Claims
- 1. A composition comprising a lubricant and at least one compound of the formulae I or/and II ##STR20## in which the radicals R.sub.1 are identical or different and independently of one another are C.sub.8 -C.sub.20 -alkyl which is unsubstituted or substituted by 1 or 2 hydroxyl groups or/and interrupted by --O--, or are C.sub.1 -C.sub.4 -alkylene--COOR'.sub.2, C.sub.1 -C.sub.4 -alkylene--CO--NR".sub.2 R.sub.4 or C.sub.5 -C.sub.12 -cycloalkyl, R.sub.2, R'.sub.2 and R".sub.2 independently of one another are C.sub.1 -C.sub.20 -alkyl, allyl, methallyl, propargyl, C.sub.5 -C.sub.12 -cycloalkyl, phenyl or benzyl, R.sub.3 is hydrogen, C.sub.1 -C.sub.20 -alkyl, C.sub.2 -C.sub.18 -alkenyl or halogen, R.sub.4 is hydrogen, C.sub.1 -C.sub.20 -alkyl or C.sub.2 -C.sub.18 -alkenyl, Z.sub.1 is --S--or --C(Z.sub.3)(Z.sub.4)-- and Z.sub.2 is hydrogen, C.sub.1 -C.sub.20 -alkyl or --CH.sub.2 --S--R.sub.1, Z.sub.3 and Z.sub.4 independently of one another being hydrogen or methyl, with the proviso that the phenols of the formula II are free of the --CH.sub.2 --S--R.sub.1 functional group in the m-position relative to the OH group.
- 2. A composition according to claim 1, comprising a lubricant and at least one compound of the formulae I or II, in which R.sub.2 is methyl, ethyl or branched C.sub.3 -C.sub.20 -alkyl, allyl, methallyl, propargyl or benzyl and R.sub.1, R.sub.3, Z.sub.1 and Z.sub.2 are as defined in claim 1.
- 3. A composition according to claim 1, comprising at least one compound of the formulae I or/and II, in which the radicals R.sub.1 are identical or different and independently of one another are C.sub.8 -C.sub.20 -alkyl or C.sub.1 -C.sub.4 -alkylene--COOR.sub.2 ', R.sub.2 and R.sub.2 ' are C.sub.1 -C.sub.20 -alkyl, Z.sub.1 is --CH.sub.2 -- or --C(CH.sub.3).sub.2 -- and Z.sub.2 is as defined in claim 1.
- 4. A composition according to claim 1, comprising at least one compound of the formula I, in which the radicals R.sub.1 independently of one another are C.sub.8 -C.sub.20 -alkyl groups, which are unsubstituted, or C.sub.1 -C.sub.20 -alkyl groups, which are substituted by 1 or 2 hydroxyl groups.
- 5. A composition according to claim 1, wherein the radicals R.sub.1 are identical and are C.sub.8 -C.sub.12 -alkyl groups.
- 6. A composition according to claim 1, comprising at least one compound of the formula IIa ##STR21## in which R.sub.1, R.sub.3, Z.sub.1 and Z.sub.2 are as defined in claim 1.
- 7. A composition according to claim 6, wherein R.sub.3 is hydrogen and Z.sub.1 is --C(Z.sub.3)(Z.sub.4)--.
- 8. A composition according to claim 6, wherein Z.sub.2 is the radical --CH.sub.2 --S--R.sub.1.
- 9. A composition according to claim 1, comprising 0.01-10.0% by weight of a compound of the formula I or/and II, relative to the lubricant.
- 10. A compound of formula IIa ##STR22## in which the radicals R.sub.1 are identical or different and independently of one another are C.sub.1 -C.sub.20 -alkyl which is unsubstituted or substituted by 1 or 2 hydroxyl groups or/and interrupted by --O--, or are C.sub.1 -C.sub.4 -alkylene--COOR.sub.2 ', C.sub.1 -C.sub.4 -alkylene--CO--NR.sub.2 "R.sub.4, C.sub.5 -C.sub.12 -cycloalkyl, phenyl, 1-naphthyl, 2-naphthyl, C.sub.1 -C.sub.4 -alkyl-phenyl or phenyl-C.sub.1 -C.sub.4 -alkyl, R.sub.3 is hydrogen, C.sub.1 -C.sub.20 -alkyl, C.sub.2 -C.sub.18 -alkenyl or halogen, Z.sub.1 is --S-- or --C(Z.sub.3)(Z.sub.4)-- and Z.sub.2 is hydrogen, C.sub.1 -C.sub.20 -alkyl or --CH.sub.2 --S--R.sub.1, with the proviso that the phenols of the formula II are free of the --CH.sub.2 --S--R.sub.1 functional group in the m-position relative to the OH group.
- 11. A compound according to claim 10, wherein R.sub.3 is hydrogen and Z.sub.1 is --C(Z.sub.3)(Z.sub.4)--.
- 12. A compound according to claim 10, wherein Z.sub.2 is a --CH.sub.2 --S--R.sub.1 radical.
Priority Claims (1)
Number |
Date |
Country |
Kind |
5235/86 |
Dec 1986 |
CHX |
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Parent Case Info
This is a divisional of application Ser. No. 136,686 filed on Dec. 22, 1987, now abandoned, and a continuation of application Ser. No. 578,926, filed Sep. 6, 1990, now abandoned.
US Referenced Citations (19)
Foreign Referenced Citations (2)
Number |
Date |
Country |
165209 |
Dec 1985 |
EPX |
273013 |
Jun 1988 |
EPX |
Non-Patent Literature Citations (4)
Entry |
Chemical Abstract 86:5067n; Synthesis of New Organosulfur Derivatives of Shielded Phenols, Jan. 1977. |
Chemical Abstract 89:27167j; Phenol Derivatives as Oil Stabilizers, Jul. 1978. |
J. Am Chem. Soc. vol. 71 p. 2264 Jan. (1949). |
Abdullaeva, Chem. Abstracts 83:79881h Sep. 1975. |
Divisions (1)
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Number |
Date |
Country |
Parent |
136686 |
Dec 1987 |
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