The present invention relates to an absorbent surface cleaning pad, such as a floor cleaning pad, and to a method for fabricating the surface cleaning pad in such a way as to provide zoned absorbency.
Conventional floor mops comprise a handle rotatably connected to a mop head and a disposable absorbent cleaning sheet coupled to the mop head. One side of the disposable absorbent cleaning sheet is placed in direct contact with a surface to be cleaned and the opposing side of the cleaning sheet is coupled to the mop head. The cleaning sheet absorbs and retains fluids, and loosens and traps dirt particles on the cleaning surface.
The cleaning sheet may comprise an absorbent portion that includes superabsorbent polymer (SAP) particles. The SAP particles can escape from the absorbent portion during manufacture, shipment, and normal use conditions. This phenomenon is commonly referred to as particle shake-out. A reduction in the amount or volume of SAP particles within the cleaning sheet hinders the performance and decreases the absorbency rating of the cleaning sheet.
Attempts have been made to overcome this problem in other fields such as the field of baby diapers, adult incontinence products, sanitary napkins and the like. For example, an absorbent structure for such products is disclosed in U.S. Pat. No. 6,562,742, which illustrates a diaper absorbent body with SAP particles placed in discrete locations or zones within the structure. According to the disclosure of U.S. Pat. No. 6,562,742, which is incorporated herein by reference in its entirety, superabsorbent polymer particles are placed in at least one strata of an upper ply in longitudinal discrete lanes along the length of the core, and the lanes are separated by adjacent lanes including fibers and a binder. Such a discrete placement of SAP particles is disclosed to allow for better containment of the particles, facilitate flow of liquid in the Z-direction because of the presence of areas with little or no SAP, and allow for easier flow and wicking of the fluid along the length of the core (x-direction). The areas with little or no SAP particles may be additionally densified to improve integrity and create higher capillary tension within smaller pores.
Nevertheless, there continues to be a need for an improved absorbent cleaning pad, such as a floor cleaning pad, and an improved method for fabricating the cleaning pad in such a way as to provide zoned absorbency.
According to one aspect of the invention, a surface cleaning pad is provided having a pad body with a cleansing surface configured for contact with a surface to be cleaned and an opposed surface configured to be coupled to a cleaning implement. The cleansing surface and the opposed surface together define a thickness of the pad body. The surface cleaning pad also has superabsorbent polymer particles maintained within a zone of the pad body. The zone of the pad body occupies the thickness of the pad body and an area that is contiguous yet less than that of the cleansing surface.
According to another aspect of the invention, a method is provided for forming a surface cleaning pad body having a matrix web of binder fibers and superabsorbent polymer particles. The method includes depositing a mass of binder fibers onto a conveyor. All but a selected area of the mass of binder fibers is shielded, and superabsorbent polymer particles are deposited onto the selected area of the mass of binder fibers so as to disburse superabsorbent polymer particles throughout a thickness of the mass of binder fibers. The mass of binder fibers is formed into a web structure that substantially contains the superabsorbent polymer particles, thereby providing a cleaning pad body with superabsorbent polymer particles substantially contained in a zone of the mass of binder fibers that occupies the thickness of the mass of binder fibers and the selected area. An attachment device is applied to the cleaning pad body, thereby configuring the pad body for attachment to a cleaning implement.
According to yet another aspect of the invention, a method is provided for forming cleaning pad bodies. The method includes forming a substrate of fibers. Superabsorbent polymer particles are applied to the substrate in zones extending along the substrate separated by a gap extending along the substrate. The substrate is parted along the gap to form substrate portions each having an edge portion substantially devoid of superabsorbent polymer particles. The substrate is parted substantially perpendicular to the gap to form cleaning pad bodies.
Exemplary embodiments of the invention will be described with reference to the drawings, of which:
a is a bottom view of an absorbent cleaning pad in accordance with another exemplary embodiment of the present invention;
b is a bottom view of an absorbent cleaning pad in accordance with yet another exemplary embodiment of the present invention;
c is a bottom view of an absorbent cleaning pad in accordance with still another exemplary embodiment of the present invention;
Although the invention is illustrated and described herein with reference to specific embodiments, the invention is not intended to be limited to the details shown. Rather, various modifications may be made in the details within the scope and range of equivalents of the claims and without departing from the invention. Also, the embodiments selected for illustration in the figures are not shown to scale and are not limited to the proportions shown.
As used herein, the term “superabsorbent polymer (SAP) particle” refers to any absorbent material having a g/g capacity for water of at least about 20 g/g, when measured under a confining pressure of 0.3 psi. Non-limiting examples of suitable superabsorbent materials include water insoluble, water-swellable superabsorbent gelling polymers which are described in U.S. application Ser. No. 09/831,480, the disclosure of which is incorporated herein by reference in its entirety.
Referring to the overall structure of one exemplary embodiment,
More specifically, the exemplary absorbent cleaning pad (or sheet) 110 is provided with an airlaid composite 120. Two folded dirt entrapment members 125 are adhered to a cleaning side 152 of the airlaid composite 120 by an adhesive 130 and extend along the length of the airlaid composite 120. A barrier layer 140 is adhered to an opposing attachment side 155 of the airlaid composite 120 and is folded around the width-wise sides 124 of the airlaid composite 120, thereby enclosing the width-wise sides 124 of the airlaid composite 120. Two attachment members 145 are adhered to the barrier layer 140 by an adhesive 130.
The airlaid composite 120 of the exemplary embodiment absorbs and retains fluids and/or other matter residing on a cleaning surface. The cleaning side 152 of the cleaning pad 110 is in direct contact with the floor surface, and the opposing attachment side 155 of the absorbent cleaning pad 110 is in contact with a cleaning implement such as a mop head (not shown). The dirt entrapment members 125 serve to facilitate the removal of soils from the surface being cleaned by contacting and trapping larger soil particles. The barrier layer 140 substantially prevents fluid from passing from the airlaid composite 120 to the cleaning implement, to keep the cleaning implement substantially free of fluid. The barrier layer 140 also substantially prevents absorbent particles within the airlaid composite 120 from escaping out of the exposed width-wise sides 124 of the airlaid composite 120.
The attachment members 145 provide a single attachment mechanism that can be used to temporarily couple the absorbent cleaning pad 110 to a cleaning implement such as a mop head. In this exemplary embodiment, the attachment members 145 are composed of loop fastening material available from Velcro USA Inc. of Manchester, N.H., USA. Additional benefits and features of attachment mechanisms are disclosed in U.S. application Ser. No. 11/241,438, filed concurrently herewith. The disclosure of U.S. application Ser. No. 11/241,438 is incorporated herein by reference in its entirety. Also, benefits and features of additional optional components, such as cuff components, are disclosed in U.S. application Ser. No. 11/240,949 and U.S. application Ser. No. 11/241,437, filed concurrently herewith, which are incorporated herein by reference in their entirety.
The exemplary embodiment of the absorbent cleaning pad 110 comprises a unitized airlaid composite 120 having an absorbent core composed of at least binder fibers, absorbent fibers and superabsorbent polymer (SAP) particles 150. The absorbent core should be of sufficient integrity to ensure that the absorbent core does not deform and exhibit discontinuities during its normal use in cleansing a surface. The SAP particles 150 provide the airlaid composite 120 with increased absorbency, while the binder and absorbent fibers form the overall structure of the airlaid composite 120. In this embodiment, the binder fibers are optionally bi-component fibers and the absorbent fibers are optionally cellulosic fibers.
The absorbency portion of the airlaid composite 120 may optionally be composed of pulp fibers, rayon fibers, superabsorbent fibers, a combination of superabsorbent and pulp fibers, a combination of superabsorbent and rayon fibers, a combination of pulp, superabsorbent and rayon fibers, a non-woven web and a in-situ (liquid) superabsorbent, a tissue and in-situ (liquid) superabsorbent, a pulp and in-situ (liquid) superabsorbent, rayon fibers and a in-situ (liquid) superabsorbent, pulp, rayon fibers and a in-situ (liquid) superabsorbent, or a combination thereof of any of the above. The absorbent core component is an essentially hydrophilic material capable of absorbing and retaining fluids. The absorbent component may be composed of fibers, powders, and polymeric binders, any of which may be natural or synthetic.
The exposed sides of the airlaid composite 120 may be sealed or covered to substantially limit the SAP particles 150 from escaping out of the exposed sides of the airlaid composite 120. According to exemplary embodiments of this invention, however, to prevent the escapement of the SAP particles 150, the SAP particles may be concentrated or zoned an adequate distance away from one or more of the exposed sides of the airlaid composite 120. The matrix web of binder fibers would substantially inhibit the zoned SAP particles from migrating a significant distance toward the exposed sides of the airlaid composite 120. An example of a zoned SAP region is illustrated in
Additional benefits and features of an airlaid composite construction are disclosed in U.S. application Ser. No. 11/240,929, filed concurrently herewith. The disclosure of U.S. application Ser. No. 11/240,929 is incorporated herein by reference in its entirety.
In addition to airlaid composites, other absorbent pad body materials, structures and/or processes are contemplated as well. For example, in another exemplary embodiment an absorbent core prepared by expanding a polymer tow, disclosed in International Publication No. WO 2004/017883, is also contemplated for use as an absorbent pad. The disclosure of International Publication No. WO 2004/017883 is incorporated herein by reference in its entirety. In this exemplary embodiment, the absorbent core comprises a plurality of filaments in the form of an expanded tow, and a layer comprising a liquid superabsorbent material on surfaces of the filaments. The liquid superabsorbent polymer may be applied to the expanded tow, for example, by spraying or by application using a gravure roller. In this embodiment, the liquid superabsorbent polymer is applied to a portion(s) of the width and/or the length of the expanded tow.
Referring now to
The SAP particles 150 are also substantially prevented from escaping through the cleaning side 152 and the attachment side 155 of the airlaid composite. The dense web of binder fibers at the cleaning side 152 and the attachment side 155 of the airlaid composite substantially prevents the SAP particles 150 from escaping. In addition, the barrier layer 140 substantially prevents the SAP particles 150 from escaping out of the attachment side 155 of the airlaid composite 120, as illustrated in
The exemplary embodiment provides several advantages. The zoned SAP particles reduce particle shake out, gel blocking, and manufacturing costs and promote efficient fluid absorption throughout the airlaid composite. SAP particle shake-out hinders the performance of the cleaning pad and degrades the cleaning pad's absorbency rating. By virtue of the zoned SAP, the exemplary cleaning pad 110 can retain a greater number of SAP particles within the airlaid composite.
The discrete placement of SAP particles also facilitates the flow of fluid along the regions of the cleaning pad devoid of SAP particles. The regions without SAP particles promote flow and wicking of fluid along the entire length and width of the exemplary airlaid composite. Therefore, the discrete placement of SAP particles promotes the utilization of the entire airlaid composite for absorption.
The discrete placement of SAP particles also substantially reduces gel blocking within the airlaid composite, thereby improving the cleaning pad's ability to absorb and retain fluid. Gel blocking leads to the inhibition of fluid flow throughout the entire airlaid composite, thereby reducing the absorbency rating of the cleaning pad. In other words, the airlaid composite cannot efficiently absorb fluid if too many SAP particles are positioned or concentrated on the cleaning surface of the airlaid composite, as the swelled SAP particles prevent the fluid from traveling in the z-direction (i.e., along the thickness of the airlaid composite). The discrete placement of SAP particles promotes uniform fluid absorption throughout the exemplary airlaid composite.
From the manufacturing perspective, by virtue of the SAP zone 150 illustrated in
Another exemplary embodiment of a cleaning pad 510 is illustrated in
By virtue of the zoned SAP 550, the barrier layer (not shown) of the exemplary embodiment illustrated in
Another exemplary embodiment of a cleaning pad 510 is illustrated in
Another exemplary embodiment of a cleaning pad 510 is illustrated in
Alternatively, the cleaning pad embodiment shown in
Although only one example of an airlaid composite forming system is illustrated, this invention is not limited to the particular airlaid composite forming system selected for illustration in the Figures, and this invention is not limited to an absorbent pad having an airlaid structure. Other airlaid forming systems and other pad-producing processes are contemplated as well.
The airlaid composite forming system 600 comprises a moving perforated forming wire 602, which acts as a conveyor, with forming head equipment mounted thereabove. In the orientation illustrated in
Forming heads 604 and 606 each receives a flow of an air fluidized fiber material (e.g., binder fibers, wood pulp, other fibrous materials, or combination thereof) via supply channels 608. A suction source 614 mounted beneath the perforated moving wire 602, draws air downwardly through the perforated moving wire 602. In one embodiment, the binder fiber material is distributed and compacted (by the air flow) over the width of the wire 602 to form an light web layer on the surface of the wire 602. A second forming head (not shown) is provided to distribute a second web layer 616 composed of a mixture of binder fibers and cellulosic fibers onto the light web layer.
The SAP particles are introduced into the particle dispenser 620 through a tube 618. The particle dispenser 620 is configured to direct (e.g., spray, sprinkle, release, etc.) the SAP particles onto the perforated moving wire 602 above the web layer 616. The SAP particles are either distributed over a portion of the width and/or length of the web layer 616 or distributed over the entire web layer 616. The SAP particles blend and disseminate through the web layer 616 and are thereby maintained throughout the entire thickness of the airlaid composite.
A third forming head 606 is provided to distribute another web layer 622 of binder and/or cellulosic fibers over the SAP particles. Although only two forming heads are illustrated, more forming heads may be required to distribute additional layers of binder fiber or cellulosic fiber. Thereafter, the web layers are heated for a period of time until the binder fibers melt together to form a web-like structure, i.e., an airlaid composite.
In functional terms, the first light web layer including binder fibers is oriented toward the cleaning surface and provides structure to the airlaid composite. The second web layer 616 including binder fibers and cellulosic fibers is maintained over the first light web layer and provides structure and absorbency to the airlaid composite. The SAP particles are maintained over the second web layer 616 to provide additional absorbency to the airlaid composite. The third web layer 622 including binder fibers and cellulosic fibers are maintained over the SAP particles and is oriented toward the cleaning implement. The third web layer 622 provides structure and absorbency to the airlaid composite. The web layers collectively form an airlaid composite according to one embodiment.
Although not shown, in yet another exemplary embodiment, a preformed sheet comprising SAP particles may be positioned above the light web layer 616, as an alternative to using the particle dispenser 620. The preformed sheet may be of any size equal to or smaller than the light web layer 616.
Still referring to the airlaid composite forming system illustrated in
In still another exemplary embodiment and still referring to
Still referring to the airlaid composite forming system illustrated in
As an alternative to configuring the particle dispenser 620 to distribute the SAP particles over the segment “F” of the web layer 616, a screen may be positioned above the web layer 616 to limit the placement of the SAP particle zone 550 to a segment “F” of the web layer 616. In this exemplary embodiment, the particle dispenser 620 is configured to distribute the SAP particles over the entire web layer 616, although the screen limits the distribution of the SAP particles to the segment “F” above the web layer 616.
While preferred embodiments of the invention have been shown and described herein, it will be understood that such embodiments are provided by way of example only. Numerous variations, changes and substitutions will occur to those skilled in the art without departing from the spirit of the invention. Accordingly, it is intended that the appended claims cover all such variations as fall within the spirit and scope of the invention. Also, the embodiments selected for illustration in the figures are not shown to scale and are not limited to the proportions shown.
Number | Name | Date | Kind |
---|---|---|---|
869842 | Hill | Oct 1907 | A |
916755 | Moseke | Mar 1909 | A |
1002268 | Hayden | Sep 1911 | A |
1205979 | Dohm | Nov 1916 | A |
1742318 | Newton et al. | Jan 1930 | A |
2136827 | Schur | Nov 1938 | A |
2301505 | Bates | Nov 1942 | A |
2478148 | Wilson et al. | Aug 1949 | A |
2581069 | Bertolet, Jr. | Jan 1952 | A |
2733468 | Haber | Feb 1956 | A |
2739334 | Hardey | Mar 1956 | A |
2755498 | Park | Jul 1956 | A |
2764774 | Belsky et al. | Oct 1956 | A |
2777148 | Belsky et al. | Jan 1957 | A |
2816313 | Beck et al. | Dec 1957 | A |
2853730 | Belsky et al. | Sep 1958 | A |
2916759 | Smith | Dec 1959 | A |
2958146 | Van Dusen, Jr. et al. | Nov 1960 | A |
3012264 | Nash | Dec 1961 | A |
3015834 | Marrinson et al. | Jan 1962 | A |
3025202 | Morgan et al. | Mar 1962 | A |
3077627 | Ashworth | Feb 1963 | A |
3099855 | Nash | Aug 1963 | A |
3196475 | Brown | Jul 1965 | A |
3199136 | George | Aug 1965 | A |
3221356 | Schirmer | Dec 1965 | A |
D205500 | Deitel et al. | Aug 1966 | S |
3271231 | Moggio et al. | Sep 1966 | A |
3362037 | Griffin | Jan 1968 | A |
3395415 | Leland | Aug 1968 | A |
3395416 | Hughes | Aug 1968 | A |
3395418 | Malmo | Aug 1968 | A |
3412418 | Griffin | Nov 1968 | A |
3425085 | Moss | Feb 1969 | A |
3449784 | Moss | Jun 1969 | A |
3473184 | Buck, Jr. | Oct 1969 | A |
3501813 | Lee et al. | Mar 1970 | A |
3528076 | Anderson | Sep 1970 | A |
3528120 | Lindstrom | Sep 1970 | A |
3545876 | Leland | Dec 1970 | A |
3581706 | Rasmussen et al. | Jun 1971 | A |
3593359 | Strauss et al. | Jul 1971 | A |
3680170 | Sims | Aug 1972 | A |
3692622 | Dunning | Sep 1972 | A |
3698030 | Lockett | Oct 1972 | A |
3711886 | Strauss | Jan 1973 | A |
3713744 | Sims | Jan 1973 | A |
3717905 | Furbeck | Feb 1973 | A |
3720976 | Bailey | Mar 1973 | A |
3733234 | Dunning | May 1973 | A |
3737938 | Saltzstein | Jun 1973 | A |
3760450 | Griffin et al. | Sep 1973 | A |
3761991 | Moss | Oct 1973 | A |
3764451 | Dunning | Oct 1973 | A |
3776807 | Dunning et al. | Dec 1973 | A |
3792505 | Saltzstein | Feb 1974 | A |
3825381 | Dunning et al. | Jul 1974 | A |
3827100 | Griffin et al. | Aug 1974 | A |
3836346 | Stalego | Sep 1974 | A |
3860002 | Kolbach | Jan 1975 | A |
3877103 | Nash | Apr 1975 | A |
3896518 | Von Post et al. | Jul 1975 | A |
3945736 | Rittenbaum et al. | Mar 1976 | A |
3964213 | Tobey | Jun 1976 | A |
3965519 | Hermann | Jun 1976 | A |
3966519 | Mitchell et al. | Jun 1976 | A |
3973291 | Kolbach | Aug 1976 | A |
3976734 | Dunning et al. | Aug 1976 | A |
3978541 | Gustafsson | Sep 1976 | A |
3991431 | Thielen | Nov 1976 | A |
3991432 | Griffin et al. | Nov 1976 | A |
3996639 | Griffin et al. | Dec 1976 | A |
4007510 | Scoggin, Jr. et al. | Feb 1977 | A |
4016628 | Kolbach | Apr 1977 | A |
4027672 | Karami | Jun 1977 | A |
4032239 | Maupin | Jun 1977 | A |
4070726 | Joffre | Jan 1978 | A |
4071983 | Thielen | Feb 1978 | A |
4074959 | Curry et al. | Feb 1978 | A |
4087506 | Cook et al. | May 1978 | A |
4095007 | Marshall | Jun 1978 | A |
4099288 | Rittenbaum et al. | Jul 1978 | A |
4106153 | Lemelson | Aug 1978 | A |
4114223 | Buchanan | Sep 1978 | A |
4114224 | Disko | Sep 1978 | A |
RE29789 | Kolbach | Oct 1978 | E |
4141772 | Buell | Feb 1979 | A |
4153664 | Sabee | May 1979 | A |
4184224 | Joffre | Jan 1980 | A |
4193751 | Miller | Mar 1980 | A |
4212302 | Karami | Jul 1980 | A |
4213459 | Sigl et al. | Jul 1980 | A |
4217078 | Buell | Aug 1980 | A |
4219899 | Zurawin et al. | Sep 1980 | A |
4223063 | Sabee | Sep 1980 | A |
4225998 | Thielen | Oct 1980 | A |
4252761 | Schoggen et al. | Feb 1981 | A |
4264289 | Day | Apr 1981 | A |
4268340 | Fitzgerald et al. | May 1981 | A |
4351793 | Day | Sep 1982 | A |
4375447 | Chung | Mar 1983 | A |
4375448 | Appel et al. | Mar 1983 | A |
4377230 | Bürkner | Mar 1983 | A |
4388056 | Lee et al. | Jun 1983 | A |
4429001 | Kolpin et al. | Jan 1984 | A |
4435234 | Hunt | Mar 1984 | A |
4516360 | Gringer et al. | May 1985 | A |
4516361 | Gringer | May 1985 | A |
4551191 | Kock et al. | Nov 1985 | A |
4562610 | Davis et al. | Jan 1986 | A |
4564969 | Heinonen | Jan 1986 | A |
4575891 | Valente | Mar 1986 | A |
4583486 | Miller | Apr 1986 | A |
4585448 | Enloe | Apr 1986 | A |
4592708 | Feist et al. | Jun 1986 | A |
4598441 | Stemmler | Jul 1986 | A |
4600458 | Kramer et al. | Jul 1986 | A |
4601938 | Deacon et al. | Jul 1986 | A |
4603069 | Haq et al. | Jul 1986 | A |
4610678 | Weisman et al. | Sep 1986 | A |
D287173 | Libman | Dec 1986 | S |
4640810 | Laursen et al. | Feb 1987 | A |
4650480 | Stemmler | Mar 1987 | A |
4678527 | Ulman | Jul 1987 | A |
4685167 | Murray | Aug 1987 | A |
4685915 | Hasse et al. | Aug 1987 | A |
4698871 | Patkos | Oct 1987 | A |
4712268 | Heinonen | Dec 1987 | A |
4732797 | Johnson et al. | Mar 1988 | A |
4750233 | Swain | Jun 1988 | A |
4761258 | Enloe | Aug 1988 | A |
4764325 | Angstadt | Aug 1988 | A |
4765780 | Angstadt | Aug 1988 | A |
4769267 | Hoyt | Sep 1988 | A |
4769283 | Sipinen et al. | Sep 1988 | A |
4784892 | Storey et al. | Nov 1988 | A |
4793019 | Stima et al. | Dec 1988 | A |
4797310 | Barby et al. | Jan 1989 | A |
4808474 | Sipinen | Feb 1989 | A |
4811449 | Kobayashi | Mar 1989 | A |
4812283 | Farley et al. | Mar 1989 | A |
4813944 | Haney et al. | Mar 1989 | A |
4820579 | Aszman | Apr 1989 | A |
4823427 | Gibbs et al. | Apr 1989 | A |
4834735 | Alemany et al. | May 1989 | A |
4843674 | Jones | Jul 1989 | A |
4852201 | Wundrock et al. | Aug 1989 | A |
4852210 | Krajicek | Aug 1989 | A |
4859388 | Peterson et al. | Aug 1989 | A |
4902544 | Kim et al. | Feb 1990 | A |
4902559 | Eschwey et al. | Feb 1990 | A |
4904440 | Angstadt | Feb 1990 | A |
4908175 | Angstadt | Mar 1990 | A |
4927346 | Kaiser et al. | May 1990 | A |
4927582 | Bryson | May 1990 | A |
4935158 | Aszman et al. | Jun 1990 | A |
4945599 | Flynn | Aug 1990 | A |
D310589 | Paciullo et al. | Sep 1990 | S |
D310901 | Paciullo et al. | Sep 1990 | S |
D310902 | Paciullo et al. | Sep 1990 | S |
D311318 | Ovens | Oct 1990 | S |
4961242 | Kresse et al. | Oct 1990 | A |
4962563 | Bachar | Oct 1990 | A |
4971471 | Sloan | Nov 1990 | A |
4987632 | Rowe et al. | Jan 1991 | A |
4991250 | Young | Feb 1991 | A |
4995133 | Newell | Feb 1991 | A |
5004579 | Wislinski et al. | Apr 1991 | A |
5012544 | Verry | May 1991 | A |
5017324 | Kaiser et al. | May 1991 | A |
5028224 | Pieper et al. | Jul 1991 | A |
5028646 | Miller et al. | Jul 1991 | A |
5029357 | Gootoff et al. | Jul 1991 | A |
5042105 | Buck et al. | Aug 1991 | A |
5044040 | Tetrault | Sep 1991 | A |
5047023 | Berg | Sep 1991 | A |
5064484 | Craig et al. | Nov 1991 | A |
5066527 | Newell | Nov 1991 | A |
5068079 | Gustafsson | Nov 1991 | A |
5071489 | Silvenis et al. | Dec 1991 | A |
5087506 | Palumbo | Feb 1992 | A |
5090832 | Rivera et al. | Feb 1992 | A |
5092699 | Silvenis | Mar 1992 | A |
5094559 | Rivera et al. | Mar 1992 | A |
5102585 | Pieper et al. | Apr 1992 | A |
5115535 | Casademunt Ferre et al. | May 1992 | A |
5128082 | Makoui | Jul 1992 | A |
5138738 | Nicholson | Aug 1992 | A |
5143680 | Molnar et al. | Sep 1992 | A |
5143779 | Newkirk et al. | Sep 1992 | A |
5156902 | Pieper et al. | Oct 1992 | A |
5160331 | Forester et al. | Nov 1992 | A |
5165138 | Garabedian | Nov 1992 | A |
5176668 | Bernardin | Jan 1993 | A |
5177831 | Wirth | Jan 1993 | A |
5178931 | Perkins et al. | Jan 1993 | A |
5205012 | Coley | Apr 1993 | A |
5211903 | Reifenhauser | May 1993 | A |
5213817 | Pelley | May 1993 | A |
5217787 | Monahan | Jun 1993 | A |
5226991 | Svaighert | Jul 1993 | A |
5227107 | Dickenson et al. | Jul 1993 | A |
5230119 | Woods et al. | Jul 1993 | A |
5230843 | Howard et al. | Jul 1993 | A |
D338705 | Spokoiny | Aug 1993 | S |
5248524 | Soderlund | Sep 1993 | A |
5262223 | Palumbo et al. | Nov 1993 | A |
5269049 | Gustafsson et al. | Dec 1993 | A |
5279854 | Kendall et al. | Jan 1994 | A |
5280664 | Lin | Jan 1994 | A |
5288220 | Kugler et al. | Feb 1994 | A |
5292239 | Zeldin et al. | Mar 1994 | A |
5292582 | Gibbs et al. | Mar 1994 | A |
5294478 | Wanek et al. | Mar 1994 | A |
5304160 | Igaue et al. | Apr 1994 | A |
5306453 | Shulman | Apr 1994 | A |
5308896 | Hansen et al. | May 1994 | A |
5330456 | Robinson | Jul 1994 | A |
5331711 | Kelly | Jul 1994 | A |
5333347 | Stranders | Aug 1994 | A |
5343587 | Findley | Sep 1994 | A |
5348547 | Payne et al. | Sep 1994 | A |
5350370 | Jackson et al. | Sep 1994 | A |
5356403 | Faulks et al. | Oct 1994 | A |
5372865 | Arakawa et al. | Dec 1994 | A |
5378528 | Makoui | Jan 1995 | A |
5395675 | Altholz et al. | Mar 1995 | A |
5397413 | Trimble et al. | Mar 1995 | A |
5410771 | Bereza | May 1995 | A |
5410772 | Lewis | May 1995 | A |
5415650 | Sigl | May 1995 | A |
5415717 | Perneborn | May 1995 | A |
5419015 | Garcia | May 1995 | A |
5422169 | Roe | Jun 1995 | A |
5425725 | Tanzer et al. | Jun 1995 | A |
5426809 | Muta | Jun 1995 | A |
5429788 | Ribble et al. | Jul 1995 | A |
5439364 | Gerking et al. | Aug 1995 | A |
5442830 | Ohm | Aug 1995 | A |
5445777 | Noel et al. | Aug 1995 | A |
5447677 | Griffoul et al. | Sep 1995 | A |
5451442 | Pieniak et al. | Sep 1995 | A |
5452491 | Thompson | Sep 1995 | A |
5454659 | Vosbikian et al. | Oct 1995 | A |
5461749 | Ahlberg et al. | Oct 1995 | A |
5462537 | Carr et al. | Oct 1995 | A |
5470653 | Honeycutt et al. | Nov 1995 | A |
5471697 | Daconta | Dec 1995 | A |
5471703 | Niven | Dec 1995 | A |
5477582 | Yamashita | Dec 1995 | A |
5483720 | Decoopman et al. | Jan 1996 | A |
5490905 | Huovila et al. | Feb 1996 | A |
5494622 | Heath et al. | Feb 1996 | A |
5505718 | Roe et al. | Apr 1996 | A |
5507065 | McBride et al. | Apr 1996 | A |
5514122 | Morris et al. | May 1996 | A |
5514324 | Bachar | May 1996 | A |
5525397 | Shizuno et al. | Jun 1996 | A |
5540332 | Kopacz et al. | Jul 1996 | A |
5553344 | Rosenkrantz | Sep 1996 | A |
5558713 | Siegfried et al. | Sep 1996 | A |
5562645 | Tanzer et al. | Oct 1996 | A |
5567472 | Siegfried et al. | Oct 1996 | A |
5569230 | Fisher et al. | Oct 1996 | A |
5571537 | Geus et al. | Nov 1996 | A |
5575785 | Gryskiewicz et al. | Nov 1996 | A |
5592713 | Rones | Jan 1997 | A |
5596787 | Stevens et al. | Jan 1997 | A |
5609255 | Nichols | Mar 1997 | A |
5613263 | Nolte | Mar 1997 | A |
5614147 | Pelley | Mar 1997 | A |
5618281 | Betrabet et al. | Apr 1997 | A |
5620432 | Goulait et al. | Apr 1997 | A |
5638569 | Newell | Jun 1997 | A |
5672404 | Callahan, Jr. et al. | Sep 1997 | A |
5678278 | McBride et al. | Oct 1997 | A |
5681305 | Korpman | Oct 1997 | A |
5707731 | Honeycutt et al. | Jan 1998 | A |
D391710 | Hanaoka | Mar 1998 | S |
D391711 | Hanaoka et al. | Mar 1998 | S |
5740578 | Moore | Apr 1998 | A |
5750066 | Vonderhaar et al. | May 1998 | A |
5771524 | Woods et al. | Jun 1998 | A |
5804512 | Lickfield et al. | Sep 1998 | A |
5810800 | Hunter et al. | Sep 1998 | A |
5815878 | Murakami et al. | Oct 1998 | A |
5836039 | Rimer | Nov 1998 | A |
5839147 | Chia-Yi et al. | Nov 1998 | A |
5845361 | Murakami et al. | Dec 1998 | A |
5863565 | Rossillon et al. | Jan 1999 | A |
5885516 | Christensen | Mar 1999 | A |
5888006 | Ping et al. | Mar 1999 | A |
D409343 | Kingry et al. | May 1999 | S |
5904674 | Bonjour | May 1999 | A |
5915437 | Petner | Jun 1999 | A |
5916507 | Dabi et al. | Jun 1999 | A |
5916670 | Tan et al. | Jun 1999 | A |
5922140 | Wills | Jul 1999 | A |
5926896 | Allemann et al. | Jul 1999 | A |
D413417 | Reede | Aug 1999 | S |
5937471 | Liao | Aug 1999 | A |
5944706 | Palumbo et al. | Aug 1999 | A |
5953784 | Suzuki et al. | Sep 1999 | A |
5960508 | Holt et al. | Oct 1999 | A |
5972265 | Marra et al. | Oct 1999 | A |
D417050 | Reede | Nov 1999 | S |
5988920 | Kunkler et al. | Nov 1999 | A |
5989478 | Ouellette et al. | Nov 1999 | A |
5997989 | Gessner et al. | Dec 1999 | A |
6003191 | Sherry et al. | Dec 1999 | A |
6004308 | Haddock | Dec 1999 | A |
6006761 | Meledandri | Dec 1999 | A |
D420561 | Kunkler | Feb 2000 | S |
6020536 | Osterdahl et al. | Feb 2000 | A |
6022818 | Welchel et al. | Feb 2000 | A |
RE36601 | Woods et al. | Mar 2000 | E |
D423742 | Kingry et al. | Apr 2000 | S |
6045622 | Holt et al. | Apr 2000 | A |
6047435 | Suzuki et al. | Apr 2000 | A |
6048123 | Holt et al. | Apr 2000 | A |
6048489 | Reiter et al. | Apr 2000 | A |
D426039 | Tintelnot et al. | May 2000 | S |
6098239 | Vosbikian | Aug 2000 | A |
6098249 | Toney et al. | Aug 2000 | A |
6101661 | Policicchio et al. | Aug 2000 | A |
6119298 | Kenmochi | Sep 2000 | A |
6127594 | Rosseland | Oct 2000 | A |
6141820 | Schmiedhoff et al. | Nov 2000 | A |
6142750 | Benecke | Nov 2000 | A |
6143393 | Abe et al. | Nov 2000 | A |
6159596 | Calhoun et al. | Dec 2000 | A |
6170114 | Woodnorth et al. | Jan 2001 | B1 |
6172276 | Hetzler et al. | Jan 2001 | B1 |
6202250 | Kenmochi et al. | Mar 2001 | B1 |
6202259 | Burr et al. | Mar 2001 | B1 |
6207602 | Gessner et al. | Mar 2001 | B1 |
6218593 | Torimae et al. | Apr 2001 | B1 |
6220999 | Kugler et al. | Apr 2001 | B1 |
6243909 | Graham et al. | Jun 2001 | B1 |
6245413 | Kenmochi et al. | Jun 2001 | B1 |
D445227 | Tintelnot | Jul 2001 | S |
6293934 | Kumasaka | Sep 2001 | B1 |
6298517 | McKay | Oct 2001 | B1 |
6305046 | Kingry et al. | Oct 2001 | B1 |
6317917 | Hsu | Nov 2001 | B1 |
6319593 | Kenmochi et al. | Nov 2001 | B1 |
6330735 | Hahn et al. | Dec 2001 | B1 |
6331345 | Kauschke et al. | Dec 2001 | B1 |
6332234 | Graham et al. | Dec 2001 | B1 |
6332346 | Komiya et al. | Dec 2001 | B2 |
6332996 | Dit Picard et al. | Dec 2001 | B1 |
6368609 | Fontenot et al. | Apr 2002 | B1 |
6380151 | Masters et al. | Apr 2002 | B1 |
6389637 | Hurell | May 2002 | B1 |
6405403 | McKay | Jun 2002 | B1 |
D461028 | Ng | Jul 2002 | S |
D461029 | Ng | Jul 2002 | S |
6416697 | Venturino et al. | Jul 2002 | B1 |
6423048 | Suzuki et al. | Jul 2002 | B1 |
D462150 | Rader et al. | Aug 2002 | S |
6437214 | Everett et al. | Aug 2002 | B1 |
6443936 | Hamilton et al. | Sep 2002 | B1 |
6454690 | Kugler et al. | Sep 2002 | B2 |
D464181 | Ng | Oct 2002 | S |
6458299 | Wierer et al. | Oct 2002 | B1 |
6458442 | McKay | Oct 2002 | B1 |
6461086 | Milanowski et al. | Oct 2002 | B1 |
6465378 | Gessner et al. | Oct 2002 | B2 |
D465890 | Rivera et al. | Nov 2002 | S |
6479061 | Fontenot et al. | Nov 2002 | B2 |
6484346 | Kingry et al. | Nov 2002 | B2 |
6485667 | Tan | Nov 2002 | B1 |
6503238 | Torstensson et al. | Jan 2003 | B1 |
6511466 | Nagami et al. | Jan 2003 | B1 |
6513184 | Brown et al. | Feb 2003 | B1 |
6540424 | Hall et al. | Apr 2003 | B1 |
6550092 | Brown et al. | Apr 2003 | B1 |
6554937 | Kenmochi et al. | Apr 2003 | B1 |
D477701 | Kunkler et al. | Jul 2003 | S |
6591442 | Kaminstein | Jul 2003 | B2 |
6601261 | Holt et al. | Aug 2003 | B1 |
6606757 | Vosbikian et al. | Aug 2003 | B2 |
6611986 | Seals | Sep 2003 | B1 |
6617490 | Chen et al. | Sep 2003 | B1 |
6623576 | Mitchell et al. | Sep 2003 | B2 |
D481184 | Clare et al. | Oct 2003 | S |
D482829 | Vosbikian et al. | Nov 2003 | S |
6651290 | Kingry et al. | Nov 2003 | B2 |
6652498 | Glasgow et al. | Nov 2003 | B1 |
6652798 | Edvardsson | Nov 2003 | B1 |
6656569 | Roussel et al. | Dec 2003 | B1 |
6659670 | Blouse | Dec 2003 | B1 |
6663306 | Policicchio et al. | Dec 2003 | B2 |
6664438 | Guidotti | Dec 2003 | B1 |
6669391 | Policicchio et al. | Dec 2003 | B2 |
6681434 | Smith | Jan 2004 | B2 |
D486616 | Hall et al. | Feb 2004 | S |
D487173 | Clare et al. | Feb 2004 | S |
6684445 | Rios et al. | Feb 2004 | B1 |
6687943 | Zorzo | Feb 2004 | B2 |
6692172 | Hsu | Feb 2004 | B1 |
6692603 | Lindsay et al. | Feb 2004 | B1 |
6701567 | Smith | Mar 2004 | B2 |
6705792 | Smith | Mar 2004 | B2 |
6710099 | Cinelli et al. | Mar 2004 | B2 |
6710225 | Everett et al. | Mar 2004 | B1 |
6716206 | Jackson | Apr 2004 | B2 |
6717029 | Baker | Apr 2004 | B2 |
6723892 | Daley et al. | Apr 2004 | B1 |
6737009 | Taylor et al. | May 2004 | B2 |
6743318 | Vaders | Jun 2004 | B2 |
6745434 | Smith et al. | Jun 2004 | B2 |
6750165 | Kakiuchi et al. | Jun 2004 | B2 |
6766552 | Policicchio et al. | Jul 2004 | B1 |
D494721 | Kotani | Aug 2004 | S |
6781027 | Fenwick et al. | Aug 2004 | B2 |
6783722 | Taylor | Aug 2004 | B2 |
D497699 | Chi-Hsiang et al. | Oct 2004 | S |
6802833 | Kudo | Oct 2004 | B2 |
6803334 | Mizutani et al. | Oct 2004 | B2 |
6807702 | Keck et al. | Oct 2004 | B2 |
6810554 | McKay | Nov 2004 | B2 |
6811338 | Manske, Jr. et al. | Nov 2004 | B1 |
6811642 | Ochi | Nov 2004 | B2 |
6813799 | Otsuji et al. | Nov 2004 | B2 |
6813801 | Tanaka et al. | Nov 2004 | B2 |
6814519 | Policicchio et al. | Nov 2004 | B2 |
6815058 | Watanabe et al. | Nov 2004 | B2 |
6818166 | Edwardson et al. | Nov 2004 | B2 |
6840926 | Nukina et al. | Jan 2005 | B2 |
6842936 | Policicchio et al. | Jan 2005 | B2 |
6844066 | Hamed | Jan 2005 | B2 |
6846448 | Rymer et al. | Jan 2005 | B2 |
6851164 | Andersen | Feb 2005 | B2 |
6854911 | Policicchio et al. | Feb 2005 | B2 |
6866740 | Vaders | Mar 2005 | B2 |
6871372 | Vosbikian et al. | Mar 2005 | B2 |
6878238 | Bakken et al. | Apr 2005 | B2 |
6888044 | Fell et al. | May 2005 | B2 |
6890622 | Adam et al. | May 2005 | B2 |
6893522 | Crainic | May 2005 | B1 |
6893525 | Schmidt et al. | May 2005 | B1 |
6910823 | Policicchio et al. | Jun 2005 | B2 |
6911022 | Steger et al. | Jun 2005 | B2 |
6911174 | Creagan | Jun 2005 | B2 |
6923798 | Heden et al. | Aug 2005 | B2 |
6939492 | Jackson et al. | Sep 2005 | B2 |
6948873 | Policicchio et al. | Sep 2005 | B2 |
6968591 | Tanaka | Nov 2005 | B2 |
6993805 | Prodoehl et al. | Feb 2006 | B2 |
7013528 | Parker et al. | Mar 2006 | B2 |
7024721 | McKay | Apr 2006 | B2 |
7028364 | Policicchio et al. | Apr 2006 | B2 |
7033965 | Takabayashi et al. | Apr 2006 | B2 |
7039969 | Zorzo | May 2006 | B2 |
7096531 | Policicchio | Aug 2006 | B2 |
7137169 | Murphy et al. | Nov 2006 | B2 |
7144173 | Policicchio et al. | Dec 2006 | B2 |
7163349 | Policicchio et al. | Jan 2007 | B2 |
7175727 | Melius | Feb 2007 | B2 |
20020042962 | Willman et al. | Apr 2002 | A1 |
20020050016 | Willman et al. | May 2002 | A1 |
20020168216 | Policicchio et al. | Nov 2002 | A1 |
20020168910 | Vuillaume et al. | Nov 2002 | A1 |
20020174500 | Micciche et al. | Nov 2002 | A1 |
20020177831 | Daley et al. | Nov 2002 | A1 |
20020180092 | Abba et al. | Dec 2002 | A1 |
20020193032 | Newkirk et al. | Dec 2002 | A1 |
20030003830 | Ouederni et al. | Jan 2003 | A1 |
20030009839 | Streutker et al. | Jan 2003 | A1 |
20030024062 | McKay | Feb 2003 | A1 |
20030028988 | Streutker et al. | Feb 2003 | A1 |
20030041953 | Farell et al. | Mar 2003 | A1 |
20030044569 | Kacher et al. | Mar 2003 | A1 |
20030045197 | Kakiuchi et al. | Mar 2003 | A1 |
20030049407 | Kacher et al. | Mar 2003 | A1 |
20030070746 | Woods et al. | Apr 2003 | A1 |
20030082358 | Wenstrup | May 2003 | A1 |
20030106568 | Keck et al. | Jun 2003 | A1 |
20030110584 | Clare et al. | Jun 2003 | A1 |
20030114067 | Matela et al. | Jun 2003 | A1 |
20030119400 | Beitz et al. | Jun 2003 | A1 |
20030119401 | Chakravarty et al. | Jun 2003 | A1 |
20030119402 | Melius et al. | Jun 2003 | A1 |
20030120238 | Gustavsson et al. | Jun 2003 | A1 |
20030126710 | Policicchio et al. | Jul 2003 | A1 |
20030135181 | Chen et al. | Jul 2003 | A1 |
20030140441 | Stafford | Jul 2003 | A1 |
20030157856 | Schroeder et al. | Aug 2003 | A1 |
20030180083 | Hall et al. | Sep 2003 | A1 |
20030195485 | Rangachari et al. | Oct 2003 | A1 |
20030200991 | Keck et al. | Oct 2003 | A1 |
20030203162 | Fenwick et al. | Oct 2003 | A1 |
20030203691 | Fenwick et al. | Oct 2003 | A1 |
20030211802 | Keck et al. | Nov 2003 | A1 |
20030219591 | Bany et al. | Nov 2003 | A1 |
20030220039 | Chen et al. | Nov 2003 | A1 |
20030221274 | Makhija et al. | Dec 2003 | A1 |
20030224686 | Andersen | Dec 2003 | A1 |
20030227106 | Fuller et al. | Dec 2003 | A1 |
20030229327 | Imsangjan et al. | Dec 2003 | A1 |
20030236510 | Yasumura et al. | Dec 2003 | A1 |
20040011382 | Kingry et al. | Jan 2004 | A1 |
20040019995 | Kowalski et al. | Feb 2004 | A1 |
20040031119 | McKay | Feb 2004 | A1 |
20040038008 | Levine et al. | Feb 2004 | A1 |
20040043214 | Topolkaraev et al. | Mar 2004 | A1 |
20040049166 | Chen et al. | Mar 2004 | A1 |
20040054331 | Hamilton et al. | Mar 2004 | A1 |
20040064119 | Guidotti et al. | Apr 2004 | A1 |
20040074520 | Truong et al. | Apr 2004 | A1 |
20040087928 | Ducker | May 2004 | A1 |
20040093678 | Hart et al. | May 2004 | A1 |
20040102124 | Suzuki | May 2004 | A1 |
20040111817 | Chen et al. | Jun 2004 | A1 |
20040121686 | Wong et al. | Jun 2004 | A1 |
20040128786 | Policicchio et al. | Jul 2004 | A1 |
20040140048 | Lindsay et al. | Jul 2004 | A1 |
20040177863 | McKay | Sep 2004 | A1 |
20040177935 | Hamed et al. | Sep 2004 | A1 |
20040192136 | Gusky et al. | Sep 2004 | A1 |
20040204697 | Litvay | Oct 2004 | A1 |
20040206372 | Holt et al. | Oct 2004 | A1 |
20040206464 | Li et al. | Oct 2004 | A1 |
20040234760 | Hamed | Nov 2004 | A1 |
20040253892 | Baker et al. | Dec 2004 | A1 |
20040253893 | Castellani | Dec 2004 | A1 |
20040253894 | Fell et al. | Dec 2004 | A1 |
20040254551 | Carnes et al. | Dec 2004 | A1 |
20050000047 | Kelly et al. | Jan 2005 | A1 |
20050004541 | Roberts | Jan 2005 | A1 |
20050039287 | Moser | Feb 2005 | A1 |
20050045296 | Adam et al. | Mar 2005 | A1 |
20050054253 | Minoguchi et al. | Mar 2005 | A1 |
20050055791 | Lin | Mar 2005 | A1 |
20050061356 | Wong et al. | Mar 2005 | A1 |
20050079361 | Hamed et al. | Apr 2005 | A1 |
20050081888 | Pung et al. | Apr 2005 | A1 |
20050085150 | Hamed | Apr 2005 | A1 |
20050092417 | Billgren et al. | May 2005 | A1 |
20050109442 | Neubauer et al. | May 2005 | A1 |
20050109449 | Scott et al. | May 2005 | A1 |
20050112980 | Strandqvist et al. | May 2005 | A1 |
20050113775 | English et al. | May 2005 | A1 |
20050113776 | Venturino et al. | May 2005 | A1 |
20050113791 | Neubauer et al. | May 2005 | A1 |
20050118399 | Perneborn | Jun 2005 | A1 |
20050118916 | Ducker et al. | Jun 2005 | A1 |
20050120497 | Lynde et al. | Jun 2005 | A1 |
20050130539 | Allen et al. | Jun 2005 | A1 |
20050132518 | Chen et al. | Jun 2005 | A1 |
20050138749 | Keck et al. | Jun 2005 | A1 |
20050155630 | Kilkenny et al. | Jul 2005 | A1 |
20050166347 | Fereshtehkhou et al. | Aug 2005 | A1 |
20050170728 | Crainic | Aug 2005 | A1 |
Number | Date | Country | |
---|---|---|---|
20070078421 A1 | Apr 2007 | US |