Claims
- 1. A two-part thermally curable epoxy adhesive composition comprising:
- (a) an epoxy resin having an average epoxide functionality of greater than one;
- (b) a catalytically effective amount of a curing agent comprising the reaction product of
- (1) a substituted pentafluoroantimonic acid having the general formula H.sup.+ SbF.sub.5 X.sup.- wherein X is halogen, a hydroxy, or an OR group wherein OR is the residue of an aliphatic or aromatic alcohol; and
- (2) a substituted aniline selected from the group consisting of 4-aminobenzoic acid or a lower alkyl ester hereof, 4-amino-2-chlorobenzoic acid or a lower alkyl ester thereof, 5-amino-2-chlorobenzoic acid or a lower alkyl ester thereof, 3-amino-5-nitrobenzoic acid or a lower alkyl ester thereof, 2-bromoaniline, 3-bromoaniline, 4-bromoaniline, 2,4-dibromoaniline, 2-aminoacetophenone, 3-aminoacetophenone and 4-aminoacetophenone;
- (c) an aliphatic polyol, a cycloaliphatic polyol, or an alkanol-substituted arene polyol, or a mixture of two or more of the foregoing said polyols having about 2 to 18 carbon atoms, at least two hydroxy groups being primary or secondary; and
- (d) a toughening agent that does not react with the epoxy resin during curing and having an epoxide compatible component substantially soluble in said epoxy resin and an epoxide incompatible component substantially insoluble in said epoxy resin.
- 2. A composition according to claim 1, further characterized in that when tested in accordance with Test Method A which measures viscosity at four hours at 25.degree. C. at a shear rate of 100.sup.-1 seconds, said composition will not exhibit a viscosity increase greater than about eight-fold.
- 3. A composition according to claim 2, wherein said viscosity increase is not greater than about five-fold.
- 4. A composition according to claim 3, wherein said viscosity increase is not greater than about three-fold.
- 5. A composition according to claim 1, further comprising tannic acid.
CROSS-REFERENCE TO RELATED APPLICATION
This application is a continuation-in-part of U.S.S.N. 07/900,607, filed Jun. 18, 1992, now abandoned.
US Referenced Citations (3)
Foreign Referenced Citations (1)
Number |
Date |
Country |
963058 |
Jul 1964 |
GBX |
Continuation in Parts (1)
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Number |
Date |
Country |
Parent |
900607 |
Jun 1992 |
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