The present invention concerns articles of manufacture having functional surfaces such as gripping surfaces thereon, and methods of making the same by additive manufacturing.
There are a variety of manufactured objects where it is desirable to have different functional characteristics on the surface of the part rather than in the body of the object. For example, a power tool handle may require a substantially rigid body, yet a gripping surface that provides cushioning and/or vibration isolation to the operator.
Such characteristics are traditionally imparted by adhesively attaching two different materials to one another (see, e.g., U.S. Pat. No. 6,974,626) or overmolding a soft material onto another, harder, substrate material (see, e.g., U.S. Pat. No. 7,808,816). Disadvantages of overmolding, however, are that it is a complex process that requires expensive tooling, the expensive tooling makes it difficult to customize, and the resulting products may encounter adhesion problems during extended field use.
Additive manufacturing with different grades of materials offers some promise for these types of applications, but changing materials during additive manufacturing can slow the process, mechanical properties can be limited by the materials available, and again adhesion issues between different materials may be encountered during extended field use.
Accordingly, there is a need for new ways to manufacture three-dimensional objects as a single, unitary, piece of material, which objects have surface regions with functional characteristics that differ from other portions of the object.
In some embodiments, a polymer object includes (a) a body portion having a surface portion thereon; (b) at least a first array of feature elements formed on said surface portion, each of said feature elements comprising: (i) a support structure connected to said surface portion and extending upward therefrom; and (ii) a top segment connected to said support structure, said top structure and said support structure together defining an internal cavity formed therein; (c) said polymer object produced as a single piece object by an additive manufacturing process.
In some embodiments, the polymer object is a single unitary member (one-piece construction without seams or other connections). The polymer object may be formed of a single material.
In some embodiments, the feature elements are configured to deform or collapse by bending and/or buckling upon application of pressure thereto (e.g., constant pressure such as by grasping, vibratory pressure, etc.) and return to their previous configuration upon removal of such pressure.
In some embodiments, the support structure comprises a circumferential wall or a plurality of arms (e.g., 2, 3, 4, 5, 6, 7 or 8 arms).
In some embodiments, (i) all of said feature elements in said array have the same external configuration, and optionally wherein at least some of said feature elements in said array have internal dimensions (e.g., arm thickness) that differ from that of other feature elements in said array (e.g., to provide variable stiffness or elasticity in different regions of the array); or (ii) said array comprises a first set of feature elements and a second set of feature elements interspersed with one another, the feature elements of said first set having a height greater than the feature elements of said second set.
In some embodiments, at least some of said feature elements further comprise at least one support post positioned within said support structure, each said support post interconnecting said surface portion and said top segment.
In some embodiments, the top segment is flat, convexely curved, concavely curved, or a combination thereof.
In some embodiments, the array comprises a dispersed array, a nested array (e.g., to produce progressively increasing stiffness as the surface is compressed), or a combination thereof.
In some embodiments, the object surface portion on which said array is formed comprises a flat region, a concavely curved region, a convexly curved region, or a combination thereof.
In some embodiments, at least one of said top segment and said support structure has at least one orifice formed therein (e.g., wherein said feature element comprises a perforated dome).
In some embodiments, each feature element has a height of from 1 or 2 millimeters to 10 or 20 millimeters, or more; each feature element has a maximum width of from 1 or 2 millimeters to 10, 20 or 40 millimeters, or more; and/or said feature elements are included in said surface array at a density of from 1, 2, 10 or 20 per square centimeter of, to 100, 200, or 300 per square centimeter, or more.
In some embodiments, the additive manufacturing comprises stereolithography, including both top-down and bottom-up stereolithography such as continuous liquid interface production (e.g., from a single batch of polymerizable resin) or selective laser sintering (e.g., from a single batch of sinterable polymer particulate).
In some embodiments, the resin comprises a dual cure resin (e.g., a flexible or elastomeric polyurethane dual cure resin).
In some embodiments, the object comprises a hand grip or hand grip wrap, and said surface portion comprises a gripping region of said grip or grip wrap.
In some embodiments, a method of making an object as described above includes (a) forming said object by an additive manufacturing process; (b) optionally washing said object; and (c) optionally further curing said object (e.g., by baking).
In some embodiments, the additive manufacturing process comprises selective laser sintering or stereolithography.
The foregoing and other objects and aspects of the present invention are explained in greater detail in the drawings herein and the specification set forth below. The disclosures of all United States patent references cited herein are to be incorporated herein by reference.
The present invention is now described more fully hereinafter with reference to the accompanying drawings, in which embodiments of the invention are shown. This invention may, however, be embodied in many different forms and should not be construed as limited to the embodiments set forth herein; rather these embodiments are provided so that this disclosure will be thorough and complete and will fully convey the scope of the invention to those skilled in the art.
As used herein, the term “and/or” includes any and all possible combinations or one or more of the associated listed items, as well as the lack of combinations when interpreted in the alternative (“or”).
1. Methods of Making.
Objects or constructs as described herein can be produced by any suitable process, but are preferably produced by additive manufacturing, particularly by selective laser sintering (SLS) of stereolithography, and in some embodiments by continuous liquid interface production (CLIP).
Techniques for additive manufacturing are known. Suitable techniques include bottom-up or top-down additive manufacturing, generally known as stereolithography Such methods are known and described in, for example, U.S. Pat. No. 5,236,637 to Hull, U.S. Pat. Nos. 5,391,072 and 5,529,473 to Lawton, U.S. Pat. No. 7,438,846 to John, U.S. Pat. No. 7,892,474 to Shkolnik, U.S. Pat. No. 8,110,135 to El-Siblani, U.S. Patent Application Publication Nos. 2013/0292862 to Joyce, and US Patent Application Publication No. 2013/0295212 to Chen et al. The disclosures of these patents and applications are incorporated by reference herein in their entirety.
CLIP is known and described in, for example, U.S. Pat. Nos. 9,211,678; 9,205,601; and 9,216,546; and also in J. Tumbleston, D. Shirvanyants, N. Ermoshkin et al., Continuous liquid interface production of 3D Objects, Science 347, 1349-1352 (published online 16 Mar. 2015). See also R. Janusziewcz et al., Layerless fabrication with continuous liquid interface production, Proc. Natl. Acad. Sci. USA 113, 11703-11708 (Oct. 18, 2016). In some embodiments, CLIP employs features of a bottom-up three dimensional fabrication as described above, but the the irradiating and/or said advancing steps are carried out while also concurrently maintaining a stable or persistent liquid interface between the growing object and the build surface or window, such as by: (i) continuously maintaining a dead zone of polymerizable liquid in contact with said build surface, and (ii) continuously maintaining a gradient of polymerization zone (such as an active surface) between the dead zone and the solid polymer and in contact with each thereof, the gradient of polymerization zone comprising the first component in partially cured form. In some embodiments of CLIP, the optically transparent member comprises a semipermeable member (e.g., a fluoropolymer), and the continuously maintaining a dead zone is carried out by feeding an inhibitor of polymerization through the optically transparent member, thereby creating a gradient of inhibitor in the dead zone and optionally in at least a portion of the gradient of polymerization zone. Other approaches for carrying out CLIP that can be used in the present invention and potentially obviate the need for a semipermeable “window” or window structure include utilizing a liquid interface comprising an immiscible liquid (see L. Robeson et al., WO 2015/164234, published Oct. 29, 2015), generating oxygen as an inhibitor by electrolysis (see I Craven et al., WO 2016/133759, published Aug. 25, 2016), and incorporating magnetically positionable particles to which the photoactivator is coupled into the polymerizable liquid (see J. Rolland, WO 2016/145182, published Sep. 15, 2016).
In one non-limiting embodiment, the object may be produced on a Carbon Inc., M1 additive manufacturing apparatus, available from Carbon, Inc., 1089 Mills Way, Redwood City, Calif. 94063 USA.
After the intermediate three-dimensional object is formed, it is optionally washed, optionally dried (e.g., air dried) and/or rinsed (in any sequence). It is then further cured, preferably by heating.
Heating may be active heating (e.g., in an oven, such as an electric, gas, solar oven or microwave oven, or combination thereof), or passive heating (e.g., at ambient temperature). Active heating will generally be more rapid than passive heating and in some embodiments is preferred, but passive heating—such as simply maintaining the intermediate at ambient temperature for a sufficient time to effect further cure—may in some embodiments also be employed.
2. Materials.
Any suitable material can be used as the polymerizable liquid or resin to carry out the present invention (including expansion lattices, compression lattices, and clamping apparatus comprising the two integrally formed with one another). Preferably, the material is one which produces an elastomeric product. In some embodiments, the objects are comprised of a polyurethane material (including polyurea materials). In some embodiments, the objects are produced from a dual cure stereolithography resin.
Dual cure stereolithography resins suitable for stereolithography techniques (particularly for CLIP) are described in J. Rolland et al., U.S. Pat. Nos. 9,453,142 and 9,598,606 (see also US Patent Application Pub. Nos. US 2016/0136889; 2016/0137838; and 2016/016077). These resins usually include a first polymerizable system typically polymerized by light (sometimes referred to as “Part A”) from which an intermediate object is produced, and also include at least a second polymerizable system (“Part B”) which is usually cured after the intermediate object is first formed, and which impart desirable structural and/or tensile properties to the final object.
In some embodiments, the polymerizable liquid is a Carbon, Inc. elastic polyurethane (EPU) resin such as EPU40, or a flexible polyurethane (FPU) resin, such as FPU50, available from Carbon, Inc., 1089 Mills Way, Redwood City, Calif. 94063 USA. For SLS, examples of suitable materials include PrimePart® ST (PEBA 2301), available from EOS Manufacturing Solutions, and Duraform TPU and Duraform FLEX, available from 3D Systems.
Objects.
In brief overview, numerous small three-dimensional structures (domes, arches, lattices, etc.) are formed on the surface of an object during additive manufacturing thereof. When a force is applied on the object surface, the small structures deform by bending and/or buckling. The bending or buckling stiffness of the small structures can be tuned to be less than, and in some cases substantially less than, the tensile or compressive stiffness of the entire object as a whole. The geometries (thickness, span, configuration, etc.) of the small structures, and the manner in which the structures are arranged throughout the object surface, can be varied to achieve a wide range of topical stiffness or tactile characteristics not achievable with a solid surface continuum. When desired, by building variable structures in different surface portions of the same object, the topical stiffness of the object can vary from area to area.
In some embodiments, the object is formed as a single piece object, such as a single unitary member (one-piece construction without seams or other connections).
An array of small three-dimensional structures on the surface of a larger object is shown in
Each element 13 is in turn comprised of a supporting structure (in the case of
While the surface portion 12 is shown as uniformly flat throughout and beneath the array, it will be appreciated that the surface portion beneath each raised element may be either elevated, for example as a convex surface region beneath a raised element (e.g., to reduce the amount by which an element can be depressed), or depressed, for example as a concave surface region beneath a raised element (e.g., to increase the amount by which a raised element can be depressed). For example, in some embodiments, the surface portion beneath the raised elements can be configured so that when the raised elements are depressed, the top portions thereof become substantially co-planar with the surface portion 12, presenting or creating a substantially smooth overall configuration on the surface portion.
The (optional, but in some embodiments preferable) orifice 25 included in the top segment 22 serves to provide additional edges to enhance grip, and to provide additional channels for enhanced air-flow and breathability (see “Applications” below).
Progressive, Nested, and Composite Arrays.
As previously noted, the feature elements of an array may be the same as one another, or may differ from one another, in shape, internal geometry, and/or size. For example, as shown in
Arrays may be nested in one or two dimensions, or dispersed, as shown in
Additional non-limiting examples of surface structures that can be included in arrays as described herein are shown in
Additional configurations (of both individual surface elements, and the manner in which they are arranged on the surface of an object) can readily be envisioned.
Applications.
The foregoing can be applied in a variety of ways to a variety of different objects, such as: (A) Skin and body contact applications-softer feel, perception of quality, better grip and friction, surface ventilation (sports equipment such as golf clubs, tennis racquets, ping pong paddles, and bicycle handlebar grips, helmet liners, etc.; consumer equipment such as headset earpieces; sunglass earpieces; watch band inner surfaces, shoe inserts (inner soles), etc.; medical devices such as hearing aid earpiece inserts, tool grips, etc. (B) Noise and/or vibration isolation (vibration absorbing surfaces), including automotive and aerospace applications (steering wheel covers and wraps (grip enhancement and vibration isolation); interior trim components (noise reduction), etc., and consumer and biomedical applications such as power tool grips (for vibration isolation), etc.
The present invention is explained in greater detail in the following non-limiting Example.
An array of small three-dimensional structures (configured in substantially the same manner as shown in
The foregoing is illustrative of the present invention, and is not to be construed as limiting thereof. The invention is defined by the following claims, with equivalents of the claims to be included therein.
This applications claims priority to U.S. Provisional Application Ser. No. 62/530,599, filed Jul. 10, 2017, the disclosure of which is hereby incorporated by reference in its entirety.
Number | Date | Country | |
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62530599 | Jul 2017 | US |