Claims
- 1. A sulfonated polyester compound useful as a soil release agent having isophthalate groups and terephthalate groups wherein the molar ratio of isophthalate groups to terephthalate groups is at least 0.15.
- 2. The sulfonated polyester compound of claim 1 wherein the molar ratio of isophthalate groups to terephthalate groups is from about 0.25 to 0.33.
- 3. The sulfonated polyester compounds of claim 1 wherein the sulfonated substituents of the sulfonated polyester compound are selected from the group consisting of 5-sulfoisophthalic acid and esters thereof, sulfobenzoic acid and esters thereof and isethionates.
- 4. The sulfonated polyester compound of claim 1 comprising monomers selected from the group consisting of dicarboxylic acids and esters thereof and polyols.
- 5. The sulfonated polyester compound of claim 4 wherein the dicarboxylic acids and esters thereof are selected from the group consisting of terephthalic acid, alkyl esters of terephthalic acid, phthalic acid, phthalic anhydride alkyl esters of phthalic acid, succinic acid, substituted succinic acid, esters of succinic acid, succinic anhydrides, adipic acid, and esters of adipic acid and combinations thereof.
- 6. The sulfonated polyester compound of claim 4 wherein the polyols are selected from the group consisting of ethylene glycol, 1,2-propanediol, 1,3-propanediol, glycerol and neopentyl glycol.
- 7. A method of producing a sulfonated polyester compound suitable for use as a soil release agent comprising:a) reacting at least one compound of Formula (I): XSO3—R—(COOY)n (I) wherein X is a cation, R is an aryl group, Y is selected from the group consisting of hydrogen and an alkyl group, and n is a positive integer with at least one compound of Formula (II): R1—(OH)m (II) wherein R1 is selected from the group consisting of an alkyl group, a cycloalkyl group and an aryl group, which may be substituted with an alkyl group or an aryl group, and m is a positive integer and optionally with a compound of Formula (III): R2—(COOZ)p (III) wherein R2 is selected from the group consisting of an alkyl group and an aryl group, Z is selected from the group consisting of hydrogen and an alkyl group, and p is a positive integer, and optionally with a compound of Formula (IV): wherein R3 and R4 are each independently selected from the group consisting of hydrogen and an alkyl group, and q is a positive integer to produce at least one ester compound intermediate, and reacting the resulting ester compound intermediate with a homo- or co-poly (ethylene terephthalate) to produce the sulfonated polyester, wherein the amount of each of isophthalate and terephthalate-containing compounds is controlled to provide a molar ratio of isophthalate groups to terephthalate groups in the sulfonated polyester compound of at least 0.15.
- 8. The method of claim 7 wherein the molar ratio of isophthalate groups to terephthalate groups from about 0.25 to 0.33.
Parent Case Info
This application claims the benefit of provisional application Ser. No. 60/307,966 filed Jul. 27, 2001.
US Referenced Citations (17)
Provisional Applications (1)
|
Number |
Date |
Country |
|
60/307966 |
Jul 2001 |
US |