Explosively-propelled liquids are used to disrupt explosive devices, including improvised explosive devices (IEDs). One system relies on mass-focusing shaped-charges to propel a liquid fluid on target. See, for example, U.S. Pat. No. 10,921,089 (Atty. Ref. 338287: 15-20 US) and U.S. patent application Ser. No. 17/170,304 (Atty. Ref. 338710: 15-20A US) filed Feb. 8, 2021, each of which are incorporated by reference herein to the extent not inconsistent herewith.
There are several commercial and improvised shaped-charges that drive water and each have their strengths and weaknesses. A common method is to attach the explosives to a plastic former, which is either seated inside the fluid, sandwiched between fluid chambers, or is on the outside surface of the fluid container. Pressure fields are produced by shaping explosives into hemispherical, linear (wedge or hemi-cylindrical), rod and conical charge geometries. When the explosives are initiated, shocks form inside the water column and reflect off of the free field surfaces. Various parameters such as angles and corners within the container of fluid or on the explosive former define the pressure-time history of the gases and shocks acting on the water. There are regions of high and low pressure that will differentially accelerate the water to form a jet. High pressure regions are due to a Mach-stem effect which are formed by collisions of shocks, usually along a central axis or plane. A slug of water is the projectile, and water behind the explosives traps the gases, thus increasing the duration of pressure acting on the slug. Shocks can also reflect at the tamper boundaries and move back into the water, amplifying the pressure.
A common charge configuration of mass focusing shaped-charges driving a liquid fluid is linear and are symmetric along a bisecting plane. In the case of the Hydrajet™ disrupter (U.S. Pat. No. 6,269,725 by Cherry), a tall chevron profiled wedge former of explosives with an angle of 90 degrees is utilized and placed inside a rectangular shaped fluid-filled chamber. Cherry proposes an adjustable apex angle and a scalability in disrupter size. Another example of a linear charge is the mod series of disrupters (U.S. Pat. No. 6,584,908 by Alford). In that case, rather than a wedge, it is an arc section of a hemi-cylindrical shape. Alford uses two separate water chambers and sandwiches sheet explosives between them. The jet profile is similar to the Hydrajet™ disrupter. Linear high explosive charges that drive water form blade shaped water jets. A transverse cross sectioning of the jet would have the approximate profile of a narrow ellipse.
Omni-directional mass jetting high explosive disrupters are good at delivering high impulse to a target and use a rod-shaped explosive charge at the core of a cylindrically-shaped container. Those tools have axial symmetry. Omnidirectional tools produce low density jets because they rapidly particulate into droplets. Examples of these are the Mineral Water Bottle charge and the Bottler charge (U.S. Pat. No. 9,322,624). The bottler charge has three hemi-cylindrical indentations on the outer bottle surface that create a shock cavity effect and linear fluid jets at the center of each one.
Some water-based charges are more effective at perforating barriers such as liquid follow-through (LIFT) charges (U.S. Pat. No. 4,955,939). Conical LIFT charges have an air void. The explosives are rectangular prisms or right-angle cylinders and oriented so that the flat face of the cylinder it abutting the water. The detonator is positioned coaxially down the center of the charge. The explosive detonation wave shock couples at the water interface producing an approximate planar shock front that travels into the water surrounding the hollow cavity causing the water to collapse into the void and jet forward. The thin plastic liner collapses on itself and flows at the leading edge of the jetting fluid. Another example of conical LIFT charge is the Rocksmith Precision Closer™ disrupter (U.S. Pat. No. 8,677,902). The cone angles are approximately 45 to 60 degrees and the jets are moving at extremely high velocities, traveling in some cases in excess of Mach 10. An example of a linear LIFT charge is the Stingray™ disrupter (U.S. Pat. No. 8,091,479 B1). LIFT charges generally produce narrow fluid jets of low mass. They have high jet stretch rates and are good barrier penetrators but yield low bulk work on media and low impulse in our testing. As a result, they are relatively poor general disruption tools.
Water and other fluids can be driven explosively using shaped-charges to form liquid jets which move at relatively high velocity and can perform work on a target. Explosives are shaped and immersed in the water or placed on the outside of a water container. The explosives' detonation produces shock waves that move through the water. Typically, to create a jet, the charge is configured such that the shocks along a central axis or a bisecting plane converge and form a Mach stem. The pressure is higher in the center compared to the sides. A pressure gradient results in the water accelerating differentially as its position moves away from the center. The result is a jet that has a velocity profile with faster water at its front and the gradient is such that the water slows as one moves towards the explosive gas products. That velocity profile provides a number of challenges, including jet destabilization, gasification and atomization arising from shock waves in the fluid.
Provided herein are shaped-charges that stabilize the jet by the use of specially configured attenuating bodies that minimize or avoid the destabilizing effects associated with the shock waves moving through the fluid, while also ensuring that the generated liquid fluid jet has appropriate characteristics for reliable explosive target (e.g., IED's) disruption.
The filler focusing shaped-charges provided herein address the above-discussed problems by specially designed surfaces lined with one or more attenuating bodies to increase the efficiency of a jetted filler that is explosively propelled from a container volume. Conventional shaped-charges, in contrast, tend to have a uniform container thickness and, due to costs and plastic material molding processes, are very thin. For example, typical container wall thicknesses are between 0.01″ and 0.08″ and thus do not contribute much to the shock effects. The fluid-mass shaped-charges and related methods described herein utilize an attenuating body to improve fluid jet characteristics by controlled attenuation of the underlying shock and associated physical effects. For example, changing a plastic wall thickness of a container to between 0.25″ and 0.5″ by connecting an attenuating body to the sides of the container can be beneficial, including by attenuating body layer around the outer side surface of a container (e.g., a wrapping that wraps around the container or a sleeve the slides over the container sidewall, including a sidewall that has a circular circumference). The special layer, referred herein as an “attenuating body” (AB), increases relative work by the fluid jet and increases impulse and target penetration. Depending on the attenuating body position on the shaped-charge, attendant functional benefit of the attenuating body includes reduced fluid (e.g., water) gasification, an increase in inertial tamping, and increase in fluid jet velocity toward target. Positioning an attenuating body at various locations on the shaped-charge can dramatically increase the shaped-charge effectiveness at increased stand-off distance from a target, including by decreasing the rate of fluid jet stretch.
The shaped-charges and related methods are compatible with a range of explosives used to propel the liquid onto a target. For example, the explosive used to propel fluid liquid toward a target can be a shaped-conformable explosive that conforms to a shell surface. In another example, the explosive can be a volume-occupying explosive contained within a shell internal volume. The shell and explosive, whether in a surface or a container-supported configuration, are positioned in a container interior volume within a filler, including a fluid mass and/or solid particles. Both the explosive shell and the filler is contained within the container. As described herein, one or more attenuating bodies are connected to the container and/or the explosive shell to provide fluid jet characteristics by attenuating shock waves based, in part, on the application of interest.
Provided herein are shaped-charges for focusing a filler comprising a container having an interior volume to contain a shell laden with explosives and the filler. The filler can be a liquid such as water, HEET (see, e.g., U.S. Pat. No. 11,187,487, specifically incorporated by reference herein for HEET compositions and related disrupters), or other liquid that is explosively propelled to disrupt a target. The filler can be particulate solids, such as steel shot or other fine material, including garnet, sand and the like, that can form an explosively propelled jet. Filler is used broadly herein, with the devices and methods compatible with a combination of liquid and solid-containing fillers, so long as the solid particles are able to flow under an applied stress. The shell has a surface with a geometric shape configured to support a shape-conforming explosive or contain an explosive volume, wherein the geometric shape has a central longitudinal axis or a bisecting symmetry plane. The shell surface has a shell distal end, a shell proximal end that faces the distal end, and a shell sidewall that connects the distal end to the proximal end. For a shell that supports a shape-conforming explosive, the sidewall may correspond to the thickness of the shell, with a distal end shell surface that faces the target and the opposed proximal end shell surface that faces away from the target. For a shell that is a container to contain an explosive volume, there may be more distinct shell sidewalls that physically separate the shell distal and proximal end surfaces. An attenuating body, such as an AB layer, is connected to at least a portion of the container surface inner and/or outer-facing surfaces. Preferably, the attenuating body has an attenuating body thickness of between 0.03″ and 2″, such as between 0.03″ and 1″, that can be connected to one or more surfaces of a conventional shaped-charge container. In this manner, conventional shaped-charges can be retro-fitted with an attenuating layer to improve shaped-charge performance. The attenuating body thickness may spatially vary, including depending on the application of interest and the material composition of the attenuating body. For example, a distal surface (e.g., the depth of the shaper) on a CAT-shaped embodiment (see, e.g., U.S. Pat. No. 10,921,089, incorporated by reference herein for the CAT embodiments), may be filled with an attenuating body, such as between about 1″ and 2″, including about 1.8″. This relatively thick attenuating body can fill the CAT distal surface shape that is, effectively, an indentation (concave shape). In this aspect, the attenuating body may have a maximum thickness along the central longitudinal axis where the indentation is greatest, tapering to a minimum at the edge of the distal surface that connects to a container sidewall.
The explosives forming surface shell or explosives filled shell (also referred herein more generally as “shell”) is longitudinally aligned or centrally positioned relative to the attenuating body, and the corresponding container surface to which the attenuating body is connected. “Connected” is used broadly herein and can refer to a container surface that functionally is at least partially formed from the attenuating body or a more distinct component that is separately provided to the container surface. Depending on the shell configuration, explosives filled shell container or explosives shell support surface, their alignment or central positioning may be with respect to the shell longitudinal axis or the shell bisecting symmetry plane. This reflects that the shaped-charge can tolerate some off-center variance without unduly impacting the shock attenuation function of the attenuating body. The explosives shell or explosives body may be moved backward and forward, thereby impacting the relative length of the tamp and slug region. In an embodiment, the attenuating body, container surface, and explosives shell are all concentrically aligned with each other, with the longitudinal axes of each aligned and identically positioned. Furthermore, the shaped-charge can also accommodate an air gap in the container, for embodiments where fluid does not completely fill the container interior volume, to create a lift effect. Alternatively, the air gap may correspond to a bladder, in order to create a rarefaction wave shaper at the distal end of the CAT charge.
A channel can extend through the container surface and terminates or passes through the shell surface at a contact position coincident with the central longitudinal axis or the bisecting symmetry plane. The channel is configured to functionally provide the ability to reliably and safely detonate the explosives with an initiator. In other words, there is an initiator contact point connected to the shape conforming explosive or the explosive volume configured to initiate detonation of the shape conforming explosive or the explosive volume. The initiator may be an electric or non-electric detonator, detonation cord or sensitized detonation cord. The channel can terminate at the shell surface and then wire, shock tube and/or detonation cord can be fed along the channel out to the environment. A blasting machine can fire the stimulus, to initiate a detonator and controlled detonation of the explosive associated with the shell. In this manner, the fluid in the container is controllably expelled, with an improved jet characteristic provided by the attenuating body.
More specifically, the attenuating body has an attenuating body parameter configured to provide reflected shock wave attenuation after actuation of the initiator to detonate the explosives and explosively drive fluid from the interior volume of the container toward a target. The container may be formed from the attenuating body, in whole or in part. The attenuating body parameter may be any one or more of attenuating body thickness, material composition, bulk density, heterogeneity, geometry, location on the container surface, one of the shock Hugoniot parameters (e.g., bulk speed of sound or ‘s’ number), and any combination thereof. “Heterogeneity” refers to different portions of the attenuating body having a different material property, such as gas spaces, porosity, material composition (solid, liquid, gas portions), void space fraction, composition fraction (e.g., percentage volumes occupied by a solid, liquid, or gas), and so are particularly relevant for foams and aerogels. For example, the percentage volume that is solid can vary from very low (approaching 5% or less) to very high (above 95% or greater). Of course, many applications of interest preferably have low density foams, so that the percentage of volume of solid is preferably less than 50%. The attenuating body parameter(s) are selected to provide, for the application of interest, a desired shock attenuation. The shock impedance, and shock velocity is defined by the equation of state. Hugoniot parameters include material density, bulk speed of sound, and ‘s’ number. There is an approximately linear relationship between the shock velocity and particle velocity. The slope of the line is the ‘s’ number. In this manner, we not only reduce the intensity of the reflected wave but at the corner of the container there is a timing mismatch so that the shock traveling in the AB is slower than that in the water at the air boundary. The colliding waves do not amplify at the corners like they would without the AB.
Exemplary AB densities include, but are not limited to, AB density on a distal container surface. Between about 0.015 g/cm3-1 g/cm3; for AB on container sidewalls between about 0.5 g/cm3-2 g/cm3 (including between 0.8 g/cm3-1.5 g/cm3). For a jet clipper (e.g., a second attenuating body), density may be between 0.5 g/cm3-2 g/cm3.
The attenuating body may be formed of a material selected from the group consisting of: plastic; foam; wood; clay; wax; natural or synthetic rubber; and combinations thereof, including in multilayers and/or composites. The container may itself correspond to the attenuating body, in whole or in part. For example, the container may be made of the attenuating body, including an attenuating body comprising one or more of a foam, rubber (natural or synthetic), plastic, metal, wood, clay, wax.
The invention provided herein is compatible with attenuating body/bodies connected at any of a variety of surfaces. The robust accommodation of attenuating body positions reflects the ability of the instant invention to accommodate a diverse range of applications. For example, shock wave behavior is dependent on any of a variety of application properties, including fluid composition, material composition of the components of the shaped-charge (e.g., type of explosive, detonator, container composition, shell composition), physical parameters (e.g., thicknesses, spatial dimensions, container volume) and target/bomb characteristics (stand-off distance, target surface property, environment such as in air or underwater). Any one or more of the application properties are used to inform attenuating body or bodies parameter, including location, layer thickness, use of multiple layers, contour, and the like. For underwater applications, low density foam is placed in front of the water slug and displaces the water between the target and the water slug. The water environment creates the tamp- no container needed when the shaped-charge is underwater. Because the extreme confinement created by a submerged water environment, the IED explosive may detonate on impact of the water jet. This issue is addressed by adding a denser layer of a surface material attenuation of rarefaction shock waves (SMART) at the end of the foam which is adjacent to the bomb. This clips the jet tip and attenuates the precursor shock wave going into the bomb.
Exemplary positions of the attenuating body include: In an embodiment, the attenuating body is connected to at least a portion of the container sidewall. In an embodiment, the attenuating body is connected to at least a portion of the container distal end and/or proximal end. In an embodiment, the attenuating body is connected to all surfaces of the container, thereby covering the container outer-facing or inner-facing surface. In an embodiment, the attenuating body is connected to at least a portion of the shell surface. In an embodiment, the attenuating body is connected to one or more of the shell sidewall, shell distal end, or the shell proximal end. In an embodiment, a first attenuating body is connected to at least a portion of the shell surface and a second attenuating body is connected to at least a portion of the container surface. The attenuating body may correspond to a sleeve that slide over at least a portion of the container side-wall outer surface. The sleeve may be open-ended so that the container distal end is not covered. Alternatively, the sleeve may be closed-ended so that the container distal end (along with at least a portion of the container sidewall) is covered. The AB may slide over an outer-facing sidewall surface of the container in a tight-fit configuration.
In an embodiment, the shaped-charge comprises a plurality of shells.
In an embodiment, the container and attenuating body are independently formed of a material having a low density, including a density of less than 1.1 g/cm3, and the attenuating body is optionally contoured to increase an effective standoff distance compared to an equivalent shaped-charge without the attenuating body by lowering the rate of jet stretch.
In an embodiment, the explosives forming shell is formed of a plastic material. In an embodiment, the geometric shape of the shell, including a plastic shell, comprises: a truncated cone having an open distal end and a closed proximal end, the closed proximal end having a smoothly-curved concave shape; an outer circumference with a plurality of cut-outs radially spaced around the outer circumference; wherein the geometric shape is axially-symmetric about a central longitudinal axis. U.S. Pat. No. 10,921,089, which is specifically incorporated by reference herein for the “truncated cone” geometry.
In an embodiment, provided is a second attenuating body that is a distal surface layer in contact with the attenuating body that at least partially covers the container distal surface.
The AB may be an AB layer. The AB may comprise two AB materials, such as a at least one attenuating body corresponding to an AB layer having a layer thickness connected to an outer surface or an inner surface of the attenuating body, wherein the sum of the layer thickness and the attenuating body thickness is between 0.25″ and 1.5″. The layer may comprise: natural rubber; synthetic rubber, silicone, clay, Teflon™, neoprene, sorbothane, nitrile, PVC, or polyurethane. The AB layer may be a sleeve that slips over an outer-facing of the container sidewall.
The AB layer may have a density of between 0.015 g/cm3 and 2.0 g/cm3, or between 0.8 g/cm3 and 1.8 g/cm3.
Any of the attenuating bodies may comprise a multilayer comprising a plurality of distinct attenuating body layers. Each layer can be independently selected to have a thickness and material composition.
The attenuating body may be a layer that is prefabricated into the charge design (e.g., incorporated with a surface of the shell and/or container) or connected to the attenuating body sidewall inner or outer-facing surface. The connection may be by a tight-fit frictional force or may include an adhesive layer. The connection may be by an elastic force, wherein an AB is flexible, bendable and/or stretchable. The AB may be painted, sprayed, or otherwise applied onto a surface.
The shaped-charge may further comprise an AB layer configured to slip over an outer surface of the attenuating body (e.g., accessible) surface of the container. In this manner, there can be “on-site” retro-fitting of a layer over a standard shaped-charge. The AB layer may have a substantial thickness to for an AB body volume that is configured to be placed into the container volume, thereby occupying a fraction of the container volume, such as up to 30% of the container volume, for example.
The attenuating body thickness may spatially-vary. In this manner, additional jet characteristic control is achieved. For example, thicker attenuating body layer may correspond to regions where an increase in rarefaction wave dissipation is desired, including near corners.
The shaped-charge may further comprise an AB layer that: partially covers the sidewall; covers the container proximal end; covers the distal end of the container, or an attenuating body connected thereto, and the AB layer is contoured with a spatially-varying thickness; covers the distal end of the container, or an attenuating body connected thereto, and the AB layer is not contoured and instead has a spatially-constant thickness; covers the container sidewall and the distal end of the container; covers the entire container surface; covers the entire shell surface; or any combination thereof.
The shaped-charge may further comprise: a foam having a density less than 0.5 g/cm3 positioned to fill a gap between the shaped-charge and a target, wherein the foam reduces water gasification and reduces a liquid jet forward velocity gradient; and a barrier layer adjacent or in contact with a target surface, wherein the barrier layer has a density of between 0.5 g/cm3 to 2 g/cm3.
In an embodiment, the explosives shell is concentrically aligned with respect to the container surface and the attenuating body is connected to at least a portion of the container surface.
Also provided herein are methods of explosively driving a filler, including a fluid and/or solid particles, to disrupt an explosive target using any the of the filler focusing shaped-charges provided herein. For example, the method may comprise the steps of: providing the shaped-charge with a fluid liquid positioned in the interior volume, wherein the shell is immersed in the liquid and aligning the mass focusing shaped-charge with an explosive target. The initiator is actuated to detonate the explosive in or on the shell surface and initiate a detonation wave that travels substantially parallel to the longitudinal axis, wherein the geometric shape and position of the shell and the attenuating body are configured to generate a tamp and timing of rarefaction waves to increase a pressure duration and amplitude to drive the liquid toward the explosive target and increase a bulk mass of a liquid jet. In particular, the increase in bulk mass is relative to an equivalent filler focusing shaped-charge without any of the attenuating body. The increase in bulk mass of the liquid jet may be characterized as a greater than 5%, greater than 10%, greater than 20%, or greater than 50% increase, such as up to between 50% to 60%, compared to a corresponding shaped-charge without any of the attenuating bodies. The generated liquid jet has a gaseous bubble in an interior or a void in the front portion of the liquid jet, such that upon target impact a shock impulse is reduced to minimize risk of target explosive shock initiation. Furthermore, the liquid jet tip may narrow in width or diameter, which also reduces the risk of target explosive shock initiation. In this manner, the target is disrupted while avoiding an uncontrolled explosion for a target that is an IED or the like.
The method may further comprise the step of adjusting a jet characteristic by adjusting an attenuating body characteristic without changing a shaped-charge geometry or liquid container geometry. Examples of attenuating body characteristic include a thickness of the attenuating body layer, attenuating body volume, density, Young's modulus, porosity, material uniformity, yield strength, and shock Hugoniot properties such as the bulk speed of sound and ‘s’ number.
The attenuating body may be positioned on the shaped-charge at an incident site. Alternatively, the attenuating body may be pre-installed. For an attenuating body that is a separate component from the surface, an adhesive may be used to connect the attenuating body to a surface. The attenuating body may be an AB layer adhesively fixed to the surface, or may slip over the surface.
The method may further comprise the step of: applying a jet-clipper layer having a density of between 0.5 g/cm3 to 2.0 g/cm3 on a target surface of the explosive target; and/or applying a foam having a density less than 0.25 g/cm3 to at least partially fill a gap between the container distal surface and the target surface. The jet-clipper layer results in the rapid erosion of the jet tip, thus reducing the velocity of the water impacting the target barrier and then impacting the explosives after the bomb's skin is perforated. The jet-clipper layer also attenuates precursor shock waves generated during target impact. Notably, the use of the intervening foam and/or jet-clipper layer is beneficial when the shaped-charge is submerged underwater for example against improvised ship mines.
The explosive forming shell may have a special geometry configured to support a shape-conforming explosive and ensure a fluid is appropriately propelled from the shaped-charge toward the target. In one embodiment, this is achieved by a special geometry that is generally described herein as a catenary paraboloid, specifically a plastic shell and facing distal end of the container (also referred herein as a plastic body, so that “container” and “plastic body” may be interchanged) in which the plastic shell is positioned. The fluid immerses the plastic shell and the fluid portion between the shell surface and the distal end of the plastic body is the projectile region corresponding to liquid that will be propelled toward a target upon detonation of the explosive supported by the plastic shell surface.
As described, the shaped-charges focus a filler, including a fluid mass. The shaped-charges are particularly suited for disrupting IEDs. The shaped-charges can comprise a plastic shell having a surface with a geometric shape configured to support a shape-conforming explosive. In this manner, the geometric shape is configured to provide desired explosive characteristics on the supported explosive to force a filler or a fluid mass toward a target. The geometric shape may comprise a truncated cone having an open distal end and a closed proximal end, the closed proximal end having a smoothly-curved concave shape, an outer circumference with a plurality of cut-outs radially spaced around the outer circumference. The geometric shape may be axially-symmetric about a central longitudinal axis. A cylindrical plastic body has an interior volume for containing a liquid and the plastic shell, the cylindrical plastic body having: a plastic body closed distal end having a geometric shape that is substantially matched to the concave shape of the plastic shell closed proximal end; a plastic body proximal end that faces the plastic body distal end; wherein the plastic shell is concentrically positioned to the cylindrical plastic body with respect to the central longitudinal axis. A channel extends through the cylindrical plastic body proximal end and terminates at the plastic shell surface at a contact position coincident with the central longitudinal axis, wherein the channel is configured to accommodate a detonator. In this manner, a detonator can be operably connected to the shape-conforming explosive at the central longitudinal axis for precise and well-controlled detonation.
The shaped-charge may further comprise the shape-conforming explosive mated to at least a portion of the plastic shell surface.
The plastic body proximal end may comprise an end cap that fluidically seals the liquid and plastic shell in the cylindrical plastic body interior volume.
The shaped-charge may further comprise a detonator in a press-fit configuration in the channel and, when present, the shape-conforming explosive, to fluidically seal the liquid in the interior volume.
The shaped-charge is compatible with a range of curvatures, including a concave shape that is a catenary paraboloid.
In use, the plastic shell is laterally positioned in the interior volume of the cylindrical plastic body to form a tamper region having a tamper length and a projectile region having a projectile length, wherein a ratio of the tamper length to the projectile length is between 1:1 to 2.5:1.
The cone angle can be selected from a range that is greater than or equal to 90° and less than or equal to 150°. This reflects that the invention is compatible with a range of geometries and filler (fluid mass) characteristics. For example, depending on the application of interest, including target characteristics such as barrier properties, stand-off distance, and desired fluid impact and post-impact characteristics, the cone angle, lengths, curvatures are varied. This can impact the surface area and, therefore, the amount of explosives supported by the surface.
The shaped-charge is compatible with a range of interior volumes, including between 32 and 7040 fluid ounces and/or an outer diameter of between 3 inches and 25 inches.
The shaped-charge may have a transition region on the plastic shell surface for smoothly transitioning from the truncated cone to the smoothly-curved concave shape. In this aspect, “smoothly transitioning” refers to a continuous slope such that there are not observable discontinuities or sharp edges on the surface.
In an embodiment, the plastic shell closed proximal end has a diameter that is between 30% and 80% of the diameter of the open end.
The shaped-charges described herein may further comprise a fluid positioned in the interior volume. In an embodiment, the fluid is a highly efficient energy transfer (HEET) fluid, including any of those described in U.S. Pat. No. 11,187,487 titled “DISRUPTER DRIVEN HIGHLY EFFICIENT ENERGY TRANSFER FLUID JETS” filed Aug. 18, 2017, which is specifically incorporated by reference herein for the HEET fluids described therein. Specific examples include a combination of liquid and solid particles, such that the HEET fluid combines the advantages of both water and solid projectiles as they have viscoelastic behavior and can have solid particles mixed into a fluid, including sand mixtures, and/or is a high viscosity fluid such as corn syrup, molasses or the like.
In an embodiment, the plastic body has a sidewall thickness and a front face thickness, wherein the sidewall thickness is between 2 and 4 times thicker than the front face thickness. The sidewall is optionally formed of a plastic material having a higher density than a plastic material of the front face. Examples include, but are not limited to, polyvinyl chloride (PVC), Polyterafluroethylene, Polyoxymethylene (POM) such as Delrin® plastic, phenolic Polyethylene terephthalate (PET), polyethylene terephthalate (PETE), Chlorinated Polyvinylchloride, Phenolic plastics. Similarly, sidewall relative to front face density may have a ratio up to 1.5. As described herein, the plastic body may correspond to the container to which an attenuating body is connected.
The shaped-charge may be further described in terms of one or more of: the truncated cone has a truncated cone angle of between 90° and 150°; the smoothly-curved concave shape corresponds to a paraboloid; and/or the truncated cone and paraboloid transition at a transition region, and the transition region is approximately tangential to both the truncated cone and the paraboloid.
The shaped-charge may have an explosive weight per unit area of between 1 g/in2 and 6 g/in2.
The shaped-charge may further comprise: a spherical projectile adjacent to the exterior distal surface of the plastic body and placed at the center of the concavity along the longitudinal axis. The spherical projectile is preferably a polyball formed of a polyurethane. The spherical projectile preferably has a spherical geometry and diameter that is between about 10% to 50% of the diameter of the plastic shell open distal end. In this configuration, the spherical projectile is physically separated from the fluid contained in the plastic body by the thickness of the wall of the plastic body distal surface.
The shaped-charge has a geometric shape configured to generate a liquid jet having an annular cross-section upon impact with a target, including specifically the plastic shell surface and cylindrical plastic body closed distal end. This annular cross-section (e.g., a ring of liquid having a cylindrical outer surface) is a unique jet-shape that reduces shock impulse and thus enables the shaped-charge to have twice the explosive load of comparable commercial disrupters without causing shock initiation of explosives on impact.
The shape conforming explosive is preferably a sheet explosive or a detonation cord explosive connected to a distal-facing surface of the plastic shell.
The shaped-charge has a geometry configured to reduce a forward velocity gradient of a generated fluid jet. In this manner, the liquid fluid jet maintains integrity after explosive detonation.
The outer surface of the plastic body distal end may comprise a plurality of scores to generate petal formation, prevent cylindrical plastic body impact on the target during use and minimize risk of unwanted shock initiation. The scores may be on the outer-facing and/or inner-facing surface of the plastic body distal end. The scores may be characterized as recess features in the surface having a penetration depth. Exemplary penetration depths correspond to between 10% and 90% wall thickness, such as about 30%-60%. The exact penetration depth is variable in that the purpose of the scores is to generate structural faults, such that upon explosive motion of the filler, including a liquid fluid mass, the distal end surface of the plastic body physically separates and falls apart to avoid impact force on a barrier target. Without such scoring, there is a risk of the distal end being carried along with the front face of the filler (particulate solids or liquid fluid) jet and making impact on the barrier target, with attendant potential uncontrolled path in the target interior. Scoring the front face to induce petal formation of the plastic and using low density and high ductility plastic (Polypropylene, polyethylene) prevents the shaped-charge body plastic from impacting at close standoffs.
Also provided herein are methods of explosively driving a fluid to disrupt an explosive target using any of the shaped-charges described herein. The method may comprise the steps of: providing a shaped-charge of the instant invention with a liquid positioned in the interior volume, wherein the plastic shell is immersed in the liquid; aligning the mass focusing shaped-charge with an explosive target; initiating a detonation wave in the shape-conforming explosive that travels substantially parallel to the longitudinal axis, wherein the geometric shape and position of the plastic shell and the plastic body distal end are configured to generate a tamp and timing of rarefaction waves to increase a pressure duration and amplitude to drive the liquid toward the explosive target; and generating a liquid jet having an annular cross-section upon explosive target impact to reduce shock impulse and minimize risk of target explosive shock initiation. In this manner, the explosive target is disrupted. As described, the method may further comprise use of one or more attenuating bodies to provide further control of the impact of the rarefaction waves that otherwise adversely impact the liquid jet and/or minimize jet stretching, gasification or atomization.
Also provided herein are methods of making any of the shaped-charges described herein, such as by forming the shell, the container, and attenuating body, wherein the container can accommodate the shell in an interior volume, along with liquid, such that the shell (and explosive supported by the plastic shell) is immersed in the liquid with the attenuating body providing further improvement to the liquid fluid jet after detonation of the explosives associated with the shell.
Provided herein are shaped charges where the filler is a fluid mass. Also provided herein are shaped-charges where the filler comprises solid particles. For example, the shaped-charges may be generally similar to those where the filler is a liquid, but with a liner positioned in the container volume to separate a proximal explosive volume from a distal attenuating body volume. The liner itself has a liner volume configured to contain the solid particles. The liner may have any of a range of geometries, so long as upon explosive initiation, a jet formed from solid particles is controllably propelled on target. The solid particles may fuse under explosive pressures to form a unit mass that flows hydrodynamically. In this aspect, the shaped charges are more classical in nature, in that the filler is a more solid material that is crushed and flow in the form of a jet toward a target.
Also provided herein are propellant driven fluid disrupters comprising: a barrel having a bore with a barrel proximal end and a barrel distal end; a breech chamber operably connected to the barrel proximal end; a fluid at least partially filling the bore; an attenuating body breech plug positioned toward the barrel proximal end, such that the fluid extends from the attenuating body toward the barrel distal end; a blank cartridge positioned in the breech chamber and facing the attenuating body breech plug; an attenuating body muzzle plug positioned at the barrel distal end, wherein the attenuating body muzzle plug and the attenuating body breech plug fluidically seal the fluid in the barrel between the attenuating body muzzle plug and the attenuating body breech plug. The attenuating body breech plug has one or more attenuating body breech plug material properties configured to reduce primary shock and the attenuating body muzzle plug has one or more attenuating body muzzle plug material properties to reduce rarefaction waves upon detonation of explosives in the blank cartridge. The AB plug material properties include those describe above, such as AB thickness, material composition, bulk density, heterogeneity, geometry, a shock Hugoniot parameters such as bulk speed of sound or s-number, and any combination thereof. Shock impedance, and shock velocity is defined by the equation of state. Hugoniot parameters include material density, bulk speed of sound, and s-number. There is an approximately linear relationship between the shock velocity and particle velocity. The slope of the line is the s-number.
In an embodiment, the propellant driven fluid disrupter has at least one or both of: an AB body breech plug positioned toward the barrel proximal end, and/or an AB muzzle plug positioned at the barrel distal end. For example, one of the plugs may be a conventional-type plug. Although the invention is compatible with one of an AB plug, preferably, there is an AB body breech plug and an AB muzzle plug. In an embodiment, the muzzle plug may comprise a JSP.
The attenuating body of each of the muzzle plug and breech plug may have an independently selectable: density of between 1 lb/ft3 and 6 lb/ft3 and is a foam; crushable and pulverizable rigid closed cell foam; flexible compressible closed cell foam; material composition that is polyurethane foam, synthetic rubber, polyethylene foam, and/or neoprene. In this context, “crushable and pulverizable” refers to a material that breaks apart upon explosion, including by the explosives in a blank cartridge, so that what remains are microparticles having a micron-scaled sized particles (e.g., less than 1 mm, less than 500 μm, less than 100 μm, including average effective particle diameter).
The attenuating body breech plug may have a geometry that is a half-capsule or a right angle cylinder, or contoured to conform to the chamber, optional forcing cone and bore, each with a flat base that is adjacent to a distal end of the blank cartridge.
Without wishing to be bound by any particular theory, there may be discussion herein of beliefs or understandings of underlying principles relating to the devices and methods disclosed herein. It is recognized that regardless of the ultimate correctness of any mechanistic explanation or hypothesis, an embodiment of the invention can nonetheless be operative and useful.
In the following description, numerous specific details of the devices, device components and methods of the present invention are set forth in order to provide a thorough explanation of the precise nature of the invention. It will be apparent, however, to those of skill in the art that the invention can be practiced without these specific details.
In general, the terms and phrases used herein have their art-recognized meaning, which can be found by reference to standard texts, journal references and contexts known to those skilled in the art. The following definitions are provided to clarify their specific use in the context of the invention.
“Filler” is used broadly herein to refer to a material that is able to fill the interior volume of the container or a layer that itself define explosive volume from an attenuating body volume, immersing a shell surface, and that is capable of being explosively driven in a jet geometry toward a target. The filler can be solid-based plurality of particles, liquid-based or a combination of solid(s) and liquid(s). “Fluid” refers to a liquid-based material that is contained in the interior volume of the container and that immerses the shell surface. “Particle” refers to fine solid particles configured to form a jet toward a target after explosive propulsion. The solid particles may fuse under explosive pressures to form a unit mass that flows hydrodynamically. The shaped-charges are compatible with any number of liquids, including water and high-density liquids, such as corn syrup. As described herein and at U.S. Pat. No. 11,187,487, the fluid may be a high energy efficient (HEET) fluid. The fluid may comprise solid particles suspended in a liquid medium.
“Attenuating body” refers to one or more layers of material that are connected to the shaped-charge to provide desired control of the fluid or solid jet generated upon detonation of the explosives associated with the shell or liner. That attenuating body is also referred herein as “SMART”. The attenuating body may correspond to an AB layer that is configured to be positioned on another surface. In this aspect “connected” refers to an attenuating body that is connected to the shaped-charge in a manner that the functionality of the components of the shaped-charge is maintained. For example, an attenuating body connected to a container wall does not impact the ability of the wall to contain the liquid. The connection may be direct or indirect. For example, there may be an adhesive applied to adhesively connect the attenuating body to a surface. There may be an intervening attenuating body, such as an attenuating body layer, between a surface of the shaped-charge and an attenuating body. This is also described herein as an attenuating body multilayer configuration. One function of the attenuating body is to functionally adjust a wall surface thickness so as to impact reflected shock waves that are propagated in the contained liquid and interact with liquid/wall interfaces. The thickness of the attenuating body is selected to achieve the desired fluid jet outcome and, as explained, depends on various parameters. Exemplary thicknesses include ranges between 0.03″ and 1″. The thickness of an attenuating body may be spatially constant or spatially vary. A spatially-varying attenuating body thickness is also referred herein as a “contoured” attenuating body. The attenuating body may be conformable to a surface. In this manner, the attenuating body has a flexibility such that it can deform and conform to a surface, including a curved surface or a sharp-edged surface. The container material can be the attenuating body and thus the container thickness can be varied and contoured at various locations to provide improved jet characteristics. The container may also have a bisecting symmetry plane.
The attenuating body may correspond to a foam. “Foam” refers to a material that is formed by trapping pockets of gas in a liquid or a solid. A solid foam can be closed-cell or open-cell, depending on whether the pockets are completely surrounded by the solid material. In an open-cell foam, gas pockets connect to each other, including via pores. In a closed-cell, gas pockets are not connected to each other. The foam is polydisperse and is characterized as not uniform and stochastic. Foams efficiently attenuate shockwaves because of the heterogeneous structure in combination with low bulk density. In this manner, pressure waves are broken up and dispersed, thereby providing good shock tamping. Depending on the application of interest, which influences the desired liquid jet characteristics, the foam can be made from any of a range of materials, such as plastic, rubber (natural or synthetic), aluminum or other metals. For example, blasting cap protectors are made from aluminum foam because an aluminum foam absorbs the shock. The attenuating body may also be an aerogel. “Aerogel” refers to a synthetic porous material derived from a gel, where the liquid component has been replaced with a gas without significant collapse of the gel structure. Exemplary aerogels include, but are not limited to, solid smoke, solid air, solid cloud, blue smoke, silica aerogels, carbon aerogels, polymer-based aerogels, metal-oxide aerogels, and the like.
“AB layer” is used broadly to refer to an AB providing functional benefit of the shaped charge. The AB layer may be a layer of material affixed to and/or adjacent to another material. For example, the AB layer may be a shape-conforming material that is effectively wrapped around another surface. The AB layer may be a sleeve of material that slides over a container surface, such as container side-wall outer facing surface. The AB layer may be adhered to a surface by a layer of adhesive, such as an inner or outer-facing container surface. The AB layer may be provided with a substantial thickness so that the AB layer is effectively an AB volume that occupies a fraction of the container volume, such as up to 10%, up to 20% or up to 30% of the container volume. The AB layer may be adjacent to, in physical contact with, or connected to the distal surface of the container volume. In this manner, the AB platform described herein is versatile and can be used in a number of various configurations, depending on the application of interest. The AB layer may be a sheet of constant thickness that is contoured to the proximal container face or may be flexible and bendable such that it conforms to a contoured surface. An AB layer may be an air cell or a low density foam. The AB layer may be a volume of material that has curvature on its distal surface, and occupies a significant volume. This aspect is generally characterized as an AB layer having a substantial thickness that results in the AB layer being an AB body volume.
“Focusing” refers to the ability to force liquid in a desired direction with desired properties related to jet formation, stability, and impact pressure or force against a target, including post-barrier penetration.
The term “substantially matched” refers to two components that are similar. In the context of a geometric shape, it refers to a deviation from absolute correspondence that does not adversely impact functional properties associated with the fluid jet and target disruption. The term is intended to reflect that the shaped-charges provided herein are able to tolerate differences between surfaces (e.g., plastic shell surface and cylindrical plastic body distal end) without significant degradation in a liquid jet parameter. As desired, the term may be optionally quantitatively defined, such as curve parameters that differ by less than 10% from each other, such as curvature, distances, and any parameters associated with a corresponding curve fit, such as:
where the parameter “a” is within 10% for each of the two best-fit curves (with surface then formed as a rotation of the function about the central longitudinal axis). In a similar manner, best-fitting of any of the curves or corresponding surfaces may be performed to define whether two surfaces are substantially matched.
Unless otherwise defined, “approximately” or “substantially” refers to a value that is within 10% of a desired or true value, and can correspondingly include identically matched.
“Proximal” and “distal” are relative to the detonator and target. A distal position is further from the detonator and closer to the target than a proximal position. In other words, distal is toward the direction of a target, and proximal more away from the target. The terms are useful in describing relative positions of components.
The terms “central longitudinal axis” and “bisecting symmetry plane” are used to refer to relative positions with respect to the shaped-charge and associated target. In general, a longitudinal axis corresponds to the notional line leading from the shaped-charge toward a target, and is relevant for shells that have a container volume for containing an explosive. A “bisecting symmetry plane” is generally relevant for a shell having a surface to support a surface-conforming explosive. For desired fluid jet characteristics, the surface has a plane of symmetry, referred herein as a bisecting symmetry plane, where the distal shell surface faces toward the target through the container distal end.
The invention can be further understood by the following non-limiting examples.
Referring to
The shell 30 has a shell distal end 33, a shell proximal end 34 and a shell sidewall 35 that connects the shell distal end surface with the shell proximal surface, with shell bisecting symmetry plane illustrated by 120 in
As discussed herein, the attenuating body 11 is selected and positioned to provide desired filler or fluid mass expulsion characteristics by controllably manipulating reflected shock waves upon detonation of the explosives positioned in the container with attendant fluid shock wave/wall surface interaction. Particularly relevant attenuating body characteristics are material composition and body thickness 12. Preferred thicknesses include a thickness between 0.03″ and 1″ or between 0.75 mm and 2.6 cm. The attenuating body may contact an outer and/or inner surface of container 25. In some embodiments, attenuating body 11 may contact at least a portion of a surface of the shell 30, including contacting both a container surface and a shell surface, or only one of a shell surface or a container surface. In a preferred embodiment, the contact is to an outer surface of the container 25. The container 11 surfaces may include container distal 210, proximal 220 and side surface 205. A stem 42 may accommodate channel 250 through which an explosive initiator operably connects, such as an electrical line for an electronically-triggered explosive, with a fluid jet directed to a target 1700. In this manner, there is an initiator contact point 251 configured to initiate detonation of the explosive (whether explosive volume or shape-conforming) to drive filler out the distal end of the container toward a target in the form of a filler jet 2110 (see, e.g.,
The shaped-charges and related methods of using an attenuation body, such as by lining the side-wall or the front-face of a jetting water high explosive shaped-charge with specific materials and thicknesses, increases the fluid jet efficiency. Side-wall lining with an attenuating body increases the measured relative work, impulse and penetration by up to 50%. Water gasification is reduced and a slight increase in inertial tamping increases the jet velocity. Alternatively, using an attenuating body on the front face has a different beneficial effect. Front-face attenuating body having a low density and optionally contoured material dramatically increases the charge's effectiveness at greater standoffs by lowering the rate of jet stretch.
Water and other fluids (e.g., HEET) can be driven explosively using shaped-charges to form liquid jets which move at relatively high velocity and can perform work on a target. Explosives are shaped and immersed in the fluid (e.g., water) or placed on the outside of a water container. The explosives' detonation produces shock waves that move through the water. Typically, to create a jet, the charge is configured such that the shocks along a central axis or a bisecting plane converge and form a Mach stem. The pressure is higher in the center compared to the sides. A pressure gradient results in the water accelerating differentially as its position moves away from the center. The result is a jet that has a velocity profile with faster water at its front and the gradient is such that the water slows as one moves towards the explosive gas products.
The attenuating body provided herein stabilizes the fluid and reduces gasification and atomization resulting from shock waves in the fluid. This maximizes the amount of liquid fluid propagating in the jet and increases the distance the jet will travel in air or inside a medium before it breaks apart. Most jets fail to propagate beyond a few feet in air. The work function and impulse are highly dependent on the velocity of the jetting liquid and the mass of fluid during impact with an object.
In the arts of improvised explosive device (IED) neutralization or ordnance disposal, jetting fluids can be used to break apart bombs. Containers are accessed, fuze components are destroyed, and explosives and components are expelled and separated. If the purpose of the jetting water is to neutralize IEDs, the fluid mass focusing shaped-charge is referred to as a high explosives disrupter. These tools can also be used to breech structures such as bomb casings, vehicle bodies or buildings.
When a shaped-charge is initiated, the detonation wave couples to the fluid and it generates shock waves inside of the fluid. These shocks are essential in creating a particle forward velocity gradient which macroscopically causes the formation of a fluid jet. Without the velocity gradient, the fluid tends to move as a unit mass and not jet. These jetting fluid can do work cutting through materials such as steel and low strength continuous media. Fluid jets, due to their relatively low density and high heat capacity, are preferred to access and disable IEDs. The relatively low impact pressures have a reduced risk of shock initiating explosives inside an IED or bomb. In addition, due to a fluid jet's resistance to compression, including for water, high mass, inviscid and inelastic nature, the duration of loading is very long, resulting in maximized momentum and energy transfer to impacted targets.
Unfortunately, the very same shock waves that are necessary to form the fluid jet ultimately result in its destruction. They cause the fluid to atomize and to gasify, thereby adversely impacting jet integrity and attendant energy transfer. Liquid fluids, including water, cannot withstand tensor or hoop stress and thus forms droplets as the jet expands radially and stretches apart from lengthening. Furthermore, at room temperature, water boils at relatively low pressures. For example, at 25° C., water boils when the atmospheric pressure above liquid water surface drops to below approximately 0.5 psi. After the explosion, because of the water's high heat capacity, the bulk of the water in the charge container remains at room temperature. As explained below, water vapor bubbles form inside the water projectile region and these bubbles progressively grow. Generally, a vapor bubble forms along the symmetry axis or plane of the water-filled charge and at the corners. The bubbles can destroy the jet early in its formation so that the bulk density of the jet is too low to perform work. The water is transformed into gas rather than forming a jetting liquid.
The water gasification results from the shock waves associated with detonation of the explosive that reflect at the container walls, and water-air boundaries. The shock wave unloads and the reflected wave is a rarefaction wave also known as a release wave. Unlike the primary compressive shock wave caused by the explosion, rarefaction waves are tensor waves and are negative pressure waves. At the front face, due to the intensity of the primary shock wave, the reflective wave can be at the critical pressure to induce water bubble formation. The tension is amplified when the rarefaction waves collide. The tensor stress causes a void in the water which then creates a surface for the water to boil at the interface with the void. This is the reason the explosive's distance from the container front-face and tamp-back wall is critical to allow the principle shock to attenuate. At the corners, the shocks reflected off the side and the front converge and amplify also causing gasification at the corner of the jet. Once a water vapor bubble forms there is a second water-gas boundary and now shock reflections occur at this interface. The process results in the continual growth of the gas bubble until the shocks dissipate.
The amplitude of the reflected shocks and the decompression of the fluid (e.g., water) is dependent on the shock impedance and the shock Hugoniot properties of the container, air, and fluid (e.g., water). Two well defined properties are the bulk speed of sound and the pre-shock density. Generally, the container shell thickness for most mass-focusing shaped-charges is uniform and very thin because of the cost and the plastic material molding process. Typical container wall thicknesses are between 0.01″ and 0.08″ and thus do not contribute much to the shock effects. However, we recently observed that changing the plastic wall thickness to between 0.25″ and 0.5″ on the sides of a container can be beneficial. However, increasing the front wall thickness can be highly detrimental for two main reasons. The first is the plastic fragments can be driven at high velocity and shock initiate explosives when they impact an IED. The second effect is not so obvious and that is the dramatic reduction of the forward velocity gradient. The fluid is projected forward as a low velocity slug rather than forming a jet. Understanding and accommodating these effects are important for the configuration, positioning and use of attenuating body to better control and improve fluid jets with attendant functional benefit of tailored impact to the target.
Experimentation and CTH hydrocode modeling further clarify the reason for the improved jetting properties of manipulating the high explosive disrupter container side-wall material and thickness. Using 0.25″ thick ASA 3D printed plastic side wall to the CAT shaped-charge results in a 50% increase in cavitation and in penetration, and a 40% increase in impulse. 3D printed ASA material is considered a non-ideal material in that it is inhomogeneous in structure and density and as a result is similar to foams, which are known to attenuate shocks. Shock attenuation is also dependent on the speed of sound and the density. Generally, lower speed of sound materials and/or lower density materials will attenuate shocks more efficiently. The ASA has the approximate density of water and is a form of acrylic which has similar sound speed to water. There is not a significant inertial tamping benefit. The improvement in performance is believed to be due to the shocks on the side-wall attenuating through the plastic and also due to the timing mismatch of the release waves traveling back into the water compared to the front.
Experiments with an attenuating body corresponding to a 0.25″ thick silicone rubber lining the side-wall has similar results to the ASA material. The silicone rubber has a measured density of 1.25 g/cm3 and the ASA material is reported to have a density of approximately 1 g/cm3. If density was a primary contributor due to increased inertial tamp then a 25% increase in density should show a measurable increase in performance, but it did not improve penetration in a multi-layered panel penetration test. The observed results are consistent with the theory of shock attenuation in the sidewall and reduction of the Mach stem effect at the front corner due to timing mismatch created by differing wall thickness at the front and side. The front corner region is predicted to be the most sensitive zone to add side-wall material. To validate this, a band of silicone rubber was placed only on the sides of the projectile region of the water and not the back tamp water in the container. In the multi-layered spaced panel test, the partially covered sidewall performed similarly to the completely lined sidewall.
To assess the benefits of inertial tamping and using a high strength material to further confine the water, CTH modeling was conducted for the CAT mass-focusing shaped-charge using a 0.25″ thick steel sidewall liner. Steel is approximately 8 times the density of water. The result was poor jet formation and gasification of the water in the projectile region. The high speed of sound in steel, above 5,500 m/sec, and the impedance mismatch at the steel-water boundary, transitioning from a high Z to a low Z material resulted in amplification of the rarefaction wave effects. From this, we conclude that the preferred attenuating body material is a low Z material compared to water and a lower speed of sound material, non-ideal. Representative ranges of low Z values as comparing the acoustic impedance difference to water: silicone rubber −27%, polyethylene foam −22.6%, natural gum rubber −1%, LDPE 19%, polyurethane 20%, neoprene 31%, HDPE 55%, polypropylene 60%, and PVC 118%. In contrast, steel is a high Z material and its acoustic impedance difference compared to water is 2998%. The materials relative shock impedance difference to water is similar to their acoustic impedances. Shock impedance is more complex because it will change with the shock velocity, which depends on the quantity of explosives used.
High percent elongation materials would hold together longer as they stretch from the radial expansion after the explosion. The shocks are reflected repeatedly in the water and a material that stays in contact with the water for a longer duration would further improve their effectiveness. Natural gum rubber has a relatively low sound speed, 1,500 m/s, comparable to water at 1,480 m/s at room temperature. Rubbers are well known for very large percentage elongation, and natural rubber is reported to stretch to 500% without failure. A36 mild steel, in contrast, has an approximate percent elongation of 20%-40%.
Experiments are conducted by wrapping the axisymmetric CAT shaped-charge side wall with 0.25″ and 0.5″ thickness natural gum rubber sheet as the attenuating body. This performs slightly better than the silicone rubber sheet attenuating body but has a density of approximately 1 g/cm3. In a multi-layered spaced panel test in which the layers were separated by a 3″ spacing, the CAT shaped-charge covered with the 0.25″ thickness sheet showed a 50% increase in penetration compared to the tool with no wrapping. The 0.5″ thick natural rubber sheet showed a 30% increase in penetration compared to the control and the average hole diameter in the panels is slightly larger. Furthermore, only covering the water slug region of the CAT with the attenuating body has similar results compared to the sidewall completely lined with the attenuating body.
CTH in silico modeling experiments were completed on a linear mass focusing shaped-charge with an attenuating body made from various materials such as silicone, Teflon®, neoprene, PVC, and polyurethane. For polyurethane, the density was varied. The attenuating body thickness was 0.25″ thick or 0.5″ thick in the CTH simulations. In all cases, the experiments show a slight increase in jet tip velocity and a jet with reduced gasification compared the control simulation without an attenuating body. In addition, substituting an attenuating body with the equivalent volume of water did not improve the jet or reduce gasification.
The benefits of a sidewall attenuating body applies to all axisymmetric and linear mass-focusing shaped-charges. The lining that is the attenuating body does not measurably increase the weight or the dimensions of the charges. This makes the attenuating body a practical way to improve efficiency by optimizing the amount of fluid (e.g., water) contributing to penetration, cavitation and impulse for the same net explosive weight. The practical deployment of the high explosive disrupters is not adversely impacted and optionally the attenuating body can be added at the incident site simplifying deployment. For example, the attenuating body can be an AB layer that is positioned over an outer surface, and any portions thereof, of the shaped-charge container. Rapid application can be done by using a pre-applied high strength tape such as 3M VHB Transfer Tape. The cost of most rubbers and plastics such as PVC are reasonable making volume production of AB layers affordable. The velocity will not increase significantly which means there is no increase in the risk of shock initiation due to the jet impacting an IED in a region containing explosives. Several commercially available high explosive disrupters would receive immediate benefits from the attenuating bodies and related methods described herein.
Placing an attenuating body at the front (e.g., distal surface) of a high explosive mass focusing shaped-charge has a very different effect than placing an attenuating body on the container sidewall. CTH simulations of polyurethane foams placed on a charge face of varying density from 0.015 g/cm3 to 1 g/cm3 were examined. The thickness was one inch for all densities. The lowest density had no observable effect. At the 1 g/cm3 density the jet did not form and the water moved as a unit mass and there was a reduction in gasification at the jet central plane. At 0.5 g/cm3, gasification at the jet central plane was reduced and the jet stretch was significantly slowed. The forward velocity gradient was reduced. At the one charge diameter distance, the jet was wide and the length shortened. The CTH stimulations predict that the jet would produce large cavities but low penetration through medium at typical standoffs of one charge diameter. A reduced forward velocity gradient has the benefit that the rate of jet lengthening is slower and thus the high explosive disrupter produces jets that remained intact at significantly larger standoffs before the jet is stretched apart into droplets.
Experiments with GreatStuff™ foam, 0.016 g/cm3, of approximately 1-inch thickness at the charge face did not show a loss in penetration in the multi-layered separated panel tests. These observations are consistent with CTH simulations.
Underwater tests indicate there is a dramatically reduced performance of commercially available mass-focusing shaped-charges. The effectively infinite medium of water at the front of the charge may have similar effects as the CTH modeled 1 g/cm3 foam materials that are placed against the charge front face. The jet will not form and the water in the charge will move as a unit mass. In addition, the ideal penetration equation predicts that in a fluid-fluid interaction, water jet erosion pushing through water dramatically reduces the distance the jet will travel before being completely ablated. We have shown in underwater experiments that placing a foam, such as 0.15 g/cm3 density Styrofoam®, between the charge face and the target results in jet formation and perforation of thin steel barriers. Furthermore, the jet penetrates through a medium of gun powder placed adjacent to the steel barrier. In one embodiment, we use a hemi-cylindrical mass-focusing linear shaped-charge.
Multiple layers of materials are beneficial in controlling the shock impact effects on explosives inside of IEDs, including at the disrupter distal surface that faces toward the IED. Accordingly, provided herein is an attenuating body formed from a plurality of attenuating body layers. We demonstrate the limits to the quantity of explosives that should be used to drive water to neutralize bombs. Water jets from disrupters can shock initiate common IED explosives after impacting the skin of a bomb. Disrupter standoff may need to be adjusted such that the jet tip erodes in flight. At the time of arrival, the velocity on impact is lower due to the forward velocity gradient for longer standoff distances. This results in the impact pressure, which is proportional to the square of the jet velocity, to be reduced below the critical pressure of initiation of the IED's explosives. Furthermore, jet stretch causes the fluid tip to narrow which also reduces the shock impulse. This increase in the distance to traverse to the target causes the jet to stretch and atomize and thus results in reduced performance such as lower target cavitation and impulse. Based on this, provided herein are shaped-charges and related methods that avoids the need to change the standoff by using an optional low-density foam to fill the gap between the shaped-charge distal surface and the target. The low-density foam is coupled with a layer of higher density material near or in contact with the bomb barrier. The higher density material can be a density of 0.5 g/cm3 to 2 g/cm3 and adjacent to the target. This material clips the jet and exploits the shock impedance of the materials and the process of shock attenuation to reduce the impact pressures and compressive heating of the IED explosives that are on the other side of the bomb barrier. We refer to this layer as a “jet clipper” layer and is further helpful in IED defeat. The jet clipper layer can be used with or without a low-density foam medium and has been experimentally shown to reduce the probability of shock initiation of IED explosives (see, e.g.,
Using attenuating bodies greatly improves the efficiency of high explosive shaped-charges that drive a fluid, including water. For a given explosive weight the relative work and penetration is readily increased by 50% through the use of attenuating bodies compared to an equivalent fluid mass focusing shaped-charge without an attenuating body. The increase in the mass of the jet because of preservation of liquid water contributed to a 40% increase in impulse. Attenuating bodies, including AB layers, are cost effective and can be prefabricated into the charge design through molds or connected to the sidewalls by various connectors, such as clips, fasteners and/or adhesives. For axisymmetric charges, the attenuating body can be slipped onto the body, including on an outer surface of the container. Molds for plastics and synthetic rubbers such as polyurethane can be made such that the container sidewall is of an optimized thickness compared to the front. The front of the container (distal container surface) should be as thin as possible for maximum work, penetration and impulse. Also, the thin-walled distal container surface reduces plastic impacting the target. Foams at the jet front can be used to preserve liquid water by reducing water gasification and dramatically reduce the forward velocity gradient. Foaming the disrupter front by providing foam to the container distal surface, or anywhere between the target and container distal surface, improves the jet's effective working distance because the jet will form more slowly and thus be intact at greater standoff distances. Attenuating body materials, including an AB layer, are affordable and do not drastically increase the cost of the charge. The attenuating body may be an AB layer that is formed from distinct attenuating body layers. The total additional volume and weight does not greatly increase and so portability of the charge is not adversely affected. For the first time, a high explosive disrupter's jet characteristics can be modified without changing the charge geometry or the shaped-charge container that contains the fluid. Examples include, but are not limited to, wraps, sleeves, appliques such as spray or painted on materials, which can be provided on-site or ahead of time.
A Catenary Advanced Technology (CAT) disrupter is a mass focusing shaped-charge that explosively drives a large volume of water, or other liquid such as Highly Efficient Energy Transfer (HEET) fluid as described in any of U.S. patent application Ser. No. 15/731,874, U.S. Pat. No. 10,451,378, U.S. Pub. No. 2020/0025508, each to Vabnick et al. The liquids jet at relatively high velocity to disrupt improvised explosive devices (IEDs). The jet may perforate the barrier(s) of a bomb, destroy fusing components and cause separation of the firing train to include expulsion of the explosive main charge. The CAT disrupter has an axially symmetric geometry. The shell may be formed of a plastic material, that shapes the explosives (also referred herein as an HE former) is a hybridization of a truncated cone at the opening which transitions to a smooth-curved surface such as a parabola at the closed end. Sheet explosives are mated to the surface of the HE former. An enhanced water charge (EWC) was previously developed using a plastic bowl lined with sheet explosives or lined with overlapping wraps of detonation cord. As with all mass focusing shaped-charges, the CAT disrupter uses a Mach-stem effect to cause a higher pressure field along its axis of longitudinal symmetry. The water near the center is accelerated more than the water in the periphery. The CAT disrupter fluid jet tip can be explosively propelled in a range from transonic to supersonic velocities. The jet velocity can be controlled by the amount of explosives applied to the explosive former or by modifying disrupter geometric parameters to include cone angle and tamper mass-to-projectile mass ratio. Due to the HE former's parabolic base, the water is collimated and has a greatly reduced forward velocity gradient (FVG) compared to other mass focusing charges. This results in unprecedented penetration and effective working distance. The CAT shaped-charge can disrupt IEDs up to four times farther than other fluid mass focusing disrupters of comparable size. Modification of the cone angle can also be used to change the jet profile including the cross-sectional area at any point along its length.
One embodiment of the CAT disrupter has a container volume of approximately 64 ounces and drives a water slug that is 5 to 10 times the volume of the water projectile in a propellant-driven water cannon/dearmer such as the percussion actuated non-electric (PAN) disrupter (U.S. Pat. No. 4,957,027) or similar dearmer.
The CAT disrupter jet profile in cross section is similar to the jet formed by the PAN with the Reverse Velocity Jet Tamper (ReVJeT) disrupter enhancer adapter (U.S. Pat. No. 10,451,378). The CAT disrupter average jet cross sectional area is significantly larger and travels at higher velocity. Using the maximum explosive load tested, the velocity of the CAT disrupter jet tip averages five times faster than that of a PAN jet.
Several inefficiencies in mass focusing explosive shaped-charges are minimized in the design of the CAT disrupter. A dominant destructive hydrodynamic factor in all mass focusing high explosive tools is the FVG. The jet will break up into droplets or particles, thus losing the jet's effective density and its ability to transfer momentum and energy. The FVG can be explained qualitatively by dividing the jet into discrete elements. Proceeding from the rear of the jet to its front, each element is progressively faster. The rate of jet stretch increases with explosive load. The FVG can be complex and may not be linear. The jet stretches apart by this hydrodynamic stress. Atomization also occurs from the turbulence inside the jet and air drag along its front and sides. The CAT disrupter FVG is considerably reduced compared to other disrupter high explosive shaped-charges described herein. As described, further improvements are provided by attenuating body, including on the container distal surface, foam and a jet-clipper layer positioned toward the target, including adjacent the target surface.
The disrupter can also be used to drive HEET fluids (U.S. patent application Ser. No. 15/731,874 titled “High Energy Efficient Transfer Fluids” filed Aug. 18, 2017). There are experimentally demonstrated advantages which show that higher density liquids have improved penetration, notable increases in bulk work and momentum transfer and, due to their higher mass can lower jet velocities. The latter is important when impact sensitive explosives are present inside an IED. Due to the hydrodynamic characteristics of the jet, the impact pressures have a squared dependence with jet velocity. The shock Hugoniot properties of the HEET fluids also may contribute to the reduced risk of shock initiation of explosives inside an IED when they are impacted by a disrupter jet. In addition, experiments showed HEET-filled disrupters had increase performance with respect to stand off.
An initiator comprising a detonator can be coaxially seated in contact with charge apex and initiated. The resultant detonation wave shock couples into the water and shock waves move inside the fluid. Due to shock impedance at the water-container interface, the shock rarefaction waves reflect back into the water slug which can further contribute to water movement. In one embodiment of the CAT disrupter, the sidewalls of the fluid container were three times thicker than the front face and used higher density PVC compared to the front face which was made from ASA material. Tests of CAT disrupters constructed from uniformly thick ASA sidewalls and front were less efficient at penetration and impulse than the CAT disrupter embodiment using a thick PVC side wall. Provided is a method of using inertial confinement and shock impedance to increase the efficiency of the CAT disrupter. Thus, PETE plastic on the side wall can further improve the efficiency of the CAT disrupter given it is of higher density than PVC. PVC and PETE are 1.35 and 1.5 times the density of ASA, respectively. As described herein, and illustrated in
We observed that thickening the wall on the front face of the charge and using a high strength, brittle plastic had negative effects on performance. High explosive disrupters whose front surface are made from low ultimate tensile strength and high tensile elongation plastics such as low-density polyethylene (LDPE), high density polyethylene (HDPE), or polypropylene (PP) should have better performance with respect to jet velocity, penetration and impulse. Wall thicknesses between 0.02 inches and 0.08 inches result in good performance. Brittle plastics that have similar densities to water fracture into particles that travel along with the jet and resulted in explosive initiation on impact with targets filled with common explosives. The attenuating bodies provided herein can address these issues.
Due to the normalized velocity profile of the CAT jet, a high strength, high durometer (80-95) polyurethane ball can be placed at the axial center of the shock wave dampener. The ball can be used as a jet stabilizing projectile (JSP) (U.S. Pat. Pub. No. 2021/0041205 (published Feb. 11, 2021; now U.S. Pat. No. 11,262,155, incorporated by reference herein) titled “Fluid Jet Stabilizing Projectile for Enhanced IED”) and behaves similarly to the JSP used with the PAN disrupter and ReVJeT adapter. Such a ball is particularly useful for jet tip shapes that are annular, as such a shape promotes hydraulic trapping of the polyurethane ball. The polyball seats inside the hollow region of the jet and is trapped by the jet due to its flow properties. The ball causes a slip stream such that air drag is reduced around the jet tip and a low-pressure zone behind the ball will cause the water to flow forward around the rear surface of the ball creating hydraulic stabilization of its flight. The advantages of a JSP for bomb disablement is increased barrier limit thickness and the reduced surface area on impact which is known to lower shock impulse as previously described. Polyurethane has similar shock Hugoniot properties as water and thus reduces the risk of shock initiation of explosives due to shock impedance. The JSP should be 10% to 50% of the CAT container diameter to produce the air drag benefits. In comparison, Rock et al. (U.S. Pat. No. 8,677,902) propose using a small metallic bead in the apex of the hollow void (shock cavity) of their LIFT charge. They propose the small bead material to be copper, steel, lead or depleted uranium, which are at least nine times the density of water. The small bead is explosively driven forward, but does not ride the jet tip. There is an extreme forward velocity gradient in a conical LIFT and the metal bead would not behave like a JSP. The JSP can be encased in an attenuating body on the distal face of a high explosive disrupter. The attenuating body may have a recess to optionally seat a JSP. See also, U.S. Pat. No. 11,421,971 (incorporated by reference herein).
In one embodiment, the shell is specially configured to have a desired geometric shape to achieve the desired functional benefits described herein with respect to a subsequently generated fluid projectile. The shaped-charges provided herein are compatible with a range of shell types and shapes. For example, more generic shapes are reflected in
In terms of geometrical shape having curvatures,
The position of the shell surface 40 along the central plane can be adjusted by changing the position of the shell stem 42 that accommodates channel 250 for the initiator detonator.
A channel 250 is configured to operably connect to an initiator detonator for detonating shape-confirming explosive that is at least partially mated to shell surface 40.
The shell 30 has a specially configured surface to ensure appropriate forces on the filler (including a liquid fluid mass) 20 contained in the container interior volume 27 of the container 25 upon detonation of explosives supported by the shell surface. In an embodiment, the shell is a plastic shell. A shape-conforming explosive is positioned on the shell surface, wherein the plastic shell surface has the desired three-dimensional geometry. The plastic shell surface can be concave-shaped. The concave-shaped surface is a “catenary paraboloid”, such as generally illustrated in
As illustrated in
Optionally, the shell distal end has one or more scores to facilitate, after detonation, well-controlled separation of the distal end to further reduce risk of unwanted detonation.
Various additional embodiments are illustrated in
The devices and methods provided herein are compatible with a filler which comprises solid particles, such as solid particles that have fluid-like characteristics. The solid particles are sized and have characteristics such that they may flow under an applied shear. Accordingly, the filler may be described as being formed of fine particles. Fine refers to an average particle diameter that is sufficiently small such that the filler, as a whole, has fluid-like capabilities including flowing under an applied shear force and forming a jet from the shaped-charges described herein, and that can move in a manner so as to fill a desired volume. For example, the particles may have an average characteristic diameter that is less than or equal to 5 mm, 1 mm, 500 μm, or 40 μm. Exemplary materials from which particles may be formed include, but are not limited to, shot (e.g., S70 shot), glass, garnet, sand, ceramic, plastic, metal (e.g., copper, brass, or lead), hydrocarbons, sugar, and/or salt.
Any of the devices and methods may have a container with a built-in funnel so that solid particles may be poured into the container, including within a liner positioned in the container. The SMART devices and methods provided herein can be applied for a filler that comprises solid particles, including for liners having any of a variety of geometries that contain the solid particles, including conical-shaped, portion of a cone, linear (wedge-shaped), hemi-cylindrical; hemi-spherical; and symmetrically curved side surfaces that optionally extend from a central flat region that is a flat surface (trumpet-shaped). Because solid particles cannot withstand hoop stress or any tensor stress, and certainly not to the extent a filler that is liquid can, incorporating SMART is particularly beneficial in the context of a filler comprising fine solid particles to reduce those stresses and provide an improved jet comprising solid particles.
Provided herein are liner-based shaped charges wherein the fill comprises particles, including solid particles positioned within the liner, and/or a unitary and continuous material formed from a ductile material with a wall thickness of up to 0.25″, with an attenuating body (SMART) material positioned adjacent to a distal liner surface. Use of such a SMART-liner configuration beneficially provides an increased efficiency of the shaped charges. This provides an important functional benefit of reducing the required quantity of explosives that would otherwise be needed and attendant dramatic decrease in costs. Applications include mining applications. In addition, in a breaching application, use of such a SMART-liner configuration has the added benefit of reducing or avoiding hazardous fragments from conventional breach tools that have metal skins.
Adjacent to the liner proximal surface 2630, explosives are positioned in the explosive volume 2640 defined by the liner proximal surface 2630 and container 25 walls. Liner distal end 2650 is sealingly connected to the container sidewall, including by attenuating body 11, or a separate seal layer, such as a ring, positioned around the region between the liner distal end 2650 and container 25. As desired, additional attenuating body 11a may be positioned adjacent to the container sidewall to further influence jet characteristics. Attenuating body 11a and 11 may be the same or may be a different material, such as a layer material 11a and a foam material for 11. The geometry of the liner refers to the liner narrowing to a minimum distance 2660 at the proximal-most position of the liner corresponding to the minimum distance between liner and container 25 proximal end. Filler corresponding to particles 2670 are positioned in the liner, illustrated as liner volume 2675, and may be filled via a funnel 2300 (see, e.g.,
Instead of comprising particles, the liner can alternatively comprise a unit mass of material, including a conventional classical shaped charge liner. Exemplary liners include, but are not limited to, a shaped sheet of a ductile materials, such as copper, steel, or the like, of defined wall thickness up to 0.25″.
An AB can be used as the breech (e.g., chamber) plug and as the muzzle plug of a gun disrupter, namely a propellant-driven liquid disrupter. In this manner, a plug formed of an AB material can be used as a shock decoupler between the water column in the barrel and the explosive cartridge, including a blank cartridge, used to propel water out of the barrel in a water jet. Such disrupter platforms generate waves that can adversely impact and even destroy the water jet, as confirmed by high-speed video and in flash X-ray. See, e.g., U.S. Pat. Nos. 10,451,378 and 10,760,872, describing a ReVJeT device useful in enhancing liquid jet parameters. Addressing and avoiding pressure waves are beneficial. When the pressure wave arrives at a water-air interface, it reflects back into the water column as a rarefaction wave (tensor wave). It has the same damaging effect, but to a lesser degree, than the high explosives generated rarefaction waves. Any time there is a transition of a high impedance material (water) to an extremely low impedance material (air) the reflected wave pressure amplitude changes sign. Thus, when the rarefaction wave arrives at the proximal (chamber side) of the water column, it reflects back into the water as a compressive wave. We see the effect as rings of water spraying radially because water cannot withstand hoop stress. The damaging pressure waves are even more pronounced in shorter barrels.
The AB (e.g., SMART material) attenuates the explosive wave at the proximal end of liquid in the disrupter barrel and then the AB positioned at the muzzle end of the disrupter barrel further attenuates the reflected wave at the distal side of the water column, in a manner similar to that explained in the earlier examples related to the high explosive shaped charges. The tensor wave amplitude is lower.
In conventional systems having a breech plug that is not an AB, the non-AB plug, due to the muzzle blast, appears to be driven up through the center of the water column of the water jet. It is similar to driving a nail through the middle of the water column, with the result being that the water column is hollowed out. In contrast, a plug formed of an AB, such as a foam material, will break up and atomize. This avoids the problem of a conventional non-AB plug that is driven up the center of the water column and thus degrades and even destroys it and adversely impacts a desired jet parameter useful for target disruption. This reflects the fact that a “tube” of water has much less penetration than a “rod” of water.
In addition, to the advantages of using an AB described for the above mass focusing shaped charges, specially configured and positioned AB provides important functional benefits for water cannons, described herein as a propellant driven disrupters that explosively drive a jet of liquid from a barrel to a target. Referring to
Breech plug AB can have any of a variety of geometries, including but not limited to, a geometry that is a half-capsule 2761 (
A cylindrical 2762 (right-angle) AB plug is illustrated in
The invention is compatible with use of at least one of an AB muzzle plug and AB breech plug. For example, the AB muzzle plug could instead be a JSP, including any of the JSP's provided in U.S. Pat. No. 11,262,155, which is specifically incorporated by reference herein for the JSP geometry, compositions, and uses.
All references throughout this application, for example patent documents including issued or granted patents or equivalents; patent application publications; and non-patent literature documents or other source material; are hereby incorporated by reference herein in their entireties, as though individually incorporated by reference, to the extent each reference is at least partially not inconsistent with the disclosure in this application (for example, a reference that is partially inconsistent is incorporated by reference except for the partially inconsistent portion of the reference).
The terms and expressions which have been employed herein are used as terms of description and not of limitation, and there is no intention in the use of such terms and expressions of excluding any equivalents of the features shown and described or portions thereof, but it is recognized that various modifications are possible within the scope of the invention claimed. Thus, it should be understood that although the present invention has been specifically disclosed by preferred embodiments, exemplary embodiments and optional features, modification and variation of the concepts herein disclosed may be resorted to by those skilled in the art, and that such modifications and variations are considered to be within the scope of this invention as defined by the appended claims. The specific embodiments provided herein are examples of useful embodiments of the present invention and it will be apparent to one skilled in the art that the present invention may be carried out using a large number of variations of the devices, device components, methods steps set forth in the present description. As will be obvious to one of skill in the art, methods and devices useful for the present methods can include a large number of optional composition and processing elements and steps.
As used herein and in the appended claims, the singular forms “a”, “an”, and “the” include plural reference unless the context clearly dictates otherwise. Thus, for example, reference to “a cell” includes a plurality of such cells and equivalents thereof known to those skilled in the art. As well, the terms “a” (or “an”), “one or more” and “at least one” can be used interchangeably herein. It is also to be noted that the terms “comprising”, “including”, and “having” can be used interchangeably. The expression “of any of claims XX-YY” (wherein XX and YY refer to claim numbers) is intended to provide a multiple dependent claim in the alternative form, and in some embodiments is interchangeable with the expression “as in any one of claims XX-YY.”
When a group of substituents is disclosed herein, it is understood that all individual members of that group and all subgroups, are disclosed separately. When a Markush group or other grouping is used herein, all individual members of the group and all combinations and subcombinations possible of the group are intended to be individually included in the disclosure.
Every device, system, formulation, combination of components, or method described or exemplified herein can be used to practice the invention, unless otherwise stated.
Whenever a range is given in the specification, for example, a temperature range, a time range, or a composition or concentration range, all intermediate ranges and subranges, as well as all individual values included in the ranges given are intended to be included in the disclosure. It will be understood that any subranges or individual values in a range or subrange that are included in the description herein can be excluded from the claims herein.
All patents and publications mentioned in the specification are indicative of the levels of skill of those skilled in the art to which the invention pertains. References cited herein are incorporated by reference herein in their entirety to indicate the state of the art as of their publication or filing date and it is intended that this information can be employed herein, if needed, to exclude specific embodiments that are in the prior art. For example, when composition of matter are claimed, it should be understood that compounds known and available in the art prior to Applicant's invention, including compounds for which an enabling disclosure is provided in the references cited herein, are not intended to be included in the composition of matter claims herein.
As used herein, “comprising” is synonymous with “including,” “containing,” or “characterized by,” and is inclusive or open-ended and does not exclude additional, unrecited elements or method steps. As used herein, “consisting of” excludes any element, step, or ingredient not specified in the claim element. As used herein, “consisting essentially of” does not exclude materials or steps that do not materially affect the basic and novel characteristics of the claim. In each instance herein any of the terms “comprising”, “consisting essentially of” and “consisting of” may be replaced with either of the other two terms. The invention illustratively described herein suitably may be practiced in the absence of any element or elements, limitation or limitations which is not specifically disclosed herein.
One of ordinary skill in the art will appreciate that starting materials, biological materials, reagents, synthetic methods, purification methods, analytical methods, assay methods, and biological methods other than those specifically exemplified can be employed in the practice of the invention without resort to undue experimentation. All art-known functional equivalents, of any such materials and methods are intended to be included in this invention. The terms and expressions which have been employed are used as terms of description and not of limitation, and there is no intention that in the use of such terms and expressions of excluding any equivalents of the features shown and described or portions thereof, but it is recognized that various modifications are possible within the scope of the invention claimed. Thus, it should be understood that although the present invention has been specifically disclosed by preferred embodiments and optional features, modification and variation of the concepts herein disclosed may be resorted to by those skilled in the art, and that such modifications and variations are considered to be within the scope of this invention as defined by the appended claims.
The inventions described herein were invented by employees of the United States Government and thus, may be manufactured and used by or for the U.S. Government for governmental purposes without the payment of royalties. This application claims the benefit of priority to U.S. Pat. App. 63/295,347, filed Dec. 30, 2021, which is hereby incorporated by reference to the extent not inconsistent herewith.
Number | Date | Country | |
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63295347 | Dec 2021 | US |