Patent Application
20100263821
The invention relates to methods for preparing super-alloy and stainless steel components that have improved mechanical and corrosive properties.
Metals can oxidize, corrode, and become brittle if they are exposed to relatively high temperatures (i.e., greater than or equal to about 700° C.) and especially if they are present in oxidative environments. Environments, such as those with high temperatures and corrosive atmospheres, can be produced in gas turbines, such as gas turbines used for power generation applications. It would be beneficial to be able to manufacture metal components that last longer in high-temperature, oxidative environments.
Embodiments of the invention include a method for producing a component that includes melting a stainless steel alloy and transferring the melted stainless steel alloy to a mold. The mold is mechanically vibrated while the melted stainless steel solidifies. The component is then removed from the mold.
Embodiments of the present invention also include a method for producing a component that includes melting a super-alloy and transferring the melted super-alloy to a mold. The mold is mechanically vibrated while the melted super-alloy solidifies. The component is then removed from the mold.
The above described and other features are exemplified by the following detailed description.
These and other features of this invention will be more readily understood from the following detailed description of the various aspects of the invention taken in conjunction with the accompanying drawings that depict various embodiments of the invention, in which:
In embodiments of the present invention, a casting of molten material in a mold is performed while mechanical vibration of the mold occurs. The mold is mechanically vibrated and the vibration continues until the molten material solidifies. The resulting component has improved mechanical properties and is more resistant to corrosion. The mechanically vibration has a frequency range of from 8 to 60 Hz.
The metal component can be any one of, for example, combustion liners or transition pieces, buckets, nozzles, blades, vanes, shrouds, as well as other components, for example, components that will be disposed in a hot gas stream in a turbine engine. The metal component can include stainless steel and super-alloys.
A super-alloy, or high-performance alloy, is an alloy that exhibits excellent mechanical strength and creep resistance at high temperatures, good surface stability, and corrosion and oxidation resistance. A super-alloy's base alloying element is usually nickel or nickel-iron. Included in super-alloys are nickel-chromium-iron alloys such as INCONEL® (Special Metals Corporation) alloys; nickel-iron-chromium alloys such as INCOLOY® (Special Metals Corporation) alloys; nickel-iron alloys; and nickel-chromium molybdenum alloys such as HASTELLOY® (Haynes International) alloys.
A wide variety of iron-based stainless steel alloys are useful in embodiments of the present invention. Martensitic stainless steel alloy whose chemistry and processing achieve an excellent combination of strength and toughness is suitable for use in embodiments of the present invention and is described in U.S. Pat. No. 6,743,305. Such a steel alloy is characterized by a hardening phase of copper-rich precipitates, which in combination with certain chemistry and processing requirements yields the desired strength and toughness properties for the alloy. Duplex stainless steels are characterized by high strength and resistance to stress cracking and generally have less nickel than martenistic stainless steel. Another useful stainless steel in an embodiment of the invention is austenitic stainless steel.
Possible constituents of the stainless steel alloys used in embodiments of this invention include chromium, nickel, copper, molybdenum, manganese, silicon, copper, carbon and niobium.
As known in the art, chromium provides the stainless properties for the alloy, and for this reason a minimum chromium content of 14 weight percent is required for the alloy.
High alloy steels, such as but not limited to Fe-12Cr stainless steels (hereinafter Fe-12Cr steels), are known in the art. The high alloy steels possess desirable characteristics for use in various engineering articles. For example, these engineering articles may be employed in use at high temperatures, and may be subjected to thermal aging.
The process description herein is merely exemplary in purpose, and is not intended to limit the application in any manner. Such a process allows for the convenient preparation of articles having intricate and large geometries, such as turbine components.
It is possible in embodiments of the invention to dispose additional layers or coatings on the component parts. These coatings include thermal barrier coatings or erosion resistant coatings.
The terms “first,” “second,” and the like, herein do not denote any order, quantity, or importance, but rather are used to distinguish one element from another, and the terms “a” and “an” herein do not denote a limitation of quantity, but rather denote the presence of at least one of the referenced item. The modifier “about” used in connection with a quantity is inclusive of the stated value and has the meaning dictated by the context, (e.g., includes the degree of error associated with measurement of the particular quantity). The suffix “(s)” as used herein is intended to include both the singular and the plural of the term that it modifies, thereby including one or more of that term (e.g., the metal(s) includes one or more metals). Ranges disclosed herein are inclusive and independently combinable (e.g., ranges of “up to about 25 wt %, or, more specifically, about 5 wt % to about 20 wt %”, is inclusive of the endpoints and all intermediate values of the ranges of “about 5 wt % to about 25 wt %,” etc).
While various embodiments are described herein, it will be appreciated from the specification that various combinations of elements, variations or improvements therein may be made by those skilled in the art, and are within the scope of the invention. In addition, many modifications may be made to adapt a particular situation or material to the teachings of the invention without departing from essential scope thereof. Therefore, it is intended that the invention not be limited to the particular embodiment disclosed as the best mode contemplated for carrying out this invention, but that the invention will include all embodiments falling within the scope of the appended claims.
