Substrates having repeating patterns of apertures for absorbent articles

Information

  • Patent Grant
  • 11213436
  • Patent Number
    11,213,436
  • Date Filed
    Friday, January 3, 2020
    5 years ago
  • Date Issued
    Tuesday, January 4, 2022
    3 years ago
Abstract
The present disclosure is directed to substrates or topsheets having repeating patterns of apertures for absorbent articles. Each of the repeat units comprises at least three apertures.
Description
FIELD

The present disclosure is directed generally to substrates or topsheets having repeating patterns of apertures for absorbent articles.


BACKGROUND

Absorbent articles are used to absorb and contain bodily exudates (e.g., urine, menses, and BM) in infants, children, and adults. Absorbent articles may comprise diapers, pants, adult incontinence products, and sanitary napkins, for example. The absorbent articles typically comprise a liquid permeable topsheet, a liquid impermeable backsheet, and an absorbent core disposed at least partially the topsheet and the backsheet. Apertures may be formed in the topsheet to allow bodily exudate penetration through the topsheet. Apertures are sometimes present in a topsheet in a uniform manner (e.g., a one size, one shape aperture that is repeated throughout the topsheet with uniform spacing between the apertures). Topsheets with uniform aperture patterns may not be desired because they do not look customized. If apertures were to be presented in patterns, bodily exudate penetration becomes more complicated owing to the non-uniform nature of the topsheets. What is needed are absorbent article topsheets comprising repeating patterns of apertures comprising a plurality of repeat unit that perform parity to or better than topsheets with uniform aperture patterns with respect to penetration, absorbency, softness, run-off, and rewet.


SUMMARY

The present disclosure provides absorbent article with substrates or topsheets having repeating patterns of apertures comprising a plurality of repeat units that perform parity to or better than uniform aperture patterns and that also provide consumers with a more fanciful topsheet that is aesthetically appealing. The substrates or topsheets with repeating patterns of apertures comprising a plurality of repeat units perform parity to or better than topsheets with uniform aperture patterns with respect to penetration, absorbency, softness, run-off, and rewet. Repeating patterns of apertures comprising a plurality of repeat units may further provide signals of multiple functions, such as larger apertures for absorbency and smaller apertures for breathability. For sufficient bodily exudate acquisition and to minimize bodily exudate run-off and leakage, it may be desirable to have a minimum size for the apertures in the repeat units and have certain effective open areas in the topsheets to allow the bodily exudates to penetrate the topsheet and be absorbed by the hydrophilic layers underneath the topsheet (e.g., an acquisition layer or an absorbent core). Effective open areas in the topsheets that are too high, however, may lead to higher rewet and reduced softness of the topsheets. As such, desirable effective open areas in the range of 5% to 50%, 5% to 30%, or 5% to 15% may provide a good balance of softness and absorbency. When repeating patterns of apertures comprising a plurality of repeat units (compared to uniform apertures throughout) are utilized in topsheets to enhance visual aesthetics and perception of performance, the same technical requirements apply. At the same effective open area ranges of a uniform apertured topsheet, a topsheet with the repeating pattern of apertures comprising a plurality of repeat units may provide a topsheet that is not only visually appealing, but also efficacious. If the individual repeat units are too small (e.g., too many repeat units across a lateral width or longitudinal length of an absorbent article), the apertures, by necessity, will also be smaller than desired for bodily exudate handling. On the other hand, if the individual repeat units are too large, or are surrounded by too much land area (e.g., only one or one and a half repeat units across an absorbent article width), the bodily exudates may only be absorbed into the repeat unit area having apertures and not into surrounding land areas of the repeat units that are free of apertures and the absorbent article may not perform as well.


The present disclosure is directed, in part, to an absorbent article comprising a central lateral axis, a central longitudinal axis extending perpendicular to the central lateral axis, a liquid permeable apertured topsheet, a liquid impermeable backsheet, and an absorbent core disposed at least partially intermediate the topsheet and the backsheet. The absorbent core may comprise an absorbent material that is substantially free of air-felt or free of air-felt. The absorbent article has a total length along the central longitudinal axis, as measured according to the Repeat Unit Measurement Test. The absorbent article has a total width along the central lateral axis, as measured according to the Repeat Unit Measurement Test. The apertured topsheet comprises a repeating pattern of apertures comprising a plurality of repeat units. Each of the repeat units is the same or substantially the same. The repeat units repeat between about 3 and about 7 times along the total width, as measured by the Repeat Unit Measurement Test herein. At least a majority of the repeat units have a repeat unit area in the range of about 200 mm2 to about 1500 mm2 or about 900 mm2 to about 1500 mm2.





BRIEF DESCRIPTION OF THE DRAWINGS

While the specification concludes with claims particularly pointing out and distinctly claiming the subject matter which is regarded as forming the present invention, it is believed that the present disclosure will be better understood from the following description which is taken in conjunction with the accompanying drawings in which the designations are used to designate substantially identical elements and in which:



FIG. 1 is a plan view of an example absorbent article in the form of a taped diaper, garment-facing surface facing the viewer, in a flat laid-out state;



FIG. 2 is a plan view of the example absorbent article of FIG. 1, wearer-facing surface facing the viewer, in a flat laid-out state;



FIG. 3 is a front perspective view of the absorbent article of FIGS. 1 and 2 in a fastened position;



FIG. 4 is a front perspective view of an absorbent article in the form of a pant;



FIG. 5 is a rear perspective view of the absorbent article of FIG. 4;



FIG. 6 is a plan view of the absorbent article of FIG. 4, laid flat, with a garment-facing surface facing the viewer;



FIG. 7 is a cross-sectional view of the absorbent article taken about line 7-7 of FIG. 6;



FIG. 8 is a cross-sectional view of the absorbent article taken about line 8-8 of FIG. 6;



FIG. 9 is a plan view of an example absorbent core or an absorbent article;



FIG. 10 is a cross-sectional view, taken about line 10-10, of the absorbent core of FIG. 9;



FIG. 11 is a cross-sectional view, taken about line 11-11, of the absorbent core of FIG. 10;



FIG. 12 is a plan view of an example absorbent article of the present disclosure that is a sanitary napkin;



FIG. 13 is an example cross-sectional view taken within a front waist region of an absorbent article;



FIG. 14 is an example cross-sectional view taken within a crotch region of an absorbent article;



FIG. 15 is an example cross-sectional view taken within a back waist region of an absorbent article;



FIG. 16 is a photograph of a portion of repeat unit with apertures, wherein perimeters of at least some of the apertures comprise a melt lip;



FIGS. 17 and 18 are photographs of portions of topsheets comprising repeating patterns of apertures comprising a plurality of repeat units;



FIGS. 19-21 are schematic illustrations of portion of topsheets comprising repeating patterns of apertures comprising a plurality of repeat units;



FIG. 22 is a schematic illustration of a portion of a topsheet comprising a repeating pattern of apertures comprising a plurality of repeat unit, wherein the repeat units are substantially similar;



FIG. 23 is a schematic illustration of a portion of a topsheet comprising a repeating pattern of apertures comprising a plurality of repeat unit, wherein the repeat units are substantially similar;



FIG. 24 is an example repeat unit boundary identification linked to the Repeat Unit Measurement Test herein;



FIG. 25 is an example repeat unit boundary identification taken in a substrate comprising a repeating pattern of apertures comprising a plurality of repeat units linked to the Repeat Unit Measurement Test herein; and



FIG. 26 is an example absorbent article having a topsheet comprising a repeating pattern of apertures comprising a plurality of repeat units linked to the Repeat Unit Measurement Test herein.





DETAILED DESCRIPTION

Various non-limiting forms of the present disclosure will now be described to provide an overall understanding of the principles of the structure, function, manufacture, and use of the substrates having repeating patterns of apertures for absorbent articles disclosed herein. One or more examples of these non-limiting forms are illustrated in the accompanying drawings. Those of ordinary skill in the art will understand that the substrates having repeating patterns of apertures for absorbent articles specifically described herein and illustrated in the accompanying drawings are non-limiting example forms and that the scope of the various non-limiting forms of the present disclosure are defined solely by the claims. The features illustrated or described in connection with one non-limiting form may be combined with the features of other non-limiting forms. Such modifications and variations are intended to be included within the scope of the present disclosure.


As used herein, the term “absorbent article”, refers to devices which absorb and contain bodily exudates (e.g., BM, urine, menses), and, more specifically, refers to devices which are placed against or in proximity to the body of the wearer to absorb and contain the various bodily exudates discharged from the body. The term absorbent article includes, but is not limited to, diapers, pants, training pants, adult incontinence products, and sanitary napkins, and liners. The term “absorbent article” may also encompass cleaning or dusting pads or substrates that have some absorbency.


As used herein, the terms “join”, “joined”, “joining”, “bond”, “bonded”, “bonding”, “attach”, “attached”, or “attaching” encompass configurations whereby an element is directly secured to another element by affixing the element directly to the other element, and configurations whereby an element is indirectly secured to another element by affixing the element to intermediate member(s) which in turn are affixed to the other element.


As used herein, the term “nanofibers”, refers to very small diameter fibers having an average diameter less than about 1 micron.


As used herein, the term “meltblown”, refers to fibers formed by extruding a molten thermoplastic material through a plurality of fine, usually circular, die capillaries as molten threads or filaments into a high velocity gas (e.g., air) stream which attenuates the filaments of molten thermoplastic material to reduce their diameter, which may be to a microfiber diameter. Thereafter, the meltblown fibers are carded by the high velocity gas stream and are deposited on a collecting surface to form a web of randomly dispersed meltblown fibers.


As used herein, the term “spunbond”, refers to small diameter fibers which are formed by extruding a molten thermoplastic material as filaments from a plurality of fine, usually circular, capillaries of a spinneret with the diameter of the extruded filaments then being rapidly reduced as by, for example, eductive drawing or other well-known spunbonding mechanisms.


Example absorbent articles designs that may contain substrates or topsheets with repeating patterns of apertures comprising a plurality of repeat units are first discussed below. The substrates may be topsheets, outer cover nonwoven materials, or other substrates of absorbent articles.


General Description of an Absorbent Article

An example absorbent article 10 according to the present disclosure, shown in the form of a taped diaper, is represented in FIGS. 1-3. FIG. 1 is a plan view of the example absorbent article 10, garment-facing surface 2 facing the viewer in a flat, laid-out state (i.e., no elastic contraction). FIG. 2 is a plan view of the example absorbent article 10 of FIG. 1, wearer-facing surface 4 facing the viewer in a flat, laid-out state. FIG. 3 is a front perspective view of the absorbent article 10 of FIGS. 1 and 2 in a fastened configuration. The absorbent article 10 of FIGS. 1-3 is shown for illustration purposes only as the present disclosure may be used for making a wide variety of diapers, including adult incontinence products, pants, or other absorbent articles, such as sanitary napkins and absorbent pads, for example.


The absorbent article 10 may comprise a front waist region 12, a crotch region 14, and a back waist region 16. The crotch region 14 may extend intermediate the front waist region 12 and the back waist region 16. The front wait region 12, the crotch region 14, and the back waist region 16 may each be ⅓ of the length of the absorbent article 10. The absorbent article 10 may comprise a front end edge 18, a back end edge 20 opposite to the front end edge 18, and longitudinally extending, transversely opposed side edges 22 and 24 defined by the chassis 52.


The absorbent article 10 may comprise a liquid permeable topsheet 26, a liquid impermeable backsheet 28, and an absorbent core 30 positioned at least partially intermediate the topsheet 26 and the backsheet 28. The absorbent article 10 may also comprise one or more pairs of barrier leg cuffs 32 with or without elastics 33, one or more pairs of leg elastics 34, one or more elastic waistbands 36, and/or one or more acquisition materials 38. The acquisition material or materials 38 may be positioned intermediate the topsheet 26 and the absorbent core 30. An outer cover material 40, such as a nonwoven material, may cover a garment-facing side of the backsheet 28. The absorbent article 10 may comprise back ears 42 in the back waist region 16. The back ears 42 may comprise fasteners 46 and may extend from the back waist region 16 of the absorbent article 10 and attach (using the fasteners 46) to the landing zone area or landing zone material 44 on a garment-facing portion of the front waist region 12 of the absorbent article 10. The absorbent article 10 may also have front ears 47 in the front waist region 12. The absorbent article 10 may have a central lateral (or transverse) axis 48 and a central longitudinal axis 50. The central lateral axis 48 extends perpendicular to the central longitudinal axis 50.


In other instances, the absorbent article may be in the form of a pant having permanent or refastenable side seams. Suitable refastenable seams are disclosed in U.S. Pat. Appl. Pub. No. 2014/0005020 and U.S. Pat. No. 9,421,137. Referring to FIGS. 4-8, an example absorbent article 10 in the form of a pant is illustrated. FIG. 4 is a front perspective view of the absorbent article 10. FIG. 5 is a rear perspective view of the absorbent article 10. FIG. 6 is a plan view of the absorbent article 10, laid flat, with the garment-facing surface facing the viewer. Elements of FIG. 4-8 having the same reference number as described above with respect to FIGS. 1-3 may be the same element (e.g., absorbent core 30). FIG. 7 is an example cross-sectional view of the absorbent article taken about line 7-7 of FIG. 6. FIG. 8 is an example cross-sectional view of the absorbent article taken about line 8-8 of FIG. 6. FIGS. 7 and 8 illustrate example forms of front and back belts 54, 56. The absorbent article 10 may have a front waist region 12, a crotch region 14, and a back waist region 16. Each of the regions 12, 14, and 16 may be ⅓ of the length of the absorbent article 10. The absorbent article 10 may have a chassis 52 (sometimes referred to as a central chassis or central panel) comprising a topsheet 26, a backsheet 28, and an absorbent core 30 disposed at least partially intermediate the topsheet 26 and the backsheet 28, and an optional acquisition material 38, similar to that as described above with respect to FIGS. 1-3. The absorbent article 10 may comprise a front belt 54 in the front waist region 12 and a back belt 56 in the back waist region 16. The chassis 52 may be joined to a wearer-facing surface 4 of the front and back belts 54, 56 or to a garment-facing surface 2 of the belts 54, 56. Side edges 23 and 25 of the front belt 54 may be joined to side edges 27 and 29, respectively, of the back belt 56 to form two side seams 58. The side seams 58 may be any suitable seams known to those of skill in the art, such as butt seams or overlap seams, for example. When the side seams 58 are permanently formed or refastenably closed, the absorbent article 10 in the form of a pant has two leg openings 60 and a waist opening circumference 62. The side seams 58 may be permanently joined using adhesives or bonds, for example, or may be refastenably closed using hook and loop fasteners, for example.


Belts

Referring to FIGS. 7 and 8, the front and back belts 54 and 56 may comprise front and back inner belt layers 66 and 67 and front and back outer belt layers 64 and 65 having an elastomeric material (e.g., strands 68 or a film (which may be apertured)) disposed at least partially therebetween. The elastic elements 68 or the film may be relaxed (including being cut) to reduce elastic strain over the absorbent core 30 or, may alternatively, run continuously across the absorbent core 30. The elastics elements 68 may have uniform or variable spacing therebetween in any portion of the belts. The elastic elements 68 may also be pre-strained the same amount or different amounts. The front and/or back belts 54 and 56 may have one or more elastic element free zones 70 where the chassis 52 overlaps the belts 54, 56. In other instances, at least some of the elastic elements 68 may extend continuously across the chassis 52.


The front and back inner belt layers 66, 67 and the front and back outer belt layers 64, 65 may be joined using adhesives, heat bonds, pressure bonds or thermoplastic bonds. Various suitable belt layer configurations can be found in U.S. Pat. Appl. Pub. No. 2013/0211363.


Front and back belt end edges 55 and 57 may extend longitudinally beyond the front and back chassis end edges 19 and 21 (as shown in FIG. 6) or they may be co-terminus. The front and back belt side edges 23, 25, 27, and 29 may extend laterally beyond the chassis side edges 22 and 24. The front and back belts 54 and 56 may be continuous (i.e., having at least one layer that is continuous) from belt side edge to belt side edge (e.g., the transverse distances from 23 to 25 and from 27 to 29). Alternatively, the front and back belts 54 and 56 may be discontinuous from belt side edge to belt side edge (e.g., the transverse distances from 23 to 25 and 27 to 29), such that they are discrete.


As disclosed in U.S. Pat. No. 7,901,393, the longitudinal length (along the central longitudinal axis 50) of the back belt 56 may be greater than the longitudinal length of the front belt 54, and this may be particularly useful for increased buttocks coverage when the back belt 56 has a greater longitudinal length versus the front belt 54 adjacent to or immediately adjacent to the side seams 58.


The front outer belt layer 64 and the back outer belt layer 65 may be separated from each other, such that the layers are discrete or, alternatively, these layers may be continuous, such that a layer runs continuously from the front belt end edge 55 to the back belt end edge 57. This may also be true for the front and back inner belt layers 66 and 67—that is, they may also be longitudinally discrete or continuous. Further, the front and back outer belt layers 64 and 65 may be longitudinally continuous while the front and back inner belt layers 66 and 67 are longitudinally discrete, such that a gap is formed between them—a gap between the front and back inner and outer belt layers 64, 65, 66, and 67 is shown in FIG. 7 and a gap between the front and back inner belt layers 66 and 67 is shown in FIG. 8.


The front and back belts 54 and 56 may include slits, holes, and/or perforations providing increased breathability, softness, and a garment-like texture. Underwear-like appearance can be enhanced by substantially aligning the waist and leg edges at the side seams 58 (see FIGS. 4 and 5).


The front and back belts 54 and 56 may comprise graphics (see e.g., 78 of FIG. 1). The graphics may extend substantially around the entire circumference of the absorbent article 10 and may be disposed across side seams 58 and/or across proximal front and back belt seams 15 and 17; or, alternatively, adjacent to the seams 58, 15, and 17 in the manner described in U.S. Pat. No. 9,498,389 to create a more underwear-like article. The graphics may also be discontinuous.


Alternatively, instead of attaching belts 54 and 56 to the chassis 52 to form a pant, discrete side panels may be attached to side edges of the chassis 22 and 24. Suitable forms of pants comprising discrete side panels are disclosed in U.S. Pat. Nos. 6,645,190; 8,747,379; 8,372,052; 8,361,048; 6,761,711; 6,817,994; 8,007,485; 7,862,550; 6,969,377; 7,497,851; 6,849,067; 6,893,426; 6,953,452; 6,840,928; 8,579,876; 7,682,349; 7,156,833; and 7,201,744.


Topsheet

The topsheet 26 is the part of the absorbent article 10 that is in contact with the wearer's skin. The topsheet 26 may be joined to portions of the backsheet 28, the absorbent core 30, the barrier leg cuffs 32, and/or any other layers as is known to those of ordinary skill in the art. The topsheet 26 may be compliant, soft-feeling, and non-irritating to the wearer's skin. Further, at least a portion of, or all of, the topsheet may be liquid permeable, permitting liquid bodily exudates to readily penetrate through its thickness. Some topsheets may be manufactured from a wide range of materials, such as porous foams, reticulated foams, apertured plastic films, woven materials, nonwoven materials, woven or nonwoven materials of natural fibers (e.g., wood or cotton fibers), synthetic fibers or filaments (e.g., polyester or polypropylene or bicomponent PE/PP fibers or mixtures thereof), or a combination of natural and synthetic fibers. The topsheet may have one or more layers. The topsheet may be apertured (e.g., FIG. 2, element 27), may have any suitable three-dimensional features, and/or may have a plurality of embossments (e.g., a bond pattern). The topsheet may be apertured by overbonding a material and then rupturing the overbonds through ring rolling, such as disclosed in U.S. Pat. No. 5,628,097, to Benson et al., issued on May 13, 1997 and disclosed in U.S. Pat. Appl. Publication No. US 2016/0136014 to Arora et al. Any portion of the topsheet may be coated with a skin care composition, an antibacterial agent, a surfactant, and/or other beneficial agents. The topsheet may be hydrophilic or hydrophobic or may have hydrophilic and/or hydrophobic portions or layers. If the topsheet is hydrophobic, typically apertures will be present so that bodily exudates may pass through the topsheet. Repeating patterns of apertures comprising a plurality of repeat units in the topsheets will be discussed in greater detail below.


Backsheet

The backsheet 28 is generally that portion of the absorbent article 10 positioned proximate to the garment-facing surface of the absorbent core 30. The backsheet 28 may be joined to portions of the topsheet 26, the outer cover material 40, the absorbent core 30, and/or any other layers of the absorbent article by any attachment methods known to those of skill in the art. The backsheet 28 prevents, or at least inhibits, the bodily exudates absorbed and contained in the absorbent core 10 from soiling articles such as bedsheets, undergarments, and/or clothing. The backsheet is typically liquid impermeable, or at least substantially liquid impermeable. The backsheet may, for example, be or comprise a thin plastic film, such as a thermoplastic film having a thickness of about 0.012 mm to about 0.051 mm. Other suitable backsheet materials may include breathable materials which permit vapors to escape from the absorbent article, while still preventing, or at least inhibiting, bodily exudates from passing through the backsheet.


Outer Cover Material

The outer cover material (sometimes referred to as a backsheet nonwoven) 40 may comprise one or more nonwoven materials joined to the backsheet 28 and that covers the backsheet 28. The outer cover material 40 forms at least a portion of the garment-facing surface 2 of the absorbent article 10 and effectively “covers” the backsheet 28 so that film is not present on the garment-facing surface 2. The outer cover material 40 may comprise a bond pattern, apertures, and/or three-dimensional features. The outer cover material 40 may have the repeating patterns of apertures comprising the plurality of repeat units discussed herein.


Absorbent Core

As used herein, the term “absorbent core” 30 refers to the component of the absorbent article 10 having the most absorbent capacity and that comprises an absorbent material. Referring to FIGS. 9-11, in some instances, absorbent material 72 may be positioned within a core bag or a core wrap 74. The absorbent material may be profiled or not profiled, depending on the specific absorbent article. The absorbent core 30 may comprise, consist essentially of, or consist of, a core wrap, absorbent material 72, and glue enclosed within the core wrap. The absorbent material may comprise superabsorbent polymers, a mixture of superabsorbent polymers and air felt, only air felt, and/or a high internal phase emulsion foam. In some instances, the absorbent material may comprise at least 80%, at least 85%, at least 90%, at least 95%, at least 99%, or up to 100% superabsorbent polymers, by weight of the absorbent material. In such instances, the absorbent material may free of air felt, or at least mostly free of air felt. The absorbent core periphery, which may be the periphery of the core wrap, may define any suitable shape, such as rectangular “T,” “Y,” “hour-glass,” or “dog-bone” shaped, for example. An absorbent core periphery having a generally “dog bone” or “hour-glass” shape may taper along its width towards the crotch region 14 of the absorbent article 10.


Referring to FIGS. 9-11, the absorbent core 30 may have areas having little or no absorbent material 72, where a wearer-facing surface of the core bag 74 may be joined to a garment-facing surface of the core bag 74. These areas having little or no absorbent material may be referred to as “channels” 76. These channels can embody any suitable shapes and any suitable number of channels may be provided. In other instances, the absorbent core may be embossed to create the impression of channels. The absorbent core in FIGS. 9-11 is merely an example absorbent core. Many other absorbent cores with or without channels are also within the scope of the present disclosure.


Barrier Leg Cuffs/Leg Elastics

Referring to FIGS. 1 and 2, for example, the absorbent article 10 may comprise one or more pairs of barrier leg cuffs 32 and one or more pairs of leg elastics 34. The barrier leg cuffs 32 may be positioned laterally inboard of leg elastics 34. Each barrier leg cuff 32 may be formed by a piece of material which is bonded to the absorbent article 10 so it can extend upwards from a wearer-facing surface 4 of the absorbent article 10 and provide improved containment of body exudates approximately at the junction of the torso and legs of the wearer. The barrier leg cuffs 32 are delimited by a proximal edge joined directly or indirectly to the topsheet and/or the backsheet and a free terminal edge, which is intended to contact and form a seal with the wearer's skin. The barrier leg cuffs 32 may extend at least partially between the front end edge 18 and the back end edge 20 of the absorbent article 10 on opposite sides of the central longitudinal axis 50 and may be at least present in the crotch region 14. The barrier leg cuffs 32 may each comprise one or more elastics 33 (e.g., elastic strands or strips) near or at the free terminal edge. These elastics 33 cause the barrier leg cuffs 32 to help form a seal around the legs and torso of a wearer. The leg elastics 34 extend at least partially between the front end edge 18 and the back end edge 20. The leg elastics 34 essentially cause portions of the absorbent article 10 proximate to the chassis side edges 22, 24 to help form a seal around the legs of the wearer. The leg elastics 34 may extend at least within the crotch region 14.


Elastic Waistband

Referring to FIGS. 1 and 2, the absorbent article 10 may comprise one or more elastic waistbands 36. The elastic waistbands 36 may be positioned on the garment-facing surface 2 or the wearer-facing surface 4. As an example, a first elastic waistband 36 may be present in the front waist region 12 near the front belt end edge 18 and a second elastic waistband 36 may be present in the back waist region 16 near the back end edge 20. The elastic waistbands 36 may aid in sealing the absorbent article 10 around a waist of a wearer and at least inhibiting bodily exudates from escaping the absorbent article 10 through the waist opening circumference. In some instances, an elastic waistband may fully surround the waist opening circumference of an absorbent article.


Acquisition Materials

Referring to FIGS. 1, 2, 7, and 8, one or more acquisition materials 38 may be present at least partially intermediate the topsheet 26 and the absorbent core 30. The acquisition materials 38 are typically hydrophilic materials that provide significant wicking of bodily exudates. These materials may dewater the topsheet 26 and quickly move bodily exudates into the absorbent core 30. The acquisition materials 38 may comprise one or more nonwoven materials, foams, cellulosic materials, cross-linked cellulosic materials, air laid cellulosic nonwoven materials, spunlace materials, or combinations thereof, for example. In some instances, portions of the acquisition materials 38 may extend through portions of the topsheet 26, portions of the topsheet 26 may extend through portions of the acquisition materials 38, and/or the topsheet 26 may be nested with the acquisition materials 38. Typically, an acquisition material 38 may have a width and length that are smaller than the width and length of the topsheet 26. The acquisition material may be a secondary topsheet in the feminine pad context. The acquisition material may have one or more channels as described above with reference to the absorbent core 30 (including the embossed version). The channels in the acquisition material may align or not align with channels in the absorbent core 30. In an example, a first acquisition material may comprise a nonwoven material and as second acquisition material may comprise a cross-linked cellulosic material. In some instances, the acquisition material may comprise the repeating pattern of apertures comprising the plurality of repeat units discussed herein.


Landing Zone

Referring to FIGS. 1 and 2, the absorbent article 10 may have a landing zone area 44 that is formed in a portion of the garment-facing surface 2 of the outer cover material 40. The landing zone area 44 may be in the back waist region 16 if the absorbent article 10 fastens from front to back or may be in the front waist region 12 if the absorbent article 10 fastens back to front. In some instances, the landing zone 44 may be or may comprise one or more discrete nonwoven materials that are attached to a portion of the outer cover material 40 in the front waist region 12 or the back waist region 16 depending upon whether the absorbent article fastens in the front or the back. In essence, the landing zone 44 is configured to receive the fasteners 46 and may comprise, for example, a plurality of loops configured to be engaged with, a plurality of hooks on the fasteners 46, or vice versa. The landing zone may comprise the repeating pattern of apertures comprising the plurality of repeat units discussed herein.


Wetness Indicator/Graphics

Referring to FIG. 1, the absorbent articles 10 of the present disclosure may comprise graphics 78 and/or wetness indicators 80 that are visible from the garment-facing surface 2. The graphics 78 may be printed on the landing zone 40, the backsheet 28, and/or at other locations. The wetness indicators 80 are typically applied to the absorbent core facing side of the backsheet 28, so that they can be contacted by bodily exudates within the absorbent core 30. In some instances, the wetness indicators 80 may form portions of the graphics 78. For example, a wetness indicator may appear or disappear and create/remove a character within some graphics. In other instances, the wetness indicators 80 may coordinate (e.g., same design, same pattern, same color) or not coordinate with the graphics 78.


Front and Back Ears

Referring to FIGS. 1 and 2, as referenced above, the absorbent article 10 may have front and/or back ears 47, 42 in a taped diaper context. Only one set of ears may be required in most taped diapers. The single set of ears may comprise fasteners 46 configured to engage the landing zone or landing zone area 44. If two sets of ears are provided, in most instances, only one set of the ears may have fasteners 46, with the other set being free of fasteners. The ears, or portions thereof, may be elastic or may have elastic panels. In an example, an elastic film or elastic strands may be positioned intermediate a first nonwoven material and a second nonwoven material. The elastic film may or may not be apertured. The ears may be shaped. The ears may be integral (e.g., extension of the outer cover material 40, the backsheet 28, and/or the topsheet 26) or may be discrete components attached to a chassis 52 of the absorbent article on a wearer-facing surface 4, on the garment-facing surface 2, or intermediate the two surfaces 4, 2.


Sensors

Referring again to FIG. 1, the absorbent articles of the present disclosure may comprise a sensor system 82 for monitoring changes within the absorbent article 10. The sensor system 82 may be discrete from or integral with the absorbent article 10. The absorbent article 10 may comprise sensors that can sense various aspects of the absorbent article 10 associated with insults of bodily exudates such as urine and/or BM (e.g., the sensor system 82 may sense variations in temperature, humidity, presence of ammonia or urea, various vapor components of the exudates (urine and feces), changes in moisture vapor transmission through the absorbent articles garment-facing layer, changes in translucence of the garment-facing layer, and/or color changes through the garment-facing layer). Additionally, the sensor system 82 may sense components of urine, such as ammonia or urea and/or byproducts resulting from reactions of these components with the absorbent article 10. The sensor system 82 may sense byproducts that are produced when urine mixes with other components of the absorbent article 10 (e.g., adhesives, agm). The components or byproducts being sensed may be present as vapors that may pass through the garment-facing layer. It may also be desirable to place reactants in the absorbent article that change state (e.g. color, temperature) or create a measurable byproduct when mixed with urine or BM. The sensor system 82 may also sense changes in pH, pressure, odor, the presence of gas, blood, a chemical marker or a biological marker or combinations thereof. The sensor system 82 may have a component on or proximate to the absorbent article that transmits a signal to a receiver more distal from the absorbent article, such as an iPhone, for example. The receiver may output a result to communicate to the caregiver a condition of the absorbent article 10. In other instances, a receiver may not be provided, but instead the condition of the absorbent article 10 may be visually or audibly apparent from the sensor on the absorbent article.


Packages

The absorbent articles of the present disclosure may be placed into packages. The packages may comprise polymeric films and/or other materials. Graphics and/or indicia relating to properties of the absorbent articles may be formed on, printed on, positioned on, and/or placed on outer portions of the packages. Each package may comprise a plurality of absorbent articles. The absorbent articles may be packed under compression so as to reduce the size of the packages, while still providing an adequate amount of absorbent articles per package. By packaging the absorbent articles under compression, caregivers can easily handle and store the packages, while also providing distribution savings to manufacturers owing to the size of the packages.


Arrays

“Array” means a display of packages comprising disposable absorbent articles of different article constructions (e.g., different elastomeric materials [compositionally and/or structurally] in the side panels, side flaps and/or belts flaps, different graphic elements, different product structures, fasteners or lack thereof). The packages may have the same brand and/or sub-brand and/or the same trademark registration and/or having been manufactured by or for a common manufacturer and the packages may be available at a common point of sale (e.g. oriented in proximity to each other in a given area of a retail store). An array is marketed as a line-up of products normally having like packaging elements (e.g., packaging material type, film, paper, dominant color, design theme, etc.) that convey to consumers that the different individual packages are part of a larger line-up. Arrays often have the same brand, for example, “Huggies,” and same sub-brand, for example, “Pull-Ups.” A different product in the array may have the same brand “Huggies” and the sub-brand “Little Movers.” The differences between the “Pull-Ups” product of the array and the “Little Movers” product in the array may include product form, application style, different fastening designs or other structural elements intended to address the differences in physiological or psychological development. Furthermore, the packaging is distinctly different in that “Pull-Ups” is packaged in a predominately blue or pink film bag and “Little Movers” is packaged in a predominately red film bag.


Further regarding “Arrays,” as another example an array may be formed by different products having different product forms manufactured by the same manufacturer, for example, “Kimberly-Clark”, and bearing a common trademark registration for example, one product may have the brand name “Huggies,” and sub-brand, for example, “Pull-Ups.” A different product in the array may have a brand/sub-brand “Good Nites” and both are registered trademarks of The Kimberly-Clark Corporation and/or are manufactured by Kimberly-Clark. Arrays also often have the same trademarks, including trademarks of the brand, sub-brand, and/or features and/or benefits across the line-up. “On-line Array” means an “Array” distributed by a common on-line source.


Sanitary Napkin

Referring to FIG. 12, an absorbent article of the present disclosure may be a sanitary napkin 110. The sanitary napkin 110 may comprise a liquid permeable topsheet 114, a liquid impermeable, or substantially liquid impermeable, backsheet 116, and an absorbent core 118. The liquid impermeable backsheet 116 may or may not be vapor permeable. The absorbent core 118 may have any or all of the features described herein with respect to the absorbent core 30 and, in some forms, may have a secondary topsheet 119 (STS) instead of the acquisition materials disclosed above. The STS 119 may comprise one or more channels, as described above (including the embossed version). In some forms, channels in the STS 119 may be aligned with channels in the absorbent core 118. The sanitary napkin 110 may also comprise wings 120 extending outwardly with respect to a longitudinal axis 180 of the sanitary napkin 110. The sanitary napkin 110 may also comprise a lateral axis 190. The wings 120 may be joined to the topsheet 114, the backsheet 116, and/or the absorbent core 118. The sanitary napkin 110 may also comprise a front edge 122, a back edge 124 longitudinally opposing the front edge 122, a first side edge 126, and a second side edge 128 longitudinally opposing the first side edge 126. The longitudinal axis 180 may extend from a midpoint of the front edge 122 to a midpoint of the back edge 124. The lateral axis 190 may extend from a midpoint of the first side edge 128 to a midpoint of the second side edge 128. The sanitary napkin 110 may also be provided with additional features commonly found in sanitary napkins as is known in the art. The topsheet or secondary topsheet of the sanitary napkin may comprise the repeating pattern of apertures comprising the plurality of repeat units discussed herein.


Examples Cross-sections of Absorbent Articles


FIGS. 13-15 illustrate example cross-sectional views of absorbent articles within the scope of the present disclosure. FIG. 13 is an example cross-sectional view taken within a front waist region 12 of an absorbent article. FIG. 14 is an example cross-sectional view taken within a crotch region 14 of an absorbent article. FIG. 15 is an example cross-sectional view taken within a back waist region 16 of an absorbent article. In FIGS. 13-15, an outer cover material is element 40, a liquid permeable topsheet is element 26, opacity patches are elements 84, a liquid impermeable backsheet is element 28, an absorbent core is element 30, with the core bag being element 74, an absorbent material is element 72, and a distribution material is element 86. The distribution material 86 may comprise cross-linked cellulosic material and may be optional. An acquisition material is element 88. A liquid permeable topsheet is element 26. Barrier leg cuffs are elements 90. Elastics in the barrier leg cuffs are elements 92. Back ears are elements 42. Fasteners on the back ears 42 are elements 46. Construction glues and/or bonds between the various layers and/or components have been removed for clarity. Other cross-sectional configurations known to those of skill in the art are also within the scope of the present disclosure.


Substrates

The substrates in the absorbent articles having the repeating pattern of apertures comprising the plurality of repeat units may be topsheets, topsheet laminates, acquisition materials, topsheet and acquisition material laminates, outer cover nonwoven materials, nonwoven materials of ears, landing zones, and/or other substrates in absorbent articles. The substrates may have one or more layers. In various instances, the substrates or topsheets may comprise one or more nonwoven materials, one or more films, or one or more nonwovens and one or more films, for example. The repeating pattern of apertures comprising the plurality of repeat units will be discussed in the topsheet context below, but the present disclosure covers other substrates and/or laminates in an absorbent article. The repeating pattern of apertures comprising the plurality of repeat units may be used for more than one component of an absorbent article, such as a topsheet and an outer cover nonwoven material, for example. In another instance, the topsheet and the outer cover nonwoven material may have the same pattern, but the topsheet may utilize apertures to create the pattern and the outer cover nonwoven material may utilize embossing to create the same or a similar pattern.


Topsheets

The topsheets of the absorbent articles discussed above are now described in greater detail. The topsheets may each comprise one or more nonwoven materials and/or one or more films. Each nonwoven material may have one or more layers (i.e., Spunbond-meltblown-spunbond). Any of the layers may comprise cotton or natural fibers. In an example, a topsheet may have two layers of a nonwoven material. A first layer may form a wearer-facing surface of the topsheet in the absorbent article and a second layer may form a garment-facing surface of the topsheet in the absorbent article. The first and second layers may be hydrophobic or hydrophilic. The first layer may be more hydrophobic or more hydrophilic than the second layer. The first layer may be hydrophobic, while the second layer may be hydrophilic. Both layers may be hydrophobic or hydrophilic. The topsheet may comprise spunbond fibers, carded fibers, cotton fibers, meltblown fibers, nanofibers (i.e., less than one micro), and/or other suitable type of fibers (natural or synthetic). The first layer and/or the second layer may comprise spunbond fibers. The first layer may comprise spunbond fibers or carded fibers and the second layer may comprise spunbond fibers or carded fibers. The topsheet may comprise a whitening or opacifying agent, such as Titanium Dioxide, for example. The apertures of the repeating pattern of apertures may extend through all layers of a topsheet or may extend through less than all layers of a topsheet. For example, a first layer of a topsheet may have apertures while a second layer may not. The topsheets or substrates may comprise printing, ink, colored glues, and/or indicia on one or more layers thereof. Any of the layers may be tinted or colored (other than white). For example, a first layer may be white and a second layer may be light blue. As another example, the first layer may be light blue while a second layer may be dark blue. The various layers may or may not have the same color and/or opacity.


Repeat Units

The topsheets of the present disclosure may comprise a plurality of repeat units. Each of the repeat units may have at least two (or 3, or 4, or 5 etc.) apertures having a different size, shape, aspect ratio (i.e., major axis to minor axis), and/or angle relative to a central longitudinal axis of a topsheet on an absorbent article. In another instance, each of the repeat units may have at least 3 (or 4, or 5 etc.) apertures having a different size, shape, aspect ratio, and/or angle relative to the central longitudinal axis of a topsheet on an absorbent article. Each repeat unit will have at least three apertures, and likely more than three apertures. In some instances, all of the apertures in a repeat unit may be the same or different in size, shape, aspect ratio, and/or angle relative to the central longitudinal axis of a topsheet on an absorbent article. In other instances, some of the apertures in a repeat unit may be the same or different in size, shape, aspect ratio, and/or angle relative to the central longitudinal axis of a topsheet in an absorbent article. When it is said that the various apertures in a repeat until are “the same” or “different” this means the design is intended to be the same or different and is not merely process tolerances.


In an instance, substrates or topsheets comprising repeating patterns of apertures comprising the plurality of repeat units may have repeat units that all have the same apertures. Stated another way, all of the apertures in a repeat unit may be the same size, shape etc. and the repeat units may all be the same or at least a majority of the repeat units may be the same.


In some examples, and referring to FIG. 16, portions of perimeters of at least some of the apertures 310 in the repeat units may comprise one or more melt lips 312 or fused portions. In some examples, portions of perimeters of at least some of the apertures may be free of a melt lip. Thus, in certain examples, the one or more melt lips 312 may at least partially or fully surround the apertures 310. In an example, the one or more melt lips 312 may surround from about 25% of a perimeter of the apertures 310 to about 100% of the perimeter of the apertures 310. In certain examples, the one or more melt lips 312 may be formed on lateral sides of the apertures 310 and not on leading and/or trailing edges of the apertures 310 (see MD and CD arrows for reference in FIG. 16). It is believed that the one or more melt lips 312 may be formed during an overbonding step (as taught in U.S. Pat. Appl. Publication No. 2016/0136014 to Arora et al.) and may add strength to an apertured topsheet, for example.


Examples of portions of substrates or topsheet comprising repeating patterns of apertures comprising a plurality of repeat units are illustrated in FIGS. 17-21. Apertures are identified as 310 and land areas are identified as 314. Additional aperture patterns and configurations, including example methods of making are disclosed in U.S. Pat. Appl. Pub. No. 2016/0136014 to Arora et al.


Various suitable processes for aperturing the substrates or topsheets described herein may be utilized. For example, the apertures in the substrates or topsheets may be formed by hydroforming carded webs, laser cutting, punching with a patterned roll, hot pin methods, overbonding and ring rolling as disclosed in U.S. Pat. Appl. Publication No. US 2016/0136014, or other suitable methods. Additional aperturing processes that may be utilized are described in U.S. Pat. Nos. 9,023,261, 8,158,043, 8,241,543, and 8,679,391, for example.


Referring to FIGS. 20 and 21, an equity element 316 may be present in a central area of each repeat unit, or less than each repeat unit. The equity element 316 may be a heart, leaf, star, logo, brand identifier, or any other suitable element. The equity element 316 may have a defined space 318 surrounding it in at least a majority of the repeat units. The defined space 318 may be a land area without apertures. In certain patterned repeat units, it may be important to have this defined space 318 surrounding the equity element 316 to allow the equity element 316 to stand out to a viewer. The defined space 318 may be surrounded by a grid of apertures 320. The grid of apertures 320 may have apertures that are different or the same in size, shape, aspect ratio, and/or angle relative to the central longitudinal axis of a topsheet on an absorbent article compared to the aperture or apertures forming the equity element. The grid may form a diamond pattern. The grid may be formed of one or more rows of apertures.


Referring again to FIGS. 20 and 21, at least some of the apertures in one or more of the repeat units may be different in size and/or shape than other apertures in the one or more repeat units, excluding process tolerances. Further, at least some of the apertures in one or more repeat units may be the same in size and/or shape as other apertures in the one or more repeat units, excluding process tolerances. Each repeat unit, or some repeat units, may comprise a central region of one or more apertures 500 that is spaced apart from other apertures 502. Each repeat unit, or some repeat units, may comprise a central pattern of one or more apertures 504 that may be fully, or partially surrounded by an outer pattern of apertures 506.


Substantially Similar Repeat Units

Although, in some instances, the apertures in each repeat unit are generally designed to be the same, process variations may cause the repeat units to appear slightly different. Examples of repeat units that are substantially similar are illustrated in FIGS. 22 and 23. Referring to FIG. 22, a repeating pattern of apertures 400 comprising a plurality of repeat units 402, 404, and 406 are illustrated in a substrate 408. The apertures 400 in the repeat units 402 and 406 are the same, but at least one aperture 401 in the repeat unit 404 is slightly different from the apertures 400. This could be from process conditions were the aperture 401 did not fully form or rupture or from variations in a precursor material. Referring to FIG. 23, a repeating pattern of apertures 400′ comprising a plurality of repeat units 402′, 404′, and 406′ are illustrated in a substrate 408′. The apertures in the repeat units 402′ and 406 are the same, but at least one aperture 401′ is slightly different from the apertures 400′. This could be from process conditions were the aperture 401′ did not form or rupture or from variations in a precursor material. The repeat units 402, 404, and 406 may be considered substantially the same and, likewise, the repeat units 402′, 404′, and 406′ may be considered substantially the same. In other instances, various apertures of the repeat unit may be slightly angled relative to a central longitudinal axis or a central lateral axis and the repeat units may still be considered substantially the same. Also, the shapes and sizes of the various apertures in the various repeat units may be slightly different and the repeat units may still be considered substantially the same.


Aperture Aspect Ratio

The apertures of the repeating pattern of apertures comprising the plurality of repeat units may have an aspect ratio of greater than one, for example, greater than two, greater than 3, greater than 5, or greater than 10, but typically less than 15, according to the Aperture Test herein. The repeat units may comprise apertures having more than one aspect ratio, such as two or more distinct populations or having a substantially continuous distribution of aspect ratios having a slope greater than zero. Additionally, the repeat units may comprise apertures with more than two effective aperture areas, either as two or more distinct populations or as a distribution of aperture areas having a slope greater than zero. The Relative Standard Deviation of the aperture aspect ratios in the apertures of the repeating pattern of apertures comprising repeat units may be at least about 30%, at least about 40%, or at least about 45%.


Aperture Density

The apertures of the repeating pattern of apertures comprising the plurality of repeat units may have an Aperture Density, according to the Aperture Test herein, of at least about 150, at least about 175, at least about 200, or at least about 300, but less than 1,000, for example.


% Effective Open Area

The topsheets or substrates comprising the repeating pattern of apertures comprising the plurality of repeat units may have an Effective Open Area between about 3% to about 50%, about 5% to about 50%, about 5% to about 40%, about 5% to about 30%, about 5% to about 25%, about 5% to about 20%, or about 5% to about 15%, specifically reciting all 0.1% increments within the specified ranges and all ranges formed therein or thereby. All Effective Open Area percentages are determined using the Aperture Test described herein.


Effective Aperture Area

The topsheets or substrates comprising the repeating pattern of apertures comprising the plurality of repeat units may have apertures having an Effective Aperture Area in the range of about 0.3 mm2 to about 15 mm2, 0.3 mm2 to about 14 mm2, 0.4 mm2 to about 12 mm2, 0.3 mm2 to about 10 mm2, 0.5 mm2 to about 8 mm2, or 1.0 mm2 to about 8 mm2, specifically reciting all 0.05 mm2 increments within the specified ranges and all ranges formed therein or thereby. All Effective Aperture Areas are determined using the Aperture Test described herein. A plurality of the apertures in the repeating pattern of apertures comprising the plurality of repeat units may be different in Effective Aperture Areas. The Relative Standard Deviation of the Effective Aperture Areas in the repeating pattern of apertures comprising the plurality of repeat units may be at least about 50%, or at least about 55%, or at least about 60%, for example.


Repeat Unit Measurements

The various repeat units may have certain characteristics, such as repeat unit area (overall X-Y plane area of the repeat unit), repeat unit width, repeat unit length, for example. Absorbent articles comprising topsheets or substrates comprising a repeating pattern of apertures having a plurality of repeat units may have certain numbers of repeat units relative to the absorbent article's dimensions and/or total area. Those properties are discussed below.


Repeat Unit Area

All of or a majority of individual repeat units in a repeating pattern of apertures comprising a plurality of repeat units of a topsheet or substrate may have a repeat unit area in the range of about 200 mm2 to about 2,000 mm2, about 500 mm2 to about 1,750 mm2, about 900 mm2 to about 1500 mm2, about 730 mm2 to about 1,500 mm2, about 730 mm2 to about 1,300 mm2, about 700 mm2 to about 1,500 mm2, about 750 mm2 to about 1,500 mm2, about 1,000 mm2 to about 1,500 mm2, about 1,100 mm2 to about 1,400 mm2, about 1,150 mm2 to about 1,300 mm2, about 500 mm2 to about 1,300 mm2, about 600 mm2 to about 1,100 mm2, about 650 mm2 to about 1,100 mm2, about 700 mm2 to about 1,110 mm2, about 700 mm2 to about 1,000 mm2, about 750 mm2 to about 1000 mm2, about 725 mm2 to about 975 mm2, about 730 mm2 to about 750 mm2, about 785 mm2 to about 805 mm2, about 860 mm2 to about 880 mm2, about 940 mm2 to about 960 mm2, about 200 mm2 to about 600 mm2, or about 250 mm2 to about 600 mm2, specifically reciting all 0.1 mm2 increments within the specified ranges and all ranges formed therein or thereby. The repeat unit area may also be about 951 mm2. Repeat unit areas are measured according to the Repeat Unit Measurement Test herein.


Repeat Unit Width

All of or a majority of individual repeat units in a repeating pattern of apertures comprising a plurality of repeat units of a topsheet or substrate may have a repeat unit width in the range of about 10 mm to about 100 mm, about 25 mm to about 75 mm, about 30 mm to about 70 mm, about 35 mm to about 65 mm, about 45 mm to about 55 mm, about 35 mm to about 55 mm, about 40 mm to about 60 mm, about 45 mm to about 55 mm, about 50 mm, about 10 mm to about 50 mm, about 15 mm to about 50 mm, about 20 mm to about 50 mm, about 25 mm to about 50 mm, about 30 mm to about 45 mm, about 34 mm to about 42 mm, or about 35 mm to about 41 mm, about 34 mm to about 36 mm, about 36 mm to about 38 mm, about 40 mm to about 42 mm, specifically reciting all 0.1 mm increments within the specified ranges and all ranges formed therein or thereby. The repeat unit width may also be about 41 mm. Repeat unit widths are measured according to the Repeat Unit Measurement Test herein.


Repeat Unit Length

All of or a majority of individual repeats unit in a repeating pattern of apertures comprising a plurality of repeat units of a topsheet or substrate may have a repeat unit length in the range of about 10 mm to about 100 mm, about 25 mm to about 75 mm, about 35 mm to about 65 mm, about 35 mm to about 55 mm, about 35 to about 50, about 40 mm to about 60 mm, about 45 mm to about 55 mm, about 50 mm, about 51 mm, about 51.5 mm, about 15 mm to about 50 mm, about 20 mm to about 50 mm, about 25 mm to about 50 mm, about 30 mm to about 45 mm, about 34 mm to about 38 mm, about 35 mm to about 37 mm, about 40 mm to about 44 mm, about 41 mm to about 43 mm, specifically reciting all 0.1 mm increments within the specified ranges and all ranges formed therein or thereby. The repeat unit length may also be about 42 mm. Repeat unit lengths are measured according to the Repeat Unit Measurement Test herein.


Repeat Units Per Total Length of an Absorbent Article

An absorbent article may have a certain number of repeat units per the total length of the absorbent article in the range of about 3 to about 30, about 3 to about 25, about 4 to about 18, about 5 to about 16, about 5 to about 12, about 6 to about 16, about 6.1 to about 15.8, about 4 to about 20, about 5 to about 20, about 5 to about 18, about 6 to about 17, about 7 to about 16, about 7.5 to about 15.8, or about 7.5 to about 13.4, specifically reciting all 0.1 increments within the specified ranges and all ranges formed therein or thereby. Repeat units per total length of an absorbent article are measured according to the Repeat Unit Measurement Test herein.


Repeat Units Per Total Width of an Absorbent Article

An absorbent article may have a certain number of repeat units per total width of the absorbent article in the range of about 2 to about 10, about 2 to about 8, about 2 to about 7.5, about 2.5 to about 7, about 3 to about 7, about 3 to about 5, about 3 to about 6.5, about 3.2 to about 6.3, about 3.5 to about 6.5, about 4 to about 6.5, about 4 to about 6.3, or about 4 to about 5.4, specifically reciting all 0.1 increments within the specified ranges and all ranges formed therein or thereby. Repeat units per total width of an absorbent article are measured according to the Repeat Unit Measurement Test herein.


Repeat Units Per Total Area of an Absorbent Article

An absorbent article may have a certain number of repeat units per total area of an absorbent article in the range of about 20 to about 220, about 30 to about 220, about 30 to about 210, about 30 to about 200, about 35 to about 110, about 35 to about 200, about 30 to about 180, about 35 to about 180, about 35 to about 175, about 40 to about 170, about 41.7 to about 170, about 40 to about 190, about 45 to about 185, about 50 to about 175, about 53 to about 170, about 53.6 to about 169.7, or about 53.6 to about 132.3, specifically reciting all 0.1 increments within the specified ranges and all ranges formed therein or thereby. The repeat units per total area of an absorbent article are measured according to the Repeat Unit Measurement Test herein.









TABLE 1







Absorbent Article Dimensions
















S0
S1
S2
S3
S4
S5
S6
S7


Length (mm)
315
373
403
440
488
516
528
567


Width (mm)
162
206
206
206
206
222
222
222


Area (mm2)
51,030
76,838
83,018
90,640
100,528
114,552
117,216
125,874







Repeat Unit Dimensions
















Width
Length
Area








(mm)
(mm)
(mm2)







Pattern 1
35.2
36.4
792.8







Pattern 2
37.3
35.9
868.1







Pattern 3
40.9
42.2
951.2







Pattern 4
35.0
36.1
741.7







Pattern 5
50.0
51.5
1,225.0












Repeat Units/Total Absorbent Article Length
















S0
S1
S2
S3
S4
S5
S6
S7


Pattern 1
8.7
10.2
11.1
12.1
13.4
14.2
14.5
15.6


Pattern 2
8.8
10.4
11.2
12.3
13.6
14.4
14.7
15.8


Pattern 3
7.5
8.8
9.5
10.4
11.6
12.2
12.5
13.4


Pattern 4
8.7
10.3
11.2
12.2
13.5
14.3
14.6
15.7


Pattern 5
6.1
7.2
7.8
8.5
9.5
10.0
10.3
11.0







Repeat Units/Total Absorbent Article Width
















S0
S1
S2
S3
S4
S5
S6
S7


Pattern 1
4.6
5.9
5.9
5.9
5.9
6.3
6.3
6.3


Pattern 2
4.3
5.5
5.5
5.5
5.5
6.0
6.0
6.0


Pattern 3
4.0
5.0
5.0
5.0
5.0
5.4
5.4
5.4


Pattern 4
4.6
5.9
5.9
5.9
5.9
6.3
6.3
6.3


Pattern 5
3.2
4.1
4.1
4.1
4.1
4.4
4.4
4.4







Repeat Units/Total Absorbent Article Area
















S0
S1
S2
S3
S4
S5
S6
S7


Pattern 1
64.4
96.9
104.7
114.3
126.8
144.5
147.9
158.8


Pattern 2
58.8
88.5
95.6
104.4
115.8
132.0
135.0
145.0


Pattern 3
53.6
80.8
87.3
95.3
105.7
120.4
123.2
132.3


Pattern 4
68.8
103.6
111.9
122.2
135.5
154.4
158.0
169.7


Pattern 5
41.7
62.7
67.8
74.0
82.1
93.5
95.7
102.8









The above discussed repeat unit measurements were tested for various absorbent article sizes and for sample repeating patterns of apertures comprising a plurality of repeat units as the topsheet of the absorbent articles as illustrated below. All testing was in accordance with the Repeat Unit Measurement Test herein. “S” in Table 1 below means size of an absorbent article as they are made commercially, although the present disclosure also includes adult incontinence sizes and preemie sizes of absorbent articles.


Embossing

As an alternative execution, a substrate or a topsheet may comprise a repeating pattern of embossments comprising a plurality of repeat units formed by embossing instead of using apertures. The embossments/repeat units formed by embossing may have the same measurements as expressed above with respect to the repeating patterns of apertures comprising the plurality of repeat units and may be measured using the Repeat Unit Measurement Test. As a further execution, a top sheet or a substrate may comprise a repeating pattern comprising the plurality of repeat units formed of embossments and apertures, while still retaining the same measurements expressed above with respect to the repeating patterns of apertures comprising the plurality of repeat units.


Zones of Repeat Units

In some instances, zones of repeat units may be present in topsheets or substrates of absorbent articles. The zones may be suitably positioned for urine, BM, or menses acquisition. The repeat units in the various zones may all be the same or may be different between the various zones.


As an example, an absorbent article may have a central lateral axis. A first repeating pattern of apertures comprising a first plurality of the same first repeat units may be on a first side of the central lateral axis. A second, different repeating pattern of apertures comprising a second plurality of the same second repeat units may be on a second side of the central lateral axis. The first and second repeat units may be different in aperture size, aperture shape, aperture aspect ratio, repeat unit area, aperture pattern, repeat unit width, and/or repeat unit length. In an instance, the pattern of the first repeat units on the first side of the central lateral axis may be the same as a second pattern of the second repeat units on the second side of the central lateral axis. In such an instance, the patterns may have the same aesthetic appearance, but may be different scales (e.g., repeat unit areas on one side of the lateral axis are smaller). In other instances, the aesthetic appearance of the first repeat units may be different than the second repeat units.


A similar concept may apply to zones that are on a first side of central longitudinal axis and a second side of the central longitudinal axis. Alternatively, a first zone may be surrounded by a second zone. In some instances, more than two, or more than three zones may be provided. Any of the various zones may have any suitable size and shape.


Materials

Some topsheets or substrates of the present disclosure may comprise PE/PP bicomponent fiber spunbond webs. Other suitable webs may comprise spunbond webs comprising side-by-side crimped fibers (e.g., PE/PP or PP/PP) that are bonded via calendar (thermal point) bonding or through-air bonding. Other suitable webs may comprise carded, through-air bonded or resin bonded (highloft) nonwovens comprising PE/PP or PE/PET fibers. The webs may comprise nanofibers, optionally with other fibers. In some instances, multiple layer webs may be desired over a single layer webs (even at the same basis weight) due to increased uniformity/opacity and the ability to combine webs having different properties. For example, an extensible spunbond nonwoven carrier layer may be combined with a soft, highloft nonwoven (spunbond or carded) to create an apertured web that is both soft and strong. The layers may have the same or different surface energy. For example, a top layer of a topsheet or substrate may be hydrophobic and the lower layer may be hydrophilic. The layers may have different permeability/capillarity, e.g. the upper layer may have higher permeability and the lower layer have higher capillarity in order to set up a capillary gradient and aid in moving fluid away from the surface (or topsheet) of an absorbent article and into an absorbent core of the absorbent article.


Fibers of the topsheet and substrate webs may comprise any suitable thermoplastic polymers. Example thermoplastic polymers are polymers that melt and then, upon cooling, crystallize or harden, but that may be re-melted upon further heating.


The thermoplastic polymers may be derived from any suitable material including renewable resources (including bio-based and recycled materials), fossil minerals and oils, and/or biodegradable materials. Some suitable examples of thermoplastic polymers include polyolefins, polyesters, polyamides, copolymers thereof, and combinations thereof. Polypropylene and/or polypropylene copolymers, including atactic polypropylene; isotactic polypropylene, syndiotactic polypropylene, and combination thereof may also be used.


The thermoplastic polymer component may be a single polymer species or a blend of two or more thermoplastic polymers e.g., two different polypropylene resins. As an example, fibers of a first nonwoven layer of a topsheet or substrate web may comprise polymers such as polypropylene and blends of polypropylene and polyethylene, while a second nonwoven layer of the topsheet or substrate web may comprise fibers selected from polypropylene, polypropylene/polyethylene blends, and polyethylene/polyethylene terephthalate blends. In some forms, a second nonwoven layer may comprise fibers selected from cellulose rayon, cotton, other hydrophilic fiber materials, or combinations thereof. The fibers may also comprise a super absorbent material such as polyacrylate or any combination of suitable materials.


The fibers of the topsheet or substrate webs may comprise monocomponent fibers, bi-component fibers, and/or bi-constituent fibers, round fibers or non-round fibers (e.g., capillary channel fibers), and may have major cross-sectional dimensions (e.g., diameter for round fibers) ranging from about 0.1 microns to about 500 microns. The fibers may also be a mixture of different fiber types, differing in such features as chemistry (e.g. polyethylene and polypropylene), components (mono- and bi-), denier (micro denier and >2 denier), shape (i.e. capillary and round) and the like. The fibers may range from about 0.1 denier to about 100 denier.


As used herein, the term “monocomponent fiber(s)” refers to a fiber formed from one extruder using one or more polymers. This is not meant to exclude fibers formed from one polymer to which small amounts of additives have been added for coloration, antistatic properties, lubrication, hydrophilicity, etc.


As used herein, the term “bi-component fiber(s)” refers to fibers which have been formed from at least two different polymers extruded from separate extruders but spun together to form one fiber. Bi-component fibers are also sometimes referred to as conjugate fibers or multicomponent fibers. The polymers are arranged in substantially constantly positioned distinct zones across the cross-section of the bi-component fibers and extend continuously along the length of the bi-component fibers. The configuration of such a bi-component fiber may be, for example, a sheath/core arrangement wherein one polymer is surrounded by another, or may be a side-by-side arrangement, a pie arrangement, or an “islands-in-the-sea” arrangement. Some specific examples of fibers which may be used in the first nonwoven layer include polyethylene/polypropylene side-by-side bi-component fibers. Another example is a polypropylene/polyethylene bi-component fiber where the polyethylene is configured as a sheath and the polypropylene is configured as a core within the sheath. Still another example is a polypropylene/polypropylene bi-component fiber where two different propylene polymers are configured in a side-by-side configuration. Additionally, forms are contemplated where the fibers of a nonwoven layer are crimped.


Bi-component fibers may comprise two different resins, e.g. a first polypropylene resin and a second polypropylene resin. The resins may have different melt flow rates, molecular weights, or molecular weight distributions.


As used herein, the term “bi-constituent fiber(s)” refers to fibers which have been formed from at least two polymers extruded from the same extruder as a blend. Bi-constituent fibers do not have the various polymer components arranged in relatively constantly positioned distinct zones across the cross-sectional area of the fiber and the various polymers are usually not continuous along the entire length of the fiber, instead usually forming fibrils which start and end at random. Bi-constituent fibers are sometimes also referred to as multi-constituent fibers. In other examples, a bi-component fiber may comprise multiconstituent components.


As used herein, the term “non-round fiber(s)” describes fibers having a non-round cross-section, and includes “shaped fibers” and “capillary channel fibers.” Such fibers may be solid or hollow, and they may be tri-lobal, delta-shaped, and may be fibers having capillary channels on their outer surfaces. The capillary channels may be of various cross-sectional shapes such as “U-shaped”, “H-shaped”, “C-shaped” and “V-shaped”. One practical capillary channel fiber is T-401, designated as 4DG fiber available from Fiber Innovation Technologies, Johnson City, Tenn. T-401 fiber is a polyethylene terephthalate (PET polyester).


Other example nonwoven materials for the topsheet or substrate webs may comprise spunbond materials, carded materials, melt blown materials, spunlace materials, needle punched materials, wet-laid materials, or air-laid materials, for example.


Repeat Unit Measurement Test

An absorbent article specimen is taped to a rigid flat surface in a planar configuration with a topsheet having a repeating pattern of apertures comprising a plurality of single repeat units facing upward. The article is taped in such way as to avoid introducing distortions of the repeating pattern of apertures due to the extent of longitudinal and lateral extension of the absorbent article. Any absorbent article(s) being tested are conditioned at 23° C.±2° C. and 50%±2% relative humidity for 2 hours prior to testing. For the purposes of this method, all patterns and distances are taken to be based on the projection of the aperture pattern onto a two-dimensional plane.


A single repeat unit (hereafter “SRU”) (for subsequent dimensional measurement) within the topsheet having the repeating pattern of apertures comprising the plurality of repeating units is defined as follows. An arbitrary aperture is identified, referred to hereafter as the “chosen aperture” (hereafter “CA”). Any other aperture in the topsheet recognized to be in an equivalent position based on the translational symmetry of the repeat units is referred to as an “equivalent aperture” (hereafter “EA”). The SRU is defined as the set of points that are closer (via Euclidean distance) to the center of the CA than to the center of any other EA in the topsheet. The SRU identified for measurement must not touch the edge of the topsheet. After finding all points within the SRU, if it is found that the SRU touches the edge of the topsheet, this procedure is repeated with an alternative CA. The process is repeated until a SRU that does not touch the edge of the topsheet is identified.


One approach to determining the set of points of a SRU is based on identifying a polygonal boundary. Referring to FIG. 24, the boundary of the SRU is the convex polygon formed by the intersection of line segments that immediately border the topsheet region containing the CA. The line segments are identified from lines drawn perpendicular to the midpoint of lines connecting the center of the CA to the center of all neighboring and nearby EA.


Referring to FIG. 25, the SRU length (L) is defined as the feret diameter parallel to the longitudinal axis of the absorbent article, and the SRU width (W) is defined as the feret diameter parallel to the lateral axis of the absorbent article. The feret diameter is the distance between two parallel lines, both of which are tangential to the boundary of the SRU, and is recorded to the nearest 0.1 mm.


The interior area of the SRU is recorded to the nearest 0.1 mm2.


Referring to FIG. 26, the total lateral width of the absorbent article is measured along the central lateral axis (line X), and is recorded to the nearest 0.1 mm. The total longitudinal length of the absorbent article is measured along the central longitudinal axis (line Y), and is recorded to the nearest 0.1 mm. The total area of the absorbent article is calculated by multiplying the total absorbent article width by the total absorbent article length, and is recorded to the nearest 0.1 mm2.


The number of SRU's per length of the absorbent article is calculated by dividing the total absorbent article longitudinal length by the SRU length and is recorded to the nearest 0.1 SRU's. The number of SRU's per width of the absorbent article is calculated by dividing the total absorbent article lateral width by the SRU width and is recorded to the nearest 0.1 SRU's. The number of SRU's per total area of the absorbent article is calculated by dividing the total absorbent article area (total absorbent article longitudinal length x total absorbent article lateral width) by the SRU area and is recorded to the nearest 0.1 SRU's.


Repeat this procedure on five separate substantially similar absorbent articles having topsheets with a repeating pattern of apertures comprising a plurality repeat units that are the same or substantially the same, and report each of the measurements as the average of the five replicates.


Aperture Test

Aperture dimensions, Effective Aperture Area, % Effective Open Area, among other measurements, are obtained from specimen images acquired using a flatbed scanner. The scanner is capable of scanning in reflectance mode at a resolution of 6400 dpi and 8 bit grayscale (a suitable scanner is an Epson Perfection V750 Pro from Epson America Inc., Long Beach Calif. or equivalent). The scanner is interfaced with a computer running an image analysis program (a suitable program is ImageJ v. 1.47 or equivalent, National Institute of Health, USA). The specimen images are distance calibrated against an acquired image of a ruler certified by NIST. A steel frame is used to mount the specimen, which is then backed with a black glass tile (P/N 11-0050-30, available from HunterLab, Reston, Va.) prior to acquiring the specimen image. The resulting image is then thresheld, separating open aperture regions from specimen material regions, and analyzed using the image analysis program. All testing is performed in a conditioned room maintained at about 23±2° C. and about 50±2% relative humidity.


Sample Preparation

To obtain a specimen, tape an absorbent article to a rigid flat surface in a planar configuration. Any leg elastics may be cut to facilitate laying the article flat. A rectilinear steel frame (100 mm square, 1.5 mm thick with an opening 60 mm square) is used to mount the specimen. Take the steel frame and place double-sided adhesive tape on the bottom surface surrounding the interior opening. Remove the release paper of the tape, and adhere the steel frame to the apertured layer of the article. Align the frame so that it is parallel and perpendicular to a machine direction (MD) and a cross direction (CD) of the apertured layer. Using a razor blade excise the apertured layer from the underlying layers of the article around the outer perimeter of the frame. Carefully remove the specimen such that its longitudinal and lateral extension is maintained to avoid distortion of the apertures. A cryogenic spray (such as Cyto-Freeze, Control Company, Houston Tex.) may be used to remove the specimen from the underlying layers if necessary. Five replicates obtained from five substantially similar articles are prepared for analysis. If the apertured layer of interest is too small to accommodate the steel frame, reduce the frame dimensions accordingly to accomplish the goals of removal of the specimen without distortion of the apertures while leaving an opening of sufficient size to allow for scanning a significant portion of the apertured layer. An apertured or patterned apertured substrate raw material is prepared for testing by extending or activating it under the same process conditions, and to the same extent, as it would be for use on the absorbent article, and then in its extended state adhering it to the steel frame as described above for testing. Condition the samples at about 23° C. ±2° C. and about 50%±2% relative humidity for 2 hours prior to testing.


Image Acquisition

Place the ruler on the scanner bed, oriented parallel to sides of the scanner glass, and close the lid. Acquire a calibration image of the ruler in reflectance mode at a resolution of 6400 dpi (approximately 252 pixels per mm) and 8 bit grayscale, with the field of view corresponding to the dimensions of an interior of the steel frame. Save the calibration image as an uncompressed TIFF format file. Lift the lid and remove the ruler. After obtaining the calibration image, all specimens are scanned under the same conditions and measured based on the same calibration file. Next, place the framed specimen onto the center of the scanner bed, lying flat, with the outward facing surface of the specimen facing the scanner's glass surface. Orient the specimen so that sides of the frame are aligned parallel with and perpendicular to the sides of the scanner's glass surface, so that the resulting specimen image will have the MD vertically running from top to bottom. Place the black glass tile on top of the frame covering the specimen, close the lid and acquire a scanned image. Scan the remaining four replicates in like fashion. If necessary, crop all images to a rectangular field of view circumscribing the apertured region, and resave the files.


% Effective Open Area Calculation

Open the calibration image file in the image analysis program and perform a linear distance calibration using the imaged ruler. This distance calibration scale will be applied to all subsequent specimen images prior to analysis. The 8-bit grayscale image is then converted to a binary image in the following way: If the histogram of gray level (GL) values (ranging from 0 to 255, one bin with propensity Pi per gray level i) has exactly two local maxima, the threshold gray level value t is defined as that value for which Pt−1>Pt and Pt≤Pt+1. If the histogram has greater than two local maxima, the histogram is iteratively smoothed using a windowed arithmetic mean of size 3, and this smoothing is performed iteratively until exactly two local maxima exist. The threshold gray level value t is defined as that value for which Pt−1>Pt and Pt≤Pt+1. This procedure identifies the gray level (GL) value for the minimum population located between the dark pixel peak of the aperture holes and the lighter pixel peak of the specimen material. If the histogram contains either zero or one local maximum, the method cannot proceed further, and no output parameters are defined. Threshold the image at the minimum gray level value to generate a binary image. In the binary image the apertures appear as black, with a GL value of 255, and specimen as white, with a GL value of 0.


Using the image analysis program, analyze each of the discrete aperture regions. Measure and record all of the individual aperture areas to the nearest 0.01 mm2, including partial apertures along the edges of the image. Discard any apertures with an area less than 0.3 mm2 as “non-effective”. Sum the remaining “effective” aperture areas (including whole and partial apertures), divide by the total area included in the image and multiply by 100. Record this value as the % effective open area to the nearest 0.01%.


In like fashion, analyze the remaining four specimen images. Calculate and report the average % effective open area values to the nearest 0.01% for the five replicates.


Effective Aperture Dimension Measurements

Open the calibration image (containing the ruler) file in the image analysis program. Resize the resolution of the original image from 6400 dpi to 640 dpi (approximately 25.2 pixels per mm) using a bicubic interpolation. Perform a linear distance calibration using the imaged ruler. This distance calibration scale will be applied to all subsequent specimen images prior to analysis. Open a specimen image in the image analysis program. Resize the resolution of the original image from 6400 dpi to 640 dpi (approximately 25.2 pixels per mm) using a bicubic interpolation. A distance scale is set according to the linear distance calibration established using the calibration image. The 8-bit grayscale image is then converted to a binary image in the following way: If the histogram of gray level (GL) values (ranging from 0 to 255, one bin with propensity Pi per gray level i) has exactly two local maxima, the threshold gray level value t is defined as that value for which Pt−1>Pt and Pt≤Pt+1. If the histogram has greater than two local maxima, the histogram is iteratively smoothed using a windowed arithmetic mean of size 3, and this smoothing is performed iteratively until exactly two local maxima exist. The threshold gray level value t is defined as that value for which Pt−1>Pt and Pt≤Pt+1. This procedure identifies the gray level (GL) value for the minimum population located between the dark pixel peak of the aperture holes and the lighter pixel peak of the specimen material. If the histogram contains either zero or one local maximum, the method cannot proceed further, and no output parameters are defined. Threshold the image at the minimum gray level value to generate a binary image. In the binary image, the apertures appear as black, with a GL value of 255, and specimen as white, with a GL value of 0. Next, two morphological operations are then performed on the binary image. First, a closing (a dilation operation, which converts any white background pixel that is touching, 8-connected, a black aperture region pixel into a black aperture region pixel thereby adding a layer of pixels around the periphery of the aperture region, followed by an erosion operation, which removes any black aperture region pixel that is touching, 8-connected, a white background pixel thereby removing a layer of pixels around the periphery of the aperture region, iterations=1, pixel count=1), which removes stray fibers within an aperture hole. Second, an opening (an erosion operation followed by a dilation operation, iterations=1, pixel count=1), which removes isolated black pixels. Pad the edges of the image during the erosion step to ensure that black boundary pixels are maintained during the operation. Lastly, fill any remaining voids enclosed within the black aperture regions.


Using the image analysis program, analyze each of the discrete aperture regions. During the analysis exclude measurements of partial apertures along the edges of the image, so that only whole apertures are measured. Measure and record all of the individual effective aperture areas, perimeters, feret diameters (length of the apertures) along with its corresponding angle of orientation in degrees from 0 to 180, and minimum feret diameters (width of the apertures). Record the measurements for each of the individual elements areas to the nearest 0.01 mm2, the perimeters and feret diameters (length and width), to the nearest 0.01 mm, and angles to the nearest 0.01 degree. Discard any apertures with an area less than 0.3 mm2 as “non-effective”. Record the number of remaining apertures, divide by the area of the image, and record as the Aperture Density value. The angle of orientation for an aperture aligned with the MD (vertical in the image) will have an angle of 90 degrees. Apertures with a positive slope, increasing from left to right, will have an angle between zero and 90 degrees. Apertures with a negative slope, decreasing from left to right, will have an angle between 90 and 180 degrees. Using the individual aperture angles calculate an Absolute Feret Angle by subtracting 90 degrees from the original angle of orientation and taking its absolute value. In addition to these measurements, calculate an Aspect Ratio value for each individual aperture by dividing the aperture length by its width. Repeat this analysis for each of the remaining four replicate images. Calculate and report the statistical mean and standard deviation for each of the effective aperture dimension, the Absolute Feret Angle, and the Aspect Ratio measurements using all of the aperture values recorded from the replicates. Record the average of the individual Absolute Feret Angle measurements as the Average Absolute Feret Angle value. Calculate and report the % relative standard deviation (RSD) for each of the aperture dimension, the Absolute Feret Angle, and the Aspect Ratio measurements by dividing the standard deviation by the mean and multiplying by 100.


The dimensions and values disclosed herein are not to be understood as being strictly limited to the exact numerical values recited. Instead, unless otherwise specified, each such dimension is intended to mean both the recited value and a functionally equivalent range surrounding that value. For example, a dimension disclosed as “40 mm” is intended to mean “about 40 mm.”


Every document cited herein, including any cross referenced or related patent or application, is hereby incorporated herein by reference in its entirety unless expressly excluded or otherwise limited. The citation of any document is not an admission that it is prior art with respect to any embodiment disclosed or claimed herein or that it alone, or in any combination with any other reference or references, teaches, suggests or discloses any such embodiment. Further, to the extent that any meaning or definition of a term in this document conflicts with any meaning or definition of the same term in a document incorporated by reference, the meaning or definition assigned to that term in this document shall govern.


While particular embodiments of the present disclosure have been illustrated and described, it would be obvious to those skilled in the art that various other changes and modifications may be made without departing from the spirit and scope of the present disclosure. It is therefore intended to cover in the appended claims all such changes and modifications that are within the scope of this disclosure.

Claims
  • 1. An absorbent article comprising: a central lateral axis;a central longitudinal axis extending perpendicular to the central lateral axis;a topsheet that is liquid permeable, apertured, and nonwoven;a backsheet that is liquid impermeable; andan absorbent core disposed at least partially intermediate the topsheet and the backsheet;the absorbent article having a length along the central longitudinal axis;the absorbent article having a width along the central lateral axis;wherein the topsheet comprises a grid of apertures formed by a first plurality of rows of apertures extending in a first direction and a second plurality of rows extending in a second direction, wherein the rows of apertures of the first and second plurality of rows are uniformly spaced, the grid of apertures comprising repeat units, with each repeat unit being defined between (i) centerlines of two adjacent rows of the first plurality of rows, and (ii) centerlines of two adjacent rows of the second plurality of rows that intersect respective ones of the centerlines of the two adjacent rows of the first plurality of rows, wherein the intersections of the centerlines of rows of the first plurality of rows and the centerlines of rows of the second plurality of rows do not comprise an aperture;wherein each aperture of the first and second plurality of rows comprises a major axis and a minor axis shorter than the major axis, the major axis of all apertures in the first plurality of rows having a first orientation and the major axis of all apertures in the second plurality of rows having a second orientation that is different from the first orientation;wherein each of the repeat units is substantially the same, and each of the repeat units comprises a central region comprising first apertures and a defined space between the central region and bordering apertures of the adjacent rows of apertures, and wherein the first apertures in each central region are positioned to form a shape of an equity element; andwherein the repeat units repeat at least along the width of the absorbent article;wherein the repeat units have a repeat unit length defined between adjacent intersections of the centerlines of the first and second plurality of rows parallel to the central longitudinal axis of the absorbent article, a repeat unit width defined between adjacent intersections of the centerlines of the first and second plurality of rows parallel to the central lateral axis of the absorbent article, and a repeat unit area in a range of about 730 mm2 to 1,400 mm2.
  • 2. The absorbent article of claim 1, wherein the repeat unit width of at least a majority of the repeat units is in the range of about 30 mm to about 70 mm.
  • 3. The absorbent article of claim 1, wherein the repeat unit length of at least a majority of the repeat units is in the range of about 30 mm to about 70 mm.
  • 4. The absorbent article of claim 1, wherein the repeat unit area is in the range of about 730 mm2 to about 1,300 mm2.
  • 5. The absorbent article of claim 1, wherein the repeat units repeat along the width of the absorbent article between about 3 and about 7 times and repeat along the length of the absorbent article between about 4 to about 18 times.
  • 6. The absorbent article of claim 1, wherein a first zone of the topsheet comprises a first subset of the repeat units, and a second zone of the topsheet comprises a second subset of the repeat units, wherein the first subset differs from the second subset in a least one of aperture size, aperture shape, aperture aspect ratio, or aperture pattern.
  • 7. The absorbent article of claim 1, wherein a quantity of the repeat units of the absorbent article is between about 30 to about 180.
  • 8. The absorbent article of claim 1, wherein the repeat units repeat along the width of the absorbent article between about 3 and about 5 times and repeat along the length of the article between about 5 and about 12 times, and wherein a total number of repeat units is between about 35 to about 180, and wherein at least a majority of the repeat units have a repeat unit area in a range of about 1,100 mm2 to about 1,400 mm2.
  • 9. The absorbent article of claim 1, wherein the equity element is one of a heart, a leaf, a star, a logo, or a brand identifier.
  • 10. The absorbent article of claim 9, wherein the shape of the equity element is not the same as the shape defined by the bordering apertures.
  • 11. The absorbent article of claim 1, wherein at least some of the apertures comprise melt lips on portions of perimeters of the at least some of the apertures.
  • 12. The absorbent article of claim 1, wherein at least some of the apertures are free of melt lips on perimeters of the at least some of the apertures.
  • 13. The absorbent article of claim 1, wherein at least some of the apertures in one or more of the repeat units are different in aperture size or aperture shape than other apertures in the one or more repeat units.
  • 14. The absorbent article of claim 1, wherein at least some of the apertures in one or more of the repeat units are the same in aperture size and aperture shape as other apertures in the one or more repeat units.
  • 15. The absorbent article of claim 1, wherein the central region is at least partially, or fully surrounded by the outer region.
  • 16. The absorbent article of claim 1, wherein the topsheet is multilayered comprising a first layer on a wearer-facing surface of the absorbent article and a second layer disposed between the first layer and the absorbent core.
  • 17. The absorbent article of claim 16, wherein the first layer is hydrophobic, and wherein the second layer is hydrophilic.
  • 18. The absorbent article of claim 16, wherein at least one of the first layer or the second layer comprises spunbond fibers.
  • 19. The absorbent article of claim 16, wherein the first layer comprises spunbond fibers or carded fibers, and wherein the second layer comprises the spunbond fibers or the carded fibers.
  • 20. The absorbent article of claim 1, wherein the topsheet comprises at least one of a whitening additive or an opacifying additive.
CROSS REFERENCE TO RELATED APPLICATIONS

This application is a continuation of, and claims priority under 35 U.S.C. § 120 to, U.S. patent application Ser. No. 15/897,184, filed on Feb. 15, 2018, which claims the benefit, under 35 U.S.C. § 119(e), of U.S. Provisional Patent Application Ser. No. 62/459,765, filed on Feb. 16, 2017, the entire disclosures of which are fully incorporated by reference herein.

US Referenced Citations (524)
Number Name Date Kind
D116633 Rubner Sep 1939 S
3137893 Gelpke Jun 1964 A
3559648 Mason, Jr. Feb 1971 A
3655501 Tesch Apr 1972 A
3673026 Brown Jun 1972 A
3814101 Kozak Jun 1974 A
3849845 Obenaus Nov 1974 A
3860003 Buell Jan 1975 A
3886941 Duane et al. Jun 1975 A
3890974 Kozak Jun 1975 A
D237114 Fröidh et al. Oct 1975 S
3911173 Sprague, Jr. Oct 1975 A
3929135 Thompson Dec 1975 A
D238449 Matsumoto Jan 1976 S
D239137 Appleman Mar 1976 S
D240563 Whitehead et al. Jul 1976 S
D240564 Whitehead et al. Jul 1976 S
D247368 Whitehead Feb 1978 S
D247371 Whitehead Feb 1978 S
4137180 Naik et al. Jan 1979 A
4199464 Cambre Apr 1980 A
D259219 Bates May 1981 S
4306559 Nishizawa et al. Dec 1981 A
4323069 Ahr et al. Apr 1982 A
4324246 Mullane et al. Apr 1982 A
4327730 Sorensen May 1982 A
D276184 Whitehead Oct 1984 S
D276368 Whitehead Nov 1984 S
4573986 Minetola et al. Mar 1986 A
4588630 Shimalla May 1986 A
4609518 Curro et al. Sep 1986 A
4610678 Goldman et al. Sep 1986 A
4623340 Luceri Nov 1986 A
4629643 Curro et al. Dec 1986 A
D287637 Grasso Jan 1987 S
4637819 Ouellette et al. Jan 1987 A
4673402 Weisman et al. Jun 1987 A
4676784 Erdman et al. Jun 1987 A
4704112 Suzuki et al. Nov 1987 A
4741941 Englebert et al. May 1988 A
4780352 Palumbo et al. Oct 1988 A
4781710 Megison et al. Nov 1988 A
4785996 Ziecker et al. Nov 1988 A
4798604 Carter Jan 1989 A
4818587 Ejima et al. Apr 1989 A
4834735 Alemany et al. May 1989 A
4840829 Suzuki et al. Jun 1989 A
4842666 Werenicz Jun 1989 A
4844965 Foxman Jul 1989 A
4888231 Angstadt Dec 1989 A
4908026 Sukiennik Mar 1990 A
4950264 Osborn, III Aug 1990 A
5108820 Kaneko et al. Apr 1992 A
5122407 Yeo et al. Jun 1992 A
5147345 Young et al. Sep 1992 A
5151092 Buell et al. Sep 1992 A
5226992 Morman Jul 1993 A
5234423 Alemany et al. Aug 1993 A
5296622 Uphues et al. Mar 1994 A
D349159 Huffman Jul 1994 S
D350196 Huffman Aug 1994 S
D350197 Huffman Aug 1994 S
H1377 Perry Nov 1994 H
5369858 Gilmore et al. Dec 1994 A
5370764 Alikhan Dec 1994 A
D354856 Schulz Jan 1995 S
5382773 Kurihara et al. Jan 1995 A
5415640 Kirby et al. May 1995 A
5418045 Pike et al. May 1995 A
5433715 Tanzer et al. Jul 1995 A
5437653 Gilman et al. Aug 1995 A
D362120 Suskind et al. Sep 1995 S
D363610 Saffran Oct 1995 S
5456982 Hansen et al. Oct 1995 A
5485662 Hodges, Jr. et al. Jan 1996 A
D367764 Makoui Mar 1996 S
D368587 Schulz Apr 1996 S
5503076 Yeo Apr 1996 A
5518801 Chappell et al. May 1996 A
5520673 Yarbrough et al. May 1996 A
5536555 Zelazoski et al. Jul 1996 A
5571096 Dobrin et al. Nov 1996 A
5573830 Schulz Nov 1996 A
D377419 Schulz Jan 1997 S
5597645 Pike et al. Jan 1997 A
5599335 Goldman et al. Feb 1997 A
5605749 Pike et al. Feb 1997 A
5607760 Roe Mar 1997 A
5609587 Roe Mar 1997 A
5628097 Benson et al. May 1997 A
5628737 Dobrin et al. May 1997 A
5635191 Roe et al. Jun 1997 A
5643588 Roe et al. Jul 1997 A
D382162 Ertolacci Aug 1997 S
D382713 Giesler, Sr. Aug 1997 S
5660788 Gray et al. Aug 1997 A
D384210 du Grosriez Sep 1997 S
5665083 Igaue et al. Sep 1997 A
5667562 Midkiff Sep 1997 A
5667619 Alikhan Sep 1997 A
5704101 Majors et al. Jan 1998 A
5709735 Midkiff et al. Jan 1998 A
5714107 Levy et al. Feb 1998 A
5718698 Dobrin et al. Feb 1998 A
5731061 Bezier Mar 1998 A
5735984 Hoff et al. Apr 1998 A
H1732 Johnson Jun 1998 H
5759990 Wahl et al. Jun 1998 A
5770144 James et al. Jun 1998 A
D395955 du Grosriez Jul 1998 S
5780155 Ishizawa et al. Jul 1998 A
5797894 Cadieux et al. Aug 1998 A
5804021 Abuto et al. Sep 1998 A
5824352 Yang et al. Oct 1998 A
D402475 Mattheeussen Dec 1998 S
5846230 Osborn, III et al. Dec 1998 A
5873968 Pike et al. Feb 1999 A
5874160 Keck Feb 1999 A
D406791 Schulz Mar 1999 S
5885267 Mishima et al. Mar 1999 A
D407902 Schulz Apr 1999 S
D408152 Wilhelm Apr 1999 S
5895380 Turi et al. Apr 1999 A
5897541 Uitenbroek et al. Apr 1999 A
5897543 Francis Apr 1999 A
5914084 Benson et al. Jun 1999 A
5916661 Benson et al. Jun 1999 A
5919177 Georger et al. Jul 1999 A
D412574 Trombetta Aug 1999 S
D412575 Trombetta Aug 1999 S
D412980 Trombetta Aug 1999 S
D412981 Trombetta Aug 1999 S
5941864 Roe Aug 1999 A
5965468 Marmon et al. Oct 1999 A
5968025 Roe et al. Oct 1999 A
5990376 Inoue et al. Nov 1999 A
5998696 Schone Dec 1999 A
6015936 Takai et al. Jan 2000 A
6025535 Octavio Feb 2000 A
6030372 Buell et al. Feb 2000 A
D421341 Bak Mar 2000 S
D426303 Weyenberg Jun 2000 S
D426709 Latchoo Jun 2000 S
D426887 Rubio Jun 2000 S
D426889 Bissah Jun 2000 S
6093871 Takai et al. Jul 2000 A
D429893 Jahner Aug 2000 S
D430406 Ingalls Sep 2000 S
D430407 Ingalls Sep 2000 S
D430665 Kirkbride Sep 2000 S
6114595 Moore et al. Sep 2000 A
6117523 Sugahara Sep 2000 A
6117524 Hisanaka et al. Sep 2000 A
6120488 VanRijswijck Sep 2000 A
6129972 McNeil Oct 2000 A
D433572 Bissah Nov 2000 S
D434568 Bissah Dec 2000 S
D434849 Kirkbride Dec 2000 S
6159881 Datta et al. Dec 2000 A
6168849 Braverman et al. Jan 2001 B1
D439057 Bissah et al. Mar 2001 S
D439660 Velazquez Mar 2001 S
D439661 Velazquez Mar 2001 S
6203905 Pike Mar 2001 B1
6206865 Chen et al. Mar 2001 B1
6228462 Lee et al. May 2001 B1
6231555 Lynard May 2001 B1
6261666 Enderby Jul 2001 B1
6262331 Nakahata et al. Jul 2001 B1
6270623 Goda et al. Aug 2001 B1
6271192 Verstrat et al. Aug 2001 B1
6274218 Shimizu Aug 2001 B1
6274237 Nakajima et al. Aug 2001 B1
D448078 Deoliveira Sep 2001 S
D448478 Deoliveira Sep 2001 S
6303208 Pelkie Oct 2001 B1
D451682 Jahner Dec 2001 S
6326430 Berte Dec 2001 B1
6344111 Wilhelm Feb 2002 B1
6348541 Kanda et al. Feb 2002 B1
6361781 Lorant Mar 2002 B2
6376456 Murphy et al. Apr 2002 B1
6410823 Daley et al. Jun 2002 B1
6413920 Bettiol et al. Jul 2002 B1
6452064 Thoren et al. Sep 2002 B1
6454747 Shimada et al. Sep 2002 B1
6454989 Neely et al. Sep 2002 B1
6464831 Trokhan Oct 2002 B1
6468626 Takai et al. Oct 2002 B1
6475600 Morman et al. Nov 2002 B1
6479130 Takai et al. Nov 2002 B1
6494920 Weuthen et al. Dec 2002 B1
6498284 Roe Dec 2002 B1
6506473 Hisanaka et al. Jan 2003 B1
6528439 Stokes et al. Mar 2003 B1
6534149 Daley et al. Mar 2003 B1
6610391 Molee Aug 2003 B2
6620777 Heibel et al. Sep 2003 B2
6632504 Gillespie et al. Oct 2003 B1
6649547 Arnold et al. Nov 2003 B1
6676646 Bast et al. Jan 2004 B2
6713159 Blenke et al. Mar 2004 B1
6716441 Osborne et al. Apr 2004 B1
6846561 Gownder et al. Jan 2005 B1
6849065 Schmidt et al. Feb 2005 B2
6849319 Cree et al. Feb 2005 B2
D506317 Hallberg Jun 2005 S
D506618 Seguinot Jun 2005 S
D507413 Farahat Jul 2005 S
6916969 Helmfridsson et al. Jul 2005 B1
6924261 Grandmaire et al. Aug 2005 B2
D512505 Vinson Dec 2005 S
6992058 Grandmaire et al. Jan 2006 B2
6996851 Nordness et al. Feb 2006 B2
7005558 Johansson et al. Feb 2006 B1
D517816 Dwiggins Mar 2006 S
7033340 Muscat et al. Apr 2006 B1
7056404 McFall Jun 2006 B2
7063895 Rodrigues et al. Jun 2006 B2
7067711 Kuroda et al. Jun 2006 B2
D529607 Lindner Oct 2006 S
7118639 Delucia et al. Oct 2006 B2
D545572 Barkey Jul 2007 S
D546068 Vidal Jul 2007 S
D551343 Harsjo Sep 2007 S
D561481 Mecchi Feb 2008 S
7371919 Busam et al. May 2008 B1
7378033 Harrison et al. May 2008 B2
7381417 Gamez-Garcia Jun 2008 B2
D581170 Delaney Nov 2008 S
D581524 Macaulay Nov 2008 S
D583464 Francoeur Dec 2008 S
D584401 Francoeur Jan 2009 S
D585649 Bachmann Feb 2009 S
D586564 Enderby Feb 2009 S
D612491 Sullivan Conrad Mar 2010 S
7803244 Siqueira et al. Sep 2010 B2
7806880 Roe et al. Oct 2010 B2
D632496 Nugent Feb 2011 S
D632896 Sanders Feb 2011 S
7887522 Roe et al. Feb 2011 B2
7967801 Hammons et al. Jun 2011 B2
7981850 Doi et al. Jul 2011 B2
8022267 Hellstroem et al. Sep 2011 B2
D651410 Nugent Jan 2012 S
D656740 Nugent Apr 2012 S
8186296 Brown et al. May 2012 B2
8188022 Sengupta et al. May 2012 B2
8211414 Chen et al. Jul 2012 B2
8226625 Turner et al. Jul 2012 B2
8226626 Turner et al. Jul 2012 B2
8227660 Hara et al. Jul 2012 B2
8231595 Turner et al. Jul 2012 B2
8251965 Costea et al. Aug 2012 B2
D668332 Hough Oct 2012 S
D673780 Van Straten Jan 2013 S
8388594 Turner et al. Mar 2013 B2
D682420 Abram May 2013 S
8454571 Rezai et al. Jun 2013 B2
8524649 Leyrer et al. Sep 2013 B2
D692130 Biggs Oct 2013 S
D694024 Dwiggins Nov 2013 S
D708444 Love Jul 2014 S
9018154 Blondel Apr 2015 B2
9034230 Qureshi et al. May 2015 B2
9044353 Stone et al. Jun 2015 B2
9149968 Wilhelm et al. Oct 2015 B2
9237973 Abuto et al. Jan 2016 B2
D750385 Martin Mar 2016 S
D750386 Martin Mar 2016 S
9441188 Schramm, Jr. et al. Sep 2016 B2
D768393 Ellis Oct 2016 S
D777451 Hunt Jan 2017 S
9550309 Gibson et al. Jan 2017 B2
D778436 Coslett et al. Feb 2017 S
20010005540 Hisanaka et al. Jun 2001 A1
20010008683 Takai Jul 2001 A1
20010053901 Mizutani et al. Dec 2001 A1
20020013563 Desai et al. Jan 2002 A1
20020016122 Curro et al. Feb 2002 A1
20020022817 Ishikawa Feb 2002 A1
20020028624 Mizutani et al. Mar 2002 A1
20020034912 Curro et al. Mar 2002 A1
20020062113 Thomas et al. May 2002 A1
20020062115 Wada et al. May 2002 A1
20020081927 Maldonado et al. Jun 2002 A1
20020089079 Shelley et al. Jul 2002 A1
20020098762 Shelley et al. Jul 2002 A1
20020098764 Mleziva et al. Jul 2002 A1
20020147435 Coles et al. Oct 2002 A1
20020172371 Baker et al. Nov 2002 A1
20020182371 Soon et al. Dec 2002 A1
20020182396 Delucia et al. Dec 2002 A1
20020193032 Newkirk et al. Dec 2002 A1
20030003269 Lee et al. Jan 2003 A1
20030004481 Matsuoka et al. Jan 2003 A1
20030011099 Maldonado et al. Jan 2003 A1
20030021951 Desai et al. Jan 2003 A1
20030026945 Lasko Feb 2003 A1
20030028165 Curro et al. Feb 2003 A1
20030077430 Grimm et al. Apr 2003 A1
20030082377 Hartzog et al. May 2003 A1
20030082979 Bean et al. May 2003 A1
20030104748 Brown et al. Jun 2003 A1
20030109839 Costea et al. Jun 2003 A1
20030125687 Gubemick et al. Jul 2003 A1
20030145517 Miller Aug 2003 A1
20030149412 Damaghi et al. Aug 2003 A1
20030187415 Kudo et al. Oct 2003 A1
20030217945 Kiene et al. Nov 2003 A1
20030232558 Moody, III Dec 2003 A1
20040029479 Snider Feb 2004 A1
20040038851 Aubay et al. Feb 2004 A1
20040043189 Huang Mar 2004 A1
20040065208 Hart et al. Apr 2004 A1
20040067709 Kishine et al. Apr 2004 A1
20040071716 Jansen et al. Apr 2004 A1
20040081804 Basler Apr 2004 A1
20040087924 Sroda May 2004 A1
20040092902 Schuehle et al. May 2004 A1
20040116027 Termonia et al. Jun 2004 A1
20040116322 Manakopoulos et al. Jun 2004 A1
20040118811 Stone et al. Jun 2004 A1
20040122396 Maldonado et al. Jun 2004 A1
20040122404 Meyer et al. Jun 2004 A1
20040127128 Thomas Jul 2004 A1
20040127875 Hammons et al. Jul 2004 A1
20040161586 Cree et al. Aug 2004 A1
20040162536 Becker et al. Aug 2004 A1
20040170813 Digiacomantonio et al. Sep 2004 A1
20040176734 Rasmussen et al. Sep 2004 A1
20040181199 Moberg-Alehammar et al. Sep 2004 A1
20040204337 Corona, III et al. Oct 2004 A1
20040209042 Peacock et al. Oct 2004 A1
20040241399 Marmon Dec 2004 A1
20040265533 Hoying Dec 2004 A1
20050003980 Baker et al. Jan 2005 A1
20050025964 Fairbanks et al. Feb 2005 A1
20050026527 Schmidt et al. Feb 2005 A1
20050027270 Cree et al. Feb 2005 A1
20050087292 Mcfall et al. Apr 2005 A1
20050096614 Perez et al. May 2005 A1
20050131366 Shimada Jun 2005 A1
20050148971 Kuroda et al. Jul 2005 A1
20050175385 Cho et al. Aug 2005 A1
20050202208 Kelly Sep 2005 A1
20050228353 Thomas Oct 2005 A1
20050233140 Oh et al. Oct 2005 A1
20050244619 Kauschke et al. Nov 2005 A1
20050256027 Heibel et al. Nov 2005 A1
20050256475 Komatsu et al. Nov 2005 A1
20050288647 Ellingson et al. Dec 2005 A1
20060019063 Kelly Jan 2006 A1
20060020251 Kelly Jan 2006 A1
20060068176 Zafiroglu et al. Mar 2006 A1
20060069361 Olson Mar 2006 A1
20060087053 O'Donnell et al. Apr 2006 A1
20060107505 Desai et al. May 2006 A1
20060113049 Knobloch Jun 2006 A1
20060129114 Mason et al. Jun 2006 A1
20060135028 Arendt et al. Jun 2006 A1
20060135923 Boggs et al. Jun 2006 A1
20060141885 Cobbs et al. Jun 2006 A1
20060142710 Kigata et al. Jun 2006 A1
20060148358 Hall et al. Jul 2006 A1
20060179539 Harber Aug 2006 A1
20060252669 Heibel et al. Nov 2006 A1
20070015427 Yanagawase et al. Jan 2007 A1
20070021022 Kishine et al. Jan 2007 A1
20070032772 Ehrnsperger et al. Feb 2007 A1
20070036943 Hirose et al. Feb 2007 A1
20070048498 Cree Mar 2007 A1
20070073254 Ponomarenko et al. Mar 2007 A1
20070088307 Arizti et al. Apr 2007 A1
20070099817 Smith et al. May 2007 A1
20070135787 Raidel et al. Jun 2007 A1
20070191802 Gubemick et al. Aug 2007 A1
20070256286 Ngai Nov 2007 A1
20070275622 Masuda et al. Nov 2007 A1
20070275868 Dykstra Nov 2007 A1
20070293413 McFarland et al. Dec 2007 A1
20080076692 Carvell et al. Mar 2008 A1
20080138574 Maschino et al. Jun 2008 A1
20080143009 Kurian et al. Jun 2008 A1
20080249494 Digiacomantonio et al. Oct 2008 A1
20080294135 Hara et al. Nov 2008 A1
20080294138 Andersson et al. Nov 2008 A1
20080295256 Broze et al. Dec 2008 A1
20080300562 Ahoniemi et al. Dec 2008 A1
20080312343 Braun et al. Dec 2008 A1
20080312622 Beruda et al. Dec 2008 A1
20080317984 Yamashita et al. Dec 2008 A1
20090030390 Hammons et al. Jan 2009 A1
20090030391 Hammons et al. Jan 2009 A1
20090082746 Thomas et al. Mar 2009 A1
20090104831 Bornemann et al. Apr 2009 A1
20090124155 Tiemeier et al. May 2009 A1
20090131896 Ebitsuka et al. May 2009 A1
20090157021 Sullivan et al. Jun 2009 A1
20090191779 Cree Jul 2009 A1
20090233046 Iulianetti Sep 2009 A1
20090247978 Boissier Oct 2009 A1
20090259208 Hellstrom et al. Oct 2009 A1
20090299316 Seyler Dec 2009 A1
20090318050 Okaya Dec 2009 A1
20100004615 Boissier Jan 2010 A1
20100019415 Stone et al. Jan 2010 A1
20100035014 Hammons et al. Feb 2010 A1
20100036338 Hammons et al. Feb 2010 A1
20100036346 Hammons et al. Feb 2010 A1
20100100067 Pugliese, III Apr 2010 A1
20100105273 Motomura et al. Apr 2010 A1
20100107396 Yagyu et al. May 2010 A1
20100130952 Murai May 2010 A1
20100159770 Walser et al. Jun 2010 A1
20100164733 Ales et al. Jul 2010 A1
20100190679 Vanpachtenbeke et al. Jul 2010 A1
20100196653 Curro et al. Aug 2010 A1
20100227130 Takahashi Sep 2010 A1
20100233438 Stone et al. Sep 2010 A1
20100252138 Tseng Oct 2010 A1
20100261399 Katsuya et al. Oct 2010 A1
20100280471 Shah Nov 2010 A1
20100330326 Turner et al. Dec 2010 A1
20110004176 Andersson Jan 2011 A1
20110024940 Khalid et al. Feb 2011 A1
20110046592 Nishikawa et al. Feb 2011 A1
20110073513 Weisman et al. Mar 2011 A1
20110106036 Staahl et al. May 2011 A1
20110117307 Fraser et al. May 2011 A1
20110184370 Seyler et al. Jul 2011 A1
20110189915 Morimoto et al. Aug 2011 A1
20110196330 Hammons et al. Aug 2011 A1
20110236683 Takebe et al. Sep 2011 A1
20110245141 Gizaw et al. Oct 2011 A1
20110264064 Arora et al. Oct 2011 A1
20110269663 Clowes et al. Nov 2011 A1
20110301312 Blondel Dec 2011 A1
20110305870 Curro et al. Dec 2011 A1
20110313385 Hammons et al. Dec 2011 A1
20110319853 Yamashita et al. Dec 2011 A1
20120003423 Cree et al. Jan 2012 A1
20120035566 Sagisaka et al. Feb 2012 A1
20120043036 Polat Feb 2012 A1
20120095426 Visscher et al. Apr 2012 A1
20120121882 Okaya May 2012 A1
20120171913 Fox et al. Jul 2012 A1
20120177886 Kanya et al. Jul 2012 A1
20120273990 O'Donnell et al. Nov 2012 A1
20120282436 Coe et al. Nov 2012 A1
20120289917 Abuto et al. Nov 2012 A1
20120295060 Mullane Nov 2012 A1
20120296304 Choo et al. Nov 2012 A1
20130012898 Bergendahl et al. Jan 2013 A1
20130029555 Morimoto Jan 2013 A1
20130097101 Ortiz Apr 2013 A1
20130109612 Corona, III et al. May 2013 A1
20130121944 Leyrer et al. May 2013 A1
20130121945 Leyrer et al. May 2013 A1
20130129657 Streuli May 2013 A1
20130139666 Raidel et al. Jun 2013 A1
20130226122 Roe et al. Aug 2013 A1
20130253461 Xu et al. Sep 2013 A1
20130310300 Leyrer et al. Nov 2013 A1
20130310301 Sivik et al. Nov 2013 A1
20140029815 Kadir et al. Jan 2014 A1
20140031779 Hammons et al. Jan 2014 A1
20140033605 Sondjaja et al. Feb 2014 A1
20140044934 Bills et al. Feb 2014 A1
20140047649 Blondel Feb 2014 A1
20140066873 Kawakami et al. Mar 2014 A1
20140087130 Seyler et al. Mar 2014 A1
20140121624 Kirby et al. May 2014 A1
20140148773 Brown et al. May 2014 A1
20140148774 Brown et al. May 2014 A1
20140151934 Thomas et al. Jun 2014 A1
20140163500 Roe et al. Jun 2014 A1
20140163506 Roe et al. Jun 2014 A1
20140163511 Roe et al. Jun 2014 A1
20140228795 Castanares et al. Aug 2014 A1
20140296809 Hammons et al. Oct 2014 A1
20140296815 Takken et al. Oct 2014 A1
20140303581 Karlsson Oct 2014 A1
20140315779 Zander Oct 2014 A1
20140324009 Lee et al. Oct 2014 A1
20140336605 Hardie et al. Nov 2014 A1
20140378639 Blondel et al. Dec 2014 A1
20150099086 Kim et al. Apr 2015 A1
20150191677 Blondel Jul 2015 A1
20150197708 Jin Jul 2015 A1
20150209189 Mullane Jul 2015 A1
20150250663 Wagner et al. Sep 2015 A1
20150283001 Arizti et al. Oct 2015 A1
20150283003 Rosati et al. Oct 2015 A1
20150329799 Schramm, Jr. et al. Nov 2015 A1
20150337239 Gonzalez de Cossio et al. Nov 2015 A1
20160024426 Sivik et al. Jan 2016 A1
20160024427 Sivik et al. Jan 2016 A1
20160024428 Dykstra et al. Jan 2016 A1
20160024429 Dykstra et al. Jan 2016 A1
20160024430 Dykstra et al. Jan 2016 A1
20160024431 Dykstra et al. Jan 2016 A1
20160024432 Sivik et al. Jan 2016 A1
20160024434 Sivik et al. Jan 2016 A1
20160032220 Sivik et al. Feb 2016 A1
20160113826 Liu et al. Apr 2016 A1
20160129626 Arora et al. May 2016 A1
20160136003 Mullane et al. May 2016 A1
20160136010 Roe et al. May 2016 A1
20160136014 Arora et al. May 2016 A1
20160136015 Giovanni et al. May 2016 A1
20160136016 Mullane et al. May 2016 A1
20160136919 Roe et al. May 2016 A1
20170151103 Bianchi et al. Jun 2017 A1
20170175313 Song Jun 2017 A1
20180000654 Arora et al. Jan 2018 A1
20180000655 Mullane et al. Jan 2018 A1
20180000656 Roe et al. Jan 2018 A1
20180228660 Mullane et al. Aug 2018 A1
20180235817 Mullane et al. Aug 2018 A1
20180318144 Giovanni et al. Nov 2018 A1
20190240082 Mullane et al. Aug 2019 A1
20190290503 Mullane et al. Sep 2019 A1
20200246199 Mullane et al. Aug 2020 A1
Foreign Referenced Citations (176)
Number Date Country
2182304 Jan 1997 CA
2183776 Mar 1997 CA
2733472 Sep 2009 CA
2482306 Oct 2011 CA
1207662 Feb 1999 CN
2331362 Aug 1999 CN
1290156 Apr 2001 CN
2567250 Aug 2003 CN
1575787 Feb 2005 CN
1772984 May 2006 CN
1901862 Jan 2007 CN
2897211 May 2007 CN
202724134 Nov 2009 CN
201505226 Jun 2010 CN
101790606 Jul 2010 CN
201618014 Nov 2010 CN
201855363 Jun 2011 CN
101724132 Nov 2011 CN
102673030 Sep 2012 CN
101940514 Dec 2013 CN
103747955 Apr 2014 CN
103842570 Jun 2014 CN
2806401 Aug 1979 DE
4106295 Sep 1992 DE
19647459 May 1998 DE
19846857 Mar 2000 DE
165807 Dec 1985 EP
0172025 Feb 1986 EP
0172723 Feb 1986 EP
0172724 Feb 1986 EP
0330212 Aug 1989 EP
0343840 Nov 1989 EP
359501 Mar 1990 EP
495212 Jul 1992 EP
535579 Apr 1993 EP
545423 Jun 1993 EP
0212284 Sep 1993 EP
0589224 Mar 1994 EP
0691427 Jan 1996 EP
0696655 Feb 1996 EP
749736 Dec 1996 EP
749737 Dec 1996 EP
749738 Dec 1996 EP
749739 Dec 1996 EP
749740 Dec 1996 EP
0761846 Mar 1997 EP
0934737 Aug 1999 EP
983758 Mar 2000 EP
1022007 Jul 2000 EP
1040807 Oct 2000 EP
1084689 Mar 2001 EP
1086676 Mar 2001 EP
0710472 Apr 2001 EP
1290995 Mar 2003 EP
1066006 May 2003 EP
1352948 Oct 2003 EP
1140228 Mar 2004 EP
1625195 May 2007 EP
1740682 Jun 2009 EP
1756168 Jul 2009 EP
2110472 Oct 2009 EP
2284250 Feb 2011 EP
2347872 Jul 2011 EP
1781717 Nov 2012 EP
1988793 Jul 2014 EP
2862975 Feb 2006 FR
2002400 Feb 1979 GB
2103933 Mar 1983 GB
2225724 Jun 1990 GB
2296464 Jul 1996 GB
2310606 Sep 1997 GB
03186261 Aug 1991 JP
H04327211 Nov 1992 JP
H04327256 Nov 1992 JP
H05195406 Aug 1993 JP
6038818 Feb 1994 JP
06280150 Oct 1994 JP
H07216653 Aug 1995 JP
2587116 Mar 1997 JP
H0959823 Mar 1997 JP
H09310226 Dec 1997 JP
10272152 Oct 1998 JP
2790875 Dec 1998 JP
H11152624 Jun 1999 JP
2001032139 Feb 2001 JP
2002180331 Jun 2002 JP
2003003334 Jan 2003 JP
2003275238 Sep 2003 JP
2004041870 Feb 2004 JP
2004187810 Jul 2004 JP
2004154250 Aug 2004 JP
2005040235 Feb 2005 JP
2005200795 Jul 2005 JP
2005245789 Sep 2005 JP
2008006272 Jan 2008 JP
2008127705 Jun 2008 JP
2008174880 Jul 2008 JP
2008179939 Aug 2008 JP
2009050621 Mar 2009 JP
2009172354 Aug 2009 JP
2010051697 Mar 2010 JP
2010269029 Dec 2010 JP
2011078477 Apr 2011 JP
2011135979 Jul 2011 JP
2011239835 Dec 2011 JP
2012050548 Mar 2012 JP
2012154010 Aug 2012 JP
2012158547 Aug 2012 JP
5034078 Sep 2012 JP
2013011051 Jan 2013 JP
4357591 Feb 2013 JP
2014034741 Feb 2014 JP
2014097240 May 2014 JP
2014511739 May 2014 JP
5528660 Jun 2014 JP
3209591 Mar 2017 JP
2001064584 Jul 2001 KR
20010064584 Jul 2001 KR
20030089593 Nov 2003 KR
20140006704 Jan 2014 KR
20150100549 Sep 2015 KR
9003464 Apr 1990 WO
WO 9110415 Jul 1991 WO
WO 9311726 Jun 1993 WO
WO 9315701 Aug 1993 WO
WO 9513773 May 1995 WO
WO 9517867 Jul 1995 WO
9607689 Mar 1996 WO
WO 9610481 Apr 1996 WO
WO 9611107 Apr 1996 WO
WO 9619313 Jun 1996 WO
9621759 Jul 1996 WO
WO 9702133 Jan 1997 WO
WO 200701320 Jan 1997 WO
WO 9703818 Feb 1997 WO
WO199709020 Mar 1997 WO
WO199711661 Apr 1997 WO
9853896 Dec 1998 WO
9920725 Apr 1999 WO
WO 9930660 Jun 1999 WO
WO 9939671 Aug 1999 WO
9960975 Dec 1999 WO
WO 2000001334 Jan 2000 WO
WO 2000028929 May 2000 WO
WO 2000037249 Jun 2000 WO
WO 2000062826 Oct 2000 WO
WO 2001072251 Oct 2001 WO
WO 2002100632 Dec 2002 WO
WO 2003015681 Feb 2003 WO
WO 03024706 Mar 2003 WO
WO 2003071019 Aug 2003 WO
03102043 Dec 2003 WO
WO 2004009009 Jan 2004 WO
2004050812 Jun 2004 WO
2004058497 Jul 2004 WO
WO 2004098474 Nov 2004 WO
2005087907 Sep 2005 WO
2005097834 Oct 2005 WO
2007116346 Oct 2007 WO
2008005693 Jan 2008 WO
2010141309 Dec 2010 WO
WO 2011080643 Jul 2011 WO
WO 201214957 Feb 2012 WO
WO 2012052172 Apr 2012 WO
2012076432 Jun 2012 WO
2013068388 May 2013 WO
2013068394 May 2013 WO
WO 201391150 Jun 2013 WO
2013142486 Sep 2013 WO
2013163360 Oct 2013 WO
2013163388 Oct 2013 WO
WO 2013147222 Oct 2013 WO
2014022652 Feb 2014 WO
2014108106 Jul 2014 WO
2015130088 Sep 2015 WO
2017082834 May 2017 WO
Non-Patent Literature Citations (29)
Entry
Machine Translation of JP-2010051697-A, Mar. 2010 (Year: 2010).
Pad Size Chart, Apr. 2015 (Year: 2015).
International Search Report and Written Opinion, PCT/US2018/018280, dated Apr. 13, 2018.
All Office Actions, U.S. Appl. No. 15/897,184.
All Office Actions, U.S. Appl. No. 14/933,013.
All Office Actions, U.S. Appl. No. 14/933,015.
All Office Actions, U.S. Appl. No. 14/933,021.
All Office Actions, U.S. Appl. No. 16/032,117.
All Office Actions, U.S. Appl. No. 14/933,024.
All Office Actions, U.S. Appl. No. 15/704,027.
All Office Actions, U.S. Appl. No. 14/933,030.
All Office Actions, U.S. Appl. No. 15/704,030.
All Office Actions, U.S. Appl. No. 15/953,586.
All Office Actions, U.S. Appl. No. 15/953,742.
All Office Actions, U.S. Appl. No. 16/386,632.
All Office Actions, U.S. Appl. No. 16/432,084.
All Office Actions, U.S. Appl. No. 14/933,034.
All Office Actions, U.S. Appl. No. 15/704,035.
All Office Actions, U.S. Appl. No. 14/933,039.
Amimasr E., “Analysis of Basis Weight Uniformity of Microfiber Nonwovens and Its Impact on Permeability and Filtration Properties,” North Carolina State University, 2012, retrieved from the Internet URL https://repositoryJib.ncsu.edu/handle/1840.16/9096, 294 pages.
Analyze Menu, retrieved from the Internet URL “https://imagej.nih.gov/ij/docs/menus/analyze.html”, retrieved on Dec. 19, 2021, 12 pages.
ASTM D3954-94 (Reapproved 2010), “Standard Test Method for Dropping Point of Waxes,” D3954-94 (2010), 2 pages.
Auto Threshold—ImageJ, http://imagej.netlAuto_Threshold, last modified on Dec. 15, 2017, 7 pages.
Ferreira, T. and Rasband W., “ImageJ User Guide,” IJ 1.46r, Retrieved from the Internet URL https://imagej.nih.gov/i/docs/guide/user-guide.pdf. Last modified Sep./Oct. 2012, p. 79.
Morphological Image Processing, Retrieved from the Internet URL https://www.cs.auckland.ac.nz/courses/compsci773slc/lectures/ImageProcessing-html/topic4.htm#erosion, retrieved on Apr. 19, 2021, 7 pages.
Process Menu, retrieved from the Internet URL “https://imagej.nih.gov/ij/docs/menus/process.html”, retrieved on Dec. 19, 2021, 17 pages.
Schuck, P. “Size-Distribution Analysis of Macromolecules by Sedimentation Velocity Ultracentrifugation and Lamm Equation Modeling,” Biophysical Journal, vol. 78, Mar. 2000, pp. 1606-1619.
All Office Actions; U.S. Appl. No. 17/361,681.
U.S. Appl. No. 17/361,681, filed Jun. 29, 2021, to Timothy Ian Mullane et al.
Related Publications (1)
Number Date Country
20200139346 A1 May 2020 US
Provisional Applications (1)
Number Date Country
62459765 Feb 2017 US
Continuations (1)
Number Date Country
Parent 15897184 Feb 2018 US
Child 16733554 US