A-2128
CH2OCH2CH2OCH3
NO2
CH2CH3
CH2CH2CH3


A-2129
CH2OCH2CH2OCH3
NO2
CH2CH3
CH2CH2OCH3


A-2130
CH2OCH2CH2OCH3
NO2
CH2CH3
OCH3


A-2131
CH2OCH2CH2OCH3
NO2
CH2OCH3
CH3


A-2132
CH2OCH2CH2OCH3
NO2
CH2OCH3
CH2CH3


A-2133
CH2OCH2CH2OCH3
NO2
CH2OCH3
CH2CH2CH3


A-2134
CH2OCH2CH2OCH3
NO2
CH2OCH3
CH2CH2OCH3


A-2135
CH2OCH2CH2OCH3
NO2
CH2OCH3
OCH3


A-2136
CH2OCH2CH2OCH3
NO2
CH2OCH2CH3
CH3


A-2137
CH2OCH2CH2OCH3
NO2
CH2OCH2CH3
CH2CH3


A-2138
CH2OCH2CH2OCH3
NO2
CH2OCH2CH3
CH2CH2CH3


A-2139
CH2OCH2CH2OCH3
NO2
CH2OCH2CH3
CH2CH2OCH3


A-2140
CH2OCH2CH2OCH3
NO2
CH2OCH2CH3
OCH3


A-2141
CH2OCH2CH2OCH3
NO2
CH2(CO)OCH3
CH3


A-2142
CH2OCH2CH2OCH3
NO2
CH2(CO)OCH3
CH2CH3


A-2143
CH2OCH2CH2OCH3
NO2
CH2(CO)OCH3
CH2CH2CH3


A-2144
CH2OCH2CH2OCH3
NO2
CH2(CO)OCH3
CH2CH2OCH3


A-2145
CH2OCH2CH2OCH3
NO2
CH2(CO)OCH3
OCH3


A-2146
CH2OCH2CH2OCH3
NO2
CH2CHCH2
CH3


A-2147
CH2OCH2CH2OCH3
NO2
CH2CHCH2
CH2CH3


A-2148
CH2OCH2CH2OCH3
NO2
CH2CHCH2
CH2CH2CH3


A-2149
CH2OCH2CH2OCH3
NO2
CH2CHCH2
CH2CH2OCH3


A-2150
CH2OCH2CH2OCH3
NO2
CH2CHCH2
OCH3


A-2151
CH2OCH2CH2OCH3
NO2
CH2CCH
CH3


A-2152
CH2OCH2CH2OCH3
NO2
CH2CCH
CH2CH3


A-2153
CH2OCH2CH2OCH3
NO2
CH2CCH
CH2CH2CH3


A-2154
CH2OCH2CH2OCH3
NO2
CH2CCH
CH2CH2OCH3


A-2155
CH2OCH2CH2OCH3
NO2
CH2CCH
OCH3


A-2156
CH2OCH2CH2OCH3
NO2
CH2C6H5
CH3


A-2157
CH2OCH2CH2OCH3
NO2
CH2C6H5
CH2CH3


A-2158
CH2OCH2CH2OCH3
NO2
CH2C6H5
CH2CH2CH3


A-2159
CH2OCH2CH2OCH3
NO2
CH2C6H5
CH2CH2OCH3


A-2160
CH2OCH2CH2OCH3
NO2
CH2C6H5
OCH3


A-2161
SO2CH3
H
CH3
CH3


A-2162
SO2CH3
H
CH3
CH2CH3


A-2163
SO2CH3
H
CH3
CH2CH2CH3


A-2164
SO2CH3
H
CH3
CH2CH2OCH3


A-2165
SO2CH3
H
CH3
OCH3


A-2166
SO2CH3
H
CH2CH3
CH3


A-2167
SO2CH3
H
CH2CH3
CH2CH3


A-2168
SO2CH3
H
CH2CH3
CH2CH2CH3


A-2169
SO2CH3
H
CH2CH3
CH2CH2OCH3


A-2170
SO2CH3
H
CH2CH3
OCH3


A-2171
SO2CH3
H
CH2OCH3
CH3


A-2172
SO2CH3
H
CH2OCH3
CH2CH3


A-2173
SO2CH3
H
CH2OCH3
CH2CH2CH3


A-2174
SO2CH3
H
CH2OCH3
CH2CH2OCH3


A-2175
SO2CH3
H
CH2OCH3
OCH3


A-2176
SO2CH3
H
CH2OCH2CH3
CH3


A-2177
SO2CH3
H
CH2OCH2CH3
CH2CH3


A-2178
SO2CH3
H
CH2OCH2CH3
CH2CH2CH3


A-2179
SO2CH3
H
CH2OCH2CH3
CH2CH2OCH3


A-2180
SO2CH3
H
CH2OCH2CH3
OCH3


A-2181
SO2CH3
H
CH2(CO)OCH3
CH3


A-2182
SO2CH3
H
CH2(CO)OCH3
CH2CH3


A-2183
SO2CH3
H
CH2(CO)OCH3
CH2CH2CH3


A-2184
SO2CH3
H
CH2(CO)OCH3
CH2CH2OCH3


A-2185
SO2CH3
H
CH2(CO)OCH3
OCH3


A-2186
SO2CH3
H
CH2CHCH2
CH3


A-2187
SO2CH3
H
CH2CHCH2
CH2CH3


A-2188
SO2CH3
H
CH2CHCH2
CH2CH2CH3


A-2189
SO2CH3
H
CH2CHCH2
CH2CH2OCH3


A-2190
SO2CH3
H
CH2CHCH2
OCH3


A-2191
SO2CH3
H
CH2CCH
CH3


A-2192
SO2CH3
H
CH2CCH
CH2CH3


A-2193
SO2CH3
H
CH2CCH
CH2CH2CH3


A-2194
SO2CH3
H
CH2CCH
CH2CH2OCH3


A-2195
SO2CH3
H
CH2CCH
OCH3


A-2196
SO2CH3
H
CH2C6H5
CH3


A-2197
SO2CH3
H
CH2C6H5
CH2CH3


A-2198
SO2CH3
H
CH2C6H5
CH2CH2CH3


A-2199
SO2CH3
H
CH2C6H5
CH2CH2OCH3


A-2200
SO2CH3
H
CH2C6H5
OCH3


A-2201
SO2CH3
F
CH3
CH3


A-2202
SO2CH3
F
CH3
CH2CH3


A-2203
SO2CH3
F
CH3
CH2CH2CH3


A-2204
SO2CH3
F
CH3
CH2CH2OCH3


A-2205
SO2CH3
F
CH3
OCH3


A-2206
SO2CH3
F
CH2CH3
CH3


A-2207
SO2CH3
F
CH2CH3
CH2CH3


A-2208
SO2CH3
F
CH2CH3
CH2CH2CH3


A-2209
SO2CH3
F
CH2CH3
CH2CH2OCH3


A-2210
SO2CH3
F
CH2CH3
OCH3


A-2211
SO2CH3
F
CH2OCH3
CH3


A-2212
SO2CH3
F
CH2OCH3
CH2CH3


A-2213
SO2CH3
F
CH2OCH3
CH2CH2CH3


A-2214
SO2CH3
F
CH2OCH3
CH2CH2OCH3


A-2215
SO2CH3
F
CH2OCH3
OCH3


A-2216
SO2CH3
F
CH2OCH2CH3
CH3


A-2217
SO2CH3
F
CH2OCH2CH3
CH2CH3


A-2218
SO2CH3
F
CH2OCH2CH3
CH2CH2CH3


A-2219
SO2CH3
F
CH2OCH2CH3
CH2CH2OCH3


A-2220
SO2CH3
F
CH2OCH2CH3
OCH3


A-2221
SO2CH3
F
CH2(CO)OCH3
CH3


A-2222
SO2CH3
F
CH2(CO)OCH3
CH2CH3


A-2223
SO2CH3
F
CH2(CO)OCH3
CH2CH2CH3


A-2224
SO2CH3
F
CH2(CO)OCH3
CH2CH2OCH3


A-2225
SO2CH3
F
CH2(CO)OCH3
OCH3


A-2226
SO2CH3
F
CH2CHCH2
CH3


A-2227
SO2CH3
F
CH2CHCH2
CH2CH3


A-2228
SO2CH3
F
CH2CHCH2
CH2CH2CH3


A-2229
SO2CH3
F
CH2CHCH2
CH2CH2OCH3


A-2230
SO2CH3
F
CH2CHCH2
OCH3


A-2231
SO2CH3
F
CH2CCH
CH3


A-2232
SO2CH3
F
CH2CCH
CH2CH3


A-2233
SO2CH3
F
CH2CCH
CH2CH2CH3


A-2234
SO2CH3
F
CH2CCH
CH2CH2OCH3


A-2235
SO2CH3
F
CH2CCH
OCH3


A-2236
SO2CH3
F
CH2C6H5
CH3


A-2237
SO2CH3
F
CH2C6H5
CH2CH3


A-2238
SO2CH3
F
CH2C6H5
CH2CH2CH3


A-2239
SO2CH3
F
CH2C6H5
CH2CH2OCH3


A-2240
SO2CH3
F
CH2C6H5
OCH3


A-2241
SO2CH3
Cl
CH3
CH3


A-2242
SO2CH3
Cl
CH3
CH2CH3


A-2243
SO2CH3
Cl
CH3
CH2CH2CH3


A-2244
SO2CH3
Cl
CH3
CH2CH2OCH3


A-2245
SO2CH3
Cl
CH3
OCH3


A-2246
SO2CH3
Cl
CH2CH3
CH3


A-2247
SO2CH3
Cl
CH2CH3
CH2CH3


A-2248
SO2CH3
Cl
CH2CH3
CH2CH2CH3


A-2249
SO2CH3
Cl
CH2CH3
CH2CH2OCH3


A-2250
SO2CH3
Cl
CH2CH3
OCH3


A-2251
SO2CH3
Cl
CH2OCH3
CH3


A-2252
SO2CH3
Cl
CH2OCH3
CH2CH3


A-2253
SO2CH3
Cl
CH2OCH3
CH2CH2CH3


A-2254
SO2CH3
Cl
CH2OCH3
CH2CH2OCH3


A-2255
SO2CH3
Cl
CH2OCH3
OCH3


A-2256
SO2CH3
Cl
CH2OCH2CH3
CH3


A-2257
SO2CH3
Cl
CH2OCH2CH3
CH2CH3


A-2258
SO2CH3
Cl
CH2OCH2CH3
CH2CH2CH3


A-2259
SO2CH3
Cl
CH2OCH2CH3
CH2CH2OCH3


A-2260
SO2CH3
Cl
CH2OCH2CH3
OCH3


A-2261
SO2CH3
Cl
CH2(CO)OCH3
CH3


A-2262
SO2CH3
Cl
CH2(CO)OCH3
CH2CH3


A-2263
SO2CH3
Cl
CH2(CO)OCH3
CH2CH2CH3


A-2264
SO2CH3
Cl
CH2(CO)OCH3
CH2CH2OCH3


A-2265
SO2CH3
Cl
CH2(CO)OCH3
OCH3


A-2266
SO2CH3
Cl
CH2CHCH2
CH3


A-2267
SO2CH3
Cl
CH2CHCH2
CH2CH3


A-2268
SO2CH3
Cl
CH2CHCH2
CH2CH2CH3


A-2269
SO2CH3
Cl
CH2CHCH2
CH2CH2OCH3


A-2270
SO2CH3
Cl
CH2CHCH2
OCH3


A-2271
SO2CH3
Cl
CH2CCH
CH3


A-2272
SO2CH3
Cl
CH2CCH
CH2CH3


A-2273
SO2CH3
Cl
CH2CCH
CH2CH2CH3


A-2274
SO2CH3
Cl
CH2CCH
CH2CH2OCH3


A-2275
SO2CH3
Cl
CH2CCH
OCH3


A-2276
SO2CH3
Cl
CH2C6H5
CH3


A-2277
SO2CH3
Cl
CH2C6H5
CH2CH3


A-2278
SO2CH3
Cl
CH2C6H5
CH2CH2CH3


A-2279
SO2CH3
Cl
CH2C6H5
CH2CH2OCH3


A-2280
SO2CH3
Cl
CH2C6H5
OCH3


A-2281
SO2CH3
Br
CH3
CH3


A-2282
SO2CH3
Br
CH3
CH2CH3


A-2283
SO2CH3
Br
CH3
CH2CH2CH3


A-2284
SO2CH3
Br
CH3
CH2CH2OCH3


A-2285
SO2CH3
Br
CH3
OCH3


A-2286
SO2CH3
Br
CH2CH3
CH3


A-2287
SO2CH3
Br
CH2CH3
CH2CH3


A-2288
SO2CH3
Br
CH2CH3
CH2CH2CH3


A-2289
SO2CH3
Br
CH2CH3
CH2CH2OCH3


A-2290
SO2CH3
Br
CH2CH3
OCH3


A-2291
SO2CH3
Br
CH2OCH3
CH3


A-2292
SO2CH3
Br
CH2OCH3
CH2CH3


A-2293
SO2CH3
Br
CH2OCH3
CH2CH2CH3


A-2294
SO2CH3
Br
CH2OCH3
CH2CH2OCH3


A-2295
SO2CH3
Br
CH2OCH3
OCH3


A-2296
SO2CH3
Br
CH2OCH2CH3
CH3


A-2297
SO2CH3
Br
CH2OCH2CH3
CH2CH3


A-2298
SO2CH3
Br
CH2OCH2CH3
CH2CH2CH3


A-2299
SO2CH3
Br
CH2OCH2CH3
CH2CH2OCH3


A-2300
SO2CH3
Br
CH2OCH2CH3
OCH3


A-2301
SO2CH3
Br
CH2(CO)OCH3
CH3


A-2302
SO2CH3
Br
CH2(CO)OCH3
CH2CH3


A-2303
SO2CH3
Br
CH2(CO)OCH3
CH2CH2CH3


A-2304
SO2CH3
Br
CH2(CO)OCH3
CH2CH2OCH3


A-2305
SO2CH3
Br
CH2(CO)OCH3
OCH3


A-2306
SO2CH3
Br
CH2CHCH2
CH3


A-2307
SO2CH3
Br
CH2CHCH2
CH2CH3


A-2308
SO2CH3
Br
CH2CHCH2
CH2CH2CH3


A-2309
SO2CH3
Br
CH2CHCH2
CH2CH2OCH3


A-2310
SO2CH3
Br
CH2CHCH2
OCH3


A-2311
SO2CH3
Br
CH2CCH
CH3


A-2312
SO2CH3
Br
CH2CCH
CH2CH3


A-2313
SO2CH3
Br
CH2CCH
CH2CH2CH3


A-2314
SO2CH3
Br
CH2CCH
CH2CH2OCH3


A-2315
SO2CH3
Br
CH2CCH
OCH3


A-2316
SO2CH3
Br
CH2C6H5
CH3


A-2317
SO2CH3
Br
CH2C6H5
CH2CH3


A-2318
SO2CH3
Br
CH2C6H5
CH2CH2CH3


A-2319
SO2CH3
Br
CH2C6H5
CH2CH2OCH3


A-2320
SO2CH3
Br
CH2C6H5
OCH3


A-2321
SO2CH3
CN
CH3
CH3


A-2322
SO2CH3
CN
CH3
CH2CH3


A-2323
SO2CH3
CN
CH3
CH2CH2CH3


A-2324
SO2CH3
CN
CH3
CH2CH2OCH3


A-2325
SO2CH3
CN
CH3
OCH3


A-2326
SO2CH3
CN
CH2CH3
CH3


A-2327
SO2CH3
CN
CH2CH3
CH2CH3


A-2328
SO2CH3
CN
CH2CH3
CH2CH2CH3


A-2329
SO2CH3
CN
CH2CH3
CH2CH2OCH3


A-2330
SO2CH3
CN
CH2CH3
OCH3


A-2331
SO2CH3
CN
CH2OCH3
CH3


A-2332
SO2CH3
CN
CH2OCH3
CH2CH3


A-2333
SO2CH3
CN
CH2OCH3
CH2CH2CH3


A-2334
SO2CH3
CN
CH2OCH3
CH2CH2OCH3


A-2335
SO2CH3
CN
CH2OCH3
OCH3


A-2336
SO2CH3
CN
CH2OCH2CH3
CH3


A-2337
SO2CH3
CN
CH2OCH2CH3
CH2CH3


A-2338
SO2CH3
CN
CH2OCH2CH3
CH2CH2CH3


A-2339
SO2CH3
CN
CH2OCH2CH3
CH2CH2OCH3


A-2340
SO2CH3
CN
CH2OCH2CH3
OCH3


A-2341
SO2CH3
CN
CH2(CO)OCH3
CH3


A-2342
SO2CH3
CN
CH2(CO)OCH3
CH2CH3


A-2343
SO2CH3
CN
CH2(CO)OCH3
CH2CH2CH3


A-2344
SO2CH3
CN
CH2(CO)OCH3
CH2CH2OCH3


A-2345
SO2CH3
CN
CH2(CO)OCH3
OCH3


A-2346
SO2CH3
CN
CH2CHCH2
CH3


A-2347
SO2CH3
CN
CH2CHCH2
CH2CH3


A-2348
SO2CH3
CN
CH2CHCH2
CH2CH2CH3


A-2349
SO2CH3
CN
CH2CHCH2
CH2CH2OCH3


A-2350
SO2CH3
CN
CH2CHCH2
OCH3


A-2351
SO2CH3
CN
CH2CCH
CH3


A-2352
SO2CH3
CN
CH2CCH
CH2CH3


A-2353
SO2CH3
CN
CH2CCH
CH2CH2CH3


A-2354
SO2CH3
CN
CH2CCH
CH2CH2OCH3


A-2355
SO2CH3
CN
CH2CCH
OCH3


A-2356
SO2CH3
CN
CH2C6H5
CH3


A-2357
SO2CH3
CN
CH2C6H5
CH2CH3


A-2358
SO2CH3
CN
CH2C6H5
CH2CH2CH3


A-2359
SO2CH3
CN
CH2C6H5
CH2CH2OCH3


A-2360
SO2CH3
CN
CH2C6H5
OCH3


A-2361
SO2CH3
CH3
CH3
CH3


A-2362
SO2CH3
CH3
CH3
CH2CH3


A-2363
SO2CH3
CH3
CH3
CH2CH2CH3


A-2364
SO2CH3
CH3
CH3
CH2CH2OCH3


A-2365
SO2CH3
CH3
CH3
OCH3


A-2366
SO2CH3
CH3
CH2CH3
CH3


A-2367
SO2CH3
CH3
CH2CH3
CH2CH3


A-2368
SO2CH3
CH3
CH2CH3
CH2CH2CH3


A-2369
SO2CH3
CH3
CH2CH3
CH2CH2OCH3


A-2370
SO2CH3
CH3
CH2CH3
OCH3


A-2371
SO2CH3
CH3
CH2OCH3
CH3


A-2372
SO2CH3
CH3
CH2OCH3
CH2CH3


A-2373
SO2CH3
CH3
CH2OCH3
CH2CH2CH3


A-2374
SO2CH3
CH3
CH2OCH3
CH2CH2OCH3


A-2375
SO2CH3
CH3
CH2OCH3
OCH3


A-2376
SO2CH3
CH3
CH2OCH2CH3
CH3


A-2377
SO2CH3
CH3
CH2OCH2CH3
CH2CH3


A-2378
SO2CH3
CH3
CH2OCH2CH3
CH2CH2CH3


A-2379
SO2CH3
CH3
CH2OCH2CH3
CH2CH2OCH3


A-2380
SO2CH3
CH3
CH2OCH2CH3
OCH3


A-2381
SO2CH3
CH3
CH2(CO)OCH3
CH3


A-2382
SO2CH3
CH3
CH2(CO)OCH3
CH2CH3


A-2383
SO2CH3
CH3
CH2(CO)OCH3
CH2CH2CH3


A-2384
SO2CH3
CH3
CH2(CO)OCH3
CH2CH2OCH3


A-2385
SO2CH3
CH3
CH2(CO)OCH3
OCH3


A-2386
SO2CH3
CH3
CH2CHCH2
CH3


A-2387
SO2CH3
CH3
CH2CHCH2
CH2CH3


A-2388
SO2CH3
CH3
CH2CHCH2
CH2CH2CH3


A-2389
SO2CH3
CH3
CH2CHCH2
CH2CH2OCH3


A-2390
SO2CH3
CH3
CH2CHCH2
OCH3


A-2391
SO2CH3
CH3
CH2CCH
CH3


A-2392
SO2CH3
CH3
CH2CCH
CH2CH3


A-2393
SO2CH3
CH3
CH2CCH
CH2CH2CH3


A-2394
SO2CH3
CH3
CH2CCH
CH2CH2OCH3


A-2395
SO2CH3
CH3
CH2CCH
OCH3


A-2396
SO2CH3
CH3
CH2C6H5
CH3


A-2397
SO2CH3
CH3
CH2C6H5
CH2CH3


A-2398
SO2CH3
CH3
CH2C6H5
CH2CH2CH3


A-2399
SO2CH3
CH3
CH2C6H5
CH2CH2OCH3


A-2400
SO2CH3
CH3
CH2C6H5
OCH3


A-2401
SO2CH3
CF3
CH3
CH3


A-2402
SO2CH3
CF3
CH3
CH2CH3


A-2403
SO2CH3
CF3
CH3
CH2CH2CH3


A-2404
SO2CH3
CF3
CH3
CH2CH2OCH3


A-2405
SO2CH3
CF3
CH3
OCH3


A-2406
SO2CH3
CF3
CH2CH3
CH3


A-2407
SO2CH3
CF3
CH2CH3
CH2CH3


A-2408
SO2CH3
CF3
CH2CH3
CH2CH2CH3


A-2409
SO2CH3
CF3
CH2CH3
CH2CH2OCH3


A-2410
SO2CH3
CF3
CH2CH3
OCH3


A-2411
SO2CH3
CF3
CH2OCH3
CH3


A-2412
SO2CH3
CF3
CH2OCH3
CH2CH3


A-2413
SO2CH3
CF3
CH2OCH3
CH2CH2CH3


A-2414
SO2CH3
CF3
CH2OCH3
CH2CH2OCH3


A-2415
SO2CH3
CF3
CH2OCH3
OCH3


A-2416
SO2CH3
CF3
CH2OCH2CH3
CH3


A-2417
SO2CH3
CF3
CH2OCH2CH3
CH2CH3


A-2418
SO2CH3
CF3
CH2OCH2CH3
CH2CH2CH3


A-2419
SO2CH3
CF3
CH2OCH2CH3
CH2CH2OCH3


A-2420
SO2CH3
CF3
CH2OCH2CH3
OCH3


A-2421
SO2CH3
CF3
CH2(CO)OCH3
CH3


A-2422
SO2CH3
CF3
CH2(CO)OCH3
CH2CH3


A-2423
SO2CH3
CF3
CH2(CO)OCH3
CH2CH2CH3


A-2424
SO2CH3
CF3
CH2(CO)OCH3
CH2CH2OCH3


A-2425
SO2CH3
CF3
CH2(CO)OCH3
OCH3


A-2426
SO2CH3
CF3
CH2CHCH2
CH3


A-2427
SO2CH3
CF3
CH2CHCH2
CH2CH3


A-2428
SO2CH3
CF3
CH2CHCH2
CH2CH2CH3


A-2429
SO2CH3
CF3
CH2CHCH2
CH2CH2OCH3


A-2430
SO2CH3
CF3
CH2CHCH2
OCH3


A-2431
SO2CH3
CF3
CH2CCH
CH3


A-2432
SO2CH3
CF3
CH2CCH
CH2CH3


A-2433
SO2CH3
CF3
CH2CCH
CH2CH2CH3


A-2434
SO2CH3
CF3
CH2CCH
CH2CH2OCH3


A-2435
SO2CH3
CF3
CH2CCH
OCH3


A-2436
SO2CH3
CF3
CH2C6H5
CH3


A-2437
SO2CH3
CF3
CH2C6H5
CH2CH3


A-2438
SO2CH3
CF3
CH2C6H5
CH2CH2CH3


A-2439
SO2CH3
CF3
CH2C6H5
CH2CH2OCH3


A-2440
SO2CH3
CF3
CH2C6H5
OCH3


A-2441
SO2CH3
SO2CH3
CH3
CH3


A-2442
SO2CH3
SO2CH3
CH3
CH2CH3


A-2443
SO2CH3
SO2CH3
CH3
CH2CH2CH3


A-2444
SO2CH3
SO2CH3
CH3
CH2CH2OCH3


A-2445
SO2CH3
SO2CH3
CH3
OCH3


A-2446
SO2CH3
SO2CH3
CH2CH3
CH3


A-2447
SO2CH3
SO2CH3
CH2CH3
CH2CH3


A-2448
SO2CH3
SO2CH3
CH2CH3
CH2CH2CH3


A-2449
SO2CH3
SO2CH3
CH2CH3
CH2CH2OCH3


A-2450
SO2CH3
SO2CH3
CH2CH3
OCH3


A-2451
SO2CH3
SO2CH3
CH2OCH3
CH3


A-2452
SO2CH3
SO2CH3
CH2OCH3
CH2CH3


A-2453
SO2CH3
SO2CH3
CH2OCH3
CH2CH2CH3


A-2454
SO2CH3
SO2CH3
CH2OCH3
CH2CH2OCH3


A-2455
SO2CH3
SO2CH3
CH2OCH3
OCH3


A-2456
SO2CH3
SO2CH3
CH2OCH2CH3
CH3


A-2457
SO2CH3
SO2CH3
CH2OCH2CH3
CH2CH3


A-2458
SO2CH3
SO2CH3
CH2OCH2CH3
CH2CH2CH3


A-2459
SO2CH3
SO2CH3
CH2OCH2CH3
CH2CH2OCH3


A-2460
SO2CH3
SO2CH3
CH2OCH2CH3
OCH3


A-2461
SO2CH3
SO2CH3
CH2(CO)OCH3
CH3


A-2462
SO2CH3
SO2CH3
CH2(CO)OCH3
CH2CH3


A-2463
SO2CH3
SO2CH3
CH2(CO)OCH3
CH2CH2CH3


A-2464
SO2CH3
SO2CH3
CH2(CO)OCH3
CH2CH2OCH3


A-2465
SO2CH3
SO2CH3
CH2(CO)OCH3
OCH3


A-2466
SO2CH3
SO2CH3
CH2CHCH2
CH3


A-2467
SO2CH3
SO2CH3
CH2CHCH2
CH2CH3


A-2468
SO2CH3
SO2CH3
CH2CHCH2
CH2CH2CH3


A-2469
SO2CH3
SO2CH3
CH2CHCH2
CH2CH2OCH3


A-2470
SO2CH3
SO2CH3
CH2CHCH2
OCH3


A-2471
SO2CH3
SO2CH3
CH2CCH
CH3


A-2472
SO2CH3
SO2CH3
CH2CCH
CH2CH3


A-2473
SO2CH3
SO2CH3
CH2CCH
CH2CH2CH3


A-2474
SO2CH3
SO2CH3
CH2CCH
CH2CH2OCH3


A-2475
SO2CH3
SO2CH3
CH2CCH
OCH3


A-2476
SO2CH3
SO2CH3
CH2C6H5
CH3


A-2477
SO2CH3
SO2CH3
CH2C6H5
CH2CH3


A-2478
SO2CH3
SO2CH3
CH2C6H5
CH2CH2CH3


A-2479
SO2CH3
SO2CH3
CH2C6H5
CH2CH2OCH3


A-2480
SO2CH3
SO2CH3
CH2C6H5
OCH3


A-2481
SO2CH3
NO2
CH3
CH3


A-2482
SO2CH3
NO2
CH3
CH2CH3


A-2483
SO2CH3
NO2
CH3
CH2CH2CH3


A-2484
SO2CH3
NO2
CH3
CH2CH2OCH3


A-2485
SO2CH3
NO2
CH3
OCH3


A-2486
SO2CH3
NO2
CH2CH3
CH3


A-2487
SO2CH3
NO2
CH2CH3
CH2CH3


A-2488
SO2CH3
NO2
CH2CH3
CH2CH2CH3


A-2489
SO2CH3
NO2
CH2CH3
CH2CH2OCH3


A-2490
SO2CH3
NO2
CH2CH3
OCH3


A-2491
SO2CH3
NO2
CH2OCH3
CH3


A-2492
SO2CH3
NO2
CH2OCH3
CH2CH3


A-2493
SO2CH3
NO2
CH2OCH3
CH2CH2CH3


A-2494
SO2CH3
NO2
CH2OCH3
CH2CH2OCH3


A-2495
SO2CH3
NO2
CH2OCH3
OCH3


A-2496
SO2CH3
NO2
CH2OCH2CH3
CH3


A-2497
SO2CH3
NO2
CH2OCH2CH3
CH2CH3


A-2498
SO2CH3
NO2
CH2OCH2CH3
CH2CH2CH3


A-2499
SO2CH3
NO2
CH2OCH2CH3
CH2CH2OCH3


A-2500
SO2CH3
NO2
CH2OCH2CH3
OCH3


A-2501
SO2CH3
NO2
CH2(CO)OCH3
CH3


A-2502
SO2CH3
NO2
CH2(CO)OCH3
CH2CH3


A-2503
SO2CH3
NO2
CH2(CO)OCH3
CH2CH2CH3


A-2504
SO2CH3
NO2
CH2(CO)OCH3
CH2CH2OCH3


A-2505
SO2CH3
NO2
CH2(CO)OCH3
OCH3


A-2506
SO2CH3
NO2
CH2CHCH2
CH3


A-2507
SO2CH3
NO2
CH2CHCH2
CH2CH3


A-2508
SO2CH3
NO2
CH2CHCH2
CH2CH2CH3


A-2509
SO2CH3
NO2
CH2CHCH2
CH2CH2OCH3


A-2510
SO2CH3
NO2
CH2CHCH2
OCH3


A-2511
SO2CH3
NO2
CH2CCH
CH3


A-2512
SO2CH3
NO2
CH2CCH
CH2CH3


A-2513
SO2CH3
NO2
CH2CCH
CH2CH2CH3


A-2514
SO2CH3
NO2
CH2CCH
CH2CH2OCH3


A-2515
SO2CH3
NO2
CH2CCH
OCH3


A-2516
SO2CH3
NO2
CH2C6H5
CH3


A-2517
SO2CH3
NO2
CH2C6H5
CH2CH3


A-2518
SO2CH3
NO2
CH2C6H5
CH2CH2CH3


A-2519
SO2CH3
NO2
CH2C6H5
CH2CH2OCH3


A-2520
SO2CH3
NO2
CH2C6H5
OCH3


A-2521
CF3
H
CH3
CH3


A-2522
CF3
H
CH3
CH2CH3


A-2523
CF3
H
CH3
CH2CH2CH3


A-2524
CF3
H
CH3
CH2CH2OCH3


A-2525
CF3
H
CH3
OCH3


A-2526
CF3
H
CH2CH3
CH3


A-2527
CF3
H
CH2CH3
CH2CH3


A-2528
CF3
H
CH2CH3
CH2CH2CH3


A-2529
CF3
H
CH2CH3
CH2CH2OCH3


A-2530
CF3
H
CH2CH3
OCH3


A-2531
CF3
H
CH2OCH3
CH3


A-2532
CF3
H
CH2OCH3
CH2CH3


A-2533
CF3
H
CH2OCH3
CH2CH2CH3


A-2534
CF3
H
CH2OCH3
CH2CH2OCH3


A-2535
CF3
H
CH2OCH3
OCH3


A-2536
CF3
H
CH2OCH2CH3
CH3


A-2537
CF3
H
CH2OCH2CH3
CH2CH3


A-2538
CF3
H
CH2OCH2CH3
CH2CH2CH3


A-2539
CF3
H
CH2OCH2CH3
CH2CH2OCH3


A-2540
CF3
H
CH2OCH2CH3
OCH3


A-2541
CF3
H
CH2(CO)OCH3
CH3


A-2542
CF3
H
CH2(CO)OCH3
CH2CH3


A-2543
CF3
H
CH2(CO)OCH3
CH2CH2CH3


A-2544
CF3
H
CH2(CO)OCH3
CH2CH2OCH3


A-2545
CF3
H
CH2(CO)OCH3
OCH3


A-2546
CF3
H
CH2CHCH2
CH3


A-2547
CF3
H
CH2CHCH2
CH2CH3


A-2548
CF3
H
CH2CHCH2
CH2CH2CH3


A-2549
CF3
H
CH2CHCH2
CH2CH2OCH3


A-2550
CF3
H
CH2CHCH2
OCH3


A-2551
CF3
H
CH2CCH
CH3


A-2552
CF3
H
CH2CCH
CH2CH3


A-2553
CF3
H
CH2CCH
CH2CH2CH3


A-2554
CF3
H
CH2CCH
CH2CH2OCH3


A-2555
CF3
H
CH2CCH
OCH3


A-2556
CF3
H
CH2C6H5
CH3


A-2557
CF3
H
CH2C6H5
CH2CH3


A-2558
CF3
H
CH2C6H5
CH2CH2CH3


A-2559
CF3
H
CH2C6H5
CH2CH2OCH3


A-2560
CF3
H
CH2C6H5
OCH3


A-2561
CF3
F
CH3
CH3


A-2562
CF3
F
CH3
CH2CH3


A-2563
CF3
F
CH3
CH2CH2CH3


A-2564
CF3
F
CH3
CH2CH2OCH3


A-2565
CF3
F
CH3
OCH3


A-2566
CF3
F
CH2CH3
CH3


A-2567
CF3
F
CH2CH3
CH2CH3


A-2568
CF3
F
CH2CH3
CH2CH2CH3


A-2569
CF3
F
CH2CH3
CH2CH2OCH3


A-2570
CF3
F
CH2CH3
OCH3


A-2571
CF3
F
CH2OCH3
CH3


A-2572
CF3
F
CH2OCH3
CH2CH3


A-2573
CF3
F
CH2OCH3
CH2CH2CH3


A-2574
CF3
F
CH2OCH3
CH2CH2OCH3


A-2575
CF3
F
CH2OCH3
OCH3


A-2576
CF3
F
CH2OCH2CH3
CH3


A-2577
CF3
F
CH2OCH2CH3
CH2CH3


A-2578
CF3
F
CH2OCH2CH3
CH2CH2CH3


A-2579
CF3
F
CH2OCH2CH3
CH2CH2OCH3


A-2580
CF3
F
CH2OCH2CH3
OCH3


A-2581
CF3
F
CH2(CO)OCH3
CH3


A-2582
CF3
F
CH2(CO)OCH3
CH2CH3


A-2583
CF3
F
CH2(CO)OCH3
CH2CH2CH3


A-2584
CF3
F
CH2(CO)OCH3
CH2CH2OCH3


A-2585
CF3
F
CH2(CO)OCH3
OCH3


A-2586
CF3
F
CH2CHCH2
CH3


A-2587
CF3
F
CH2CHCH2
CH2CH3


A-2588
CF3
F
CH2CHCH2
CH2CH2CH3


A-2589
CF3
F
CH2CHCH2
CH2CH2OCH3


A-2590
CF3
F
CH2CHCH2
OCH3


A-2591
CF3
F
CH2CCH
CH3


A-2592
CF3
F
CH2CCH
CH2CH3


A-2593
CF3
F
CH2CCH
CH2CH2CH3


A-2594
CF3
F
CH2CCH
CH2CH2OCH3


A-2595
CF3
F
CH2CCH
OCH3


A-2596
CF3
F
CH2C6H5
CH3


A-2597
CF3
F
CH2C6H5
CH2CH3


A-2598
CF3
F
CH2C6H5
CH2CH2CH3


A-2599
CF3
F
CH2C6H5
CH2CH2OCH3


A-2600
CF3
F
CH2C6H5
OCH3


A-2601
CF3
Cl
CH3
CH3


A-2602
CF3
Cl
CH3
CH2CH3


A-2603
CF3
Cl
CH3
CH2CH2CH3


A-2604
CF3
Cl
CH3
CH2CH2OCH3


A-2605
CF3
Cl
CH3
OCH3


A-2606
CF3
Cl
CH2CH3
CH3


A-2607
CF3
Cl
CH2CH3
CH2CH3


A-2608
CF3
Cl
CH2CH3
CH2CH2CH3


A-2609
CF3
Cl
CH2CH3
CH2CH2OCH3


A-2610
CF3
Cl
CH2CH3
OCH3


A-2611
CF3
Cl
CH2OCH3
CH3


A-2612
CF3
Cl
CH2OCH3
CH2CH3


A-2613
CF3
Cl
CH2OCH3
CH2CH2CH3


A-2614
CF3
Cl
CH2OCH3
CH2CH2OCH3


A-2615
CF3
Cl
CH2OCH3
OCH3


A-2616
CF3
Cl
CH2OCH2CH3
CH3


A-2617
CF3
Cl
CH2OCH2CH3
CH2CH3


A-2618
CF3
Cl
CH2OCH2CH3
CH2CH2CH3


A-2619
CF3
Cl
CH2OCH2CH3
CH2CH2OCH3


A-2620
CF3
Cl
CH2OCH2CH3
OCH3


A-2621
CF3
Cl
CH2(CO)OCH3
CH3


A-2622
CF3
Cl
CH2(CO)OCH3
CH2CH3


A-2623
CF3
Cl
CH2(CO)OCH3
CH2CH2CH3


A-2624
CF3
Cl
CH2(CO)OCH3
CH2CH2OCH3


A-2625
CF3
Cl
CH2(CO)OCH3
OCH3


A-2626
CF3
Cl
CH2CHCH2
CH3


A-2627
CF3
Cl
CH2CHCH2
CH2CH3


A-2628
CF3
Cl
CH2CHCH2
CH2CH2CH3


A-2629
CF3
Cl
CH2CHCH2
CH2CH2OCH3


A-2630
CF3
Cl
CH2CHCH2
OCH3


A-2631
CF3
Cl
CH2CCH
CH3


A-2632
CF3
Cl
CH2CCH
CH2CH3


A-2633
CF3
Cl
CH2CCH
CH2CH2CH3


A-2634
CF3
Cl
CH2CCH
CH2CH2OCH3


A-2635
CF3
Cl
CH2CCH
OCH3


A-2636
CF3
Cl
CH2C6H5
CH3


A-2637
CF3
Cl
CH2C6H5
CH2CH3


A-2638
CF3
Cl
CH2C6H5
CH2CH2CH3


A-2639
CF3
Cl
CH2C6H5
CH2CH2OCH3


A-2640
CF3
Cl
CH2C6H5
OCH3


A-2641
CF3
Br
CH3
CH3


A-2642
CF3
Br
CH3
CH2CH3


A-2643
CF3
Br
CH3
CH2CH2CH3


A-2644
CF3
Br
CH3
CH2CH2OCH3


A-2645
CF3
Br
CH3
OCH3


A-2646
CF3
Br
CH2CH3
CH3


A-2647
CF3
Br
CH2CH3
CH2CH3


A-2648
CF3
Br
CH2CH3
CH2CH2CH3


A-2649
CF3
Br
CH2CH3
CH2CH2OCH3


A-2650
CF3
Br
CH2CH3
OCH3


A-2651
CF3
Br
CH2OCH3
CH3


A-2652
CF3
Br
CH2OCH3
CH2CH3


A-2653
CF3
Br
CH2OCH3
CH2CH2CH3


A-2654
CF3
Br
CH2OCH3
CH2CH2OCH3


A-2655
CF3
Br
CH2OCH3
OCH3


A-2656
CF3
Br
CH2OCH2CH3
CH3


A-2657
CF3
Br
CH2OCH2CH3
CH2CH3


A-2658
CF3
Br
CH2OCH2CH3
CH2CH2CH3


A-2659
CF3
Br
CH2OCH2CH3
CH2CH2OCH3


A-2660
CF3
Br
CH2OCH2CH3
OCH3


A-2661
CF3
Br
CH2(CO)OCH3
CH3


A-2662
CF3
Br
CH2(CO)OCH3
CH2CH3


A-2663
CF3
Br
CH2(CO)OCH3
CH2CH2CH3


A-2664
CF3
Br
CH2(CO)OCH3
CH2CH2OCH3


A-2665
CF3
Br
CH2(CO)OCH3
OCH3


A-2666
CF3
Br
CH2CHCH2
CH3


A-2667
CF3
Br
CH2CHCH2
CH2CH3


A-2668
CF3
Br
CH2CHCH2
CH2CH2CH3


A-2669
CF3
Br
CH2CHCH2
CH2CH2OCH3


A-2670
CF3
Br
CH2CHCH2
OCH3


A-2671
CF3
Br
CH2CCH
CH3


A-2672
CF3
Br
CH2CCH
CH2CH3


A-2673
CF3
Br
CH2CCH
CH2CH2CH3


A-2674
CF3
Br
CH2CCH
CH2CH2OCH3


A-2675
CF3
Br
CH2CCH
OCH3


A-2676
CF3
Br
CH2C6H5
CH3


A-2677
CF3
Br
CH2C6H5
CH2CH3


A-2678
CF3
Br
CH2C6H5
CH2CH2CH3


A-2679
CF3
Br
CH2C6H5
CH2CH2OCH3


A-2680
CF3
Br
CH2C6H5
OCH3


A-2681
CF3
CN
CH3
CH3


A-2682
CF3
CN
CH3
CH2CH3


A-2683
CF3
CN
CH3
CH2CH2CH3


A-2684
CF3
CN
CH3
CH2CH2OCH3


A-2685
CF3
CN
CH3
OCH3


A-2686
CF3
CN
CH2CH3
CH3


A-2687
CF3
CN
CH2CH3
CH2CH3


A-2688
CF3
CN
CH2CH3
CH2CH2CH3


A-2689
CF3
CN
CH2CH3
CH2CH2OCH3


A-2690
CF3
CN
CH2CH3
OCH3


A-2691
CF3
CN
CH2OCH3
CH3


A-2692
CF3
CN
CH2OCH3
CH2CH3


A-2693
CF3
CN
CH2OCH3
CH2CH2CH3


A-2694
CF3
CN
CH2OCH3
CH2CH2OCH3


A-2695
CF3
CN
CH2OCH3
OCH3


A-2696
CF3
CN
CH2OCH2CH3
CH3


A-2697
CF3
CN
CH2OCH2CH3
CH2CH3


A-2698
CF3
CN
CH2OCH2CH3
CH2CH2CH3


A-2699
CF3
CN
CH2OCH2CH3
CH2CH2OCH3


A-2700
CF3
CN
CH2OCH2CH3
OCH3


A-2701
CF3
CN
CH2(CO)OCH3
CH3


A-2702
CF3
CN
CH2(CO)OCH3
CH2CH3


A-2703
CF3
CN
CH2(CO)OCH3
CH2CH2CH3


A-2704
CF3
CN
CH2(CO)OCH3
CH2CH2OCH3


A-2705
CF3
CN
CH2(CO)OCH3
OCH3


A-2706
CF3
CN
CH2CHCH2
CH3


A-2707
CF3
CN
CH2CHCH2
CH2CH3


A-2708
CF3
CN
CH2CHCH2
CH2CH2CH3


A-2709
CF3
CN
CH2CHCH2
CH2CH2OCH3


A-2710
CF3
CN
CH2CHCH2
OCH3


A-2711
CF3
CN
CH2CCH
CH3


A-2712
CF3
CN
CH2CCH
CH2CH3


A-2713
CF3
CN
CH2CCH
CH2CH2CH3


A-2714
CF3
CN
CH2CCH
CH2CH2OCH3


A-2715
CF3
CN
CH2CCH
OCH3


A-2716
CF3
CN
CH2C6H5
CH3


A-2717
CF3
CN
CH2C6H5
CH2CH3


A-2718
CF3
CN
CH2C6H5
CH2CH2CH3


A-2719
CF3
CN
CH2C6H5
CH2CH2OCH3


A-2720
CF3
CN
CH2C6H5
OCH3


A-2721
CF3
CH3
CH3
CH3


A-2722
CF3
CH3
CH3
CH2CH3


A-2723
CF3
CH3
CH3
CH2CH2CH3


A-2724
CF3
CH3
CH3
CH2CH2OCH3


A-2725
CF3
CH3
CH3
OCH3


A-2726
CF3
CH3
CH2CH3
CH3


A-2727
CF3
CH3
CH2CH3
CH2CH3


A-2728
CF3
CH3
CH2CH3
CH2CH2CH3


A-2729
CF3
CH3
CH2CH3
CH2CH2OCH3


A-2730
CF3
CH3
CH2CH3
OCH3


A-2731
CF3
CH3
CH2OCH3
CH3


A-2732
CF3
CH3
CH2OCH3
CH2CH3


A-2733
CF3
CH3
CH2OCH3
CH2CH2CH3


A-2734
CF3
CH3
CH2OCH3
CH2CH2OCH3


A-2735
CF3
CH3
CH2OCH3
OCH3


A-2736
CF3
CH3
CH2OCH2CH3
CH3


A-2737
CF3
CH3
CH2OCH2CH3
CH2CH3


A-2738
CF3
CH3
CH2OCH2CH3
CH2CH2CH3


A-2739
CF3
CH3
CH2OCH2CH3
CH2CH2OCH3


A-2740
CF3
CH3
CH2OCH2CH3
OCH3


A-2741
CF3
CH3
CH2(CO)OCH3
CH3


A-2742
CF3
CH3
CH2(CO)OCH3
CH2CH3


A-2743
CF3
CH3
CH2(CO)OCH3
CH2CH2CH3


A-2744
CF3
CH3
CH2(CO)OCH3
CH2CH2OCH3


A-2745
CF3
CH3
CH2(CO)OCH3
OCH3


A-2746
CF3
CH3
CH2CHCH2
CH3


A-2747
CF3
CH3
CH2CHCH2
CH2CH3


A-2748
CF3
CH3
CH2CHCH2
CH2CH2CH3


A-2749
CF3
CH3
CH2CHCH2
CH2CH2OCH3


A-2750
CF3
CH3
CH2CHCH2
OCH3


A-2751
CF3
CH3
CH2CCH
CH3


A-2752
CF3
CH3
CH2CCH
CH2CH3


A-2753
CF3
CH3
CH2CCH
CH2CH2CH3


A-2754
CF3
CH3
CH2CCH
CH2CH2OCH3


A-2755
CF3
CH3
CH2CCH
OCH3


A-2756
CF3
CH3
CH2C6H5
CH3


A-2757
CF3
CH3
CH2C6H5
CH2CH3


A-2758
CF3
CH3
CH2C6H5
CH2CH2CH3


A-2759
CF3
CH3
CH2C6H5
CH2CH2OCH3


A-2760
CF3
CH3
CH2C6H5
OCH3


A-2761
CF3
CF3
CH3
CH3


A-2762
CF3
CF3
CH3
CH2CH3


A-2763
CF3
CF3
CH3
CH2CH2CH3


A-2764
CF3
CF3
CH3
CH2CH2OCH3


A-2765
CF3
CF3
CH3
OCH3


A-2766
CF3
CF3
CH2CH3
CH3


A-2767
CF3
CF3
CH2CH3
CH2CH3


A-2768
CF3
CF3
CH2CH3
CH2CH2CH3


A-2769
CF3
CF3
CH2CH3
CH2CH2OCH3


A-2770
CF3
CF3
CH2CH3
OCH3


A-2771
CF3
CF3
CH2OCH3
CH3


A-2772
CF3
CF3
CH2OCH3
CH2CH3


A-2773
CF3
CF3
CH2OCH3
CH2CH2CH3


A-2774
CF3
CF3
CH2OCH3
CH2CH2OCH3


A-2775
CF3
CF3
CH2OCH3
OCH3


A-2776
CF3
CF3
CH2OCH2CH3
CH3


A-2777
CF3
CF3
CH2OCH2CH3
CH2CH3


A-2778
CF3
CF3
CH2OCH2CH3
CH2CH2CH3


A-2779
CF3
CF3
CH2OCH2CH3
CH2CH2OCH3


A-2780
CF3
CF3
CH2OCH2CH3
OCH3


A-2781
CF3
CF3
CH2(CO)OCH3
CH3


A-2782
CF3
CF3
CH2(CO)OCH3
CH2CH3


A-2783
CF3
CF3
CH2(CO)OCH3
CH2CH2CH3


A-2784
CF3
CF3
CH2(CO)OCH3
CH2CH2OCH3


A-2785
CF3
CF3
CH2(CO)OCH3
OCH3


A-2786
CF3
CF3
CH2CHCH2
CH3


A-2787
CF3
CF3
CH2CHCH2
CH2CH3


A-2788
CF3
CF3
CH2CHCH2
CH2CH2CH3


A-2789
CF3
CF3
CH2CHCH2
CH2CH2OCH3


A-2790
CF3
CF3
CH2CHCH2
OCH3


A-2791
CF3
CF3
CH2CCH
CH3


A-2792
CF3
CF3
CH2CCH
CH2CH3


A-2793
CF3
CF3
CH2CCH
CH2CH2CH3


A-2794
CF3
CF3
CH2CCH
CH2CH2OCH3


A-2795
CF3
CF3
CH2CCH
OCH3


A-2796
CF3
CF3
CH2C6H5
CH3


A-2797
CF3
CF3
CH2C6H5
CH2CH3


A-2798
CF3
CF3
CH2C6H5
CH2CH2CH3


A-2799
CF3
CF3
CH2C6H5
CH2CH2OCH3


A-2800
CF3
CF3
CH2C6H5
OCH3


A-2801
CF3
SO2CH3
CH3
CH3


A-2802
CF3
SO2CH3
CH3
CH2CH3


A-2803
CF3
SO2CH3
CH3
CH2CH2CH3


A-2804
CF3
SO2CH3
CH3
CH2CH2OCH3


A-2805
CF3
SO2CH3
CH3
OCH3


A-2806
CF3
SO2CH3
CH2CH3
CH3


A-2807
CF3
SO2CH3
CH2CH3
CH2CH3


A-2808
CF3
SO2CH3
CH2CH3
CH2CH2CH3


A-2809
CF3
SO2CH3
CH2CH3
CH2CH2OCH3


A-2810
CF3
SO2CH3
CH2CH3
OCH3


A-2811
CF3
SO2CH3
CH2OCH3
CH3


A-2812
CF3
SO2CH3
CH2OCH3
CH2CH3


A-2813
CF3
SO2CH3
CH2OCH3
CH2CH2CH3


A-2814
CF3
SO2CH3
CH2OCH3
CH2CH2OCH3


A-2815
CF3
SO2CH3
CH2OCH3
OCH3


A-2816
CF3
SO2CH3
CH2OCH2CH3
CH3


A-2817
CF3
SO2CH3
CH2OCH2CH3
CH2CH3


A-2818
CF3
SO2CH3
CH2OCH2CH3
CH2CH2CH3


A-2819
CF3
SO2CH3
CH2OCH2CH3
CH2CH2OCH3


A-2820
CF3
SO2CH3
CH2OCH2CH3
OCH3


A-2821
CF3
SO2CH3
CH2(CO)OCH3
CH3


A-2822
CF3
SO2CH3
CH2(CO)OCH3
CH2CH3


A-2823
CF3
SO2CH3
CH2(CO)OCH3
CH2CH2CH3


A-2824
CF3
SO2CH3
CH2(CO)OCH3
CH2CH2OCH3


A-2825
CF3
SO2CH3
CH2(CO)OCH3
OCH3


A-2826
CF3
SO2CH3
CH2CHCH2
CH3


A-2827
CF3
SO2CH3
CH2CHCH2
CH2CH3


A-2828
CF3
SO2CH3
CH2CHCH2
CH2CH2CH3


A-2829
CF3
SO2CH3
CH2CHCH2
CH2CH2OCH3


A-2830
CF3
SO2CH3
CH2CHCH2
OCH3


A-2831
CF3
SO2CH3
CH2CCH
CH3


A-2832
CF3
SO2CH3
CH2CCH
CH2CH3


A-2833
CF3
SO2CH3
CH2CCH
CH2CH2CH3


A-2834
CF3
SO2CH3
CH2CCH
CH2CH2OCH3


A-2835
CF3
SO2CH3
CH2CCH
OCH3


A-2836
CF3
SO2CH3
CH2C6H5
CH3


A-2837
CF3
SO2CH3
CH2C6H5
CH2CH3


A-2838
CF3
SO2CH3
CH2C6H5
CH2CH2CH3


A-2839
CF3
SO2CH3
CH2C6H5
CH2CH2OCH3


A-2840
CF3
SO2CH3
CH2C6H5
OCH3


A-2841
CF3
NO2
CH3
CH3


A-2842
CF3
NO2
CH3
CH2CH3


A-2843
CF3
NO2
CH3
CH2CH2CH3


A-2844
CF3
NO2
CH3
CH2CH2OCH3


A-2845
CF3
NO2
CH3
OCH3


A-2846
CF3
NO2
CH2CH3
CH3


A-2847
CF3
NO2
CH2CH3
CH2CH3


A-2848
CF3
NO2
CH2CH3
CH2CH2CH3


A-2849
CF3
NO2
CH2CH3
CH2CH2OCH3


A-2850
CF3
NO2
CH2CH3
OCH3


A-2851
CF3
NO2
CH2OCH3
CH3


A-2852
CF3
NO2
CH2OCH3
CH2CH3


A-2853
CF3
NO2
CH2OCH3
CH2CH2CH3


A-2854
CF3
NO2
CH2OCH3
CH2CH2OCH3


A-2855
CF3
NO2
CH2OCH3
OCH3


A-2856
CF3
NO2
CH2OCH2CH3
CH3


A-2857
CF3
NO2
CH2OCH2CH3
CH2CH3


A-2858
CF3
NO2
CH2OCH2CH3
CH2CH2CH3


A-2859
CF3
NO2
CH2OCH2CH3
CH2CH2OCH3


A-2860
CF3
NO2
CH2OCH2CH3
OCH3


A-2861
CF3
NO2
CH2(CO)OCH3
CH3


A-2862
CF3
NO2
CH2(CO)OCH3
CH2CH3


A-2863
CF3
NO2
CH2(CO)OCH3
CH2CH2CH3


A-2864
CF3
NO2
CH2(CO)OCH3
CH2CH2OCH3


A-2865
CF3
NO2
CH2(CO)OCH3
OCH3


A-2866
CF3
NO2
CH2CHCH2
CH3


A-2867
CF3
NO2
CH2CHCH2
CH2CH3


A-2868
CF3
NO2
CH2CHCH2
CH2CH2CH3


A-2869
CF3
NO2
CH2CHCH2
CH2CH2OCH3


A-2870
CF3
NO2
CH2CHCH2
OCH3


A-2871
CF3
NO2
CH2CCH
CH3


A-2872
CF3
NO2
CH2CCH
CH2CH3


A-2873
CF3
NO2
CH2CCH
CH2CH2CH3


A-2874
CF3
NO2
CH2CCH
CH2CH2OCH3


A-2875
CF3
NO2
CH2CCH
OCH3


A-2876
CF3
NO2
CH2C6H5
CH3


A-2877
CF3
NO2
CH2C6H5
CH2CH3


A-2878
CF3
NO2
CH2C6H5
CH2CH2CH3


A-2879
CF3
NO2
CH2C6H5
CH2CH2OCH3


A-2880
CF3
NO2
CH2C6H5
OCH3










Examples of preferred compounds I.B, where X is CR2, are the individual compounds compiled in Tables 11 to 240 below. Moreover, the meanings mentioned below for the individual variables in the Tables are per se, independently of the combination in which they are mentioned, a particularly preferred embodiment of the substituents in question.




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Table 11: compounds of formula I.B1 (I.B1-1.1-I.B1-1.2880) in which R2 is SCH3, R4 is H and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 12: compounds of formula I.B1 (I.B1-2.1-I.B1-2.2880) in which R2 is SCH3, R4 is H and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 13: compounds of formula I.B1 (I.B1-3.1-I.B1-3.2880) in which R2 is SCH3, R4 is F and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 14: compounds of formula I.B1 (I.B1-4.1-I.B1-4.2880) in which R2 is SCH3, R4 is F and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 15: compounds of formula I.B1 (I.B1-5.1-I.B1-5.2880) in which R2 is SCH3, R4 is Cl and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 16: compounds of formula I.B1 (I.B1-6.1-I.B1-6.2880) in which R2 is SCH3, R4 is Cl and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 17: compounds of formula I.B1 (I.B1-7.1-I.B1-7.2880) in which R2 is SCH3, R4 is CN and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 18: compounds of formula I.B1 (I.B1-8.1-I.B1-8.2880) in which R2 is SCH3, R4 is CN and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 19: compounds of formula I.B1 (I.B1-9.1-I.B1-9.2880) in which R2 is SCH3, R4 is CH3 and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 20: compounds of formula I.B1 (I.B1-10.1-I.B1-10.2880) in which R2 is SCH3, R4 is CH3 and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 21: Compounds of formula I.B2 (I.B2-1.1-I.B2-1.2880) in which R2 is SCH2CH3, R4 is H and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 22: Compounds of formula I.B2 (I.B2-2.1-I.B2-2.2880) in which R2 is SCH2CH3, R4 is H and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 23: compounds of formula I.B2 (I.B2-3.1-I.B2-3.2880) in which R2 is SCH2CH3, R4 is F and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 24: compounds of formula I.B2 (I.B2-4.1-I.B2-4.2880) in which R2 is SCH2CH3, R4 is F and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 25: compounds of formula I.B2 (I.B2-5.1-I.B2-5.2880) in which R2 is SCH2CH3, R4 is Cl and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 26: compounds of formula I.B2 (I.B2-6.1-I.B2-6.2880) in which R2 is SCH2CH3, R4 is Cl and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 27: compounds of formula I.B2 (I.B2-7.1-I.B2-7.2880) in which R2 is SCH2CH3, R4 is CN and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 28: compounds of formula I.B2 (I.B2-8.1-I.B2-8.2880) in which R2 is SCH2CH3, R4 is CN and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 29: compounds of formula I.B2 (I.B2-9.1-I.B2-9.2880) in which R2 is SCH2CH3, R4 is CH3 and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 30: compounds of formula I.B2 (I.B2-10.1-I.B2-10.2880) in which R2 is SCH2CH3, R4 is CH3 and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 31: compounds of formula I.B3 (I.B3-1.1-I.B3-1.2880) in which R2 is SO2CH2CH3, R4 is H and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 32: compounds of formula I.B3 (I.B3-2.1-I.B3-2.2880) in which R2 is SO2CH2CH3, R4 is H and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 33: compounds of formula I.B3 (I.B3-3.1-I.B3-3.2880) in which R2 is SO2CH2CH3, R4 is F and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 34: compounds of formula I.B3 (I.B3-4.1-I.B3-4.2880) in which R2 is SO2CH2CH3, R4 is F and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 35: compounds of formula I.B3 (I.B3-5.1-I.B3-5.2880) in which R2 is SO2CH2CH3, R4 is Cl and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 36: compounds of formula I.B3 (I.B3-6.1-I.B3-6.2880) in which R2 is SO2CH2CH3, R4 is Cl and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 37: compounds of formula I.B3 (I.B3-7.1-I.B3-7.2880) in which R2 is SO2CH2CH3, R4 is CN and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 38: compounds of formula I.B3 (I.B3-8.1-I.B3-8.2880) in which R2 is SO2CH2CH3, R4 is CN and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 39: compounds of formula I.B3 (I.B3-9.1-I.B3-9.2880) in which R2 is SO2CH2CH3, R4 is CH3 and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 40: compounds of formula I.B3 (I.B3-10.1-I.B3-10.2880) in which R2 is SO2CH2CH3, R4 is CH3 and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 41: compounds of formula I.B4 (I.B4-1.1-I.B4-1.2880) in which R2 is SOCH3, R4 is H and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 42: compounds of formula I.B4 (I.B4-2.1-I.B4-2.2880) in which R2 is SOCH3, R4 is H and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 43: compounds of formula I.B4 (I.B4-3.1-I.B4-3.2880) in which R2 is SOCH3, R4 is F and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 44: compounds of formula I.B4 (I.B4-4.1-I.B4-4.2880) in which R2 is SOCH3, R4 is F and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 45: compounds of formula I.B4 (I.B4-5.1-I.B4-5.2880) in which R2 is SOCH3, R4 is Cl and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 46: compounds of formula I.B4 (I.B4-6.1-I.B4-6.2880) in which R2 is SOCH3, R4 is Cl and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 47: compounds of formula I.B4 (I.B4-7.1-I.B4-7.2880) in which R2 is SOCH3, R4 is CN and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 48: compounds of formula I.B4 (I.B4-8.1-I.B4-8.2880) in which R2 is SOCH3, R4 is CN and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 49: compounds of formula I.B4 (I.B4-9.1-I.B4-9.2880) in which R2 is SOCH3, R4 is CH3 and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 50: compounds of formula I.B4 (I.B4-10.1-I.B4-10.2880) in which R2 is SOCH3, R4 is CH3 and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 51: compounds of formula I.B5 (I.B5-1.1-I.B5-1.2880) in which R2 is SOCH2CH3, R4 is H and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 52: compounds of formula I.B5 (I.B5-2.1-I.B5-2.2880) in which R2 is SOCH2CH3, R4 is H and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 53: compounds of formula I.B5 (I.B5-3.1-I.B5-3.2880) in which R2 is SOCH2CH3, R4 is F and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 54: compounds of formula I.B5 (I.B5-4.1-I.B5-4.2880) in which R2 is SOCH2CH3, R4 is F and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 55: compounds of formula I.B5 (I.B5-5.1-I.B5-5.2880) in which R2 is SOCH2CH3, R4 is Cl and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 56: compounds of formula I.B5 (I.B5-6.1-I.B5-6.2880) in which R2 is SOCH2CH3, R4 is Cl and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 57: compounds of formula I.B5 (I.B5-7.1-I.B5-7.2880) in which R2 is SOCH2CH3, R4 is CN and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 58: compounds of formula I.B5 (I.B5-8.1-I.B5-8.2880) in which R2 is SOCH2CH3, R4 is CN and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 59: compounds of formula I.B5 (I.B5-9.1-I.B5-9.2880) in which R2 is SOCH2CH3, R4 is CH3 and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 60: compounds of formula I.B5 (I.B5-10.1-I.B5-10.2880) in which R2 is SOCH2CH3, R4 is CH3 and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 61: compounds of formula I.B6 (I.B6-1.1-I.B6-1.2880) in which R2 is OCH3, R4 is H and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 62: compounds of formula I.B6 (I.B6-2.1-I.B6-2.2880) in which R2 is OCH3, R4 is H and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 63: compounds of formula I.B6 (I.B6-3.1-I.B6-3.2880) in which R2 is OCH3, R4 is F and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 64: compounds of formula I.B6 (I.B6-4.1-I.B6-4.2880) in which R2 is OCH3, R4 is F and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 65: compounds of formula I.B6 (I.B6-5.1-I.B6-5.2880) in which R2 is OCH3, R4 is Cl and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 66: compounds of formula I.B6 (I.B6-6.1-I.B6-6.2880) in which R2 is OCH3, R4 is Cl and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 67: compounds of formula I.B6 (I.B6-7.1-I.B6-7.2880) in which R2 is OCH3, R4 is CN and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 68: compounds of formula I.B6 (I.B6-8.1-I.B6-8.2880) in which R2 is OCH3, R4 is CN and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 69: compounds of formula I.B6 (I.B6-9.1-I.B6-9.2880) in which R2 is OCH3, R4 is CH3 and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 70: compounds of formula I.B6 (I.B6-10.1-I.B6-10.2880) in which R2 is OCH3, R4 is CH3 and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 71: Compounds of formula I.B7 (I.B7-1.1-I.B7-1.2880) in which R2 is OCH2CH3, R4 is H and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 72: compounds of formula I.B7 (I.B7-2.1-I.B7-2.2880) in which R2 is OCH2CH3, R4 is H and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 73: compounds of formula I.B7 (I.B7-3.1-I.B7-3.2880) in which R2 is OCH2CH3, R4 is F and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 74: compounds of formula I.B7 (I.B7-4.1-I.B7-4.2880) in which R2 is OCH2CH3, R4 is F and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 75: compounds of formula I.B7 (I.B7-5.1-I.B7-5.2880) in which R2 is OCH2CH3, R4 is Cl and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 76: compounds of formula I.B7 (I.B7-6.1-I.B7-6.2880) in which R2 is OCH2CH3, R4 is Cl and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 77: compounds of formula I.B7 (I.B7-7.1-I.B7-7.2880) in which R2 is OCH2CH3, R4 is CN and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 78: compounds of formula I.B7 (I.B7-8.1-I.B7-8.2880) in which R2 is OCH2CH3, R4 is CN and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 79: compounds of formula I.B7 (I.B7-9.1-I.B7-9.2880) in which R2 is OCH2CH3, R4 is CH3 and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 80: compounds of formula I.B7 (I.B7-10.1-I.B7-10.2880) in which R2 is OCH2CH3, R4 is CH3 and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 81: compounds of formula I.B8 (I.B8-1.1-I.B8-1.2880) in which R2 is OCHF2, R4 is H and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 82: compounds of formula I.B8 (I.B8-2.1-I.B8-2.2880) in which R2 is OCHF2, R4 is H and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 83: compounds of formula I.B8 (I.B8-3.1-I.B8-3.2880) in which R2 is OCHF2, R4 is F and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 84: compounds of formula I.B8 (I.B8-4.1-I.B8-4.2880) in which R2 is OCHF2, R4 is F and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 85: compounds of formula I.B8 (I.B8-5.1-I.B8-5.2880) in which R2 is OCHF2, R4 is Cl and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 86: compounds of formula I.B8 (I.B8-6.1-I.B8-6.2880) in which R2 is OCHF2, R4 is Cl and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 87: compounds of formula I.B8 (I.B8-7.1-I.B8-7.2880) in which R2 is OCHF2, R4 is CN and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 88: compounds of formula I.B8 (I.B8-8.1-I.B8-8.2880) in which R2 is OCHF2, R4 is CN and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 89: compounds of formula I.B8 (I.B8-9.1-I.B8-9.2880) in which R2 is OCHF2, R4 is CH3 and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 90: compounds of formula I.B8 (I.B8-10.1-I.B8-10.2880) in which R2 is OCHF2, R4 is CH3 and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 91: compounds of formula I.B9 (I.B9-1.1-I.B9-1.2880) in which R2 is OCH2CF3, R4 is H and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 92: compounds of formula I.B9 (I.B9-2.1-I.B9-2.2880) in which R2 is OCH2CF3, R4 is H and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 93: compounds of formula I.B9 (I.B9-3.1-I.B9-3.2880) in which R2 is OCH2CF3, R4 is F and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 94: compounds of formula I.B9 (I.B9-4.1-I.B9-4.2880) in which R2 is OCH2CF3, R4 is F and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 95: compounds of formula I.B9 (I.B9-5.1-I.B9-5.2880) in which R2 is OCH2CF3, R4 is Cl and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 96: compounds of formula I.B9 (I.B9-6.1-I.B9-6.2880) in which R2 is OCH2CF3, R4 is Cl and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 97: compounds of formula I.B9 (I.B9-7.1-I.B9-7.2880) in which R2 is OCH2CF3, R4 is CN and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 98: compounds of formula I.B9 (I.B9-8.1-I.B9-8.2880) in which R2 is OCH2CF3, R4 is CN and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 99: compounds of formula I.B9 (I.B9-9.1-I.B9-9.2880) in which R2 is OCH2CF3, R4 is CH3 and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 100: compounds of formula I.B9 (I.B9-10.1-I.B9-10.2880) in which R2 is OCH2CF3, R4 is CH3 and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 101: Compounds of formula I.B10 (I.B10-1.1-I.B10-1.2880) in which R2 is OCH2CH2OCH3, R4 is H and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 102: compounds of formula I.B10 (I.B10-2.1-I.B10-2.2880) in which R2 is OCH2CH2OCH3, R4 is H and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 103: compounds of formula I.B10 (I.B10-3.1-I.B10-3.2880) in which R2 is OCH2CH2OCH3, R4 is F and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 104: compounds of formula I.B10 (I.B10-4.1-I.B10-4.2880) in which R2 is OCH2CH2OCH3, R4 is F and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 105: compounds of formula I.B10 (I.B10-5.1-I.B10-5.2880) in which R2 is OCH2CH2OCH3, R4 is Cl and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 106: compounds of formula I.B10 (I.B10-6.1-I.B10-6.2880) in which R2 is OCH2CH2OCH3, R4 is Cl and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 107: compounds of formula I.B10 (I.B10-7.1-I.B10-7.2880) in which R2 is OCH2CH2OCH3, R4 is CN and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 108: compounds of formula I.B10 (I.B10-8.1-I.B10-8.2880) in which R2 is OCH2CH2OCH3, R4 is CN and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 109: compounds of formula I.B10 (I.B10-9.1-I.B10-9.2880) in which R2 is OCH2CH2OCH3, R4 is CH3 and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 110: compounds of formula I.B10 (I.B10-10.1-I.B10-10.2880) in which R2 is OCH2CH2OCH3, R4 is CH3 and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 111: compounds of formula I.B11 (I.B11-1.1-I.B11-1.2880) in which R2 is H, R4 is H and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 112: compounds of formula I.B11 (I.B11-2.1-I.B11-2.2880) in which R2 is H, R4 is H and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 113: compounds of formula I.B11 (I.B11-3.1-I.B11-3.2880) in which R2 is H, R4 is F and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 114: compounds of formula I.B11 (I.B11-4.1-I.B11-4.2880) in which R2 is H, R4 is F and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 115: compounds of formula I.B11 (I.B11-5.1-I.B11-5.2880) in which R2 is H, R4 is Cl and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 116: compounds of formula I.B11 (I.B11-6.1-I.B11-6.2880) in which R2 is H, R4 is Cl and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 117: compounds of formula I.B11 (I.B11-7.1-I.B11-7.2880) in which R2 is H, R4 is CN and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 118: compounds of formula I.B11 (I.B11-8.1-I.B11-8.2880) in which R2 is H, R4 is CN and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 119: compounds of formula I.B11 (I.B11-9.1-I.B11-9.2880) in which R2 is H, R4 is CH3 and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 120: compounds of formula I.B11 (I.B11-10.1-I.B11-10.2880) in which R2 is H, R4 is CH3 and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 121: compounds of formula I.B12 (I.B12-1.1-I.B12-1.2880) in which R2 is SO2CH3, R4 is H and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 122: compounds of formula I.B12 (I.B12-2.1-I.B12-2.2880) in which R2 is SO2CH3, R4 is H and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 123: compounds of formula I.B12 (I.B12-3.1-I.B12-3.2880) in which R2 is SO2CH3, R4 is F and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 124: compounds of formula I.B12 (I.B12-4.1-I.B12-4.2880) in which R2 is SO2CH3, R4 is F and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 125: compounds of formula I.B12 (I.B12-5.1-I.B12-5.2880) in which R2 is SO2CH3, R4 is Cl and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 126: compounds of formula I.B12 (I.B12-6.1-I.B12-6.2880) in which R2 is SO2CH3, R4 is Cl and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 127: compounds of formula I.B12 (I.B12-7.1-I.B12-7.2880) in which R2 is SO2CH3, R4 is CN and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 128: compounds of formula I.B12 (I.B12-8.1-I.B12-8.2880) in which R2 is SO2CH3, R4 is CN and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 129: compounds of formula I.B12 (I.B12-9.1-I.B12-9.2880) in which R2 is SO2CH3, R4 is CH3 and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 130: compounds of formula I.B12 (I.B12-10.1-I.B12-10.2880) in which R2 is SO2CH3, R4 is CH3 and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 131: compounds of formula I.B13 (I.B13-1.1-I.B13-1.2880) in which R2 is CH2OCH2CF3, R4 is H and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 132: compounds of formula I.B13 (I.B13-2.1-I.B13-2.2880) in which R2 is CH2OCH2CF3, R4 is H and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 133: compounds of formula I.B13 (I.B13-3.1-I.B13-3.2880) in which R2 is CH2OCH2CF3, R4 is F and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 134: compounds of formula I.B13 (I.B13-4.1-I.B13-4.2880) in which R2 is CH2OCH2CF3, R4 is F and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 135: compounds of formula I.B13 (I.B13-5.1-I.B13-5.2880) in which R2 is CH2OCH2CF3, R4 is Cl and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 136: compounds of formula I.B13 (I.B13-6.1-I.B13-6.2880) in which R2 is CH2OCH2CF3, R4 is Cl and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 137: compounds of formula I.B13 (I.B13-7.1-I.B13-7.2880) in which R2 is CH2OCH2CF3, R4 is CN and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 138: compounds of formula I.B13 (I.B13-8.1-I.B13-8.2880) in which R2 is CH2OCH2CF3, R4 is CN and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 139: compounds of formula I.B13 (I.B13-9.1-I.B13-9.2880) in which R2 is CH2OCH2CF3, R4 is CH3 and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 140: compounds of formula I.B13 (I.B13-10.1-I.B13-10.2880) in which R2 is CH2OCH2CF3, R4 is CH3 and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 141: Compounds of formula I.B14 (I.B14-1.1-I.B14-1.2880) in which R2 is isoxazolin-3-yl, R4 is H and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 142: compounds of formula I.B14 (I.B14-2.1-I.B14-2.2880) in which R2 is isoxazolin-3-yl, R4 is H and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 143: compounds of formula I.B14 (I.B14-3.1-I.B14-3.2880) in which R2 is isoxazolin-3-yl, R4 is F and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 144: compounds of formula I.B14 (I.B14-4.1-I.B14-4.2880) in which R2 is isoxazolin-3-yl, R4 is F and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 145: compounds of formula I.B14 (I.B14-5.1-I.B14-5.2880) in which R2 is isoxazolin-3-yl, R4 is Cl and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 146: compounds of formula I.B14 (I.B14-6.1-I.B14-6.2880) in which R2 is isoxazolin-3-yl, R4 is Cl and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 147: compounds of formula I.B14 (I.B14-7.1-I.B14-7.2880) in which R2 is isoxazolin-3-yl, R4 is CN and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 148: compounds of formula I.B14 (I.B14-8.1-I.B14-8.2880) in which R2 is isoxazolin-3-yl, R4 is CN and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 149: compounds of formula I.B14 (I.B14-9.1-I.B14-9.2880) in which R2 is isoxazolin-3-yl, R4 is CH3 and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 150: compounds of formula I.B14 (I.B14-10.1-I.B14-10.2880) in which R2 is isoxazolin-3-yl, R4 is CH3 and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 151: compounds of formula I.B15 (I.B15-1.1-I.B15-1.2880) in which R2 is 5-methyl-isoxazolin-3-yl, R4 is H and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 152: compounds of formula I.B15 (I.B15-2.1-I.B15-2.2880) in which R2 is 5-methyl-isoxazolin-3-yl, R4 is H and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 153: compounds of formula I.B15 (I.B15-3.1-I.B15-3.2880) in which R2 is 5-methyl-isoxazolin-3-yl, R4 is F and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 154: compounds of formula I.B15 (I.B15-4.1-I.B15-4.2880) in which R2 is 5-methyl-isoxazolin-3-yl, R4 is F and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 155: compounds of formula I.B15 (I.B15-5.1-I.B15-5.2880) in which R2 is 5-methyl-isoxazolin-3-yl, R4 is Cl and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 156: compounds of formula I.B15 (I.B15-6.1-I.B15-6.2880) in which R2 is 5-methyl-isoxazolin-3-yl, R4 is Cl and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 157: compounds of formula I.B15 (I.B15-7.1-I.B15-7.2880) in which R2 is 5-methyl-isoxazolin-3-yl, R4 is CN and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 158: compounds of formula I.B15 (I.B15-8.1-I.B15-8.2880) in which R2 is 5-methyl-isoxazolin-3-yl, R4 is CN and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 159: compounds of formula I.B15 (I.B15-9.1-I.B15-9.2880) in which R2 is 5-methyl-isoxazolin-3-yl, R4 is CH3 and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 160: compounds of formula I.B15 (I.B15-10.1-I.B15-10.2880) in which R2 is 5-methyl-isoxazolin-3-yl, R4 is CH3 and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 161: compounds of formula I.B16 (I.B16-1.1-I.B16-1.2880) in which R2 is isoxazol-3-yl, R4 is H and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 162: compounds of formula I.B16 (I.B16-2.1-I.B16-2.2880) in which R2 is isoxazol-3-yl, R4 is H and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 163: compounds of formula I.B16 (I.B16-3.1-I.B16-3.2880) in which R2 is isoxazol-3-yl, R4 is F and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 164: compounds of formula I.B16 (I.B16-4.1-I.B16-4.2880) in which R2 is isoxazol-3-yl, R4 is F and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 165: compounds of formula I.B16 (I.B16-5.1-I.B16-5.2880) in which R2 is isoxazol-3-yl, R4 is Cl and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 166: compounds of formula I.B16 (I.B16-6.1-I.B16-6.2880) in which R2 is isoxazol-3-yl, R4 is Cl and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 167: compounds of formula I.B16 (I.B16-7.1-I.B16-7.2880) in which R2 is isoxazol-3-yl, R4 is CN and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 168: compounds of formula I.B16 (I.B16-8.1-I.B16-8.2880) in which R2 is isoxazol-3-yl, R4 is CN and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 169: compounds of formula I.B16 (I.B16-9.1-I.B16-9.2880) in which R2 is isoxazol-3-yl, R4 is CH3 and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 170: compounds of formula I.B16 (I.B16-10.1-I.B16-10.2880) in which R2 is isoxazol-3-yl, R4 is CH3 and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 171: compounds of formula I.B17 (I.B17-1.1-I.B17-1.2880) in which R2 is 5-methyl-isoxazol-3-yl, R4 is H and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 172: compounds of formula I.B17 (I.B17-2.1-I.B17-2.2880) in which R2 is 5-methyl-isoxazol-3-yl, R4 is H and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 173: compounds of formula I.B17 (I.B17-3.1-I.B17-3.2880) in which R2 is 5-methyl-isoxazol-3-yl, R4 is F and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 174: compounds of formula I.B17 (I.B17-4.1-I.B17-4.2880) in which R2 is 5-methyl-isoxazol-3-yl, R4 is F and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 175: compounds of formula I.B17 (I.B17-5.1-I.B17-5.2880) in which R2 is 5-methyl-isoxazol-3-yl, R4 is Cl and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 176: compounds of formula I.B17 (I.B17-6.1-I.B17-6.2880) in which R2 is 5-methyl-isoxazol-3-yl, R4 is Cl and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 177: compounds of formula I.B17 (I.B17-7.1-I.B17-7.2880) in which R2 is 5-methyl-isoxazol-3-yl, R4 is CN and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 178: compounds of formula I.B17 (I.B17-8.1-I.B17-8.2880) in which R2 is 5-methyl-isoxazol-3-yl, R4 is CN and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 179: compounds of formula I.B17 (I.B17-9.1-I.B17-9.2880) in which R2 is 5-methyl-isoxazol-3-yl, R4 is CH3 and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 180: compounds of formula I.B17 (I.B17-10.1-I.B17-10.2880) in which R2 is 5-methyl-isoxazol-3-yl, R4 is CH3 and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 181: compounds of formula I.B18 (I.B18-1.1-I.B18-1.2880) in which R2 is 3-methyl-isoxazolin-5-yl, R4 is H and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 182: compounds of formula I.B18 (I.B18-2.1-I.B18-2.2880) in which R2 is 3-methyl-isoxazolin-5-yl, R4 is H and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 183: compounds of formula I.B18 (I.B18-3.1-I.B18-3.2880) in which R2 is 3-methyl-isoxazolin-5-yl, R4 is F and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 184: compounds of formula I.B18 (I.B18-4.1-I.B18-4.2880) in which R2 is 3-methyl-isoxazolin-5-yl, R4 is F and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 185: compounds of formula I.B18 (I.B18-5.1-I.B18-5.2880) in which R2 is 3-methyl-isoxazolin-5-yl, R4 is Cl and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 186: compounds of formula I.B18 (I.B18-6.1-I.B18-6.2880) in which R2 is 3-methyl-isoxazolin-5-yl, R4 is Cl and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 187: compounds of formula I.B18 (I.B18-7.1-I.B18-7.2880) in which R2 is 3-methyl-isoxazolin-5-yl, R4 is CN and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 188: compounds of formula I.B18 (I.B18-8.1-I.B18-8.2880) in which R2 is 3-methyl-isoxazolin-5-yl, R4 is CN and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 189: compounds of formula I.B18 (I.B18-9.1-I.B18-9.2880) in which R2 is 3-methyl-isoxazolin-5-yl, R4 is CH3 and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 190: compounds of formula I.B18 (I.B18-10.1-I.B18-10.2880) in which R2 is 3-methyl-isoxazolin-5-yl, R4 is CH3 and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 191: Compounds of formula I.B19 (I.B19-1.1-I.B19-1.2880) in which R2 is 3-methyl-isoxazol-5-yl, R4 is H and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 192: compounds of formula I.B19 (I.B19-2.1-I.B19-2.2880) in which R2 is 3-methyl-isoxazol-5-yl, R4 is H and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 193: compounds of formula I.B19 (I.B19-3.1-I.B19-3.2880) in which R2 is 3-methyl-isoxazol-5-yl, R4 is F and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 194: compounds of formula I.B19 (I.B19-4.1-I.B19-4.2880) in which R2 is 3-methyl-isoxazol-5-yl, R4 is F and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 195: compounds of formula I.B19 (I.B19-5.1-I.B19-5.2880) in which R2 is 3-methyl-isoxazol-5-yl, R4 is Cl and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 196: compounds of formula I.B19 (I.B19-6.1-I.B19-6.2880) in which R2 is 3-methyl-isoxazol-5-yl, R4 is Cl and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 197: compounds of formula I.B19 (I.B19-7.1-I.B19-7.2880) in which R2 is 3-methyl-isoxazol-5-yl, R4 is CN and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 198: compounds of formula I.B19 (I.B19-8.1-I.B19-8.2880) in which R2 is 3-methyl-isoxazol-5-yl, R4 is CN and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 199: compounds of formula I.B19 (I.B19-9.1-I.B19-9.2880) in which R2 is 3-methyl-isoxazol-5-yl, R4 is CH3 and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 200: compounds of formula I.B19 (I.B19-10.1-I.B19-10.2880) in which R2 is 3-methyl-isoxazol-5-yl, R4 is CH3 and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 201: compounds of formula I.B20 (I.B20-1.1-I.B20-1.2880) in which R2 is CH3, R4 is H and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 202: compounds of formula I.B20 (I.B20-2.1-I.B20-2.2880) in which R2 is CH3, R4 is H and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 203: compounds of formula I.B20 (I.B20-3.1-I.B20-3.2880) in which R2 is CH3, R4 is F and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 204: compounds of formula I.B20 (I.B20-4.1-I.B20-4.2880) in which R2 is CH3, R4 is F and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 205: compounds of formula I.B20 (I.B20-5.1-I.B20-5.2880) in which R2 is CH3, R4 is Cl and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 206: compounds of formula I.B20 (I.B20-6.1-I.B20-6.2880) in which R2 is CH3, R4 is Cl and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 207: compounds of formula I.B20 (I.B20-7.1-I.B20-7.2880) in which R2 is CH3, R4 is CN and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 208: compounds of formula I.B20 (I.B20-8.1-I.B20-8.2880) in which R2 is CH3, R4 is CN and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 209: compounds of formula I.B20 (I.B20-9.1-I.B20-9.2880) in which R2 is CH3, R4 is CH3 and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 210: compounds of formula I.B20 (I.B20-10.1-I.B20-10.2880) in which R2 is CH3, R4 is CH3 and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 211: compounds of formula I.B21 (I.B21-1.1-I.B21-1.2880) in which R2 is CH2OCH3, R4 is H and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 212: compounds of formula I.B21 (I.B21-2.1-I.B21-2.2880) in which R2 is CH2OCH3, R4 is H and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 213: compounds of formula I.B21 (I.B21-3.1-I.B21-3.2880) in which R2 is CH2OCH3, R4 is F and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 214: compounds of formula I.B21 (I.B21-4.1-I.B21-4.2880) in which R2 is CH2OCH3, R4 is F and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 215: compounds of formula I.B21 (I.B21-5.1-I.B21-5.2880) in which R2 is CH2OCH3, R4 is Cl and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 216: compounds of formula I.B21 (I.B21-6.1-I.B21-6.2880) in which R2 is CH2OCH3, R4 is Cl and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 217: compounds of formula I.B21 (I.B21-7.1-I.B21-7.2880) in which R2 is CH2OCH3, R4 is CN and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 218: compounds of formula I.B21 (I.B21-8.1-I.B21-8.2880) in which R2 is CH2OCH3, R4 is CN and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 219: compounds of formula I.B21 (I.B21-9.1-I.B21-9.2880) in which R2 is CH2OCH3, R4 is CH3 and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 220: compounds of formula I.B21 (I.B21-10.1-I.B21-10.2880) in which R2 is CH2OCH3, R4 is CH3 and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 221: compounds of formula I.B22 (I.B22-1.1-I.B22-1.2880) in which R2 is OCH2CH(CH2)2, R4 is H and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 222: compounds of formula I.B22 (I.B22-2.1-I.B22-2.2880) in which R2 is OCH2CH(CH2)2, R4 is H and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 223: compounds of formula I.B22 (I.B22-3.1-I.B22-3.2880) in which R2 is OCH2CH(CH2)2, R4 is F and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 224: compounds of formula I.B22 (I.B22-4.1-I.B22-4.2880) in which R2 is OCH2CH(CH2)2, R4 is F and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 225: compounds of formula I.B22 (I.B22-5.1-I.B22-5.2880) in which R2 is OCH2CH(CH2)2, R4 is Cl and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 226: compounds of formula I.B22 (I.B22-6.1-I.B22-6.2880) in which R2 is OCH2CH(CH2)2, R4 is Cl and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 227: compounds of formula I.B22 (I.B22-7.1-I.B22-7.2880) in which R2 is OCH2CH(CH2)2, R4 is CN and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 228: compounds of formula I.B22 (I.B22-8.1-I.B22-8.2880) in which R2 is OCH2CH(CH2)2, R4 is CN and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 229: compounds of formula I.B22 (I.B22-9.1-I.B22-9.2880) in which R2 is OCH2CH(CH2)2, R4 is CH3 and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 230: compounds of formula I.B22 (I.B22-10.1-I.B22-10.2880) in which R2 is OCH2CH(CH2)2, R4 is CH3 and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 231: compounds of formula I.B23 (I.B23-1.1-I.B23-1.2880) in which R2 is NCH3SO2CH3, R4 is H and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 232: compounds of formula I.B23 (I.B23-2.1-I.B23-2.2880) in which R2 is NCH3SO2CH3, R4 is H and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 233: compounds of formula I.B23 (I.B23-3.1-I.B23-3.2880) in which R2 is NCH3SO2CH3, R4 is F and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 234: compounds of formula I.B23 (I.B23-4.1-I.B23-4.2880) in which R2 is NCH3SO2CH3, R4 is F and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 235: compounds of formula I.B23 (I.B23-5.1-I.B23-5.2880) in which R2 is NCH3SO2CH3, R4 is Cl and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 236: compounds of formula I.B23 (I.B23-6.1-I.B23-6.2880) in which R2 is NCH3SO2CH3, R4 is Cl and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 237: compounds of formula I.B23 (I.B23-7.1-I.B23-7.2880) in which R2 is NCH3SO2CH3, R4 is CN and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 238: compounds of formula I.B23 (I.B23-8.1-I.B23-8.2880) in which R2 is NCH3SO2CH3, R4 is CN and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 239: compounds of formula I.B23 (I.B23-9.1-I.B23-9.2880) in which R2 is NCH3SO2CH3, R4 is CH3 and R5 is F and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


Table 240: compounds of formula I.B23 (I.B23-10.1-I.B23-10.2880) in which R2 is NCH3SO2CH3, R4 is CH3 and R5 is Cl and the combination of R1, R3, R6 and R7 for a compound corresponds in each case to one row of Table A;


The compounds of the formula I can be prepared by standard methods of organic chemistry, e.g. by the methods described hereinafter in schemes 1 to 5. The substituents, variables and indices in schemes 1 to 5 are as defined above for formula I, if not otherwise specified.


The compounds of formula (I) can be prepared for instance as shown in the Scheme 1 below.




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4-Amino-1,2,5-oxadiazole compounds of formula III can be reacted with benzoyl derivatives of formula II to afford compounds of the formula I. Z is a leaving group, such as halogen, in particular Cl, an anhydride residue or an active ester residue. Especially in case of Z being halogen the reaction is suitably carried out in the presence of a base. Suitable bases are for example carbonates, such as lithium, sodium or potassium carbonates, amines, such as trimethylamine or triethylamine, and basic N-heterocycles, such as pyridine, 2,6-dimethylpyridine or 2,4,6-trimethylpyridine. Suitable solvents are in particular aprotic solvents such as pentane, hexane, heptane, octane, cyclohexane, dichloromethane, chloroform, 1,2-dichlorethane, benzene, chlorobenzene, toluene, the xylenes, dichlorobenzene, trimethylbenzene, pyridine, 2,6-dimethylpyridine, 2,4,6-trimethylpyridine, acetonitrile, diethyl ether, tetrahydrofuran, 2-methyl tetrahydrofuran, methyl tert-butylether, 1,4-dioxane, N,N-dimethyl formamide, N-methyl pyrrolidinone or mixtures thereof. The starting materials are generally reacted with one another in equimolar or nearly equimolar amounts at a reaction temperature usually in the range of −20° C. to 100° C. and preferably in the range of −5° C. to 50° C.


Alternatively, compounds of formula (I) can also be prepared as shown in Scheme 2. Reaction of a 4-amino-1,2,5-oxadiazole compound III with a benzoic acid derivative of formula IV yields compound I. The reaction is preferably carried in the presence of a suitable activating agent which converts the acid group of compound IV into an activated ester or amide. For this purpose activating agents known in the art, such as 1,1′, carbonyldiimidazole (CDI), dicyclohexyl carbodiimide (DCC), 1-ethyl-3-(3-dimethylaminopropyl)carbodiimide (EDC) or 2,4,6-tripropyl-1,3,5,2,4,6-trioxatriphosphorinane-2,4,6-trioxide (T3P) can be employed. The activated ester or amide can be formed, depending in particular on the specific activating agent used, either in situ by contacting compound IV with the activating agent in the presence of compound III, or in a separate step prior to the reaction with compound III. It may be advantageous, especially in cases where DCC or EDC are used as activating agent, to include further additives in the activating reaction, such as hydroxybenzotriazole (HOBt), nitrophenol, pentafluorophenol, 2,4,5-trichlorophenol or N-hydroxysuccinimide. It may further be advantageous to prepare the activated ester or amide in the presence of a base, for example a tertiary amine. The activated ester or amide is either in situ or subsequently reacted with the amine of formula III to afford the amide of formula I. The reaction normally takes place in anhydrous inert solvents, such as chlorinated hydrocarbons, e.g. dichloromethane or dichloroethane, ethers, e.g. tetrahydrofuran or 1,4-dioxane or carboxamides, e.g. N,N-dimethylformamide, N,N-dimethylacetamide or N-methylpyrrolidone. The reaction is ordinarily carried out at temperatures in the range from −20° C. to +25° C.




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The compounds of formula II and their respective benzoic acid precursors of formula IV can be obtained by purchase or can be prepared by processes known in the art or disclosed in the literature, e.g. in WO 9746530, WO 9831676, WO 9831681, WO 2002/018352, WO 2000/003988, US 2007/0191335, U.S. Pat. No. 6,277,847.


The 4-amino-1,2,5-oxadiazole compounds of the formula III are either commercially available or are obtainable according to methods known from the literature. For example, 3-alkyl-4-amino-1,2,5-oxadiazoles can be prepared from 3-ketoesters pursuant to a procedure described in Russian Chemical Bulletin, Int. Ed., 54(4), 1032-1037 (2005), as depicted in Scheme 3.




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As shown in Scheme 4, the compounds of the formula III, where R7 is halogen, can be prepared from commercially available 3,4-diamino-1,2,5-oxadiazole according to procedures described in the literature, e.g. by the Sandmeyer-type reaction disclosed in Heteroatom Chemistry, 15(3), 199-207 (2004).




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As shown in Scheme 5, the compounds of the formula III, where R7 is a nucleophilic residue, can be prepared by introducing the nucleophilic residue via the substitution of a leaving group L, e.g. halogene, in the 4-position of the 1,2,5-oxadiazoles compounds of formula V in accordance to precedures disclosed, for example in Journal of Chemical Research, Synopses (6), 190 (1985), in Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya (9), 2086-8 (1986) or in Russian Chemical Bulletin (Translation of Izvestiya Akademii Nauk, Seriya Khimicheskaya), 53(3), 596-614 (2004).




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As a rule, the compounds of formula I including their stereoisomers, salts, tautomers and N-oxides, and their precursors in the synthesis process, can be prepared by the methods described above. If individual compounds can not be prepared via the above-described routes, they can be prepared by derivatization of other compounds I or the respective precursor or by customary modifications of the synthesis routes described. For example, in individual cases, certain compounds of formula I can advantageously be prepared from other compounds of formula I by derivatization, e.g. by ester hydrolysis, amidation, esterification, ether cleavage, olefination, reduction, oxidation and the like, or by customary modifications of the synthesis routes described.


The reaction mixtures are worked up in the customary manner, for example by mixing with water, separating the phases, and, if appropriate, purifying the crude products by chromatography, for example on alumina or on silica gel. Some of the intermediates and end products may be obtained in the form of colorless or pale brown viscous oils which are freed or purified from volatile components under reduced pressure and at moderately elevated temperature. If the intermediates and end products are obtained as solids, they may be purified by recrystallization or trituration.


The compounds of formula I and their agriculturally suitable salts are useful as herbicides. They are useful as such or as an appropriately formulated composition. The herbicidal compositions comprising the compound I, in particular the preferred aspects thereof, control vegetation on non-crop areas very efficiently, especially at high rates of application. They act against broad-leaved weeds and weed grasses in crops such as wheat, rice, corn, soybeans and cotton without causing any significant damage to the crop plants. This effect is mainly observed at low rates of application.


Depending on the application method in question, the compounds of formula I, in particular the preferred aspects thereof, or compositions comprising them can additionally be employed in a further number of crop plants for eliminating unwanted plants. Examples of suitable crops are the following:



Allium cepa, Ananas comosus, Arachis hypogaea, Asparagus officinalis, Avena sativa, Beta vulgaris spec. altissima, Beta vulgaris spec. rapa, Brassica napus var. napus, Brassica napus var. napobrassica, Brassica rapa var. silvestris, Brassica oleracea, Brassica nigra, Camellia sinensis, Carthamus tinctorius, Carya illinoinensis, Citrus limon, Citrus sinensis, Coffea arabica (Coffea canephora, Coffea liberica), Cucumis sativus, Cynodon dactylon, Daucus carota, Elaeis guineensis, Fragaria vesca, Glycine max, Gossypium hirsutum, (Gossypium arboreum, Gossypium herbaceum, Gossypium vitifolium), Helianthus annuus, Hevea brasiliensis, Hordeum vulgare, Humulus lupulus, Ipomoea batatas, Juglans regia, Lens culinaris, Linum usitatissimum, Lycopersicon lycopersicum, Malus spec., Manihot esculenta, Medicago sativa, Musa spec., Nicotiana tabacum (N. rustica), Olea europaea, Oryza sativa, Phaseolus lunatus, Phaseolus vulgaris, Picea abies, Pinus spec., Pistacia vera, Pisum sativum, Prunus avium, Prunus persica, Pyrus communis, Prunus armeniaca, Prunus cerasus, Prunus dulcis and Prunus domestica, Ribes sylvestre, Ricinus communis, Saccharum officinarum, Secale cereale, Sinapis alba, Solanum tuberosum, Sorghum bicolor (s. vulgare), Theobroma cacao, Trifolium pratense, Triticum aestivum, Triticale, Triticum durum, Vicia faba, Vitis vinifera, Zea mays.


The term “crop plants” also includes plants which have been modified by breeding, mutagenesis or genetic engineering. Genetically modified plants are plants whose genetic material has been modified in a manner which does not occur under natural conditions by crossing, mutations or natural recombination (i.e. reassembly of the genetic information). Here, in general, one or more genes are integrated into the genetic material of the plant to improve the properties of the plant.


Accordingly, the term “crop plants” also includes plants which, by breeding and genetic engineering, have acquired tolerance to certain classes of herbicides, such as hydroxyphenylpyruvate dioxygenase (HPPD) inhibitors, acetolactate synthase (ALS) inhibitors, such as, for example, sulfonylureas (EP-A-0257993, U.S. Pat. No. 5,013,659) or imidazolinones (see, for example, U.S. Pat. No. 6,222,100, WO 01/82685, WO 00/26390, WO 97/41218, WO 98/02526, WO 98/02527, WO 04/106529, WO 05/20673, WO 03/14357, WO 03/13225, WO 03/14356, WO 04/16073), enolpyruvylshikimate 3-phosphate synthase (EPSPS) inhibitors, such as, for example, glyphosate (see, for example, WO 92/00377), glutamine synthetase (GS) inhibitors, such as, for example, glufosinate (see, for example, EP-A-0242236, EP-A-242246), or oxynil herbicides (see, for example, U.S. Pat. No. 5,559,024).


Numerous crop plants, for example Clearfield® oilseed rape, tolerant to imidazolinones, for example imazamox, have been generated with the aid of classic breeding methods (mutagenesis). Crop plants such as soybeans, cotton, corn, beet and oilseed rape, resistant to glyphosate or glufosinate, which are available under the tradenames RoundupReady® (glyphosate) and Liberty Link® (glufosinate) have been generated with the aid of genetic engineering methods.


Accordingly, the term “crop plants” also includes plants which, with the aid of genetic engineering, produce one or more toxins, for example those of the bacterial strain Bacillus ssp. Toxins which are produced by such genetically modified plants include, for example, insecticidal proteins of Bacillus spp., in particular B. thuringiensis, such as the endotoxins Cry1Ab, Cry1Ac, Cry1F, Cry1Fa2, Cry2Ab, Cry3A, Cry3Bb1, Cry9c, Cry34Ab1 or Cry35Ab1; or vegetative insecticidal proteins (VIPs), for example VIP1, VIP2, VIP3, or VIP3A; insecticidal proteins of nematode-colonizing bacteria, for example Photorhabdus spp. or Xenorhabdus spp.; toxins of animal organisms, for example wasp, spider or scorpion toxins; fungal toxins, for example from Streptomycetes; plant lectins, for example from peas or barley; agglutinins; proteinase inhibitors, for example trypsin inhibitors, serine protease inhibitors, patatin, cystatin or papain inhibitors, ribosome-inactivating proteins (RIPs), for example ricin, corn-RIP, abrin, luffin, saporin or bryodin; steroid-metabolizing enzymes, for example 3-hydroxysteroid oxidase, ecdysteroid-IDP glycosyl transferase, cholesterol oxidase, ecdysone inhibitors, or HMG-CoA reductase; ion channel blockers, for example inhibitors of sodium channels or calcium channels; juvenile hormone esterase; receptors of the diuretic hormone (helicokinin receptors); stilbene synthase, bibenzyl synthase, chitinases and glucanases. In the plants, these toxins may also be produced as pretoxins, hybrid proteins or truncated or otherwise modified proteins. Hybrid proteins are characterized by a novel combination of different protein domains (see, for example, WO 2002/015701). Further examples of such toxins or genetically modified plants which produce these toxins are disclosed in EP-A 374 753, WO 93/007278, WO 95/34656, EP-A 427 529, EP-A 451 878, WO 03/018810 and WO 03/052073. The methods for producing these genetically modified plants are known to the person skilled in the art and disclosed, for example, in the publications mentioned above. Numerous of the toxins mentioned above bestow, upon the plants by which they are produced, tolerance to pests from all taxonomic classes of arthropods, in particular to beetles (Coeleropta), dipterans (Diptera) and butterflies (Lepidoptera) and to nematodes (Nematoda).


Genetically modified plants which produce one or more genes coding for insecticidal toxins are described, for example, in the publications mentioned above, and some of them are commercially available, such as, for example, YieldGard® (corn varieties producing the toxin Cry1Ab), YieldGard® Plus (corn varieties which produce the toxins Cry1Ab and Cry3Bb1), Starlink® (corn varieties which produce the toxin Cry9c), Herculex® RW (corn varieties which produce the toxins Cry34Ab1, Cry35Ab1 and the enzyme phosphinothricin-N-acetyltransferase [PAT]); NuCOTN® 33B (cotton varieties which produce the toxin Cry1Ac), Bollgard® I (cotton varieties which produce the toxin Cry1Ac), Bollgard® II (cotton varieties which produce the toxins Cry1Ac and Cry2Ab2); VIPCOT® (cotton varieties which produce a VIP toxin); NewLeaf® (potato varieties which produce the toxin Cry3A); Bt-Xtra®, NatureGard®, KnockOut®, BiteGard®, Protecta®, Bt11 (for example Agrisure® CB) and Bt176 from Syngenta Seeds SAS, France (corn varieties which produce the toxin Cry1Ab and the PAT enyzme), MIR604 from Syngenta Seeds SAS, France (corn varieties which produce a modified version of the toxin Cry3A, see WO 03/018810), MON 863 from Monsanto Europe S.A., Belgium (corn varieties which produce the toxin Cry3Bb1), IPC 531 from Monsanto Europe S.A., Belgium (cotton varieties which produce a modified version of the toxin Cry1Ac) and 1507 from Pioneer Overseas Corporation, Belgium (corn varieties which produce the toxin Cry1F and the PAT enzyme).


Accordingly, the term “crop plants” also includes plants which, with the aid of genetic engineering, produce one or more proteins which are more robust or have increased resistance to bacterial, viral or fungal pathogens, such as, for example, pathogenesis-related proteins (PR proteins, see EP-A 0 392 225), resistance proteins (for example potato varieties producing two resistance genes against Phytophthora infestans from the wild Mexican potato Solanum bulbocastanum) or T4 lysozyme (for example potato cultivars which, by producing this protein, are resistant to bacteria such as Erwinia amylvora).


Accordingly, the term “crop plants” also includes plants whose productivity has been improved with the aid of genetic engineering methods, for example by enhancing the potential yield (for example biomass, grain yield, starch, oil or protein content), tolerance to drought, salt or other limiting environmental factors or resistance to pests and fungal, bacterial and viral pathogens.


The term “crop plants” also includes plants whose ingredients have been modified with the aid of genetic engineering methods in particular for improving human or animal diet, for example by oil plants producing health-promoting long-chain omega 3 fatty acids or monounsaturated omega 9 fatty acids (for example Nexera® oilseed rape).


The term “crop plants” also includes plants which have been modified with the aid of genetic engineering methods for improving the production of raw materials, for example by increasing the amylopectin content of potatoes (Amflora® potato).


Furthermore, it has been found that the compounds of formula I are also suitable for the defoliation and/or desiccation of plant parts, for which crop plants such as cotton, potato, oilseed rape, sunflower, soybean or field beans, in particular cotton, are suitable. In this regard, there have been found compositions for the desiccation and/or defoliation of plants, processes for preparing these compositions and methods for desiccating and/or defoliating plants using the compounds of formula I.


As desiccants, the compounds of formula I are particularly suitable for desiccating the above-ground parts of crop plants such as potato, oilseed rape, sunflower and soybean, but also cereals. This makes possible the fully mechanical harvesting of these important crop plants.


Also of economic interest is to facilitate harvesting, which is made possible by concentrating within a certain period of time the dehiscence, or reduction of adhesion to the tree, in citrus fruit, olives and other species and varieties of pomaceous fruit, stone fruit and nuts. The same mechanism, i.e. the promotion of the development of abscission tissue between fruit part or leaf part and shoot part of the plants is also essential for the readily controllable defoliation of useful plants, in particular cotton.


Moreover, a shortening of the time interval in which the individual cotton plants mature leads to an increased fiber quality after harvesting.


The compounds of formula I, or the herbicidal compositions comprising the compounds of formula I, can be used, for example, in the form of ready-to-spray aqueous solutions, powders, suspensions, also highly concentrated aqueous, oily or other suspensions or dispersions, emulsions, oil dispersions, pastes, dusts, materials for broadcasting, or granules, by means of spraying, atomizing, dusting, spreading, watering or treatment of the seed or mixing with the seed. The use forms depend on the intended purpose; in each case, they should ensure the finest possible distribution of the active ingredients according to the invention.


The herbicidal compositions comprise a herbicidally effective amount of at least one compound of the formula I or an agriculturally useful salt of I, and auxiliaries which are customary for the formulation of crop protection agents.


Examples of auxiliaries customary for the formulation of crop protection agents are inert auxiliaries, solid carriers, surfactants (such as dispersants, protective colloids, emulsifiers, wetting agents and tackifiers), organic and inorganic thickeners, bactericides, antifreeze agents, antifoams, if appropriate colorants and, for seed formulations, adhesives.


Examples of thickeners (i.e. compounds which impart to the formulation modified flow properties, i.e. high viscosity in the state of rest and low viscosity in motion) are polysaccharides, such as xanthan gum (Kelzan® from Kelco), Rhodopol® 23 (Rhone Poulenc) or Veegum® (from R.T. Vanderbilt), and also organic and inorganic sheet minerals, such as Attaclay® (from Engelhardt).


Examples of antifoams are silicone emulsions (such as, for example, Silikon® SRE, Wacker or Rhodorsil® from Rhodia), long-chain alcohols, fatty acids, salts of fatty acids, organofluorine compounds and mixtures thereof.


Bactericides can be added for stabilizing the aqueous herbicidal formulation. Examples of bactericides are bactericides based on diclorophen and benzyl alcohol hemiformal (Proxel® from ICI or Acticide® RS from Thor Chemie and Kathon® MK from Rohm & Haas), and also isothiazolinone derivates, such as alkylisothiazolinones and benzisothiazolinones (Acticide MBS from Thor Chemie).


Examples of antifreeze agents are ethylene glycol, propylene glycol, urea or glycerol.


Examples of colorants are both sparingly water-soluble pigments and water-soluble dyes. Examples which may be mentioned are the dyes known under the names Rhodamin B, C.I. Pigment Red 112 and C.I. Solvent Red 1, and also pigment blue 15:4, pigment blue 15:3, pigment blue 15:2, pigment blue 15:1, pigment blue 80, pigment yellow 1, pigment yellow 13, pigment red 112, pigment red 48:2, pigment red 48:1, pigment red 57:1, pigment red 53:1, pigment orange 43, pigment orange 34, pigment orange 5, pigment green 36, pigment green 7, pigment white 6, pigment brown 25, basic violet 10, basic violet 49, acid red 51, acid red 52, acid red 14, acid blue 9, acid yellow 23, basic red 10, basic red 108.


Examples of adhesives are polyvinylpyrrolidone, polyvinyl acetate, polyvinyl alcohol and tylose.


Suitable inert auxiliaries are, for example, the following:


mineral oil fractions of medium to high boiling point, such as kerosene and diesel oil, furthermore coal tar oils and oils of vegetable or animal origin, aliphatic, cyclic and aromatic hydrocarbons, for example paraffin, tetrahydronaphthalene, alkylated naphthalenes and their derivatives, alkylated benzenes and their derivatives, alcohols such as methanol, ethanol, propanol, butanol and cyclohexanol, ketones such as cyclohexanone or strongly polar solvents, for example amines such as N-methylpyrrolidone, and water.


Solid carriers are mineral earths such as silicas, silica gels, silicates, talc, kaolin, limestone, lime, chalk, bole, loess, clay, dolomite, diatomaceous earth, calcium sulfate, magnesium sulfate and magnesium oxide, ground synthetic materials, fertilizers such as ammonium sulfate, ammonium phosphate, ammonium nitrate and ureas, and products of vegetable origin, such as cereal meal, tree bark meal, wood meal and nutshell meal, cellulose powders, or other solid carriers.


Suitable surfactants (adjuvants, wetting agents, tackifiers, dispersants and also emulsifiers) are the alkali metal salts, alkaline earth metal salts and ammonium salts of aromatic sulfonic acids, for example lignosulfonic acids (e.g. Borrespers-types, Borregaard), phenolsulfonic acids, naphthalenesulfonic acids (Morwet types, Akzo Nobel) and dibutylnaphthalenesulfonic acid (Nekal types, BASF SE), and of fatty acids, alkyl- and alkylarylsulfonates, alkyl sulfates, lauryl ether sulfates and fatty alcohol sulfates, and salts of sulfated hexa-, hepta- and octadecanols, and also of fatty alcohol glycol ethers, condensates of sulfonated naphthalene and its derivatives with formaldehyde, condensates of naphthalene or of the naphthalenesulfonic acids with phenol and formaldehyde, polyoxyethylene octylphenol ether, ethoxylated isooctyl-, octyl- or nonylphenol, alkylphenyl or tributylphenyl polyglycol ether, alkylaryl polyether alcohols, isotridecyl alcohol, fatty alcohol/ethylene oxide condensates, ethoxylated castor oil, polyoxyethylene alkyl ethers or polyoxypropylene alkyl ethers, lauryl alcohol polyglycol ether acetate, sorbitol esters, lignosulfite waste liquors and proteins, denatured proteins, polysaccharides (e.g. methylcellulose), hydrophobically modified starches, polyvinyl alcohol (Mowiol types Clariant), polycarboxylates (BASF SE, Sokalan types), polyalkoxylates, polyvinylamine (BASF SE, Lupamine types), polyethyleneimine (BASF SE, Lupasol types), polyvinylpyrrolidone and copolymers thereof.


Powders, materials for broadcasting and dusts can be prepared by mixing or grinding the active ingredients together with a solid carrier.


Granules, for example coated granules, impregnated granules and homogeneous granules, can be prepared by binding the active ingredients to solid carriers.


Aqueous use forms can be prepared from emulsion concentrates, suspensions, pastes, wettable powders or water-dispersible granules by adding water. To prepare emulsions, pastes or oil dispersions, the compounds of formula I or Ia, either as such or dissolved in an oil or solvent, can be homogenized in water by means of a wetting agent, tackifier, dispersant or emulsifier. Alternatively, it is also possible to prepare concentrates comprising active substance, wetting agent, tackifier, dispersant or emulsifier and, if desired, solvent or oil, which are suitable for dilution with water.


The concentrations of the compounds of formula I in the ready-to-use preparations can be varied within wide ranges. In general, the formulations comprise from 0.001 to 98% by weight, preferably 0.01 to 95% by weight of at least one active compound. The active compounds are employed in a purity of from 90% to 100%, preferably 95% to 100% (according to NMR spectrum).


The formulations or ready-to-use preparations may also comprise acids, bases or buffer systems, suitable examples being phosphoric acid or sulfuric acid, or urea or ammonia.


The compounds of formula I of the invention can for example be formulated as follows:


1. Products for Dilution with Water


A. Water-Soluble Concentrates


10 parts by weight of active compound are dissolved in 90 parts by weight of water or a water-soluble solvent. As an alternative, wetters or other adjuvants are added. The active compound dissolves upon dilution with water. This gives a formulation with an active compound content of 10% by weight.


B. Dispersible Concentrates


20 parts by weight of active compound are dissolved in 70 parts by weight of cyclohexanone with addition of 10 parts by weight of a dispersant, for example polyvinylpyrrolidone. Dilution with water gives a dispersion. The active compound content is 20% by weight.


C. Emulsifiable Concentrates


15 parts by weight of active compound are dissolved in 75 parts by weight of an organic solvent (e.g. alkylaromatics) with addition of calcium dodecylbenzenesulfonate and castor oil ethoxylate (in each case 5 parts by weight). Dilution with water gives an emulsion. The formulation has an active compound content of 15% by weight.


D. Emulsions


25 parts by weight of active compound are dissolved in 35 parts by weight of an organic solvent (e.g. alkylaromatics) with addition of calcium dodecylbenzenesulfonate and castor oil ethoxylate (in each case 5 parts by weight). This mixture is introduced into 30 parts by weight of water by means of an emulsifier (e.g. Ultraturrax) and made into a homogeneous emulsion. Dilution with water gives an emulsion. The formulation has an active compound content of 25% by weight.


E. Suspensions


In an agitated ball mill, 20 parts by weight of active compound are comminuted with addition of 10 parts by weight of dispersants and wetters and 70 parts by weight of water or an organic solvent to give a fine active compound suspension. Dilution with water gives a stable suspension of the active compound. The active compound content in the formulation is 20% by weight.


F. Water-Dispersible Granules and Water-Soluble Granules


50 parts by weight of active compound are ground finely with addition of 50 parts by weight of dispersants and wetters and made into water-dispersible or water-soluble granules by means of technical appliances (for example extrusion, spray tower, fluidized bed). Dilution with water gives a stable dispersion or solution of the active compound. The formulation has an active compound content of 50% by weight.


G. Water-Dispersible Powders and Water-Soluble Powders


75 parts by weight of active compound are ground in a rotor-stator mill with addition of 25 parts by weight of dispersants, wetters and silica gel. Dilution with water gives a stable dispersion or solution of the active compound. The active compound content of the formulation is 75% by weight.


H. Gel Formulations


In a ball mill, 20 parts by weight of active compound, 10 parts by weight of dispersant, 1 part by weight of gelling agent and 70 parts by weight of water or of an organic solvent are ground to give a fine suspension. Dilution with water gives a stable suspension with active compound content of 20% by weight.


2. Products to be Applied Undiluted


I. Dusts


5 parts by weight of active compound are ground finely and mixed intimately with 95 parts by weight of finely divided kaolin. This gives a dusting powder with an active compound content of 5% by weight.


J. Granules (GR, FG, GG, MG)


0.5 parts by weight of active compound are ground finely and associated with 99.5 parts by weight of carriers. Current methods here are extrusion, spray-drying or the fluidized bed. This gives granules to be applied undiluted with an active compound content of 0.5% by weight.


K. ULV Solutions (UL)


10 parts by weight of active compound are dissolved in 90 parts by weight of an organic solvent, for example xylene. This gives a product to be applied undiluted with an active compound content of 10% by weight.


The compounds of formula I or the herbicidal compositions comprising them can be applied pre- or post-emergence, or together with the seed of a crop plant. It is also possible to apply the herbicidal compositions or active compounds by applying seed, pretreated with the herbicidal compositions or active compounds, of a crop plant. If the active compounds are less well tolerated by certain crop plants, application techniques may be used in which the herbicidal compositions are sprayed, with the aid of the spraying equipment, in such a way that as far as possible they do not come into contact with the leaves of the sensitive crop plants, while the active compounds reach the leaves of undesirable plants growing underneath, or the bare soil surface (post-directed, lay-by).


In a further embodiment, the compounds of formula I or the herbicidal compositions can be applied by treating seed.


The treatment of seed comprises essentially all procedures familiar to the person skilled in the art (seed dressing, seed coating, seed dusting, seed soaking, seed film coating, seed multilayer coating, seed encrusting, seed dripping and seed pelleting) based on the compounds of formula I according to the invention or the compositions prepared therefrom. Here, the herbicidal compositions can be applied diluted or undiluted.


The term seed comprises seed of all types, such as, for example, corns, seeds, fruits, tubers, cuttings and similar forms. Here, preferably, the term seed describes corns and seeds.


The seed used can be seed of the useful plants mentioned above, but also the seed of transgenic plants or plants obtained by customary breeding methods.


The rates of application of active compound are from 0.001 to 3.0, preferably 0.01 to 1.0, kg/ha of active substance (a.s.), depending on the control target, the season, the target plants and the growth stage. To treat the seed, the compounds of formula I are generally employed in amounts of from 0.001 to 10 kg per 100 kg of seed.


It may also be advantageous to use the compounds of formula I in combination with safeners. Safeners are chemical compounds which prevent or reduce damage to useful plants without substantially affecting the herbicidal action of the compounds of formula I on unwanted plants. They can be used both before sowing (for example in the treatment of seed, or on cuttings or seedlings) and before or after the emergence of the useful plant. The safeners and the compounds of formula I can be used simultaneously or in succession.


Suitable safeners are, for example, (quinolin-8-oxy)acetic acids, 1-phenyl-5-haloalkyl-1H-1,2,4-triazole-3-carboxylic acids, 1-phenyl-4,5-dihydro-5-alkyl-1H-pyrazole-3,5-dicarboxylic acids, 4,5-dihydro-5,5-diaryl-3-isoxazolecarboxylic acids, dichloroacetamides, alpha-oximinophenylacetonitriles, acetophenone oximes, 4,6-dihalo-2-phenylpyrimidines, N-[[4-(aminocarbonyl)phenyl]sulfonyl]-2-benzamides, 1,8-naphthalic anhydride, 2-halo-4-(haloalkyl)-5-thiazolecarboxylic acids, phosphorothiolates and O-phenyl N-alkylcarbamates and their agriculturally useful salts and, provided that they have an acid function, their agriculturally useful derivatives, such as amides, esters and thioesters.


To broaden the activity spectrum and to obtain synergistic effects, the compounds of the formula I can be mixed and jointly applied with numerous representatives of other herbicidal or growth-regulating groups of active compounds or with safeners. Suitable mixing partners are, for example, 1,2,4-thiadiazoles, 1,3,4-thiadiazoles, amides, aminophosphoric acid and its derivatives, aminotriazoles, anilides, aryloxy/heteroaryloxyalkanoic acids and their derivatives, benzoic acid and its derivatives, benzothiadiazinones, 2-(hetaroyl/aroyl)-1,3-cyclohexanediones, heteroaryl aryl ketones, benzylisoxazolidinones, meta-CF3-phenyl derivatives, carbamates, quinoline carboxylic acid and its derivatives, chloroacetanilides, cyclohexenone oxime ether derivates, diazines, dichloropropionic acid and its derivatives, dihydrobenzofurans, dihydrofuran-3-ones, dinitroanilines, dinitrophenols, diphenyl ethers, dipyridyls, halocarboxylic acids and their derivatives, ureas, 3-phenyluracils, imidazoles, imidazolinones, N-phenyl-3,4,5,6-tetrahydrophthalimides, oxadiazoles, oxiranes, phenols, aryloxy- and heteroaryloxyphenoxypropionic esters, phenylacetic acid and its derivatives, 2-phenylpropionic acid and its derivatives, pyrazoles, phenylpyrazoles, pyridazines, pyridinecarboxylic acid and its derivatives, pyrimidyl ethers, sulfonamides, sulfonylureas, triazines, triazinones, triazolinones, triazolecarboxamides, uracils and also phenylpyrazolines and isoxazolines and their derivatives.


Moreover, it may be useful to apply the compounds of formula I alone or in combination with other herbicides or else also mixed with further crop protection agents, jointly, for example with compositions for controlling pests or phytopathogenic fungi or bacteria. Also of interest is the miscibility with mineral salt solutions which are employed for alleviating nutritional and trace element deficiencies. Other additives such as nonphytotoxic oils and oil concentrates may also be added.


Examples of herbicides which can be used in combination with the compounds of formula I according to the present invention are:


b1) from the group of the lipid biosynthesis inhibitors:


alloxydim, alloxydim-sodium, butroxydim, clethodim, clodinafop, clodinafop-propargyl, cycloxydim, cyhalofop, cyhalofop-butyl, diclofop, diclofop-methyl, fenoxaprop, fenoxaprop-ethyl, fenoxaprop-P, fenoxaprop-P-ethyl, fluazifop, fluazifop-butyl, fluazifop-P, fluazifop-P-butyl, haloxyfop, haloxyfop-methyl, haloxyfop-P, haloxyfop-P-methyl, metamifop, pinoxaden, profoxydim, propaquizafop, quizalofop, quizalofop-ethyl, quizalofop-tefuryl, quizalofop-P, quizalofop-P-ethyl, quizalofop-P-tefuryl, sethoxydim, tepraloxydim, tralkoxydim, benfuresate, butylate, cycloate, dalapon, dimepiperate, EPTC, esprocarb, ethofumesate, flupropanate, molinate, orbencarb, pebulate, prosulfocarb, TCA, thiobencarb, tiocarbazil, triallate and vernolate;


b2) from the group of the ALS inhibitors:


amidosulfuron, azimsulfuron, bensulfuron, bensulfuron-methyl, bispyribac, bispyribac-sodium, chlorimuron, chlorimuron-ethyl, chlorsulfuron, cinosulfuron, cloransulam, cloransulam-methyl, cyclosulfamuron, diclosulam, ethametsulfuron, ethametsulfuron-methyl, ethoxysulfuron, flazasulfuron, florasulam, flucarbazone, flucarbazone-sodium, flucetosulfuron, flumetsulam, flupyrsulfuron, flupyrsulfuron-methyl-sodium, foramsulfuron, halosulfuron, halosulfuron-methyl, imazamethabenz, imazamethabenz-methyl, imazamox, imazapic, imazapyr, imazaquin, imazethapyr, imazosulfuron, iodosulfuron, iodosulfuron-methyl-sodium, mesosulfuron, metosulam, metsulfuron, metsulfuron-methyl, nicosulfuron, orthosulfamuron, oxasulfuron, penoxsulam, primisulfuron, primisulfuron-methyl, propoxycarbazone, propoxycarbazone-sodium, prosulfuron, pyrazosulfuron, pyrazosulfuron-ethyl, pyribenzoxim, pyrimisulfan, pyriftalid, pyriminobac, pyriminobac-methyl, pyrithiobac, pyrithiobac-sodium, pyroxsulam, rimsulfuron, sulfometuron, sulfometuron-methyl, sulfosulfuron, thiencarbazone, thiencarbazone-methyl, thifensulfuron, thifensulfuron-methyl, triasulfuron, tribenuron, tribenuron-methyl, trifloxysulfuron, triflusulfuron, triflusulfuron-methyl and tritosulfuron;


b3) from the group of the photosynthesis inhibitors:


ametryn, amicarbazone, atrazine, bentazone, bentazone-sodium, bromacil, bromofenoxim, bromoxynil and its salts and esters, chlorobromuron, chloridazone, chlorotoluron, chloroxuron, cyanazine, desmedipham, desmetryn, dimefuron, dimethametryn, diquat, diquatdibromide, diuron, fluometuron, hexazinone, ioxynil and its salts and esters, isoproturon, isouron, karbutilate, lenacil, linuron, metamitron, methabenzthiazuron, metobenzuron, metoxuron, metribuzin, monolinuron, neburon, paraquat, paraquat-dichloride, paraquat-dimetilsulfate, pentanochlor, phenmedipham, phenmedipham-ethyl, prometon, prometryn, propanil, propazine, pyridafol, pyridate, siduron, simazine, simetryn, tebuthiuron, terbacil, terbumeton, terbuthylazine, terbutryn, thidiazuron and trietazine;


b4) from the group of the protoporphyrinogen-IX oxidase inhibitors:


acifluorfen, acifluorfen-sodium, azafenidin, bencarbazone, benzfendizone, bifenox, butafenacil, carfentrazone, carfentrazone-ethyl, chlomethoxyfen, cinidon-ethyl, fluazolate, flufenpyr, flufenpyr-ethyl, flumiclorac, flumiclorac-pentyl, flumioxazin, fluoroglycofen, fluoroglycofen-ethyl, fluthiacet, fluthiacet-methyl, fomesafen, halosafen, lactofen, oxadiargyl, oxadiazon, oxyfluorfen, pentoxazone, profluazol, pyraclonil, pyraflufen, pyraflufen-ethyl, saflufenacil, sulfentrazone, thidiazimin, 2-chloro-5-[3,6-dihydro-3-methyl-2,6-dioxo-4-(trifluoromethyl)-1(2H)-pyrimidinyl]-4-fluoro-N-[(isopropyl)methylsulfamoyl]benzamide (H-1; CAS 372137-35-4), ethyl [3-[2-chloro-4-fluoro-5-(1-methyl-6-trifluoromethyl-2,4-dioxo-1,2,3,4-tetrahydropyrimidin-3-yl)phenoxy]-2-pyridyloxy]acetate (H-2; CAS 353292-31-6), N-ethyl-3-(2,6-dichloro-4-trifluoromethylphenoxy)-5-methyl-1H-pyrazole-1-carboxamide (H-3; CAS 452098-92-9), N-tetrahydrofurfuryl-3-(2,6-dichloro-4-trifluoromethylphenoxy)-5-methyl-1H-pyrazole-1-carboxamide (H-4; CAS 915396-43-9), N-ethyl-3-(2-chloro-6-fluoro-4-trifluoromethylphenoxy)-5-methyl-1H-pyrazole-1-carboxamide (H-5; CAS 452099-05-7), N-tetrahydrofurfuryl-3-(2-chloro-6-fluoro-4-trifluoromethylphenoxy)-5-methyl-1H-pyrazole-1-carboxamide (H-6; CAS 45100-03-7), 3-[7-fluoro-3-oxo-4-(prop-2-ynyl)-3,4-dihydro-2H-benzo[1,4]oxazin-6-yl]-1,5-dimethyl-6-thioxo-[1,3,5]triazinan-2,4-dione, 1,5-dimethyl-6-thioxo-3-(2,2,7-trifluoro-3-oxo-4-(prop-2-ynyl)-3,4-dihydro-2H-benzo[b][1,4]oxazin-6-yl)-1,3,5-triazinane-2,4-dione, 2-(2,2,7-Trifluoro-3-oxo-4-prop-2-ynyl-3,4-dihydro-2H-benzo[1,4]oxazin-6-yl)-4,5,6,7-tetrahydro-isoindole-1,3-dione and 1-Methyl-6-trifluoromethyl-3-(2,2,7-trifluoro-3-oxo-4-prop-2-ynyl-3,4-dihydro-2H-benzo[1,4]oxazin-6-yl)-1H-pyrimidine-2,4-dione;


b5) from the group of the bleacher herbicides:


aclonifen, amitrol, beflubutamid, benzobicyclon, benzofenap, clomazone, diflufenican, fluridone, flurochloridone, flurtamone, isoxaflutole, mesotrione, norflurazon, picolinafen, pyrasulfutole, pyrazolynate, pyrazoxyfen, sulcotrione, tefuryltrione, tembotrione, topramezone, 4-hydroxy-3-[[2-[(2-methoxyethoxy)methyl]-6-(trifluoromethyl)-3-pyridyl]carbonyl]bicyclo[3.2.1]oct-3-en-2-one (H-7; CAS 352010-68-5) and 4-(3-trifluoromethylphenoxy)-2-(4-trifluoromethylphenyl)pyrimidine (H-8; CAS 180608-33-7);


b6) from the group of the EPSP synthase inhibitors:


glyphosate, glyphosate-isopropylammonium and glyphosate-trimesium (sulfosate);


b7) from the group of the glutamine synthase inhibitors:


bilanaphos (bialaphos), bilanaphos-sodium, glufosinate and glufosinate-ammonium;


b8) from the group of the DHP synthase inhibitors:


asulam;


b9) from the group of the mitose inhibitors:


amiprophos, amiprophos-methyl, benfluralin, butamiphos, butralin, carbetamide, chlorpropham, chlorthal, chlorthal-dimethyl, dinitramine, dithiopyr, ethalfluralin, fluchloralin, oryzalin, pendimethalin, prodiamine, propham, propyzamide, tebutam, thiazopyr and trifluralin;


b10) from the group of the VLCFA inhibitors:


acetochlor, alachlor, anilofos, butachlor, cafenstrole, dimethachlor, dimethanamid, dimethenamid-P, diphenamid, fentrazamide, flufenacet, mefenacet, metazachlor, metolachlor, metolachlor-S, naproanilide, napropamide, pethoxamid, piperophos, pretilachlor, propachlor, propisochlor, pyroxasulfone (KIH-485) and thenylchlor;


Compounds of the formula 2:




embedded image


in which the variables have the following meanings:


Y is phenyl or 5- or 6-membered heteroaryl as defined at the outset, which radicals may be substituted by one to three groups Raa; RA, RB, RC, RD are H, halogen or C1-C4-alkyl; A is O or NH; q is 0 or 1.


Compounds of the formula 2 have in particular the following meanings:




embedded image


where # denotes the bond to the skeleton of the molecule; and


RA, RB, RC, RD are H, Cl, F or CH3; RE is halogen, C1-C4-alkyl or C1-C4-haloalkyl; RF is C1-C4-alkyl; RG is halogen, C1-C4-alkoxy or C1-C4-haloalkoxy; RH is H, halogen, C1-C4-alkyl, C1-C4-haloalkyl or C1-C4-haloalkoxy; r is 0, 1, 2 or 3; A is oxygen; q is 0 or 1.


Preferred compounds of the formula 2 have the following meanings:




embedded image


RA is H; RB, RC are F; R24 is H or F; A is oxygen; q is 0 or 1.


Particularly preferred compounds of the formula 2 are:


3-[5-(2,2-difluoroethoxy)-1-methyl-3-trifluoromethyl-1H-pyrazol-4-ylmethane-sulfonyl]-4-fluoro-5,5-dimethyl-4,5-dihydroisoxazole (2-1); 3-{[5-(2,2-difluoroethoxy)-1-methyl-3-trifluoromethyl-1H-pyrazol-4-yl]fluoromethanesulfonyl}-5,5-dimethyl-4,5-dihydroisoxazole (2-2); 4-(4-fluoro-5,5-dimethyl-4,5-dihydroisoxazole-3-sulfonylmethyl)-2-methyl-5-trifluoromethyl-2H-[1,2,3]triazole (2-3); 4-[(5,5-dimethyl-4,5-dihydroisoxazole-3-sulfonyl)fluoromethyl]-2-methyl-5-trifluoromethyl-2H-[1,2,3]triazole (2-4); 4-(5,5-dimethyl-4,5-dihydroisoxazole-3-sulfonylmethyl)-2-methyl-5-trifluoromethyl-2H-[1,2,3]triazole (2-5); 3-{[5-(2,2-difluoroethoxy)-1-methyl-3-trifluoromethyl-1H-pyrazol-4-yl]difluoromethanesulfonyl}-5,5-dimethyl-4,5-dihydroisoxazole (2-6); 4-[(5,5-dimethyl-4,5-dihydroisoxazole-3-sulfonyl)difluoromethyl]-2-methyl-5-trifluoromethyl-2H-[1,2,3]triazole (2-7); 3-{[5-(2,2-difluoroethoxy)-1-methyl-3-trifluoromethyl-1H-pyrazol-4-yl]difluoromethanesulfonyl}-4-fluoro-5,5-dimethyl-4,5-dihydroisoxazole (2-8); 4-[difluoro-(4-fluoro-5,5-dimethyl-4,5-dihydroisoxazole-3-sulfonyl)methyl]-2-methyl-5-trifluoromethyl-2H-[1,2,3]triazole (2-9);


b11) from the group of the cellulose biosynthesis inhibitors:


chlorthiamid, dichlobenil, flupoxam and isoxaben;


b12) from the group of the decoupler herbicides:


dinoseb, dinoterb and DNOC and its salts;


b13) from the group of the auxin herbicides:


2,4-D and its salts and esters, 2,4-DB and its salts and esters, aminopyralid and its salts such as aminopyralid-tris(2-hydroxypropyl)ammonium and its esters, benazolin, benazolin-ethyl, chloramben and its salts and esters, clomeprop, clopyralid and its salts and esters, dicamba and its salts and esters, dichlorprop and its salts and esters, dichlorprop-P and its salts and esters, fluroxypyr, fluroxypyr-butometyl, fluroxypyr-meptyl, MCPA and its salts and esters, MCPA-thioethyl, MCPB and its salts and esters, mecoprop and its salts and esters, mecoprop-P and its salts and esters, picloram and its salts and esters, quinclorac, quinmerac, TBA (2,3,6) and its salts and esters, triclopyr and its salts and esters, and 5,6-dichloro-2-cyclopropyl-4-pyrimidinecarboxylic acid (H-9; CAS 858956-08-8) and its salts and esters;


b14) from the group of the auxin transport inhibitors: diflufenzopyr, diflufenzopyr-sodium, naptalam and naptalam-sodium;


b15) from the group of the other herbicides: bromobutide, chlorflurenol, chlorflurenol-methyl, cinmethylin, cumyluron, dalapon, dazomet, difenzoquat, difenzoquat-metilsulfate, dimethipin, DSMA, dymron, endothal and its salts, etobenzanid, flamprop, flamprop-isopropyl, flamprop-methyl, flamprop-M-isopropyl, flamprop-M-methyl, flurenol, flurenol-butyl, flurprimidol, fosamine, fosamine-ammonium, indanofan, maleic hydrazide, mefluidide, metam, methyl azide, methyl bromide, methyl-dymron, methyl iodide, MSMA, oleic acid, oxaziclomefone, pelargonic acid, pyributicarb, quinoclamine, triaziflam, tridiphane and 6-chloro-3-(2-cyclopropyl-6-methylphenoxy)-4-pyridazinol (H-10; CAS 499223-49-3) and its salts and esters.


Examples of preferred safeners C are benoxacor, cloquintocet, cyometrinil, cyprosulfamide, dichlormid, dicyclonone, dietholate, fenchlorazole, fenclorim, flurazole, fluxofenim, furilazole, isoxadifen, mefenpyr, mephenate, naphthalic anhydride, oxabetrinil, 4-(dichloroacetyl)-1-oxa-4-azaspiro[4.5]decane (H-11; MON4660, CAS 71526-07-3) and 2,2,5-trimethyl-3-(dichloroacetyl)-1,3-oxazolidine (H-12; R-29148, CAS 52836-31-4).


The active compounds of groups b1) to b15) and the safeners C are known herbicides and safeners, see, for example, The Compendium of Pesticide Common Names (http://www.alanwood.net/pesticides/); B. Hock, C. Fedtke, R. R. Schmidt, Herbizide [Herbicides], Georg Thieme Verlag, Stuttgart, 1995. Further herbicidally active compounds are known from WO 96/26202, WO 97/41116, WO 97/41117, WO 97/41118, WO 01/83459 and WO 2008/074991 and from W. Kramer et al. (ed.) “Modern Crop Protection Compounds”, Vol. 1, Wiley VCH, 2007 and the literature quoted therein.


The invention also relates to compositions in the form of a crop protection composition formulated as a 1-component composition comprising an active compound combination comprising at least one compound of the formula I and at least one further active compound, preferably selected from the active compounds of groups b1 to b15, and at least one solid or liquid carrier and/or one or more surfactants and, if desired, one or more further auxiliaries customary for crop protection compositions.


The invention also relates to compositions in the form of a crop protection composition formulated as a 2-component composition comprising a first component comprising at least one compound of the formula I, a solid or liquid carrier and/or one or more surfactants and a second component comprising at least one further active compound selected from the active compounds of groups b1 to b15, a solid or liquid carrier and/or one or more surfactants, where additionally both components may also comprise further auxiliaries customary for crop protection compositions.


In binary compositions comprising at least one compound of the formula I as component A and at least one herbicide B, the weight ratio of the active compounds A:B is generally in the range of from 1:1000 to 1000:1, preferably in the range of from 1:500 to 500:1, in particular in the range of from 1:250 to 250:1 and particularly preferably in the range of from 1:75 to 75:1.


In binary compositions comprising at least one compound of the formula I as component A and at least one safener C, the weight ratio of the active compounds A:C is generally in the range of from 1:1000 to 1000:1, preferably in the range of from 1:500 to 500:1, in particular in the range of from 1:250 to 250:1 and particularly preferably in the range of from 1:75 to 75:1.


In ternary compositions comprising both at least one compound of the formula I as component A, at least one herbicide B and at least one safener C, the relative parts by weight of the components A:B are generally in the range of from 1:1000 to 1000:1, preferably in the range of from 1:500 to 500:1, in particular in the range of from 1:250 to 250:1 and particularly preferably in the range of from 1:75 to 75:1; the weight ratio of the components A:C is generally in the range of from 1:1000 to 1000:1, preferably in the range of from 1:500 to 500:1, in particular in the range of from 1:250 to 250:1 and particularly preferably in the range of from 1:75 to 75:1; and the weight ratio of the components B:C is generally in the range of from 1:1000 to 1000:1, preferably in the range of from 1:500 to 500:1, in particular in the range of from 1:250 to 250:1 and particularly preferably in the range of from 1:75 to 75:1. Preferably, the weight ratio of the components A+B to the component C is in the range of from 1:500 to 500:1, in particular in the range of from 1:250 to 250:1 and particularly preferably in the range of from 1:75 to 75:1.


Examples of particularly preferred compositions according to the invention comprising in each case one individualized compound of the formula I and one mixing partner or a mixing partner combination are given in Table B below.


A further aspect of the invention relates to the compositions B-1 to B-1236 listed in Table B below, where in each case one row of Table B corresponds to a herbicidal composition comprising one of the compounds of formula I individualized in the above description (component 1) and the further active compound from groups b1) to b15) and/or safener C stated in each case in the row in question (component 2). The active compounds in the compositions described are in each case preferably present in synergistically effective amounts.












TABLE B







Herbicide(s) B
Safener C


















B-1
clodinafop-propargyl
—


B-2
cycloxydim
—


B-3
cyhalofop-butyl
—


B-4
fenoxaprop-P-ethyl
—


B-5
pinoxaden
—


B-6
profoxydim
—


B-7
tepraloxydim
—


B-8
tralkoxydim
—


B-9
esprocarb
—


B-10
prosulfocarb
—


B-11
thiobencarb
—


B-12
triallate
—


B-13
bensulfuron-methyl
—


B-14
bispyribac-sodium
—


B-15
cyclosulfamuron
—


B-16
flumetsulam
—


B-17
flupyrsulfuron-methyl-sodium
—


B-18
foramsulfuron
—


B-19
imazamox
—


B-20
imazapic
—


B-21
imazapyr
—


B-22
imazaquin
—


B-23
imazethapyr
—


B-24
imazosulfuron
—


B-25
iodosulfuron-methyl-sodium
—


B-26
mesosulfuron
—


B-27
nicosulfuron
—


B-28
penoxsulam
—


B-29
propoxycarbazone-sodium
—


B-30
pyrazosulfuron-ethyl
—


B-31
pyroxsulam
—


B-32
rimsulfuron
—


B-33
sulfosulfuron
—


B-34
thiencarbazone-methyl
—


B-35
tritosulfuron
—


B-36
2,4-D and its salts and esters
—


B-37
aminopyralid and its salts and esters
—


B-38
clopyralid and its salts and esters
—


B-39
dicamba and its salts and esters
—


B-40
fluroxypyr-meptyl
—


B-41
quinclorac
—


B-42
quinmerac
—


B-43
H-9
—


B-44
diflufenzopyr
—


B-45
diflufenzopyr-sodium
—


B-46
clomazone
—


B-47
diflufenican
—


B-48
fluorochloridone
—


B-49
isoxaflutol
—


B-50
mesotrione
—


B-51
picolinafen
—


B-52
sulcotrione
—


B-53
tefuryltrione
—


B-54
tembotrione
—


B-55
topramezone
—


B-56
H-7
—


B-57
atrazine
—


B-58
diuron
—


B-59
fluometuron
—


B-60
hexazinone
—


B-61
isoproturon
—


B-62
metribuzin
—


B-63
propanil
—


B-64
terbuthylazine
—


B-65
paraquat dichloride
—


B-66
flumioxazin
—


B-67
oxyfluorfen
—


B-68
saflufenacil
—


B-69
sulfentrazone
—


B-70
H-1
—


B-71
H-2
—


B-72
glyphosate
—


B-73
glyphosate-isopropylammonium
—


B-74
glyphosate-trimesium (sulfosate)
—


B-75
glufosinate
—


B-76
glufosinate-ammonium
—


B-77
pendimethalin
—


B-78
trifluralin
—


B-79
acetochlor
—


B-80
cafenstrole
—


B-81
dimethenamid-P
—


B-82
fentrazamide
—


B-83
flufenacet
—


B-84
mefenacet
—


B-85
metazachlor
—


B-86
metolachlor-S
—


B-87
pyroxasulfone
—


B-88
isoxaben
—


B-89
dymron
—


B-90
indanofan
—


B-91
oxaziclomefone
—


B-92
triaziflam
—


B-93
chlorotoluron
—


B-94
atrazine + H-1
—


B-95
atrazine + glyphosate
—


B-96
atrazine + mesotrione
—


B-97
atrazine + nicosulfuron
—


B-98
atrazine + tembotrione
—


B-99
atrazine + topramezone
—


B-100
clomazone + glyphosate
—


B-101
diflufenican + clodinafop-propargyl
—


B-102
diflufenican + fenoxaprop-P-ethyl
—


B-103
diflufenican + flupyrsulfuron-methyl-sodium
—


B-104
diflufenican + glyphosate
—


B-105
diflufenican + mesosulfuron-methyl
—


B-106
diflufenican + pinoxaden
—


B-107
diflufenican + pyroxsulam
—


B-108
flumetsulam + glyphosate
—


B-109
flumioxazin + glyphosate
—


B-110
imazapic + glyphosate
—


B-111
imazethapyr + glyphosate
—


B-112
isoxaflutol + H-1
—


B-113
isoxaflutol + glyphosate
—


B-114
metazachlor + H-1
—


B-115
metazachlor + glyphosate
—


B-116
metazachlor + mesotrione
—


B-117
metazachlor + nicosulfuron
—


B-118
metazachlor + terbuthylazine
—


B-119
metazachlor + topramezone
—


B-120
metribuzin + glyphosate
—


B-121
pendimethalin + H-1
—


B-122
pendimethalin + clodinafop-propargyl
—


B-123
pendimethalin + fenoxaprop-P-ethyl
—


B-124
pendimethalin + flupyrsulfuron-methyl-sodium
—


B-125
pendimethalin + glyphosate
—


B-126
pendimethalin + mesosulfuron-methyl
—


B-127
pendimethalin + mesotrione
—


B-128
pendimethalin + nicosulfuron
—


B-129
pendimethalin + pinoxaden
—


B-130
pendimethalin + pyroxsulam
—


B-131
pendimethalin + tembotrione
—


B-132
pendimethalin + topramezone
—


B-133
pyroxasulfone + tembotrione
—


B-134
pyroxasulfone + topramezone
—


B-135
sulfentrazone + glyphosate
—


B-136
terbuthylazine + H-1
—


B-137
terbuthylazine + foramsulfuron
—


B-138
terbuthylazine + glyphosate
—


B-139
terbuthylazine + mesotrione
—


B-140
terbuthylazine + nicosulfuron
—


B-141
terbuthylazine + tembotrione
—


B-142
terbuthylazine + topramezone
—


B-143
trifluralin + glyphosate
—


B-144
—
benoxacor


B-145
—
cloquintocet


B-146
—
cyprosulfamide


B-147
—
dichlormid


B-148
—
fenchlorazole


B-149
—
isoxadifen


B-150
—
mefenpyr


B-151
—
H-11


B-152
—
H-12


B-153
clodinafop-propargyl
benoxacor


B-154
cycloxydim
benoxacor


B-155
cyhalofop-butyl
benoxacor


B-156
fenoxaprop-P-ethyl
benoxacor


B-157
pinoxaden
benoxacor


B-158
profoxydim
benoxacor


B-159
tepraloxydim
benoxacor


B-160
tralkoxydim
benoxacor


B-161
esprocarb
benoxacor


B-162
prosulfocarb
benoxacor


B-163
thiobencarb
benoxacor


B-164
triallate
benoxacor


B-165
bensulfuron-methyl
benoxacor


B-166
bispyribac-sodium
benoxacor


B-167
cyclosulfamuron
benoxacor


B-168
flumetsulam
benoxacor


B-169
flupyrsulfuron-methyl-sodium
benoxacor


B-170
foramsulfuron
benoxacor


B-171
imazamox
benoxacor


B-172
imazapic
benoxacor


B-173
imazapyr
benoxacor


B-174
imazaquin
benoxacor


B-175
imazethapyr
benoxacor


B-176
imazosulfuron
benoxacor


B-177
iodosulfuron-methyl-sodium
benoxacor


B-178
mesosulfuron
benoxacor


B-179
nicosulfuron
benoxacor


B-180
penoxsulam
benoxacor


B-181
propoxycarbazone-sodium
benoxacor


B-182
pyrazosulfuron-ethyl
benoxacor


B-183
pyroxsulam
benoxacor


B-184
rimsulfuron
benoxacor


B-185
sulfosulfuron
benoxacor


B-186
thiencarbazone-methyl
benoxacor


B-187
tritosulfuron
benoxacor


B-188
2,4-D and its salts and esters
benoxacor


B-189
aminopyralid and its salts and esters
benoxacor


B-190
clopyralid and its salts and esters
benoxacor


B-191
dicamba and its salts and esters
benoxacor


B-192
fluroxypyr-meptyl
benoxacor


B-193
quinclorac
benoxacor


B-194
quinmerac
benoxacor


B-195
H-9
benoxacor


B-196
diflufenzopyr
benoxacor


B-197
diflufenzopyr-sodium
benoxacor


B-198
clomazone
benoxacor


B-199
diflufenican
benoxacor


B-200
fluorochloridone
benoxacor


B-201
isoxaflutol
benoxacor


B-202
mesotrione
benoxacor


B-203
picolinafen
benoxacor


B-204
sulcotrione
benoxacor


B-205
tefuryltrione
benoxacor


B-206
tembotrione
benoxacor


B-207
topramezone
benoxacor


B-208
H-7
benoxacor


B-209
atrazine
benoxacor


B-210
diuron
benoxacor


B-211
fluometuron
benoxacor


B-212
hexazinone
benoxacor


B-213
isoproturon
benoxacor


B-214
metribuzin
benoxacor


B-215
propanil
benoxacor


B-216
terbuthylazine
benoxacor


B-217
paraquat dichloride
benoxacor


B-218
flumioxazin
benoxacor


B-219
oxyfluorfen
benoxacor


B-220
saflufenacil
benoxacor


B-221
sulfentrazone
benoxacor


B-222
H-1
benoxacor


B-223
H-2
benoxacor


B-224
glyphosate
benoxacor


B-225
glyphosate-isopropylammonium
benoxacor


B-226
glyphosate-trimesium (sulfosate)
benoxacor


B-227
glufosinate
benoxacor


B-228
glufosinate-ammonium
benoxacor


B-229
pendimethalin
benoxacor


B-230
trifluralin
benoxacor


B-231
acetochlor
benoxacor


B-232
cafenstrole
benoxacor


B-233
dimethenamid-P
benoxacor


B-234
fentrazamide
benoxacor


B-235
flufenacet
benoxacor


B-236
mefenacet
benoxacor


B-237
metazachlor
benoxacor


B-238
metolachlor-S
benoxacor


B-239
pyroxasulfone
benoxacor


B-240
isoxaben
benoxacor


B-241
dymron
benoxacor


B-242
indanofan
benoxacor


B-243
oxaziclomefone
benoxacor


B-244
triaziflam
benoxacor


B-245
atrazine + H-1
benoxacor


B-246
atrazine + glyphosate
benoxacor


B-247
atrazine + mesotrione
benoxacor


B-248
atrazine + nicosulfuron
benoxacor


B-249
atrazine + tembotrione
benoxacor


B-250
atrazine + topramezone
benoxacor


B-251
clomazone + glyphosate
benoxacor


B-252
diflufenican + clodinafop-propargyl
benoxacor


B-253
diflufenican + fenoxaprop-P-ethyl
benoxacor


B-254
diflufenican + flupyrsulfuron-methyl-sodium
benoxacor


B-255
diflufenican + glyphosate
benoxacor


B-256
diflufenican + mesosulfuron-methyl
benoxacor


B-257
diflufenican + pinoxaden
benoxacor


B-258
diflufenican + pyroxsulam
benoxacor


B-259
flumetsulam + glyphosate
benoxacor


B-260
flumioxazin + glyphosate
benoxacor


B-261
imazapic + glyphosate
benoxacor


B-262
imazethapyr + glyphosate
benoxacor


B-263
isoxaflutol + H-1
benoxacor


B-264
isoxaflutol + glyphosate
benoxacor


B-265
metazachlor + H-1
benoxacor


B-266
metazachlor + glyphosate
benoxacor


B-267
metazachlor + mesotrione
benoxacor


B-268
metazachlor + nicosulfuron
benoxacor


B-269
metazachlor + terbuthylazine
benoxacor


B-270
metazachlor + topramezone
benoxacor


B-271
metribuzin + glyphosate
benoxacor


B-272
pendimethalin + H-1
benoxacor


B-273
pendimethalin + clodinafop-propargyl
benoxacor


B-274
pendimethalin + fenoxaprop-P-ethyl
benoxacor


B-275
pendimethalin + flupyrsulfuron-methyl-sodium
benoxacor


B-276
pendimethalin + glyphosate
benoxacor


B-277
pendimethalin + mesosulfuron-methyl
benoxacor


B-278
pendimethalin + mesotrione
benoxacor


B-279
pendimethalin + nicosulfuron
benoxacor


B-280
pendimethalin + pinoxaden
benoxacor


B-281
pendimethalin + pyroxsulam
benoxacor


B-282
pendimethalin + tembotrione
benoxacor


B-283
pendimethalin + topramezone
benoxacor


B-284
pyroxasulfone + tembotrione
benoxacor


B-285
pyroxasulfone + topramezone
benoxacor


B-286
sulfentrazone + glyphosate
benoxacor


B-287
terbuthylazine + H-1
benoxacor


B-288
terbuthylazine + foramsulfuron
benoxacor


B-289
terbuthylazine + glyphosate
benoxacor


B-290
terbuthylazine + mesotrione
benoxacor


B-291
terbuthylazine + nicosulfuron
benoxacor


B-292
terbuthylazine + tembotrione
benoxacor


B-293
terbuthylazine + topramezone
benoxacor


B-294
trifluralin + glyphosate
benoxacor


B-295
clodinafop-propargyl
cloquintocet


B-296
cycloxydim
cloquintocet


B-297
cyhalofop-butyl
cloquintocet


B-298
fenoxaprop-P-ethyl
cloquintocet


B-299
pinoxaden
cloquintocet


B-300
profoxydim
cloquintocet


B-301
tepraloxydim
cloquintocet


B-302
tralkoxydim
cloquintocet


B-303
esprocarb
cloquintocet


B-304
prosulfocarb
cloquintocet


B-305
thiobencarb
cloquintocet


B-306
triallate
cloquintocet


B-307
bensulfuron-methyl
cloquintocet


B-308
bispyribac-sodium
cloquintocet


B-309
cyclosulfamuron
cloquintocet


B-310
flumetsulam
cloquintocet


B-311
flupyrsulfuron-methyl-sodium
cloquintocet


B-312
foramsulfuron
cloquintocet


B-313
imazamox
cloquintocet


B-314
imazapic
cloquintocet


B-315
imazapyr
cloquintocet


B-316
imazaquin
cloquintocet


B-317
imazethapyr
cloquintocet


B-318
imazosulfuron
cloquintocet


B-319
iodosulfuron-methyl-sodium
cloquintocet


B-320
mesosulfuron
cloquintocet


B-321
nicosulfuron
cloquintocet


B-322
penoxsulam
cloquintocet


B-323
propoxycarbazone-sodium
cloquintocet


B-324
pyrazosulfuron-ethyl
cloquintocet


B-325
pyroxsulam
cloquintocet


B-326
rimsulfuron
cloquintocet


B-327
sulfosulfuron
cloquintocet


B-328
thiencarbazone-methyl
cloquintocet


B-329
tritosulfuron
cloquintocet


B-330
2,4-D and its salts and esters
cloquintocet


B-331
aminopyralid and its salts and esters
cloquintocet


B-332
clopyralid and its salts and esters
cloquintocet


B-333
dicamba and its salts and esters
cloquintocet


B-334
fluroxypyr-meptyl
cloquintocet


B-335
quinclorac
cloquintocet


B-336
quinmerac
cloquintocet


B-337
H-9
cloquintocet


B-338
diflufenzopyr
cloquintocet


B-339
diflufenzopyr-sodium
cloquintocet


B-340
clomazone
cloquintocet


B-341
diflufenican
cloquintocet


B-342
fluorochloridone
cloquintocet


B-343
isoxaflutol
cloquintocet


B-344
mesotrione
cloquintocet


B-345
picolinafen
cloquintocet


B-346
sulcotrione
cloquintocet


B-347
tefuryltrione
cloquintocet


B-348
tembotrione
cloquintocet


B-349
topramezone
cloquintocet


B-350
H-7
cloquintocet


B-351
atrazine
cloquintocet


B-352
diuron
cloquintocet


B-353
fluometuron
cloquintocet


B-354
hexazinone
cloquintocet


B-355
isoproturon
cloquintocet


B-356
metribuzin
cloquintocet


B-357
propanil
cloquintocet


B-358
terbuthylazine
cloquintocet


B-359
paraquat dichloride
cloquintocet


B-360
flumioxazin
cloquintocet


B-361
oxyfluorfen
cloquintocet


B-362
saflufenacil
cloquintocet


B-363
sulfentrazone
cloquintocet


B-364
H-1
cloquintocet


B-365
H-2
cloquintocet


B-366
glyphosate
cloquintocet


B-367
glyphosate-isopropylammonium
cloquintocet


B-368
glyphosate-trimesium (sulfosate)
cloquintocet


B-369
glufosinate
cloquintocet


B-370
glufosinate-ammonium
cloquintocet


B-371
pendimethalin
cloquintocet


B-372
trifluralin
cloquintocet


B-373
acetochlor
cloquintocet


B-374
cafenstrole
cloquintocet


B-375
dimethenamid-P
cloquintocet


B-376
fentrazamide
cloquintocet


B-377
flufenacet
cloquintocet


B-378
mefenacet
cloquintocet


B-379
metazachlor
cloquintocet


B-380
metolachlor-S
cloquintocet


B-381
pyroxasulfone
cloquintocet


B-382
isoxaben
cloquintocet


B-383
dymron
cloquintocet


B-384
indanofan
cloquintocet


B-385
oxaziclomefone
cloquintocet


B-386
triaziflam
cloquintocet


B-387
atrazine + H-1
cloquintocet


B-388
atrazine + glyphosate
cloquintocet


B-389
atrazine + mesotrione
cloquintocet


B-390
atrazine + nicosulfuron
cloquintocet


B-391
atrazine + tembotrione
cloquintocet


B-392
atrazine + topramezone
cloquintocet


B-393
clomazone + glyphosate
cloquintocet


B-394
diflufenican + clodinafop-propargyl
cloquintocet


B-395
diflufenican + fenoxaprop-p-ethyl
cloquintocet


B-396
diflufenican + flupyrsulfuron-methyl-sodium
cloquintocet


B-397
diflufenican + glyphosate
cloquintocet


B-398
diflufenican + mesosulfuron-methyl
cloquintocet


B-399
diflufenican + pinoxaden
cloquintocet


B-400
diflufenican + pyroxsulam
cloquintocet


B-401
flumetsulam + glyphosate
cloquintocet


B-402
flumioxazin + glyphosate
cloquintocet


B-403
imazapic + glyphosate
cloquintocet


B-404
imazethapyr + glyphosate
cloquintocet


B-405
isoxaflutol + H-1
cloquintocet


B-406
isoxaflutol + glyphosate
cloquintocet


B-407
metazachlor + H-1
cloquintocet


B-408
metazachlor + glyphosate
cloquintocet


B-409
metazachlor + mesotrione
cloquintocet


B-410
metazachlor + nicosulfuron
cloquintocet


B-411
metazachlor + terbuthylazine
cloquintocet


B-412
metazachlor + topramezone
cloquintocet


B-413
metribuzin + glyphosate
cloquintocet


B-414
pendimethalin + H-1
cloquintocet


B-415
pendimethalin + clodinafop-propargyl
cloquintocet


B-416
pendimethalin + fenoxaprop-P-ethyl
cloquintocet


B-417
pendimethalin + flupyrsulfuron-methyl-sodium
cloquintocet


B-418
pendimethalin + glyphosate
cloquintocet


B-419
pendimethalin + mesosulfuron-methyl
cloquintocet


B-420
pendimethalin + mesotrione
cloquintocet


B-421
pendimethalin + nicosulfuron
cloquintocet


B-422
pendimethalin + pinoxaden
cloquintocet


B-423
pendimethalin + pyroxsulam
cloquintocet


B-424
pendimethalin + tembotrione
cloquintocet


B-425
pendimethalin + topramezone
cloquintocet


B-426
pyroxasulfone + tembotrione
cloquintocet


B-427
pyroxasulfone + topramezone
cloquintocet


B-428
sulfentrazone + glyphosate
cloquintocet


B-429
terbuthylazine + H-1
cloquintocet


B-430
terbuthylazine + foramsulfuron
cloquintocet


B-431
terbuthylazine + glyphosate
cloquintocet


B-432
terbuthylazine + mesotrione
cloquintocet


B-433
terbuthylazine + nicosulfuron
cloquintocet


B-434
terbuthylazine + tembotrione
cloquintocet


B-435
terbuthylazine + topramezone
cloquintocet


B-436
trifluralin + glyphosate
cloquintocet


B-437
clodinafop-propargyl
dichlormid


B-438
cycloxydim
dichlormid


B-439
cyhalofop-butyl
dichlormid


B-440
fenoxaprop-P-ethyl
dichlormid


B-441
pinoxaden
dichlormid


B-442
profoxydim
dichlormid


B-443
tepraloxydim
dichlormid


B-444
tralkoxydim
dichlormid


B-445
esprocarb
dichlormid


B-446
prosulfocarb
dichlormid


B-447
thiobencarb
dichlormid


B-448
triallate
dichlormid


B-449
bensulfuron-methyl
dichlormid


B-450
bispyribac-sodium
dichlormid


B-451
cyclosulfamuron
dichlormid


B-452
flumetsulam
dichlormid


B-453
flupyrsulfuron-methyl-sodium
dichlormid


B-454
foramsulfuron
dichlormid


B-455
imazamox
dichlormid


B-456
imazapic
dichlormid


B-457
imazapyr
dichlormid


B-458
imazaquin
dichlormid


B-459
imazethapyr
dichlormid


B-460
imazosulfuron
dichlormid


B-461
iodosulfuron-methyl-sodium
dichlormid


B-462
mesosulfuron
dichlormid


B-463
nicosulfuron
dichlormid


B-464
penoxsulam
dichlormid


B-465
propoxycarbazone-sodium
dichlormid


B-466
pyrazosulfuron-ethyl
dichlormid


B-467
pyroxsulam
dichlormid


B-468
rimsulfuron
dichlormid


B-469
sulfosulfuron
dichlormid


B-470
thiencarbazone-methyl
dichlormid


B-471
tritosulfuron
dichlormid


B-472
2,4-D and its salts and esters
dichlormid


B-473
aminopyralid and its salts and esters
dichlormid


B-474
clopyralid and its salts and esters
dichlormid


B-475
dicamba and its salts and esters
dichlormid


B-476
fluroxypyr-meptyl
dichlormid


B-477
quinclorac
dichlormid


B-478
quinmerac
dichlormid


B-479
H-9
dichlormid


B-480
diflufenzopyr
dichlormid


B-481
diflufenzopyr-sodium
dichlormid


B-482
clomazone
dichlormid


B-483
diflufenican
dichlormid


B-484
fluorochloridone
dichlormid


B-485
isoxaflutol
dichlormid


B-486
mesotrione
dichlormid


B-487
picolinafen
dichlormid


B-488
sulcotrione
dichlormid


B-489
tefuryltrione
dichlormid


B-490
tembotrione
dichlormid


B-491
topramezone
dichlormid


B-492
H-7
dichlormid


B-493
atrazine
dichlormid


B-494
diuron
dichlormid


B-495
fluometuron
dichlormid


B-496
hexazinone
dichlormid


B-497
isoproturon
dichlormid


B-498
metribuzin
dichlormid


B-499
propanil
dichlormid


B-500
terbuthylazine
dichlormid


B-501
paraquat dichloride
dichlormid


B-502
flumioxazin
dichlormid


B-503
oxyfluorfen
dichlormid


B-504
saflufenacil
dichlormid


B-505
sulfentrazone
dichlormid


B-506
H-1
dichlormid


B-507
H-2
dichlormid


B-508
glyphosate
dichlormid


B-509
glyphosate-isopropylammonium
dichlormid


B-510
glyphosate-trimesium (sulfosate)
dichlormid


B-511
glufosinate
dichlormid


B-512
glufosinate-ammonium
dichlormid


B-513
pendimethalin
dichlormid


B-514
trifluralin
dichlormid


B-515
acetochlor
dichlormid


B-516
cafenstrole
dichlormid


B-517
dimethenamid-P
dichlormid


B-518
fentrazamide
dichlormid


B-519
flufenacet
dichlormid


B-520
mefenacet
dichlormid


B-521
metazachlor
dichlormid


B-522
metolachlor-S
dichlormid


B-523
pyroxasulfone
dichlormid


B-524
isoxaben
dichlormid


B-525
dymron
dichlormid


B-526
indanofan
dichlormid


B-527
oxaziclomefone
dichlormid


B-528
triaziflam
dichlormid


B-529
atrazine + H-1
dichlormid


B-530
atrazine + glyphosate
dichlormid


B-531
atrazine + mesotrione
dichlormid


B-532
atrazine + nicosulfuron
dichlormid


B-533
atrazine + tembotrione
dichlormid


B-534
atrazine + topramezone
dichlormid


B-535
clomazone + glyphosate
dichlormid


B-536
diflufenican + clodinafop-propargyl
dichlormid


B-537
diflufenican + fenoxaprop-p-ethyl
dichlormid


B-538
diflufenican + flupyrsulfuron-methyl-sodium
dichlormid


B-539
diflufenican + glyphosate
dichlormid


B-540
diflufenican + mesosulfuron-methyl
dichlormid


B-541
diflufenican + pinoxaden
dichlormid


B-542
diflufenican + pyroxsulam
dichlormid


B-543
flumetsulam + glyphosate
dichlormid


B-544
flumioxazin + glyphosate
dichlormid


B-545
imazapic + glyphosate
dichlormid


B-546
imazethapyr + glyphosate
dichlormid


B-547
isoxaflutol + H-1
dichlormid


B-548
isoxaflutol + glyphosate
dichlormid


B-549
metazachlor + H-1
dichlormid


B-550
metazachlor + glyphosate
dichlormid


B-551
metazachlor + mesotrione
dichlormid


B-552
metazachlor + nicosulfuron
dichlormid


B-553
metazachlor + terbuthylazine
dichlormid


B-554
metazachlor + topramezone
dichlormid


B-555
metribuzin + glyphosate
dichlormid


B-556
pendimethalin + H-1
dichlormid


B-557
pendimethalin + clodinafop-propargyl
dichlormid


B-558
pendimethalin + fenoxaprop-P-ethyl
dichlormid


B-559
pendimethalin + flupyrsulfuron-methyl-sodium
dichlormid


B-560
pendimethalin + glyphosate
dichlormid


B-561
pendimethalin + mesosulfuron-methyl
dichlormid


B-562
pendimethalin + mesotrione
dichlormid


B-563
pendimethalin + nicosulfuron
dichlormid


B-564
pendimethalin + pinoxaden
dichlormid


B-565
pendimethalin + pyroxsulam
dichlormid


B-566
pendimethalin + tembotrione
dichlormid


B-567
pendimethalin + topramezone
dichlormid


B-568
pyroxasulfone + tembotrione
dichlormid


B-569
pyroxasulfone + topramezone
dichlormid


B-570
sulfentrazone + glyphosate
dichlormid


B-571
terbuthylazine + H-1
dichlormid


B-572
terbuthylazine + foramsulfuron
dichlormid


B-573
terbuthylazine + glyphosate
dichlormid


B-574
terbuthylazine + mesotrione
dichlormid


B-575
terbuthylazine + nicosulfuron
dichlormid


B-576
terbuthylazine + tembotrione
dichlormid


B-577
terbuthylazine + topramezone
dichlormid


B-578
trifluralin + glyphosate
dichlormid


B-579
clodinafop-propargyl
fenchlorazole


B-580
cycloxydim
fenchlorazole


B-581
cyhalofop-butyl
fenchlorazole


B-582
fenoxaprop-P-ethyl
fenchlorazole


B-583
pinoxaden
fenchlorazole


B-584
profoxydim
fenchlorazole


B-585
tepraloxydim
fenchlorazole


B-586
tralkoxydim
fenchlorazole


B-587
esprocarb
fenchlorazole


B-588
prosulfocarb
fenchlorazole


B-589
thiobencarb
fenchlorazole


B-590
triallate
fenchlorazole


B-591
bensulfuron-methyl
fenchlorazole


B-592
bispyribac-sodium
fenchlorazole


B-593
cyclosulfamuron
fenchlorazole


B-594
flumetsulam
fenchlorazole


B-595
flupyrsulfuron-methyl-sodium
fenchlorazole


B-596
foramsulfuron
fenchlorazole


B-597
imazamox
fenchlorazole


B-598
imazapic
fenchlorazole


B-599
imazapyr
fenchlorazole


B-600
imazaquin
fenchlorazole


B-601
imazethapyr
fenchlorazole


B-602
imazosulfuron
fenchlorazole


B-603
iodosulfuron-methyl-sodium
fenchlorazole


B-604
mesosulfuron
fenchlorazole


B-605
nicosulfuron
fenchlorazole


B-606
penoxsulam
fenchlorazole


B-607
propoxycarbazone-sodium
fenchlorazole


B-608
pyrazosulfuron-ethyl
fenchlorazole


B-609
pyroxsulam
fenchlorazole


B-610
rimsulfuron
fenchlorazole


B-611
sulfosulfuron
fenchlorazole


B-612
thiencarbazone-methyl
fenchlorazole


B-613
tritosulfuron
fenchlorazole


B-614
2,4-D and its salts and esters
fenchlorazole


B-615
aminopyralid and its salts and esters
fenchlorazole


B-616
clopyralid and its salts and esters
fenchlorazole


B-617
dicamba and its salts and esters
fenchlorazole


B-618
fluroxypyr-meptyl
fenchlorazole


B-619
quinclorac
fenchlorazole


B-620
quinmerac
fenchlorazole


B-621
H-9
fenchlorazole


B-622
diflufenzopyr
fenchlorazole


B-623
diflufenzopyr-sodium
fenchlorazole


B-624
clomazone
fenchlorazole


B-625
diflufenican
fenchlorazole


B-626
fluorochloridone
fenchlorazole


B-627
isoxaflutol
fenchlorazole


B-628
mesotrione
fenchlorazole


B-629
picolinafen
fenchlorazole


B-630
sulcotrione
fenchlorazole


B-631
tefuryltrione
fenchlorazole


B-632
tembotrione
fenchlorazole


B-633
topramezone
fenchlorazole


B-634
H-7
fenchlorazole


B-635
atrazine
fenchlorazole


B-636
diuron
fenchlorazole


B-637
fluometuron
fenchlorazole


B-638
hexazinone
fenchlorazole


B-639
isoproturon
fenchlorazole


B-640
metribuzin
fenchlorazole


B-641
propanil
fenchlorazole


B-642
terbuthylazine
fenchlorazole


B-643
paraquat dichloride
fenchlorazole


B-644
flumioxazin
fenchlorazole


B-645
oxyfluorfen
fenchlorazole


B-646
saflufenacil
fenchlorazole


B-647
sulfentrazone
fenchlorazole


B-648
H-1
fenchlorazole


B-649
H-2
fenchlorazole


B-650
glyphosate
fenchlorazole


B-651
glyphosate-isopropylammonium
fenchlorazole


B-652
glyphosate-trimesium (sulfosate)
fenchlorazole


B-653
glufosinate
fenchlorazole


B-654
glufosinate-ammonium
fenchlorazole


B-655
pendimethalin
fenchlorazole


B-656
trifluralin
fenchlorazole


B-657
acetochlor
fenchlorazole


B-658
cafenstrole
fenchlorazole


B-659
dimethenamid-P
fenchlorazole


B-660
fentrazamide
fenchlorazole


B-661
flufenacet
fenchlorazole


B-662
mefenacet
fenchlorazole


B-663
metazachlor
fenchlorazole


B-664
metolachlor-S
fenchlorazole


B-665
pyroxasulfone
fenchlorazole


B-666
isoxaben
fenchlorazole


B-667
dymron
fenchlorazole


B-668
indanofan
fenchlorazole


B-669
oxaziclomefone
fenchlorazole


B-670
triaziflam
fenchlorazole


B-671
atrazine + H-1
fenchlorazole


B-672
atrazine + glyphosate
fenchlorazole


B-673
atrazine + mesotrione
fenchlorazole


B-674
atrazine + nicosulfuron
fenchlorazole


B-675
atrazine + tembotrione
fenchlorazole


B-676
atrazine + topramezone
fenchlorazole


B-677
clomazone + glyphosate
fenchlorazole


B-678
diflufenican + clodinafop-propargyl
fenchlorazole


B-679
diflufenican + fenoxaprop-P-ethyl
fenchlorazole


B-680
diflufenican + flupyrsulfuron-methyl-sodium
fenchlorazole


B-681
diflufenican + glyphosate
fenchlorazole


B-682
diflufenican + mesosulfuron-methyl
fenchlorazole


B-683
diflufenican + pinoxaden
fenchlorazole


B-684
diflufenican + pyroxsulam
fenchlorazole


B-685
flumetsulam + glyphosate
fenchlorazole


B-686
flumioxazin + glyphosate
fenchlorazole


B-687
imazapic + glyphosate
fenchlorazole


B-688
imazethapyr + glyphosate
fenchlorazole


B-689
isoxaflutol + H-1
fenchlorazole


B-690
isoxaflutol + glyphosate
fenchlorazole


B-691
metazachlor + H-1
fenchlorazole


B-692
metazachlor + glyphosate
fenchlorazole


B-693
metazachlor + mesotrione
fenchlorazole


B-694
metazachlor + nicosulfuron
fenchlorazole


B-695
metazachlor + terbuthylazine
fenchlorazole


B-696
metazachlor + topramezone
fenchlorazole


B-697
metribuzin + glyphosate
fenchlorazole


B-698
pendimethalin + H-1
fenchlorazole


B-699
pendimethalin + clodinafop-propargyl
fenchlorazole


B-700
pendimethalin + fenoxaprop-P-ethyl
fenchlorazole


B-701
pendimethalin + flupyrsulfuron-methyl-sodium
fenchlorazole


B-702
pendimethalin + glyphosate
fenchlorazole


B-703
pendimethalin + mesosulfuron-methyl
fenchlorazole


B-704
pendimethalin + mesotrione
fenchlorazole


B-705
pendimethalin + nicosulfuron
fenchlorazole


B-706
pendimethalin + pinoxaden
fenchlorazole


B-707
pendimethalin + pyroxsulam
fenchlorazole


B-708
pendimethalin + tembotrione
fenchlorazole


B-709
pendimethalin + topramezone
fenchlorazole


B-710
pyroxasulfone + tembotrione
fenchlorazole


B-711
pyroxasulfone + topramezone
fenchlorazole


B-712
sulfentrazone + glyphosate
fenchlorazole


B-713
terbuthylazine + H-1
fenchlorazole


B-714
terbuthylazine + foramsulfuron
fenchlorazole


B-715
terbuthylazine + glyphosate
fenchlorazole


B-716
terbuthylazine + mesotrione
fenchlorazole


B-717
terbuthylazine + nicosulfuron
fenchlorazole


B-718
terbuthylazine + tembotrione
fenchlorazole


B-719
terbuthylazine + topramezone
fenchlorazole


B-720
trifluralin + glyphosate
fenchlorazole


B-721
clodinafop-propargyl
isoxadifen


B-722
cycloxydim
isoxadifen


B-723
cyhalofop-butyl
isoxadifen


B-724
fenoxaprop-P-ethyl
isoxadifen


B-725
pinoxaden
isoxadifen


B-726
profoxydim
isoxadifen


B-727
tepraloxydim
isoxadifen


B-728
tralkoxydim
isoxadifen


B-729
esprocarb
isoxadifen


B-730
prosulfocarb
isoxadifen


B-731
thiobencarb
isoxadifen


B-732
triallate
isoxadifen


B-733
bensulfuron-methyl
isoxadifen


B-734
bispyribac-sodium
isoxadifen


B-735
cyclosulfamuron
isoxadifen


B-736
flumetsulam
isoxadifen


B-737
flupyrsulfuron-methyl-sodium
isoxadifen


B-738
foramsulfuron
isoxadifen


B-739
imazamox
isoxadifen


B-740
imazapic
isoxadifen


B-741
imazapyr
isoxadifen


B-742
imazaquin
isoxadifen


B-743
imazethapyr
isoxadifen


B-744
imazosulfuron
isoxadifen


B-745
iodosulfuron-methyl-sodium
isoxadifen


B-746
mesosulfuron
isoxadifen


B-747
nicosulfuron
isoxadifen


B-748
penoxsulam
isoxadifen


B-749
propoxycarbazone-sodium
isoxadifen


B-750
pyrazosulfuron-ethyl
isoxadifen


B-751
pyroxsulam
isoxadifen


B-752
rimsulfuron
isoxadifen


B-753
sulfosulfuron
isoxadifen


B-754
thiencarbazone-methyl
isoxadifen


B-755
tritosulfuron
isoxadifen


B-756
2,4-D and its salts and esters
isoxadifen


B-757
aminopyralid and its salts and esters
isoxadifen


B-758
clopyralid and its salts and esters
isoxadifen


B-759
dicamba and its salts and esters
isoxadifen


B-760
fluroxypyr-meptyl
isoxadifen


B-761
quinclorac
isoxadifen


B-762
quinmerac
isoxadifen


B-763
H-9
isoxadifen


B-764
diflufenzopyr
isoxadifen


B-765
diflufenzopyr-sodium
isoxadifen


B-766
clomazone
isoxadifen


B-767
diflufenican
isoxadifen


B-768
fluorochloridone
isoxadifen


B-769
isoxaflutol
isoxadifen


B-770
mesotrione
isoxadifen


B-771
picolinafen
isoxadifen


B-772
sulcotrione
isoxadifen


B-773
tefuryltrione
isoxadifen


B-774
tembotrione
isoxadifen


B-775
topramezone
isoxadifen


B-776
H-7
isoxadifen


B-777
atrazine
isoxadifen


B-778
diuron
isoxadifen


B-779
fluometuron
isoxadifen


B-780
hexazinone
isoxadifen


B-781
isoproturon
isoxadifen


B-782
metribuzin
isoxadifen


B-783
propanil
isoxadifen


B-784
terbuthylazine
isoxadifen


B-785
paraquat dichloride
isoxadifen


B-786
flumioxazin
isoxadifen


B-787
oxyfluorfen
isoxadifen


B-788
saflufenacil
isoxadifen


B-789
sulfentrazone
isoxadifen


B-790
H-1
isoxadifen


B-791
H-2
isoxadifen


B-792
glyphosate
isoxadifen


B-793
glyphosate-isopropylammonium
isoxadifen


B-794
glyphosate-trimesium (sulfosate)
isoxadifen


B-795
glufosinate
isoxadifen


B-796
glufosinate-ammonium
isoxadifen


B-797
pendimethalin
isoxadifen


B-798
trifluralin
isoxadifen


B-799
acetochlor
isoxadifen


B-800
cafenstrole
isoxadifen


B-801
dimethenamid-P
isoxadifen


B-802
fentrazamide
isoxadifen


B-803
flufenacet
isoxadifen


B-804
mefenacet
isoxadifen


B-805
metazachlor
isoxadifen


B-806
metolachlor-S
isoxadifen


B-807
pyroxasulfone
isoxadifen


B-808
isoxaben
isoxadifen


B-809
dymron
isoxadifen


B-810
indanofan
isoxadifen


B-811
oxaziclomefone
isoxadifen


B-812
triaziflam
isoxadifen


B-813
atrazine + H-1
isoxadifen


B-814
atrazine + glyphosate
isoxadifen


B-815
atrazine + mesotrione
isoxadifen


B-816
atrazine + nicosulfuron
isoxadifen


B-817
atrazine + tembotrione
isoxadifen


B-818
atrazine + topramezone
isoxadifen


B-819
clomazone + glyphosate
isoxadifen


B-820
diflufenican + clodinafop-propargyl
isoxadifen


B-821
diflufenican + fenoxaprop-P-ethyl
isoxadifen


B-822
diflufenican + flupyrsulfuron-methyl-sodium
isoxadifen


B-823
diflufenican + glyphosate
isoxadifen


B-824
diflufenican + mesosulfuron-methyl
isoxadifen


B-825
diflufenican + pinoxaden
isoxadifen


B-826
diflufenican + pyroxsulam
isoxadifen


B-827
flumetsulam + glyphosate
isoxadifen


B-828
flumioxazin + glyphosate
isoxadifen


B-829
imazapic + glyphosate
isoxadifen


B-830
imazethapyr + glyphosate
isoxadifen


B-831
isoxaflutol + H-1
isoxadifen


B-832
isoxaflutol + glyphosate
isoxadifen


B-833
metazachlor + H-1
isoxadifen


B-834
metazachlor + glyphosate
isoxadifen


B-835
metazachlor + mesotrione
isoxadifen


B-836
metazachlor + nicosulfuron
isoxadifen


B-837
metazachlor + terbuthylazine
isoxadifen


B-838
metazachlor + topramezone
isoxadifen


B-839
metribuzin + glyphosate
isoxadifen


B-840
pendimethalin + H-1
isoxadifen


B-841
pendimethalin + clodinafop-propargyl
isoxadifen


B-842
pendimethalin + fenoxaprop-P-ethyl
isoxadifen


B-843
pendimethalin + flupyrsulfuron-methyl-sodium
isoxadifen


B-844
pendimethalin + glyphosate
isoxadifen


B-845
pendimethalin + mesosulfuron-methyl
isoxadifen


B-846
pendimethalin + mesotrione
isoxadifen


B-847
pendimethalin + nicosulfuron
isoxadifen


B-848
pendimethalin + pinoxaden
isoxadifen


B-849
pendimethalin + pyroxsulam
isoxadifen


B-850
pendimethalin + tembotrione
isoxadifen


B-851
pendimethalin + topramezone
isoxadifen


B-852
pyroxasulfone + tembotrione
isoxadifen


B-853
pyroxasulfone + topramezone
isoxadifen


B-854
sulfentrazone + glyphosate
isoxadifen


B-855
terbuthylazine + H-1
isoxadifen


B-856
terbuthylazine + foramsulfuron
isoxadifen


B-857
terbuthylazine + glyphosate
isoxadifen


B-858
terbuthylazine + mesotrione
isoxadifen


B-859
terbuthylazine + nicosulfuron
isoxadifen


B-860
terbuthylazine + tembotrione
isoxadifen


B-861
terbuthylazine + topramezone
isoxadifen


B-862
trifluralin + glyphosate
isoxadifen


B-863
clodinafop-propargyl
mefenpyr


B-864
cycloxydim
mefenpyr


B-865
cyhalofop-butyl
mefenpyr


B-866
fenoxaprop-P-ethyl
mefenpyr


B-867
pinoxaden
mefenpyr


B-868
profoxydim
mefenpyr


B-869
tepraloxydim
mefenpyr


B-870
tralkoxydim
mefenpyr


B-871
esprocarb
mefenpyr


B-872
prosulfocarb
mefenpyr


B-873
thiobencarb
mefenpyr


B-874
triallate
mefenpyr


B-875
bensulfuron-methyl
mefenpyr


B-876
bispyribac-sodium
mefenpyr


B-877
cyclosulfamuron
mefenpyr


B-878
flumetsulam
mefenpyr


B-879
flupyrsulfuron-methyl-sodium
mefenpyr


B-880
foramsulfuron
mefenpyr


B-881
imazamox
mefenpyr


B-882
imazapic
mefenpyr


B-883
imazapyr
mefenpyr


B-884
imazaquin
mefenpyr


B-885
imazethapyr
mefenpyr


B-886
imazosulfuron
mefenpyr


B-887
iodosulfuron-methyl-sodium
mefenpyr


B-888
mesosulfuron
mefenpyr


B-889
nicosulfuron
mefenpyr


B-890
penoxsulam
mefenpyr


B-891
propoxycarbazone-sodium
mefenpyr


B-892
pyrazosulfuron-ethyl
mefenpyr


B-893
pyroxsulam
mefenpyr


B-894
rimsulfuron
mefenpyr


B-895
sulfosulfuron
mefenpyr


B-896
thiencarbazone-methyl
mefenpyr


B-897
tritosulfuron
mefenpyr


B-898
2,4-D and its salts and esters
mefenpyr


B-899
aminopyralid and its salts and esters
mefenpyr


B-900
clopyralid and its salts and esters
mefenpyr


B-901
dicamba and its salts and esters
mefenpyr


B-902
fluroxypyr-meptyl
mefenpyr


B-903
quinclorac
mefenpyr


B-904
quinmerac
mefenpyr


B-905
H-9
mefenpyr


B-906
diflufenzopyr
mefenpyr


B-907
diflufenzopyr-sodium
mefenpyr


B-908
clomazone
mefenpyr


B-909
diflufenican
mefenpyr


B-910
fluorochloridone
mefenpyr


B-911
isoxaflutol
mefenpyr


B-912
mesotrione
mefenpyr


B-913
picolinafen
mefenpyr


B-914
sulcotrione
mefenpyr


B-915
tefuryltrione
mefenpyr


B-916
tembotrione
mefenpyr


B-917
topramezone
mefenpyr


B-918
H-7
mefenpyr


B-919
atrazine
mefenpyr


B-920
diuron
mefenpyr


B-921
fluometuron
mefenpyr


B-922
hexazinone
mefenpyr


B-923
isoproturon
mefenpyr


B-924
metribuzin
mefenpyr


B-925
propanil
mefenpyr


B-926
terbuthylazine
mefenpyr


B-927
paraquat dichloride
mefenpyr


B-928
flumioxazin
mefenpyr


B-929
oxyfluorfen
mefenpyr


B-930
saflufenacil
mefenpyr


B-931
sulfentrazone
mefenpyr


B-932
H-1
mefenpyr


B-933
H-2
mefenpyr


B-934
glyphosate
mefenpyr


B-935
glyphosate-isopropylammonium
mefenpyr


B-936
glyphosate-trimesium (sulfosate)
mefenpyr


B-937
glufosinate
mefenpyr


B-938
glufosinate-ammonium
mefenpyr


B-939
pendimethalin
mefenpyr


B-940
trifluralin
mefenpyr


B-941
acetochlor
mefenpyr


B-942
cafenstrole
mefenpyr


B-943
dimethenamid-P
mefenpyr


B-944
fentrazamide
mefenpyr


B-945
flufenacet
mefenpyr


B-946
mefenacet
mefenpyr


B-947
metazachlor
mefenpyr


B-948
metolachlor-S
mefenpyr


B-949
pyroxasulfone
mefenpyr


B-950
isoxaben
mefenpyr


B-951
dymron
mefenpyr


B-952
indanofan
mefenpyr


B-953
oxaziclomefone
mefenpyr


B-954
triaziflam
mefenpyr


B-955
atrazine + H-1
mefenpyr


B-956
atrazine + glyphosate
mefenpyr


B-957
atrazine + mesotrione
mefenpyr


B-958
atrazine + nicosulfuron
mefenpyr


B-959
atrazine + tembotrione
mefenpyr


B-960
atrazine + topramezone
mefenpyr


B-961
clomazone + glyphosate
mefenpyr


B-962
diflufenican + clodinafop-propargyl
mefenpyr


B-963
diflufenican + fenoxaprop-P-ethyl
mefenpyr


B-964
diflufenican + flupyrsulfuron-methyl-sodium
mefenpyr


B-965
diflufenican + glyphosate
mefenpyr


B-966
diflufenican + mesosulfuron-methyl
mefenpyr


B-967
diflufenican + pinoxaden
mefenpyr


B-968
diflufenican + pyroxsulam
mefenpyr


B-969
flumetsulam + glyphosate
mefenpyr


B-970
flumioxazin + glyphosate
mefenpyr


B-971
imazapic + glyphosate
mefenpyr


B-972
imazethapyr + glyphosate
mefenpyr


B-973
isoxaflutol + H-1
mefenpyr


B-974
isoxaflutol + glyphosate
mefenpyr


B-975
metazachlor + H-1
mefenpyr


B-976
metazachlor + glyphosate
mefenpyr


B-977
metazachlor + mesotrione
mefenpyr


B-978
metazachlor + nicosulfuron
mefenpyr


B-979
metazachlor + terbuthylazine
mefenpyr


B-980
metazachlor + topramezone
mefenpyr


B-981
metribuzin + glyphosate
mefenpyr


B-982
pendimethalin + H-1
mefenpyr


B-983
pendimethalin + clodinafop-propargyl
mefenpyr


B-984
pendimethalin + fenoxaprop-P-ethyl
mefenpyr


B-985
pendimethalin + flupyrsulfuron-methyl-sodium
mefenpyr


B-986
pendimethalin + glyphosate
mefenpyr


B-987
pendimethalin + mesosulfuron-methyl
mefenpyr


B-988
pendimethalin + mesotrione
mefenpyr


B-989
pendimethalin + nicosulfuron
mefenpyr


B-990
pendimethalin + pinoxaden
mefenpyr


B-991
pendimethalin + pyroxsulam
mefenpyr


B-992
pendimethalin + tembotrione
mefenpyr


B-993
pendimethalin + topramezone
mefenpyr


B-994
pyroxasulfone + tembotrione
mefenpyr


B-995
pyroxasulfone + topramezone
mefenpyr


B-996
sulfentrazone + glyphosate
mefenpyr


B-997
terbuthylazine + H-1
mefenpyr


B-998
terbuthylazine + foramsulfuron
mefenpyr


B-999
terbuthylazine + glyphosate
mefenpyr


B-1000
terbuthylazine + mesotrione
mefenpyr


B-1001
terbuthylazine + nicosulfuron
mefenpyr


B-1002
terbuthylazine + tembotrione
mefenpyr


B-1003
terbuthylazine + topramezone
mefenpyr


B-1004
trifluralin + glyphosate
mefenpyr


B-1005
clodinafop-propargyl
H-12


B-1006
cycloxydim
H-12


B-1007
cyhalofop-butyl
H-12


B-1008
fenoxaprop-P-ethyl
H-12


B-1009
pinoxaden
H-12


B-1010
profoxydim
H-12


B-1011
tepraloxydim
H-12


B-1012
tralkoxydim
H-12


B-1013
esprocarb
H-12


B-1014
prosulfocarb
H-12


B-1015
thiobencarb
H-12


B-1016
triallate
H-12


B-1017
bensulfuron-methyl
H-12


B-1018
bispyribac-sodium
H-12


B-1019
cyclosulfamuron
H-12


B-1020
flumetsulam
H-12


B-1021
flupyrsulfuron-methyl-sodium
H-12


B-1022
foramsulfuron
H-12


B-1023
imazamox
H-12


B-1024
imazapic
H-12


B-1025
imazapyr
H-12


B-1026
imazaquin
H-12


B-1027
imazethapyr
H-12


B-1028
imazosulfuron
H-12


B-1029
iodosulfuron-methyl-sodium
H-12


B-1030
mesosulfuron
H-12


B-1031
nicosulfuron
H-12


B-1032
penoxsulam
H-12


B-1033
propoxycarbazone-sodium
H-12


B-1034
pyrazosulfuron-ethyl
H-12


B-1035
pyroxsulam
H-12


B-1036
rimsulfuron
H-12


B-1037
sulfosulfuron
H-12


B-1038
thiencarbazone-methyl
H-12


B-1039
tritosulfuron
H-12


B-1040
2,4-D and its salts and esters
H-12


B-1041
aminopyralid and its salts and esters
H-12


B-1042
clopyralid and its salts and esters
H-12


B-1043
dicamba and its salts and esters
H-12


B-1044
fluroxypyr-meptyl
H-12


B-1045
quinclorac
H-12


B-1046
quinmerac
H-12


B-1047
B-9
H-12


B-1048
diflufenzopyr
H-12


B-1049
diflufenzopyr-sodium
H-12


B-1050
clomazone
H-12


B-1051
diflufenican
H-12


B-1052
fluorochloridone
H-12


B-1053
isoxaflutol
H-12


B-1054
mesotrione
H-12


B-1055
picolinafen
H-12


B-1056
sulcotrione
H-12


B-1057
tefuryltrione
H-12


B-1058
tembotrione
H-12


B-1059
topramezone
H-12


B-1060
H-7
H-12


B-1061
atrazine
H-12


B-1062
diuron
H-12


B-1063
fluometuron
H-12


B-1064
hexazinone
H-12


B-1065
isoproturon
H-12


B-1066
metribuzin
H-12


B-1067
propanil
H-12


B-1068
terbuthylazine
H-12


B-1069
paraquat dichloride
H-12


B-1070
flumioxazin
H-12


B-1071
oxyfluorfen
H-12


B-1072
saflufenacil
H-12


B-1073
sulfentrazone
H-12


B-1074
H-1
H-12


B-1075
H-2
H-12


B-1076
glyphosate
H-12


B-1077
glyphosate-isopropylammonium
H-12


B-1078
glyphosate-trimesium (sulfosate)
H-12


B-1079
glufosinate
H-12


B-1080
glufosinate-ammonium
H-12


B-1081
pendimethalin
H-12


B-1082
trifluralin
H-12


B-1083
acetochlor
H-12


B-1084
cafenstrole
H-12


B-1085
dimethenamid-P
H-12


B-1086
fentrazamide
H-12


B-1087
flufenacet
H-12


B-1088
mefenacet
H-12


B-1089
metazachlor
H-12


B-1090
metolachlor-S
H-12


B-1091
pyroxasulfone
H-12


B-1092
isoxaben
H-12


B-1093
dymron
H-12


B-1094
indanofan
H-12


B-1095
oxaziclomefone
H-12


B-1096
triaziflam
H-12


B-1097
atrazine + H-1
H-12


B-1098
atrazine + glyphosate
H-12


B-1099
atrazine + mesotrione
H-12


B-1100
atrazine + nicosulfuron
H-12


B-1101
atrazine + tembotrione
H-12


B-1102
atrazine + topramezone
H-12


B-1103
clomazone + glyphosate
H-12


B-1104
diflufenican + clodinafop-propargyl
H-12


B-1105
diflufenican + fenoxaprop-P-ethyl
H-12


B-1106
diflufenican + flupyrsulfuron-methyl-sodium
H-12


B-1107
diflufenican + glyphosate
H-12


B-1108
diflufenican + mesosulfuron-methyl
H-12


B-1109
diflufenican + pinoxaden
H-12


B-1110
diflufenican + pyroxsulam
H-12


B-1111
flumetsulam + glyphosate
H-12


B-1112
flumioxazin + glyphosate
H-12


B-1113
imazapic + glyphosate
H-12


B-1114
imazethapyr + glyphosate
H-12


B-1115
isoxaflutol + H-1
H-12


B-1116
isoxaflutol + glyphosate
H-12


B-1117
metazachlor + H-1
H-12


B-1118
metazachlor + glyphosate
H-12


B-1119
metazachlor + mesotrione
H-12


B-1120
metazachlor + nicosulfuron
H-12


B-1121
metazachlor + terbuthylazine
H-12


B-1122
metazachlor + topramezone
H-12


B-1123
metribuzin + glyphosate
H-12


B-1124
pendimethalin + H-1
H-12


B-1125
pendimethalin + clodinafop-propargyl
H-12


B-1126
pendimethalin + fenoxaprop-P-ethyl
H-12


B-1127
pendimethalin + flupyrsulfuron-methyl-sodium
H-12


B-1128
pendimethalin + glyphosate
H-12


B-1129
pendimethalin + mesosulfuron-methyl
H-12


B-1130
pendimethalin + mesotrione
H-12


B-1131
pendimethalin + nicosulfuron
H-12


B-1132
pendimethalin + pinoxaden
H-12


B-1133
pendimethalin + pyroxsulam
H-12


B-1134
pendimethalin + tembotrione
H-12


B-1135
pendimethalin + topramezone
H-12


B-1136
pyroxasulfone + tembotrione
H-12


B-1137
pyroxasulfone + topramezone
H-12


B-1138
sulfentrazone + glyphosate
H-12


B-1139
terbuthylazine + H-1
H-12


B-1140
terbuthylazine + foramsulfuron
H-12


B-1141
terbuthylazine + glyphosate
H-12


B-1142
terbuthylazine + mesotrione
H-12


B-1143
terbuthylazine + nicosulfuron
H-12


B-1144
terbuthylazine + tembotrione
H-12


B-1145
terbuthylazine + topramezone
H-12


B-1146
trifluralin + glyphosate
H-12


B-1147
2-1
—


B-1148
2-2
—


B-1149
2-3
—


B-1150
2-4
—


B-1151
2-5
—


B-1152
2-6
—


B-1153
2-7
—


B-1154
2-8
—


B-1155
2-9
—


B-1156
2-1
benoxacor


B-1157
2-2
benoxacor


B-1158
2-3
benoxacor


B-1159
2-4
benoxacor


B-1160
2-5
benoxacor


B-1161
2-6
benoxacor


B-1162
2-7
benoxacor


B-1163
2-8
benoxacor


B-1164
2-9
benoxacor


B-1165
2-1
cloquintocet


B-1166
2-2
cloquintocet


B-1167
2-3
cloquintocet


B-1168
2-4
cloquintocet


B-1169
2-5
cloquintocet


B-1170
2-6
cloquintocet


B-1171
2-7
cloquintocet


B-1172
2-8
cloquintocet


B-1173
2-9
cloquintocet


B-1174
2-1
cyprosulfamide


B-1175
2-2
cyprosulfamide


B-1176
2-3
cyprosulfamide


B-1177
2-4
cyprosulfamide


B-1178
2-5
cyprosulfamide


B-1179
2-6
cyprosulfamide


B-1180
2-7
cyprosulfamide


B-1181
2-8
cyprosulfamide


B-1182
2-9
cyprosulfamide


B-1183
2-1
dichlormid


B-1184
2-2
dichlormid


B-1185
2-3
dichlormid


B-1186
2-4
dichlormid


B-1187
2-5
dichlormid


B-1188
2-6
dichlormid


B-1189
2-7
dichlormid


B-1190
2-8
dichlormid


B-1191
2-9
dichlormid


B-1192
2-1
fenchlorazole


B-1193
2-2
fenchlorazole


B-1194
2-3
fenchlorazole


B-1195
2-4
fenchlorazole


B-1196
2-5
fenchlorazole


B-1197
2-6
fenchlorazole


B-1198
2-7
fenchlorazole


B-1199
2-8
fenchlorazole


B-1200
2-9
fenchlorazole


B-1201
2-1
isoxadifen


B-1202
2-2
isoxadifen


B-1203
2-3
isoxadifen


B-1204
2-4
isoxadifen


B-1205
2-5
isoxadifen


B-1206
2-6
isoxadifen


B-1207
2-7
isoxadifen


B-1208
2-8
isoxadifen


B-1209
2-9
isoxadifen


B-1210
2-1
mefenpyr


B-1211
2-2
mefenpyr


B-1212
2-3
mefenpyr


B-1213
2-4
mefenpyr


B-1214
2-5
mefenpyr


B-1215
2-6
mefenpyr


B-1216
2-7
mefenpyr


B-1217
2-8
mefenpyr


B-1218
2-9
mefenpyr


B-1219
2-1
H-11


B-1220
2-2
H-11


B-1221
2-3
H-11


B-1222
2-4
H-11


B-1223
2-5
H-11


B-1224
2-6
H-11


B-1225
2-7
H-11


B-1226
2-8
H-11


B-1227
2-9
H-11


B-1228
2-1
H-12


B-1229
2-2
H-12


B-1230
2-3
H-12


B-1231
2-4
H-12


B-1232
2-5
H-12


B-1233
2-6
H-12


B-1234
2-7
H-12


B-1235
2-8
H-12


B-1236
2-9
H-12









The compounds of formula I and the compositions according to the invention may also have a plant-strengthening action. Accordingly, they are suitable for mobilizing the defense system of the plants against attack by unwanted microorganisms, such as harmful fungi, but also viruses and bacteria. Plant-strengthening (resistance-inducing) substances are to be understood as meaning, in the present context, those substances which are capable of stimulating the defense system of treated plants in such a way that, when subsequently inoculated by unwanted microorganisms, the treated plants display a substantial degree of resistance to these microorganisms.


The compounds of formula I can be employed for protecting plants against attack by unwanted microorganisms within a certain period of time after the treatment. The period of time within which their protection is effected generally extends from 1 to 28 days, preferably from 1 to 14 days, after the treatment of the plants with the compounds of formula I, or, after treatment of the seed, for up to 9 months after sowing.


The compounds of formula I and the compositions according to the invention are also suitable for increasing the harvest yield.


Moreover, they have reduced toxicity and are tolerated well by the plants.

Claims
  • 1-28. (canceled)
  • 29: An 1,2,5-oxadiazole compound of formula I,
  • 30: The compound as claimed in claim 29, an N-oxide or an agriculturally suitable salt thereof, where R1 is selected from the group consisting of cyano, halogen, nitro, C1-C6-alkyl, C3-C6-cycloalkyl, C2-C6-alkenyl, C2-C6-alkynyl, C1-C6-haloalkyl, C1-C6-alkoxy, C1-C4-alkoxy-C1-C4-alkyl, C1-C4-haloalkoxy-C1-C4-alkyl, C1-C4-alkoxy-C1-C4-alkoxy-Z1, C1-C4-alkylthio-C1-C4-alkyl, C1-C4-alkylthio-C1-C4-alkylthio-Z1, C2-C6-alkenyloxy, C2-C6-alkynyloxy, C1-C6-haloalkoxy, C1-C4-haloalkoxy-C1-C4-alkoxy and R1b—S(O)k, where Z1 is as defined in claim 1, where k is 0, 1 or 2 and where R1b is selected from C1-C4-alkyl and C1-C4-haloalkyl.
  • 31: The compound as claimed in claim 29, an N-oxide or an agriculturally suitable salt thereof, where R1 is selected from the group consisting of halogen, cyano, nitro, C1-C4-alkyl, C3-C6-cycloalkyl, C1-C4-haloalkyl, C1-C4-alkoxy-C1-C4-alkyl, C1-C4-haloalkoxy-C1-C4-alkyl, C1-C4-alkoxy-C1-C4-alkoxy-C1-C4-alkyl, C1-C4-alkylthio-C1-C4-alkyl, C1-C4-alkylthio-C1-C4-alkylthio-C1-C4-alkyl, C1-C4-alkoxy, C1-C4-haloalkoxy, C3-C4-alkenyloxy, C3-C4-alkynyloxy, C1-C4-alkoxy-C1-C4-alkoxy, C1-C4-haloalkoxy-C1-C4-alkoxy, C1-C4-alkyl-S(O)k and C1-C4-haloalkyl-S(O)k, where k is 0 or 2.
  • 32: The compound as claimed in claim 29, an N-oxide or an agriculturally suitable salt thereof, where R1 is selected from the group consisting of halogen, nitro, C1-C4-alkyl, C3-C6-cycloalkyl, C1-C4-haloalkyl, C1-C4-alkoxy-C1-C4-alkyl, C1-C4-alkoxy-C1-C4-alkoxy-C1-C4-alkyl, C1-C4-alkoxy, C1-C4-haloalkoxy, C1-C4-alkylthio, C1-C4-haloalkylthio and C1-C4-alkylsulfonyl.
  • 33: The compound as claimed in claim 29, an N-oxide or an agriculturally suitable salt thereof, where X is N.
  • 34: The compound as claimed in claim 29, an N-oxide or an agriculturally suitable salt thereof, where X is CR2 and R2 is not hydrogen.
  • 35: The compound as claimed in claim 29, an N-oxide or an agriculturally suitable salt thereof, where X is CR2 and R2 is hydrogen.
  • 36: The compound as claimed in claim 29, an N-oxide or an agriculturally suitable salt thereof, where R2 is 5- or 6-membered heterocyclyl, where heterocyclyl is a saturated, partially unsaturated or aromatic heterocyclic radical, which contains as a ring member 1 heteroatom selected from the group consisting of O, N and S and 0, 1, 2 or 3 further nitrogen atoms, where heterocyclyl is unsubstituted or carries 1, 2 or 3 radicals R21 which are identical or different.
  • 37: The compound as claimed in claim 29, an N-oxide or an agriculturally suitable salt thereof, where R2 is 5- or 6-membered heterocyclyl selected from the group consisting of isoxazolinyl, 1,2-dihydrotetrazolonyl, 1,4-dihydrotetrazolonyl, tetrahydrofuryl, dioxolanyl, piperidinyl, morpholinyl, piperazinyl, isoxazolyl, pyrazolyl, thiazolyl, oxazolyl, furyl, pyridinyl, pyrimidinyl and pyrazinyl, where heterocyclyl is unsubstituted or carries 1, 2 or 3 radicals R21 which are identical or different and selected from the group consisting of C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy, C1-C4-alkoxy-C1-C4-alkyl and C1-C4-alkylthio-C1-C4-alkyl.
  • 38: The compound as claimed in claim 29, an N-oxide or an agriculturally suitable salt thereof, where R2 is selected from the group consisting of hydrogen, halogen, C1-C6-alkyl, C3-C6-cycloalkyl-C1-C4-alkoxy, C1-C4-alkoxy-C1-C4-alkyl, C1-C4-haloalkoxy-C1-C4-alkyl, C2-C6-alkenyl, C2-C6-alkynyl, C1-C4-alkoxy, C1-C4-haloalkoxy, C3-C6-alkenyloxy, C3-C6-alkynyloxy, C3-C6-haloalkenyloxy, C3-C6-haloalkynyloxy, C1-C4-alkoxy-C1-C4-alkoxy, C1-C4-alkoxycarbonyl, C1-C4-alkyl-S(O)k and C1-C4-haloalkyl-S(O)k, where k is 0, 1 or 2, N(C1-C4-alkyl)SO2(C1-C4-alkyl), isoxazolyl and isoxazolinyl, where the last two mentioned radicals may be unsubstituted or carry 1 or 2 radicals selected from halogen and C1-C4-alkyl.
  • 39: The compound as claimed in claim 29, an N-oxide or an agriculturally suitable salt thereof, where R2 is
  • 40: The compound as claimed in claim 29, an N-oxide or an agriculturally suitable salt thereof, where R3 is selected from the group consisting of hydrogen, halogen, cyano, nitro, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy, C1-C4-haloalkoxy, C2-C4-alkenyl, C2-C4-alkynyl, C3-C4-alkenyloxy, C3-C4-alkynyloxy or R2b—S(O)k, where k is 0, 1 or 2 and where R2b is selected from C1-C4-alkyl and C1-C4-haloalkyl.
  • 41: The compound as claimed in claim 29, an N-oxide or an agriculturally suitable salt thereof, where R3 is selected from the group consisting of hydrogen, halogen, cyano, nitro, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy, C1-C4-haloalkoxy, C1-C4-alkylthio, C1-C4-haloalkylthio, C1-C4-alkyl-S(O)2 and C1-C4-haloalkyl-S(O)2.
  • 42: The compound as claimed in claim 29, an N-oxide or an agriculturally suitable salt thereof, where R4 is selected from the group consisting of hydrogen, CHF2, CF3, CN, NO2, CH3 and halogen.
  • 43: The compound as claimed in claim 29, an N-oxide or an agriculturally suitable salt thereof, where R5 is selected from the group consisting of CHF2, CF3 and halogen.
  • 44: The compound as claimed in claim 29, an N-oxide or an agriculturally suitable salt thereof, where R6 is selected from the group consisting of cyano, C1-C6-alkyl, C1-C6-cyano-alkyl, C1-C6-alkoxy, C2-C6-alkenyl, C2-C6-haloalkenyl, C2-C6-alkynyl, C2-C6-haloalkynyl, C1-C4-alkoxy-C1-C4-alkyl, C1-C4-haloalkoxy-C1-C4-alkyl, RbRbN—S(O)n—Z, RbO—S(O)n—Z, Rb—S(O)n—Z, Rd—C(═O)O—C1-C3-alkyl, Rd—O—C(═O)O—C1-C3-alkyl, RdO—C(═O)—C1-C3-alkyl, ReRfN—C(═O)—C1-C3-alkyl, phenyl-Z and where phenyl is unsubstituted or substituted by 1, 2, 3 or 4 groups R′, which are identical or different.
  • 45: The compound as claimed in claim 29, an N-oxide or an agriculturally suitable salt thereof, where R6 is selected from the group consisting of C1-C6-alkyl, C2-C6-alkenyl, C2-C6-alkynyl, C1-C4-alkoxy-C1-C4-alkyl, RdO—C(═O)—C1-C3-alkyl, phenyl-Z and where phenyl is unsubstituted or substituted by 1, 2, 3 or 4 groups R′, which are identical or different.
  • 46: The compound as claimed in claim 29, an N-oxide or an agriculturally suitable salt thereof, where R7 is selected from the group consisting of C1-C4-alkyl, C3-C7-cycloalkyl, C1-C4-haloalkyl, C2-C6-alkenyl, C2-C6-alkynyl, C1-C4-alkoxy and C1-C4-alkoxy-C1-C4-alkyl.
  • 47: The compound as claimed in claim 29, an N-oxide or an agriculturally suitable salt thereof, where R1 is selected from the group consisting of halogen, nitro, C1-C4-alkyl, C3-C6-cycloalkyl, C1-C4-haloalkyl, C1-C4-alkoxy-C1-C4-alkyl, C1-C4-alkoxy-C1-C4-alkoxy-C1-C4-alkyl, C1-C4-alkoxy, C1-C4-haloalkoxy, C1-C4-alkylthio, C1-C4-haloalkylthio and C1-C4-alkylsulfonyl; andR3 is selected from the group consisting of hydrogen, halogen, cyano, nitro, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy, C1-C4-haloalkoxy, C1-C4-alkylthio, C1-C4-haloalkylthio and C1-C4-alkylsulfonyl.
  • 48: The compound as claimed in claim 29, an N-oxide or an agriculturally suitable salt thereof, where X is CR2 and the variables R1, R2, R3, R4, R5, R6 and R7 have the following meanings: R1 is selected from the group consisting of halogen, nitro, cyclopropyl, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy-C1-C4-alkyl, C1-C4-alkoxy-C1-C4-alkoxy-C1-C4-alkyl and C1-C4-alkyl-S(O)2;R2 is selected from the group consisting of hydrogen, halogen, C1-C4-alkyl, C1-C4-alkoxy, C1-C4-haloalkoxy, C3-C6-cycloalkyl-C1-C2-alkoxy, C1-C2-alkoxy-C1-C2-alkyl, C1-C2-haloalkoxy-C1-C2-alkyl, C1-C2-alkoxy-C1-C2-alkoxy, C1-C4-alkyl-S(O)k, where k is 0, 1 or 2, N(C1-C4-alkyl)SO2(C1-C4-alkyl), isoxazolyl and isoxazolinyl, where the last two mentioned radicals may be unsubstituted or carry 1 or 2 radicals selected from halogen and C1-C4-alkyl;R3 is selected from the group consisting of hydrogen, halogen, cyano, nitro, C1-C4-alkyl, C1-C4-haloalkyl and C1-C4-alkyl-S(O)2;R4 is selected from the group consisting of hydrogen, cyano, methyl and halogen;R5 is selected from the group consisting of halogen, CHF2 and CF3;R6 is selected from the group consisting of C1-C4-alkyl, C1-C2-alkoxy-C1-C2-alkyl, C2-C4-alkenyl, C2-C4-alkynyl, C1-C4-alkoxycarbonyl-C1-C4-alkyl and phenyl-C1-C2-alkyl;R7 is selected from the group consisting of C1-C4-alkyl, C1-C4-alkoxy and C1-C2-alkoxy-C1-C2-alkyl.
  • 49: The compound as claimed in claim 29, an N-oxide or an agriculturally suitable salt thereof, where X is CR2 and the variables R1, R2, R3, R4, R5, R6 and R7 have the following meanings: R1 is selected from the group consisting of chlorine, nitro, methyl, cyclopropyl, trifluoromethyl, methoxymethyl, CH2OCH2CH2OCH3 and methylsulfonyl;R2 is selected from the group consisting of hydrogen, chlorine, fluorine, methyl, methoxy, ethoxy, OCH2(cyclo-C3H5), OCHF2, OCH2CF3, OCH2CH2OCH3, methoxymethyl, CH2OCH2CF3, methylsulfonyl, ethylsulfonyl, methylsulfinyl, ethylsulfinyl, methylsulfanyl, ethylsulfanyl, NCH3SO2CH3, 3-isoxazolinyl, 5-methyl-3-isoxazolinyl, 5-isoxazolinyl, 3-methyl-5-isoxazolinyl, 3-isoxazolyl, 5-methyl-3-isoxazolyl, 5-isoxazolyl and 3-methyl-5-isoxazolyl;R3 is selected from the group consisting of hydrogen, fluorine, chlorine, bromine, cyano, nitro, methyl, trifluoromethyl and methylsulfonyl;R4 is selected from the group consisting of hydrogen, cyano, methyl, chlorine and fluorine;R5 is selected from the group consisting of chlorine and fluorine;R6 is selected from the group consisting of methyl, ethyl, methoxymethyl, ethoxymethyl, prop-2-enyl, prop-2-ynyl, methoxycarbonylmethyl and benzyl;R7 is selected from the group consisting of methyl, ethyl, propyl, methoxy, ethoxy, methoxymethyl, methoxyethyl and ethoxymethyl.
  • 50: The compound as claimed in claim 29, an N-oxide or an agriculturally suitable salt thereof, where X is N and the variables R1, R3, R4, R5, R6 and R7 have the following meanings: R1 is selected from the group consisting of halogen, nitro, cyclopropyl, C1-C4-alkyl, C1-C4-haloalkyl, C1-C4-alkoxy-C1-C4-alkyl, C1-C4-alkoxy-C1-C4-alkoxy-C1-C4-alkyl and C1-C4-alkyl-S(O)2;R3 is selected from the group consisting of hydrogen, halogen, cyano, nitro, C1-C4-alkyl, C1-C4-haloalkyl and C1-C4-alkyl-S(O)2;R4 is selected from the group consisting of hydrogen, cyano, methyl and halogen;R5 is selected from the group consisting of halogen, CHF2 and CF3;R6 is selected from the group consisting of C1-C4-alkyl, C1-C2-alkoxy-C1-C2-alkyl, C2-C4-alkenyl, C2-C4-alkynyl, C1-C4-alkoxycarbonyl-C1-C4-alkyl and phenyl-C1-C2-alkyl;R7 is selected from the group consisting of C1-C4-alkyl, C1-C4-alkoxy and C1-C2-alkoxy-C1-C2-alkyl.
  • 51: The compound as claimed in claim 29, an N-oxide or an agriculturally suitable salt thereof, where X is N and the variables R1, R3, R4, R5, R6 and R7 have the following meanings: R1 is selected from the group consisting of chlorine, nitro, methyl, cyclopropyl, trifluoromethyl, methoxymethyl, CH2OCH2CH2OCH3 and methylsulfonyl;R3 is selected from the group consisting of hydrogen, fluorine, chlorine, bromine, cyano, nitro, methyl, trifluoromethyl and methylsulfonyl;R4 is selected from the group consisting of hydrogen, cyano, methyl, chlorine and fluorine;R5 is selected from the group consisting of chlorine and fluorine;R6 is selected from the group consisting of methyl, ethyl, methoxymethyl, ethoxymethyl, prop-2-enyl, prop-2-ynyl, methoxycarbonylmethyl and benzyl;R7 is selected from the group consisting of methyl, ethyl, propyl, methoxy, ethoxy, methoxymethyl, methoxyethyl and ethoxymethyl.
  • 52: The compound as claimed in claim 29, an N-oxide or an agriculturally suitable salt thereof, where X is CR2 and the variables R1, R2, R3, R4, R5, R6 and R7 have the following meanings: R1 is selected from the group consisting of chlorine, nitro, methyl, cyclopropyl, trifluoromethyl, methoxymethyl, CH2OCH2CH2OCH3 and methylsulfonyl;R2 is selected from the group consisting of hydrogen, chlorine, fluorine, methyl, CH2OCH2CF3, methylsulfonyl, ethylsulfonyl, methylsulfanyl, ethylsulfanyl, 3-isoxazolinyl, 5-methyl-3-isoxazolinyl, 5-isoxazolinyl, 3-methyl-5-isoxazolinyl, 3-isoxazolyl, 5-methyl-3-isoxazolyl, 5-isoxazolyl and 3-methyl-5-isoxazolyl;R3 is selected from the group consisting of hydrogen, fluorine, chlorine, cyano, nitro, methyl, trifluoromethyl and methylsulfonyl;R4 is selected from the group consisting of hydrogen, cyano, methyl, chlorine and fluorine;R5 is selected from the group consisting of chlorine and fluorine;R6 is selected from the group consisting of methyl, ethyl, methoxymethyl, ethoxymethyl, prop-2-ynyl and methoxycarbonylmethyl;R7 is selected from the group consisting of methyl, ethyl and methoxy.
  • 53: The compound as claimed in claim 29, an N-oxide or an agriculturally suitable salt thereof, where X is CR2 and the variable R3 is not hydrogen.
  • 54: The compound as claimed in claim 29, an N-oxide or an agriculturally suitable salt thereof, where X is CR2 and the variables R2 and R3 are not hydrogen.
  • 55: A composition comprising at least one compound as claimed in claim 29, an N-oxide or an agriculturally suitable salt thereof, and at least one auxiliary, which is customary for formulating crop protection compounds.
  • 56: A method for controlling unwanted vegetation which comprises allowing a herbicidally effective amount of at least one compound as claimed in claim 29, an N-oxide or an agriculturally suitable salt thereof, or a composition comprising at least one compound as claimed in claim 29 to act on plants, their seed, their habitat, or on a combination of two or all thereof.
Priority Claims (1)
Number Date Country Kind
13188043.7 Oct 2013 EP regional
PCT Information
Filing Document Filing Date Country Kind
PCT/EP2014/071382 10/7/2014 WO 00