Patent Application
20100216645
This application claims Paris Convention of DE 10 2009 010 011.3 filed Feb. 21, 2009 the complete disclosure of which is hereby incorporated by reference.
The invention concerns a method for connecting two or more superconducting wires, each comprising at least one filament that contains MgB2, wherein the superconducting connection is realized by exposed end regions of the filaments via a superconducting matrix.
A method of this type is disclosed in U.S. Pat. No. 7,226,894 B2.
Superconducting wires, through which an electric current can flow without loss, are used in a plurality of ways, in particular, for high-field magnet coils. Superconducting materials thereby become superconducting only below a material-specific transition temperature Tc such that superconducting materials must be cooled for technical use. One of the most important superconducting materials in the technical field is NbTi which has a transition temperature of approximately 10K. Since this low transition temperature requires cooling with cryogenic helium (boiling point approximately 4K), the use of NbTi is relatively expensive.
In 2001, superconductivity was discovered in the Mg-B system, which enables relatively inexpensive cooling without cryogenic helium with a transition temperature of approximately 39K for MgB2. For this reason, the operating costs of technical systems could be reduced and the ease of maintenance be increased. MgB2 also has a higher critical magnetic field Bc2 compared to NbTi. For this reason, the superconducting system MgB2 is currently the subject matter of numerous research and development activities.
One difficulty with the technical use of the MgB2 superconducting system is the provision of superconducting connecting points (“joints”), in particular, between two MgB2 superconducting wires. The quality of the superconducting connecting points thereby delimits the efficiency of the overall superconducting system.
U.S. Pat. NO. 6,921,865 B2 discloses a joint of two superconducting wires, wherein exposed NbTi filaments of the superconducting wires project into bulk MgB2 powder and are compressed therewith.
DE 39 05 424 C2 describes a method for connecting oxidic superconductors, in which their contact surfaces are thermally melted.
U.S. Pat. No. 7,226,894 B2 discloses a connection between two MgB2 superconducting wires, wherein the MgB2 filaments are exposed at the ends of two superconducting wires and are overlapped. The exposed ends are then heated together with a mixture of boron powder and magnesium powder, wherein boron and magnesium react to form MgB2. The generated MgB2 superconductingly connects the two wires. The generated MgB2 is, however, highly porous and the resulting current carrying capacity of the joint is relatively small.
DE 10 2006 020 829 A1 describes a superconductive joint with superconducting wire conductor leads made from e.g. MgB2. Free conductor lead ends are thereby disposed in a bushing containing bulk MgB2 powder. The bulk powder is subsequently compressed together with the bushing.
EP 0 280 812 B1 discloses various compositions of high temperature superconductors, in particular, of the YBCO-type.
It is the underlying purpose of the invention to improve the quality, in particular, the current carrying capacity and critical magnetic field strength of a superconducting connection of MgB2 superconducting wires.
This object is achieved by a method of the above-mentioned type, which is characterized in that
a) bulk powder of a high-temperature superconducting (HTS) powder with a transition temperature of Tc>40K is provided, into which the exposed end regions of the filaments project,
b) and the bulk powder is compacted together with the projecting exposed end regions of the filaments to form a compressed element.
In accordance with the present invention, the superconducting connection of the superconducting wires is realized by a compressed element made from HTS material.
The quasi-monolithic compressed element made from HTS material is generated during the connecting process of the superconducting wires.
The HTS powder surrounds the exposed (i.e. the non-superconducting cover is removed) end regions of the MgB2 filaments and fills, in particular, any existing space between the exposed end regions. Compacting the HTS powder reliably produces and solidifies a superconducting path having a high current carrying capacity between the exposed end regions. The HTS material itself is also superconducting at the normal operating temperature of the MgB2 filaments (with a transition temperature of approximately 39K), since it has a higher transition temperature (transition temperature >40K) than the MgB2 filaments.
The HTS powder material is compacted through mechanical compression. Mechanical compression is thereby typically carried out without temperature load or heating. In particular, the temperature remains that low during mechanical compression such that the high-temperature superconducting material (HTS material) does not start to melt. Suitable pressing methods are, in particular, uniaxial pressing and isostatic pressing, in particular cold-isostatic pressing (CIP).
The invention provides in total a simple and inexpensive method for producing high-quality joints for connecting MgB2 superconducting wires, which can be technically realized without problems as a standard industrial procedure.
In one preferred variant of the inventive method, the bulk powder is subjected to uniaxial pressing in step b). Uniaxial pressing is particularly easy to perform.
In one particularly preferred method variant, the compressed element is compacted to at least 30%, preferably at least 40%, preferentially at least 50%, of the theoretical density of the HTS material of the HTS powder in step b). These densities yield particularly high current carrying capacities of the joint.
In one advantageous method variant, the bulk powder additionally contains a binding agent, in particular, a metallic binding agent. The binding agent improves the pressing behavior and/or the solidity of the compressed element. The binding agent in the bulk powder is typically present in the form of powder and preferably comprises metals having good electric conducting properties such as Cu, Ag or Al. When a binding agent is used, the binding agent portion is typically 10 to 70 volume % in the bulk powder.
In one particularly preferred method variant, for step b), the bulk powder is filled into a plastically deformable, in particular, metallic container, and the container is compressed with the bulk powder in step b) such that after compression, the compressed element is tightly enclosed in the container. The likewise compressed container protects the compressed element against mechanical damage, in particular, rupture of the superconducting connection between the superconducting wires in a simple fashion without any additional production step. In accordance with the invention, the plastically deformable container is typically durable at cryogenic temperatures that are required to obtain the superconducting state of the HTS and the MgB2.
In another advantageous method variant, subsequent to step b), the compressed element is introduced into a protective coating, in particular, wherein the compressed element is cast into a plastic resin. The protective coating protects the compressed element against mechanical damage, in particular, against rupture of the superconducting connection between the wires. Compression of the bulk HTS powder can thereby be carried out in any fashion (irrespective of the protective coating). The protective coating can subsequently be adjusted to the compressed element. In accordance with the invention, the protective coating, in particular, the plastic resin, is typically durable at cryogenic temperatures that are required to obtain the superconducting state of the HTS and the MgB2.
In another particularly preferred method variant, the exposed end regions of the filaments of the different superconducting wires are disposed in the bulk powder in such a fashion that they abut each other, in particular, are interwoven with each other. This reduces the danger of badly conducting transitions between the filaments of the different wires and the space between the filaments of different wires is minimized. Mutual abutment of the wires can be ensured in a simple fashion by twisting them together. Twisting together is realized in the simplest fashion as long as the filaments still have their metallic plasticity (i.e. prior to conversion of Mg and B into MgB2).
The present invention also concerns a superconducting joint of two or more superconducting wires, each comprising at least one filament that contains MgB2, characterized in that the superconducting wires are superconductingly connected to each other through exposed end regions of the filaments via a superconducting matrix of a compressed high-temperature superconducting (HTS) powder with a transition temperature of Tc>40K. The compressed HTS powder provides a superconducting connection between the superconducting wires at the operating temperature of MgB2. The HTS material and thereby also the entire joint have very good current carrying properties.
In one particularly preferred embodiment of the inventive joint, the HTS material in the HTS powder is a type of layered cuprate, in particular, wherein the HTS material in the HTS powder comprises YBa2Cu3Ox or ReBa2Cu3Ox or Bi2Sr2CaCu2Ox or (Bi,Pb)2Sr2CaCu2Ox or (Bi,Pb)2Sr2Ca2Cu3Ox, with Re: one or more rare earth elements. These HTS materials have particularly high current carrying properties for joints of MgB2 superconducting wires.
In one preferred embodiment, the superconducting matrix is surrounded by a coating. The coating may have already been provided during compression (container) or also be arranged around the compressed element after compression (protective coating). The coating may, in particular, be formed from metal (e.g. as a metal container) or also comprise a plastic resin into which the superconducting matrix is cast. The coating thereby tightly holds the compressed HTS powder together, thereby safeguarding the superconducting connection and, in particular, preventing rupture of the superconducting connection.
Finally, in one preferred embodiment of the inventive joint, the joint is produced by an inventive method as mentioned above.
Further advantages of the invention can be extracted from the description and the drawing. The features mentioned above and below may be used individually or collectively in arbitrary combination in accordance with the invention. The embodiments shown and described are not to be understood as an exhaustive enumeration but have exemplary character for describing the invention.
The invention is illustrated in the drawing and is explained in more detail with reference to embodiments.
a, 3b show schematic cross-sectional views of a pressing means for compacting bulk HTS powder in accordance with the invention, with projecting, exposed filaments of two superconducting wires prior to compression (
Each filament 3a, 3b is exposed in one end region 13 (in
a to 6 illustrate the inventive production of a joint or an HTS powder compressed element between and around the ends of the two wires 1, 2.
As is illustrated in
By lowering a pressing ram 6 in the direction of arrow 7 onto the bulk powder 4, the bulk powder 4 can be mechanically compacted. The pressing ram 6 is typically lowered by a hydraulic or mechanical mechanism providing a force. In the present example, the pressing process is performed without temperature load and does not require any protective gas conditions either.
b shows the compressed element (also called green body) 8 after compacting the bulk powder. The pressing ram 6 has been introduced as far as possible into the pressing mold 5. After removal of the pressing ram 6 (and in most cases also of the pressing mold bottom 9), the compressed element 8 can be easily removed.
| Number | Date | Country | Kind |
|---|---|---|---|
| 10 2009 010 011.3 | Feb 2009 | DE | national |
