This is a U.S. national stage of application No. PCT/JP2010/062705, filed on Jul. 28, 2010. Priority under 35 U.S.C. §119(a) and 35 U.S.C. §365(b) is claimed from Japanese Application No. 2009-177693, filed Jul. 30, 2009, the disclosure of which is also incorporated herein by reference.
The present invention relates to an art of a super-micro bubble generation device which can generate super-micro bubbles in liquid.
In recent years, the art of utilizing super-micro bubbles of several hundred nm to several dozen μm in size (diameter) has been attracting attention. The super-micro bubbles are used in liquid such as tap water, the water of lakes and marshes or rivers, or marine water or the like. The said super-micro bubbles have the property that the surface areas thereof are very large. The said super-micro bubbles also have physiochemical property such as self-pressure effect. Technology of utilizing the characteristics of such micro bubbles in effluent purification, purification, physical care in the bathtub, and the like has been developing.
One method for generating the super-micro bubbles having the said properties has become public knowledge. That method has steps of, spinning around motor in liquid; raising the flow rate by pump pressure; inhaling the air; and stirring. As such, bubbles are generated. The generated bubbles are then torn into super-micro bubbles by a rotating wing or a cutting tool. Moreover, another method for generating the super-micro bubbles has also become public knowledge. In that method, a liquid jetting nozzle is disposed around an air jetting nozzle, and bubbles jetted from the air jetting nozzle are torn into super-micro bubbles by the force of jet flow of the liquid jetting nozzle. Furthermore, another method for generating the super-micro bubbles has also become public knowledge. In that method, bubbles are generated by stirring, and the generated bubbles go through the eyes of a mesh membrane so as to fine down to super-micro bubbles (for example, see Patent Literature 1).
By using the conventional method of spinning around motor in liquid; raising the flow rate by pump pressure; inhaling the air; stirring; and tearing into super-micro bubbles by the rotating wing or the cutting tool, it is able to generate large amount of super-micro bubbles. However, fast rotation of the rotating wing or the cutting tool will cause corrosion due to cavitation or abrasion of devices. These will lead to significant damage, and thus, durability will become a problem. When the process liquid, discharged water, or the lakes and marshes or rivers, or marine water or the like with very poor quality is used, deterioration will proceed because the liquid directly contact to the device.
Meanwhile, when the method of which the generated bubbles go through the eyes of the mesh membrane so as to fine down to super-micro bubbles is applied, the mesh membrane will become depleted in the long run since the mesh membrane is made of organic substance. Moreover, when the mesh membrane is provided at right angle with liquid surface, the generated super-micro bubbles will overlap with other super-micro bubbles and will coalesce in a mass bubble. To avoid this, the mesh membrane should be provided parallel to the liquid surface, that is, installation method is limited.
Moreover, when the method of which the liquid jetting nozzle is disposed around the air jetting nozzle and bubbles jetted from the air jetting nozzle are torn into super-micro bubbles by the force of jet flow of the liquid jetting nozzle is applied, it is difficult to stabilize the particle size because there is limitation in pore size of the nozzle.
Therefore, considering the above-mentioned problems, the object of the present invention is to provide a super-micro bubble generation device which can generate super-micro bubbles using a simple method and can be installed by a method which provides a higher degree of freedom of installation to enable the device to be designed so as to be suitable for a place where the device is to be installed and to meet functional requirements.
The above-mentioned problems are solved by the following means.
Briefly stated, a super-micro bubble generation device of the present invention comprises: a compressor for delivering gas under pressure, and a bubble generation medium for discharging the gas, which has been delivered under pressure, as super-micro bubbles into liquid, wherein the said bubble generation medium consists of a high-density compound which is an electrically conductive substance. The said super-micro bubble generation device further comprises a liquid jetting device for jetting liquid in the direction substantially perpendicular to the direction in which the bubble generation medium discharges the super-micro bubbles, said liquid being the same kind of liquid as the liquid into which the super-micro bubbles are discharged.
With regard to the super-micro bubble generation device of the present invention, the said bubble generation medium is formed into a conical shape. The gas from the said compressor passes through the said bubble generation medium from a bottom face of the cone toward a vertex, wherein the said liquid being the same kind of liquid as the liquid into which the super-micro bubbles are discharged is jetted toward the vertex of the cone of the said bubble generation medium by the said liquid jetting device.
With regard to the super-micro bubble generation device of the present invention, an outer periphery of the said bubble generation medium is covered with a covering material, wherein the said covering material has the property of lowering the contact angle at which the liquid meets the surface of the said covering material.
The present invention constructed as the above brings the following effects.
According to the super-micro bubble generation device of the present invention, the bubble generation medium consisting of the high-density compound would not deteriorate due to expansion and contraction since the high-density compound is a solid substance which does not have flexibility. Also, the high-density compound would not become eroded due to temporal change since it is made of inorganic material. Thus, the super-micro bubble generation device is prevented from damage and degradation. Also, because the generated super-micro bubbles separates from the bubble generation medium as soon as they are generated, they would not coalesce in a mass bubble. Thus, the super-micro bubbles can be generated by using a simple method. Also, the super-micro bubble generation device can be installed by a method which provides a higher degree of freedom of installation to enable the device to be designed so as to be suitable for a place where the device is to be installed and to meet functional requirements. Moreover, since the said high-density compound is an electrically conductive substance, negatively charged ions tend to range on the surface of the high-density compound. The bubbles generated from the said bubble generation medium become negatively charged by receiving the negatively charged ions from the surface of the high-density compound. The bubbles would not coalesce in a mass bubble since each bubble act repulsively due to this negative electric charge.
According to the super-micro bubble generation device of the present invention, the liquid is jetted toward the vertex of the cone. Then, the liquid will flow along the curved surface of the cone. In this way, it is able to make the size of the injection hole smaller, and thus, lower pressure is needed for jetting the liquid. The generated super-micro bubbles separate from the bubble generation medium as soon as they are generated, and thus, the super-micro bubbles would not coalesce in a mass bubble. As just described, the super-micro bubbles can be generated by using a simple method. Also, the super-micro bubble generation device can be installed by a method which provides a higher degree of freedom of installation to enable the device to be designed so as to be suitable for a place where the device is to be installed and to meet functional requirements. Also, since the said high-density compound is an electrically conductive substance, bubbles generated from the bubble generation medium are negatively charged. The bubbles would not coalesce in a mass bubble since each bubble act repulsively due to this negative electric charge.
According to the super-micro bubble generation device of the present invention, the covering material has the property that contact angle at which the liquid meets the surface of the covering material is low. Accordingly, the surrounding liquid is attracted to the covering material. Thus, a thin liquid film is formed between the super-micro bubbles and the covering material. This makes it easy to separate the super-micro bubbles from the bubble generation medium. Thus, the super-micro bubbles would not coalesce in a mass bubble. Moreover, there is an effect of separating the super-micro bubbles by liquid flow by jetting liquid toward the bubble generation medium coated with the covering material from the liquid jetting device. There is also an effect of separating the super-micro bubbles by making the contact angle, at which the liquid interface meets the surface of the covering material, smaller. Combination of these effects makes it easy to separate super-micro bubbles.
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Next, explanation will be given on the mode for carrying out the invention.
As shown in
The compressor 2 is a device for delivering gas under pressure into an internal space 3a of the bubble generation medium 3 through the intermediary of a gas supply line 11. The gas delivered under pressure by the compressor 2 is not limited to air. For example, the gas may be ozone gas or nitrogen gas. And the said liquid may be such as fresh water or sea water of rivers or lakes, water, or industrial wastewater. Furthermore, the said liquid also may be solvent such as pharmaceutical products. In that case, the pharmaceutical products are stirred or mixed by using the said super-micro bubbles.
The gas delivered under pressure by the compressor 2 passes through the gas supply line 11, and then the gas will be delivered under pressure into the internal space 3a of the bubble generation medium 3. The bubble generation medium 3 consists of a high-density compound whose solid texture is made of molecular structure consisting of ionic bonds. Moreover, the said high-density compound is an electrically conductive substance, and thus, bubbles generated from the bubble generation medium 3 are negatively charged. In other words, the super-micro bubbles are negatively charged by addition of free electrons on passing through the bubble generation medium 3, which is the electrically conductive substance. The bubbles would not coalesce in a mass bubble since each bubble act repulsively due to this negative electric charge. For instance, the said electrically conductive substance is made of carbon-based material.
Moreover, as shown in
Moreover, the bubble generation medium 3 consisting of the high-density compound would not become worn even though liquid flow injected from the liquid jetting device 4 hits the high-density compound because it is activated. Thus, durability of the bubble generation medium 3 has been improved.
The liquid jetting device 4 is a device for separating super-micro bubbles generated from a surface site 3c of the bubble generation medium 3 by the liquid flow. The liquid jetting device 4 jets liquid being the same kind of liquid as the liquid into which the super-micro bubbles are discharged. Because of this constitution, the super-micro bubbles can be separated by the liquid flow without influencing fluid composition. Moreover, it is able to prevent different kind of liquid being mixed into the liquid.
As shown in
Thus, as shown in
Also, the bubble generation medium 3 may be coated with a coating material 5 which is a covering material. The coating material 5 is an inorganic material which has the property that contact angle at which the liquid interface meets the surface of the coating material 5 is low (for example, if the liquid is water, the coating material 5 may be made of superhydrophilic material). In this embodiment, the coating material 5 is made of silica glass. The contact angle signifies wetting force of materials. The value of wetting force will rise as contact angle becomes lower. However, the coating material 5 is not limited to material which is made of silica glass.
The coating material 5 is applied to the surface site 3c of the bubble generation medium 3 so as to cover its surface. The silica glass that makes up the coating material 5 has the property of lowering the contact angle at which the liquid interface meets the surface of the coating material 5, and thus the coating material 5 attracts surrounding liquid instead of shedding. In other words, the liquid spreads on the surface of the coating material 5 as thin film rather than forming droplets. Also, the coating material 5 is porous having a lot of tiny pores 5a of several μm to several dozen μm in diameter. The pores 5a are communicated with the pores 3b of the bubble generation medium 3.
As a result, as shown in
Moreover, there is an effect of separating the super-micro bubbles by liquid flow by jetting liquid toward the bubble generation medium 3 coated with the coating material 5 from the liquid jetting device 4. There is also an effect of separating the super-micro bubbles by making the contact angle, at which the liquid interface meets the surface of the coating material 5, smaller. Combination of these effects makes it easy to separate super-micro bubbles.
As shown in
Also, as shown in
For this reason, as shown in
Next, explanation will be given on the configuration of the bubble generation medium 3.
As shown in
Also, the liquid jetting device 4 is a device for jetting liquid in the direction substantially perpendicular to the direction in which the bubble generation medium 3 discharges the super-micro bubbles, that is, jetting liquid in the direction parallel to the surface site 3c, which is the widest of all of plate faces of the generation medium 3. The direction of jetting liquid is sufficient if the said direction is substantially perpendicular to the direction in which the super-micro bubbles are discharged, that is, the said direction may be any direction shown in
Because of this constitution, as shown in
Moreover, as shown in
Moreover, as shown in
Furthermore, the liquid jetting direction is not limited to such directions shown in this embodiment. For example, the liquid may be jetted in the same direction parallel to all of the side walls. Alternatively, the liquid may be jetted in the same direction parallel to three of the side walls and in the opposite direction parallel to the other side wall.
Moreover, as shown in
Moreover, as shown in
Furthermore, the liquid jetting direction is not limited to such directions shown in this embodiment. For example, the liquid may be jetted in a direction opposite to the gas supplying direction.
Moreover, as shown in
Moreover, the liquid jetting device 4 is facing the bubble generation medium 3. In other words, as shown in
In this way, it is able to make the size of the injection hole 4a smaller, and thus, lower pressure is needed for jetting the liquid. The generated super-micro bubbles separate from the bubble generation medium 3 as soon as they are generated, and thus, the super-micro bubbles would not coalesce in a mass bubble. As just described, the super-micro bubbles can be generated by using a simple method. Also, the super-micro bubble generation device 1 can be installed by a method which provides a higher degree of freedom of installation to enable the device to be designed so as to be suitable for a place where the device is to be installed and to meet functional requirements.
Also, as shown in
Moreover, a bubble guide groove 55, which is formed around the bubble generation medium 3, is provided downstream of the liquid flow jetted from the liquid jetting device 4. As shown in
Moreover, the bubble generation medium 3 and the liquid jetting device 4, which comprise the super-micro bubble generation device 1, may be configured in a unified manner. If constituted in this manner, positional relationship between the generation medium 3 and the injection hole 4a of the liquid jetting device 4 is maintained constant consistently. Accordingly, it is able to save many steps for adjusting position thereof. Moreover, a wall surface facing the liquid jetting device 4 may be inclined in an arc-like shape when seen from a side. Because of this constitution, the direction of super-micro bubbles movement can be guided. The super-micro bubbles move along the surface site 3c of the plate face of the bubble generation medium 3 by the jetted liquid flow from the liquid jetting device 4. In this way, it is able to preserve a distance between each super-micro bubble. As such, the super-micro bubbles would not coalesce in a mass bubble.
Moreover, the bubble generation medium 3 may be formed into a tabular shape, wherein several gas supply lines 11 are provided in parallel inside the bubble generation medium 3. In this case, the gas passes through the gas supply lines 11, and is delivered under pressure into the internal space 3a of the bubble generation medium 3. The gas supply lines 11 are branched inside the bubble generation medium 3. The said branched gas supply lines 11 are arranged in parallel. The super-micro bubbles are generated from the surface site 3c of the bubble generation medium 3 by gas pressure from the gas supply lines 11. Keeping wide interval between each gas supply line 11 which is arranged in parallel respectively makes it harder for super-micro bubbles to coalesce in a mass bubble.
However, the numbers or shape of the liquid jetting device is not limited to the state described in this embodiment. For example, more than three liquid jetting devices may be provided. Furthermore, the shape or material of the gas supply line 11 is not limited to the state described in this embodiment. For example, the gas supply line 11 may be a metallic pipe or a plastic pipe.
The super-micro bubble generation device of the present invention is industrially useful because it can generate super-micro bubbles using a simple method and can be installed by a method which provides a higher degree of freedom of installation to enable the device to be designed so as to be suitable for a place where the device is to be installed and to meet functional requirements. In this way, the generated super-micro bubbles separate from the bubble generation medium 3 as soon as they are generated, and thus, the super-micro bubbles would not coalesce in a mass bubble. As just described, the super-micro bubbles can be generated by using a simple method. Also, the super-micro bubble generation device 1 can be installed by a method which provides a higher degree of freedom of installation to enable the device to be designed so as to be suitable for a place where the device is to be installed and to meet functional requirements.
Number | Date | Country | Kind |
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2009-177693 | Jul 2009 | JP | national |
Filing Document | Filing Date | Country | Kind | 371c Date |
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PCT/JP2010/062705 | 7/28/2010 | WO | 00 | 4/2/2012 |
Publishing Document | Publishing Date | Country | Kind |
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WO2011/013706 | 2/3/2011 | WO | A |
Number | Name | Date | Kind |
---|---|---|---|
1920719 | Stich | Aug 1933 | A |
2937506 | Stirlen | May 1960 | A |
5560874 | Sheckler et al. | Oct 1996 | A |
7686284 | Henley | Mar 2010 | B2 |
7900895 | Farrell et al. | Mar 2011 | B1 |
20060244160 | Pakdaman | Nov 2006 | A1 |
Number | Date | Country |
---|---|---|
56-47726 | Apr 1981 | JP |
2003-245533 | Sep 2003 | JP |
2005-334869 | Dec 2005 | JP |
2006-61817 | Mar 2006 | JP |
2007-260529 | Oct 2007 | JP |
2008-132437 | Jun 2008 | JP |
2009-101250 | May 2009 | JP |
Entry |
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International Search Report for International Application No. PCT/JP2010/062705, mailed Aug. 31, 2010, with English translation. |
Decision of Refusal for Japanese Patent Application No. 2009-177693; Date of Mailing: Sep. 16, 2014, with English translation. |
Number | Date | Country | |
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20120175791 A1 | Jul 2012 | US |