Supertwist liquid-crystal displays and liquid-crystal mixtures therefor

Description

The invention relates to supertwist liquid-crystal displays (SLCDs or supertwisted nematic (STN) displays) having very short response times and good steepnesses and angle dependencies, and to the novel nematic liquid-crystal mixtures used therein.

SLCDs are known, for example from EP 0 131 216 B1; DE 34 23 993 A1; EP 0 098 070 A2; M. Schadt and F. Leenhouts, 17th Freiburg Congress on Liquid Crystals (8.-10.04.87); K. Kawasaki et al., SID 87 Digest 391 (20.6); M. Schadt and F. Leenhouts, SID 87 Digest 372 (20.1); K. Katoh et al., Japanese Journal of Applied Physics, Vol. 26, No. 11, L 1784-L 1786 (1987); F. Leenhouts et al., Appl. Phys. Lett. 50 (21), 1468 (1987); H. A. van Sprang and H. G. Koopman, J. Appl. Phys. 62 (5), 1734 (1987); T. J. Scheffer and J. Nehring, Appl. Phys. Lett. 45 (10), 1021 (1984), M. Schadt and F. Leenhouts, Appl. Phys. Lett. 50 (5), 236 (1987), and E. P. Raynes, Mol. Cryst. Liq. Cryst. Letters Vol. 4 (1), pp. 1-8 (1986). The term SLCD here covers any relatively highly twisted display element with a value for the twist angle of between 160° and 360°, such as, for example, the display elements of Waters et al. (C. M. Waters et al., Proc. Soc. Inf. Disp. (New York) (1985) (3rd Intern. Display Conference, Kobe, Japan), STN-LCDs (DE-A 35 03 259), SBE-LCDs (T. J. Scheffer and J. Nehring, Appi. Phys. Lett. 45 (1984) 1021), OMI-LCDs (M. Schadt and F. Leenhouts, Appl. Phys. Lett. 50 (1987), 236, DST-LCDs (EP-A 0 246 842) or BW-STN-LCDs (K. Kawasaki et al., SID 87 Digest 391 (20.6)).

SLCDs of this type are distinguished, in comparison to standard TN displays, by significantly better steepnesses of the electro-optical characteristic line and consequently better contrast values, and by significantly lower angle dependence of the contrast. Of particular interest are SLCDs having very short response times, in particular also at relatively low temperatures. In order to achieve short response times, the rotational viscosities of the liquid-crystal mixtures have hitherto been optimized using usually monotropic additives having relatively high vapour pressure. However, the response times achieved were not adequate for all applications.

In order to achieve a steep electro-optical characteristic line in SLCDs, the liquid-crystal mixtures should have relatively large values for K

3

/K

1

and relatively small values for Δε/ε

1

.

In addition to optimization of the contrast and the response times, further important requirements are made of mixtures of this type:

1. A broad d/p window

2. High long-term chemical stability

3. High electrical resistance

4. Low frequency and temperature dependence of the threshold voltage.

The parameter combinations achieved are still far from adequate, in particular for high-multiplex, but also for low- and medium-multiplex STNs (1/400). This is in some cases attributable to the fact that the various requirements are affected in opposite manners by material parameters.

There thus continues to be a great demand for SLCDs, in particular for high-resolution displays (XGAs), having very short response times and at the same time a large operating temperature range, high characteristic line steepness, good angle dependence of the contrast and low threshold voltage which meet the abovementioned requirements.

The invention has an object of providing SLCDs which do not have the abovementioned disadvantages, or only do so to a lesser extent, and at the same time have very good response times, in particular at low temperatures, and very good steepnesses.

Upon further study of the specification and appended claims, further objects and advantages of this invention will become apparent to those skilled in the art.

Particularly, it has been found that advantages are achieved if nematic liquid-crystal mixtures are used which comprise compounds of the formula IA

in combination with compounds of the formula IB

in which

R

a

and R

c

,

independently of one another, are H or an alkyl group having

1 to 7 carbon atoms,

R

b

is an alkyl or alkoxy group having 1 to 10 carbon atoms or an

alkenyl or alkenyloxy group having 2 to 10 carbon atoms,

R

d

is F, OCF

3

, OCHF

2

, alkyl or alkoxy having 1 to 7 carbon

atoms or alkenyl having 2 to 7 carbon atoms,

Y

1

and Y

2

,

independently of one another, are H or F,

q

is 0 or 1

and

n and p,

independently of one another, are 0, 1 or 2.

The use of the compounds of the formulae IA and IB in the mixtures for SLCDs according to the invention produces

high steepness of the electro-optical characteristic line

low temperature dependence of the threshold voltage and

very short response times, in particular at low temperatures.

The compounds of the formula IA are covered by the very broad generic claim in WO 95/30723 as components of liquid-crystalline media. However, the specific combination of the compounds of the formula IA with the compounds IB which produces, in particular, high steepness of the electro-optical characteristic line and low temperature dependence of the threshold voltage, is not described therein.

The compounds of the formulae IA and IB significantly shorten, in particular, the response times of SLCD mixtures while simultaneously increasing the steepness and retaining the low temperature dependence of the threshold voltage.

Furthermore, the mixtures according to the invention are distinguished by the following advantages:

they have low viscosity,

they have low temperature dependence of the threshold voltage and the operating voltage, and

they effect long storage times of the display at low temperatures.

The invention thus also includes to a liquid-crystal display having

two outer plates which, together with a frame, form a cell,

a nematic liquid-crystal mixture of positive dielectric anisotropy which is present in the cell,

electrode layers with alignment layers on the insides of the outer plates,

a pre-tilt angle between the longitudinal axis of the molecules at the surface of the outer plates and the outer plates of from about 0 degrees to 30 degrees, and

a twist angle of the liquid-crystal mixture in the cell from alignment layer to alignment layer with a value of between 22.5° and 600°,

a nematic liquid-crystal mixture consisting of

a) 15-90% by weight of a liquid-crystalline component A consisting of one or more compounds having a dielectric anisotropy of greater than +1.5;

b) 0-60% by weight of a liquid-crystalline component B consisting of one or more compounds having a dielectric anisotropy of between −1.5 and +1.5;

c) 0-20% by weight of a liquid-crystalline component D consisting of one or more compounds having a dielectric anisotropy of below −1.5, and

d) if desired, an optically active component C in such an amount that the ratio between the layer thickness (separation of the outer plates) and the natural pitch of the chiral nematic liquid-crystal mixture is from about 0.2 to 1.3,

characterized in that the liquid-crystal mixture additionally comprises at least one compound of the formula IA

in which

R

a

is H or an alkyl group having 1 to 7 carbon atoms,

R

b

is an alkyl or alkoxy group having 1 to 10 carbon atoms or an

alkenyl or alkenyloxy group having 2 to 10 carbon atoms,

and

n

is 0,1 or 2

and simultaneously comprises at least one compound of the formula IB

in which

R

c

is H or an alkyl group having 1 to 7 carbon atoms,

R

d

is F, OCF

3

, OCHF

2

, an alkyl or alkoxy group having 1 to 7

carbon atoms or an alkenyl group having 2 to 7 carbon atoms,

Y

1

and Y

2

,

independently of one another, are H or F,

p

is 0, 1 or 2,

q

is 0 or 1.

The invention also relates to corresponding liquid-crystal mixtures for use in SLCDs, in particular in medium- and low-multiplexed SLCDs.

The compounds of the formulae IA and IB are prepared by methods known per se, as described in the literature (Houben-Weyl, Methoden der organischen Chemie [Methods of Organic Chemistry], Georg-Thieme-Verlag, Stuttgart), to be precise under reaction conditions which are known and suitable for said reactions.

Use can be made here of variants which are known per se, but are not mentioned here in greater detail.

The formula IB includes the following preferred compounds

in which R

c

, Y

1

and p are as defined above, and R

c

is an alkyl or alkoxy group having 1 to 7 carbon atoms. R

c

is particularly preferably methyl, ethyl, n-propyl, n-pentyl, methoxy, ethoxy, n-propoxy or n-butoxy.

Further preferred compounds of the formula IB are those of the sub-formulae IB6 and IB7

in which R

c

and R

e

are as defined above, and R

f

is alkenyl having 2 to 7 carbon atoms, in particular vinyl, 1E-propenyl, 1E-butenyl, 3E-butenyl, 1E-pentenyl or 3E-pentenyl.

Mixtures which, in addition to the compounds of the formula IA, comprise the compounds IB2, IB5, IB6 and/or IB7 are preferred.

Preferred compounds of the formulae IA and IB are those in which n and p, independently of one another, are 0 or 2.

R

a

and R

c

are preferably, independently of one another, H, a methyl group, an ethyl group or an n-propyl group, in particular H or a methyl group.

R

b

is preferably a straight-chain alkoxy group having 1 to 7 carbon atoms. In particular, R

b

is a methoxy, ethoxy or n-propoxy group. R

b

is very particularly preferably a methoxy group.

R

d

is preferably F, OCF

3

, OCHF

2

, a methyl, ethyl or n-propoxy group or a methoxy, ethoxy or n-propoxy group. R

d

is particularly preferably F, OCF

3

or OCHF

2

.

Preference is given to compounds of the formulae IB in which Y

1

is F and Y

2

is simultaneously H. Preference is furthermore given to compounds of the formula IB in which Y

1

and Y

2

are simultaneously H.

Of the compounds of the formulae IA and IB and the sub-formulae, preference is given to those in which at least one of the radicals present therein has one of the preferred meanings indicated.

The compounds of the formula IB1, IB2 and IB7 are particularly preferred.

Component A preferably comprises compounds of the formulae II and/or III

in which

R is an alkyl, alkoxy or alkenyl group having 1 to 12 carbon atoms, in which, in addition, one or two non-adjacent CH

2

groups may be replaced by —O—, —CH═CH—, —CO—, —OCO— or —COO— in such a way that O atoms are not linked directly to one another,

are each, independently of one another

L

1

to L

6

are each, independently of one another, H or F,

Z

1

is —COO—, —CH

2

CH

2

— or a single bond,

Z

2

is —CH

2

CH

2

—, —COO—, —C≡C— or a single bond,

Q

is —CF

2

—, —CHF—, —OCF

2

—, —OCHF— or a single bond,

Y

is F or Cl

a

is 1 or 2, and

b

is 0 or 1,

where compounds of the formula IB are excluded from the scope of the formula III.

Preferred compounds of the formula II conform to the sub-formulae IIa to IIh:

in which R, L

1

, L

2

and L

3

are as defmed above.

Particular preference is given to mixtures which comprise one or more compounds of the following sub-formulae

in which R is as defined above.

Preference is furthermore given to mixtures which comprise one or more compounds of the formula IIh in which L

2

is H and L

1

is H or F, in particular F.

In a particularly preferred embodiment, component A additionally comprises compounds of the formulae AI to AIV:

and Q

1

are each, independently of one another,

Z

3

is

—CH

2

CH

2

—, —CO—O—, —O—CO— or a single bond.

The mixtures according to the invention preferably comprise one or more polar compounds having a high clearing point selected from the group consisting of the compounds AIV1 to AIV4:

In the compounds AIV1 to AIV4, the 1,4-phenylene rings can also be laterally substituted by one or two fluorine atoms. Preferred compounds of this type are the compounds of the formulae AIV1-1, AIV1-2 and AIV1-3:

In the mixtures according to the invention which comprise compounds of the formulae AIV1 to AIV4, the proportion of these compounds is preferably from about 2 to 25%.

Preferred compounds of the formula III conform to the sub-formulae IIIa-IIIv:

in which R is as defined above, L

3

and L

4

, independently of one another, are H or F, and R

3

is alkyl or alkoxy having 1 to 7 carbon atoms.

Of the compounds of the formulae IIIa to IIIv, particular preference is given to those in which L

4

is F, furthermore those in which L

3

and L

4

are F.

In addition to one or more compounds of the formulae IA and IB, preferred mixtures comprise one, two, three or more compounds of the formulae IIa, IIb, IIc, IIf, IIIb, IIId, IIIf, IIIh, IIIi, IIIm, IIIs, IIIt or IIIu, preferably one or more compounds of the formula IIIb, IIId, IIIh, IIIt or IIIu, and from one to four compounds of the formulae IA and IB and from one to three compounds of the formulae IIa, IIb and/or IIc.

In the above- and below-mentioned preferred compounds of the sub-formulae to the formulae II and III, R, R

1

and R

2

, unless stated otherwise, are preferably straight-chain alkyl, alkenyl or alkoxy, in particular alkyl, having 1 to 12 carbon atoms, in particular having 1 to 7 carbon atoms.

Preference is furthermore given to mixtures which comprise one or more compounds of the sub-formula IIIb1

in which R

3

is as defined above.

In the compounds of the formula IIIb1, R

3

is particularly preferably n-propyl, n-pentyl or n-heptyl.

The individual compounds, for example of the formulae II and III or their sub-formulae, or alternatively other compounds which can be used in the SLCDs according to the invention, are either known or can be prepared analogously to known compounds.

Preferred liquid-crystal mixtures comprise none or small amounts of one or more compounds of Component B, preferably from 2 to 20%. The compounds of group B are distinguished, in particular, by their low rotational viscosity values γ

1

.

Further preferred liquid-crystal mixtures comprise a plurality of compounds of Component A, preferably from 20 to 65%, particularly preferably from 30 to 50%.

Component B preferably comprises one or more compounds selected from the group consisting of the compounds of the formulae IV1 to IV9:

in which R

1

and R

2

are as defined for R, and R

3

and R

4

, independently of one another, are an alkyl or alkoxy group having 1 to 7 carbon atoms.

Component B optionally additionally comprises one or more compounds selected from the group consisting of the compounds of the formulae IV10 to IV24:

in which R

1

and R

2

are as defined for R, R

3

and R

4

, independently of one another, are an alkyl or alkoxy group having 1 to 7 carbon atoms, and the 1,4-phenylene groups in IV10 to IV19, IV23 and IV24 may each, independently of one another, also be monosubstituted or polysubstituted by fluorine.

Particular preference is given to mixtures comprising one or more compounds of the following formula:

in which R

1#

is alkenyl having 1 to 7 carbon atoms, and R

2#

is straight-chain alkyl having 1 to 4 carbon atoms.

In these compounds, R

1#

is particularly preferably vinyl, 1E-propenyl, 1-butenyl, 3E-butenyl or 3E-pentenyl. R

2#

is particularly preferably methyl, ethyl or propyl, in particular methyl or ethyl.

Component B furthermore preferably comprises one or more compounds selected from the group consisting of the compounds of the formulae IV25 to IV31:

in which R

1

and R

2

are as defined for R, and L is F or H. The 1,4-phenylene groups in the compounds IV25 to IV31 may also each, independently of one another, be monosubstituted or polysubstituted by fluorine.

Mixtures which comprise compounds of the formula IV25 in which L is F are preferred.

Particular preference is given to compounds of the formulae IV25 to IV31 in which R

1

is alkyl and R

2

is alkyl or alkoxy, in particular alkoxy, in each case having 1 to 7 carbon atoms. Preference is furthermore given to compounds of the formulae IV25 and IV31 in which L is F.

In the compounds of the formulae IV1 to IV15 and IV17 to IV31, R

1

and R

2

are particularly preferably straight-chain alkyl or alkoxy having 1 to 12 carbon atoms.

Component B optionally comprises one or more compounds selected from the group consisting of the compounds of the formulae VI and VII:

in which C

r

H

2r+1

is a straight-chain alkyl group having up to 9 carbon atoms.

In a further preferred embodiment, the liquid-crystal mixtures according to the invention, besides components A, B, C and D, additionally comprise one or more compounds selected from the group consisting of the compounds of the formulae VIII and IX

in which R

1

and R

2

are as defined above.

Preference is furthermore given to liquid-crystal mixtures comprising at least one component selected from the group consisting of the compounds of the formulae X to XIV:

in which Hal is F or Cl, L is H or F, and R and R

3

are as defined above, in particular in which R and R

3

are alkyl having 1 to 5 carbon atoms.

The liquid-crystalline mixtures optionally comprise an optically active component C in such an amount that the ratio between the layer thickness (separation of the outer plates) and the natural pitch of the chiral nematic liquid-crystal mixture is greater than 0.2. For the component, a multiplicity of chiral dopants, some of which are commercially available, is available to the person skilled in the art, for example such as cholesteryl nonanoate, S-811 from Merck KGaA, Darmstadt, and CB15 (BDH, Poole, UK). The choice of dopants is not crucial per se.

The proportion of the compounds of component C is preferably from 0 to 10%, in particular from 0 to 5%, particularly preferably from 0 to 3%

In a particularly preferred embodiment, the mixtures according to the invention comprise from about 2 to 45%, in particular from 5 to 25%, of liquid-crystalline tolan compounds. This enables smaller layer thicknesses to be used, significantly shortening the response times. The tolan compounds are preferably selected from Group T consisting of the compounds of the formulae T1, T2 and T3:

in which

preferably

also

in the formula T1 and also

in the formula T2,

d

is 0 or 1,

L

1

to L

6

are each, independently of one another, H or F,

Q

is —CF

2

—, —CHF—, —OCF

2

—, —OCHF— or a single

bond,

Y

is F or Cl,

Z

4

is —CO—O—, —CH

2

CH

2

— or a single bond, and

R

1

and R

2

are as defined above.

Preferred compounds of the formula T1 conform to the sub-formulae T1a and T1b

in which L

1

to L

4

are H or F, and Q—Y is F, Cl or OCF

3

, in particular F or OCF

3

.

Preferred compounds of the formula T2 conform to the sub-formulae T2a to T2g

in which R

1

, R

2

and Z

4

are as defined above, and L

1

to L

6

are H or F.

Particularly preferred compounds of the formula T2e are those in which one, two or three of the radicals L

1

to L

6

are F and the others are H, where L

1

and L

2

or L

3

and L

4

or L

5

and L

6

are not both simultaneously F.

Preferred compounds of the formula T3 conform to the sub-formulae T3a to T3e

in which R

1

, R

2

and Z

4

are as defined above.

The proportion of compounds from Group T is preferably from 2 to 45%, in particular from 5 to 30%.

In a further particularly preferred embodiment, the mixtures according to the invention preferably comprise from about 5 to 20% of one or more compounds having a dielectric anisotropy of less than −2 (component D).

Component) preferably comprises one or more compounds containing the structural unit 2,3-difluoro-1,4-phenylene, for example compounds as described in DE-A 38 07 801, 38 07 861, 38 07 863, 38 07 864 or 38 07 908. Particular preference is given to tolans containing this structural unit, as described in International Patent Application PCT/DE 88/00133, in particular those of the formulae T2f and T2g.

Further known compounds of component D are, for example, derivatives of 2,3-dicyanohydroquinones or cyclohexane derivatives containing the structural unit

as described in DE-A 32 31 707 or DE-A 34 07 013 respectively.

The liquid-crystal mixture according to the invention preferably comprises one or more compounds selected from Group 1 consisting of compounds of the formulae B1I to B1IV:

in which

R

1

, R

2

and Z

4

are as defined above and

and/or at least one compound selected from Group B2 consisting of compounds of the formulae B2I to B2III:

in which

R

is as defined above,

Z

5

is —CH

2

CH

2

—, —CO—O— or a single bond,

Q

2

alkyl

is an alkyl group having 1 to 9 carbon atoms,

X

is CN or F, and

L

is H or F,

and/or at least one compound selected from Group B3 consisting of compounds of the formulae B3I to B3III:

in which

R

1

and R

2

,

independently of one another, are as defined above,

Y

is F or Cl, and

The proportion of the compounds from Group B1 is preferably from 10 to 50%, in particular from 15 to 40%. Compounds of the formulae B1III and B1IIV are preferred.

Particularly preferred compounds from Group B1 are those of the following sub-formulae:

in which

R

1a

is CH

3

—(CH

2

)

p

—, CH

3

—(CH

2

)

p

—O—, CH

3

—(CH

2

)

p

—O—CH

2

—,

trans-H—(CH

2

)

q

—CH═CH(CH

2

CH

2

)

s

—CH

2

O— or

trans-H—(CH

2

)

q

—CH═CH—(CH

2

CH

2

)

s

—,

R

2a

is CH

3

—(CH

2

)

p

—;

p

is 1, 2, 3 or 4,

s

is 0 or 1.

The proportion of the compounds of the abovementioned sub-formulae B1IIIa and B1IIIb together with the compounds of the formula IB1 is preferably from about 5 to 45%, particularly preferably from about 10% to 35%.

The proportion of the compounds of the sub-formula B1IVa or of the compounds of the formula B1IV is preferably from about 5 to 40%, particularly preferably from about 10 to 35%.

In a particularly preferred embodiment, the mixtures simultaneously comprise compounds of the formulae B1III and B1IV together with the compounds of the formulae IB1 and IB2, where the total proportion for components from Group B1 is observed.

If compounds of the formulae B1I and/or B1III are present, R

1

and R

2

are preferably each, independently of one another, n-alkyl having 1 to 7 carbon atoms or (trans)-n-alkenyl having 3 to 7 carbon atoms. Z is preferably a single bond.

Preference is furthermore given to mixtures according to the invention which comprise one or more compounds of the formula B1IV in which

and R

1

and R

2

have one of the preferred meanings indicated above and are particularly preferably n-alkyl having 1 to 7 carbon atoms.

In all cases, the total proportion of components from Group B1 is observed.

The proportion of the compounds from group B2 is preferably from about 0 to 45%, in particular from 5 to 20%. The proportion (preferred ranges) for B2I to B2III is as follows:

B2I:

from about 5 to 30%, preferably from about 5 to 15%,

sum of B2II

from about 5 to 25%, preferably from about 10 to 20%.

and B2III:

Preferred compounds from Group B2 are shown below:

in which R

1

, R

2

, L and Z

5

are as defined above.

In these compounds, R

1

is preferably n-alkyl having 1 to 7 carbon atoms or (trans)-n-alkenyl having 3 to 7 carbon atoms, Z

5

is preferably a single bond, R

2

preferably has the preferred meaning given above for R or is fluorine, and L is preferably fluorine.

The mixtures according to the invention preferably comprise one or more compounds selected from the group consisting of B2Ic, B2IIa and B2IIIa in a total proportion of from about 5 to 35%

In a particularly preferred embodiment, the mixtures according to the invention, in addition to B2Ic, B2IIa and B2IIIa (L═F), comprise further terminally fluorinated compounds, selected, for example, from the group consisting of

and/or polar heterocyclic compounds selected from the group consisting of

in which R

1

is preferably n-alkyl having 1 to 7 carbon atoms or (trans)-n-alkenyl having 3 to 7 carbon atoms, h is 0 or 1, X

0

is F, Cl, CF

3

, —OCF

3

or —OCHF

2

, and L is H or F.

The total proportion of all terminally fluorinated compounds is preferably from about 5 to 75%, in particular from about 15 to 50%.

The proportion of compounds from Group B3 is preferably from about 5 to 30%, particularly preferably from about 10 to 20%. R

1

is preferably n-alkyl or n-alkoxy, in each case having 1 to 9 carbon atoms.

However, it is also possible to employ analogous compounds containing alkenyl or alkenyloxy groups. Compounds of the formula B3I are preferred.

The term “alkenyl” in the definition of R, R

1

, R

2

, R

f

and R

d

covers straight-chain and branched alkenyl groups having carbon up to 7 atoms, in particular the straight-chain groups. Particularly preferred alkenyl groups are C

2

-C

7

-1E-alkenyl, C

4

-C

7

-3E-alkenyl, C

5

-C

7

-4-alkenyl, C

6

-C

7

-5-alkenyl and C

7

-6-alkenyl, in particular C

2

-C

7

-1E-alkenyl, C

4

-C

7

-3E-alkenyl and C

5

-C

7

-4-alkenyl.

Examples of preferred alkenyl groups are vinyl, 1E-propenyl, 1E-butenyl, 1E-pentenyl, 1E-hexenyl, 1E-heptenyl, 3-butenyl, 3E-pentenyl, 3E-hexenyl, 3E-heptenyl, 4-pentenyl, 4Z-hexenyl, 4E-hexenyl, 4Z-heptenyl, 5-hexenyl, 6-heptenyl and the like. Groups having up to 5 carbon atoms are generally preferred.

The terms “alkyl” and “alkoxy” in the definitions of R

a

, R

b

, R

c

, R

d

, R

e

, R, R

1

, R

2

, R

3

and R

4

cover straight-chain and branched alkyl and alkoxy groups, in particular the straight-chain groups. Particularly preferred alkyl and alkoxy groups are ethyl, propyl, butyl, pentyl, hexyl, heptyl, ethoxy, propoxy, butoxy, pentoxy, hexyloxy or heptyloxy, furthermore methyl, octyl, nonyl, decyl, undecyl, dodecyl, methoxy, octyloxy, nonyloxy, decyloxy, undecyloxy or dodecyloxy.

The mixtures according to the invention comprise compounds of the formulae IA and IB and preferably compounds from at least one of groups B1, B2 and B3. They preferably comprise one or more compounds from Group B1 and one or more compounds from Group B2 and/or B3.

In a preferred embodiment, the liquid-crystalline media according to the invention comprise 3, 4, 5 or 6 compounds of the formulae IA and/or IB; the content of these compounds is generally from 10 to 80% by weight, preferably from 15 to 50% by weight, based on the mixture as a whole.

In a further preferred embodiment, the mixtures comprise

one or more compounds of the following formulae

in which R

1

, R

2

and L have the preferred meanings given under compounds of Component B. The proportion of these compounds in the liquid-crystal mixtures is preferably from 0 to 45%, in particular from 5 to 30%;

one or more, in particular 1, 2, 3 or 4, compounds selected from the compounds of the formulae IIIb, IIId, IIIf, IIIh, IIIi, IIIm, IIIs, IIIt and IIIu;

at least two compounds selected from the compounds of the formulae IIb1, IIb2, IIc1 and IIc2. The proportion of these compounds in the liquid-crystal mixtures is preferably from 0 to 60% by weight, particularly from 10 to 45%;

one or more compounds of the formula T1 or T2, in particular one or more compounds of the formula T2a and/or T2b, where the proportion of these compounds in the liquid-crystal mixtures is preferably from 0 to 25%, in particular from 1 to 15%.

Further particularly preferred embodiments relate to liquid-crystal mixtures comprising

at least two compounds of the formula AI or AII;

one or more compounds in which R is a trans-alkenyl group or trans-alkenyloxy group;

one or more compounds selected from the following group:

in which R

1

, R

2

and L have the preferred meanings given under compounds of Component B, and R

3

and R

4

are as defined above. The 1,4-phenylene group in the abovementioned compounds may also be substituted by fluorine;

one or more compounds of the formulae

in which R, R

1

and R

2

are as defined above.

In particular when used in SLCDs having high layer thicknesses, the mixtures according to the invention are distinguished by very low total response times (t

tot

=t

on

+t

off

). Low total response times are an important criterion, in particular, for SLCDs for use as displays in laptops in order to be able to display cursor movements without interference.

The liquid-crystal mixtures used in the STN and TN cells according to the invention are dielectrically positive with Δ∈≧1. Particular preference is given to liquid-crystal mixtures where Δ∈≧3 and very particularly to those where Δ∈≧5.

The liquid-crystal mixtures according to the invention have favourable values for the threshold voltage V

10/0/20

and for the rotational viscosity γ

1

. If the value for the optical path difference d·Δn is specified, the value for the layer thickness d is determined by the optical anisotropy Δn. In particular at relatively high values for d·Δn, the use of liquid-crystal mixtures according to the invention having a relatively high value for the optical anisotropy is generally preferred since the value for d can then be chosen to be relatively small, which results in more favourable values for the response times. However, liquid-crystal displays according to the invention which contain liquid-crystal mixtures according to the invention having relatively small values for Δn are also characterized by advantageous values for the response times.

The liquid-crystal mixtures according to the invention are furthermore characterized by advantageous values for the steepness of the electro-optical characteristic line and can be operated at high multiplex rates, in particular at temperatures above 20° C. In addition, the liquid-crystal mixtures according to the invention have high stability and favourable values for the electrical resistance and the frequency dependence of the threshold voltage. The liquid-crystal displays according to the invention have a broad operating temperature range and good angle dependence of the contrast.

The construction of the liquid-crystal display elements according to the invention from polarizers, electrode base plates and electrodes having a surface treatment such that the preferential alignment (director) of the liquid-crystal molecules in each case adjacent thereto is usually twisted by a value of from 160° to 720° from one electrode to the other corresponds to the structure which is conventional for display elements of this type. The term “conventional structure” is broadly drawn here and also includes all derivatives and modifications of the TN and STN cell, in particular also matrix display elements, and display elements which contain additional magnets.

The surface tilt angle at the two outer plates may be identical or different. Identical tilt angles are preferred. Preferred TN displays have pre-tilt angles between the longitudinal axis of the molecules at the surface of the outer plates and the outer plates of from 0° to 7°, preferably from 0.01° to 5°, in particular from 0.1 to 2°. In STN displays, the pre-tilt angle is from 1° to 30°, preferably from 1° to 12°, in particular from 3° to 10°.

The twist angle of the TN mixture in the cell has a value of between 22.5° and 170°, preferably between 45° and 130°, in particular between 80° and 115°. The twist angle of the STN mixture in the display from alignment layer to alignment layer has a value of between 100° and 600°, preferably between 170° and 300°, in particular between 180° and 270°.

The liquid-crystal mixtures which can be used according to the invention are prepared in a manner which is conventional per se. In general, the desired amount of the components used in a lesser amount is dissolved in the components making up the principal constituent, advantageously at elevated temperature. It is also possible to mix solutions of the components in an organic solvent, for example in acetone, chloroform or methanol, and, after mixing, to remove the solvent again, for example by distillation.

The dielectrics may also contain further additives which are known to the person skilled in the art and are described in the literature. For example, 0-15% of pleochroic dyes may be added.

The entire disclosure of all applications, patents and publications, cited above, and of corresponding German application No. 199 20 405.5, filed May 4, 1999 is hereby incorporated by reference.

EXAMPLES

Without further elaboration, it is believed that one skilled in the art can, using the preceding description, utilize the present invention to its fullest extent. The following preferred specific embodiments are, therefore, to be construed as merely illustrative, and not limitative of the remainder of the disclosure in any way whatsoever.

In the foregoing and in the following examples, all temperatures are set forth uncorrected in degrees Celsius; and, unless otherwise indicated, all parts and percentages are by weight.

In the present application and in the examples below, the structures of the liquid-crystal compounds are indicated by acronyms, the transformation into chemical formulae taking place in accordance with Tables A and B below. All radicals C

n

H

2n+1

and C

m

H

2n+1

are straight-chain alkyl radicals having n and m carbon atoms respectively. The alkenyl radicals have the trans-configuration. The coding in Table B is self-evident. In Table A, only the acronym for the parent structure is given. In individual cases, the acronym for the parent structure is followed, separated by a hyphen, by a code for the substituents R

1

, R

2

, L

1

, L

2

and L

3

:

Code for

R

1

, R

2

, L

1

, L

2

, L

3

R

1

R

2

L

1

L

2

L

3

nm

C

n

H

2n+1

C

m

H

2m+1

H

H

H

nOm

OC

n

H

2n+1

C

m

H

2m+1

H

H

H

nO.m

C

n

H

2n+1

OC

m

H

2m+1

H

H

H

n

C

n

H

2n+1

CN

H

H

H

nN.F

C

n

H

2n+1

CN

H

H

F

nN.F.F

C

n

H

2n+1

CN

H

F

F

nF

C

n

H

2n+1

F

H

H

H

nOF

OC

n

H

2n+1

F

H

H

H

nCl

C

n

H

2n+1

Cl

H

H

H

nF.F

C

n

H

2n+1

F

H

H

F

nmF

C

n

H

2n+1

C

m

H

2m+1

F

H

H

nCF

3

C

n

H

2n+1

CF

3

H

H

H

nOCF

3

C

n

H

2n+1

OCF

3

H

H

H

n-Am

C

n

H

2n+1

—C≡C—C

m

H

2m+1

H

H

H

n-AN

C

n

H

2n+1

—C≡C—CN

H

H

H

n-Vm

C

n

H

2n+1

—CH═CH—C

m

H

2m+1

H

H

H

nV-Vm

C

n

H

2n+1

—CH═CH—

—CH═CH—C

m

H

2m+1

H

H

H

The TN and STN displays preferably contain liquid-crystalline mixtures composed of one or more compounds from Tables A and B.

TABLE A

(L

1

, L

2

and L

3

= H or F)

BCH

CBC

CCH

CCP

CPTP

PTP

ECCP

EPCH

PCH

CCPC

TABLE B

Inm

K3n

CCP-nV-m

CCG-V-F

CBC-nmF

CC-n-V

CU-n-AN

CC-nV-Vm

CCP-V-m

CCP-V2-m

PPTUI-n-m

CCP-nV2-m

CVCP-nV-m

CVCP-nV-Om

CVCP-nV2-m

CVCP-nV2-Om

CVCP-nV2-Om

The examples below are intended to illustrate the invention without representing a limitation.

S-N

smectic-nematic phase transition temperature

N-I

nematic-isotropic phase transition temperature

cl.p.

clearing point

visc.

rotational viscosity (mPa · s)

Δn

optical anisotropy (589 nm, 20° C.)

Δε

dielectric anisotropy (1 kHz, 20° C.)

t

on

time from switching on until 90% of the maximum contrast is

achieved

t

off

time from switching off until 10% of the maximum contrast is

achieved

V

10

threshold voltage = characteristic voltage at a relative contrast

of 10% (also abbreviated to V

(10,0,20)

)

V

90

characteristic voltage at a relative contrast of 90%

V

90

/V

10

steepness

V

op

operating voltage

t

ave

(t

on

+ t

off

)/2 (average response time)

d

cell thickness

p

pitch

Above and below, all temperatures are given in °C. Percentages are per cent by weight. The values for the response times and viscosities relate to 20° C., unless states otherwise. The response time is, unless stated otherwise, the average value t

ave

of the switch-on and switch-off times.

The SLCD is, unless stated otherwise, addressed with a rectangular voltage of 80 Hz.

Example 1

An STN mixture comprising

ME2N.F

5.00%

Clearing point:

77.0° C.

ME3N.F

5.00%

Δn:

0.1423

ME4N.F

6.00%

Twist:

240°

PCH-3N.F.F

18.00%

V

10

:

1.37 V

PCH-3

9.00%

V

90

/V

10

:

1.044

CC-1V-V1

8.00%

d · Δn:

0.85 μm

CCG-V-F

10.00%

CCP-V-1

13.50%

CVCP-V-O1

5.00%

CVCP-1V-O1

5.00%

PTP-102

5.50%

PTP-201

2.00%

CPTP-301

5.50%

CPTP-302

2.50%

Example 2

An STN mixture comprising

ME2N.F

5.00%

Clearing point:

76.5° C.

ME3N.F

5.00%

Δn:

0.1410

ME4N.F

6.00%

Twist:

240°

PCH-3N.F.F

18.00%

V

10

:

1.35 V

PCH-3

9.00%

V

90

/V

10

:

1.045

CC-3-V1

8.00%

d · Δn:

0.85 μm

CCG-V-F

9.00%

CCP-V-1

14.00%

CVCP-V-O1

5.00%

CVCP-1V-O1

5.00%

PTP-102

5.50%

PTP-201

2.00%

CPTP-301

5.50%

CPTP-302

3.00%

Example 3

An STN mixture comprising

ME2N.F

5.00%

Clearing point:

76.0° C.

ME3N.F

5.00%

Δn:

0.1410

ME4N.F

6.00%

Twist:

240°

PCH-3N.F.F

18.00%

V

10

:

1.36 V

PCH-3

9.00%

V

90

/V

10

:

1.064

CC-3-V1

8.00%

d · Δn:

0.85 μm

CCG-V-F

6.00%

CCP-V-1

17.00%

CVCP-V-1

5.00%

CVCP-1V-1

5.00%

PTP-102

5.50%

PTP-201

1.50%

CPTP-301

6.00%

CPTP-302

3.00%

Example 4

An STN mixture comprising

PCH-3N.F.F

10.00%

Clearing point:

96.0° C.

ME2N.F

6.00%

Δn:

0.1399

ME3N.F

6.00%

Twist:

240°

ME4N.F

9.00%

V

10

:

1.29 V

ME5N.F

9.00%

V

90

/V

10

:

1.043

CC-5-V

3.00%

d · Δn:

0.85 μm

CCG-V-F

15.00%

CCP-V-1

9.00%

CVCP-V-1

5.00%

CVCP-1V-1

5.00%

CVCP-V-O1

5.00%

CVCP-1V-O1

5.00%

PTP-102

3.00%

CPTP-301

3.00%

CBC-33F

4.00%

CBC-53F

3.00%

Example 5

An STN mixture comprising

PCH-3N.F.F

10.00%

Clearing point:

95.0° C.

ME2N.F

6.00%

Δn:

0.1386

ME3N.F

6.00%

Twist:

240°

ME4N.F

9.00%

V

10

:

1.27 V

ME5N.F

9.00%

V

90

/V

10

:

1.039

CC-5-V

3.00%

d · Δn:

0.85 μm

CCG-V-F

15.00%

CCP-V-1

9.00%

CCP-V2-1

5.00%

CVCP-V-1

5.00%

CVCP-V-O1

5.00%

CVCP-1V-O1

5.00%

PTP-102

3.00%

CPTP-301

3.00%

CBC-33F

4.00%

CBC-53F

3.00%

Example 6

An STN mixture comprising

PCH-3N.F.F

10.00%

Clearing point:

95.0° C.

ME2N.F

6.00%

Δn:

0.1380

ME3N.F

6.00%

Twist:

240°

ME4N.F

9.00%

V

10

:

1.27 V

ME5N.F

9.00%

V

90

/V

10

:

1.053

CC-5-V

3.00%

d · Δn:

0.85 μm

CCG-V-F

15.00%

CCP-V-1

9.00%

CCP-V2-1

10.00%

CVCP-V-O1

5.00%

CVCP-1V-O1

5.00%

PTP-102

3.00%

CPTP-301

3.00%

CBC-33F

4.00%

CBC-53F

3.00%

Example 7

An STN mixture comprising

ME2N.F

4.00%

Clearing point:

97.0° C.

ME3N.F

4.00%

Δn:

0.1734

ME4N.F

10.00%

Twist:

240°

PCH-3N.F.F

18.00%

V

10

:

1.44 V

CC-5-V

11.50%

V

90

/V

10

:

1.074

CVCP-V-O1

4.00%

CVCP-1V-O1

4.00%

CCP-V-1

14.00%

CBC-33F

5.00%

CBC-53F

3.00%

PPTUI-3-2

22.50%

Example 8

An STN mixture comprising

PCH-3N.F.F

19.00%

Clearing point:

91.0° C.

ME2N.F

4.00%

Δn:

0.1423

ME3N.F

4.00%

Twist:

240°

ME4N.F

10.00%

V

10

:

1.43 V

CC-5-V

3.00%

V

90

/V

10

:

1.054

CC-3-V1

7.00%

d · Δn:

0.85 μm

CVCP-V-O1

4.00%

CVCP-V-1

4.50%

CCP-V-1

15.00%

CCP-V2-1

14.00%

PPTUI-3-2

11.50%

CVCP-1V-O1

4.00%

Example 9

An STN mixture comprising

ME2N.F

2.00%

Clearing point:

85.0° C.

ME3N.F

3.00%

Δn:

0.1411

ME4N.F

6.00%

Twist:

240°

PCH-3N.F.F

17.00%

V

10

:

1.48 V

PCH-3

19.00%

V

90

/V

10

:

1.043

CVCP-V-O1

4.00%

d · Δn:

0.85 μm

CVCP-1V-O1

4.00%

CCP-V-1

15.00%

CCP-V2-1

14.00%

CCG-V-F

6.00%

PPTUI-3-2

10.00%

Example 10

An STN mixture comprising

ME2N.F

2.00%

ME3N.F

2.00%

PCH-3N.F.F

13.00%

PCH-3

26.00%

CVCF-V-O1

4.00%

CVCP-1V-O1

4.00%

CC-3-V1

6.00%

CCP-V-1

14.00%

CCP-V2-1

13.00%

CCG-V-F

5.00%

PPTUI-3-2

11.00%

Clearing point:

92.0° C.

Δn:

0.1411

Twist:

240°

V

10

:

1.81 V

V

90

/V

10

:

1.039

d · Δn:

0.85 μm

Example 11

An STN mixture comprising

ME2N.F

6.00%

ME3N.F

6.00%

ME4N.F

10.00%

ME5N.F

10.00%

FCH-3N.F.F

10.00%

CCG-V-F

10.00%

CC-5-V

10.00%

CCP-V-1

9.00%

CVCP-V-O1

5.00%

CVCP-1V-O1

5.00%

CCPC-33

4.00%

CCPC-34

3.00%

CPTP-301

4.00%

CPTP-302

4.00%

CPTP-303

4.00%

Clearing point:

98.0° C.

Δn:

0.1414

Twist:

240°

V

10

:

1.28 V

V

90

/V

10

:

1.062

d · Δn:

0.85 μm

Example 12

An STN mixture comprising

ME2N.F

7.00%

ME3N.F

7.00%

ME4N.F

10.00%

ME5N.F

10.00%

CP-1V-N

12.00%

CP-V2-N

19.00%

CCP-V-1

10.00%

CVCP-V-O1

5.00%

CVCP-1V-O1

5.00%

CCPC-33

5.00%

CCPC-34

5.00%

CCPC-35

5.00%

Clearing point:

+94.5° C.

Δn:

0.1447

Twist:

240°

V

10

:

1.33 V

V

90

/V

10

:

1.023

d · Δn:

0.85 μm

Example 13

An STN mixture comprising

ME2N.F

6.00%

ME3N.F

6.00%

ME4N.F

9.00%

ME5N.F

9.00%

CP-1V-N

11.00%

CP-V2-N

11.00%

CC-5-V

10.00%

CCP-V-1

15.00%

CVCP-V-O1

5.00%

CVCP-1V-O1

5.00%

CCPC-33

4.00%

CCPC-34

3.00%

CPTP-301

3.00%

CPTP-302

3.00%

Clearing point:

+96.5° C.

Δn:

+0.1424

Twist:

240°

V

10

:

1.47 V

V

90

/V

10

:

1.029

d · Δn:

0.85 μm

Example 14

An STN mixture comprising

PCH-3

20.00%

PCH-3N.F.F

20.00%

CC-5-V

1.00%

CCG-V-F

17.00%

CCP-V-1

15.00%

CVCP-V-1

5.00%

CVCP-V-O1

5.00%

CVCP-1V-O1

4.00%

PTP-102

3.00%

CPTP-301

5.00%

CPTP-302

5.00%

Clearing point:

+92.0° C.

Δn:

+0.1321

Twist:

240°

V

10

:

1.78 V

V

90

/V

10

:

1.029

d · Δn:

0.85 μm

Example 15

An STN mixture comprising

PCH-3

20.00%

PCH-3N.F.F

18.00%

ME2N.F

1.00%

ME3N.F

1.00%

CCG-V-F

16.00%

CCP-V-1

15.00%

CCP-V2-1

2.50%

CVCP-V-1

5.00%

CVCP-V-O1

5.00%

CVCP-1V-O1

5.00%

PTP-102

5.00%

CPTP-302

5.00%

CPTP-303

1.50%

Clearing point:

+91.5° C.

Δn:

+0.1329

Twist:

240°

V

10

:

1.77 V

V

90

/V

10

:

1.027

d · Δn:

0.85 μm

Example 16

An STN mixture comprising

PCH-3N.F.F

11.00%

ME2N.F

6.00%

ME3N.F

6.00%

ME4N.F

9.00%

ME5N.F

9.00%

CC-5-V

3.00%

CCG-V-F

13.00%

CCP-V-1

16.00%

CVCP-V-1

5.00%

CVCP-V-O1

5.00%

CVCP-1V-O1

5.00%

CBC-33F

3.00%

CBC-53F

3.00%

CBC-55F

3.00%

CCPC-33

3.00%

Clearing point:

+101.0° C.

Δn:

+0.1291

Twist:

240°

V

10

:

1.29 V

V

90

/V

10

:

1.052

d · Δn:

0.85 μm

Example 17

An STN mixture comprising

PCH-3N.F.F

14.00%

ME2N.F

4.00%

ME3N.F

4.00%

ME4N.F

6.00%

ME5N.F

6.00%

CC-5-V

4.00%

CCG-V-F

18.50%

CCP-V-1

16.00%

CVCP-V-1

5.00%

CVCP-V-O1

5.00%

CVCP-1V-O1

5.00%

PTP-102

2.00%

CPTP-302

3.50%

CBC-33F

3.00%

CBC-53F

2.00%

CBC-55F

2.00%

Clearing point:

+101.0° C.

Δn:

+0.1298

Twist:

240°

V

10

:

1.48 V

V

90

/V

10

:

1.044

d · Δn:

0.85 μm

Example 18

An STN mixture comprising

PCH-3N.F.F

14.00%

ME2N.F

4.00%

ME3N.F

4.00%

ME4N.F

6.00%

ME5N.F

7.00%

CC-5-V

3.00%

CCG-V-F

15.00%

CCP-V-1

14.00%

CVCP-V-1

6.00%

CVCP-V-O1

6.00%

CVCP-1V-O1

6.00%

PTP-102

5.00%

CPTP-302

5.00%

CBC-33F

3.00%

CBC-53F

2.00%

Clearing point:

+99.0° C.

Δn:

+0.1404

Twist:

240°

V

10

:

1.46 V

V

90

/V

10

:

1.046

d · Δn:

0.85 μm

Example 19

An STN mixture comprising

PCH-3N.F.F

10.00%

ME2N.F

3.00%

ME3N.F

3.00%

ME4N.F

5.00%

ME5N.F

5.00%

CC-5-V

17.00%

CCG-V-F

10.00%

CCP-V-1

14.00%

CVCP-V-1

5.00%

CVCP-V-O1

5.00%

CVCP-1V-O1

5.00%

PTP-102

5.00%

CPTP-301

4.00%

CPTP-302

5.00%

CPTP-303

4.00%

Clearing point:

+101.0° C.

Δn:

+0.1395

Twist:

240°

V

10

:

1.77 V

V

90

/V

10

:

1.059

d · Δn:

0.85 μm

Example 20

An STN mixture comprising

PCH-3N.F.F

14.00%

ME2N.F

4.00%

ME3N.F

4.00%

ME4N.F

6.00%

ME5N.F

6.00%

CCG-V-F

18.50%

CCP-V-1

16.00%

CVCP-V-1

5.00%

CVCP-V-O1

5.00%

CVCP-1V-O1

5.00%

PTP-102

5.00%

CPTP-301

4.50%

CBC-33F

3.00%

CBC-53F

2.00%

CBC-55F

2.00%

Clearing point:

+103.0° C.

Δn:

+0.1411

Twist:

240°

V

10

:

1.49 V

V

90

/V

10

:

1.051

d · Δn:

0.85 μm

Example 21

An STN mixture comprising

PCH-3

22.00%

PCH-3N.F.F

20.00%

ME2N.F

1.00%

ME3N.F

1.00%

CCG-V-F

8.00%

CCP-V-1

15.00%

CVCP-V2-1

4.00%

CVCP-V-1

5.00%

CVCP-V-C1

5.00%

CVCP-1V-O1

5.00%

PTP-102

4.00%

CPTP-301

4.00%

CPTP-302

4.00%

CBC-33

2.00%

Clearing pcint:

+93.5° C.

Δn:

+0.1372

Twist:

240°

V

10

:

1.71 V

V

90

/V

10

:

1.019

d · Δn:

0.85 μm

Example 22

An STN mixture comprising

CGU-2-F

8.00%

CGU-3-F

8.00%

CCZU-2-F

5.00%

CCZU-3-F

13.00%

CCZU-5-F

5.00%

CCP-3F.F.F

8.00%

CCP-V-1

14.00%

CVCP-V-O1

5.00%

CVCP-1V-O1

5.00%

PGU-3-F

8.00%

PGU-5-F

8.00%

PGU-2-F

8.00%

PPTUI-3-2

5.00%

Clearing point:

+102.0° C.

Δn:

+0.1429

Twist:

240°

V

10

:

1.60 V

V

90

/V

10

:

1.109

d · Δn:

0.85 μm

Example 23

An STN mixture comprising

ME2N.F

8.00%

ME3N.F

9.00%

ME4.N.F

12.00%

PCH-3N.F.F

13.00%

CCG-V-F

24.00%

CVCP-V-1

5.00%

CVCP-V-O1

5.00%

CVCP-1V-O1

3.00%

CCPC-33

3.00%

CCPC-34

2.00%

CBC-33

3.00%

PPTUI-3-2

7.00%

PPTU-3-4

6.00%

Clearing point:

+91.0° C.

Δn:

+0.1552

Twist:

240°

V

10

:

1.14 V

V

90

/V

10

:

1.061

d · Δn:

0.85 μm

Example 24

An STN mixture comprising

PCH-3N.F.F

10.00%

ME2N.F

6.00%

ME3N.F

6.00%

ME4.N.F

9.00%

ME5.N.F

9.00%

CC-5-V

3.00%

CCG-V-F

15.00%

CCP-V-1

9.00%

CCP-V2-1

5.00%

CVCP-V-1

7.00%

CVCP-1V-1

8.00%

PTP-102

3.00%

CPTP-301

3.00%

CBC-33F

4.00%

CBC-53F

3.00%

Clearing point:

+92.0° C.

Δn:

+0.1384

Twist:

240°

V

10

:

1.28 V

V

90

/V

10

:

1.037

d · Δn:

0.85 μm

Example 25

An STN mixture comprising

PCH-3

27.00%

PCH-3N.F.F

13.00%

B-30.FN.F

10.00%

CC-5-V

2.00%

CCP-V-1

15.00%

CCP-V2-1

13.00%

CVCP-V-1

5.00%

CVCP-V-O1

5.00%

CVCP-1V-O1

5.00%

CPTP-302

3.00%

CBC-33

2.00%

Clearing point:

+91.0° C.

Δn:

+0.1313

Twist:

240°

V

10

:

1.74 V

V

90

/V

10

:

1.009

d · Δn:

0.85 μm

Example 26

An STN mixture comprising

ME2N.F

8.00%

ME3N.F

9.00%

ME4.N.F

12.00%

ME5.N.F

11.00%

PCH-3N.F.F.

15.00%

CCG-V-F

9.00%

CCP-V-1

6.00%

CVCP-V-O1

5.00%

CVCP-1V-O1

5.00%

CPTP-301

2.00%

CCPC-33

5.00%

CCPC-34

5.00%

CCPC-35

5.00%

CBC-33F

3.00%

Clearing point:

+90.0° C.

Δn:

+0.1371

Twist:

240°

V

10

:

1.02 V

V

90

/V

10

:

1.022

d · Δn:

0.85 μm

Example 27

An STN mixture comprising

ME2N.F

8.00%

ME3N.F

8.00%

ME4.N.F

9.00%

ME5.N.F

9.00%

PCH-3N.F.F

15.00%

CCG-V-F

9.00%

CCP-V-1

7.00%

CVCP-V-O1

5.00%

CVCP-1V-O1

5.00%

PPTUI-3-2

5.00%

CCPC-33

5.00%

CCPC-34

5.00%

CCPC-35

5.00%

CC-5-V

5.00%

Clearing point:

+90.5° C.

Δn:

+0.1374

Twist:

240°

V

10

:

1.10 V

V

90

/V

10

:

1.023

d · Δn:

0.85 μm

Example 28

An STN mixture comprising

PCH-3N.F.F

11.00%

ME2N.F

6.00%

ME3N.F

6.00%

ME4.N.F

9.00%

ME5.N.F

9.00%

CCG-V-F

13.00%

CCP-V-1

16.00%

CVCP-V-1

5.00%

CVCP-V-O1

5.00%

CVCP-1V-O1

5.00%

PTP-102

2.00%

CPTP-301

2.00%

CBC-33F

4.00%

CBC-53F

4.00%

CBC-55F

3.00%

Clearing point:

+103.0° C.

Δn:

+0.1408

Twist:

240°

V

10

:

1.28 V

V

90

/V

10

:

1.030

d · Δn:

0.85 μm

Example 29

An STN mixture comprising

PCH-3N.F.F

19.00%

ME2N.F

5.00%

ME3N.F

5.00%

ME4.N.F

9.00%

ME5.N.F

9.00%

CCG-V-F

7.50%

CCP-V-1

8.00%

CVCP-V-1

5.00%

CVCP-V-O1

5.00%

CVCP-1V-O1

5.00%

PTP-102

3.00%

CPTP-302

4.50%

CBC-33

3.00%

CCPC-33

4.00%

CCPC-34

4.00%

CCPC-35

4.00%

Clearing point:

+98.5° C.

Δn:

+0.1408

Twist:

240°

V

10

:

1.23 V

V

90

/V

10

:

1.032

d · Δn:

0.85 μm

Example 30

An STN mixture comprising

PCH-3N.F.F

10.00%

ME2N.F

6.00%

ME3N.F

6.00%

ME4.N.F

9.00%

ME5.N.F

9.00%

CC-5-V

3.00%

CCG-V-F

15.00%

CCP-V-1

9.00%

CVCP-V2-1

5.00%

CVCP-V-O1

7.00%

CVCP-1V-O1

8.00%

PTP-102

3.00%

CPTP-301

3.00%

CBC-33F

4.00%

CBC-53F

3.00%

Clearing poiflt:

+98.0° C.

Δn:

+0.1405

Twist:

240°

V

10

:

1.32 V

V

90

/V

10

:

1.051

d · Δn:

0.85 μm

Example 31

An STN mixture comprising

PCH-3N.F.F

20.00%

ME2N.F

5.00%

ME3N.F

5.00%

ME4.N.F

9.00%

ME5.N.F

9.00%

CCG-V-F

7.00%

CCP-V-1

8.00%

CVCP-V-1

5.00%

CVCP-V-O1

5.00%

CVCP-1V-O1

5.00%

PPTUI-3-2

5.50%

CBC-33

2.50%

CCPC-33

5.00%

CCPC-34

5.00%

CCPC-35

4.00%

Clearing point:

+98.0° C.

Δn:

+0.1403

Twist:

240°

V

10

:

1.20 V

V

90

/V

10

:

1.045

d · Δn:

0.85 μm

Example 32

An STN mixture comprising

PCH-3N.F.F

14.00%

ME2N.F

4.00%

ME3N.F

4.00%

ME4.N.F

7.00%

ME5.N.F

7.00%

CC-5-V

3.00%

CCG-V-F

15.00%

CCP-V-1

14.00%

CVCP-V-1

6.00%

CVCP-V-O1

6.00%

CVCP-IV-O1

6.00%

PPTUI-3-2

6.50%

CBC-33F

4.00%

CBC-53F

3.50%

Clearing point:

+101.5° C.

Δn:

+0.1400

Twist:

240°

V

10

:

1.44 V

V

90

/V

10

:

1.040

d · Δn:

0.85 μm

Example 33

An STN mixture comprising

PCH-3N.F.F

10.00%

ME2N.F

3.00%

ME3N.F

3.00%

ME4.N.F

6.00%

ME5.N.F

6.00%

CC-5-V

18.00%

CCG-V-F

7.00%

CCP-V-1

13.00%

CVCP-V-1

5.00%

CVCP-V-O1

5.00%

CVCP-1V-O1

5.00%

PPTUI-3-2

12.50%

CCPC-33

2.50%

CCPC-34

2.00%

CCPC-35

2.00%

Clearing point:

+104.5° C.

Δn:

+0.1402

Twist:

240°

V

10

:

1.71 V

V

90

/V

10

:

1.049

d · Δn:

0.85 μm

Example 34

An STN mixture comprising

PCH-3

27.00%

PCH-3N.F.F

23.00%

CC-5-V

2.00%

CCP-V-1

15.00%

CCP-V2-1

6.00%

CVCP-V-1

5.00%

CVCP-V-O1

5.00%

CVCP-1V-O1

5.00%

CPTP-301

5.00%

CPTP-302

5.00%

CBC-33

2.00%

Clearing point:

+90.5° C.

Δn:

+0.1324

Twist:

240°

V

10

:

1.73 V

V

90

/V

10

:

1.023

d · Δn:

0.85 μm

Example 35

An STN mixture comprising

PCH-3

22.00%

PCH-3N.F.F

20.00%

ME2N.F

2.00%

ME3N.F

1.00%

CC-5-V

1.00%

CCG-V-F

8.00%

CCP-V-1

15.00%

CCP-V2-1

4.00%

CVCP-V-1

5.00%

CVCP-V-O1

5.00%

CVCP-1V-O1

5.00%

PTP-102

3.00%

CPTP-302

5.00%

CBC-33

4.00%

Clearing point:

+92.0° C.

Δn:

+0.1312

Twist:

240°

V

10

:

1.70 V

V

90

/V

10

:

1.023

d · Δn:

0.85 μm

Example 36

An STN mixture comprising

PCH-3N.F.F

17.00%

ME2N.F

2.00%

ME3N.F

3.00%

ME4N.F

7.00%

CC-3-V1

10.00%

CC-5-V

10.00%

CVCP-1V-O1

4.00%

CVCP-V-O1

4.00%

CVCP-V-1

4.00%

CCP-V-1

16.00%

CCP-V2-1

16.00%

PPTUI-3-2

7.00%

Clearing point:

+95.0° C.

Δn:

+0.1226

Twist:

240°

V

10

:

1.85 V

V

90

/V

10

:

1.050

d · Δn:

0.85 μm

Example 37

An STN mixture comprising

ME2N.F

4.00%

ME3N.F

4.00%

ME4N.F

12.00%

PCH-3N.F.F

10.00%

CC-5-V

3.00%

CC-3-V1

8.00%

CCP-V-1

16.00%

CCP-V2-1

16.00%

CVCP-V-O1

5.00%

CVCP-V-1

5.00%

PPTUI-3-2

7.00%

CBC-33F

5.00%

CBC-53F

5.00%

Clearing point:

+116.0° C.

Δn:

+0.1404

Twist:

240°

V

10

:

1.73 V

V

90

/V

10

:

1.051

d · Δn:

0.85 μm

Example 38

An STN mixture comprising.

ME2N.F

2.00%

ME3N.F

3.00%

ME4N.F

9.00%

PCH-3N.F.F

12.50%

CC-5-V

3.50%

CC-3-V1

9.00%

CCP-V-1

16.00%

CCP-V2-1

16.00%

CVCP-V-O1

5.00%

CVCP-V-1

5.00%

PPTUI-3-2

9.00%

CBC-33F

5.00%

CBC-53F

5.00%

Clearing point:

+120.0° C.

Δn:

+0.1407

Twist:

240°

V

10

:

1.97 V

V

90

/V

10

:

1.047

d · Δn:

0.85 μm

Example 39

An STN mixture comprising

ME2N.F

4.00%

ME3N.F

4.00%

ME4N.F

12.00%

PCH-3N.F.F

22.00%

PCH-3

5.00%

CC-3-V1

2.00%

CCG-V-F

9.00%

CCP-V-1

8.50%

CVCP-V-O1

5.00%

CVCP-1V-O1

5.00%

CVCP-V-1

5.00%

CPTP-301

5.50%

CPTP-302

2.00%

CBC-33F

5.50%

CBC-53F

5.50%

Clearing point:

+92.0° C.

Δn:

+0.1374

Twist:

240°

V

10

:

1.29 V

V

90

/V

10

:

1.040

d · Δn:

0.85 μm

Example 40

An STN mixture comprising

ME2N.F

2.00%

ME3N.F

3.00%

ME4N.F

3.00%

PCH-3N.F.F

11.00%

PCH-3

25.00%

CVCP-V-O1

4.00%

CVCP-1V-O1

4.00%

CC-3-V1

5.00%

CCP-V-1

14.00%

CCP-V2-1

14.00%

CCG-V-F

5.00%

PPTUI-3-2

10.00%

Clearing point:

+92.0° C.

Δn:

+0.1417

Twist:

240°

V

10

:

1.71 V

V

90

/V

10

:

1.042

d · Δn:

0.85 μm

Example 41

An STN mixture comprising

ME2N.F

4.00%

ME3N.F

4.00%

ME4N.F

12.00%

PCH-3N.F.F

18.50%

PCH-3

8.50%

CC-3-V1

2.00%

CCG-V-F

9.00%

CCP-V-1

9.00%

CVCP-V-O1

5.00%

CVCP-1V-O1

5.00%

CVCP-V-1

5.00%

CPTP-301

6.00%

CBC-33F

6.00%

CBC-53F

6.00%

Clearing point:

+95.0° C.

Δn:

+0.1372

Twist:

240°

V

10

:

1.34 V

V

90

/V

10

:

1.037

d · Δn:

0.85 μm

Example 42

An STN mixture comprising

PCH-3N.F.F

16.00%

ME2N.F

2.00%

ME3N.F

3.00%

ME4.N.F

6.00%

CC-3-V1

8.00%

CC-5-V

13.00%

CVCP-1V-O1

4.00%

CVCP-V-1

4.00%

CCP-V-1

16.00%

CCP-V2-1

16.00%

CCG-V-F

5.00%

PPTUI-3-2

7.00%

Clearing point:

+95.0° C.

Δn:

+0.1193

Twist:

240°

V

10

:

1.86 V

V

90

/V

10

:

1.055

d · Δn:

0.85 μm

Example 43

An STN mixture comprising

ME2N.F

8.00%

ME3N.F

8.00%

ME4.N.F

14.50%

PCH-3

16.00%

CC-3-V1

3.50%

CCG-V-F

18.00%

CCP-V-1

7.00%

CVCP-V-O1

5.00%

CVCP-1V-O1

5.00%

CVCP-V-1

5.00%

CPTP-301

2.00%

CBC-33F

4.00%

CBC-53F

4.00%

Clearing point:

+95.0° C.

Δn:

+0.1371

Twist:

240°

V

10

:

1.34 V

V

90

/V

10

:

1.029

d · Δn:

0.85 μm

Example 44

An STN mixture comprising

ME2N.F

8.00%

ME3N.F

8.00%

ME4.N.F

16.00%

PCH-3

10.00%

CC-3-V1

8.00%

CCG-V-F

18.00%

CCP-V-1

8.50%

CVCP-V-O1

5.00%

CVCP-1V-O1

5.00%

CVCP-V-1

5.00%

CPTP-301

4.50%

CBC-33F

4.00%

Clearing point:

+95.0° C.

Δn:

+0.1364

Twist:

240°

V

10

:

1.34 V

V

90

/V

10

:

1.037

d · Δn:

0.85 μm

Example 45

An STN mixture comprising

ME2N.F

8.00%

ME3N.F

8.00%

ME4.N.F

16.00%

PCH-3

7.00%

CC-5-V

2.00%

CC-3-V1

8.00%

CCG-V-F

18.00%

CCP-V-1

11.00%

CVCP-V-O1

5.00%

CVCP-1V-O1

5.00%

CVCP-V-1

5.00%

CPTP-301

5.00%

CPTP-301

2.00%

Clearing point:

+95.0° C.

Δn:

+0.1364

Twist:

240°

V

10

:

1.35 V

V

90

/V

10

:

1.041

d · Δn:

0.85 μm

Example 46

An STN mixture comprising

ME2N.F

2.00%

Clearing point:

+95.0° C.

ME3N.F

3.00%

Δn:

+0.1450

ME4.N.F

4.00%

Twist:

240°

PCH-3N.F.F

11.00%

V

10

:

1.72 V

PCH-3

25.00%

V

90

/V

10

:

1.038

CVCP-V-O1

4.00%

d · Δn:

0.85 μm

CVCP-1V-O1

4.00%

CVCP-V-1

16.00%

CVCP-V2-1

16.00%

CCG-V-F

5.00%

PPTUI-3-2

10.00%

Example 47

An STN mixture comprising

ME2N.F

2.00%

Clearing point:

+90.0° C.

ME3N.F

3.00%

Δn:

+0.1407

ME4.N.F

6.00%

Twist:

240°

PCH-3N.F.F

15.00%

V

10

:

1.56 V

PCH-3

19.00%

V

90

/V

10

:

1.039

CVCP-V-O1

4.00%

d · Δn:

0.85 μm

CVCP-1V-O1

4.00%

CVCP-V-1

16.00%

CVCP-V2-1

16.00%

CCG-V-F

6.00%

PPTUI-3-2

9.00%

Example 48

An STN mixture comprising

ME2N.F

8.00%

Clearing point:

+95.0° C.

ME3N.F

8.00%

Δn:

+0.1378

ME4.N.F

16.00%

Twist:

240°

PCH-3N.F.F

2.00%

V

10

:

1.33 V

PCH-3

10.00%

V

90

/V

10

:

1.036

PCH-301

6.00%

d · Δn:

0.85 μm

CCG-V-F

9.00%

CCP-V-1

16.00%

CVCP-V-O1

5.00%

CVCP-1V-O1

5.00%

CVCP-V-1

5.00%

CPTP-301

2.00%

CBC-33F

4.00%

CBC-53F

4.00%

Example 49

An STN mixture comprising

ME2N.F

5.00%

Clearing point:

+77.0° C.

ME3N.F

5.00%

Δn:

+0.1421

ME4.N.F

6.00%

Twist:

240°

PCH-3N.F.F

17.00%

V

10

:

1.37 V

PCH-3

9.00%

V

90

/V

10

:

1.051

CC-3-V1

8.00%

d · Δn:

0.85 μm

CCG-V-F

10.00%

CCP-V-1

13.50%

CVCP-V-O1

5.00%

CVCP-1V-O1

5.00%

PTP-102

5.50%

PTP-201

3.00%

CPTP-301

5.50%

CPTP-302

2.50%

Example 50

An STN mixture comprising

ME2N.F

5.00%

Clearing point:

+77.0° C.

ME3N.F

5.00%

Δn:

+0.1440

ME4.N.F

6.00%

Twist:

240°

PCH-3N.F.F

17.00%

V

10

:

1.38 V

PCH-3

9.00%

V

90

/V

10

:

1.045

CCG-V-F

10.00%

d · Δn:

0.85 μm

CVC-3-V

5.00%

CVC-3-V1

5.00%

CVCP-1V-1

5.00%

CVCP-V-O1

5.00%

CVCP-1V-O1

5.00%

PTP-102

5.50%

PTP-201

3.00%

CPTP-301

5.50%

CPTP-302

4.00%

CVCP-V-1

5.00%

Example 51

An STN mixture comprising

ME2N.F

2.50%

Clearing point:

+122.0° C.

ME3N.F

3.50%

Δn:

+0.1446

ME4.N.F

8.50%

Twist:

240°

CC-5-V

13.50%

V

10

:

2.37 V

CCG-V-F

15.00%

V

90

/V

10

:

1.043

CCP-V-1

15.00%

d · Δn:

0.85 μm

CCP-V2-1

15.00%

CVCP-V-1

4.50%

CVCP-1V-1

4.00%

CVCP-1V-O1

4.50%

PPTUI-3-2

14.00%

Example 52

An STN mixture comprising

ME2N.F

2.50%

Clearing point:

+118.0° C.

ME3N.F

3.50%

Δn:

+0.1405

ME4.N.F

9.00%

Twist:

240°

CC-5-V

15.00%

V

10

:

2.31 V

CCG-V-F

16.00%

V

90

/V

10

:

1.051

CCP-V-1

15.50%

d · Δn:

0.85 μm

COP-V2-1

15.50%

CVCP-V-1

5.00%

CVCP-1V-1

5.00%

PPTUI-3-2

13.00%

Example 53

An STN mixture comprising

ME2N.F

4.00%

Clearing point:

+95.0° C.

ME3N.F

4.00%

Δn:

+0.1715

ME4.N.F

10.00%

Twist:

240°

PCH-3N.F.F

19.00%

V

10

:

1.43 V

CC-5-V

11.00%

V

90

/V

10

:

1.076

CVCP-1V-O1

4.00%

d · Δn:

0.85 μm

CVCP-1V-1

4.00%

CCP-V-1

13.00%

CBC-33F

5.00%

CBC-53F

4.00%

PPTUI-3-2

22.00%

Example 54

An STN mixture comprising

ME2N.F

4.00%

Clearing point:

+97.0° C.

ME3N.F

4.00%

Δn:

+0.1733

ME4.N.F

10.00%

Twist:

240°

PCH-3N.F.F

18.00%

V

10

:

1.44 V

CC-5-V

11.50%

V

90

/V

10

:

1.069

CVCP-1V-O1

4.00%

d · Δn:

0.85 μm

CVCP-1V-1

4.00%

CCP-V-1

13.00%

CBC-33F

5.00%

CBC-53F

4.00%

PPTUI-3-2

22.50%

Example 55

An STN mixture comprising

ME2N.F

4.00%

Clearing point:

+97.0° C.

ME3N.F

4.00%

Δn:

+0.1735

ME4.N.F

10.00%

Twist:

240°

PCH-3N.F.F

18.00%

V

10

:

1.46 V

CC-5-V

11.00%

V

90

/V

10

:

1.073

CVCP-1V-O1

4.00%

d · Δn:

0.85 μm

CVCP-1V-1

4.00%

CCP-V-1

13.50%

CBC-33F

5.00%

CBC-53F

4.00%

PPTUI-3-2

22.50%

Example 56

An STN mixture comprising

ME2N.F

4.00%

Clearing point:

+97.0° C.

ME3N.F

4.00%

Δn:

+0.1732

ME4.N.F

10.00%

Twist:

240°

PCH-3N.F.F

18.00%

V

10

:

1.46 V

CC-5-V

11.00%

V

90

/V

10

:

1.073

CVCP-1V-O1

4.00%

d · Δn:

0.85 μm

CVCP-1V-1

4.00%

CCP-V-1

12.50%

CBC-33F

5.00%

CBC-53F

5.00%

PPTUI-3-2

22.50%

Example 57

An STN mixture comprising

PCH-3N.F.F

19.00%

Clearing point:

+95.0° C.

ME2N.F

4.00%

Δn:

+0.1417

ME3N.F

4.00%

Twist:

240°

ME4.N.F

10.50%

V

10

:

1.46 V

CC-3-V1

7.00%

V

90

/V

10

:

1.038

CVCP-1V-O1

4.50%

d · Δn:

0.85 μm

CVCP-V-O1

4.50%

CVCP-1V-1

4.50%

CCP-V-1

16.00%

CCP-V2-1

16.00%

PPTUI-3-2

10.00%

Claims

1. A supertwist liquid-crystal display comprising:two outer plates which, together with a frame, form a cell, a nematic liquid-crystal mixture of positive dielectric anisotropy which is present in the cell, electrode layers with alignment layers on the insides of the outer plates, a pre-tilt angle between the longitudinal axis of the molecules at the surface of the outer plates and the outer plates of from about 0 degrees to 30 degrees, and a twist angle of the liquid-crystal mixture in the cell from alignment layer to alignment layer with a value of from 22.5 ° to 600°, wherein the nematic liquid-crystal mixture comprises: a) 15-90% by weight of a liquid-crystalline component A consisting of one or more compounds having a dielectric anisotropy of greater than +1.5; b) 0-60% by weight of a liquid-crystalline component B consisting of one or more compounds having a dielectric anisotropy of between −1.5 and +1.5; c) 0-20% by weight of a liquid-crystalline component D consisting of one or more compounds having a dielectric anisotropy of below −1.5, and d) optionally, an optically active component C in such an amount that the ratio between the layer thickness (separation of the outer plates) and the natural pitch of the chiral nematic liquid-crystal mixture is from about 0.2 to 1.3, wherein the liquid-crystal mixture comprises at least one compound of the formula IA in which Rais H or an alkyl group having 1 to 7 carbon atoms,Rbis an alkyl or alkoxy group having 1 to 10 carbon atoms or analkenyl or alkenyloxy group having 2 to 10 carbon atoms,andnis 0, 1 or 2,and simultaneously comprises at least one compound of the formulae IB1 to IB4: in whichRcis H or an alkyl group having 1 to 7 carbon atoms,Y1is H or F,andpis 0, 1 or 2.
2. A liquid-crystal display according to claim 1, wherein the liquid-crystal mixture comprises at least one compound of the formula IA in which Rb is a straight-chain alkoxy group having 1 to 7 carbon atoms.
3. A liquid-crystal display according to claim 1, wherein the liquid-crystal mixture further comprises at least one compound of at least one of the following formulae IB5 to IB7: in which Rc, Y1, and p are as defined in claim 1,Reis an alkyl or alkoxy group having 1 to 7 carbon atoms, andRfis an alkenyl group having 2 to 7 carbon atoms.
4. A liquid-crystal display according to claim 1, wherein Component A additionally comprises at least one compound of the formulae II and/or III. in whichRis an alkyl, alkoxy or alkenyl group having 1 to 12 carbon atoms, in which, in addition, one or two non-adjacent CH2 groups are optionally replaced by —O—, —CH═CH—, —CO—, —OCO— or —COO— in such a way that O atoms are not linked directly to one another,are each, independently of one anotherL1 to L6are each, independently of one another, H or F,Z1is —COO—, —CH2CH2— or a single bond,Z2is —CH2CH2—, —COO—, —C≡C— or a single bond,Qis —CF2—, —CHF—, —OCF2—, —OCHF— or a single bond,Yis F or Cl,ais 1 or 2, andbis 0 or 1,where compounds of the formulae IB1 to IB4 are excluded from the scope of the formula III.
5. A liquid-crystal display according to claim 1, wherein Component A comprises at least one compound of at least one of the following formulae: in which R is an alkyl, alkoxy or alkenyl group having 1 to 12 carbon atoms, in which, in addition, one or two non-adjacent CH2 groups are optionally replaced by —O—, —CH═CH—, —CO—, —OCO— or —COO— in such a way that O atoms are not linked directly to one another, and L1, L2 and L3 are each independently of one another H or F.
6. A liquid-crystal display according to claim 1, wherein Component A comprises one or more compounds of the following formula: in which R3 is alkyl or alkoxy having 1 to 7 carbon atoms.
7. A liquid-crystal display according to claim 1, wherein Component A comprises one or more compounds of at least one of the following formulae: in which L1 to L4 are H or F, Q—Y is F, Cl or OCF3, and R1 is an alkyl, alkoxy or alkenyl group having 1 to 12 carbon atoms, in which, in addition, one or two non-adjacent CH2 groups are optionally replaced by —O—, —CH═CH—, —CO—, —OCO— or —COO— in such a way that O atoms are not linked directly to one another.
8. A liquid-crystal display according to claim 1, wherein Component B comprises one or more compounds selected from the group consisting of compounds of the formulae T2a to T2e: in which R1 and R2 are an alkyl, alkoxy or alkenyl group having 1 to 12 carbon atoms, in which, in addition, one or two non-adjacent CH2 groups are optionally replaced by —O—, —CH═CH—, —CO—, —OCO— or —COO— in such a way that O atoms are not linked directly to one another, and one, two or three of the radicals L1 to L6 are F and the others are H, where L1 and L2 or L3 and L4 or L5 and L6 are not both simultaneously F.
9. A liquid-crystal display according to claim 1, wherein Component B comprises one or more compounds selected from the group consisting of compounds of the formulae T3a to T3e: in which R1 and R2 are an alkyl, alkoxy or alkenyl group having 1 to 12 carbon atoms, in which, in addition, one or two non-adjacent CH2 groups are optionally replaced by —O—, —CH═CH—, —CO—, —OCO— or —COO— in such a way that O atoms are not linked directly to one another, and Z4 is —CO—O—, —CH2CH2— or a single bond.
10. A liquid-crystal display according to claim 1, wherein Component B additionally comprises one or more compounds of at least one of the formulae IV25 to IV31: in which R1 and R2 are each, independently of one another, are an alkyl, alkoxy or alkenyl group having 1 to 12 carbon atoms, in which, in addition, one or two non-adjacent CH2 groups are optionally replaced by —O—, —CH═CH—, —CO—, —OCO— or —COO— in such a way that O atoms are not linked directly to one another, and L is H or F.
11. A liquid-crystal display according to claim 1, wherein Component B additionally comprises one or more compounds of at least one of the formulae IV1 to IV24: in which R1 and R2 are each, independently of one another, are is an alkyl, alkoxy or alkenyl group having 1 to 12 carbon atoms, in which, in addition, one or two non-adjacent CH2 groups are optionally replaced by —O—, —CH═CH—, —CO—, —OCO— or —COO— in such a way that O atoms are not linked directly to one another, and R3 and R4 are an alkyl or alkoxy group having 1 to 7 carbon atoms.
12. A liquid-crystal mixture comprising:a) 15-90% by weight of a liquid-crystalline component A consisting of one or more compounds having a dielectric anisotropy of greater than +1.5; b) 0-60% by weight of a liquid-crystalline component B consisting of one or more compounds having a dielectric anisotropy of between −1.5 and +1.5; c) 0-20% by weight of a liquid-crystalline component D consisting of one or more compounds having a dielectric anisotropy of below −1.5, and d) optionally, an optically active component C in such an amount that the ratio between the layer thickness (separation of the outer plates) and the natural pitch of the chiral nematic liquid-crystal mixture is from about 0.2 to 1.3, and further comprising at least one compound of the formula IA in whichRais H or an alkyl group having 1 to 7 carbon atoms,Rbis an alkyl or alkoxy group having 1 to 10 carbon atoms or analkenyl or alkenyloxy group having 2 to 10 carbon atoms,andnis 0, 1 or 2and simultaneously comprises at least one compound of the formula IB in whichRcis H or an alkyl group having 1 to 7 carbon atoms,Rdis F, OCF3, OCHF2, an alkyl or alkoxy group having 1 to 7carbon atoms or an alkenyl group having 2 to 7 carbon atoms,Y1 and Y2,independently of one another, are H or F,qis 0 or 1andpis 0, 1 or 2.
13. A liquid-crystal display according to claim 3, wherein Component A additionally comprises at least one compound of the formulae II and/or III: in whichRis an alkyl, alkoxy or alkenyl group having 1 to 12 carbon atoms, in which, in addition, one or two non-adjacent CH2 groups are optionally replaced by —O—, —CH═CH—, —CO—, —OCO— or —COO— in such a way that O atoms are not linked directly to one another,are each, independently of one anotherL1 to L6are each, independently of one another, H or F,Z1is —COO—, —CH2CH2— or a single bond,Z2is —CH2CH2—, —COO—, —C≡C— or a single bond,Qis —CF2—, —CHF—, —OCF2—, —OCHF— or a single bond,Yis F or Cl,ais 1 or 2, andbis 0 or 1,where compounds of the formulae Ib1 to IB4 are excluded from the scope of the formula III.
14. A liquid-crystal display according to claim 3, wherein Component A comprises at least one compound of at least one of the following formulae: in which R is an alkyl, alkoxy or alkenyl group having 1 to 12 carbon atoms, in which, in addition, one or two non-adjacent CH2 groups are optionally replaced by —O—, —CH═CH—, —CO—, —OCO— or —COO— in such a way that O atoms are not linked directly to one another, and L1, L2 and L3 are each independently of one another H or F.
15. A liquid-crystal display according to claim 3, wherein Component A comprises one or more compounds of the following formula: in which R3 is alkyl or alkoxy having 1 to 7 carbon atoms.
16. A liquid-crystal display according to claim 3, wherein Component A comprises one or more compounds of at least one of the following formulae: in which L1 to L4 are H or F, Q—Y is F, Cl or OCF3, and R1 is an alkyl, alkoxy or alkenyl group having 1 to 12 carbon atoms, in which, in addition, one or two non-adjacent CH2 groups are optionally replaced by —O—, —CH═CH—, —CO—, —OCO— or —COO— in such a way that O atoms are not linked directly to one another.
17. A liquid-crystal display according to claim 3, wherein Component B comprises one or more compounds selected from the group consisting of compounds of the formulae T2a to T2e: in which R1 and R2 are an alkyl, alkoxy or alkenyl group having 1 to 12 carbon atoms, in which, in addition, one or two non-adjacent CH2 groups are optionally replaced by —O—, —CH═CH—, —CO—, —OCO— or —COO— in such a way that O atoms are not linked directly to one another, and one, two or three of the radicals L1 to L6 are F and the others are H, where L1 and L2 or L3 and L4 or L5 and L6 are not both simultaneously F.
18. A supertwist liquid-crystal display comprising:two outer plates which, together with a frame, form a cell, a nematic liquid-crystal mixture of positive dielectric anisotropy which is present in the cell, electrode layers with alignment layers on the insides of the outer plates, a pre-tilt angle between the longitudinal axis of the molecules at the surface of the outer plates and the outer plates of from about 0 degrees to 30 degrees, and a twist angle of the liquid-crystal mixture in the cell from alignment layer to alignment layer with a value of from 22.5° to 600°, wherein the nematic liquid-crystal mixture comprises: a) 15-90% by weight of a liquid-crystalline component A consisting of one or more compounds having a dielectric anisotropy of greater than +1.5; b) 0-60% by weight of a liquid-crystalline component B consisting of one or more compounds having a dielectric anisotropy of between −1.5 and +1.5; c) 0-20% by weight of a liquid-crystalline component D consisting of one or more compounds having a dielectric anisotropy of below −1.5, and d) optionally, an optically active component C in such an amount that the ratio between the layer thickness (separation of the outer plates) and the natural pitch of the chiral nematic liquid-crystal mixture is from about 0.2 to 1.3, wherein the liquid-crystal mixture comprises at least one compound of the formula IA in which Rais H or an alkyl group having 1 to 7 carbon atoms,Rbis an alkyl or alkoxy group having 1 to 10 carbon atoms or analkenyl or alkenyloxy group having 2 to 10 carbon atoms,andnis 0, 1 or 2;simultaneously comprises at least one compound of the formula IB: in whichRcis H or an alkyl group having 1 to 7 carbon atoms,Rdis F, OCF3, OCHF2, an alkyl or alkoxy group having 1 to 7carbon atoms or an alkenyl group having 2 to 7 carbon atoms,Y1 and Y2,independently of one another, are H or F,qis 0 or 1andpis 0, 1 or 2; and,wherein Component B comprises one or more compounds selected from the group consisting of compounds of the formulae T3a to T3e: in which R1 and R2 are an alkyl, alkoxy or alkenyl group having 1 to 12 carbon atoms, in which, in addition, one or two non-adjacent CH2 groups are optionally replaced by —O—, —CH═CH—, —CO—, —OCO— or —COO— in such a way that O atoms are not linked directly to one another, and Z4 is —CO—O—, —CH2CH2— or a single bond.
19. A supertwist liquid-crystal display comprising:two outer plates which, together with a frame, formn a cell, a nematic liquid-crystal mixture of positive dielectric anisotropy which is present in the cell, electrode layers with alignment layers on the insides of the outer plates, a pre-tilt angle between the longitudinal axis of the molecules at the surface of the outer plates and the outer plates of from about 0 degrees to 30 degrees, and a twist angle of the liquid-crystal mixture in the cell from alignment layer to alignment layer with a value of from 22.5° to 600°, wherein the nematic liquid-crystal mixture comprises: a) 15-90% by weight of a liquid-crystalline component A consisting of one or more compounds having a dielectric anisotropy of greater than +1.5; b) 0-60% by weight of a liquid-crystalline component B consisting of one or more compounds having a dielectric anisotropy of between −1.5 and +1.5; c) 0-20% by weight of a liquid-crystalline component D consisting of one or more compounds having a dielectric anisotropy of below −1.5, and d) optionally, an optically active component C in such an amount that the ratio between the layer thickness (separation of the outer plates) and the natural pitch of the chiral nematic liquid-crystal mixture is from about 0.2 to 1.3, wherein the liquid-crystal mixture comprises at least one compound of the formula IA in which Ra is H or an alkyl group having 1 to 7 carbon atoms, Rb is an alkyl or alkoxy group having 1 to 10 carbon atoms or an alkenyl or alkenyloxy group having 2 to 10 carbon atoms, and n is 0, 1 or 2; simultaneously comprises at least one compound of the formula IB: in whichRcis H or an alkyl group having 1 to 7 carbon atoms,Rdis F, OCF3, OCHF2, an alkyl or alkoxy group having 1 to 7carbon atoms or an alkenyl group having 2 to 7 carbon atoms,Y1 and Y2,independently of one another, are H or F,qis 0 or 1andpis 0, 1 or 2; and,wherein Component B additionally comprises one or more compounds of at least one of the formulae IV25 to IV31: in which R1 and R2 are each, independently of one another, are an alkyl, alkoxy or alkenyl group having 1 to 12 carbon atoms, in which, in addition, one or two non-adjacent CH2 groups are optionally replaced by —O—, —CH═CH—, —CO—, —OCO— or —COO— in such a way that O atoms are not linked directly to one another, and L is H or F.
20. A liquid-crystal display according to claim 18, wherein Component A additionally comprises at least one compound of the formulae II and/or III: in whichRis an alkyl, alkoxy or alkenyl group having 1 to 12 carbon atoms, in which, in addition, one or two non-adjacent CH2 groups are optionally replaced by —O—, —CH═CH—, —CO—, —OCO— or —COO— in such a way that O atoms are not linked directly to one another,are each, independently of one anotherL1 to L6are each, independently of one another, H or F,Z1is —COO—, —CH2CH2— or a single bond,Z2is —CH2CH2—, —COO—, —C≡C— or a single bond,Qis —CF2—, —CHF—, —OCF2—, —OCHF— or a single bond,Yis F or Cl,ais 1 or 2, andbis 0 or 1,where compounds of the formulae IB are excluded from the scope of the formula III.
21. A liquid-crystal display according to claim 18, wherein Component A comprises at least one compound of at least one of the following formulae: in which R is an alkyl, alkoxy or alkenyl group having 1 to 12 carbon atoms, in which, in addition, one or two non-adjacent CH2 groups are optionally replaced by —O—, —CH═CH—, —CO—, —OCO— or —COO— in such a way that O atoms are not linked directly to one another, and L1, L2 and L3 are each independently of one another H or F.
22. A liquid-crystal display according to claim 18, wherein Component A comprises one or more compounds of the following formula: in which R3 is alkyl or alkoxy having 1 to 7 carbon atoms.
23. A liquid-crystal display according to claim 18, wherein Component A comprises one or more compounds of at least one of the following formulae: in which L1 to L4 are H or F, Q—Y is F, Cl or OCF3, and R1 is an alkyl, alkoxy or alkenyl group having 1 to 12 carbon atoms, in which, in addition, one or two non-adjacent CH2 groups are optionally replaced by —O—, —CH═CH—, —CO—, —OCO— or —COO— in such a way that O atoms are not linked directly to one another.
24. A liquid-crystal display according to claim 18, wherein Component B comprises one or more compounds selected from the group consisting of compounds of the formulae T2a to T2e: in which R1 and R2 are an alkyl, alkoxy or alkenyl group having 1 to 12 carbon atoms, in which, in addition, one or two non-adjacent CH2 groups are optionally replaced by —O—, —CH═CH—, —CO—, —OCO— or —COO— in such a way that O atoms are not linked directly to one another, and one, two or three of the radicals L1 to L6 are F and the others are H, where L1 and L2 or L3 and L4 or L5 and L6 are not both simultaneously F.
25. A liquid-crystal display according to claim 19, wherein Component A additionally comprises at least one compound of the formulae II and/or III: in whichRis an alkyl, alkoxy or alkenyl group having 1 to 12 carbon atoms, in which, in addition, one or two non-adjacent CH2 groups are optionally replaced by —O—, —CH═CH—, —CO—, —OCO— or —COO— in such a way that O atoms are not linked directly to one another,are each, independently of one anotherL1 to L6are each, independently of one another, H or F,Z1is —COO—, —CH2CH2— or a single bond,Z2is —CH2CH2—, —COO—, —C≡C— or a single bond,Qis —CF2—, —CHF—, —OCF2—, —OCHF— or a single bond,Yis F or Cl,ais 1 or 2, andbis 0 or 1,where compounds of the IB are excluded from the scope of the formula III.
26. A liquid-crystal display according to claim 19, wherein Component A comprises at least one compound of at least one of the following formulae: in which R is an alkyl, alkoxy or alkenyl group having 1 to 12 carbon atoms, in which, in addition, one or two non-adjacent CH2 groups are optionally replaced by —O—, —CH═CH—, —CO—, —OCO— or —COO— in such a way that O atoms are not linked directly to one another, and L1, L2 and L3 are each independently of one another H or F.
27. A liquid-crystal display according to claim 19, wherein Component A comprises one or more compounds of the following formula: in which R3 is alkyl or alkoxy having 1 to 7 carbon atoms.
28. A liquid-crystal display according to claim 19, wherein Component A comprises one or more compounds of at least one of the following formulae: in which L1 to L4 are H or F, Q—Y is F, Cl or OCF3, and R1 is an alkyl, alkoxy or alkenyl group having 1 to 12 carbon atoms, in which, in addition, one or two non-adjacent CH2 groups are optionally replaced by —O—, —CH═CH—, —CO—, —OCO— or —COO— in such a way that O atoms are not linked directly to one another.
29. A liquid-crystal display according to claim 19, wherein Component B comprises one or more compounds selected from the group consisting of compounds of the formulae T2a to T2e: in which R1 and R2 are an alkyl, alkoxy or alkenyl group having 1 to 12 carbon atoms, in which, in addition, one or two non-adjacent CH2 groups are optionally replaced by —O—, —CH═CH—, —CO—, —OCO— or —COO— in such a way that O atoms are not linked directly to one another, and one, two or three of the radicals L1 to L6 are F and the others are H, where L1 and L2 or L3 and L4 or L5 and L6 are not both simultaneously F.

Priority Claims (1)

Number	Date	Country	Kind
199 20 405	May 1999	DE

US Referenced Citations (3)

Number	Name	Date	Kind
5679285	Bartmann et al.	Oct 1997	A
6017469	Reiffenrath et al.	Jan 2000	A
6174572	Hirschmann et al.	Jan 2001	B1

Supertwist liquid-crystal displays and liquid-crystal mixtures therefor

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CPC

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Abstract

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Priority Claims (1)

US Referenced Citations (3)