Supertwist liquid crystal display

Abstract

Supertwist liquid crystal displays having very short switching times are obtained if the nematic liquid crystal mixture contains at least one component chosen from group A consisting of compounds of the formulae AI to AVI: ##STR1## wherein R.sup.1 and R.sup.2 in each case independently of one another are each R and R is alkyl having 1-12 C atoms, wherein one or two non-adjacent CH.sub.2 groups can also be replaced by --O--, --CH.dbd.CH--, --CO--, --O--CO-- or --CO--O--, and up to four other components.

Description

The invention relates to supertwist liquid crystal displays (SLCD) having very short switching times and good gradients and angular dependencies and the new nematic liquid crystal mixtures used in these.

SLCD according to the precharacterizing clause are known, for example, from EP 0,131,216 B1; DE 34 23 993 A1; EP 0,098,070 A2; M. Schadt and F. Leenhouts, 17. Freiburger Arbeitstagung Flussigkristalle (17th Freiburg Conference on Liquid Crystals) (8.-10.04.87); K. Kawasaki et al., SID 87 Digest 391 (20.6); M. Schadt and F. Leenhouts, SID 87 Digest 372 (20.1); K. Katoh et al., Japanese Journal of Applied Physics, Vol. 26, No. 11, L 1784-L 1786 (1987); F. Leenhouts et al., Appl. Phys. Lett. 50 (21), 1468 (1967); H. A. van Sprang and H. G. Koopman, J. Appl. Phys. 62 (5), 1734 (1987); T. J. Scheffer and J. Nehring, Appl. Phys. Lett. 45 (10), 1021 (1984), M. Schadt and F. Leenhouts, Appl. Phys. Lett. 50 (5), 236 (1987) and E. P. Raynes, Mol. Cryst. Liq. Cryst. Letters Volume 4 (1), pages 1-8 (1986). The term SLCD here includes any highly twisted display element having a twisting angle, according to the content, of between 160.degree. and 360.degree., such as, for example, the display elements according to Waters et al. (C. M. Waters et al., Proc. Soc. Inf. Disp. (New York) (1985) (3rd Intern. Display Conference, Kobe, Japan), and the STN-LCDs (DE OS 35 03 259), SBE-LCDs (T. J. Scheffer and J. Nehring, Appl. Phys. Lett. 45 (1984) 1021), OMI-LCDs (M. Schadt and F. Leenhouts, Appl. Phys. Lett. 50 (1987), 236), DST-LCDs (EP OS 0 246 842) or BW-STN-LCDs (K. Kawasaki et al., SID 87 Digest 391 (20.6)).

In contrast to standard TN displays, such SLCD are distinguished by considerably better gradients of the electrooptical characteristic line and associated better contrast values, as well as by a considerably lower angular dependency of contrast. SLCD having short switching times, especially also at lower temperatures, are of particular interest. To achieve short switching times, the viscosities of the liquid crystal mixtures in particular have hitherto been optimized using usually monotropic additives of relatively high vapor pressure. However, the switching times achieved were not adequate for every use.

There is thus still a great demand for SLCD having very short switching times with a simultaneously high working temperature range, high characteristic line gradient, good angular dependency of the contrast and low threshold voltage.

The invention is based on the object of providing SLCD which have the abovementioned disadvantages to only a minor degree, if at all, and at the same time have very short switching times.

It has now been found that this object can be achieved if nematic liquid crystal mixtures containing the following components:

a) at least one component chosen from group A, consisting of compounds of the formulae AI to AVI: ##STR2## wherein R.sup.1 and R.sup.2 each independently of one another are each R and R is alkyl having 1-12 C atoms, wherein one or two non-adjacent CH.sub.2 groups can also be replaced by --O--, --CH.dbd.CH--, --CO--, --O--CO-- or --CO--O--, b) at least one component chosen from group B1, consisting of the compounds of the formulae BI to BIV: ##STR3## wherein R.sup.1 and R.sup.2 each independently of one another have the meaning given for R, Z.sup.2 is --CH.sub.2 CH.sub.2 --, --CO--O--, --O--CO-- or a single bond and ##STR4## and/or at least one component chosen from group B2, consisting of the compounds of the formulae BV to BVII: ##STR5## wherein R.sup.1 has the meaning given for R, Z.sup.0 is --CH.sub.2 CH.sub.2 -- or a single bond and Q is ##STR6## wherein n is 1 to 9, X is CN or F and Y is H or F, and/or at least one component chosen from group B3, consisting of the compounds of the formulae BVIII and BIX: ##STR7## wherein R.sup.1 and R.sup.2 each independently of one another have the meaning given for R and ##STR8## is ##STR9## c) 10-80% by weight of a liquid crystal component C, consisting of one or more compounds having a dielectric anisotropy of more than +1.5, d) 0-20% by weight of a liquid crystal component D, consisting of one or more compounds having a dielectric anisotropy of less than -1.5 and e) an optically active component E, in an amount such that the ratio between the layer thickness (separation of the plane-parallel carrier plates) and the natural pitch of the nematic liquid crystal mixture is about 0.2 to 1.3, are used.

The invention thus relates to an SLCD having

two plane-parallel carrier plates which, with an edging, form a cell, a nematic liquid crystal mixture of positive dielectric anisotropy in the cell, electrode layers with superimposed orientation layers on the insides of the carrier plates, an angle of incidence between the longitudinal axis of the molecules on the surface of the carrier plates and the carrier plates of about 1 degree to 30 degrees and a twisting angle of the liquid crystal mixture in the cell from orientation layer to orientation layer, according to the amount, of between 160.degree. and 360.degree., characterized in that the nematic liquid crystal mixture contains a) at least one component chosen from group A, consisting of compounds of the formulae AI to AVI: ##STR10## wherein R.sup.1 and R.sup.2 each independently of one another are each R and R is alkyl having 1-12 C atoms, wherein one or two non-adjacent CH.sub.2 groups can also be replaced by --O--, --CH.dbd.CH--, --CO--, --O--CO-- or --CO--O--, b) at least one component chosen from group B1, consisting of the compounds of the formulae BI to BIV: ##STR11## wherein R.sup.1 and R.sup.2 each independently of one another have the meaning given for R, Z.sup.2 is --CH.sub.2 CH.sub.2 --, --CO--O--, --O--CO-- or a single bond and ##STR12## is ##STR13## and/or at least one component chosen from group B2, consisting of the compounds of the formulae BV to BVII: ##STR14## wherein R.sup.1 has the meaning given for R, Z.sup.0 is --CH.sub.2 CH.sub.2 -- or a single bond and Q is ##STR15## wherein n is 1 to 9, X is CN or F and Y is H or F, and/or at least one component chosen from Croup B3, consisting of the compounds of the formulae BVIII and BIX: ##STR16## wherein R.sup.1 and R.sup.2 each independently of one another have the meaning given for R and ##STR17## is ##STR18## c) 10-80% by weight of a liquid crystal component C, consisting of one or more compounds having a dielectric anisotropy of more than +1.5, d) 0-20% by weight of a liquid crystal component D, consisting of one or more compounds having a dielectric anisotropy of less than -1.5 and e) an optically active component E, in an amount such that the ratio between the layer thickness (separation of the plane-parallel carrier plates) and the natural pitch of the nematic liquid crystal mixture is about 0.2 to 1.3, and in that the nematic liquid crystal mixture has a nematic phase range of at least 60.degree. C., a viscosity of not more than 30 mpa.s and a dielectric anisotropy of at least +5, the dielectric anisotropies of the compounds and the parameters relating to the nematic liquid crystal mixture being based on a temperature of 20.degree. C.

The invention also relates to corresponding liquid crystal mixtures for use in SLCD.

The individual compounds of the formulae AI to AVI, BI to BIV and CI to CIII or other compounds which can be used in the SLCD according to the invention are either-known or can be prepared analogously to the known compounds.

Preferred liquid crystal mixtures which can be used according to the invention contain one or more compounds from group A in an amount of 4% to 40%, preferably 10% to 32%. Compounds of the formula AIII to AVI are preferred. In a particularly preferred embodiment, the mixtures simultaneously contain (a) compounds of the formula AV and/or AVI and (b) compounds of the formula AIII and/or AIV. R.sup.1 and R.sup.2 preferably in each case independently of one another are n-alkyl having 1 to 7 C atoms or (trans)-n-alkenyl having 3 to 7 C atoms.

The content of component(s) from group B1 is preferably 5% to 45%, particularly preferably about 10% to 40%. Components of the formulae BIII and BIV are preferred. Particularly preferred compounds of the formula BIII are those of the following part formulae: ##STR19## wherein R.sup.1 is CH.sub.3 --(CH.sub.2).sub.n --O--, CH.sub.3 --(CH.sub.2).sub.t --, trans-H--(CH.sub.2).sub.r --CH.dbd.CH--(CH.sub.2 CH.sub.2).sub.s --CH.sub.2 O-- or trans-H--(CH.sub.2).sub.r)--CH.dbd.CH--(CH.sub.2 CH.sub.2).sub.s --,

R.sup.2 is CH.sub.3 --(CH.sub.2).sub.t --, n is 1, 2, 3 or 4, r is 0, 1, 2 or 3, s is 0 or 1 and t is 1, 2, 3 or 4.

Those of the part formula ##STR20## wherein R.sup.1 and R.sup.2 have the abovementioned meaning, are furthermore preferred.

The content of the compounds of the formula BIII of the abovementioned part formulae is preferably about 5% to 45%, particularly preferably about 10% to 35%. Particularly preferred compounds of the formula BIV are those of the following part formula: ##STR21## wherein R.sup.1 is CH.sub.3 --(CH.sub.2).sub.n --O-- or trans-H--(CH.sub.2).sub.r --CH.dbd.CH--(CH.sub.2 CH.sub.2).sub.s --CH.sub.2 O-- and R.sup.2 is CH.sub.3 --(CH.sub.2).sub.t --, wherein

n is 1, 2, 3 or 4, r is 0, 1, 2 or 3, s is 0 or 1 and t is 1, 2, 3 or 4.

The content of these compounds or of the compounds of the formula BIV is preferably about 5% to 40%, particularly preferably about 10% to 35%.

The mixtures preferably contain compounds of the formula III, in particular those of the part formula ##STR22##

In a particularly preferred embodiment, the mixtures simultaneously contain compounds of the formulae BIII and BIV, the total content of components of group B1 being maintained.

If compounds of the formulae BI and/or BIII are present, R.sup.1 and R.sup.2 preferably in each case independently of one another are n-alkyl having 1 to 7 C atoms or (trans)-n-alkenyl having 3 to 7 C atoms. Z.sup.2 is preferably a single bond. BI is particularly preferred.

Mixtures according to the invention which contain one or more compounds of the formula BIV, wherein ##STR23## is ##STR24## and R.sup.1 and R.sup.2 have one of the abovementioned preferred meanings, and particularly preferably are n-alkyl having 1 to 7 C atoms, are furthermore preferred.

The total content of components of group B1 is observed in each case.

The content of compounds of group B2 is preferably about 5% to 45%, particularly preferably 5% to 20%. The content (preferred ranges) for BV to BVII is as follows:

BV about 5% to 30%, preferably about 5% to 15% Total BVI and BVII: about 5% to 25%, preferably about 10% to 20%.

Preferred compounds of group B2 are shown below: ##STR25##

R.sup.1 is preferably n-alkyl having 1 to 7 C atoms or (trans)-n-alkenyl having 3 to 7 C atoms. Z.sup.0 is preferably a single bond. R preferably has the preferred meaning given above for R.sup.1 or is fluorine. Y is preferably fluorine.

The mixtures according to the invention preferably contain one or more compounds chosen from the group consisting of BV3, BVI1 and BVII1 in a total content of about 5 to 35%.

In a particularly preferred embodiment, the mixtures according to the invention contain, in addition to BV3, BVI1, BVII1 and BV2 (R.dbd.F), further terminally fluorinated compounds, for example chosen from the group consisting of: ##STR26## wherein R.sup.1 is preferably n-alkyl having 1 to 7 C atoms or (trans)-n-alkenyl having 3 to 7 C atoms, x is 1 or 2, y is 0 or 1 and Y is H or F.

The total content of all the terminally fluorinated compounds is preferably about 5% to 65%, in particular about 15% to 40%.

The content of compounds from group B3 is preferably about 5% to 30%, particularly preferably about 10% to 20%. R.sup.1 is preferably n-alkyl or n-alkoxy having in each case 1 to 9 C atoms. R.sup.2 is preferably n-alkyl having 1 to 9 C atoms. However, analogous compounds with alkenyl or alkenyloxy groups can also be employed. Compounds of the formula BVIII are preferred. ##STR27## is preferably 1,4-phenylene.

The mixtures according to the invention contain compounds of at least one of the groups B1, B2 and B3. Preferably, they contain one or more compounds from group B1 and one or more compounds from groups B2 and/or B3.

The content of compounds of component C is preferably about 10% to 80%, in particular about 20% to 70%. The expert can easily adjust this content to establish the desired threshold voltage, it being possible on principle to use all the customary liquid crystal compounds of .DELTA..di-elect cons.>+1.5. If predominantly less highly positive terminally fluorinated compounds (see above) are used, the total content varies more in the above range (about 35% to 80%), whereas if terminally cyano-substituted compounds are used, the content can be lower (about 10% to 35%). Particularly preferred compounds are, in addition to the abovementioned terminally fluorinated compounds, the preferred cyano compounds mentioned below: ##STR28## wherein R has the meaning given in group A,

Q is ##STR29## Z.sup.1 is ##STR30## a single bond, --CH.sub.2 CH.sub.2 --, --CO--O-- or --O--CO-- and ##STR31## is ##STR32##

Some particularly preferred smaller groups are shown below: ##STR33## R.sup.1 is preferably n-alkyl having 1 to 7 C atoms, n-oxaalkyl having 3 to 7 C atoms (for example n-alkoxymethyl) or n-alkenyl having 3-7 C atoms. Y is H or fluorine; x is 1 or 2; and y is 0 or 1.

Isothiocyanates, for example of the formula ##STR34## wherein R.sup.1 is n-alkyl having 1 to 7 C atoms or n-alkenyl having 3 to 7 C atoms, are furthermore preferred.

In a particularly preferred embodiment, the mixtures according to the invention preferably contain about 5% to 20% of one or more compounds having a dielectric anisotropy of less than -1.5 (component D). Such compounds are known, for example derivatives of 2,3-dicyanohydroquinone or cyclohexane derivatives containing the structural element ##STR35## in accordance with DE-OS 32 31 707 and DE-OS 34 07 013.

Preferably, however, compounds having the structural element 2,3-difluoro-1,4-phenylene will be chosen, for example compounds according to DE-OS 38 07 801, 38 07 861, 38 07 863, 38 07 864 or 38 07 908. Tolanes having this structural element according to International Patent Application PCE/DE 88/00133 are particularly preferred, especially those of the formulae ##STR36## wherein R.sup.1 and R.sup.2 each independently of one another are preferably n-alkyl having 1 to 7 C atoms or n-alkenyl having 3 to 7 C atoms and Z.sup.0 is --CH.sub.2 --CH.sub.2 -- or a single bond.

The component D has the effect, in particular, of improving the gradient of the characteristic line.

In a particularly preferred embodiment, the mixtures contain about 5% to 35%, particularly preferably about 10% to 20%, of liquid crystal tolane compounds. This means that lower layer thicknesses (about 5-6 .mu.m) can be used, whereupon the switching times are shortened significantly. Particularly preferred tolanes are shown below: ##STR37## R.sup.1 is preferably n-alkyl having 1 to 7 C atoms, Z.sup.0 is --CH.sub.2 CH.sub.2 -- or a single bond and

Q is ##STR38## wherein R.sup.2 is n-alkyl or n-alkoxy having in each case 1 to 7 C atoms or n-alkenyl or n-alkenyloxy having in each case 3 to 7 C atoms.

In other particularly preferred embodiments, the mixtures contain

30-60% by weight of component C, 20-70% by weight of compounds from groups A and B, 0-10% by weight of component D and an amount of component E which adds up to 100% by weight, a component D which contains one or more compounds with a 1-cyano-trans-1,4-cyclohexylene group or a 2,3-difluoro-1,4-phenylene group, at least two compounds of the formula AIII or AV, compounds of the formula AIII and AV, a component C which contains one or more compounds with a 4-fluorophenyl group or a 3,4-difluorophenyl group, at least one compound from the following group: ##STR39## wherein alkyl is a straight-chain alkyl group having 2-7 C atoms and X is H or F, one or more compounds wherein R is a trans-alkenyl or a trans-alkenyloxy group, one or more compounds chosen from the following group ##STR40## wherein R.sup.1 and R.sup.2 have the preferred meanings given in the case of component A and one of the two 1,4-phenylene groups can also be substituted by fluorine; the content of these compounds is 0% to 25%, preferably about 5% to 15%.

The expert has available a large number of chiral doping substances, some of which are commercially available, for component E. Their choice is not critical per se.

The build-up of the liquid crystal display elements according to the invention of polarizers, electrode baseplates and electrodes having a surface treatment such that the preferred orientation (director) of the liquid crystal molecules in each case adjacent thereto is usually twisted from the one electrode to the other by, according to the amount, 160.degree. to 360.degree. relative to one another, corresponds to the usual construction for such display elements. The term usual construction here is interpreted widely and also includes all the variations and modifications of the supertwist cell which are known from the literature, in particular also matrix display elements, as well as the display elements, containing additional magnets, according to DE-OS 2 748 738. The surface tilt angle of the two carrier plates can be identical or different. Identical tilt angles are preferred.

However, an essential difference between the display elements according to the invention and those which were hitherto customary and are based on the twisted nematic cell is in the choice of liquid crystal components in the liquid crystal layer.

The liquid crystal mixtures which can be used according to the invention are prepared in a manner which is customary per se. As a rule, the desired amount of the components used in the smaller amount is dissolved in the components which make up the main constituent, preferably at elevated temperature. It is also possible to mix solutions of the components in an organic solvent, for example in acetone, chloroform or methanol, and to remove the solvent again, for example by distillation, after thorough mixing.

The dielectrics can also contain other additives which are known to the expert and are described in the literature. For example 0-15% of pleochroic dyestuffs can be added.

The liquid crystal mixtures according to the invention can certainly additionally contain, apart from the components mentioned here, further customary components. One skilled in the art can determine by routine tests which other components can be employed and in which amounts without eliminating the advantages of the invention. Preferably, the mixtures predominantly comprise the components mentioned (more than 60% of them) and in particular almost exclusively these components (more than 80%, particularly preferably 100% of them).

The following examples are intended to illustrate the invention without limiting it.

The examples have the following meanings:

______________________________________S-N smectic-nematic phase transition temperature,cp. clearing point,visc. viscosity (mPa.s),T.sub.on time from switching on to reaching 90% of the maximum contrastT.sub.off time from switching off to reaching 10% of the maximum contrast______________________________________

The SLCD is driven in multiplex operation (multiplex ratio 1:100, bias 1:11, operating voltage 18.5 volts).

All the temperatures above and below are given in .degree.C. The percentage figures are percentages by weight. The values for the switching times and viscosities are based on 20.degree. C.

EXAMPLE 1

An SLCD of the OMI type having the following parameters:

______________________________________twisting angle 180.degree.angle of incidence 1.degree.d/p (layer thickness/pitch) 0.35d..DELTA.n 0.5______________________________________ containing a liquid crystal mixture having the following parameters: ______________________________________clearing point 90.degree..DELTA.n 0.1023viscosity 19 mPa.s.DELTA..epsilon. +7.4______________________________________ and consisting of 14.7% of p-trans-4-propylcyclohexyl-benzonitrile, 5% of p-trans-4-ethylcyclohexyl-benzonitrile, 10.8% of p-trans-4-butylcyclohexyl-benzonitrile, 6% of p-trans-4-pentylcyclohexyl-benzonitrile, 5% of trans-1-p-methoxyphenyl-4-propylcyclohexane, 9.8% of trans,trans-4-methoxy-4'-propylcyclohexylcyclohexane, 8% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-methylphenyl)-ethane, 8% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-ethylphenyl)-ethane 8% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-propylphenyl)-ethane, 8% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-pentylphenyl)-ethane, 8% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-fluorophenyl)-ethane, 8% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-cyanophenyl)-ethane and 0.7% of optically active 2-octyl p-(p-n-hexylbenzoyloxy)-benzoate has a switching time of T.sub.on 73 msec and T.sub.off 90 msec.

EXAMPLE 2

An SLCD of the STN type having the following parameters:

______________________________________twisting angle 220.degree.angle of incidence 1.degree.d/p 0.5d..DELTA.n 0.85______________________________________ containing a liquid crystal mixture having the following parameters: ______________________________________clearing point 80.degree. C..DELTA.n 0.1765viscosity 19 mPa.s______________________________________ and consisting of a base mixture containing 21% of p-trans-4-propylcyclohexylbenzonitrile, 5% of trans-1-p-methoxyphenyl-4-propylcyclohexane, 6% of 2-p-ethylphenyl-5-propylpyrimidine, 6% of 2-p-propylphenyl-5-propylpyrimidine, 6% of 2-p-propylphenyl-5-pentylpyrimidine, 4% of 2-p-ethylphenyl-5-heptylpyrimidine, 4% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-methylphenyl)-ethan 4% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-ethylphenyl)-ethane 4% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-propylphenyl)-ethane, 5% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-pentylphenyl)-ethane, 5% of 4-butyl-4'-propyl-tolane, 5% of 4-pentyl-4'-propyl-tolane, 5% of 4-methoxy-4'-ethyl-tolane, 7% of 4-(trans-4-propylcyclohexyl)-4'-methoxy-tolane, 6% of 4-(trans-4-propylcyclohexyl)-4'-ethoxy-tolane and 7% of 4-(trans-4-propylcyclohexyl)-4'-propoxy-tolane and a suitable chiral component (for example 0.7% of 2-octyl p-(p-n-hexylbenzoyloxy)-benzoate) exhibits short switching times.

EXAMPLE 3

An SLCD of the STN type having the following parameters:

______________________________________twisting angle 220.degree.angle of incidence 1.degree.d/p 0.5d..DELTA.n 0.85______________________________________ containing a liquid crystal mixture having the following parameters: ______________________________________clearing point 85.degree..DELTA.n 0.1494viscosity 15 mPa.s______________________________________ and consisting of a base mixture containing 13% of p-trans-4-propylcyclohexylbenzonitrile, 7% of trans-1-p-methoxyphenyl-4-propylcyclohexane, 15% of trans-1-p-isothiocyanato-4-propylcyclohexane, 7% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-methylphenyl)-ethane, 7% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-ethylphenyl)-ethane 7% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-propylphenyl)-ethane, 7% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-pentylphenyl)-ethane, 8% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-fluorophenyl)-ethane, 9% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-cyanophenyl)-ethane 5% of 4-butyl-4'-propyl-tolane, 5% of 4-pentyl-4'-propyl-tolane, 5% of 4-butyl-4'-pentyl-tolane, 5% of 4-methoxy-4'-ethyl-tolane, and a suitable chiral component (for example 0.7% of 2-octyl p-(p-n-hexylbenzoyloxy)-benzoate) exhibits short switching times.

EXAMPLE 4

An SLCD of the OMI type having the following parameters:

______________________________________twisting angle 180.degree.angle of incidence 1.degree.d/p (layer thickness/pitch) 0.35d..DELTA.n 0.5______________________________________ containing a liquid crystal mixture having the following parameters: ______________________________________clearing point 91.degree..DELTA.n 0.1020viscosity 20.7 mPa.s.DELTA..epsilon. +6.8______________________________________ and consisting of 13% of p-trans-4-propylcyclohexyl-benzonitrile, 14.3% of 1-(trans-4-propylcyclohexyl)-2-(p-cyanophenyl)ethane, 12% of 1-(trans-4-pentylcyclohexyl)-2-(p-cyanophenyl)ethane, 7% of trans,trans-4-propoxy-4'-propylcyclohexylcyclohexane, 12% of trans,trans-4-ethoxy-4'-pentylcyclohexylcyclohexane, 6% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-methylphenyl)-ethane, 6% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-ethylphenyl)-ethane 6% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-propylphenyl)-ethane, 6% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-pentylphenyl)-ethane, 5% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-fluorophenyl)-ethane, 5% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-cyanophenyl)-ethane 4% of 4,4'-bis-(trans-4-propylcyclohexyl)-biphenyl, 3% of 4,4'-bis-(trans-4-pentylcyclohexyl)-biphenyl and 0.7% of optically active 2-octyl p-(p-n-hexylbenzoyloxy)-benzoate exhibits a switching time of T.sub.on 92 msec and T.sub.off 104 msec at an operating voltage of 21 volts.

EXAMPLE 5

An SLCD of the OMI type having the following parameters:

______________________________________twisting angle 180.degree.angle of incidence 1.degree.d/p (layer thickness/pitch) 0.35d..DELTA.n 0.5______________________________________ containing a liquid crystal mixture having the following parameters: ______________________________________clearing point 88.degree..DELTA.n 0.1003viscosity 20 mPa.s.DELTA..epsilon. +6.8______________________________________ and consisting of 5% of p-trans-4-propylcyclohexyl-benzonitrile, 5% of p-trans-4-ethylcyclohexyl-benzonitrile, 14.3% of 1-(trans-4-propylcyclohexyl)-2-(p-cyanophenyl)-ethane, 12% of 1-(trans-4-pentylcyclohexyl)-2-(p-cyanophenyl)-ethane, 5% of trans-1-p-methoxyphenyl-4-propylcyclohexane, 10% of trans,trans-4-ethoxy-4'-pentylcyclohexyl-cyclohexane, 8% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-methylphenyl)-ethane, 8% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-ethylphenyl)-ethane 8% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-propylphenyl)-ethane, 8% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-pentylphenyl)-ethane, 8% of 1-(trans-4-(trans-4-propylcyclohexyl)-cyclohexyl3-2-(p-fluorophenyl)-ethane, 8% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-cyanophenyl)-ethane and 0.7% of optically active 2-octyl p-(p-n-hexylbenzoyloxy)-benzoate exhibits a switching time of T.sub.on 79 msec and T.sub.off 94 msec at an operating voltage of 20.5 volts.

Examples of liquid crystal mixtures according to the invention which exhibit short switching times in SLCD after doping with the usual chiral components are given below:

EXAMPLE 6

A liquid crystal mixture consisting of

15% of p-trans-4-propylcyclohexylbenzonitrile, 11% of p-trans-4-butylcyclohexylbenzonitrile, 4% of trans-1-p-methoxyphenyl-4-propylcyclohexane, 14% of trans,trans-4-methoxy-4'-pentylcyclohexylcyclohexane, 14% of trans,trans-4-ethoxy-4'-pentylcyclohexylcyclohexane, 6% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-methylphenyl)-ethane, 6% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-ethylphenyl)-ethane 6% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-propylphenyl)-ethane, 6% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-pentylphenyl)-ethane, 6% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-cyanophenyl)-ethane 6% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-fluorophenyl)-ethane, 3% of 4,4'-bis-(trans-4-propylcyclohexyl)-biphenyl and 3% of 4-(trans-4-pentylcyclohexyl)-4'-(trans-4-propylcyclohexyl)-biphenyl exhibits the following parameters: ______________________________________clearing point 90.degree..DELTA.n 0.0929viscosity 18 mPa.s.DELTA..epsilon. +5.4______________________________________

EXAMPLE 7

A liquid crystal mixture consisting of

12% of p-trans-4-propylcyclohexylbenzonitrile, 10% of p-trans-4-pentylcyclohexylbenzonitrile, 7% of 2-p-cyanophenyl-5-propyl-1,3-dioxane, 18% of trans,trans-4-propoxy-4'-propylcyclohexylcyclohexane, 7% of p-fluorophenyl trans,trans-4-propylcyclohexylcyclohexane-4'-carboxylate, 7% of p-fluorophenyl trans,trans-4-pentylcyclohexylcyclohexane-4'-carboxylate, 5% of p-propylphenyl trans,trans-4-propylcyclohexylcyclohexane-4'-carboxylate, 5% of p-pentylphenyl trans,trans-4-propylcyclohexylcyclohexane-4'-carboxylate, 9% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-methylphenyl)-ethane, 10% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-fluorophenyl)-ethane and 10% of 1-�trans-4-(trans-4-pentylcyclohexyl)-cyclohexyl!-2-(p-fluorophenyl)-ethan exhibits the following parameters: ______________________________________clearing point 101.degree..DELTA.n 0.0899viscosity 20 mPa .multidot. s.DELTA..epsilon. +6.5______________________________________

EXAMPLE 8

A liquid crystal mixture consisting of

16% of p-trans-4-propylcyclohexylbenzonitrile, 11% of p-trans-4-butylcyclohexylbenzonitrile, 6% of 2-p-cyanophenyl-5-ethyl-1,3-dioxane, 9% of 2-p-cyanophenyl-5-propyl-1,3-dioxane, 2% of 4-cyano-3-fluorophenyl p-ethylbenzoate, 3% of 4-cyano-3-fluorophenyl p-propylbenzoate, 8% of trans,trans-4-propoxy-4'-propylcyclohexylcyclohexane, 7% of p-fluorophenyl trans,trans-4-propylcyclohexylcyclohexane-4'-carboxylate, 7% of p-fluorophenyl trans,trans-4-pentylcyclohexylcyclohexane-4'-carboxylate, 6% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-methylphenyl)-ethane, 6% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-ethylphenyl)�sic!-ethane, 6% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-propylphenyl)-ethane, 6% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-cyanophenyl)-ethane and 7% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-fluorophenyl)-ethan exhibits the following parameters: ______________________________________clearing point 86.degree..DELTA.n 0.1073viscosity 24 mPa .multidot. s______________________________________

EXAMPLE 9

A liquid crystal mixture consisting of

13% of p-trans-4-propylcyclohexylbenzonitrile, 11% of p-trans-4-butylcyclohexylbenzonitrile, 12% of p-trans-4-ethylcyclohexylbenzonitrile, 19% of trans,trans-4-methoxy-4'-propylcyclohexylcyclohexane, 4% of 4-(trans-4-propylcyclohexyl)-4'-methoxy-tolane, 3% of 4-(trans-4-propylcyclohexyl)-4'-ethoxy-tolane, 7% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-methylphenyl)-ethane, 7% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-ethylphenyl)-ethane 7% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-propylphenyl)-ethane, 7% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl1-2-(p-pentylphenyl)-ethane and 10% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-cyanophenyl)-ethane exhibits the following parameters: ______________________________________clearing point 90.degree..DELTA.n 0.1108viscosity 22 mPa .multidot. s______________________________________

EXAMPLE 10

A liquid crystal mixture consisting of

2% of 4-cyano-3-fluorophenyl p-ethylbenzoate, 3% of 4-cyano-3-fluorophenyl p-propylbenzoate, 8% of 4-cyano-3-fluorophenyl p-pentylbenzoate, 7% of 4-cyano-3-fluorophenyl p-(trans-4-propylcyclohexyl)-benzoate, 7% of 4-cyano-3-fluorophenyl p-(trans-4-butylcyclohexyl)-benzoate, 6% of 4-cyano-3-fluorophenyl p-(trans-4-pentylcyclohexyl)-benzoate, 16% of trans,trans-4-methoxy-4'-propylcyclohexylcyclohexane, 20% of trans,trans-4-methoxy-4'-pentylcyclohexylcyclohexane, 8% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-methylphenyl)-ethane, 8% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-ethylphenyl)-ethane 8% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-propylphenyl)-ethane and 7% of 1-(trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-pentylphenyl)-ethan exhibits the following parameters: ______________________________________clearing point 91.degree..DELTA.n 0.1003viscosity 28 mPa .multidot. s______________________________________

EXAMPLE 11

A liquid crystal mixture consisting of

20% of p-trans-4-propylcyclohexylbenzonitrile, 10% of p-trans-4-pentylcyclohexylbenzonitrile, 10% of p-trans-4-ethylcyclohexylbenzonitrile, 3% of 4-cyano-3-fluorophenyl p-ethylbenzoate, 4% of 4-cyano-3-fluorophenyl p-propylbenzoate, 7% of trans-1-p-methoxyphenyl-4-propylcyclohexane, 8% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-methylphenyl)-ethane, 8% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-ethylphenyl)-ethane 8% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-propylphenyl)-ethane, 8% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-pentylphenyl)-ethane, 8% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-fluorophenyl)-ethane and 6% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-fluorophenyl)-ethan exhibits the following parameters: ______________________________________clearing point 80.degree..DELTA.n 0.1092viscosity 19 mPa .multidot. s______________________________________

EXAMPLE 12

A liquid crystal mixture consisting of

20% of p-trans-4-propylcyclohexylbenzonitrile, 13% of p-trans-4-pentylcyclohexylbenzonitrile, 12% of p-trans-4-ethylcyclohexylbenzonitrile, 5% of 4-cyano-3-fluorophenyl p-(trans-4-propylcyclohexyl)-benzoate, 8% of trans-1-p-methoxyphenyl-4-propylcyclohexane, 7% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-methylphenyl)-ethane, 8% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-ethylphenyl)-ethane 8% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-propylphenyl)-ethane, 5% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-pentylphenyl)-ethane, 8% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-fluorophenyl)-ethane and 6% of 1-�trans-4-(trans-4-pentylcyclohexyl)-cyclohexyl!-2-(p-fluorophenyl)-ethan exhibits the following parameters: ______________________________________clearing point 83.degree..DELTA.n 0.1097viscosity 20 mPa .multidot. s______________________________________

EXAMPLE 13

A liquid crystal mixture consisting of

20% of p-trans-4-propylcyclohexylbenzonitrile, 7% of p-trans-4-pentylcyclohexylbenzonitrile, 10% of p-trans-4-ethylcyclohexylbenzonitrile, 17% of 1-(trans-4-propylcyclohexyl)-2-(p-cyanophenyl)ethane, 5% of p-fluorophenyl trans,trans-4-propylcyclohexylcyclohexane-4'-carboxylate, 5% of p-fluorophenyl trans,trans-4-pentylcyclohexylcyclohexane-4'-carboxylate, 7% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-methylphenyl)-ethane, 6% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-ethylphenyl)-ethane 6% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-propylphenyl)-ethane, 9% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-fluorophenyl)-ethane and 8% of 1-�trans-4-(trans-4-pentylcyclohexyl)-cyclohexyl!-2-(p-fluorophenyl)-ethan exhibits the following parameters: ______________________________________clearing point 84.degree..DELTA.n 0.1082viscosity 21 mPa .multidot. s______________________________________

EXAMPLE 14

A liquid crystal mixture consisting of

20% of p-trans-4-propylcyclohexylbenzonitrile, 10% of p-trans-4-pentylcyclohexylbenzonitrile, 10% of p-trans-4-ethylcyclohexylbenzonitrile, 3% of 4-cyano-3-fluorophenyl p-ethylbenzoate, 4% of 4-cyano-3-fluorophenyl�sic! p-propylbenzoate, 11% of trans-1-p-methoxyphenyl-4-propylcyclohexane, 4% of trans-4-propylcyclohexyl trans,trans-4-propylcyclohexyl-cyclohexane-4'-carboxylate, 4% of trans-4-pentylcyclohexyl trans,trans-4-propylcyclohexyl-cyclohexane-4'-carboxylate, 4% of trans-4-propylcyclohexyl trans,trans-4-butyl-cyclohexyl-cyclohexane-4'-carboxylate, 8% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-methylphenyl)-ethane, 8% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-ethylphenyl)-ethane and 6% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-propylphenyl)-ethan exhibits the following parameters: ______________________________________clearing point 77.degree..DELTA.n 0.1048viscosity 20 mPa .multidot. s______________________________________

EXAMPLE 15

A liquid crystal mixture consisting of

20% of p-trans-4-propylcyclohexylbenzonitrile, 10% of p-trans-4-pentylcyclohexylbenzonitrile, 10% of p-trans-4-butylcyclohexylbenzonitrile, 3% of 4-cyano-3-fluorophenyl p-ethylbenzoate, 4% of 4-cyano-3-fluorophenyl p-propylbenzoate, 11% of trans-1-p-methoxyphenyl-4-propylcyclohexane, 6% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl3-2-(p-methylphenyl)-ethane, 6% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-ethylphenyl)-ethane 8% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-propylphenyl)-ethane, 8% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-pentylphenyl)-ethane, 9% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-fluorophenyl)-ethane and 5% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-cyanophenyl)-ethane exhibits the following parameters: ______________________________________clearing point 81.degree..DELTA.n 0.1112viscosity 20 mPa .multidot. s______________________________________

EXAMPLE 16

A liquid crystal mixture consisting of

20% of p-trans-4-propylcyclohexylbenzonitrile, 10% of p-trans-4-pentylcyclohexylbenzonitrile, 10% of p-trans-4-butylcyclohexylbenzonitrile, 3% of 4-cyano-3-fluorophenyl p-ethylbenzoate, 4% of 4-cyano-3-fluorophenyl p-propylbenzoate, 10% of trans-1-p-methoxyphenyl-4-propylcyclohexane, 6% of p-fluorophenyl trans,trans-4-propylcyclohexylcyclohexane-4g-carboxylate, 6% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-methylphenyl)-ethane, 6% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-ethylphenyl)-ethane 8% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-propylphenyl)-ethane, 8% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-pentylphenyl)-ethane and 9% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-fluorophenyl)-ethan exhibits the following parameters: ______________________________________clearing point 80.degree..DELTA.n 0.1087viscosity 19 mPa .multidot. s______________________________________

EXAMPLE 17

A liquid crystal mixture consisting of

20% of p-trans-4-propylcyclohexylbenzonitrile, 10% of p-trans-4-pentylcyclohexylbenzonitrile, 10% of p-trans-4-butylcyclohexylbenzonitrile, 3% of 4-cyano-3-fluorophenyl p-ethylbenzoate, 4% of 4-cyano-3-fluorophenyl p-propylbenzoate, 10% of trans-1-p-methoxyphenyl-4-propylcyclohexane, 6% of p-fluorophenyl trans,trans-4-propylcyclohexylcyclohexane-4'-carboxylate, 6% of p-fluorophenyl trans,trans-4-pentylcyclohexylcyclohexane-4'-carboxylate, 5% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-methylphenyl)-ethane, 5% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-ethylphenyl)-ethane 6% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-propylphenyl)-ethane, 6% of 1-(trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-pentylphenyl)-ethane and 9% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-fluorophenyl)-ethan exhibits the following parameters: ______________________________________clearing point 81.degree..DELTA.n 0.1085viscosity 20 mPa .multidot. s______________________________________

EXAMPLE 18

A liquid crystal mixture consisting of

20% of p-trans-4-propylcyclohexylbenzonitrile, 10% of p-trans-4-pentylcyclohexylbenzonitrile, 10% of p-trans-4-butylcyclohexylbenzonitrile, 3% of 4-cyano-3-fluorophenyl p-ethylbenzoate, 4% of 4-cyano-3-fluorophenyl p-propylbenzoate, 12% of trans-1-p-methoxyphenyl-4-propylcyclohexane, 5% of p-propylphenyl trans,trans-4-propylcyclohexylcyclohexane-4'-carboxylate, 5% of p-pentylphenyl trans,trans-4-propylcyclohexylcyclohexane-4'-carboxylate, 4% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-methylphenyl)-ethane, 5% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-ethylphenyl)-ethane 5% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-propylphenyl)-ethane, 5% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-pentylphenyl)-ethane, 8% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-fluorophenyl)-ethane and 4% of 1-�trans-4-(trans-4-pentylcyclohexyl)-cyclohexyl!-2-(p-fluorophenyl)-ethan exhibits the following parameters: ______________________________________clearing point 79.degree..DELTA.n 0.1087viscosity 19 mPa .multidot. s______________________________________

EXAMPLE 19

A liquid crystal mixture consisting of

3% of 4-cyano-3-fluorophenyl p-ethylbenzoate, 4% of 4-cyano-3-fluorophenyl p-propylbenzoate, 9% of 4-cyano-3-fluorophenyl p-pentylbenzoate, 4% of 4-cyano-3-fluorophenyl p-heptylbenzoate, 6% of 4-cyano-3-fluorophenyl p-(trans-4-propylcyclohexyl)-benzoate, 6% of 4-cyano-3-fluorophenyl p-(trans-4-butylcyclohexyl)-benzoate, 19% of trans-1-p-methoxyphenyl-4-propylcyclohexane, 17% of trans,trans-4-propoxy-4'-propylcyclohexylcyclohexane, 6% of p-fluorophenyl trans,trans-4-propylcyclohexylcyclohexane-4'-carboxylate, 6% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-methylphenyl)-ethane, 6% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-ethylphenyl)-ethane 7% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-propylphenyl)-ethane and 7% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-pentylphenyl)-ethane, exhibits the following parameters: ______________________________________clearing point 79.degree..DELTA.n 0.1054viscosity 22 mPa .multidot. s______________________________________

EXAMPLE 20

A liquid crystal mixture consisting of

10% of p-trans-4-propylcyclohexylbenzonitrile, 3% of 4-cyano-3-fluorophenyl p-ethylbenzoate, 4% of 4-cyano-3-fluorophenyl p-propylbenzoate, 10% of 4-cyano-3-fluorophenyl p-pentylbenzoate, 6% of 4-cyano-3-fluorophenyl p-(trans-4-propylcyclohexyl)-benzoate, 4% of 4-cyano-3-fluorophenyl p-(trans-4-butylcyclohexyl)-benzoate, 18% of trans-1-p-methoxyphenyl-4-propylcyclohexane, 10% of trans,trans-4-propoxy-4'-propylcyclohexylcyclohexane, 6% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-methylphenyl)-ethane, 7% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-ethylphenyl)-ethane 7% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-propylphenyl)-ethan 7% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-pentylphenyl)-ethane and 8% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-fluorophenyl)-ethane exhibits the following parameters: ______________________________________clearing point 78.degree..DELTA.n 0.1085viscosity 21 mPa .multidot. s______________________________________

EXAMPLE 21

A liquid crystal mixture consisting of

20% of p-trans-4-propylcyclohexylbenzonitrile, 6% of p-trans-4-pentylcyclohexylbenzonitrile, 3% of 4-cyano-3-fluorophenyl p-ethylbenzoate, 4% of 4-cyano-3-fluorophenyl p-propylbenzoate, 9% of 4-cyano-3-fluorophenyl p-pentylbenzoate, 10% of trans-1-p-methoxyphenyl-4-propylcyclohexane, 7% of trans-1-p-ethoxyphenyl-4-propylcyclohexane, 6% of p-fluorophenyl trans,trans-4-propylcyclohexylcyclohexane-4'-carboxylate, 6% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-methylphenyl)-ethane, 6% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-ethylphenyl)-ethane 7% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-propylphenyl)-ethane, 7% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-pentylphenyl)-ethane and 9% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-fluorophenyl)-ethan exhibits the following parameters: ______________________________________clearing point 74.degree..DELTA.n 0.1101viscosity 21 mPa .multidot. s______________________________________

The mixtures of Examples 9 to 21 are particularly suitable for OMI uses.

The following Tables 1 to 16 show the composition of the mixtures of Examples 22 to 132, the individual compounds being coded as follows:

AIII1: 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-(2-p-methylphenyl)-ethan AIII2: 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-(2-p-ethylphenyl)-ethane AIII3: 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-(2-p-propylphenyl)-ethane AIII4: 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-(2-p-butylphenyl)-ethane AIII5: 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-(2-p-pentylphenyl)-ethane BIII1: trans,trans-4-propyl-4'-methoxy-cyclohexylcyclohexane BIII2: trans,trans-4-propyl-4'-ethoxy-cyclohexylcyclohexane BIII3: trans,trans-4-propyl-4'-propoxy-cyclohexylcyclohexane BIII4: trans,trans-4-pentyl-4'-methoxy-cyclohexylcyclohexane BIII5: trans,trans-4-pentyl-4'-ethoxy-cyclohexylcyclohexane BIII6: trans,trans-4-propyl-4'-butyryloxy-cyclohexylcyclohexane BIII7: trans-trans-4-propyl-4'-hexanoyloxy-cyclohexylcyclohexane BIII8: trans-4-propylcyclohexyl trans-4-propylcyclohexylcarboxylate BIII9: trans-4-propylcyclohexyl trans-4-pentylcyclohexylcarboxylate BIV1: trans-1-p-methoxyphenyl-4-propylcyclohexane BIV2: trans-1-p-ethoxyphenyl-4-propylcyclohexane BIV3: trans-1-p-butoxyphenyl-4-propylcyclohexane BIV4: trans-1-p-methoxyphenyl-4-pentylcyclohexane BIV5: trans-1-p-propylphenyl-4-pentylcyclohexane BIV6: trans-1-p-ethylphenyl-4-pentylcyclohexane BV1: p-fluorophenyl trans,trans-4-propylcyclohexylcyclohexane-4'-carboxylate BV2: p-fluorophenyl trans,trans-4-pentylcyclohexylcyclohexane-4'-carboxylate BV3: trans-4-propylcyclohexyl trans,trans-4-propylcyclohexylcyclohexane-4'-carboxylate BV4: trans-4-pentylcyclohexyl trans,trans-4-propylcyclohexylcyclohexane-4'-carboxylate BV5: trans-4-propylcyclohexyl trans,trans-4-butylcyclohexylcyclohexane-4'-carboxylate BV6: trans-4-pentylcyclohexyl trans,trans-4-butylcyclohexylcyclohexane-41-carboxylate BV7: p-propylphenyl trans,trans-4-propylcyclohexylcyclohexane-4'-carboxylate BV8: p-pentylphenyl trans,trans-4-propylcyclohexylcyclohexane-4'-carboxylate BV9: p-propylphenyl trans-trans-4-butylcyclohexylcyclohexane-4'-carboxylate BV10: p-pentylphenyl trans,trans-4-butylcyclohexylcyclohexane-4'-carboxylate BVI1: 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-fluorophenyl)-ethane BVI2: 1-�trans-4-(trans-4-pentylcyclohexyl)-cyclohexyl!-2-(p-fluorophenyl)-ethane BVIII1: 2-p-ethylphenyl-5-propyl-pyrimidine BVIII2: 2-p-propylphenyl-5-propyl-pyrimidine BVIII3: 2-p-propylphenyl-5-pentyl-pyrimidine BVIII4: 2-p-ethylphenyl-5-heptyl-pyrimidine BVIII5: 2-p-pentyloxyphenyl-5-hexyl-pyrimidine BVIII6: 2-p-heptyloxyphenyl-5-hexyl-pyrimidine BVIII7: 2-p-nonyloxyphenyl-5-hexyl-pyrimidine BVIII8: 2-p-heptyloxyphenyl-5-heptyl-pyrimidine BVIII9: 2-p-nonyloxyphenyl-5-heptyl-pyrimidine BVIII10: 2-p-hexyloxyphenyl-5-nonyl-pyrimidine BVIII11: 2-p-nonyloxyphenyl-5-nonyl-pyrimidine C1: p-trans-4-ethylcyclohexylbenzonitrile C2: p-trans-4-propylcyclohexylbenzonitrile C3: p-trans-4-butylcyclohexylbenzonitrile C4: p-trans-4-pentylcyclohexylbenzonitrile C5: 1-(trans-4-propylcyclohexyl)-2-(p-cyanophenyl)-ethane C6: 1-(trans-4-pentylcyclohexyl)-2-(p-cyanophenyl)-ethane C7: 4-ethyl-4'-cyanobiphenyl C8: 4-propyl-4'-cyanobiphenyl C9: 4-pentyl-4'-cyanobiphenyl C10: 2-p-cyanophenyl-5-propyl-1,3-dioxane C11: 2-p-cyanophenyl-5-butyl-1,3-dioxane C12: 2-p-cyanophenyl-5-pentyl-1,3-dioxane C13: trans-1-p-isothiocyanatophenyl-4-propylcyclohexane C14: 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-cyanophenyl)-ethane C15: 4-cyano-3-fluorophenyl p-ethylbenzoate C16: 4-cyano-3-fluorophenyl p-propylbenzoate C17: 4-cyano-3-fluorophenyl p-pentylbenzoate C18: 4-cyano-3-fluorophenyl p-heptylbenzoate C19: 4-cyano-3-fluorophenyl p-(trans-4-propylcyclohexyl)-benzoate C20: 4-cyano-3-fluorophenyl p-(trans-4-butylcyclohexyl)-benzoate C21: 4-cyano-3-fluorophenyl p-(trans-4-pentylcyclohexyl)-benzoate C22: 2-(3-fluoro-4-cyanophenyl)-5-pentyl-pyrimidine C23: 2-(3-fluoro-4-cyanophenyl)-5-hexyl-pyrimidine C24: 2-(3-fluoro-4-cyanophenyl)-5-heptyl-pyrimidine F1: trans-1-p-fluorophenyl-4-pentylcyclohexane F2: trans-1-p-fluorophenyl-4-hexylcyclohexane F3: trans-1-p-fluorophenyl-4-heptylcyclohexane H1: 4-butyl-4'-propyl-tolan H2: 4-pentyl-4'-propyl-tolan H3: 4-butyl-4'-pentyl-tolan H4: 4-ethyl-4'-methoxy-tolan H5: 4-methyl-4'-ethoxy-tolan H6: 4-(trans-4-propylcyclohexyl)-4'-methoxy-tolan H7: 4-(trans-4-propylcyclohexyl)-41-ethoxy-tolan H8: 4-(trans-4-propylcyclohexyl)-4'-propoxy-tolan K1: 4-ethyl-4'-(trans-4-propylcyclohexyl)-biphenyl K2: 4-ethyl-4'-(trans-4-pentylcyclohexyl)-biphenyl K3: 4-nonyl-4'-(trans-4-pentylcyclohexyl)-biphenyl K4: 4-ethyl-4'-(trans-4-pentylcyclohexyl)-2'-fluorobiphenyl K5: 1-(trans-4-pentylcyclohexyl)-2-(4'-ethyl-2'-fluorobiphenyl-4-yl)-ethane L1: 4,4'-bis-(trans-4-propylcyclohexyl)-biphenyl L2: 4-(trans-4-pentylcyclohexyl)-4'-(trans-4-propylcyclohexyl)-biphenyl L3: 4,41-bis-(trans-4-pentylcyclohexyl)-biphenyl L4: 4,4-bis-(trans-4-propylcyclohexyl)-2-fluorobiphenyl L5: 4-(trans-4-pentylcyclohexyl)-4'-(trans-4-propylcyclohexyl)-2-fluorobiphenyl L6: 4,4'-bis-(trans-4-pentylcyclohexyl)-2-fluorobiphenyl.

The data for Examples 22 to 132 are to be found in Table 17.

TABLE 1__________________________________________________________________________Percentage composition of the liquid crystal mixtures corresponding tothe Examples22 to 50 in respect of components of groups A to B V Ex- am-Com- plepound 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50__________________________________________________________________________A III 1 8 7 8 8 7 8 8 8 7 7 8 6 7 7 8 6 7 7 5 8 7 6 6 6 4 5 7 7 7A III 2 8 7 8 8 7 8 8 8 6 6 8 4 6 7 8 6 7 6 5 8 8 6 5 4 6 7 7 7A III 3 8 8 8 8 8 8 8 8 6 6 6 4 6 7 8 6 7 6 5 8 8 6 6 5 4 6 7 7 7A III 4A III 5 8 8 8 8 8 8 8 8 6 5 7 7 6 7 5 5 8 5 6 6 5 4 7 7 7 7B III 1 16 10B III 2 5B III 3 18 16B III 4 19 20 9B III 5 14B III 6B III 7B III 8B III 9B IV 1 12 19 15 17 10 17 14 15 11 2 20 7 8 12 13 10 18 18 18 12B IV 2B IV 3B IV 4 16B IV 5 5 7 5 5 7 7B IV 6B V 1 6 5B V 2 4 5B V 3 4 4B V 4 4 4B V 5 4B V 6B V 7B V 8B V 9B V 10__________________________________________________________________________ TABLE 2__________________________________________________________________________Percentage composition of the liquid crystal mixtures corresponding tothe Examples51 to 80 in respect of components of groups A to B V__________________________________________________________________________Compound Example 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65__________________________________________________________________________A III 1 9 8 8 7 8 8 8 8 9 9 9 7 8 7 7A III 2 9 9 8 7 8 8 8 7 9 9 9 7 7 7 8A III 3 9 9 8 7 8 8 7 7 9 9 9 7 8 7 8A III 4A III 5 9 9 8 7 8 8 7 7 9 9 9 7 8 7 8B III 1B III 2B III 3B III 4B III 5B III 6B III 7B III 8B III 9B IV 1 10 9 12B IV 2 10 10B IV 3B IV 4B IV 5 15 17 5 5 15 5 5 7 10B IV 6 7B V 1B V 2B V 3B V 4B V 5 4B V 6B V 7B V 8B V 9B V 10__________________________________________________________________________Compound 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80__________________________________________________________________________A III 1 7 8 8 8 8 8 7 8 7 6 5 6 7 8A III 2 8 8 7 8 8 8 7 8 7 6 6 7A III 3 8 7 7 8 8 8 7 8 7 6 5 6 7 7 8A III 4A III 5 8 7 7 8 8 8 7 8 7 7 5 5 7 7 8B III 1B III 2B III 3 10B III 4B III 5B III 6B III 7B III 8B III 9B IV 1 13B IV 2 9 11 5 10 16 8 13 9B IV 3 12B IV 4B IV 5B IV 6 7 8 4 15 10 10 10 17 10 12 10B V 1B V 2B V 3B V 4B V 5 4B V 6B V 7 5B V 8 4B V 9B V 10__________________________________________________________________________ TABLE 3__________________________________________________________________________Percentage composition of the liquid crystal mixtures corresponding tothe Examples81 to 111 in respect of components of groups A to B V__________________________________________________________________________Compound Example 81 82 83 84 85 86 87 88 89 90 91 92 93 94 95 96__________________________________________________________________________A III 1 7 5 5 5 5 5 7 8 8 7 9 8 7 8 8A III 2 7 9 5 5 5 4A III 3 7 8.1 4 7 7 8 7 7 7 8 9A III 4A III 5 7 8.1 4 5 7 8 7 7 7 9B III 1 19B III 2B III 3 14 16 15 16 16B III 4B III 5B III 6 7 5 7 9 7 7B III 7 6 6 7 7 7 7B III 8 8B III 9 8B IV 1B IV 2 12 12 8 10 10 13 19 10B IV 3 10B IV 4B IV 5B IV 6 11.7B V 1 7 7 7 7 8 8 8 8 7 8 8 8 8B V 2 7 7 7 7 8 8 8 8 7 8 8 8 8B V 3B V 4B V 5B V 6B V 7 8 6 7 6 7 6 7 7 6 7 6 6B V 8 8 7 5 6B V 9B V 10__________________________________________________________________________Compound 97 98 99 100 101 102 103 104 105 106 107 108 109 110 111__________________________________________________________________________A III 1 8 4 8 5 11 9 9 9 7 8A III 2 8A III 3 8 8 8 6 7 10 9 9 12 10 9 10 10 9 10A III 4A III 5 7 9 8 5 10 9 8 11 9 11B III 1 7B III 2 12 13 17 14 22 21 10B III 3B III 4 5 11 6 12 11 5B III 5B III 6B III 7B III 8 8 9B III 9 8 9B IV 1 8 9B IV 2 19 17 19 9 10 5 15 5 7 12 10B IV 3 10 3 10 9B IV 4B IV 5B IV 6B V 1 8 8 8 7 7 9 9 9 9 8 9 9 9 7B V 2 8 8 8 6 6 9 9 9 9 8 9 9 9 6B V 3 3B V 4 2B V 5 3 2B V 6 3 2B V 7 6 9 5 3 4B V 8 9 5B V 9 4 3B V 10 4 3__________________________________________________________________________ TABLE 4__________________________________________________________________________Percentage composition of the liquid crystal mixtures corresponding tothe Examples112 to 132 in respect of components of groups A to B V__________________________________________________________________________Compound Example 112 113 114 115 116 117 118 119 120 121__________________________________________________________________________A III 1A III 2A III 3 11 8 9 4 7 11 11 12 4 11A III 4A III 5 10 13 8 6 10 12 12 10B III 1 12 15 12B III 2B III 3 12 14 12 19 19 20 15 18 19 20B III 4 12 12 10 7 8 12 10B III 5 7 10 11 8 9 7 11B III 6B III 7B III 8B III 9B IV 1 5 5B IV 2B IV 3B IV 4B IV 5B IV 6B V 1 7 7 7 8 7 8B V 2 6 6 6 6 8 6B V 3B V 4B V 5B V 6B V 7 4B V 8 4B V 9 5B V 10__________________________________________________________________________Compound 122 123 124 125 126 127 128 129 130 131 132__________________________________________________________________________A III 1 6 5 5 9 9 9 5A III 2 6 5 4A III 3 11 12 5 9 6 9 9 7 6A III 4A III 5 12 12 5 5 8 5 8 8 5B III 1 14 7B III 2B III 3 15 18 10 12 12 12B III 4 7 8 10 8 6B III 5 8 9 11 10 11B III 6 7 9B III 7 7 7B III 8B III 9B IV 1B IV 2B IV 3B IV 4B IV 5B IV 6B V 1 7 7 7 7 7 9 9 7B V 2 8 7 7 7 6 9 9 6B V 3 5 3B V 4 5 2B V 5 4 3B V 6 3B V 7 4 7 6 4 5 5B V 8 4 5 5 5B V 9 5 4 4B V 10 4__________________________________________________________________________ TABLE 5__________________________________________________________________________Percentage composition of the liquid crystal mixtures corresponding tothe Examples22 to 50 in respect of components of groups B VI to C 10__________________________________________________________________________Compound Example 22 23 24 25 26 27 28 29 30 31 32 33 34__________________________________________________________________________B VI 1 9 8 8 9 8 8 8 8 9 8B VI 2 8 8 8 8 8 8B VIII 1 5 5 5 5B VIII 2 5 4 5B VIII 3B VIII 4B VIII 5B VIII 6B VIII 7B VIII 8B VIII 9B VIII 10B VIII 11C 1 7 15 10 10 15 15C 2 15 15 15 15 15 13 14 15 22 20 20 22 22C 3 14 17 14C 4 15 15 15 15 10 7 10 10C 5 14 14 14 17C 6C 7C 8 3C 9 7C 10__________________________________________________________________________Compound 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50__________________________________________________________________________B VI 1 8 8 7 7 8B VI 2 6 6B VIII 1 5B VIII 2 5 5 5B VIII 3B VIII 4 5 5B VIII 5 5B VIII 6 4B VIII 7 4B VIII 8 5 5B VIII 9 4 5B VIII 10 5B VIII 11 4C 1 12 15 10 12C 2 13 18 20 22 20 20 20 15 13 10 17C 3 11 4 14 10C 4 7 10 13 10 10C 5 11C 6C 7 6 10C 8 9C 9C 10__________________________________________________________________________ TABLE 6__________________________________________________________________________Percentage composition of the liquid crystal mixtures corresponding tothe Examples51 to 80 in respect of components of groups B VI to C 10__________________________________________________________________________ExampleCompound 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65__________________________________________________________________________B VI 1 9 8 8 8 9 9 10 10 10 9 9 8 7B VI 2 8 8 9 9 9 8 7 7B VIII 1 6 5 7 7 7B VIII 2 6 5 7 7 7B VIII 3 7 7B VIII 4 7 5 7 7 7B VIII 5B VIII 6B VIII 7B VIII 8 5B VIII 9 5 5 5B VIII 10 4 5 5B VIII 11C 1C 2 10 14 14 18 23 15 15 15 10 19 19 15C 3 5C 4 15 15C 5 11 11C 6C 7C 8 10 10C 9 10 10C 10__________________________________________________________________________ExampleCompound 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80__________________________________________________________________________B VI 1 7 10 9B VI 2 7B VIII 1 7 7 7 6 7 7 7 6 6B VIII 2 7 7 7 7 7 7 7 7 6B VIII 3 7 7B VIII 4 7 7 7 7 7 7 7 7 7B VIII 5B VIII 6B VIII 7B VIII 8 5B VIII 9 5B VIII 10 5B VIII 11C 1C 2 15 18 23 15 10 18 18 15 16C 3 5C 4 12 6 10C 5C 6C 7C 8C 9C 10 8 8 8__________________________________________________________________________ TABLE 7__________________________________________________________________________Percentage composition of the liquid crystal mixtures corresponding tothe Examples81 to 111 in respect of components of groups B VI to C 10__________________________________________________________________________ExampleCompound 81 82 83 84 85 86 87 88 89 90 91 92 93 94 95 96 97 98 99__________________________________________________________________________B VI 1 9 8.1 11 11 10 10 7 8 7 10B VI 2 11 11 10 10 10B VIII 1 7 6.3B VIII 2 7 6.3B VIII 3 7 6.3B VIII 4 7 6.3B VIII 5B VIII 6B VIII 7B VIII 8B VIII 9B VIII 10B VIII 11C 1C 2 10 10 12 12 12 12 12 12 12 12 12 10 10 10 10 10 8C 3 8 16 8 10 11 11 11 11 10 11 10 9 9 9 9 9C 4 10 14 10 8 7 7 7 7 7 7 7 7 7 7 6 6C 5C 6C 7C 8C 9C 10__________________________________________________________________________ExampleCompound 100 101 102 103 104 105 106 107 108 109 110 111__________________________________________________________________________B VI 1 10 11 11 10B VI 2 10 11B VIII 1B VIII 2B VIII 3B VIII 4B VIII 5B VIII 6B VIII 7B VIII 8B VIII 9B VIII 10B VIII 11C 1C 2 10 20 9 9 19 9 9 11 10 10 12 12C 3 7 12 13 12 12 12 13 13 13 10C 4 3 7 7 7 7 8 8 8 5C 5C 6C 7C 8C 9C 10__________________________________________________________________________ TABLE 8__________________________________________________________________________Percentage composition of the liquid crystal mixtures corresponding tothe Examples112 to 132 in respect of components of groups B VI to C__________________________________________________________________________10ExampleCompound 112 113 114 115 116 117 118 119 120 121 122__________________________________________________________________________B VI 1 10 10 10B VI 2B VIII 1B VIII 2B VIII 3B VIII 4B VIII 5B VIII 6B VIII 7B VIII 8B VIII 9B VIII 10B VIII 11C 1C 2 12 12 13 10 14 17 18 16 10 17 18C 3 10 10 10 14 11 14C 4 5 5 8 10 7 6 10 6C 5C 6C 7C 8C 9C 10__________________________________________________________________________ExampleCompound 123 124 125 126 127 128 129 130 131 132__________________________________________________________________________B VI 1 10 10 10 11 10B VI 2 10 10 10 11 10B VIII 1B VIII 2B VIII 3B VIII 4B VIII 5B VIII 6B VIII 7B VIII 8B VIII 9B VIII 10B VIII 11C 1 5C 2 16 10 12 12 8 10 8 10 20 10C 3 8 10 15 12 17C 4 10 8 6C 5C 6C 7C 8C 9C 10__________________________________________________________________________ TABLE 9__________________________________________________________________________Percentage composition of the liquid crystal mixtures corresponding tothe Examples22 to 50 in respect of components of groups C 11 to HCom- Examplepound 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50__________________________________________________________________________C 11C 12C 13 15C 14 8 8 8 11 11 10 5 6 11 9 10 9C 15 3 2 2 3 4 4 4 2C 16 4 3 3 4 5 5 5 3C 17 8 8 9 12 12 9C 18 6 6 6 9C 19 4 4 4 7 4 6 5 6 4 5C 20 7 7 5 7C 21 6 7 3 4C 22C 23C 24F 1F 2F 3H 1 3 5H 2 5 4 5H 3 5H 4 5 4H 5 4H 6 4 6 6 5 3H 7 3 5 5 4 4H 8 7 7 6 3__________________________________________________________________________ TABLE 10__________________________________________________________________________Percentage composition of the liquid crystal mixtures corresponding tothe Examples51 to 80 in respect of components of groups C 11 to HCom- Examplepound 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80__________________________________________________________________________C 11 8 8C 12 8 8 8C 13 10 15 13 13 10 10 15 15 15 10 10 10 15C 14 10 10 9 10 10C 15 3C 16 3 3 3 3C 17 4 4C 18C 19 4C 20C 21C 22 4 4 4 4 4C 23 4 5 4 5 5C 24 5 5 5 5F 1F 2F 3H 1 5 5 5 5 5 7H 2 5 4 5 5 5 7H 3 5 5 5H 4H 5 3H 6H 7H 8__________________________________________________________________________ TABLE 11__________________________________________________________________________Percentage composition of the liquid crystal mixtures corresponding tothe Examples81 to 111 in respect of components of groups C 11 to H__________________________________________________________________________ExampleCompound 81 82 83 84 85 86 87 88 89 90 91 92 93 94 95 96 97 98 99__________________________________________________________________________C 11C 12C 13 15C 14 10 9C 15 2.7 3C 16 2.7 4C 17 7C 18 4C 19 5.4 5C 20 5C 21 4C 22C 23C 24F 1F 2F 3H 1H 2H 3H 4H 5H 6 3H 7 4H 8 4__________________________________________________________________________ExampleCompound 100 101 102 103 104 105 106 107 108 109 110 111__________________________________________________________________________C 11C 12C 13C 14C 15C 16C 17C 18C 19C 20C 21C 22C 23C 24F 1 11 10F 2 9F 3 8 10H 1H 2H 3H 4H 5H 6H 7H 8__________________________________________________________________________ TABLE 12__________________________________________________________________________Percentage composition of the liquid crystal mixtures corresponding tothe Examples112 to 132 in respect of components of groups C 11 to HExampleCompound 112 113 114 115 116 117 118 119 120 121 122 123 124 125 126 127 128 129 130 131 132__________________________________________________________________________C 11C 12C 13C 14 6C 15 4 4 4 4 4 4 2C 16 5 4 4 5 4 4 3C 17 5C 18 5C 19C 20C 21C 22C 23C 24F 1 11 10 11F 2 9 9F 3 8 10 8H 1H 2H 3H 4H 5H 6H 7H 8__________________________________________________________________________ TABLE 13__________________________________________________________________________Percentage composition of the liquid crystal mixtures corresponding tothe Examples22 to 50 in respect of components of groups K and LCom- Examplepound 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50__________________________________________________________________________K 1K 2K 3K 4K 5L 1L 2L 3L 4 5 4 5 4L 5 3 5 3 4 3L 6 5 4 2__________________________________________________________________________ TABLE 14__________________________________________________________________________Percentage composition of the liquid crystal mixtures corresponding tothe Examples51 to 80 in respect of components of groups K and LExampleCompound 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80__________________________________________________________________________K 1 6 6 10 7 8 8 9 8K 2 6 6 7 8 8 8 8K 3 7 7 6K 4 9K 5L 1 5 5 5 4 4 5 4 4L 2 5 5 4 3 4 5 4 4L 3 4 4 6 5 5L 4 4L 5 4L 6 4__________________________________________________________________________ TABLE 15__________________________________________________________________________Percentage composition of the liquid crystal mixtures corresponding tothe Examples81 to 111 in respect of components of groups K and LExampleCompound 81 82 83 84 85 86 87 88 89 90 91 92 93 94 95 96 97 98 100 101 102 103 104 105 106 107 108 109 110__________________________________________________________________________ 111K 1K 2K 3K 4K 5 5L 1L 2 3 3L 3L 4 5 4L 5 5 4L 6 5__________________________________________________________________________ TABLE 16__________________________________________________________________________Percentage composition of the liquid crystal mixtures corresponding tothe Examples112 to 132 in respect of components of groups K and LExampleCompound 112 113 114 115 116 117 118 119 120 121 122 123 124 125 126 127 128 129 131 132__________________________________________________________________________K 1K 2K 3K 4K 5L 1 5 5 6 5 6L 2 5 5 6 5 6L 3 4L 4 4 4L 5 4L 6__________________________________________________________________________ TABLE 17__________________________________________________________________________Physical data for Examples 22 to 132 Viscosity Threshold voltage Clear point at 20.degree. V (10, 0, 20)Example (.degree.C.) (mPa .multidot. S) .DELTA.n (Volts) Preferred use__________________________________________________________________________22 79 16 0.1068 2.06 (1ST) TFT23 76 15 0.0969 2.06 (1ST) TFT24 82 17 0.1019 2.00 TFT25 80 16 0.1019 1.98 (5.44) TFT26 75 16 0.1043 2.05 (5.38) TFT27 73 15 0.1059 1.89 (5.18) TFT28 81 17 0.1106 -- TFT29 82 17 0.1019 -- TFT30 77 22 0.1147 1.82 (10.4) STN31 84 21 0.1082 1.96 (5.12) OMI32 77 20 0.1048 1.45 (5.31) OMI33 79 25 0.1266 1.75 (9.81) STN34 83 25 0.1223 1.94 (10.1) STN35 90 22 0.1108 1.99 (5.03) OMI36 91 28 0.1003 1.34 (5.57) OMI37 111 23 0.1831 2.38 (7.07) TFT 2nd38 108 22 0.0999 2.42 (5.60) TFT 2nd39 79 25 0.1331 1.82 (9.42) STN40 105 22 0.1447 2.30 (8.32) GH41 80 19 0.1092 1.49 (5.07) OMI42 83 20 0.1097 1.70 (5.02) OMI43 82 18 0.1576 2.17 (2nd) NTN44 99 41 0.1450 1.46 (2nd) STN Low Duty45 87 37 0.1405 1.39 (2nd) STN Low Duty46 89 34 0.1406 1.32 (2nd) STN Low Duty47 64 31 0.1019 1.61 (5.51) Low DN mpx48 86 19 0.1115 2.70 (2nd) DSTN49 81 21 0.1310 2.68 (2nd) DSTN50 82 16 0.1240 2.55 (2nd) DSTN51 82 16 0.1181 2.70 (2nd) DSTN52 81 16 0.1292 2.59 (2nd) DSTN53 88 27 0.1355 2.71 (2nd) DSTN54 80 18 0.1509 2.64 (2nd) DSTN55 81 14 0.1226 2.81 DSTN56 85 16 0.1144 2.83 DSTN57 80 18 0.1339 2.75 (2nd) DSTN58 78 17 0.1335 2.45 (2nd) DSTN59 81 14 0.1072 2.29 DSTN60 89 16 0.1271 2.82 (2nd) DSTN61 93 18 0.1186 2.83 (2nd) DSTN62 84 20 0.1250 2.59 DSTN63 78 -- -- -- DSTN64 76 SW -- -- DSTN65 80 -- -- -- DSTN66 85 SW -- -- DSTN67 80 18 0.1339 2.75 (2nd) DSTN High Response68 78 17 0.1335 2.45 (2nd) TYPE69 81 -- -- -- TYPE70 72 27 0.1480 2.53 TYPE71 83 24 0.1313 -- TYPE72 79 23 0.1366 -- TYPE73 76 SW -- -- TYPE74 81 18 0.1387 2.64 TYPE75 86 18 0.1251 2.708 DSTN76 80 18 0.1180 2.273 DSTN77 84 17 0.1167 2.705 DSTN78 79 23 0.1189 2.43 (2nd) DSTN79 85 20 0.1122 2.55 (2nd) DSTN80 81 19 0.1219 2.29 DSTN81 81 18 0.1387 2.64 DSTN82 75 22 0.1241 2.21 (2nd) DSTN83 128 40 0.1446 1.83 STN84 110 23 0.0936 2.10 (1st) TFT TV85 111 24 0.0933 2.06 (1st)86 106 22 0.0934 2.02 (1st) TFT87 105 22 0.0922 2.02 (1st) TFT88 91 19 0.0939 2.03 (1st) TFT TV89 91 19 0.0945 2.00 (1st) TFT TV90 91 18 0.0929 2.08 (1st) TFT91 89 18 0.0916 1.98 (1st) TFT92 89 18 0.0916 1.98 (1st) TFT93 90 18 0.0923 2.03 (1st) TFT94 88 19 0.0903 2.07 (1st) TFT95 87 17 0.0979 1.96 TFT96 94 18 0.0914 2.17 (1st) TFT TV97 87 17 0.0979 1.96 TFT98 104 19 0.0985 2.18 TFT99 88 17 0.0967 2.10 TFT TV100 92 16 0.0812 2.11 TFT101 88 17 0.0873 1.86 TFT102 93 -- 0.0950 2.27 TFT TV103 90 18 0.0910 2.01 TFT TV104 91 18 0.0901 1.88 TFT TV105 93 18 0.0901 2.04 TFT TV106 94 19 0.0871 2.04 TFT TV107 82 18 0.0895 1.81 TFT TV108 79 17 0.0856 1.80 TFT TV109 80 16 0.0867 1.80 TFT TV110 80 19 0.0865 1.67 TFT TV111 81 -- 0.0909 1.82 TFT112 81 17 0.0845 1.83 TFT TV USE113 83 17 0.0827 1.88 TFT TV USE114 77 17 0.0858 1.74 TFT TV USE115 83 19 0.0896 1.70116 84 19 0.0919 1.90117 87 19 0.0949 1.70118 80 19 0.0902 1.54119 86 19 0.086 1.78120 82 19 0.0896 1.70 TFT121 82 19 0.0949 1.70 TFT122 79 19 0.0902 1.54 TFT123 86 19 0.086 1.78 TFT124 90 23 0.0959 1.55 OMI125 106 22 0.0934 2.02 TFT TV126 105 22 0.0922 2.02 TFT TV127 90 19 0.0816 2.14 TFT TV128 92 16 0.0812 2.11 TFT129 90 19 0.0815 2.03 TFT TV130 90 19 0.0835 1.95 TFT TV131 88 17 0.0873 1.86 TFT132 92 16 0.0812 2.11 TFT__________________________________________________________________________

The following examples relate to further mixtures according to the invention:

EXAMPLE 133

A liquid crystal mixture consisting of:

14.7% of p-trans-4-propylcyclohexyl-benzonitrile, 5% of p-trans-4-ethylcyclohexyl-benzonitrile, 10.8% of p-trans-4-butylcyclohexyl-benzonitrile, 6% of p-trans-4-pentylcyclohexyl-benzonitrile, 5% of trans-1-p-methoxyphenyl-4-propylcyclohexane, 9.8% of trans,trans-4-methoxy-4'-propylcyclohexylcyclohexane, 8% of 1-�p-(trans-4-propylcyclohexyl)-phenyl!-2-(p-propylphenyl)-ethane, 8% of 1-�p-(trans-4-pentylcyclohexyl)-phenyl!-2-(p-propylphenyl)-ethane, 8% of 1-�p-(trans-4-pentylcyclohexyl)-phenyl!-2-(trans-4-propylcyclohexyl)-ethane, 8% of 1-�p-(trans-4-pentylcyclohexyl)-phenyl!-2-(trans-4-pentylcyclohexyl)-ethane, 8% of 1-(trans-4-propylcyclohexyl)-2-�trans-4-(p-cyanophenyl)-cyclohexyl!-ethane 8% of p-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-fluorobenzene and 0.7% of optically active 2-octyl p-(p-n-hexylbenzoyloxy)-benzoate is prepared.

EXAMPLE 134

A liquid crystal mixture consisting of a base mixture containing

21% of p-trans-4-propylcyclohexylbenzonitrile, 5% of trans-1-p-methoxyphenyl-4-propylcyclohexane, 6% of 2-p-ethylphenyl-5-propylpyrimidine, 6% of 2-p-propylphenyl-5-propylpyrimidine, 6% of 2-p-propylphenyl-5-pentylpyrimidine, 4% of 2-p-ethylphenyl-5-heptylpyrimidine, 4% of 1-(trans-4-propylcyclohexyl)-2-�trans-4-(p-propylphenyl)-cyclohexyl!-ethane, 4% of 1-(trans-4-pentylcyclohexyl)-2-�trans-4-(p-propylphenyl)-cyclohexyl!-ethane, 4% of p-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-ethylbenzene, 5% of 1,4-bis-(trans-4-propylcyclohexyl)-benzene, 5% of 4-butyl-4'-propyl-tolane, 5% of 4-pentyl-4'-propyl-tolane, 5% of 4-methoxy-4'-ethyl-tolane, 7% of 4-(trans-4-propylcyclohexyl)-4'-methoxy-tolane, 6% of 4-(trans-4-propylcyclohexyl)�sic!-4'-ethoxytolane and 7% of 4-(trans-4-propylcyclohexyl)-4'-propoxy-tolane and a suitable chiral component (for example 0.7% of 2-octyl p-(p-n-hexylbenzoyloxy)-benzoate) exhibits short switching times.

EXAMPLE 135

A liquid crystal mixture consisting of:

13% of p-trans-4-propylcyclohexyl-benzonitrile, 14.3% of 1-(trans-4-propylcyclohexyl)-2-(p-cyanophenyl)-ethane, 12% of 1-(trans-4-pentylcyclohexyl)-2-(p-cyanophenyl)-ethane, 7% of 5-propyl-2-(trans-4-ethylcyclohexyl)-trans-1,3-dioxane, 12% of 4-(trans-4-propylcyclohexyl)-1-propylcyclohex-1-ene, 6% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-methylphenyl)-ethane, 6% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-ethylphenyl)-ethane 6% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-propylphenyl)-ethane, 6% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-pentylphenyl)-ethane, 5% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(3,4-difluorophenyl)-ethane, 5% of 1-(trans-4-propylcyclohexyl)-2-�trans-4-(3-fluoro-4-cyanophenyl)-cyclohexyl!-ethane, 4% of 4,4'-bis-(trans-4-propylcyclohexyl)-biphenyl, 3% of 4,4'-bis-(trans-4-pentylcyclohexyl)-biphenyl and 0.7% of optically active 2-octyl p-(p-n-hexylbenzoyloxy)-benzoate is prepared.

EXAMPLE 136

A liquid crystal mixture consisting of:

5% of p-trans-4-propylcyclohexyl-benzonitrile, 5% of p-trans-4-ethylcyclohexyl-benzonitrile, 14.3% of 1-(trans-4-propylcyclohexyl)-2-(p-cyanophenyl)ethane, 12% of 1-(trans-4-pentylcyclohexyl)�sic!-2-(p-cyanophenyl)-ethane, 10% of trans-1-p-methoxyphenyl-4-propylcyclohexane, 5% of 1,2-bis-(trans-4-propylcyclohexyl)-ethane, 8% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-methylphenyl)-ethane, 8% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-ethylphenyl)-ethane 8% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-propylphenyl)-ethane, 8% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-pentylphenyl)-ethane, 8% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-3,4-difluorobenzene, 8% of 4-(trans-4-propylcyclohexyl)-3'-fluoro-4'-cyanobiphenyl and 0.7% of optically active 2-octyl p-(p-n-hexylbenzoyloxy)-benzoate is prepared.

EXAMPLE 137

A liquid crystal mixture consisting of:

15% of p-trans-4-propylcyclohexylbenzonitrile, 11% of p-trans-4-butylcyclohexylbenzonitrile, 4% of trans-1-p-methoxyphenyl-4-propylcyclohexane, 14% of trans,trans-4-methoxy-4'-pentylcyclohexylcyclohexane, 14% of trans,trans-4-ethoxy-4'-pentylcyclohexylcyclohexane, 6% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-methylphenyl)-ethane, 6% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-ethylphenyl)-ethane 6% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-propylphenyl)-ethane, 6% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-pentylphenyl)-ethane, 6% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-cyanophenyl)-ethane 6% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-fluorophenyl)-ethane, 3% of 4,4'-bis-(trans-4-propylcyclohexyl)-biphenyl and 3% of 2-(p-pentylphenyl)-5-propyl-pyridine is prepared.

EXAMPLE 138

An SLC display element having the following parameters:

______________________________________twisting angle 220.degree.angle of incidence 1.degree.d/p (layer thickness/pitch) 0.36d..DELTA.n 0.85______________________________________ containing a liquid crystal mixture having the following parameters: ______________________________________clearing point 94.degree..DELTA.n 0.1238 (589 nm)viscosity 25 mPa.s.DELTA..epsilon. +7.5.epsilon..sub..perp. 5.9______________________________________ and consisting of 15% of p-trans-4-propylcyclohexyl-benzonitrile, 11% of p-trans-4-butylcyclohexyl-benzonitrile, 11% of p-trans-4-pentylcyclohexyl-benzonitrile, 5% of p-trans-4-ethylcyclohexyl-benzonitrile, 7% of 2,3-difluoro-4-ethoxyphenyl trans-4-propylcyclohexanecarboxylate, 6% of 2,3-difluoro-4-ethoxyphenyl trans-4-pentylcyclohexanecarboxylate, 7% of 2,3-difluoro-4-ethoxyphenyl trans,trans-4-propylcyclohexylcyclohexane-4'-carboxylate, 5% of 4-(trans-4-propylcyclohexyl)-2',3'-difluoro-4'-ethoxy-tolane, 5% of 4-(trans-4-pentylcyclohexyl)-2',3'-difluoro-4'-ethoxy-tolane, 6% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-methylphenyl)-ethane, 6% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-propylphenyl)-ethane, 6% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-pentylphenyl)-ethane, 4% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-cyanophenyl)-ethane and 6% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-fluorophenyl)-ethane, exhibits a characteristic line gradient V.sub.50 /V.sub.10 of 2.7%.

In an SLC display element of relatively high angle of incidence (5.degree.), d/p=0.40, d..DELTA.n=0.85 and a twisting angle of 220.degree., the same mixture exhibits a gradient V.sub.50 /V.sub.10 of 2.9% and a value .beta. of the angular dependency of the contrast of 0.4%.

EXAMPLE 139

An SLC display element having the following parameters:

______________________________________twisting angle 220.degree.angle of incidence 1.degree.d/p (layer thickness/pitch) 0.40d..DELTA.n 0.85______________________________________ containing a liquid crystal mixture having the following parameters: ______________________________________clearing point 91.degree..DELTA.n 0.1085 (589 nm)viscosity 25 mPa.s.DELTA..epsilon. +8.2.epsilon..sub..perp. 5.1______________________________________ and consisting of 15% of p-trans-4-propylcyclohexyl-benzonitrile, 11% of p-trans-4-butylcyclohexyl-benzonitrile, 11% of p-trans-4-pentylcyclohexyl-benzonitrile, 5% of p-trans-4-ethylcyclohexyl-benzonitrile, 7% of 2,3-difluoro-4-ethoxyphenyl trans-4-propylcyclohexanecarboxylate, 6% of 2,3-difluoro-4-ethoxyphenyl trans-4-pentylcyclohexanecarboxylate, 7% of 2,3-difluoro-4-ethoxyphenyl trans,trans-4-propylcyclohexylcyclohexane-4'-carboxylate, 8% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-methylphenyl)-ethane, 6% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-propylphenyl)-ethane, 8% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-pentylphenyl)-ethane, 8% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-cyanophenyl)-ethane and 8% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-fluorophenyl)-ethan exhibits a characteristic line gradient V.sub.50 /V.sub.10 of 2.2%.

EXAMPLE 140

An SLC display element having the following parameters:

______________________________________twisting angle 220.degree.angle of incidence 1.degree.d/p (layer thickness/pitch) 0.41d..DELTA.n 0.85______________________________________ containing a liquid crystal mixture having the following parameters: ______________________________________clearing point 88.degree..DELTA.n 0.1569 (589 nm)viscosity 22 mPa.s.DELTA..epsilon. +7.8.epsilon..sub..perp. 5.9______________________________________ and consisting of 15% of p-trans-4-propylcyclohexyl-benzonitrile, 11% of p-trans-4-butylcyclohexyl-benzonitrile, 11% of p-trans-4-pentylcyclohexyl-benzonitrile, 5% of p-trans-4-ethylcyclohexyl-benzonitrile, 9% of 4-propyl-2',3'-difluoro-4'-ethoxy-tolane, 9% of 4-pentyl-2',3'-difluoro-4'-ethoxy-tolane, 6% of 4-(trans-4-propylcyclohexyl)-2',3'-difluoro-4'-ethoxy-tolane, 6% of 4-(trans-4-pentylcyclohexyl)-2',3'-difluoro-4'-ethoxy-tolane, 6% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-methylphenyl)-ethane, 6% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-propylphenyl)-ethane, 6% of 1-�trans-4-(trans-4-propylcyclohexyl)�sic!-cyclohexyl!-2-(p-pentylphenyl)-ethane, 4% of 1-�trans-4-(trans-4-propylcyclohexyl)�sic!-cyclohexyl!-2-(p-cyanophenyl)-ethane, 6% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-fluorophenyl)-ethane, exhibits a characteristic line gradient V.sub.50 /V.sub.10 of 3.7%.

EXAMPLE 141

An SLC display element having the following parameters:

______________________________________twisting angle 220.degree.angle of incidence 1.degree.d/p (layer thickness/pitch) 0.42d..DELTA.n 0.85______________________________________ containing a liquid crystal mixture having the following parameters: ______________________________________clearing point 94.degree..DELTA.n 0.1420 (589 nm)viscosity 23 mPa.s.DELTA..epsilon. +8.3.epsilon..sub..perp. 5.0______________________________________ and consisting of 15% of p-trans-4-propylcyclohexyl-benzonitrile, 11% of p-trans-4-butylcyclohexyl-benzonitrile, 11% of p-trans-4-pentylcyclohexyl-benzonitrile, 5% of p-trans-4-ethylcyclohexyl-benzonitrile, 12% of 4-pentyl-2',3'-difluoro-4'-ethoxy-tolane, 5% of 4-(trans-4-propylcyclohexyl)-2',3'-difluoro-4'-ethoxy-tolane, 6% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-methylphenyl)-ethane, 6% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-propylphenyl)-ethane, 6% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-pentylphenyl)-ethane, 4% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-cyanophenyl)-ethane and 6% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-fluorophenyl)-ethan exhibits a characteristic line gradient V.sub.50 /V.sub.10 of 3.6%.

EXAMPLE 142

An SLC display element having the following parameters:

______________________________________twisting angle 220.degree.angle of incidence 1.degree.d/p (layer thickness/pitch) 0.44d..DELTA.n 0.85______________________________________ containing a liquid crystal mixture having the following parameters: ______________________________________clearing point 92.degree..DELTA.n 0.1250 (589 mn)viscosity 21 mPa.s.DELTA..epsilon. +8.2.epsilon..sub..perp. 4.3______________________________________ and consisting of 15% of p-trans-4-propylcyclohexyl�sic!-benzonitrile, 11% of p-trans-4-butylcyclohexyl-benzonitrile, 11% of p-trans-4-pentylcyclohexyl-benzonitrile, 5% of p-trans-4-ethylcyclohexyl-benzonitrile, 10% of 4-pentyl-2',3'-difluoro-4-ethoxy-tolane, 8% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-methylphenyl)-ethane, 8% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-ethylphenyl)-ethane 8% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-propylphenyl)-ethane, 8% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-pentylphenyl)-ethane, 8% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-cyanophenyl)-ethane and 8% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-fluorophenyl)-ethan exhibits a characteristic line gradient V.sub.50 /V.sub.10 of 4.0%.

EXAMPLE 143

An SLC display element having the following parameters:

______________________________________twisting angle 220.degree.angle of incidence 1.degree.d/p (layer thickness/pitch) 0.37d..DELTA.n 0.85______________________________________ containing a liquid crystal mixture having the following parameters: ______________________________________clearing point 88.degree..DELTA.n 0.1544 (589 nm)viscosity 26 mPa.s.DELTA..epsilon. +7.3.epsilon..sub..perp. 6.4______________________________________ and consisting of 15% of p-trans-4-propylcyclohexyl-benzonitrile, 11% of p-trans-4-butylcyclohexyl-benzonitrile, 11% of p-trans-4-pentylcyclohexyl-benzonitrile, 5% of p-trans-4-ethylcyclohexyl-benzonitrile, 7% of 2,3-difluoro-4-ethoxyphenyl trans-4-propylcyclohexanecarboxylate, 6% of 2,3-difluoro-4-ethoxyphenyl trans-4-butylcyclohexanecarboxylate, 7% of 2,3-difluoro-4-ethoxyphenyl trans-4-pentylcyclohexanecarboxylate, 6% of 4-propyl-2',3'-difluoro-4'-ethoxy-tolane, 4% of 4-(trans-4-propylcyclohexyl)-2',3'-difluoro-4'-ethoxy-tolane, 6% of 4-(trans-4-propylcyclohexyl)-4'-methoxy-tolane, 5% of 4-(trans-4-propylcyclohexyl)-4'-ethoxy-tolane, 7% of 4-(trans-4-propylcyclohexyl)-4'-propoxy-tolane, 6% of 1-�trans-4-(trans-4-propylcyclohexyl)-cyclohexyl!-2-(p-methylphenyl)-ethane and 4% of 1-�trans-(trans-4-propylcyclohexyl)-cyclo-hexyl!-2-(p-propylphenyl)-ethane exhibits a characteristic line gradient V.sub.50 /V.sub.10 of 2.7% and an angular dependency of the contrast .beta.=0.9%.

In the tables which follow, properties and composition of the mixtures of Examples 144 to 428 are given, the individual compounds having the following code:

ECCP-31: 1-�trans-4-(trans-4-propylcyclohexyl)cyclohexyl!-(2-p-methylphenyl)ethane ECCP-32: 1-�trans-4-(trans-4-propylcyclohexyl)cyclohexyl!-(2-p-ethylphenyl)-ethane ECCP-33: 1-�trans-4-(trans-4-propylcyclohexyl)cyclohexyl!-(2-p-propylphenyl)-ethane ECCP-34 1-�trans-4-(trans-4-propylcyclohexyl)cyclohexyl!-(2-p-butylphenyl)-ethane ECCP-35: 1-�trans-4-(trans-4-propylcyclohexyl)cyclohexyl!-(2-p-pentylphenyl)-ethane CCH-301: trans,trans-4-propyl-4'-methoxy-cyclohexylcyclohexane CCH-302: trans,trans-4-propyl-4'-ethoxy-cyclohexylcyclohexane CCH-303: trans,trans-4-propyl-4'-propoxy-cyclohexylcyclohexane CCH-501: trans,trans-4-pentyl-4'-methoxy-cyclohexylcyclohexane CCH-502: trans,trans-4-pentyl-4'-ethoxy-cyclohexylcyclohexane C-33: trans,trans-4-propyl-4'-butyryloxy-cyclohexylcyclohexane C-35: trans,trans-4-propyl-4'-hexanoyloxycyclohexylcyclohexane OS-33: trans-4-propylcyclohexyl trans-4-propylcyclohexanecarboxylate OS-53: trans-4-pentylcyclohexyl trans-4-propylcyclohexanecarboxylate PCH-301: trans-1-p-methoxyphenyl-4-propylcyclohexane PCH-302: trans-1-p-ethoxyphenyl-4-propylcyclohexane PCH-304: trans-1-p-butoxyphenyl-4-propylcyclohexane PCH-501: trans-1-p-methoxyphenyl-4-pentylcyclohexane PCH-53: trans-1-p-propylphenyl-4-pentylcyclohexane PCH-52: trans-1-p-ethylphenyl-4-pentylcyclohexane CP-3F: p-fluorophenyl trans,trans-4-propylcyclohexylcyclohexane-4'-carboxylate CP-5F: p-fluorophenyl trans,trans-4-pentylcyclohexylcyclohexane-4'-carboxylate CH-33: trans-4-propylcyclohexyl trans,trans-4-propylcyclohexylcyclohexane-4'-carboxylate CH-35: trans-4-pentylcyclohexyl trans,trans-4-propylcyclohexylcyclohexane-4'-carboxylate CH-43: trans-4-propylcyclohexyl trans,trans-4-butylcyclohexylcyclohexane-4'-carboxylate CH-45: trans-4-pentylcyclohexyl trans,trans-4-butylcyclohexylcyclohexane-41-carboxylate CP-33: p-propylphenyl trans,trans-4-propylcyclohexylcyclohexane-4'-carboxylate CP-35: p-pentylphenyl trans,trans-4-propylcyclohexylcyclohexane-4'-carboxylate CP-43: p-propylphenyl trans,trans-4-butylcyclohexylcyclohexane-4'-carboxylate CP-45: p-pentylphenyl trans,trans-4-butylcyclohexylcyclohexane-4'-carboxylate ECCP-3F: 1-�trans-4-(trans-4-propylcyclohexyl)cyclohexyl!-2-(p-fluorophenyl)-ethane ECCP-5F: 1-�trans-4-(trans-4-pentylcyclohexyl)cyclohexyl!-2-(p-fluorophenyl)-ethane PYP-32: 2-p-ethylphenyl-5-propyl-pyrimidine PYP-33: 2-p-propylphenyl-5-propyl-pyrimidine PYP-53: 2-p-propylphenyl-5-pentyl-pyrimidine PYP-72: 2-p-ethylphenyl-5-heptyl-pyrimidine PYP-605: 2-p-pentyloxyphenyl-5-hexyl-pyrimidine PYP-607: 2-p-heptyloxyphenyl-5-hexyl-pyrimidine PYP-609: 2-p-nonyloxyphenyl-5-hexyl-pyrimidine PYP-707: 2-p-heptyloxyphenyl-5-heptyl-pyrimidine PYP-709: 2-p-nonyloxyphenyl-5-heptyl-pyrimidine PYP-706: 2-p-Hexyloxyphenyl-5-nonyl-pyrimidine PYP-909: 2-p-nonyloxyphenyl-5-nonyl-pyrimidine PCH-2: p-trans-4-ethylcyclohexylbenzonitrile PCH-3: p-trans-4-propylcyclohexylbenzonitrile PCH-4: p-trans-4-butylcyclohexylbenzonitrile PCH-5: p-trans-4-pentylcyclohexylbenzonitrile G9=EPCH-3: 1-(trans-4-propylcyclohexyl)-2-(p-cyanophenyl)-ethane G15=EPCH-5: 1-(trans-4-pentylcyclohexyl)-2-(p-cyanophenyl)-ethane K6: 4-ethyl-4'-cyanobiphenyl K9: 4-propyl-4'-cyanobiphenyl K15: 4-pentyl-4'-cyanobiphenyl PDX-3: 2-p-cyanophenyl-5-propyl-1,3-dioxane PDX-4: 2-p-cyanophenyl-5-butyl-1,3-dioxane PDX-5: 2-p-cyanophenyl-5-pentyl-1,3-dioxane PCH-3S: trans-1-p-isothiocyantophenyl-4-propylcyclohexane ECCP-3: 1-�trans-4-(trans-4-propylcyclohexyl)cyclohexyl!-2-(p-cyanophenyl)-ethane ME-2N,F: 4-cyano-3-fluorophenyl p-ethylbenzoate ME-3N,F: 4-cyano-3-fluorophenyl p-propylbenzoate ME-5N,F: 4-cyano-3-fluorophenyl p-pentylbenzoate ME-7N,F: 4-cyano-3-fluorophenyl p-heptylbenzoate HP-3N,F: 4-cyano-3-fluorophenyl p-(trans-4-propylcyclohexyl)-benzoate HP-4N,F: 4-cyano-3-fluorophenyl p-(trans-4-butylcyclohexyl)-benzoate HP-5N,F: 4-cyano-3-fluorophenyl p-(trans-4-pentylcyclohexyl)-benzoate PYP-5N,F: 2-(3-fluoro-4-cyanophenyl)-5-pentylpyrimidine PYP-6N,F: 2-(3-fluoro-4-cyanophenyl)-5-hexylpyrimidine PYP-7N,F: 2-(3-fluoro-4-cyanophenyl)-5-heptylpyrimidine PCH-5F: trans-1-p-fluorophenyl-4-pentylcyclohexane PCH-7F: trans-1-p-fluorophenyl-4-hexylcyclohexane trans-1-p-fluorophenyl-4-heptylcyclohexane PTP-34: 4-butyl-4'-propyl-tolan PTP-35: 4-pentyl-4'-propyl-tolan PTP-45: 4-butyl-4'-pentyl-tolan PTP-201: 4-ethyl-4'-methoxy-tolan PTP-102: 4-methyl-4'-ethoxy-tolan CPTP-301: 4-(trans-4-propylcyclohexyl)-4'-methoxytolan CPTP-302: 4-(trans-4-propylcyclohexyl)-4'-ethoxytolan CPTP-303: 4-(trans-4-propylcyclohexyl)-4'-propoxytolan BCH-32: 4-ethyl-4'-(trans-4-propylcyclohexyl)biphenyl BCH-52: 4-ethyl-4'-(trans-4-pentylcyclohexyl)biphenyl BCH-59: 4-nonyl-4'-(trans-4-pentylcyclohexyl)biphenyl BCH-52F: 4-ethyl-4'-(trans-4-pentylcyclohexyl)-2'-fluorobiphenyl I52: 1-(trans-4-pentylcyclohexyl)-2-(4'-ethyl-2'-fluorobiphenyl-4-yl)-ethane CBC-33: 4,4'-bis-(trans-4-propylcyclohexyl)biphenyl CBC-35: 4-(trans-4-pentylcyclohexyl)-4'-(trans-4-propylcyclohexyl)-biphenyl (=CBC-53) CBC-55: 4,4'-bis-(trans-4-pentylcyclohexyl)biphenyl CBC-33F: 4,4-bis-(trans-4-propylcyclohexyl)-2-fluorobiphenyl CBC-35F: 4-(trans-4-pentylcyclohexyl)-4'-(trans-4-propylcyclohexyl)-2-fluorobipheny (=CBC-53F) CBC-55F: 4,4'-bis-(trans-4-pentylcyclohexyl)-2-fluorobiphenyl D-301: p-methoxyphenyl trans-4-propylcyclohexane carboxylate D-401: p-methoxyphenyl trans-4-butylcyclohexane carboxylate D-501: p-methoxyphenyl trans-4-pentylcyclohexane carboxylate D-302: p-ethoxyphenyl trans-4-propylcyclohexane carboxylate D-402: p-ethoxyphenyl trans-4-butylcyclohexane carboxylate D-302FF: (2,3-difluoro-4-ethoxyphenyl) trans-4-propylcyclohexane carboxylate D-402FF: (2,3-difluoro-4-ethoxyphenyl) trans-4-butylcyclohexane carboxylate D-502FF: (2,3-difluoro-4-ethoxyphenyl) trans-4-pentylcyclohexane carboxylate PYP-3N,F: 2-(3-fluoro-4-cyanophenyl)-5-propylpyrimidine CBC-44: 4,4'-bis(trans-4-butylcyclohexyl)-biphenyl PYP-3F: 2-(p-fluorophenyl)-5-propylpyrimidine PYP-5F: 2-(p-fluorophenyl)-5-pentylpyrimidine PYP-35: 2-(p-pentylphenyl)-5-propylpyrimidine PYP-53: 2-(p-propylphenyl)-5-pentylpyrimidine PYP-50CF.sub.3 : 2-(p-trifluoromethoxyphenyl)-5-pentylpyrimidine PYP-70CF.sub.3 : 2-(p-trifluoromethoxyphenyl)-5-heptylpyrimidine I 32: 1-(trans-4-propylcyclohexyl)-2-(4'-ethyl-2'-fluorobiphenyl-4-yl)-ethane I 35: 1-(trans-4-propylcyclohexyl)-2-(4'-pentyl-2 '-fluorobiphenyl-4-yl)-ethane ME-2N: p-cyanophenyl p-ethylbenzoate ME-3N: p-cyanophenyl p-propylbenzoate ME-4NF: 3-fluoro-4-cyanophenyl p-butylbenzoate BCH-5: 4-cyano-4'-(trans-4-pentylcyclohexyl)biphenyl BCH-30CF.sub.3 : 4-trifluoromethoxy-4'(trans-4-propylcyclohexyl)-biphenyl BCH-50CF.sub.3 : 4-trifluoromethoxy-4'(trans-4-pentylcyclohexyl)-biphenyl CCP-30CF.sub.3 : 1-�trans-4-(trans-4-propylcyclohexyl)cyclohexyl)-4-trifluoromethoxybenzol �sic! ECCP-30CF.sub.3 : 1-�trans-4-(trans-4-propylcyclohexyl)cyclohexyl!-2-p-trifluoromethoxyphenyl)ethane ECCP-50CF.sub.3 : 1-�trans-4-(trans-4-pentylcyclohexyl)cyclohexyl!-2-(p-trifluoromethoxyphenyl)ethane ECCP-3F,F: 1-�trans-4-(trans-4-propylcyclohexyl)cyclohexyl!-2-(3,4-difluorophenyl)-ethane CPTP-302FF: 4-(trans-4-propylcyclohexyl)-2',3'-di-fluoro-4-ethoxytolan CPTP-502FF 4-(trans-4-pentylcyclohexyl)-2',3'-di-fluoro-4-ethoxytolan PTP-302FF: 4'-propyl-2,3-difluoro-4-ethoxytolan PTP-502FF: 4'-pentyl-2,3-difluoro-4-ethoxytolan CCPC-33: p-(trans-4-propylcyclohexyl)phenyl trans-4-(trans-4-propylcyclohexyl)-cyclohexanecarboxylate CCPC-34: p-(trans-4-butylcyclohexyl)phenyl trans-4-(trans-4-(propylcyclohexyl)-cyclohexanecarboxylate CCPC-35: p-(trans-4-pentylcyclohexyl)phenyl trans-4-(trans-4-propylcyclohexyl)-cyclohexanecarboxylate K12: 4-butyl-4'-cyanobiphenyl K18: 4-hexyl-4'-cyanobiphenyl T15: 4-p-cyanophenyl-4'-pentylbiphenyl DR-31: 2-methylpyridine-5-yl trans-4-propylcyclohexanecarboxylate DR-41: 2-methylpyridine-5-yl trans-4-butylcyclohexanecarboxylate DR-51: 2-methylpyridine-5-yl trans-4-pentylcyclohexanecarboxylate CP-33F: 2-fluoro-4-propylphenyl trans-4-(trans-4-propylcyclohexyl)cyclohexanecarboxylate CP-35F: 2-fluoro-4-pentylphenyl trans-4-(trans-4-propylcyclohexyl)cyclohexanecarboxylate CP-55F: 2-fluoro-4-pentylphenyl trans-4-(trans-4-pentylcyclohexyl)cyclohexanecarboxylate CP-302F: 2,3-difluoro-4-ethoxyphenyl trans-4-(trans-4-propylcyclohexyl)cyclohexanecarboxylate CP-402FF: 2,3-difluoro-4-ethoxyphenyl trans-4-(trans-4-butylcyclohexyl)cyclohexanecarboxylate HP-2N.F: 3-fluoro-4-cyanophenylp-(trans-4-ethylcyclohexyl)-benzoate EHP-3F.F: 3,4-difluorophenylp-(trans-4-propylcyclohexylethyl)-benzoate PCH-50CF.sub.2 : trans-1-p-(difluoromethoxyphenyl)-4-pentylcyclohexane PCH-7: trans-1-p-(cyanophenyl)-4-heptylcyclohexane PDX-2: 2-p-cyanophenyl-5-ethyl-1,3-dioxane OS-35: trans-4-pentylcyclohexyl trans-4-propylcyclohexanecarboxylate CCH-3: trans,trans-4-propylcyclohexylcyclohexane-4'-carbonitrile M3: 4-methoxy-4'-cyanobiphenyl M9: 4-propoxy-4'-cyanobiphenyl T-3FN: 4-(p-cyanophenyl)-2-fluoro-4'-propylbiphenyl __________________________________________________________________________Multiplex values measured at 240.degree. twistExamples 144 145 146 147 148 149__________________________________________________________________________S .fwdarw. N �.degree.C.! <-40 <-40 <-40 <-40 <-40 <-40Clearing point �.degree.C.! +85 +89 +90 +86 +89 +90Viscosity �mm.sup.2 s.sup.-1 ! 20.degree.C. 26 25 24 23 21 28.DELTA.n (589 nm, 20.degree. C.) +0.1127 +0.1222 +0.1094 +0.1221 +0.1479 +0.1438n.sub.a (589 nm, 20.degree. C.) 1.6023 1.6166 1.5984 1.6165 1.6488 1.8400.DELTA..epsilon. (1 kHz, 20.degree. C.) +12.9 +14.5 +9.9 +10.6 +9.8 +14.8.epsilon..sub..parallel. (1 kHz, 20.degree. C.) 17.7 19.3 14.2 14.8 13.4 20.0V.sub.(10,0,20) 1.76 1.75 2.03 2.01 1.99 1.83V.sub.(50,0,20) 1.85 1.81 2.11 2.08 2.14 1.71V.sub.(90,0,20) 1.89 1.87 2.16 2.13 2.21 1.76K.sub.3 /K.sub.1 +20.degree. C. 1.77 1.89 1.74 1.77 1.38 1.68Composition �%!: CCH-3 4 PCH-3 18 PCH-2 7 PCH-2 7 PCH-2 9 PCH-3 18 PCH-3 18 PCH-4 12 PCH-3 18 PCH-3 18 PCH-3 16 PCH-4 12 PCH-4 13 PCH-8 11 PCU-4 14 PCH-4 14 PCH-4 11 PCH-5 15 PCH-5 11 MB2N.F 5 PCH-5 17 PCH-5 15 PCH-5 12 ME2N.F 3 ME2N.F 3 MB3N.F 4 CCH-303 3 PCH-7 7 BCH-5 8 ME3N.F 4 MB3N.F 3 MB5N.F s ECCP-3 8 BCH-32 10 BCH-32 8 ME5N.F 8 MB5N.F 5 ECCP-31 5 ECCP-3F 6 CP-33 5 BCH-52 8 PTP-201 3 CCH-303 6 ECCP-32 4 ECCP-5F 6 CP-35 5 ECCP-31 6 CPTP-301 3 CP-33 4 ECCP-33 4 CH-33 4 ECCP-3 7 ECCP-32 6 CPTP-302 3 CP-35 5 BCH-32 4 CH-35 4 ECCP-3P 6 ECCP-33 6 CPTP-303 4 CP-43 4 CP-33 5 CP-33 5 ECCP-5P 6 PTP-35 6 CBC-33F 4 CP-45 4 CP-35 4 CP-35 4 PTP-102 4 CP-33 5 ECCP-3 8 CP-43 4 CP-43 4 CP-35 4 ECCP-3F 6 ECCP-3 4 CP-43 4 ECCP-5F 6 ECCP-3P 6 ECCP-3P 6 ECCP-5P 4 ECCP-5P 4__________________________________________________________________________Examples 150 151 152 153 154__________________________________________________________________________S .fwdarw. N �.degree.C.! <-20 <-40 <=40 <-20 <-40Clearing point �.degree.C.! -91 +88 +89 +93 +96Viscosity �mm.sup.2 s.sup.-1 ! 20.degree.C. 24 26 21 21 20.DELTA.n (589 nm, 20.degree. C.) 0.1427 +0.1544 +0.1433 +0.1400 +0.1374n.sub.a (589 nm, 20.degree. C.) 1.6397 1.6466 1.6410 1.6339 1.6346.DELTA..epsilon. (1 kHz, 20.degree. C.) 11.1 +7.3 +9.7 +8.1 +8.6.epsilon..sub..parallel. (1 kHz, 20.degree. C.) 15.3 13.7 13.8 12.9 12.4V.sub.(10,0,20) 2.00 2.20 2.07 2.26 2.25V.sub.(50,0,20) 2.08 2.26 2.12 2.32 2.31V.sub.(90,0,20) 2.13 2.30 2.20 2.38 2.38K.sub.3 /K.sub.1 +20.degree. C. 1.78 1.54 1.58 1.51 1.59Composition �%!: PCH-2 7.0 PCH-2 5 PCH-2 7.0 PCH-2 5.0 PCH-2 12.0 PCH-3 18.0 PCH-3 15 PCH-3 18.0 PCH-3 15.0 PCH-3 15.0 PCH-4 14.0 PCH-4 11 PCH-4 14.0 PCH-4 11.0 PCH-4 10.0 PCH-5 15.0 PCH-5 11 PCH-5 12.0 PCH-5 11.0 PCH-5 8.0 PCH-7 7.0 D-302PP 7 PTP-102 5.0 PTP-302FF 7.0 PTP-201 3.0 BCH-32 8.0 D-402PP 6 PTP-201 5.0 PTP-502PP 7.0 PCH-301 3.0 CPTP-301 4.0 D-502PP 7 CPTP-302 4.0 CPTP-302 5.0 CPTP-301 5.0 CPTP-302 4.0 PTP-302PP 6 CPTP-303 3.0 CP-33 4.0 CPTP-302 5.0 CPTP-303 4.0 CPTP-302PP 4 CP-33 4.0 CP-35 5.0 CPTP-303 4.0 ECCP-3 7.0 CPTP-301 6 CP-35 4.0 ECCP-31 6.0 ECCP-31 7.0 ECCP-3P 6.0 CPTP-302 5 ECCP-31 4.0 ECCP-33 6.0 ECCP-33 7.0 ECCP-5F 6.0 CPTP-303 7 ECCP-33 4.0 ECCP-35 6.0 ECCP-35 7.0 ECCP-31 6 ECCP-35 4.0 ECCP-3 4.0 ECCP-3P 7.0 ECCP-33 4 ECCP-3 4.0 ECCP-3P 4.0 ECCP-5P 7.0 ECCP-3F 4.0 ECCP-5P 4.0 ECCP-5F 4__________________________________________________________________________Multiplex values measured at 220.degree. twist Examples 151 152 153 154__________________________________________________________________________ S .fwdarw. N �.degree.C.! <-40 <-40 <-40 <-40 Clearing point �.degree.C.! +88 +89 +93 +96 Viscosity �mm.sup.2 s.sup.-1 ! 20.degree.C. 26 21 21 20 .DELTA.n (589 nm, 20.degree. C.) +0.1544 +0.1433 +0.1400 +0.1374 n.sub.a (589 nm, 20.degree. C.) 1.6466 1.6410 1.6339 1.6346 .DELTA..epsilon. (1 kHz, 20.degree. C.) +7.3 +9.7 +8.1 +8.6 .epsilon..sub..parallel. (1 kHz, 20.degree. C.) 13.7 13.8 12.9 12.4 V.sub.(10,0,20) 2.20 2.07 2.28 2.25 V.sub.(50,0,20) 2.26 2.12 2.32 2.31 V.sub.(90,0,20) 2.30 2.20 2.38 2.38 K.sub.3 /K.sub.1 +20.degree. C. 1.54 1.58 1.51 1.59Composition �%!: PCH-2 5 PCH-2 7.0 PCH-2 5.0 PCH-2 12.0 PCH-3 15 PCH-3 18.0 PCH-3 15.0 PCH-3 15.0 PCH-4 11 PCH-4 14.0 PCH-4 11.0 PCH-4 10.0 PCH-5 11 PCH-5 12.0 PCH-5 11.0 PCH-5 8.0 D-302FF 7 PTP-102 5.0 PTP-302FF 7.0 PTP-201 3.0 D-402FF 6 PTP-201 5.0 PTP-502FF 1.0 PCH-301 3.0 D-502FF 7 CPTP-302 4.0 CPTP-302 5.0 CPTP-301 5.0 PTP-302FF 6 CPTP-303 3.0 CP-33 4.0 CPTP-302 5.0 CPTP-302FF 4 CP-33 4.0 CP-35 5.0 CPTP-303 4.0 CPTP-301 6 CP-35 4.0 ECCP-31 6.0 ECCP-31 7.0 CPTP-302 5 ECCP-31 4.0 ECCP-33 8.0 ECCP-33 7.0 CPTP-303 7 ECCP-33 4.0 ECCP-35 4.0 ECCP-35 7.0 ECCP-31 6 ECCP-35 4.0 ECCP-3 4.0 ECCP-3F 7.0 ECCP-33 4 ECCP-3 4.0 ECCP-3F 4.0 ECCP-5F 7.0 ECCP-3F 4.0 ECCP-5F 4.0 ECCP-5F 4.0__________________________________________________________________________Examples 155 156 157 158 159__________________________________________________________________________S .fwdarw. N �.degree.C.! <-30 <-30 <-40 --Clearing point �.degree.C.! +74 +118 +90 +85Viscosity �mm.sup.2 s.sup.-1 ! 20.degree.C. 23 31 20 22.2.DELTA.n (20.degree. C., 589 nm) +0.1105 +0.1184 +0.1564 +0.1021V.sub.(10,0,20) 1.15 2.22 2.06 1.54(1st)V.sub.(50,0,20) 1.51 2.51 2.34 1.88V.sub.(90,0,20) 2.00 2.97 2.80 2.32Composition �%!: PCH-5 20.00 PCH-5 18.00 PCH-5 22.00 PDX-5 11.00 PCH-4 13.00 PDX-5 8.00 PCH-4 25.00 PDX-4 10.00 ME2N.F 5.00 PDX-4 8.00 PCH-302 6.00 PDX-5 6.00 ME5N.F 4.00 PDX-5 8.00 PTP-102 5.00 PCH-3 12.00 MZ4N.F 11.00 CCH-301 10.00 PTP-201 5.00 PCH-4 8.00 PCH-301 8.00 ECCP-31 4.00 CPTP-301 5.00 CCH-303 11.00 CCH-501 4.00 ECCP-32 4.00 CPTP-303 3.00 ECCP-31 5.00 ECCP-31 5.00 CH-33 5.00 ECCP-51 6.00 ECCP-32 5.00 ECCP-32 6.00 CH-55 4.00 ECCP-55 6.00 ECCP-33 5.00 ECCP-35 7.00 CP-45 5.00 BCH-32 10.00 ECCP-3 6.00 ECCP-35 7.00 CBC-35 5.00 BCH-52 9.00 ECCP-3F 7.00 CP-3P 8.00 CBC-55 6.00 CP-3F 7.00 CP-5P 7.00 CDC-53F 5.00 CP-5F 7.00 CDC-55F 5.00 ECCP-3 9.00__________________________________________________________________________Examples 160 161 162 163 164__________________________________________________________________________S .fwdarw. N �.degree.C.! <-40Clearing point �.degree.C.! +90 95.0 +87 +87 +86Viscosity �mm.sup.2 s.sup.-1 ! 20.degree.C. 20 -- --.DELTA.n (20.degree. C., 589 nm) +0.1509 -- +0.1073 +0.1075 +0.1070V.sub.(10,0,20) 2.14 -- 1.39(1st) 1.41(1st) 1.40(1st)V.sub.(50,0,20) 2.45 -- 1.79 1.78 1.75V.sub.(90,0,20) 2.93 -- 2.33 2.27 2.21Composition �%!: PCH-3 22.00 PDX-2 7.00 PDX-2 6.00 PCH-2 7.00 PDX-2 5.00 PCH-4 20.00 PDX-3 10.50 PDX-3 11.00 PCH-3 15.00 PCH-3 20.00 PCH-5 5.00 PCH-3 9.30 PDX-4 10.00 PCH-4 12.00 PCH-4 10.00 CCH-301 7.00 PCH-4 5.80 PCH-3 12.00 ME2N.F 2.00 MZ2N.F 2.00 PTP-102 4.00 ME2N.F 2.30 PCH-4 8.00 ME3N.F 3 00 ME3N F 3 00 PTP-201 8.00 ME3N.F 3.50 PCH-302 7.00 MESN.F 8.00 MESN:F 5.00 CPTP-301 5.00 CCH-303 9.30 ECCP-31 5.00 CCH-303 10.00 CCH-303 11.00 CPTP-302 5.00 ECCP-31 7.00 ECCP-32 5.00 ECCP-31 6.00 ECCP-31 6.00 CPTP-303 6.00 ECCP-32 7.00 ECCP-33 5.00 ECCP-32 6.00 ECCP-32 6.00 ECCP-31 8.00 ECCP-33 7.00 ECCP-35 4.00 ECCP-33 8.00 ECCP-33 5.00 ECCP-33 7.00 ECCP-3 7.00 ECCP-3 6.00 ECCP-3 8.00 ECCP-3 6.00 ECCP-35 8.00 ECCP-3F 8.10 ECCP-3F 7.00 ECCP-3F 7.00 ECCP-3F 7.00 CP-3F 8.10 CP-3F 7.00 CP-3F 7.00 CP-3F 7.00 CP-5F 8.10 CP-SF 7.00 CP-SF 7.00 CP-5F 7.00__________________________________________________________________________Examples 165 166 167 168 169__________________________________________________________________________S .fwdarw. N �.degree.C.! <-20 <-40 <-30 <-20 <-40Clearing point �.degree.C.! +129 +92 +96 83 +83Viscosity �mm.sup.2 s.sup.-1 ! 20.degree.C. 34 22 22 20 20.DELTA.n (20.degree. C., 589 nm) +0.1381 +0.1046 +0.1229 0.0987 +0.1073V.sub.(10,0,20) 2.04 1.63(1st) 2.32 2.20 1.53(1st)V.sub.(50,0,20) 2.33 2.02 2.64 2.50 1.93V.sub.(90,0,20) 2.84 2.55 3.15 3.08 2.44Composition �%!: PCH-3 18.00 PCH-3 20.00 PCH-2 8.0 PCH-3 17.00 PCH-3 17.00 ME2N.F 2.00 PCH-4 18.00 PCH-3 17.00 PDX-3 8.00 PCH-4 16.00 ME3N.F 3.00 ME2N.F 2.00 PCH-6 10.00 PDX-4 7.00 PCH-5 17.00 ME5N.F 6.00 ME3N.F 3.00 G9 8.00 D-301 11.00 CCH-303 11.00 ME7N.F 6.00 CCH-303 12.00 ME2N.F 2.00 D-401 11.00 CP-3F 7.00 HP-3N.F 6.00 ECCP-31 5.00 PCH-302 8.00 D-501 11.00 CP-5F 7.00 PCH-302 6.00 ECCP-32 5.00 CPTP-301 4.00 CP-33 6.00 ECCP-3F 8.00 CCH-303 5.00 ECCP-33 5.00 ECCP-3F 8.00 CP-35 6.00 ECCP-5F 8.00 ECCP-31 4.00 ECCP-3 7.00 ECCP-31 8.00 ECCP-31 5.00 BCH-32 9.00 ECCP-32 4.00 ECCP-3F 7.00 ECCP-32 8.00 ECCP-32 6.00 ECCP-3F 10.00 CP-3F 8.00 ECCP-33 9.00 ECCP-33 6.00 CBC-33 4.00 CP-5F 8.00 CBC.33F 5.00 ECCP-35 6.00 CBC-53 4.00 CBC.53F 5.00 CBC-55 4.00 CBC-53F 6.00 CBC-53F 6.00 CBC-55F 6.00__________________________________________________________________________Examples 170 171 172 173 174__________________________________________________________________________S .fwdarw. N �.degree.C.! -- <-30 <-40 <-40Clearing point �.degree.C.! +86 +90 89.0 +85 +85Viscosity �mm.sup.2 s.sup.-1 ! 20.degree.C. 21.5 22 19.0 20 21.DELTA.n (20.degree. C., 589 nm) +0.1089 +0.1548 +0.1557 +0.1570 +0.1399V.sub.(10,0,20) 1.40(1st) 1.96 2.1 1.97 1.95(2nd)V.sub.(50,0,20) 1.80 2.25 2.4. 2.26 2.20V.sub.(90,0,20) 2.34 2.70 2.9 2&73 2.58Composition �%!: PDX-2 5.00 PCH-3 20.00 PCH-3 22.00 PCH-2 8.00 PCH-2 9.00 PCH-3 20.00 PCH-4 18.00 PCH-4 20.00 PCH-3 17.00 PCH-3 18.00 PCH-4 10.00 ME3N.F 4.00 PCH-5 3.00 K8 8.00 PCH-4 16.00 ME2N.F 2.00 ME5N.F 5.00 PCH-301 7.00 K9 C.00 PCH-6 20.00 ME3N.F 2.00 CCH-301 8.00 PTP-102 5.00 G9 6.00 BCH-32 12 00 MESN.F 6.00 PTP-102 4.00 PT7-201 5.00 ME2N.F 2.00 BCH-52 10.00 CCH-303 11.00 PTP-201 4.00 CPTP-301 8.00 ME3N.F 2.00 ECCP-31 6.00 ECCP-31 6.00 CPTP-301 6.00 CPTP-302 5.00 PCH-302 6.00 ECCP-32 5.00 ECCP-32 6.00 CPTP-302 5.00 ECCP-31 8.00 PTP-35 5.00 CPTP-302 6.00 ECCP-33 5.00 CPTP-303 6.00 ECCP-33 6.00 PTP-102 5.00 ECCP-3 6.00 ECCP-31 7.00 ECCP-35 8.00 CPTP-301 4.00 ECCP-3F 7.00 ECCP-33 7.00 BCH-32 10.00 ECCP-31 8.00 CP-3F 7.00 ECCP-35 8.00 ECCP-32 8.00 CP-5F 7.00 ECCP-33 7.00 CBC-33F 6.00 CBC-53F 6.00__________________________________________________________________________Examples 175 176 177 178 179__________________________________________________________________________S .fwdarw. N �.degree.C.! -- -- -- <-30 <-30Clearing point �.degree.C.! 90.0 +85 +88 +85 +86Viscosity �mm.sup.2 s.sup.-1 ! 20.degree.C. -- 22.4 24 24.DELTA.n (20.degree. C., 589 nm) -- +0.1082 +0.1094 +0.1Q73 +0.1082V.sub.(10,0,20) -- 1.42(1st) 1.43(1st) 1.47(1st) 1.44(1st)V.sub.(50,0,20) -- 1.80 1.83 1.87 1.82V.sub.(90,0,20) -- 2.30 2.35 2.42 2.30Composition �%!: PDX-2 6.30 PDX-3 11.00 PDX-2 5.00 PDX-3 11.60 PCH-3 19.00 PDX-3 9.50 PDX-5 10.00 PCH-3 20.00 PDX-5 9.00 PCH-4 9.00 PCH-3 18.80 PCH-3 21.00 PCH-4 10.00 PCH-3 20.00 PCH-5 7.00 PCH-4 11.80 PCH-4 12.00 ME2N.F 2.00 PCH-4 13.00 ME2N.F 2.00 CCH-303 8.40 CCH-303 5.00 ME3N.F 3.00 CCH-303 8.00 ME3N.F 3.00 ECCP-31 8.30 ECCP-31 4.00 MESN.F 6.00 ECCP-31 3.00 MESN.F 6.00 3CCP-32 8.30 ECCP-32 3.00 CCH-303 8.00 ECCP-32 5.00 CCH-303 13.00 ECCP-33 8.30 ECCP-33 4.00 ECCP-31 8.00 ECCP-33 3.00 ECCP-31 4.00 ECCP-3 8.30 ECCP-35 4.00 ECCP-32 8.00 ECCP-35 4.00 ECCP-32 5.00 ECCP-3F 7.40 ECCP-3 5.00 ECCP-33 8.00 ECCP-3 5.00 ECCP-33 4.00 CP-3F 4.40 ECCP-3F 7.00 ECCP-3 8.00 ECCP-3F 6.00 ECCP-3 8.00 CP-5F 7.40 CP-3F 7.00 ECCP-3F 6.0 CP-3F 8.00 ECCP-3F 6.00 CP-SF 7.00 CP-3F 7.00 CP-5F 7.00 CP-3F 7.00 CP-SF 7.00 CP-5F 7.00__________________________________________________________________________Examples 180 181 182 183 184__________________________________________________________________________S .fwdarw. N �.degree.C.! <-40 <0 -- <-20 <-30Clearing point �.degree.C.! +80 +80 94.0 calc. +112 +75Viscosity �mm.sup.2 s.sup.-1 ! 20.degree.C. 21 20 19.3 26 21.DELTA.n (20.degree. C., 589 nm) +0.1416 0.0980 +0.156 +0.1488 +0.1125V.sub.(10,0,20) 1.83 2.20 -- 1.95 1 35V.sub.(50,0,20) 2.07 2.50 -- 2.26 1.70V.sub.(90,0,20) 2.50 3.05 -- 2.74 2.19Composition �%!: PCH-2 9.00 PCH-3 17.00 P.CH-3 20.00 ME2N.F 2.00 PCH-3 20.00 PCH-3 18.00 PDX-3 8.00 PCH-4 10.00 ME3N.F 3.00 PCH-5 12.00 PCH-4 12.00 PDX-4 7.00 09 15.00 ME4N.F 6.00 ME2N.F 3.00 PCH-5 14.00 PCH-301 3.00 PTP-35 6.00 ME5N.F 6.00 ME3N.F 4.00 BCH-32 10.00 D-301 10.00 PTP-102 2.00 HP-3N.F 4.00 ME4N.F 9.00 DCH-52 10.00 D-401 10.00 PTP-201 4.00 PCH-301 19.00 PCH-301 11.00 DCH-52F 9.00 D-501 10.00 CPTP-301 4.00 ECCP-31 4.00 ECCP-31 6.00 ECCP-3F 6.00 CP-33 6.00 CPTP-303 4.00 ECCP-32 6.00 ECCP-32 6.00 ECCP-SF 5.00 ECCP-31 8.00 ECCP-31 7.00 ECCP-33 6.00 ECCP-33 7.00 PTP-102 7.00 ECCP-32 7.00 ECCP-33 7.00 ECCP-35 6.00 ECCP-35 7.00 ECCP-33 7.00 ECCP-35 8.00 CP-3F 9.00 ECCP-3F 9.00 ECCP-35 7.00 BCH-32 6.00 CP-5F 8.00 CP-3F 6.00 DCH-52 7.00 PTP-201 5.00 CPTP-301 5.00 CPTP-302 5.00 CPTP-303 6.00__________________________________________________________________________Examples 185 186 187 188 189__________________________________________________________________________S .fwdarw. N �.degree.C.! <0 <-40 <20 -- --Clearing point �.degree.C.! +113 +88 +101 +78 79.0Viscosity �mm.sup.2 s.sup.-1 ! 20.degree.C. 26 22 Sm -- 26.DELTA.n (20.degree. C., 589 nm) +0.1484 +0.1210 +0.126 0.1047 +0.1637V.sub.(10,0,20) 2.06 2.05 -- 2.04 --V.sub.(50,0,20) 2.36 2.32 -- 2.31 --V.sub.(90,0,20) 2.86 2.78 -- 2.81 --Composition �%!: ME2N.F 2.00 PCH-3 10.00 ME2N.F 2.00 PCH-3 17.00 PCH-3 13.00 ME3N.F 3.00 PCH-4 16.00 ME3N.F 3.00 PDX-3 8.00 PYP.3N.F 4.00 ME4N.F 6.00 PCH-5 15.00 ME5N.F 7.00 PDX-4 7.00 PYP.SN.F 4.00 ME5N.F 6.00 PCH-7 10.00 ME7N.F 6.00 PCH-301 3.00 PYP.7N.F 4.00 HP-3N.F 4.00 DCH-32 8.00 CCH-303 19.00 D-301 12.00 PYP-32 8.00 PCH-301 18.00 DCH-52 7.00 D-302FF 7.00 D-401 12.00 PYP.33 8.00 ECCP-31 5.00 ECCP-31 6.00 D-402FF 7.00 D-501 12.00 PYP-53 8.00 ECCP-32 6.00 ECCP-32 6.00 ECCP-31 9.00 BCH-52 4.00 PYP-72 8.00 ECCP-33 6.00 ECCP-33 6.00 ECCP-32 8.00 ECCP-31 6.00 ECCP-31 8.00 ECCP-35 6.00 ECCP-3F 10.00 ECCP-33 8.00 ECCP-32 5.00 ECCP-32 7.00 CP-37 9.00 ECCP-35 8.00 ECCP-33 5.00 ECCP-33 7.00 CP-5F 8.00 CPTP-302PF 8.00 ECCP-3 9.00 ECCP-35 7.00 PTP-201 5.00 CPTP-502FF 8.00 CPTP-301 5.00 CPTP-302FF 5.00 CPTP-302 4.00 CPTP-302 5.00 CPTP-303 5.00 CPTP-303 6.00__________________________________________________________________________Examples 190 191 192 193 194__________________________________________________________________________S .fwdarw. N �.degree.C.! <-30 <0 <-40 <-30 <-40Clearing point �.degree.C.! +93 +88 +80 +84 +85Viscosity �mm.sup.2 s.sup.-1 ! 20.degree.C. 23 21 20 23 22.DELTA.n (20.degree. C., 589 nm) +0.1524 0.1048 +0.1421 +0.1485 +0.1181V.sub.(10,0,20) 2.10(2nd) 2.24 1.98 1.98 2.04V.sub.(50,0,20) 2.42 2.54 2.25 2.25 2.33V.sub.(90,0,20) 2.93 3.08 2.75 2.71 2.83Composition �%!: PCH-2 7.00 PCH-3 17.00 PCH-2 7.00 PCH-2 7.00 PCH-3 15.00 PCH-3 16.00 PDX-3 8.00 PCH-3 18.00 PCH-3 16.00 PCH-4 15.00 PCH-4 10.00 PDX-4 7.00 PCH-4 14.00 PCH-4 10.00 PCH-5 14.00 PCH-5 12.00 D-301 10.00 PCH-5 14.00 PCH-5 12.00 PCH-7 8.00 BCH-5 8.00 D-401 10.00 BCH-32 10.00 BCH-5 8.00 I32 9.00 BCH-32 10.00 D-501 10.00 BCH-52 9.00 BCH-52F 9 00 BCH-2F 9.00 BCH-52 9.00 CP-33 6.00 I32 10.00 I32 10.00 ECCP-31 5.00 I32 10.00 CP-35 6.00 ECCP-3F 6.00 I35 10.00 ECCP-32 5.00 RCCP-3F 6.00 ECCP-31 5.00 ECCP-5F 5.00 ECCP-3F 5.00 ECCP-33 5.00 ECCP-SF 5.00 ECCP-32 6.00 PTP-102 7.00 ECCP-5F 6.00 ECCP-3F 8.00 PTP-102 7.00 ECCP-33 6.00 PTP-102 7.00 ECCP-SF 7.00 DCCP-35 6.00 CPTP-301 3.00__________________________________________________________________________Examples 195 196 197 198 199__________________________________________________________________________S .fwdarw. N �.degree.C.! <0 <20 <-20 <-30Clearing point �.degree.C.! +113 +110 +75 +76Viscosity �mm.sup.2 s.sup.-1 ! 20.degree.C. 25 24 25 21.DELTA.n (20.degree. C., 589 nm) +0.1523 +0.1518 +0.1000 0.1144V.sub.(10,0,20) 2.24 2.09 1.20 2.04V.sub.(50,0,20) 2.55 2.39 1.53 2.34V.sub.(90,0,20) 3.05 2.84 1.96 2.86Composition �%!: ME2N.F 2.00 ME2N.F 2.00 ME2N.F 3.00 PCH-3 17.00 ME3N.F 3.00 ME3N.F 3.00 ME3N.F 4.00 PDX-3 8.00 PYP-5N.F 8.00 ME4N.F 8.00 ME5N.F 9.00 PDX-4 7.00 PYP-6N.F 8.00 ME5N.F 8.00 ME7N.F 4.00 PCH-301 3.00 HP-3N.F 3.00 HP-3N.F 4.00 HP-3N.F 8.00 D-301 13.00 PCH-301 10.00 PCH-301 15.00 HP-IN.F 8.00 D-401 13.00 PCH-302 5.00 PTP-35 8.00 PCH-301 17.00 D-501 13.00 CCH-303 7.00 ECCP-31 6.00 CCH-303 14.00 ECCP-31 5.00 ECCP-31 7.00 ECCP-32 8.00 D-302FF 10.00 ECCP-32 4.00 ECCP-32 7.00 ECCP-33 8.00 ECCP-31 6.00 ECCP-33 4.00 ECCP-33 8.00 ECCP-35 8.00 3CCP-32 7.00 ECCP-35 4.00 ECCP-35 8.00 ECCP-3F 7.00 ECCP-33 7.00 CPTP-301 4.00 CPTP-301 6.00 CP-3F 9.00 ECCP-3& 7.00 CPTP-302 4.00 CPTP-302 5.00 CPTP-301 5.00 CPTP-303 7.00 CPTP-302 5.00 CBC-33F 4.00 CPTP-303 8.00 CBC.53F 2.00__________________________________________________________________________Examples 200 201 202 203 204__________________________________________________________________________S .fwdarw. N �.degree.C.! <0 <-20 <-40 <-40 <-30Clearing point �.degree.C.! 78 82 +92 +85 +87Viscosity �mm.sup.2 s.sup.-1 ! 20.degree.C. 19 21 22 20 23.DELTA.n (20.degree. C., 589 nm) +0.1616 +0.1609 +0.1048 +0.1272 +0.1000V.sub.(10,0,20) 2.15 2.08 1.63(1st) 2.03 1.59(1st)V.sub.(50,0,20) 2.44 2.33 2.02 2.29 1.98V.sub.(90,0,20) 2.87 2.71 2.55 2.75 2.57Composition �%!: K6 8.00 PYP-3N.F 4.00 PCH-3 20.00 PCH-3 15.00 ME2N.F 2.00 K9 10.00 PYP-5N.F 4.00 PCH-4 18.00 PCH-4 15.00 PCH-3 18.00 K12 6.00 PYP-6N.F 4.00 ME2N.F 2.00 PCH-5 14.00 PCH-4 16.00 K15 10.00 PYP-7N.F 5.00 ME3N.F 3.00 KIS 8.00 PCH-5 18 00 PCH-301 8.00 PYP-32 5.00 CCH-303 12.00 CCH-303 5.00 CCH-303 7.00 ECCP-31 8.00 PYP-33 5.00 ECCP-31 5.00 BCH-32 9.00 CP-302FF 7.00 ECCP-32 8.00 PTP-34 4.00 ECCP-32 5.00 BCH-52 9.00 ECCP-31 4.00 DCCP-33 8.00 PTP-35 4.00 ECCP-33 5.00 ECCP-31 5.00 ECCP-33 4.00 ECCP-35 8.00 PTP-45 4.00 ECCP-3 7.00 ECCP-32 5.00 ECCP-3F 8.00 ECCP-3 10.00 PCH-301 10.00 ECCP-3F 7.00 ECCP-33 5.00 ECCP-5F 8.00 PYP-32 5.00 ECCP-31 7.00 CP-3F 8.00 ECCP-3F 10.00 ECCP-3 8.00 PYP-33 5.00 ECCP-32 8.00 CP-SF 8.00 PTP-35 6.00 ECCP-33 8.00 ECCP-35 8.00 ECCP-3 10.00 PTP-201 5.00 CPTP-301 5.00__________________________________________________________________________Examples 205 206 207 208 209__________________________________________________________________________S .fwdarw. N �.degree.C.! <-40 -- <-40 <-40 --Clearing point �.degree.C.! +83 +9o +88 +82 +82Viscosity �mm.sup.2 s.sup.-1 ! 20.degree.C. 20 21 21 21 20.1.DELTA.n (20.degree. C., 589 nm) +0.1561 +0.1168 +0.1468 +0.1003 +0.1241V.sub.(10,0,20) 1.94 2.#8 #.98 1.88 1.85V.sub.(50,0,20) 2.23 2.49 2.23 2.12 2.12V.sub.(90,0,20) 2.69 2.99 2.70 2.55Composition �%!: PCH-2 8.00 PCH-3 20.00 PCH-2 9.00 PCH-3 11.00 PCH-2 17.00 PCH-3 17.00 PCH-4 18.00 PCH-3 18.00 ME2N.F 2.00 PCH-3 15.00 K8 8.00 PCH-5 15.00 PCH-4 11.00 ME3N.F 3.00 PYP-3N.F 5.00 K9 8.00 PTP-201 4.00 PCH-5 12.00 MESN.F 7.00 PYP-SN.F 5.00 G9 8.00 ECCP-31 7.00 BCH-5 8.00 ME7N.F 7.00 PCH-304 10.00 ME2N.F 2.00 ECCP-32 7.00 BCH-32 8.00 PCH-301 10 00 PCH 12 00 ME3N.F 2.00 ECCP-33 7.00 BCH-52 8.00 CCH-301 9.00 ECCP-31 8.00 PCH-302 8.00 ECCP-35 7.00 ECCP-3F 8.00 CCH-303 9.00 ECCP-32 8.00 PTP-35 5.00 ECCP-3F 7.00 ECCP-SF 8.00 ECCP-31 8.00 ECCP-33 6.00 PTP-102 5.00 CP-3F 8.00 ECCP-33 8.00 ECCP-32 8.00 CBC-33 5.00 CPTP-302FF 4.00 CPTP-301 2.00 PTP-35 8.60 ECCP-33 8.00 CBC-53 5.00 ECCP-31 8.00 PTP-102 4.00 ECCP-35 8.00 CBC-33F 4.00 ECCP-32 8.00 CP-33F 8.00 CBC-55F 4.00 ECCP-33 7.00 CP-35F 6.00 CBC-33F 5.00 CP-55F 5.00 CBC-53F 5.00 CBC-53F 3.00__________________________________________________________________________Examples 210 211 212 213 214__________________________________________________________________________S .fwdarw. N �.degree.C.! <-30 <-30 -- <-40 <-40Clearing point �.degree.C.! +86 +84 +93 +88 +91Viscosity �mm.sup.2 s.sup.-1 ! 20.degree.C. 24 24 18 19 19.DELTA.n (20.degree. C., 589 nm) +0.1073 +0.1088 +0.0901 0.0903 +0.0945V.sub.(10,0,20) 1.48(1st) 1.46(1st) 2.04 19 2.00V.sub.(50,0,20) 1.86 1.8& 2.50 2.54 2.46V.sub.(90,0,20) 2.40 2.44 3.11 3.20 3.07Composition �%!: PDX-2 6.00 ME2N.F 2.00 PCH-3 9 PCH-3 10.00 PCH-3 12.00 PDX-3 9.00 PCH-3 18.00 PCH-4 12 PCH-4 10.00 PCH-4 11.00 PCH-3 10.00 PCH-4 18.00 PCH-5 7 PCH-5 7.00 PCH-5 7.00 PCH-4 11.00 PCH-5 18.00 PCH-302 5 PCH-302 13.00 PCH-302 12.00 ME2N.F 2.00 CCH-303 5.00 CCH-303 17 OS.33 6.00 C-33 7.00 ME3N.F 3.00 D-502FF 5.00 CCH-502 8 OS.35 6.00 C-35 7.00 CCH-503 8.00 CP-302FF 7.00 CP-3F 9 OS.53 4.00 CP-3F 8.00 ECCP-31 6.00 ECCP-31 5.00 CP-5F 9 CP-3F 8.00 CP-5F 8.00 ECCP-32 6.00 ECCP-3F 8.00 ECCP-33 12 CP-5F 8.00 ECCP-31 8.00 ECCP-33 6.00 ECCP-5F 8.00 ECCP-35 11 ECCP-3i 7.00 ECCP-33 7.00 ECCP-3 6.00 ECCP-3 8.00 CBC-53 3 ECCP-33 7.00 ECCP-35 7.00 ECCP-3F 7.00 ECCP-35 7.00 CP-33 8.00 CP-3F 7.00 CP-33 7.00 CP-5F 7.00__________________________________________________________________________Examples 215 216 217 218 219 220__________________________________________________________________________S .fwdarw. N �.degree.C.! <-30 <-40 -- -- <-30 <-30Clearing point �.degree.C.! +81 +85 +67 +94 +91 +100Viscosity �mm.sup.2 s.sup.-1 ! 20.degree. C. 19 23 40 19 18 21.DELTA.n (20.degree. C., 589 nm) +0.0997 +0.1072 +0.1235 +0.0871 +0.0929 0.0915V.sub.(10,0,20) 1.71(1st) 1.44(1st) 1.14 2.04 2.08 2.08V.sub.(50,0,20) 2.13 1.79 1.28 2.46 2.55 2.57V.sub.(90,0,20) 2.72 2.25 1.46 3.14 3.18 3.23Composition �%!: PCH-3 14.60 PCH-3 19.00 ME2N.F 4 PCH-3 9 PCH-3 12.00 PCH-3 12.00 PCH-4 13.80 PCH-4 11.00 ME3N.F 6 PCH-4 12 PCH-4 L1.00 PCH-4 10.00 PCH-5 15.00 PCH-5 8.00 ME5N.F 10 PCH-5 7 PCH-5 7.00 PCH-5 7.00 PCH-302 9.00 ME2N.F 2.00 ME7N.F 10 CCH-303 14 PCH-302 8.00 CCH-303 l5.00 C-33 5.80 ME3N.F 4.00 HP-3N.F 4 CCH-502 12 CCH-303 14.00 CP-3F 7.00 C-35 5.80 ME5N.F 5.00 HP-4N.F 8 CP-3F 9 CP-3F 8.00 CP-5F 7.00 CP-3F 8.40 CCH-303 12.00 HP-SN.F 4 CP-5F 9 CP-SF 8.00 CP-33 7.00 CP-57 8.40 ECCP-31 5.00 CCH-303 9 ECCP-31 9 ECCP-3F 8.00 CP-35 6.00 ECCP-3F 5.80 ECCP-32 5.00 CCH-502 9 ECCP-33 10 ECCP-31 8.00 ECCP-31 9.00 ECCP-31 5.00 ECCP-33 4.00 PCH-302 13 ECCP-35 9 ECCP-33 8.00 ECCP-3F 10.00 ECCP-33 5.00 ECCP-3 5.00 PYP-707 4 ECCP-35 8.00 ECCP-SF 10.00 CP-33 5.00 ECCP-3F 7.00 PYP-709 4 CP-3F 8.00 PYP-909 3 CP-SF 7.00 ECCP-31 4 ECCP-33 4 ECCP-35 4__________________________________________________________________________Examples 221 222 223 224 225__________________________________________________________________________S .fwdarw. N �.degree.C.! <-30 <-30 <-40 <-30 <-40Clearing point �.degree.C.! +91 +87 +90 +94 +89Viscosity �mm.sup.2 s.sup.-1 ! 20.degree. C. 23 23 18 18 18.DELTA.n (20.degree. C., 589 nm) +0.1081 +0.1090 0.0923 0.0914 +0.0916V.sub.(10,0,20) 1.82 1.59(1st) 2.03 2.17 1.98V.sub.(50,0,20) 2.00 -1.98 2.49 2.85 2.45V.sub.(90,0,20) 2.52 2.57 3.11 3.27 3.11Composition �%!: PCH-3 20.00 ME2N.F 2.00 PCH-3 12.00 PCH-3 10.00 PCH-3 12.00 PCH-4 10.00 PCH-3 18.00 PCH-4 11.00 PCH-4 9.00 PCH-4 11.0 PCH-5 10.00 PCH-4 10.00 PCH-5 7.00 PCH-5 7.00 PCH-5 7.00 ME2N.F 3.00 PCH-5 18.00 PCH-302 10.00 PCH-302 10.00 PCH-3C2 10.00 ME3N.F 4.00 CCH-303 7.00 CCH-303 16.00 CCH-303 16.00 CCH-3C3 16.00 PCH-302 7.00 CP-302FF 7.00 CP-3F 8.00 CP-3F 8.00 CP-3F 8.00 ECCP-31 7.00 ECCP-31 4.00 CP-5F 8.00 CP-5F 8.00 CP-5F 8.00 ECCP-32 7.00 ECCP-33 4.00 ECCP-31 8.00 ECCP-31 8.00 ECCP-3F 7.00 ECCP-33 9.00 ECCP-35 8.00 ECCP-33 7.00 ECCP-33 9.00 ECCP-31 7.00 CH-33 4.00 ECCP-5F 8.00 ECCP-35 7.00 ECCP-35 9.00 ECCP-33 7.00 CH-35 4.00 ECCP-3 8.00 CP-33 7.00 CP-33 6.00 CP-33 7.00 CP-3F 8.00 CP-5F 7.00__________________________________________________________________________Examples 226 227 228 229 230__________________________________________________________________________S .fwdarw. N �.degree.C.! <-20 <-40 <-40 <-30 <-40Clearing point �.degree.C.! +87 +90 +91 +87 +91Viscosity �mm.sup.2 s.sup.-1 ! 20.degree. C. 27 18 19 23 19.DELTA.n (20.degree. C., 589 nm) +0.1076 0.00923 -0.0939 +0.1090 +0.0939V.sub.(10,0,20) 1.54 2.03 2.03 1.59(1st) 2.03V.sub.(50,0,20) 1.87 2.49 2.47 1.98 2.47V.sub.(90,0,20) 2.37 3.11 3.05 2.57 3.05Composition �%!: PDX-2 7.00 PCH-3 12.00 PCH-3 12.00 ME2N.F 2.00 PCH-3 12.00 PDX-3 12.00 PCH-4 11.00 PCH-4 11.00 PCH-3 18.00 PCH-4 11.00 PDX-4 13.00 PCH-5 7.00 PCH-5 7.00 PCH-4 16.00 PCH-5 7.00 PDX-5 12.00 PCH-302 10.00 PCH-302 12.00 PCH-5 18.00 PCH-302 12.00 PCH-302 18.00 CCH-303 10.00 C-33 7.00 CCH-303 7.00 C-33 7.00 ECCP-31 4.00 CP-3F 5.00 C-35 7.00 CP-302FF 7.00 C-36 7.00 ECCP-32 5.00 CP-5F 8.00 CP-3F 8.00 ECCP-31 4.00 CP-3F 8.00 ECCP-33 5.00 ECCP-31 8.00 CP-5F 8.00 ECCP-33 4.00 CP-5F 8.00 CH-33 3.00 ECCP-33 7.00 ECCP-3F 7.00 ECCP-3F 8.00 ECCP-3F 7.00 CH-35 3.00 ECCP-35 7.00 ECCP-31 7.00 ECCP-5F 8.00 ECCP-31 7.00 CH-43 3.00 CP-33 8.00 ECCP-33 7.00 ECCP-3 8.00 ECCP-33 7.00 CBC-33F 4.00 CP-33 7.00 CP-33 7.00 CBC-53F 4.00 CBC-55F 4.00__________________________________________________________________________Examples 231 232 233 234 235__________________________________________________________________________S .fwdarw. N �.degree.C.! -- <-40 <-40 -- --Clearing point �.degree.C.! +68 +91 +72 +84 +110Viscosity �mm.sup.2 s.sup.-1 ! 20.degree. C. 17 23 16 19 --.DELTA.n (20.degree. C., 589 nm) +0.0938 +0.1170 +0.1134 +0.1186 +0.1511V.sub.(10,0,20) 1.41 1.99 1.83 1.97(2nd) 2.22V.sub.(50,0,20) 1.79 2.30 2.12 2.25 2.56V.sub.(90,0,20) 2.29 2.78 2.56 2.68 3.11Composition �%!: PCH-2 8.0 PCH-3 22.0 K6 8.0 PCH-3 15.0 PCH-3 20.00 PCH-3 21.0 PCH-4 23.0 K9 8.0 PCH-4 10.0 PCH-4 13.00 PCH-4 10.0 PCH-5 9.0 PCH-3 20.0 PCH-5 15.0 PCH-5 15.0 PCH-5F 12.0 K6 5.0 PCH-5F 10.00 ME2N.F 2.0 BCH-5 8.0 PCH-7F 10.00 ECCP-31 4.0 PCH-7F 10.00 ME3N.F 3.0 T15 8.0 ECCP-3F 8.0 ECCP-32 5.0 ECCP-3F 10.00 PCH-302 7.0 ECCP-3 8.00 ECCP-5F 7.0 ECCP-33 5.0 ECCP-5F 10.00 CCH-303 5.0 CCH-303 10.00 CP-3F 9.0 ECCP-35 5.0 CP-3F 11.0 BCH-32 9.0 CBC-33 3.00 CP-5F 9.0 CP-3F 10.0 CP-5F 11.0 BCH-52 9.0 CBC-33F 5.00 CBC-33F 2.0 CP-5F 7.0 CPTP-303 2.0 ECCP-31 5.0 CBC-33F 5.00 CBC-53F 2.0 CCPC-33 5.0 ECCP-32 5.0 CBC-53F 5.00 CBC-55F 2.0 ECCP-33 5.0 CBC-55F 5.00 ECCP-3F 10.0__________________________________________________________________________Examples 236 237 238 239 240__________________________________________________________________________S .fwdarw. N �.degree.C.! <-40 <-20 <-40 <-30 <-30Clearing point �.degree.C.! +83 +126 +89 +87 +117Viscosity �mm.sup.2 s.sup.-1 ! 20.degree. C. 20 33 22 21 30.DELTA.n (20.degree. C., 589 nm) +0.1563 +0.1316 +0.1493 +0.1489 +0.1167V.sub.(10,0,20) 1.92 2.00 1.92 2.01 2.03V.sub.(50,0,20) 2.21 2.30 2.17 2.30 2.32V.sub.(90,0,20) 2.67 2.76 2.64 2.77 2.78Composition �%!: PCH-2 8.00 PCH-3 18.00 PCH-2 9.00 PCH-2 8.00 PCH-3 14.00 PCH-3 17.00 ME2N.F 2.00 PCH-3 16.00 PCH-3 17.00 ME2N.F 2.00 K6 6.00 ME3N.F 3.00 PCH-4 11.00 K6 6.00 ME3N.F 3.00 K9 5.00 ME5N.F 6.00 PCH-5 12.00 K9 6.00 ME5N.F 7.00 G9 7.00 ME7N.F 6.00 BCH-5 8.00 G9 6.00 ME7N.F 7.00 ME2N.F 2.00 HP-3N.F 6.00 BCH-32 8.00 ME2N.F 2.00 CCH-301 9.00 ME3N.F 3.00 CCH-302 5.00 BCH-52 8.00 ME3N.F 2.00 CCH-303 8.00 PCH-302 6.00 CCH-303 6.00 ECCP-3F 6.00 PCH-302 6.00 ECCP-31 4.00 PTP-36 5.00 ECCP-31 4.00 ECCP-5F 6.00 PTP-35 3.00 ECCP-32 6.00 PTP-102 5.00 ECCP-32 4.00 ECCP-33 6.00 PTP-102 3.00 ECCP-33 4.00 CPTP-302FF 4.00 ECCP-33 4.00 PTP-102 4.00 CPTP-302FF 4.00 CH-33 4.00 ECCP-31 8.00 ECCP-3F 5.00 PTP-201 6.00 ECCP-31 7.00 CH-35 4.00 ECCP-32 7.00 ECCP-5F 5.00 ECCP-32 7.00 CH-43 4.00 ECCP-33 8.00 CBC-33 4.00 ECCP-33 7.00 CBC-53 6.00 CBC-33 5.00 CBC-53 4.00 ECCP-35 6.00 CBC-33F 6.00 CBC-53 4.00 CBC-33F 6.00 CBC-33F 5.00 CBC-53F 6.00 CBC-53F 6.00 CBC-53F 5.00 CBC-55F 6.00 CBC-55F 6.00__________________________________________________________________________Examples 241 242 243 244 245__________________________________________________________________________S .fwdarw. N �.degree.C.! -- <-40 <-40 -- --Clearing point �.degree.C.! +68 +91 +72 +84 +119Viscosity �mm.sup.2 s.sup.-1 ! 20.degree. C. 17 23 16 19 --.DELTA.n (20.degree. C., 589 nm) +0.0938 +0.1170 +0.1134 +0.1186 +0.1511V.sub.(10,0,20) 1.41 1.99 1.83 1.97(2nd) 2.22V.sub.(50,0,20) 1.79 2.30 2.12 2.25 2.56V.sub.(90,0,20) 2.29 2.78 2.56 2.68 3.11Composition �%!: PCH-2 8.0 PCH-3 22.0 K6 8.0 PCH-3 16.0 PCH-3 20.00 PCH-3 21.0 PCH-4 23.0 K9 8.0 PCH-4 10.0 PCH-4 13.00 PCH-4 10.0 PCH-5 9.0 PCH-3 20.0 PCH-5 16.0 PCH-5 15.00 PCH-5F 12.0 K6 5.0 PCH-5F 10.0 ME2N.F 2.0 BCH-5 8.00 PCH-7F 10.0 ECCP-31 4.0 PCH-7F 10.0 ME3N.F 3.0 T15 8.00 ECCP-3F 8.0 ECCP-32 5.0 ECCP-3F 10.0 PCH-302 7.0 ECCP-3 8.00 ECCP-5F 7.0 ECCP-33 5.0 ECCP-5F 10.0 CCH-303 5.0 CCH-303 10.00 CP-3F 9.0 ECCP-35 5.0 CP3F 11.0 BCH-32 9.0 CBC-33 3.00 CP-5F 9.0 CP-3F 10.0 CP5F 11.0 BCH-52 9.0 CBC-33F 5.00 CBC-33F 2.0 CP-5F 7.0 CPTP-303 2.0 ECCP-31 5.0 PCH-53F 5.00 CBC-53F 2.0 CCPC-33 5.0 ECCP-32 5.0 PCH-55F 5.00 CBC-55F 2.0 ECCP-33 5.0 ECCP-3F 10.00__________________________________________________________________________Examples 246 247 248 249 250__________________________________________________________________________S .fwdarw. N �.degree.C.! <-40 <-30 <-40 <-40 <-30Clearing point �.degree.C.! +79 +81 +80 +91 +90Viscosity �mm.sup.2 s.sup.-1 ! 20.degree. C. 20 23 20 20 23.DELTA.n (20.degree. C., 589 nm) +0.1453 +0.1328 +0.1465 +0.1554 +0.1597V.sub.(10,0,20) 1.86 1.95 1.93 2.10 1.87V.sub.(50,0,20) 2.14 2.25 2.21 2.38 2.15V.sub.(90,0,20) 2.56 2.72 2.69 2.81 2.60Composition �%!: PCH-2 10.00 PCH-2 9.00 PCH-2 10.00 PCH-3 22.00 PCH-2 8.00 PCH-3 18.00 PCH-3 22.00 PCH-3 18.00 PCH-4 18.00 PCH-3 17.00 PCH-4 14.00 PCH-4 18.00 PCH-4 14.00 PCH-302 4.00 K6 6.00 PCH-5 14.00 K6 7.00 PCH-5 15.00 PTP-102 5.00 K9 5.00 BCH-32 8.00 K9 7.00 PTP-102 5.00 PTP-201 6.00 G9 7.00 BCH-52 8.00 ECCP-3 11.00 PTP-201 5.00 CPTP-301 4.00 ME2N 3.00 I32 7.00 ECCP-31 7.00 ECCP-3F 4.00 ECCP-31 6.00 ME3N 3.00 ECCP-3F 5.00 ECCP-32 7.00 ECCP-5F 4.00 ECCP-33 6.00 ME2N.F 2.00 ECCP-5F 5.00 ECCP-33 7.00 ECCP-31 5.00 BCH-32 10.00 ME3N.F 3.00 PTP-102 7.00 ECCP-35 7.00 ECCP-32 5.00 BCH-52 9.00 PCH-302 6.00 CPTP-301 4.00 ECCP-33 5.00 BCH-52F 10.00 PTP-102 3.00 CPTP-301 5.00 CPTP-301 4.00 CPTP-302 5.00 CPTP-302FF 4.00 ECCP-31 6.00 ECCP-32 6.00 ECCP-33 7.00 CBC-33 5.00 CBC-53 5.00__________________________________________________________________________Examples 251 252 253 254 255__________________________________________________________________________S .fwdarw. N �.degree.C.! <-40 <-30 <-30 <-40 <-30Clearing point �.degree.C.! +72 +103 +91 +80 +87Viscosity �mm.sup.2 s.sup.-1 ! 20.degree. C. 17 28 22 21 24.DELTA.n (20.degree. C., 589 nm) +0.1135 +0.1443 +0.1510 +0.1536 +0.1107V.sub.(10,0,20) 1.97 2.18 2.01 1.85 1.67(1st)V.sub.(50,0,20) 2.22 2.52 2.26 2.12 2.06V.sub.(90,0,20) 2.65 3.09 2.73 2.53 2.62Composition �%!: PCH-3 16.0 PCH-2 6.00 PCH-2 8.00 PCH-3 10.00 ME2N.F 2.00 PCH-4 16.0 PCH-3 17.00 PCH-3 16.00 ME2N.F 2.00 PCH-3 18.00 PCH-5 10.0 PCH-4 11.00 PCH-4 10.00 ME3N.F 3.00 PCH-4 17.00 PCH-302 14.0 PCH-5 13.00 PCH-5 12.00 ME5N.F 7.00 PCH-5 18.00 ECCP-3F 9.0 D-302FF 5.00 BCH-5 8.00 ME7N.F 7.00 CCH-303 7.00 ECCP-5F 9.0 D-502FF 6.00 BCH-32 9.00 PCH-301 16.00 CP-302FF 12.00 CP-3F 8.0 CP-302FF 6.00 BCH-52 8.00 PCH-501 4.00 ECCP-31 4.00 CP-5F 8.0 CP-402FF 5.00 I32 5.00 PTP-35 7.00 ECCP-3F 8.00 PTP-35 5.0 CPTP-302FF 2.00 ECCP-31 3.00 PTP-45 7.00 ECCP-5F 8.00 PTP-45 5.0 CPTP-301 6.00 ECCP-32 3.00 ECCP-31 5.00 ECCP-3 6.00 CPTP-302 5.00 ECCP-33 3.00 ECCP-32 5.00 CPTP-303 7.00 ECCP-3F 3.00 ECCP-33 5.00 ECCP-31 6.00 ECCP-5F 3.00 ECCP-35 5.00 ECCP-33 5.00 PTP-102 3.00 CBC-53F 4.00 PTP-201 6.00 CPTP-301 5.00 CPTP-302 4.00 CPTP-303 4.00__________________________________________________________________________Examples 256 257 258 259 260__________________________________________________________________________S .fwdarw. N �.degree.C.! -- <-40 <-40 -- --Clearing point �.degree.C.! -- +71 +87 +88 +125.0Viscosity �mm.sup.2 s.sup.-1 ! 20.degree. C. -- 16 18 24 --.DELTA.n (20.degree. C., 589 nm) -- +0.1142 +0.1149 +0.1073 +0.1364V.sub.(10,0,20) -- 1.94 2.27 1.54(1st) --V.sub.(50,0,20) -- 2.26 2.60 1.96 --V.sub.(90,0,20) -- 2.66 3.13 2.50Composition �%!: PCH-3 20.0 ME2N.F 2.0 PCH-3 20.0 PCH-3 18.0 PCH-3 18.00 ME2N.F 3.0 ME2N.F 3.0 PCH-5 15.0 PCH-4 16.0 ME2N.F 2.00 ME3N.F 4.0 PCH-3 20.0 PCH-302 10.0 PCH-5 18.0 ME3N.F 3.00 ME5N.F 6.0 PCH-5F 10.0 ECCP-3F 12.0 CCH-303 4.0 ME5N.F 6.00 PCH-301 8.0 PCH-7F 10.0 ECCP-5F 12.0 D-502FF 5.0 ME7N.F 6.00 PCH-302 20.0 ECCP-3F 10.0 CP-3F 11.0 CP-302FF 6.0 HP-3N.F 6.00 ECCP-31 5.0 ECCP-5F 10.0 CP-5F 10.0 ECCP-32 4.0 PCH-302 8.00 ECCP-32 5.0 CP-3F 10.0 PTP-35 5.0 ECCP-3F 8.0 CCH-303 3.00 ECCP-33 5.0 CP-5F 10.0 PTP-45 5.0 ECCP-5F 8.0 ECCP-31 5.00 ECCP-35 5.0 PTP-35 6.0 ECCP3 7.0 ECCP-32 5.00 CPTP-301 4.0 PTP-45 6.0 CH-33 3.0 ECCP-33 5.00 CPTP-302 3.0 CPTP-303 3.0 CH-35 3.0 ECCP-3F 7.00 CPTP-303 4.0 CBC-33 5.00 CCPC-33 4.0 CBC-53 5.00 CCPC-35 4.0 CBC-33F 5.00 CBC-53F 6.00 CBC-55F 6.00__________________________________________________________________________Examples 261 262 263 264 265__________________________________________________________________________S .fwdarw. N �.degree.C.! <-40 -- <-40 <0 <-20Clearing point �.degree.C.! +82 89.0 +85 +122 +119Viscosity �mm.sup.2 s.sup.-1 ! 20.degree. C. 19 -- 20 30 31.DELTA.n (20.degree. C., 589 nm) 0.1178 +0.1603 +0.1574 +0.1198 0.1156V.sub.(10,0,20) 1.65 2.0 1.93 1.99 1.93V.sub.(50,0,20) 2.06 2.4 2.20 2.29 2.21V.sub.(90,0,20) 2.67 2.8 2.63 2.76 2.64Composition �%!: PCH-3 22.00 PCH-2 7.00 PCH-2 8.00 PCH-3 14.00 PCH-3 14.00 ME2N.F 3.00 PCH-3 17.00 PCH-3 17.00 ME2N.F 2.00 ME2N.F 2.00 ME3N.F 3.00 K6 7.00 K6 6.00 ME3N.F 3.00 ME3N.F 3.00 ME5N.F 2.00 K9 5.00 K9 5.00 ME4N.F 7.00 ME4N.F 7.00 PCH-53 9.00 G9 6.00 G9 7.00 ME5N.F 7.00 ME5N.F 7.00 PCH-302 18.00 ME2N.F 2.00 ME2N.F 2.00 CCH-301 8.00 CCH-301 10.00 BCH-52 12.00 ME3N.F 2.00 ME3N.F 3.00 CCH-303 9.00 CCH-303 6.00 ECCP-31 6.00 PCH-302 7.00 PCH-302 6.00 ECCP-31 4.00 ECCP-31 4.00 ECCP-32 6.00 PTP-35 5.00 PTP-35 5.00 ECCP-32 3.00 ECCP-32 4.00 ECCP-33 6.00 PTP-102 5.00 PTP-102 5.00 ECCP-33 3.00 ECCP-33 4.00 ECCP-3 13.00 CPTP-301 4.00 CPTP-301 4.00 CP-33 5.00 CH-33 4.00 ECCP-31 8.00 ECCP-31 8.00 CP-35 5.00 CH-35 4.00 ECCP-32 8.00 ECCP-32 7.00 CH-33 3.00 CH-43 4.00 ECCP-33 7.00 ECCP-33 8.00 CH-35 3.00 CH-45 3.00 CBC-33 5.00 CBC-33 5.00 CBC-33 6.00 CBC-33 6.00 CBC-53 5.00 CBC-53 4.00 CBC-53 6.00 CBC-53 6.00 CBC-53F 6.00 CBC-53F 6.00 CBC-55F 6.00 CBC-55F 6.00__________________________________________________________________________Examples 266 267 268 269 270__________________________________________________________________________S .fwdarw. N �.degree.C.! <-40 -- <-40 <-30 --Clearing point �.degree.C.! +90 +115 +89 +116 +85Viscosity �mm.sup.2 s.sup.-1 ! 20.degree. C. 20 -- 22 30 --.DELTA.n (20.degree. C., 589 nm) +0.1498 +0.1211 0.1155 0.1165 +0.1073V.sub.(10,0,20) 2.09 2.04 2.111 1.96 1.41(1st)V.sub.(50,0,20) 2.40 2.35 2.46 2.24 1.79V.sub.(90,0,20) 2.90 2.85 3.03 2.71 2.32Composition �%!: PCH-3 22.00 PCH-3 18.00 PCH-3 18.00 PCH-3 14.00 PDX-2 6.00 PCH-4 23.00 ME2N.F 2.00 PDX-3 8.00 ME2N.F 2.00 PDX-3 11.00 CCH-301 8.00 ME3N.F 3.00 PDX-4 7.00 ME3N.F 3.00 PDX-4 10.00 PTP-102 4.00 ME4N.F 5.00 PCH-301 2.00 ME4N.F 7.00 PCH-3 12.00 PTP-201 5.00 ME5N.F 5.00 D-301 10.00 ME5N.F 7.00 PCH-4 8.00 CPTP-301 6.00 PCH-301 8.00 D-401 10.00 PCH-301 9.00 PCH-302 8.00 CPTP-302 5.00 CCH-301 9.00 D-501 10.00 CCH-301 8.00 ECCP-31 6.00 CPTP-303 5.00 ECCP-31 4.00 CP-33 6.00 ECCP-31 4.00 ECCP-32 6.00 ECCP-31 7.00 ECCP-32 4.00 CP-35 6.00 ECCP-32 6.00 ECCP-33 6.00 ECCP-33 7.00 ECCP-33 4.00 ECCP-31 5.00 ECCP-33 4.00 ECCP-3 6.00 ECCP-35 8.00 CP-33 5.00 ECCP-32 5.00 CH-33 4.00 ECCP-3F 7.00 CP-35 5.00 ECCP-33 5.00 CH-35 4.00 CP-3F 7.00 CH-33 4.00 CPTP-301 4.00 CH-43 4.00 CP-5F 7.00 CBC-53 6.00 CPTP-302 4.00 CBC-53 6.00 CBC-33F 6.00 CBC-33F 6.00 CBC-53F 6.00 CBC-53F 6.00 CBC-55F 6.00 CBC-55F 6.00__________________________________________________________________________Examples 271 272 273 274 275__________________________________________________________________________S .fwdarw. N �.degree.C.! <20 <-40 -- <-30 <-30Clearing point �.degree.C.! +112 +91 117.0 +81 +118Viscosity �mm.sup.2 s.sup.-1 ! 20.degree. C. 26 20 -- 20 33.DELTA.n (20.degree. C., 589 nm) +0.1499 +0.1554 +0.1256 +0.1459 +0.1241V.sub.(10,0,20) 2.09 2.17 2.1 1.95 1.97V.sub.(50,0,20) 2.31 2.47 2.4 2.21 2.27V.sub.(90,0,20) 2.81 2.94 2.9 2.70 2.73Composition �%!: ME2N.F 2.00 PCH-3 20.00 PCH-3 20.00 PCH-3 19.00 PCH-3 20.00 ME3N.F 3.00 PCH-4 11.00 PYP-3N.F 5.00 PCH-4 17.00 PYP-3N.F 5.00 PYP-5N.F 8.00 G9 15.00 PYP-5N.F 6.00 PCH-5 18.00 PYP-5N.F 6.00 PYP-6N.F 8.00 PTP-35 6.00 PYP-7N.F 6.00 BCH-32 12.00 PYP-7N.F 6.00 HP-3N.F 5.00 PTP-102 2.00 CCH-301 12.00 BCH-52 11.00 CCH-301 12.00 PCH-301 10.00 PTP-201 5.00 ECCP-31 4.00 ECCP-31 4.00 ECCP-31 3.00 CCH-303 12.00 CPTP-301 4.00 ECCP-32 4.00 ECCP-32 4.00 CH-33 5.00 ECCP-31 7.00 CPTP-303 4.00 ECCP-33 5.00 ECCP-33 4.00 CH-35 5.00 ECCP-32 7.00 ECCP-31 6.00 CP-43 4.00 PTP-35 6.00 CH-43 5.00 ECCP-33 8.00 ECCP-33 6.00 CH-33 4.00 PTP-102 5.00 CH-45 5.00 ECCP-35 8.00 CP-3F 8.00 CH-35 4.00 CBC-33 4.00 CPTP-301 6.00 BCH-32 6.00 CH-43 4.00 CBC-53 4.00 CPTP-302 5.00 BCH-52 7.00 CBC-33 8.00 CBC-53F 5.00 CPTP-303 7.00 CBC-53 5.00 CBC-55F 5.00 CBC-33F 4.00 CBC-53F 6.00 ECCP-3 10.00 CBC-55F 5.00__________________________________________________________________________Examples 276 277 278 279 280__________________________________________________________________________S .fwdarw. N �.degree.C.! <20 <0 <0 <0 <-40Clearing point �.degree.C.! +110 +98 +106 83 +79Viscosity �mm.sup.2 s.sup.-1 ! 20.degree. C. 24 22 25 19 18.DELTA.n (20.degree. C., 589 nm) +0.1518 +0.1235 +0.1168 +0.1527 +0.1514V.sub.(10,0,20) 2.09 2.33 2.15 2.17 2.07V.sub.(50,0,20) 2.39 2.65 2.46 2.46 2.37V.sub.(90,0,20) 2.84 3.16 2.95 2.89 2.85Composition �%!: ME2N.F 2.00 ME2N.F 2.00 PCH-5 18.00 ME2N.F 2.00 PCH-3 20.00 ME3N.F 3.00 ME3N.F 5.00 PDX-3 8.00 ME3N.F 3.00 PCH-4 15.00 ME4N.F 6.00 ME6N.F 7.00 PDX-4 8.00 K6 6.009 PCH-5 8.00 ME5N.F 6.00 ME7N.F 4.00 PDX-5 8.00 K9 8.00 PCH-302 14.00 HP-3N.F 4.00 CCH-301 13.00 PCH-301 15.00 K15 8.00 PTP-35 3.00 PCH-301 15.00 CCH-303 20.00 ECCP-31 3.00 PCH-301 7.00 PTP-102 5.00 PTC-35 8.00 ECCP-31 8.00 ECCP-32 3.00 PYP-32 6.00 PTP-201 5.00 ECCP-31 6.00 ECCP-32 8.00 ECCP-33 3.00 PYP-33 6.00 ECCP-31 5.00 ECCP-32 6.00 ECCP-33 7.00 ECCP-36 4.00 PTP-201 6.00 ECCP-32 5.00 ECCP-33 6.00 ECCP-35 7.00 CH-33 4.00 ECCP-31 8.00 ECCP-33 5.00 ECCP-35 6.00 CPTP-301 5.00 CH-35 4.00 ECCP-32 8.00 ECCP-35 3.00 ECCP-3F 7.00 CPTP-302FF 8.00 CH-43 5.00 ECCP-33 8.00 CPTP-301 5.00 CP-3F 9.00 CPTP-502FF 6.00 CBC-33 5.00 ECCP-36 8.00 CPTP-302 3.00 CPTP-301 5.00 CBC-44 5.00 ECCP-3f 8.00 CPTP-303 4.00 CPTP-302 5.00 CBC-53 5.00 ECCP-3 8.00 CPTP-303 6.00 CBC-55 4.00 ECCP-3 4.00__________________________________________________________________________Examples 281 282 283 284 285__________________________________________________________________________S .fwdarw. N �.degree.C.! -- -- <-40 -- <-40Clearing point �.degree.C.! 99.4 91.0 +85 +86 +87Viscosity �mm.sup.2 s.sup.-1 ! 20.degree. C. -- -- 23 21.5 23.DELTA.n (20.degree. C., 589 nm) -- -- +0.1072 +0.1069 +0.1074V.sub.(10,0,20) -- -- 1.44(1st) 1.40(1st) 1.49(1st)V.sub.(50,0,20) -- -- 1.79 1.80 1.88V.sub.(90,0,20) -- -- 2.25 2.34 2.38Composition �%!: PCH-3 18.80 PDX-2 6.50 PCH-3 19.00 PDX-2 5.00 PCH-3 19.00 PCH-4 12.90 PDX-3 9.80 PCH-4 11.00 PCH-3 20.00 PCH-4 11.00 ME2N.F 2.40 PCH-3 17.40 PCH-5 6.00 PCH-4 10.00 PCH-5 8.00 ME3N.F 3.50 PCH-4 12.00 ME2N.F 2.00 ME2N.F 2.00 M32N.F 2.00 CCH-303 9.40 ME2N.F 2.20 ME3N.F 4.00 ME3N.F 2.00 ME3N.F 3.00 ECCP-31 7.10 ME3N.F 3.30 ME5N.F 5.00 ME6N.F 6.00 ME5N.F 4.00 ECCP-32 7.10 ECCP-31 6.50 CCH-303 12.00 CCH-303 11.00 CCH-303 11.00 ECCP-33 7.10 ECCP-32 6.50 ECCP-31 5.00 ECCP-31 6.00 ECCP-31 3.00 ECCP-3 7.10 ECCP-33 6.50 ECCP-32 5.00 ECCP-32 6.00 ECCP-32 3.00 ECCP-3F 8.20 ECCP-3 6.50 ECCP-33 4.00 ECCP-33 5.00 ECCP-33 3.00 CP-3F 8.20 ECCP-3F 7.60 ECCP-3 5.00 ECCP-3 6.00 ECCP-3 7.00 CP-5F 8.20 CP-3F 7.60 ECCP-3F 7.00 ECCP-3F 7.00 ECCP-3F 6.00 CP-5F 7.60 CP-3F 8.00 CP3F 7.00 ECCP-5F 6.00 CP-5F 7.00 CP-5F 7.00 CP-3F 7.00 CP-5F 7.00__________________________________________________________________________Examples 286 2187 288 289 290__________________________________________________________________________S .fwdarw. N �.degree.C.! <-40 -- <-40 -- <-30Clearing point �.degree.C.! +85 +80 +91 +77 +123Viscosity �mm.sup.2 s.sup.-1 ! 20.degree. C. 20 -- 23 Cry. 34.DELTA.n (20.degree. C., 589 nm) +0.1570 +0.1647 +0.1155 +0.1503 +0.1337V.sub.(10,0,20) 1.97 2.12 1.94 2.50 2.09V.sub.(50,0,20) 2.26 2.38 2.24 2.82 2.40V.sub.(90,0,20) 2.73 2.80 2.72 3.35 2.85Composition �%!: PCH-2 8.00 PCH-3 15.0 PCH-3 22.00 PCH-3 10.00 PCH-3 20.00 PCH-3 17.00 PDX-3 8.0 PCH-4 20.00 PCH-5F 15.00 PCH-4 13.00 K6 6.00 PDX-5 8.0 PCH-5 13.00 PTP-35 6.00 PCH-5 15.00 K9 6.00 PCH301 8.0 HP-3N.F 4.00 PTP-45 6.00 HP-3N.F 5.0 G9 6.00 PTP-35 5.0 ECCP-31 5.00 PTP-201 9.00 HP-4N.F 5.00 ME2N.F 2.00 PTP-45 5.0 ECCP-32 5.00 PTP-102 9.00 ECCP-3F 5.00 ME3N.F 2.00 PTP-102 7.0 ECCP-33 6.00 BCH-5OCH3 10.00 ECCP-5F 5.00 PCH-302 6.00 PTP-201 7.0 ECCP-35 6.00 ECCP-3OCF3 9.00 CCH-303 5.00 PTP-35 5.00 ECCP-31 7.0 CP-3F 8.00 ECCP-5OCF3 9.00 CBC-33 4.00 PTP-102 5.00 ECCP-33 6.0 CP-5F 5.00 ECCP-3F 9.00 CBC-53 5.00 CPTP-301 4.00 BCH-32 12.0 BCH-321 4.00 ECCP-5F 8.00 CBC-33F 6.00 ECCP-31 8.00 BCH-52 12.0 CBC-35F 6.00 ECCP-32 8.00 CBC-55F 6.00 ECCP-33 7.00 CBC-33F 5.00 CBC-63F 6.00__________________________________________________________________________Examples 291 292 293 294 295__________________________________________________________________________S .fwdarw. N �.degree.C.! -- -- -- <-40 <-20Clearing point �.degree.C.! +80 87.0 +92 +87 +124Viscosity �mm.sup.2 s.sup.-1 ! 20.degree. C. 23 21 -- 20 32.DELTA.n (20.degree. C., 589 nm) +0.1096 +0.1322 +0.1182 +0.1294 +0.1385V.sub.(10,0,20) 1.45(1st) 2.1 2.09 2.38 1.98V.sub.(50,0,20) 1.86 2.4 2.41 2.72 2.26V.sub.(90,0,20) 2.40 2.8 2.94 3.29 2.74Composition �%!: PCH-2 7.0 PCH-2 10.0 PCH-3 22.0 PCH-3 13.00 PCH-3 18.00 PCH-3 18.0 PCH-3 20.0 PCH-4 23.0 PDX-3 8.00 ME2N.F 2.00 PCH-4 16.0 PCH-5 10.0 PCH-5 98.0 PDX-4 7.00 ME3N.F 3.00 PCH-5 15.0 G9 10.0 BCH-5 5.0 PCH-301 13.00 ME6N.F 6.00 CCH-303 5.0 ME2N 5.0 PCH-302 2.0 PCH-501 7.00 ME2N.F 6.00 D-502FF 4.0 CCH-303 4.0 ECCP-31 5.0 CP-33 6.00 HP-3N.F 6.00 CP-302FF 6.00 ECCP-3F 6.0 ECCP-32 5.0 CP35 5.00 PCH-302 11.00 ECCP-31 5.0 ECCP-5F 6.0 ECCP-33 5.0 CP-43 4.00 ECCP-31 5.00 ECCP-3F 8.0 ECCP-31 6.0 ECCP-35 4.00 CP-45 4.00 ECCP-32 5.00 ECCP-5F 8.0 ECCP-32 6.0 CP-3F 10.0 ECCP-31 5.00 ECCP-33 5.00 ECCP-3 8.0 ECCP-33 5.0 CP-5F 7.0 ECCP-32 5.00 ECCP-3F 7.00 CPTP-301 4.0 BCH-32 3.0 ECCP-33 5.00 CBC-33 5.00 CPTP-302 4.0 PTP-302FF 5.00 CBC-53 5.00 CPTP-303 4.0 PTP-502FF 5.00 CBC-33F 5.00 CPTP-502FF 5.00 CBC-53F 6.00 CPTP-301 3.00 CBC-55F 5.00__________________________________________________________________________Examples 296 297 298 299 300__________________________________________________________________________S .fwdarw. N �.degree.C.! <0 <-40 <-20 <-30 <-20Clearing point �.degree.C.! +90 +87 +88 +82 +85Viscosity �mm.sup.2 s.sup.-1 ! 20.degree. C. 36 22 20 17 18.DELTA.n (20.degree. C., 589 nm) +0.1528 +0.1355 +0.1496 +0.1425 +0.1579V.sub.(10,0,20) 1.35 1.85 2.02 2.21 2.26V.sub.(50,0,20) 1.57 2.14 2.32 2.52 2.55V.sub.(90,0,20) 1.91 2.60 2.81 3.01 3.05Composition �%!: ME2N.F 4.00 PCH-2 7.00 PCH-2 8.00 PCH-3 20.00 PYP-3N.F 4.00 ME3-N.F 6.00 PCH-3 17.00 PCH-3 16.00 PCH-4 9.00 PYP-5N.F 4.00 ME4N.F 10.00 G9 10.00 K6 6.00 ME5N.F 4.00 PYP-7N.F 5.00 ME6N.F 10.00 ME2N 5.00 K9 6.00 PCH-301 15.00 PTP-35 8.00 HP-3N.F 5.00 ME2N.F 2.00 G9 6.00 PCH-302 4.00 PTP-45 8.00 HP-4N.F 5.00 ME2N.F 3.00 ME2N.F 2.00 ECCP.31 7.00 PCH-301 16.00 HP-5N.F 4.00 HP-3N.F 5.00 ME3N.F 2.00 ECCP-32 7.00 ECCP-31 7.00 PCH-302 18.00 PCH-302 10.00 PCH-302 6.00 ECCP-33 7.00 ECCP-32 7.00 ECCP-31 5.00 CCH-303 4.00 PTP-35 3.00 ECC-35 7.00 ECCP-33 8.00 ECCP-32 5.00 ECCP-31 6.00 PTP-102 3.00 PTP-102 5.00 ECCP-35 8.00 ECCP-33 6.00 ECCP-32 7.00 CPTP-302FF 4.00 PTP-201 5.00 ECCP-3 15.00 ECCP-35 6.00 ECCP-33 7.00 ECCP-31 7.00 CPTP-301 5.00 PTP-102 5.00 CP-3F 4.00 ECCP-35 5.00 ECCP-32 7.00 CPTP-302 5.00 PTP-201 5.00 PTP-201 6.00 CPTP-301 4.00 ECCP-33 7.00 CPTP-301 6.00 CPTP-302 4.00 ECCP-35 6.00 CPTP-303 4.00 CBC-33 5.00 CPC-53 4.00__________________________________________________________________________Examples 301 302 303 304 305__________________________________________________________________________S .fwdarw. N �.degree.C.! <-30 -- <-20 <-40 <-30Clearing point �.degree.C.! +77 83.0 +85 +79 +81Viscosity �mm.sup.2 s.sup.-1 ! 20.degree. C. 21 -- 23 19 20.DELTA.n (20.degree. C., 589 nm) +0.1467 +0.1421 +0.1303 +0.1576 +0.1449V.sub.(10,0,20) 1.84 1.9 1.94 2.16(2nd) 1.86V.sub.(50,0,20) 2.10 2.2 2.24 2.46 2.14V.sub.(90,0,20) 2.50 2.7 2.72 2.92 2.55Composition �%!: PCH-2 8.00 PCH-3 18.00 PCH-2 12.00 PCH-2 5.00 PCH-2 10.00 PCH-3 18.00 PCH-4 10.00 PCH-3 20.00 PCH-3 15.00 PCH-3 18.00 K6 6.00 PCH-5 8.00 K6 12.00 PCH-4 10.00 PCH-4 14.00 K9 5.00 K6 8.00 HP-3N.F 2.00 PCH-5 10.00 PCH-5 15.00 G9 9.00 K12 6.00 ECCP-3 11.00 PTP-502FF 10.00 PTP-102 5.00 ME2N 3.00 D-302 7.00 ECCP-31 8.00 CPTP-302FF 10.00 PTP-502FF 5.00 ME2N.F 2.00 D-402 6.00 ECCP-32 8.00 PTP-35 14.00 ECCP-3F 4.00 ME3N.F 3.00 D-501 6.00 ECCP-33 8.00 ECCP-31 6.00 ECCP-5F 4.00 PCH-302 6.00 ECCP-31 7.00 ECCP35 7.00 ECCP-33 6.00 ECCP-31 5.00 PTP-35 3.00 ECCP-33 7.00 ECCP-35 6.00 ECCP-32 5.00 PTP-102 4.00 ECCP-35 6.00 ECCP-3F 8.00 ECCP-33 5.00 ECCP-31 6.00 CPTP-301 4.00 CPTP-301 5.00 ECCP-32 6.00 CPTP-302 4.00 CPTP-302 5.00 ECCP-33 5.00 CPTP-303 3.00 ECCP-36 5.00 CBC-33F 5.00 CBC-53F 6.00__________________________________________________________________________Examples 306 307 308 309 310__________________________________________________________________________S .fwdarw. N �.degree.C.! <-40 -- -- <-30 <-20Clearing point �.degree.C.! +74 112.0 +117 +90 +93Viscosity �mm.sup.2 s.sup.-1 ! 20.degree. C. 17 -- 32 42 21.DELTA.n (20.degree. C., 589 nm) +0.1137 +0.1345 +0.1329 +0.1507 0.1079V.sub.(10,0,20) 1.52(1st) 2.0 2.23 1.24 2.21V.sub.(50,0,20) 1.93 2.3 2.55 1.44 2.52V.sub.(90,0,20) 2.55 2.7 3.07 1.95 3.04Composition �%!: PCH-3 20.00 PCH-3 13.00 PCH-3 20.00 ME2N.F 4.00 PCH-3 17.00 PCH-4 8.00 ME2N.F 2.00 PCH-4 10.00 ME3N.F 6.00 PDX-3 8.00 PCH-5 9.00 ME3N.F 3.00 PCH-5 12.00 ME4N.F 10.00 PDX-4 8.00 PCH-5F 8.00 ME6N.F 6.00 PDX-3 8.00 ME5N.F 10.00 PCH-301 8.00 PCH-6F 9.00 ME7N.F 6.00 PDX-5 7.00 HP-3N.F 6.00 D-301 8.00 ECCP-3F 9.00 HP-3N.F 6.00 ECCP-3F 7.00 HP-4N.F 6.00 D-401 7.00 ECCP-5F 8.00 PCH-302 15.00 ECCP-5F 6.00 HP-5N.F 4.00 D-501 7.00 CP-3F 7.00 ECCP-31 5.00 CBC-33 4.00 PCH-302 19.00 CP-33 7.00 CP-5F 6.00 ECCP-32 5.00 CBC-53 4.00 ECCP-33 6.00 ECCP-31 5.00 ECCP-3 8.00 ECCP-33 6.00 CBC-55 4.00 ECCP-35 6.00 ECCP-32 5.00 PTP-102 4.00 ECCP-3F .00 CBC-33F 6.00 BCH-32 10.00 ECCP-33 5.00 PTP-201 4.00 I32 7.00 CBC-53F 6.00 BCH-52F 10.00 ECCP-35 5.00 CBC-53 6.00 CBC-55F 6.00 CPTP-301 3.00 CBC-33 5.00 CBC-33F 5.00 CBC-53 5.00 CBC-53F 5.00 CBC-55F 5.00__________________________________________________________________________Examples 311 312 313 314 315__________________________________________________________________________S .fwdarw. N �.degree.C.! <-30 -- <-40 <-40 <0Clearing point �.degree.C.! +125 92.0 +85 +91 +90Viscosity �mm.sup.2 s.sup.-1 ! 20.degree. C. 33 21 19 23 21.DELTA.n (20.degree. C., 589 nm) +0.1302 +0.1278cal +0.1360 +0.1153 +0.1035V.sub.(10,0,20) 2.11 2.0 1.92 1.94 2.24V.sub.(50,0,20) 2.42 2.4 2.38 2.24 3.54V.sub.(90,0,20) 2.90 2.9 2.61 2.72 3.06Composition �%!: PCH-3 20.00 PCH-2 7.00 PHC-2 6.0 PCH03 22.00 PCH-3 18.00 ME2N 3.00 PCH-3 17.00 PCH-3 18.0 PCH-4 20.00 PCH-4 17.00 ME2N.F 2.00 G9 10.00 ME2N.F 2.0 PCH-5 5.00 PCH-5 17.00 ME3N.F 3.00 ME2N 3.00 ME3N.F 3.0 ME3N.F 3.00 ECCP-31 8.00 HP-3N.F 4.00 ME2N.F 2.00 ME5N.F 6.0 ME6N.F 3.00 ECCP-32 8.00 HP-4N.F 3.00 ME3N.F 3.00 PCH-302 16.0 ECCP-31 6.00 ECCP-33 8.00 PCH-302 6.00 HP-3N.F 3.00 PCH-501 11.0 ECCP-32 6.00 ECCP-35 8.00 D-302FF 6.00 CCH-303 12.00 ECCP-31 6.0 ECCP-33 6.00 ECCP-3F 8.00 ECCP-31 4.00 ECCP-3F 6.00 ECCP-32 6.0 ECCP-35 6.00 ECCP-5F 8.00 ECCP-32 5.00 ECCP-31 6.00 BCH-32 6.0 CP-3F 9.00 ECCP-33 5.00 ECCP-32 7.00 BCH-52 5.0 CP-5F 7.00 CP-33F 5.00 ECCP-33 7.00 CPTP-301 3.0 BCH-32 7.00 CP-55F 5.00 ECCP-35 5.00 CPTP-302 4.0 CH-33 4.00 CPTP-301 4.00 CPTP-303 4.0 CH-35 4.00 CPTP-302 4.00 CCPC-35 4.0 CH-43 4.00 CPTP-303 4.00 CH-45 3.00 CPTP-301 5.00 CPTP-302 4.00 CBC-53F 5.00__________________________________________________________________________Examples 316 317 318 319 320__________________________________________________________________________S .fwdarw. N �.degree.C.! <-20 <-20 <-30 <-20 <0Clearing point �.degree.C.! +88 +121 +84 +90 +82Viscosity �mm.sup.2 s.sup.-1 ! 20.degree. C. 20 31 20 22 22.DELTA.n (20.degree. C., 589 nm) +0.1495 +0.1306 +0.1398 +0.1488 +0.1582V.sub.(10,0,20) 2.02 1.96 2.09 2.18 2.36V.sub.(50,0,20) 2.31 2.23 2.42 2.50 2.67V.sub.(90,0,20) 2.80 2.67 2.94 3.02 3.18Composition �%!: PCH-2 8.00 ME2N.F 3.00 PCH-2 6.00 ME2N.F 2.00 PCH-3 15.00 PCH-3 17.00 ME3N.F 4.00 PCH-3 20.00 ME3N.F 3.00 PCH-5OCF2 13.00 K6 6.00 ME6N.F 7.00 PCH-4 11.0 ME5N.F 8.00 PTP-35 7.00 K9 6.00 ME7N.F 8.00 PCH-5 11.0 ME7N.F 7.00 PTP-45 7.00 G9 6.00 HP-3N.F 6.00 PTP-102 7.00 PCH-301 15.00 PTP-102 7.00 ME2N.F 2.00 PCH-302 12.00 PTP-201 7.00 PCH-302 10.00 PTP-201 8.00 ME3N.F 2.00 PCH-501 8.00 ECCP-31 8.00 ECCP-31 8.00 BCH-6OCF3 10.00 PCH-302 7.00 CCH-303 5.00 ECCP-33 8.00 ECCP-32 8.00 ECCP-3OCF3 9.00 PTP-35 3.00 ECCP-31 4.00 ECCP-35 8.00 ECCP-33 8.00 ECCP-5OCF3 8.00 PTP-102 3.00 ECCP-32 4.00 ECCP-3 7.00 ECCP-35 7.00 ECCP-3F 7.00 CPTP-302FF 4.00 ECCP-33 4.00 ECCP-3F 7.00 PTP-302FF 8.00 ECCP-3 9.00 ECCP-31 7.00 ECCP-3F 4.00 CPTP-302FF 8.00 ECCP-32 7.00 ECCP-5F 5.00 CPTP-502FF 8.00 ECCP-33 7.00 CBC-33 4.00 ECCP-35 6.00 CBC-53 4.00 CBC-33 5.00 CBC-33F 6.00 CBC-53 4.00 CBC-43F 6.00 CBC-55F 6.00__________________________________________________________________________Examples 321 322 323 324 325__________________________________________________________________________S .fwdarw. N �.degree.C.! -- <-40 <-30 -- <-30Clearing point �.degree.C.! +61 +85 +88 81.0 +83Viscosity �mm.sup.2 s.sup.-1 ! 20.degree. C. 48.1 21 23 -- 21.DELTA.n (20.degree. C., 589 nm) +0.2349 +0.1212 +0.1169 +0.1408 +0.1291V.sub.(10,0,20) 1.40(2nd) 2.14 1.98 1.9 1.88V.sub.(50,0,20) 1.65 2.44 2.28 2.3 2.16V.sub.(90,0,20) 2.06 2.92 2.76 2.7 2.60Composition �%!: K6 10.00 PCH-3 18.00 PCH-3 22.00 PCH-2 10.00 PCH-2 10.00 K12 14.00 PCH-4 15.00 PCH-4 20.00 PCH-3 18.00 PCH-3 19.00 K18 45.00 PCH-5 16.00 G9 13.00 PCH-4 14.00 PCH-4 17.00 M3 5.00 PCH-7 10.00 HP-3N.F 4.00 PCH-5 14.00 BCH-52 8.00 M9 8.00 BCH-32 7.00 ECCP-31 6.00 PTP-102 6.00 PTP-35 7.00 T15 8.00 PCH-52 7.00 ECCP-32 6.00 PTP-201 3.00 ME2N.F 2.00 T-3FN 10.00 ECCP-31 7.00 ECCP-33 6.00 ECCP-3F 5.00 ME3N.F 3.00 ECCP-32 7.00 ECCP-35 5.00 ECCP-5F 5.00 ECCP-3 8.00 ECCP-33 6.00 CP-3F 8.00 ECCP-31 6.00 ECCP-31 7.00 ECCP-35 6.00 CP-5F 5.00 ECCP-32 6.00 ECCP-32 7.00 BCH-32 5.00 ECCP-33 5.00 ECCP-33 6.00 CPTP-301 4.00 ECCP-35 6.00 CPTP-302 4.00__________________________________________________________________________Examples 326 327 328 329 330__________________________________________________________________________S .fwdarw. N �.degree.C.! <-40 <-20 -- <-20 <-30Clearing point �.degree.C.! +82 +121 +72 +121 +80Viscosity �mm.sup.2 s.sup.-1 ! 20.degree. C. 21 30 35.9 31 22.DELTA.n (20.degree. C., 589 nm) +0.1463 +0.1185 +0.1147 +0.1119 +0.1462V.sub.(10,0,20) 1.87 2.07 0.81 2.09 1.94V.sub.(50,0,20) 2.16 2.37 1.09 2.37 2.23V.sub.(90,0,20) 2.60 2.86 1.46 2.86 2.71Composition �%!: PCH-3 18.00 PCH-2 9.00 ME2N.F 6.00 PCH-2 9.00 PCH-3 18.00 PCH-4 10.00 PCH-3 19.00 ME3N.F 8.00 PCH-3 19.00 PCH-4 11.00 PCH-5 7.00 ME2N.F 2.00 ME4N.F 17.00 ME2N.F 2.00 K6 8.00 K6 8.00 ME3N.F 3.00 HP-3N.F 8.00 ME3N.F 3.00 K9 7.00 K12 8.00 NE5N.F 8.00 HP-4N.F 10.00 ME5N.F 8.00 K12 6.00 D-302 7.00 CCH-303 7.00 CCH-303 18.00 CCH-303 7.00 D-302 7.00 D-402 6.00 ECCP-31 5.00 CCH-501 13.00 ECCP-31 5.00 D-402 6.00 D-501 6.00 ECCP-32 6.00 CCH-502 9.00 ECCP-32 6.00 D-502FF 6.00 ECCP-31 6.00 ECCP-33 4.00 ECCP-3 11.00 ECCP-33 4.00 PTP-102 4.00 ECCP-33 6.00 CH-33 5.00 CH-33 5.00 ECCP-31 6.00 ECCP-35 6.00 CP-33 5.00 CH-35 4.00 ECCP-33 6.00 CPTP-301 4.00 CP-35 4.00 CH-43 4.00 ECCP-35 6.00 CPTP-302 4.00 CCPC-33 5.00 CCPC-33 5.00 CBC-33 4.00 CPTP-303 4.00 CCPC-34 4.00 CCPC-34 5.00 CBC-53 5.00 CBC-33F 5.00 CBC-33F 5.00 CBC-53F 5.00 CBC-53F 5.00 CBC-55F 4.00 CBC-55F 4.00__________________________________________________________________________Examples 331 332 333 334 335__________________________________________________________________________S .fwdarw. N �.degree.C.! <-40 <-40 -- -- <-40Clearing point �.degree.C.! +78 +85 +106 +90 +87Viscosity �mm.sup.2 s.sup.-1 ! 20.degree. C. 21 22 -- 21.8 22.DELTA.n (20.degree. C., 589 nm) +0.1398 +0.1340 +0.1322 +0.1303 +0.1355V.sub.(10,0,20) 1.80 2.02 2.51 2.02 1.85V.sub.(50,0,20) 2.07 2.35 2.83 2.32 2.14V.sub.(90,0,20) 2.47 2.89 3.40 2.80 2.60Composition �%!: PCH-2 8.00 PCH-2 10.00 PCH-3 18.00 PCH-2 8.00 PCH-2 7.00 PCH-3 15.00 PCH-3 18.00 PCH-301 8.00 PCH-3 18.00 PCH-3 17.00 K6 6.00 PCH-4 14.00 CCP-3OCF3 9.00 PCH-4 18.00 G9 10.00 K9 5.00 PCH-5 13.00 CCP-5OCF3 8.00 PCH-5 14.00 ME2N 5.00 G9 9.00 G9 8.00 ECCP-3OCF3 8.00 PYP-53 5.00 ME2N.F 2.00 ME2N 3.00 ECCP-31 6.00 ECCP-5OCF3 7.00 ECCP-31 5.00 ME3N.F 3.00 ME2N.F 2.00 ECCP-32 6.00 ECCP-3F.F 7.00 ECCP-32 5.00 HP-3N.F 5.00 ME3N.F 3.00 ECCP-33 6.00 ECCP-3F 6.00 ECCP-33 5.00 PCH-302 10.00 PCH-302 8.00 ECCP-35 6.00 ECCP-3CF3 7.00 ECCP-35 6.00 CCH-303 4.00 PTP-102 3.00 CPTP-301 5.00 BCH-3OCF3 7.00 CBC-53 4.00 ECCP-31 6.00 ECCP-31 6.00 CPTP-302 4.00 PTP-102 4.00 CBC-33F 4.00 ECCP-32 7.00 ECCP-32 7.00 CPTP-303 4.00 PTP-201 4.00 CBC-53F 3.00 ECCP-33 7.00 ECCP-33 7.00 CPTP-301 2.00 CPTP-301 2.00 ECCP-35 5.00 ECCP-35 5.00 CPTP-302 2.00 CPTP-303 3.00 CPTP-301 4.00 CBC-33F 5.00 CPTP-303 3.00 CPTP-302 4.00 CBC-53F 5.00 CPTP-303 4.00__________________________________________________________________________Examples 336 337 338 339 340__________________________________________________________________________S .fwdarw. N �.degree.C.! <-40 -- -- <-30 --Clearing point �.degree.C.! +84 121.0 +77 +93 +71Viscosity �mm.sup.2 s.sup.-1 ! 20.degree. C. 20 -- 16 21 23.DELTA.n (20.degree. C., 589 nm) +0.0997 +0.1127 +0.1303 +0.1492 +0.1091V.sub.(10,0,20) 2.03 2.0 2.11 2.12 1.33(1st)V.sub.(50,0,20) 2.32 2.3 2.40 2.42 1.68V.sub.(90,0,20) 2.82 2.7 2.84 2.86 2.14Composition �%!: PCH-2 5.00 PCH-2 9.00 PCH-3 6.00 PCH-2 8.00 ME2N.F 2.00 PCH-3 18.00 PCH-3 18.00 K9 10.00 PCH-3 20.00 ME3N.F 3.00 PCH-4 14.00 ME2N.F 2.00 K15 10.00 PDX-3 8.00 PCH-3 18.00 PCH-5 9.00 ME3N.F 3.00 PCH-5F 11.00 PCH-301 4.00 PCH-4 17.00 ME2N.F 2.00 ME6N.F 9.00 PCH-7F 10.00 D-401 5.00 PCH-5 17.00 ME3N.F 3.00 CCH-303 7.00 ECCP-3F 11.00 D-501 5.00 CCH-303 5.00 CCH-303 7.00 ECCP-31 4.00 ECCP-5F 11.00 PTP-35 5.00 D-302FF 5.00 CCH-502 10.00 ECCP-32 6.00 CP-3F 9.00 PTP-45 4.00 D-502FF 6.00 ECCP-31 5.00 ECCP-33 4.00 CP-5F 9 CPTP-301 6.00 ECCP-3F 8.00 ECCP-32 6.00 CH-33 5.00 PTP-35 7.00 CPTP-302 6.00 ECCP-5F 8.00 ECCP-33 5.00 CH-35 4.00 CPTP-303 6.00 CPTP-303 5.00 ECCP-3 8.00 ECCP-35 6.00 CH-43 5.00 ECCP-31 5.00 CP-33 3.00 CCPC-33 5.00 CCPC-33 6.00 ECCP-32 5.00 CCPC-34 5.00 CCPC-34 5.00 ECCP-33 4.00 CBC-33F 4.00 ECCP-35 5.00 CBC-53F 5.00 ECCP-3 5.00 CBC-55F 4.00__________________________________________________________________________Examples 341 342 343 344 345__________________________________________________________________________S .fwdarw. N �.degree.C.! <-40 -- -- -- --Clearing point �.degree.C.! +82 +70 +84 +96 +90Viscosity �mm.sup.2 s.sup.-1 ! 20.degree. C. 19 26 -- 44 --.DELTA.n (20.degree. C., 589 nm) +0.1416 +0.1116 +0.1090 +0.1512 +0.1234V.sub.(10,0,20) 1.91 1.20(2nd) 1.57 1.30(2nd) 2.36(2nd)V.sub.(50,0,20) 2.16 1.54 1.98 1.48 2.69V.sub.(90,0,20) 2.54 1.98 2.54 1.78 3.19Composition �%!: PCH-2 10.00 ME2N.F 2.00 PCH-2 2.0 ME2N.F 8.0 PCH-2 8.0 PCH-3 22.00 ME3N.F 3.00 PCH-3 18.0 ME3N.F 10.0 PCH-3 17.0 PCH-4 8.00 ME5N.F 5.00 PCH-4 16.00 ME5N.F 11.0 PCH-5 14.0 PCH-5 15.00 ME7N.F 5.00 PCH-5 18.0 HP-3N.F 6.0 PCH-302 7.0 PTP-102 6.00 PCH-2 10.00 CCH-303 5.0 HP-4N.F 6.0 932 8.0 PTP-201 6.00 PCH-3 13.00 D-502FF 5.0 HP-5N.F 4.0 I35 8.0 ECCP-3F 3.00 PCH-4 12.00 CP-302FF 7.0 PCH-302 15.0 I52 8.0 ECCP-31 6.00 CCH-303 9.00 ECCP-31 5.0 ECCP-31 4.0 ECCP-31 6.0 ECCP-32 6.00 D-302FF 5.00 ECCP-3F 8.0 ECCP-33 4.0 ECCP-32 6.0 ECCP-33 5.00 D-502FF 6.00 ECCP-5F 8.0 ECCP-35 4.0 ECCP-3 6.0 ECCP-35 5.00 ECCP-3F 8.00 ECCP-3 8.0 BCH-32 9.0 ECCP-3F 8.0 CPTP-302 4.00 ECCP-5F 8.00 BCH-52 9.0 CBC-33F 4.0 CCPC-33 4.00 ECCP-3 8.00 BCH-52F 10.0 CBC-33F 3.00 CBC-53F 3.00__________________________________________________________________________Examples 346 347 348 349 350__________________________________________________________________________S .fwdarw. N �.degree.C.! <-30 <-30 -- <-30 <-30Clearing point �.degree.C.! +83 +88 +99 +84 +115Viscosity �mm.sup.2 s.sup.-1 ! 20.degree. C. 21 22 20.0 24 30.DELTA.n (20.degree. C., 589 nm) +0.1348 +0.1389 +0.1190 +0.1485 +0.1391V.sub.(10,0,20) 1.85 1.95 2.56(2nd) 1.90 2.00V.sub.(50,0,20) 2.12 2.24 2.93 2.19 2.29V.sub.(90,0,20) 2.52 2.70 3.52 2.66 2.75Composition �%!: PCH-2 10.00 PCH-2 10.00 PCH-2 5.00 PCH-3 10.00 PCH-3 10.00 PCH-3 19.00 PCH-3 20.00 PCH-3 15.00 ME2N.F 2.00 ME2N.F 2.00 PCH-4 13.00 PCH-4 13.00 PCH-5 14.00 ME3N.F 3.00 ME3N.F 3.00 K9 4.00 PCH-5 15.00 I32 8.00 ME5N.F 7.00 ME5N.F 6.00 BCH-52 8.00 ME2N 4.00 I35 8.00 ME7N.F 7.00 ME7N.F 6.00 PTP-35 7.00 ECCP-3F 7.00 I52 8.00 PCH-301 14.00 HP-3N.F 6.00 ME2N.F 2.00 ECCP-31 6.00 D-302FF 5.00 CCH-301 6.00 PCH-302 16.00 ME3N.F 3.00 ECCP-32 6.00 ECCP-31 7.00 PTP-302FF 5.00 ECCP-31 5.00 ECCP-3 8.00 ECCP-33 6.00 ECCP-32 7.00 PTP-502FF 5.00 ECCP-32 5.00 ECCP-31 7.00 CPTP-301 5.00 ECCP-33 7.00 ECCP-31 6.00 ECCP-33 5.00 ECCP-32 7.00 CPTP-302 4.00 ECCP-3F 8.00 ECCP-32 5.00 I32 7.00 ECCP-33 6.0 CPTP-303 4.00 ECCP-3 8.00 ECCP-33 6.00 I52 8.00 ECCP-35 6.00 ECCP-35 5.00 CBC-53 6.00 CP-302FF 5.00 CPC-33F 5.00 CPTP-301 5.00 CBC-53F 5.00 CPTP-302FF 4.00 CBC-55F 5.00 CPTP-502FF 5.00__________________________________________________________________________Examples 351 352 353 354 355__________________________________________________________________________S .fwdarw. N �.degree.C.! <-30 <-30 <-40 <-40 <-40Clearing point �.degree.C.! +86 +89 +94 +73 +77Viscosity �mm.sup.2 s.sup.-1 ! 20.degree. C. 24 23 20 17 18.DELTA.n (20.degree. C., 589 nm) +0.1073 +0.1147 +0.1517 +0.1356 +0.1461V.sub.(10,0,20) 1.48 1.92 2.29 1.82 1.91V.sub.(50,0,20) 1.85 2.21 2.63 2.08 2.19V.sub.(90,0,20) 2.40 2.68 3.17 2.49 2.62Composition �%!: PDX-2 6.00 PCH-3 22.00 PCH-3 20.0 K6 6.0 K6 6.0 PDX-3 9.00 PCH-4 23.00 PCH-4 10.0 K9 10.0 K9 10.0 PCH-3 16.00 PCH-5 9.00 PCH-5 15.0 K15 6.0 K15 10.0 PCH-4 11.00 HP-3N.F 3.00 CCH-303 8.0 PHC-2 10.0 PCH-3 12.0 ME2N.F 2.00 PCH-302 2.00 PTP-102 4.0 PCH-5F 10.0 CCH-303 10.0 ME3N.F 3.00 ECCP-31 5.00 PTP-201 5.0 PCH-7F 6.0 ECCP-3F 11.0 CCH-303 8.00 ECCP-32 5.0 CPTP-301 6.0 ECCP-3F 10.0 ECCP-5F 10.0 ECCP-31 6.00 ECCP-33 5.00 CPTP-302 5.0 ECCP-5F 10.0 CP-3F 9.0 ECCP-32 6.00 ECCP-35 4.00 CPTP-303 65.0 CP-3F 9.0 CP-5F 9.0 ECCP-33 6.00 CP-3F 10.00 ECCP-31 7.0 CP-5F 9.0 PTP-35 4.0 ECCP-3 6.00 CP-5F 7.00 ECCP-33 78.0 PTP35 4.0 PTP-45 4.0 ECCP-3F 7.00 BCH-32 5.00 ECCP-35 8.0 PTP-45 4.0 PTP-201 5.0 CP-3F 7.00 CPTP-303 6.0 CP-5F 7.00__________________________________________________________________________Examples 356 357 358 359 360__________________________________________________________________________S .fwdarw. N �.degree.C.! -- -- -- -- <-30Clearing point �.degree.C.! +87 +87 +88 +85 +81Viscosity �mm.sup.2 s.sup.-1 ! 20.degree. C. 22.2 21.5 -- 19.DELTA.n (20.degree. C., 589 nm) +0.1033 +0.1078 +0.1090 +0.1074 +0.0997V.sub.(10,0,20) 1.47(1st) 1.43(1st) 1.51(1st) 1.37(1st) 1.71(1st)V.sub.(50,0,20) 1.85 1.82 1.91 1.75 2.13V.sub.(90,0,20) 2.36 2.36 2.44 2.30 2.72Composition �%!: PDX-2 6.00 PDX-3 9.00 PCH-3 20.00 PDX-2 5.00 PCH-3 14.60 PDX-3 11.00 PDX-4 8.00 PCH-4 11.00 PCH-3 20.00 PCH-4 13.80 PDX-4 10.00 PDX-5 6.00 PCH-5 6.00 PCH-4 9.00 PCH-5 15.60 PCH-3 12.00 PCH-3 20.00 ME2N.F 2.00 ME2N.F 2.00 PCH-302 9.60 PCH-4 8.00 PCH-4 9.00 ME3N.F 3.00 ME3N.F 3.00 C-33 5.60 CCH-303 8.00 CCH-303 4.00 ME5N.F 5.00 NE5N.F 6.00 C-36 5.60 ECCP-31 6.00 ECCP-31 5.0 CCH-303 10.00 CCH-303 1.00 CP-3F 6.40 ECCP-32 6.00 ECCP-32 4.00 ECCP-31 6.0 ECCP-31 6.00 CP-5F 6.40 ECCP-33 6.00 ECCP-33 5.00 ECCP-32 5.00 ECCP-32 5.00 ECCP-3F 5.60 ECCP-3 6.00 ECCP-35 4.00 ECCP-33 5.00 ECCP-33 5.00 ECCP-31 5.60 ECCP-3F 7.00 ECCP-3 5.00 ECCP-3 6.00 ECCP-3 6.00 ECCP-33 5.60 CP-3F 7.00 ECCP-3F 7.00 ECCP-3F 7.00 ECCP-5VF 8.00 CP-31 5.60 CP-5F 7.00 CF-3F 7.00 CP-3F 7.00 CP-3F 7.00 CP-5F 7.00 CP-5F 7.00 CP-5F 7.00__________________________________________________________________________ Examples 361 362 363 364__________________________________________________________________________ S .fwdarw. N �.degree.C.! <-20 <-30 <-40 <-20 Clearing point �.degree.C.! +129 +95 +85 +78 Viscosity �mm.sup.2 s.sup.-1 ! 20.degree. C. 34 21 22 19 .DELTA.n (20.degree. C., 589 nm) +0.1381 +0.1373 +0.1165 0.1031 V.sub.(10,0,20) 2.04 2.35 2.08 2.26 V.sub.(50,0,20) 2.33 2.69 2.36 2.57 V.sub.(90,0,20) 2.84 3.22 2.85 3.15 Composition �%!: PCH-3 18.00 PCH-2 8.00 PCH-3 16.00 PCH-3 17.00 ME2N.F 2.00 PCH-3 17.00 PCH-4 15.00 PDX-3 8.00 ME3N.F 3.00 PCH-5 8.00 PC-5 16.00 PDX-4 7.00 ME5N.F 6.00 G9 8.00 PCH-7 8.00 PCH-301 3.00 ME7N.F 6.00 ME2N.F 2.00 BCH-32 5.00 D-301 10.00 HP-3N.F 6.00 PCH-302 6.00 BCH-52F 5.00 D-401 10.00 PCH-302 6.00 PTP-36 4.00 ECCP-31 6.00 D-501 10.00 CCH-303 5.00 PTP-102 3.00 ECCP-32 6.00 BCH-32 6.00 ECCP-31 4.00 CPTP-301 5.00 ECCP-33 6.00 ECCP-31 8.00 ECCP-32 4.00 ECCP-3F 6.00 ECCP-3F 8.00 ECCP-32 7.00 ECCP-3F 10.00 ECCP-31 7.00 ECCP-5F 7.00 ECCP-33 7.00 CBC-33 4.00 ECCP-32 8.00 ECCP-35 7.00 CBC-53 4.00 ECCP-33 8.00 CBC-55 4.00 CBC-33F 5.00 CBC-33F 6.00 CBC-53F 5.00 CBC-53F 6.00 CBC-55F 6.00__________________________________________________________________________Examples 365 366 367 368 369__________________________________________________________________________S .fwdarw. N �.degree.C.! <20 <-40 <-30 <0 <-30Clearing point �.degree.C.! +112 +89 +76 +94 +96Viscosity �mm.sup.2 s.sup.-1 ! 20.degree. C. 26 23 19 21 20.DELTA.n (20.degree. C., 589 nm) +0.1499 +0.1090 0.1093 +0.1201 +0.1303V.sub.(10,0,20) 2.09 1.60(1st) 2.06 2.31 2.34V.sub.(50,0,20) 2.31 2.07 2.37 2.60 2.66V.sub.(90,0,20) 2.81 2.73 2.93 3.08 3.21Composition �%!: ME2N.F 2.00 PCH-3 18.00 PCH-3 17.00 ME2N.F 2.00 ME2N.F 2.00 ME3N.F 3.00 PCH-4 16.00 PDX-3 8.00 ME3N.F 3.00 ME3N.F 3.00 PYP-5N.F 8.00 PCH-5 18.00 PDX-4 7.00 ME5N.F 7.00 ME5N.F 7.00 PYP-6N.F 8.00 CCH-303 7.00 PCH-301 3.00 ME7N.F 6.00 ME7N.F 6.00 HP-3N.F 5.00 CP-302FF 7.00 D-301 12.00 CCH301 16.00 PHC-301 15.00 PCH-301 10.00 ECCP-31 6.00 D-401 12.00 CCH-303 20.00 CCH-303 18.00 CCH-303 12.00 ECCP-33 6.00 D-501 12.00 ECCP-31 8.00 ECCP-31 8.00 ECCP-31 7.00 ECCP-3F 8.00 BCH-52 3.00 ECCP-32 7.00 ECCP-32 7.00 ECCP-32 7.00 ECCP-5F 8.00 ECCP-31 6.00 ECCP-33 7.00 ECCP-33 7.00 ECCP-33 8.00 ECCP-3 6.00 ECCP-32 5.00 ECCP-35 7.00 ECCP-35 7.00 ECCP-35 8.00 ECCP-33 5.00 CPTP-301 6.00 CPTP-301 4.00 CPTP-301 6.00 ECCP-35 5.00 CPTP-302 5.00 CPTP-302FF 8.00 CPTP-302 5.00 CPTP-301 5.00 CPTP-303 6.00 CPTP-502FF 8.00 CPTP-303 7.00 CBC-33F 4.00__________________________________________________________________________Examples 370 371 372 373 374S .fwdarw. N �.degree. C.! - <-30 - <0 <-30Clearing point �.degree. C.! +77 +84 +75 +98 +84Viscosity �mm.sup.2.sub.8.sup.-1 ! 20.degree.C. 14.7 24 16 22 24.DELTA.n (20.degree. C., 589 nm) +0.1042 +0.1088 +0.1382 +0.1011 +0.1072V.sub.(10, 0, 20) 1.77 1.46(1st) 1.98(9.0) 2.23 1.50(1st)V.sub.(60, 0, 20) 2.20 1.88 2.26 2.49 1.80V.sub.(90, 0, 20) 2.75 2.44 2.70 2.90 2.40Composition �%!: PCH-3 20.00 ME2N.F 2.00 K6 6.0 PCH-2 5.00 ME2N.F 2.00 PCH-5F 10.00 PCH-3 18.00 K9 10.0 PCH-3 18.00 PCH-3 18.00 PCH-7F 10.00 PCH-4 10.00 K16 10.0 PCH-4 10.00 PCH-4 14.00 ECCP-3F 13.00 PCH-5 18.00 PCH-5F 11.0 PDX-3 8.00 PCH-5 18.00 ECCP-5F 13.00 CCH-303 5.0 PCH-7F 10.0 CCH-303 7.00 CCH-303 9.00 CP-3F 11.00 D-502FF 5.00 ECCP-3F 11.0 D-501 6.00 D-502FF 4.00 CP-5F 11.00 CF-302FF 7.00 ECCP-5F 10.0 CP-33 5.00 CP-302FF 7.00 PTP-36 4.00 ECCP-31 5.00 CP-3F 9.0 CP-36 5.00 CP-402FF 4.00 PTP-46 6.00 ECCP-3F 8.00 CP-5F 9.0 ECCP-31 6.00 ECCP-3F 8.00 ECCP-5F 8.00 PTP-35 4.0 ECCP-32 6.00 ECCP-5F 8.00 ECCP-3 8.00 PTP-45 4.0 ECCP-33 6.00 ECCP-3 8.00 CPTP-303 6.0 ECCP-35 6.00 CCPC-33 6.00 CCPC-34 6.00Examples 375 376 377 378 379S .fwdarw. N�.degree. C.! <-40 - - - -Clearing point �.degree. C.! +93 +86 +88 +93 +75Viscosity �mm.sup.2.sub.s.sup.-1 !20.degree. C. 21 19.9 23.8 23 -.DELTA.n (20.degree. C., 589 nm) +0.1475 +0.1279 +0.1275 +0.1243 +0.1009V.sub.(10, 0, 20) 2.12 1.91 - 2.34(2nd) -V.sub.(50, 0, 20) 2.43 2.19 - 2.68 -V.sub.(90, 0, 30) 2.94 2,78 - 3.23 -Composition �%!: PCH-3 15.00 PCH-2 13.00 PCH-2 10.00 PCH-2 8.00 PCH-3 20.00 PDX-3 8.00 PCH-3 7.00 PCH-3 20.00 PCH-3 19.00 PCH-4 8.00 PDX-4 7.00 G9 10.00 PCH-4 10.00 PCH-5 18.00 PCH-5 8.00 PCH-301 4.00 K9 2.00 PYP-3N,F 5.00 I32 5.00 PCH-5F 10.00 D-301 7.00 PYP-3N.F 5.00 PYP-5N.F 5.00 I36 8.00 PCH-6F 10.00 D-401 7.00 PYP-5N.F 5.00 D-302FF 4.00 I52 8.00 ECCP-3F 10.00 D-501 7.00 PCH-301 10.00 D-402FF 4.00 ECCP-31 7.00 ECCP-5F 10.00 PTP-35 5.00 PCH-501 10.00 D-502FF 4.00 ECCP-32 7.00 CP-3F 6.00 PTP-45 4.00 ECCP-31 6.00 ECCP-31 6.00 ECCP-3 7.00 CP-5F 6.00 CPTP-301 6.00 ECCP-32 6.00 ECCP-32 5.00 ECCP-3F 8.00 ECCP-33 6.00 CPTP-302 6.00 ECCP-33 6.00 ECCP-33 6.00 CBC-33F 2.00 CPTP-303 6.00 CPTP-303 6.00 CBC-33 5.00 ECCP-35 5.00 ECCP-31 5.00 CBC-53 5.00 CBC-53 5.00 ECCP-32 5.00 CBC-33F 5.00 CBC-33F 4.00 ECCP-33 4.00 CBC-55F 5.00 CBC-55F 4.00 ECCP-3 5.00 CPTP-302FF 3.00Examples 380 381 382 383 384S .fwdarw. N �.degree. C.! <-40 <-40 - <-30 <-40Clearing point �.degree. C.! +72 +74 +93 +87 +94Viscosity �mm.sup.2.sub.8.sup.-1 ! 20.degree.C. 16 15 21 23 20.DELTA.n (20.degree. C., 589 nm) +0.1160 +0.1082 +0.1228 +0.1359 +0.1510V.sub.(10, 0, 20) 1.95 2.25 2.44(2nd) 1.88 2.26V.sub.(60, 0, 20) 2.21 2.56 2.76 2.17 2.58V.sub.(90, 0, 20) 2.59 3.04 3.28 2.60 3.10Composition �%!: PCH-3 20.00 PCH-3 20.00 PCH-3 6.00 PCH-2 10.00 PCH-3 22.0 PCH-4 7.00 PCH-5F 10.00 PCH-3 16.0 PCH-2 10.0 PCH-3 20.0 PCH-5 8.00 PCH-7F 10.00 PCH-5 13.0 PCH-5 17.0 PCH-5 3.0 PCH-5F 10.00 ECCP-3F 12.00 PCH-301 8.0 ME2N 6.0 CCH-303 6.0 PCH-6F 10.00 ECCP-6F 13.00 I32 8.0 ME2N 5.0 PTP-102 4.0 ECCP-3F 10.00 CP-3F 11.00 I35 9.0 CCH-303 4.0 PTP-201 4.0 ECCP-5F 10.00 CP-5F 10.00 962 9.0 ECCP-3F 5.0 CPTP-301 6.0 CP-3F 6.00 PTP-35 6.00 ECCP-31 7.0 ECCP-5F 5.0 CPTP-302 5.0 CP-6F 6.00 PTP-45 6.00 ECCP-32 7.0 ECCP-31 6.0 CPTP-303 6.0 PTP-35 5.00 PTP-201 3.00 ECCP-3 6.0 ECCP-32 6.0 ECCP-31 7.0 CPTP-301 4.00 ECCP-3F 6.0 ECCF-33 5.0 ECCP-33 7.0 CPTP-303 4.00 CBC-33F 4.0 CPTP-301 4.0 ECCP-35 8.0 CPTP-302 4.0 CPTP-303 4.0Examples 385 386 387 388 389S .fwdarw. N �.degree. C.! - <-40 <0 <-20 <-30Clearing point �.degree. C.! +85 +71 +94 +124 +91Viscosity �mm.sup.2.sub.8.sup.-1 ! 20.degree.C. - 17 43 33 22.DELTA.n (20.degree. C., 589 nm) +0.1157 +0.1145 +0.1532 +0.1274 +0.1512V.sub.(10, 0, 20) 2.28(2nd) 1.86 1.27 1.99 2.02V.sub.(60, 0, 20) 2.60 2.14 1.47 2.25 2.30V.sub.(90, 0, 20) 3.15 2.59 1.80 2.64 2.82Composition �%!: PCH-3 15.0 ME2N.F 2.0 ME2N.F 4.00 PCH-3 10.00 PCH-2 8.0 PCH-4 15.0 ME2N.F 3.0 ME3N.F 6.00 ME2N.F 2.00 PCH-3 16.00 PCH-5 14.0 PCH-3 10.0 ME4N.F 10.00 ME3N.F 3.00 PCH-4 10.00 PCH-302 8.0 PYP-3F 6.0 ME5N.F 10.00 ME5N.F 6.00 PCH-5 12.00 CCH-303 6.0 PYP-6F 9.0 HP-3N.P 6.00 ME7N.F 6.00 BCH-5 8.00 BCH-32 9.0 PCH-5F 9.0 HP-4N.F 6.00 HP-3N.F 6.00 BCH-32 9.00 BCH-53 9.0 PCH-7F 9.0 HP-5N.P 5.00 PCH-302 12.00 BCH-52 8.00 ECCP-31 5.0 ECCP-3F 10.0 PCH-302 20.00 BCH-32 8.00 I32 5.00 ECCP-32 5.0 ECCP-6F 10.0 ECCP-33 5.00 ECCP-31 5.00 ECCP-31 3.00 ECCP-33 5.0 CP-3F 10.0 ECCP-35 5.00 ECCP-32 6.00 ECCP-32 3.00 ECCP-3F 10.0 CF-5F 9.0 BCH-33 10.00 ECCP-33 6.00 ECCP-33 3.00 CPTP-301 5.0 BCH-62 10.00 CH-33 4.0 ECCP-3F 3.00 CPTP-303 5.0 CPTP-301 3.00 CH-35 4.00 ECCP.6F 3.00 CH-43 3.00 PTP-35 3.00 CH-45 4.00 PTP-102 6.00 CBC-33F 5.00 CBC-53F 5.00Examples 390 391 392 393 394S .fwdarw. N �.degree. C.! <20 <-30 - <-20 -Clearing point �.degree. C.! +88 +85 +92 +84 +91Viscosity �mm.sup.2.sub.8.sup.-1 ! 20.degree.C. 22 22 - 21 -.DELTA.n (20.degree. C., 589 nm) 0.1553 +0.1290 +0.1235 +0.1029 +0.1156V.sub.(10, 0, 20) 1.86 1.88 2.38(2nd) 1.86 2.06V.sub.(60, 0, 20) 2.12 2.15 2.70 2.12 2.36V.sub.(90, 0, 20) 2.51 2.62 3.20 2.57 2.85Composition �%!: PCH-3 14.00 PCH-2 10.0 PCH-2 7.0 PCH-3 14.00 PCH-3 22.0 ME2N.F 2.00 PCH-3 20.0 PCH-3 17.0 ME2N.F 2.00 PCH-4 23.0 ME3N.F 3.00 PCH-4 10.0 PCH-5 16.0 ME2N.F 3.00 PCH-5 9.0 ME3N.F 7.00 PYP.3N.F 4.0 PCH-302 5.0 ME3N.F 7.00 ECCP-3 5.0 ME5N.F 7.00 PYP-5N.F 5.0 I32 8.0 ME5N.F 7.00 PCH-53 2.0 PCH-301 8.00 PCH-301 11.0 I35 8.0 PCH-301 8.00 ECCP-31 4.0 PTP-36 7.00 ECCP-31 6.0 I52 8.0 CCH-301 8.0 ECCP-32 5.0 PTP-45 7.00 ECCP-32 6.0 ECCP-31 7.0 CCH-303 9.00 ECCP-33 5.0 ECCP-31 8.00 ECCP-33 6.0 ECCP-32 7.0 ECCP-31 6.00 ECCP-35 2.0 ECCP-32 8.00 ECCP-35 6.0 ECCP-3 5.0 ECCP-32 5.0 CP-3P 10.0 ECCP-33 8.00 CBC-33F 5.0 ECCP.3F 8.0 ECCP-33 6.00 CP-5F 7.0 ECCP-35 5.00 CBC-53F 5.0 CBC-33F 4.0 ECCF-34 6.00 BCH-32 6.0 CPTP-301 5.00 CBC-53F 4.0 CP-33 5.00 CPTP-302 4.00 CPTP-302 3.0 CP-36 5.00 CPTP-303 4.00 CP-43 5.00 CBC-33 3.00Examples 395 396 397 398 399S .fwdarw. N �.degree. C.! - <-40 <0 <-30 <-30Clearing point �.degree. C.! +90 +87 +96 76 +90Viscosity �mm.sup.2.sub.8.sup.-1 ! 20.degree.C. 21.0 16 21 15 21.DELTA.n (20.degree. C., 589 nm) +0.1284 +0.1222 +0.1104 +0.1115 +0.1074V.sub.(10, 0, 20) - 2.12 2.14 2.15 2.21V.sub.(60, 0, 20) - 2.42 2.42 2.41 2.52V.sub.(90, 0, 20) - -2.89 2.89 2.82 3.04Composition �%!: PCH-2 10.00 PCH-3 18.00 PCH-2 8.00 PCH-3 10.00 PCH-2 8.00 PCH-3 20.00 PCH-301 8.00 PCH-3 21.00 PYP-3F 10.00 PCH-3 20.00 PCH-4 10.00 PYP-3F 5.00 ME2N.F 2.00 PYP-6F 9.00 PCH-4 10.00 PYP-3N.F 4.00 PYP-6OCF3 6.00 ME2N.F 4.00 PCH-5F 9.00 PDX-3 8.00 PYP-6N.F 5.00 PYP-70CF3 5.00 CCH-303 5.00 PCH-7F 9.00 CCH-303 7.00 PCH-501 11.00 CCP-3OCF3 9.00 PCH-501 6.00 ECCP-3F 13.00 CCH-502 7.00 ECCP-31 6.00 CCP-5OCF3 8.00 D-401 6.00 ECCP-5F 12.00 CP-33 4.00 ECCP-32 6.00 ECCP-3OCF3 5.00 D-601 6.00 CP-3F 9.00 CP-36 3.00 ECCP-33 6.00 ECCP-5OCF3 7.00 CP-33 8.0 CP-5F 9.00 ECCP-31 5.00 ECCP-36 6.00 ECCP-3F.F 5.00 ECCP-31 6.00 CPTP-301 6.00 ECCP-32 6.00 CBC-33 4.00 ECCP-3F 5.00 ECCP-32 6.00 CPTP-303 5.00 ECCP-33 6.00 CBC-63 4.00 BCH-3OCF3 7.00 ECCF-33 6.00 ECCP-35 6.00 CBC-53F 5.00 CPTP-302FF 5.00 ECCP-36 6.00 CCPC-33 5.00 CPTP-302 3.00 CPTP-502FF 6.00 CBC-33 5.00 CBC-53F 5.00 CBC-63 5.00 CBC-53F 5.00Examples 400 401 402 403 404S .fwdarw. N �.degree. C.! <0 <-30 <-40 - <-30Clearing point �.degree. C.! +87 +77 +81 67.0 +81Viscosity �mm.sup.2.sub.8.sup.-1 ! 20.degree.C. 21 21 21 - 22.DELTA.n (20.degree. C., 589 nm) +0.1513 +0.1464 +0.1471 +0.1688 +0.1463V.sub.(10, 0, 20) 1.96 1.82 1.87 1.4 1.86V.sub.(60, 0, 20) 2.23 2.10 2.16 1.6 2.13V.sub.(90, 0, 20) 2.65 2.54 2.62 1.9 3.55Composition �%!: PCH-2 8.00 PCH-2 7.00 PCH-3 18.00 ME2N.F 2.00 PCH-2 7.00 PCH-3 19.00 PCH-3 12.00 PCH-4 10.00 ME3N.F 3.00 PCH-3 13.00 K6 6.00 K6 7.00 K6 8.00 ME5N.F 8.00 K6 7.00 K9 6.00 K9 7.00 K9 7.00 ME7N.F 10.00 K9 7.00 G9 6.00 K15 4.00 K12 7.00 K6 6.00 K15 3.00 ME2N.F 2.00 G9 9.00 D-302 7.00 K9 8.00 G9 9.00 ME3N.F 3.00 ME2N 3.00 D-402 6.00 K16 14.00 ME2N 3.00 PCH-302 4.00 ME2N.F 3.00 D-501 6.00 BCH-5 7.00 ME2N.F 2.00 PTP-36 3.00 ME3N.F 3.00 PTP-102 4.00 T15 5.00 ME3N.F 3.00 PTP-102 3.00 PCH-302 6.00 ECCP-31 6.00 DR-31 9.00 PCH-302 5.00 CPTP-302FF 4.00 PTP-102 3.00 ECCP-33 6.00 DR-41 9.00 PTP-502FF 4.00 ECCP-31 7.00 ECCP-31 6.00 ECCP-36 6.00 DR-51 9.00 ECCP-31 6.00 ECCP-32 7.00 ECCP-32 7.00 CBC-33 4.00 CBC-33F 5.00 ECCP-32 7.00 ECCP-33 7.00 ECCP-33 7.00 CBC-53 5.00 CBC-53F 5.00 ECCP-33 7.00 ECCP-35 6.00 ECCP-35 5.00 ECCP-35 5.00 CBC-33 5.00 CBC-33F 5.00 CBC-33F 6.00 CBC-53 4.00 CBC-53F 6.00 CBC-53F 6.00Examples 405 406 407 408 409S .fwdarw. N �.degree. C.! <-40 <-20 - <0 <-20Clearing point �.degree. C.! +90 +88 +73 +87 +91Viscosity �mm.sup.2.sub.8.sup.-1 ! 20.degree.C. 22 25 21 22 16.DELTA.n (20.degree. C., 589 nm) +0.1329 +0.0996 +0.1082 +0.1347 +0.1254V.sub.(10, 0, 20) 1.99 1.92 1.44(1st) 1.91 2.12V.sub.(60, 0, 20) 2.28 2.16 1.81 2.19 2.42V.sub.(90, 0, 20) 2.78 2.60 2.32 2.62 2.89Composition �%!: PCH-3 18.00 PCH-3 10.00 ME2N.F 2.00 PCH-2 10.00 PCH-3 18.00 PCH-4 10.00 ME2N.F 2.00 PCH-3 16.00 PCH-3 20.00 PCH-301 8.00 PCH-5 8.00 ME3N.F 3.00 PCH-4 15.00 PCH-4 10.00 PYP-3F 5.00 K6 8.00 ME3N.F 4.00 PCH-5 16.00 K6 10.00 PYP-5OCF3 5.00 K12 6.00 ME7N.F 7.00 PCH-302 10.00 K9 5.00 PYP-7OCF3 5.00 D-302 7.00 D-302FF 6.00 D-302FF 6.00 HP-3N.F 2.00 CCP-3OCF3 9.00 D-402 6.00 D-402FF 6.00 D-502FF 6.00 ECCP-3 11.00 CCP-5OCF3 8.00 D-501 6.00 CCH-301 9.00 BCCP-31 5.00 ECCP-31 8.00 ECCP-3OCF3 8.00 ECCP-31 6.00 CCH-303 9.00 ECCP-3F 8.00 ECCP-32 8.00 ECCP-5OCF3 7.00 ECCP-33 6.00 ECCP-31 6.00 ECCP-5F 8.00 ECCP-33 8.00 ECCP-3F.F 5.00 ECCP-35 6.00 ECCP-32 6.00 ECCP-3 8.00 ECCP-35 8.00 ECCP-3F 5.00 CBC-33 4.00 ECCP-33 5.00 BCH-3OCF3 7.00 CBC-53 5.00 ECCP-35 6.00 CPTP-301 3.00 CBC-55 4.00 CP-33F 5.00 CPTP-302 3.00 CP-36F 4.00 CPTP-303 4.00 CP-302FF 6.00 CCPC-33 3.00Examples 410 411 410 412 413S .fwdarw. N �.degree.C.! <-40 - <-40 <-40 -Clearing point �.degree.C.! +83 +90 +88 +82 +83Viscosity �mm.sup.2 n.sup.-1 ! 20.degree. C. 20 21 21 21 20.1.DELTA.n (20.degree. C., 589 nm) +0.1561 +0.1168 +0.1468 +0.1003 +0.1241V.sub.(10,0,20) 1.94 2.18 1.98 1.88 1.85V.sub.(50,0,20) 2.23 2.49 2.23 2.12 2.12V.sub.(90,0,20) 2.69 2.99 2.70 2.55 2.56Composition �%!: PCH-2 8.00 PCH-3 20.00 PCH-2 9.00 PCH-3 11.00 PCH-2 17.00 PCH-3 17.00 PCH-4 16.00 PCH-3 16.00 ME2N.F 2.00 PCH-3 15.00 K6 6.00 PCH-5 15.00 PCH-4 11.00 ME3N.F 3.00 PYP-3N.F 5.00 K9 6.00 PTP-201 4.00 PCH-5 12.00 ME5N.F 7.00 PYP-5N.F 5.00 G9 6.00 ECCP-31 7.00 BCH-5 8.00 ME7N.F 7.00 PCH-304 10.00 ME2N.F 2.00 ECCP-32 7.00 BCH-32 8.00 PCH-301 10.00 PCH-501 12.00 ME3N.F 2.00 ECCP-33 7.00 BCH-52 8.00 CCH-301 9.00 ECCP-31 6.00 PCH-302 6.00 ECCP-35 7.00 ECCP-3F 6.00 CCH-303 9.00 ECCP-32 6.00 PTP-35 5.00 ECCP-3F 7.00 ECCP-5F 6.00 ECCP-31 6.00 ECCP-33 6.00 PTP-102 5.00 CP-3F 8.00 ECCP-33 6.00 ECCP-32 6.00 CBC-33 5.00 CPTP-302FF 4.00 CPTP-301 2.00 PTP-35 6.00 ECCP-33 5.00 CBC-53 5.00 ECCP-31 8.00 PTP-102 4.00 ECCP-35 5.00 CBC-33F 4.00 ECCP-32 8.00 CP-33F 6.00 CBC-55F 4.00 ECCP-33 7.00 CP-35F 6.00 CBC-33F 5.00 CP-55F 5.00 CBC-53F 5.00 CBC-53F 3.00Examples 414 415 416 417 418S .fwdarw. N �.degree.C.! <-40 <-30 <-40 - <-40Clearing point �.degree.C.! +83 +70 +91 +79 +90Viscosity �mm.sup.2 s.sup.-1 ! 20.degree. C. 19 42 22 16.2 22.DELTA.n (20.degree. C., 589 nm) +0.1258 +0.1153 +0.1150 +0.1523 +0.1150V.sub.(10,0,20) 2.23 0.83 2.06 2.44 2.01V.sub.(50,0,20) 2.54 1.12 2.35 2.77 2.31V.sub.(90,0,20) 3.06 1.50 2.81 3.29 2.79Composition �%!: PCH-3 13.00 ME2N.F 6.00 PCH-3 22.00 PCH-3 10.00 PCH-3 22.00 PDX-3 8.00 ME3N.F 8.00 PCH-4 20.00 PCH-5OCF2 15.00 PCH-4 20.00 PDX-4 7.00 ME4N.F 17.0 PCH-5 7.00 PTP-35 10.00 PCH-5 5.00 PCH-301 10.00 HP-2N.F 10.00 EHP-3F.F 6.00 PTP-45 10.00 EHP-3F.F 11.00 D-301 8.00 HP-2N.F 8.00 BCH-32 8.00 PTP-201 10.00 BCH-32 8.00 D-401 7.00 CCH-303 18.00 BCCP-31 6.00 BCH-5OCF3 10.00 ECCP-31 6.00 D-501 8.00 CCH-501 13.00 ECCP-32 6.00 ECCP-3OCF3 9.00 ECCP-32 6.00 CP-33 5.00 CCH-502 9.00 BCCP-33 5.00 ECCP-5OCF3 9.00 ECCP-33 6.00 CP-35 5.00 ECCP-3 11.00 ECCP-35 5.00 ECCP-3F 8.00 ECCP-35 5.00 PTP-35 3.00 ECCP-3F 10.00 ECCP-3 9.00 ECCP-3F 8.00 PTP-45 3.00 CP-3F 5.00 CP-3F 3.00 CPTP-301 5.00 CPTP-302 5.00 ECCP-31 5.00 ECCP-32 4.00 ECCP-33 4.00Examples 419 420 421 422 423S .fwdarw. N �.degree.C.! <-40 <-20 <-20 <0 -Clearing point �.degree.C.! +82 +87 +96 +86 +120Viscosity �mm.sup.2 s.sup.-1 ! 20.degree. C. 19 20 20 18 32.DELTA.n (20.degree. C., 589 nm) +0.1098 +0.1496 +0.1572 +0.1564 +0.1330V.sub.(10,0,20) 1.68(1st) 2.03 2.23 2.33 2.34V.sub.(50,0,20) 2.13 2.32 2.64 2.66 2.68V.sub.(90,0,20) 2.78 2.78 3.05 3.18 3.27Composition �%!: PCH-2 6.00 PCH-2 8.00 ME2N.F 2.00 ME2N.F 2.00 PCH-3 20.00 PCH-3 20.00 PCH-3 17.00 ME3N.F 3.00 ME3N.F 3.00 PCH-4 13.00 PCH-4 11.00 K6 6.00 ME5N.F 8.00 ME5N.F 7.00 PCH-5 16.00 PCH-5 11.00 K9 6.00 ME7N.F 7.00 PTP-35 8.00 PCH-7 8.00 PCH-301 10.00 G9 7.00 PCH-301 15.00 PTP-45 8.00 ECCP-3 7.00 ECCP-31 7.00 ME2N.F 2.00 PCH-302 10.00 PCH-301 15.00 ECCP-3F 9.00 ECCP-32 7.00 ME3N.F 2.00 ECCP-31 8.00 ECCP-31 7.00 CBC-33 5.00 ECCP-33 7.00 PCH-302 6.00 ECCP-32 8.00 ECCP-32 7.00 CBC-55 4.00 ECCP-35 7.00 PTP-35 3.00 ECCP-33 8.00 ECCP-33 8.00 CBC-33F 6.00 ECCP-3 7.00 PTP-102 3.00 ECCP-35 7.00 ECCP-35 8.0 CBC-53F 6.00 ECCP-3F 7.00 CPTP-302FF 4.00 PTP-102 8.00 ECCP-3 15.00 CBC-55F 6.00 ECCP-31 7.00 CPTP-301 8.00 PTP-102 6.00 ECCP-32 7.00 CPTP-302 8.00 PTP-201 6.00 ECCP-33 7.00 ECCP-35 6.00 CBC-33 5.00 CBC-53 4.00Examples 424 425 426 427 428S .fwdarw. N �.degree.C.! <0 <-20 <-40 <-40 <-30Clearing point �.degree.C.! 78 82 +92 +85 +87Viscosity �mm.sup.2 s.sup.-1 ! 20.degree. C. 19 21 22 20 23.DELTA.n (20.degree. C., 589 nm) +0.1616 +0.1609 +0.1046 +0.1272 +0.1090V.sub.(10,0,20) 2.15 2.06 1.63(1st) 2.03 1.59(1st)V.sub.(50,0,20) 2.44 2.33 2.02 2.29 1.98V.sub.(90,0,20) 2.87 2.71 2.55 2.75 2.57Composition �%!: K6 8.00 PYP-3N.F 4.00 PCH-3 20.00 PCH-3 15.00 ME2N.F 2.00 K9 10.00 PYP-5N.F 4.00 PCH-4 18.00 PCH-4 15.00 PCH-3 18.00 K12 6.00 PYP-6N.F 4.00 ME2N.F 2.00 PCH-6 14.00 PCH-4 16.00 K15 10.00 PYP-7N.F 5.00 ME3N.F 3.00 K15 8.00 PCH-5 18.00 PCH-301 8.00 PYP-32 5.00 CCH-303 12.00 CCH-303 6.00 CCH-303 7.00 ECCP-31 8.00 PYP-33 5.00 ECCP-31 5.00 BCH-32 9.00 CP-302FF 7.00 ECCP-32 8.00 PTP-34 4.00 ECCP-32 5.00 BCH-52 9.00 ECCP-31 4.00 ECCP-33 8.00 PTP-35 4.00 ECCP-33 5.00 ECCP-31 5.00 ECCP-33 4.00 ECCP-35 8.00 PTP-45 4.00 ECCP-3 7.00 ECCP-32 5.00 ECCP-3F 8.00 ECCP-3 10.00 PCH-301 10.00 ECCP-3F 7.00 ECCP-33 5.00 ECCP-5F 8.00 PYP-32 5.00 ECCP-31 7.00 CP-3F 8.00 ECCP-3F 10.00 ECCP-3 8.00 PYP-33 5.00 ECCP-32 8.00 CP-5F 8.00 PTP-36 6.00 ECCP-33 8.00 ECCP-35 8.00 ECCP-3 10.00 PTP-201 5.00 CPTP-301 5.00__________________________________________________________________________

Claims

1. A supertwist liquid crystal display having

two plane-parallel carrier plates which, with an edging, form a cell,

a nematic liquid crystal mixture of positive dielectric anisotropy in the cell,

electrode layers with superimposed orientation layers on the insides of the carrier plates,

an angle of incidence between the longitudinal axis of the molecules on the surface of the carrier plates and the carrier plates of about 1 degree to 30 degrees and

a twisting angle of the liquid crystal mixture in the cell from orientation layer to orientation layer, according to the amount, of between 160.degree. and 360.degree., the nematic liquid crystal mixture comprising

a) at least one component of group A, compounds of the formulae AI to AVI: ##STR41## wherein R.sup.1 and R.sup.2 each independently of one another are each R and

R is alkyl having 1-12 C atoms, wherein one or two non-adjacent CH.sub.2 groups can also be replaced by --O--, --CH.dbd.CH--, --CO--, --O--CO-- or --CO--O--,

b) at least one component of group B3, compounds of the formulae BVIII or BIX: ##STR42## wherein R.sup.1 and R.sup.2 each independently of one another have the meaning given for R and ##STR43## is ##STR44## c) 10-80% by weight of a liquid crystal component C, which is one or more compounds having a dielectric anisotropy of more than +1.5,

d) 0-20% by weight of a liquid crystal component D, which is one or more compounds having a dielectric anisotropy of less than -1.5 and

e) an optically active component E, in an amount such that the ratio between the layer thickness (separation of the plane-parallel carrier plates) and the natural pitch of the chiral nematic liquid crystal mixture is about 0.2 to 1.3,

the nematic liquid crystal mixture having a nematic phase range of at least 60.degree. C., a viscosity of not more than 30 mPa.s and a dielectric anisotropy of at least +5, the dielectric anisotropies of the compounds and the parameters relating to the nematic liquid crystal mixture being based on a temperature of 20.degree. C.,

with the proviso that no compounds of formula BIII ##STR45## wherein Z.sup.2 is --CH.sub.2 --CH.sub.2 -- or a single bond, are present in the mixture.

2. A display according to claim 1, wherein component C contains compounds chosen from group C consisting of the compounds of the formulae CI to CIII: ##STR46## wherein R has the meaning given in claim 1,

Q is the formula ##STR47## Z.sup.1 is ##STR48## a single bond, --CH.sub.2 CH.sub.2 --, --CO--O-- or --O--CO-- and ##STR49## is ##STR50##

3. A display according to claim 1, wherein the nematic liquid crystal mixture is composed of 30-60% by weight of component C, 20-70% by weight of compounds from groups A and B3, 0-10% by weight of component D and an amount of component E which adds up to 100% by weight.

4. A display according to claim 1, wherein component D contains one or more compounds with a 1-cyano-trans-1,4-cyclohexylene group or a 2,3-difluoro-1,4-phenylene group.

5. A display according to claim 1, wherein the nematic liquid crystal mixture contains at least two compounds of the formula AIII or AV.

6. A display according to claim 5, wherein the nematic liquid crystal mixture contains compounds of the formula AIII and AV.

7. A display according to claim 1, wherein component C contains one or more compounds with a 4-fluorophenyl group or a 3,4-difluorophenyl group.

8. A display according to claim 7, wherein the liquid crystal mixture further contains at least one compound selected from the group consisting of ##STR51## wherein the alkyl is a straight-chain alkyl group having 2-7 C atoms and X is H or F.

9. A display according to claim 1, wherein the liquid crystal mixture contains one or more compounds wherein R is a trans-alkenyl group or a trans-alkenyloxy group.

10. A nematic liquid crystal mixture of the composition defined in claim 1.

11. A liquid crystal display according to claim 1, wherein component A has the formulae ##STR52##

12. A liquid crystal display according to claim 1, wherein component A has the formula ##STR53##

13. A supertwist liquid crystal display having two plane-parallel carrier plates which, with an edging, form a cell,

a nematic liquid crystal mixture of positive dielectric anisotropy in the cell,

electrode layers with superimposed orientation layers on the insides of the carrier plates,

an angle of incidence between the longitudinal axis of the molecules on the surface of the carrier plates and the carrier plates of about 1 degree to 30 degrees and

a twisting angle of the liquid crystal mixture in the cell from orientation layer to orientation layer, according to the amount, of between 160.degree. and 360.degree., wherein the nematic liquid crystal mixture comprises

a) at least one component of the formula AV: ##STR54## wherein R.sup.1 and R.sup.2 each independently of one another are each R and R is alkyl having 1-12 C atoms, wherein one or two non-adjacent CH.sub.2 groups can also be replaced by --O--, --CH.dbd.CH--, --CO--, --O--CO-- or --CO--O--,

b) at least one component of group B1 compounds of the formulae BIII or BIV: ##STR55## wherein R.sup.1 and R.sup.2 each independently of one another have the meaning given for R, Z.sup.2 is --CH.sub.2 CH.sub.2 --, --CO--O--, --O--CO-- or a single bond and ##STR56## is ##STR57## c) 10-80% by weight of a liquid crystal component C, which is one or more compounds having a dielectric anisotropy of more than +1.5,

d) 0-20% by weight of a liquid crystal component D, which is one or more compounds having a dielectric anisotropy of less than -1.5 and

e) an optically active component E, in an amount such that the ratio between the layer thickness (separation of the plane-parallel carrier plates) and the natural pitch of the chiral nematic liquid crystal mixture is about 0.2 to 1.3, and in that the nematic liquid crystal mixture has a nematic phase range of at least 60.degree. C., a viscosity of not more than 30 mPa's and a dielectric anisotropy of at least +5, the dielectric anisotropies of the compounds and the parameters relating to the nematic liquid crystal mixture being based on a temperature of 20.degree. C.,

with the proviso that no compounds of formula BIII ##STR58## wherein Z.sup.2 is --CH.sub.2 --CH.sub.2 -- or a single bond, are present in the mixture.

14. A supertwist liquid crystal display having

two plane-parallel carrier plates which, with an edging, form a cell,

a nematic liquid crystal mixture of positive dielectric anisotropy in the cell,

electrode layers with superimposed orientation layers on the insides of the carrier plates,

an angle of incidence between the longitudinal axis of the molecules on the surface of the carrier plates and the carrier plates of about 1 degree to 30 degrees and

a twisting angle of the liquid crystal mixture in the cell from orientation layer to orientation layer, according to the amount, of between 160.degree. and 360.degree., the nematic liquid crystal mixture comprising

a) at least one component of group A, compounds of the formulae:

AIII1: 1-�trans-4-(trans-4-propylcyclohexyl)-cyclo-hexyl!-(2-p-methylphenyl)-ethane

AIII2: 1-�trans-4-(trans-4-propylcyclohexyl)-cyclo-hexyl!-(2-p-ethylphenyl)-ethan

AIII3: 1-�trans-4-(trans-4-propylcyclohexyl)-cyclo-hexyl!-(2-p-propylphenyl)-ethane

AIII4: 1-�trans-4-(trans-4-propylcyclohexyl)-cyclo-hexyl!-(2-p-butylphenyl)-ethane

AIII5: 1-�trans-4-(trans-4-propylcyclohexyl)-cyclo-hexyl!-(2-p-pentylphenyl)-ethane

b) at least one component of group B3, compounds of the formulae;

BVIII1: 2-p-ethylphenyl-5-propyl-pyrimidine

BVIII2: 2-p-propylphenyl-5-propyl-pyrimidine

BVIII3: 2-p-propylphenyl-5-pentyl-pyrimidine

BVIII4: 2-p-ethylphenyl-5-heptyl-pyrimidine

BVIII5: 2-p-pentyloxyphenyl-5-hexyl-pyrimidine

BVIII6: 2-p-heptyloxyphenyl-5-hexyl-pyrimidine

BVIII7: 2-p-nonyloxyphenyl-5-hexyl-pyrimidine

BVIII8: 2-p-heptyloxyphenyl-5-heptyl-pyrimidine

BVIII9: 2-p-nonyloxyphenyl-5-heptyl-pyrimidine

BVIII10: 2-p-hexyloxyphenyl-5-nonyl-pyrimidine

BVIII11: 2-p-nonyloxyphenyl-5-nonyl-pyrimidine

c) 10-80% by weight of a liquid crystal component C, which is one or more compounds having a dielectric anisotropy of more than +1.5,

d) 0-20% by weight of a liquid crystal component D, which is one or more compounds having a dielectric anisotropy of less than -1.5 and

e) an optically active component E, in an amount such that the ratio between the layer thickness (separation of the plane-parallel carrier plates) and the natural pitch of the chiral nematic liquid crystal mixture is about 0.2 to 1.3,

the nematic liquid crystal mixture having a nematic phase range of at least 60.degree. C., a viscosity of not more than 30 mPa.s and a dielectric anisotropy of at least +5, the dielectric anisotropies of the compounds and the parameters relating to the nematic liquid crystal mixture being based on a temperature of 20.degree. C.,

with the proviso that no compounds of formula BIII ##STR59## wherein Z.sup.2 is --CH.sub.2 --CH.sub.2 -- or a single bond, are present in the mixture.