Surface modified pigments and methods for producing same and elastomers containing same

Abstract

The surface of a hydrous clay such as kaolin is modified by treatment with an alkyl dimethoxy mercaptopropylsilane and the modified clay is used as a filler in elastomers to give improved reinforcement.

Description

FIELD OF THE INVENTION

This invention relates to inorganic pigments and more especially to modifications of inorganic pigments, e.g., clays. In particular, the present invention relates to the modification of finely divided particulate clays such as kaolin clays by treatment with mercaptopropylsilanes to improve their usefulness as reinforcing fillers in rubber.

BACKGROUND OF INVENTION

It is known from U.S. Pat. No. 3,567,680 to Joseph Iannicelli, assigned to J. M. Huber Corporation, issued Mar. 2, 1971, that mercaptopropyl silanes having the formula: ##STR1## wherein Z is selected from the group consisting of hydrogen, cation, alkyl, aryl, alkylaryl, arylalkyl and derivatives thereof; X is selected from the group consisting of alkyl, alkylaryl, and arylalkyl; and R.sub.1, and R.sub.2, and R.sub.3 are selected from the group consisting of hydrogen, cation and alkyl, are suitable for modifying kaolin clays to enable them to be used as reinforcing fillers for elastomers. In fact the thus modified clays have been the candidates of choice for such fillers in commerce. It may be noted that in the Iannicelli disclosure, only the trialkoxy mercaptopropyl silanes are considered.

In U.S. Pat. No. 3,364,059 to Marzocchi, a method for treating glass fibers to improve their bonding relationship to rubbers comprises treating them with a silane which has from 1-3 highly hydrolyzable groups and an organic group attached to the silicon atom containing a thio group, as represented by the formula R.sub.n SiX.sub.(4-n) wherein X is a highly hydrolyzable group such as chlorine, bromine, iodine or other halogen; methoxy, ethoxy, propoxy or the like short-chained alkoxy group.

In Sollman et al, U.S. Pat. No. 4,143,027, mercaptosilane powder mixtures are described having superior shelf life and which are added during compounding of rubbers to provide a desirable amount of the silane therein. The object is to absorb a silane on a powder and achieve good storage stability. Example 1 shows a rubber composition comprising a hydrous clay-filled polyisoprene, various additives and the silane powder mixture, the silane compounds described being the tri-methoxy, -ethoxy and -n-propoxy mercaptopropyl silanes of which the latter two are stated to exhibit far greater stability in storage than the methoxy compounds.

SUMMARY OF THE INVENTION

It has now been found, unexpectedly, that a different structure of mercaptopropyl silanes is more desirable as a modifier of clays, producing more effective reinforcing fillers for elastomers, plastics and the like. Unexpected improvements in the resultant rubber products are in tear resistance and better stock-to-stock adhesion.

According to the invention, these silanes are represented by the formula: ##STR2## where R is alkyl, R' is (CH.sub.2).sub.3 (propyl), X is --SH and R" may be alkyl, preferably lower alkyl or an aryl group such as methyl, ethyl or phenyl.

Silanes of this type are commercially available as Dynasylan 3403, as advertised in a brochure of Dynamit Nobel, Kay-Fries Chemical Division entitled "Dynasylan Organo Functional Silanes/Coupling Agents."

The clay utilized as starting material may be any hydrous clay, e.g., one that has not been calcined, i.e., dehydroxylated, since the hydroxyl groups are needed in the treatment with the above-described silane. With regard to terminology, it may be noted that although the term "hydrous" is commonly used, strictly speaking there is no molecular water actually present in the kaolinite structure as it is now well known that kaolinite is an aluminum hydroxide silicate of approximate composition Al.sub.2 (OH).sub.4 Si.sub.2 O.sub.5. Commercially available clays useful for the present purpose include kaolins such as Alphaplate.RTM., which is a delaminated kaolin, having 80% by weight of its particles below 2 micrometers; Alphagloss.RTM. (94-96% less than 2 micrometers); and Betagloss.RTM. (94-96% less than 2 micrometers). These and other suitable kaolins are available from the Anglo-American Clays subsidiary of E.C.C. America, Inc. of Atlanta, Ga.

It is believed that the improvement in the clays modified by the silanes according to the invention, as reinforcing fillers for rubber, may arise from a change in their sterochemistry and/or in hydrophobicity.

Accordingly the invention comprises a finely divided particulate reinforcing filler pigment for elastomers--and the resultant reinforced elastomers--comprising a hydrous clay, the surface of which has been modified by treatment with a mercaptosilane having the formula: ##STR3## wherein R is alkyl, R' is (CH.sub.2).sub.3, X is SH and R" is alkyl or aryl.

Further, the invention comprises a process for preparing a finely divided particulate reinforcing filler pigment for use in elastomers comprising a hydrous clay, the surface of which has been modified by treatment with a mercaptosilane comprising: preparing a dispersed aqueous clay slurry; adding to said slurry from about 0.2 to about 0.7% based on the weight of the dry clay, of a mercaptosilane having the formula: ##STR4## wherein R is alkyl, preferably a lower alkyl, e.g., C.sub.1 to C.sub.4, R' is (CH.sub.2).sub.3, X is SH and R" is alkyl or aryl; and spray drying said slurry to produce a mercaptosilane surface modified clay for use in elastomers. A more preferred range of addition is between 0.25% and 0.45% silane based on the weight of the dry clay.

The hydrous clay is preferably a kaolin.

The invention also includes a method for reinforcing elastomers comprising the steps of modifying the surface of a hydrous clay with from about 0.2 to about 0.7% based on the weight of the dry clay, of a mercaptosilane of the formula: ##STR5## wherein R is alkyl, preferably a lower alkyl, e.g., C.sub.1 to C.sub.4, R' is (CH.sub.2).sub.3, X is SH and R" is alkyl or aryl, and combining the thus surface modified clay with an elastomeric material.

DETAILED DESCRIPTION

In a typical procedure, a kaolin clay is mined and the crude is subjected to conventional beneficiation procedures, which may include such steps as magnetic separation and bleaching, and the kaolin is then flocculated and filtered. The filter cake is redispersed in water to form a 50% to 60% solids slurry and mixed with a silane of formula (2) shown above. The reaction is almost instantaneous. Then the slurry is spray dried to give the modified clay product.

A typical formulation with rubber comprises 75 parts by weight filler to 100 parts resin, plus modifiers, aids, and the like as shown in Formulation I. Trade names throughout are identified in Table 9.

______________________________________Formulation IIngredient Parts by weight______________________________________Natsyn 2200 100.0ZnO 5.0Stearic acid 2.0Agerite white 1.0OBTS 1.25TMTD 0.2Sulfur 2.75Silane treated clay 75.0Total 187.2______________________________________

When rubber formulations such as these are subjected to conventional curing, the resultant products are found to have superior characteristics in comparison to products including prior art silane treated clay fillers--e.g., improved tear resistance, and improved stock-to-stock adhesion.

Extensive studies showed surprisingly superior properties for the products of the invention. In these studies, the silane employed was an alkyldimethoxy mercaptopropylsilane, e.g., methyldimethoxy mercaptopropylsilane, and it was used to treat hydrous kaolin clay. Typical physical properties of silane treated clays in accordance with the invention are given in Table 1. These products were prepared using silane treatment levels in the range 0.25 to 0.45% by weight of the dry clay.

TABLE 1______________________________________Mercaptosilane Treated Hydrous ClaysTYPICAL PROPERTIESPRODUCTDESIGNATION: P1 P2 P3 P4 P5______________________________________G.E. Brightness, % 87-90 85-88 90-92 85-88 90-92Specific Gravity 2.63 2.63 2.63 2.63 2.63Particle Size, in % 80 92 95 92 95less than 2 Micro-meterParticle Size, Avg. .40 .25 .20 .25 .20MicrometerpH (3) 7.0 7.0 7.0 7.0 7.0Screen Residue, % .01 .01 .01 .01 .01max. (325 mesh) (2)Moisture, % max. (1 1.0 1.0 1.0 1.0 1.0Hr. @ 105.degree. C.) aspackaged (1)Bulk Density, 50 50 50 50 50lbs./cu. ft.______________________________________ (1) A STM D280 (2) A STM D1514 (3) Ph (.+-./-0.5) 100 g. clay; 250 ml water The treated clays impart these properties to rubber compositions: 1. High modulus 2. Low Hysteresis 3. Improved Tear Resistance 4. Improved Stockto-Stock Adhesion 5. Good Heat Aging Properties 6. Low Viscosity Levels (relative to loading) 7. Improved permeability resistance to Air, Gas, and Moisture

These and other advantages of the invention will be illustrated by the following Examples, which, however, are to be considered illustrative and not delimitative of the invention otherwise set forth:

EXAMPLE I

This example is illustrative of use of the invention in passenger car tire white sidewall (WSW) portions of the tire body. The WSW-I formulation below was tested against similar formulations containing prior art products A and B which were treated in a similar process using trimethoxy mercaptopropylsilane instead of the silanes used in the present invention. The physical properties of these systems are provided in Table 2.

______________________________________WSW-I Formulation______________________________________SMR-5 30.00EPDM 10.00Chlorobutyl Rubber 60.00Treated Clay 40.00TiO.sub.2 25.00ZnO 5.00Wax 5.00Stearic Acid 1.00U-M Blue 0.40Vultac 5 1.00MBTS 0.75Sulfur 0.50TOTAL 148.65______________________________________ TABLE 2______________________________________Silane Treated Clay P4 vs. Prior Art Product ASilane Treated Clay P5 vs. Prior Art Product BCured 20 min. @ 160.degree. C. A P4 B P5______________________________________300% Modulus kg/sq. cm. 45 39 39 46Tensile kg/sq. cm. 116 140 130 138Elongation % 550 600 650 600Hardness Shore A 56 56 55 57Trouser Tear kg/cm. 13.9 15.7 13.6 16.6Stock-to-Stock 3.2 4.1 3.2 5.4Adhesion kg/cm.______________________________________

In this high chlorobutyl rubber tri-blend composition, both treated clays P4 and P5 are compared with their respective prior art counterparts.

Both treated clays provide superior tear resistance and stock-to-stock adhesion with the P5 being the most effective. All testing procedures used in this and the following examples are ASTM as identified in Table 10.

EXAMPLE II

In this second Example of the WSW-II formulation, which is higher in natural rubber content, the P5 product is compared with the prior art B product.

______________________________________WSW-II Formulation C D______________________________________Vistalon 4608 20.00 20.00SMR-5 60.00 60.00HT 1066 20.00 20.00TiO.sub.2 30.00 30.00Silane Treated Clay P5 40.00 --Prior Art B Product -- 40.00Platey Talc 20.00 20.00MgO .50 .50U-M Blue .20 .20Stearic Acid 1.00 1.00ZnO 5.00 5.00Insol. Sulfur .67 .67MBTS .75 .75Vultac 5 1.25 1.25TOTALS 199.37 199.37______________________________________ TABLE 3______________________________________WSW-II Formulation DataCured 45 min. @ 149.degree. C. C D______________________________________Modulus100% kg/sq. cm. 25.3 20.4200% kg/sq. cm. 44.9 37.9300% kg/sq. cm. 63.3 55.5Tensile kg/sq. cm. 135.0 128.0Elongation % 530 550Trouser Tearkg/cm. RT 6.8 2.6kg/cm. 100.degree. C. 4.8 3.1______________________________________

Composition C exhibits higher modulus with product P5 than Composition D with prior art B product which translates to improved buffing. Hot tear resistance is also superior by a significant margin.

The P5 product also has a high G.E. Brightness of 90-92 and can be considered as a partial replacement for TiO.sub.2 in WSW and other color applications. The cost advantage of such a substitution is also attractive.

EXAMPLE III

Example III demonstrates the advantages of using one of the products of this invention in a tire innerliner. The formulation is given below:

______________________________________Innerliner Filler Ratios F G H______________________________________HT1068 100 100 100N660 70 45 --N650 -- -- 45Hard Clay 24 -- --Silane Treated Clay P1 -- 50 50______________________________________

N660 and N650 are recognized trade carbon blacks used by the rubber industry in tire applications.

The control, composition F, uses a conventional mix of N660 (carbon black) blended with an untreated hard clay. Compositions G and H blend the silane treated product P1 with N660 and N650 carbon blacks respectively. The physical properties of the three compositions (F, G, H respectively) are given in Table 4 below.

The air permeability of compositions G and H show a significant increase in permeability resistance approaching the optimum that can be imparted by incorporating a reinforcing mineral pigment. This advantage in increased air permeability is due not only to the crosslinking ability imparted by the surface silane but also to the particle shape of the kaolin product: i.e., the P1 product is based on a delaminated kaolin.

TABLE 4______________________________________Innerliner Test DataCured @ 145.degree. C. Min. F G H______________________________________Modulus 300% kg/sq. cm. 45' 26.7 26.7 29.5Tensile kg/sq. cm. 45' 84.4 91.4 86.5Elongation % 45' 700 780 700Hardness Shore A 45' 55 55 55Scorch MS3 @ 121.degree. C. 30 30 30Viscosity ML4 @ 100.degree. C. 52 46 47Monsanto Flex Fatigue 55'1,000 cycles RT (room temp.) 50.1 34.9 29.1(70 Hr @ 100.degree. C.) Aged 16.6 21.1 15.9Air Permeability(1/sq. m/24 Hr/100 PA/0.075 cm.) 0.445 0.251 0.195______________________________________

The stress-strain results are essentially equivalent, with aged flex equal to better for the compositions containing product P1.

The improved permeability resistance obtained through carbon black reduction and replacement with treated delaminated clay permits:

1. An improved innerliner compound at reduced cost.

2. A reduction in overall chlorobutyl rubber content--also a cost savings.

3. A possible gauge reduction (thickness) which would also reduce cost.

This improved permeability resistance can also offer advantages in systems such as fuel hose, Freon hose, and tank and pond liners.

EXAMPLE IV

The advent of single ply roofing membrane has allowed the use of silane treated clays in both white and black compositions. Example IV illustrates the use of these silane treated products of the invention in both compositions. The white EPDM roofing membrane formulation is given in Table 5 along with the physical property data.

The following white EPDM roofing study demonstrates the advantages of using products P1 or P3 as (1) a reinforcing filler, (2) to extend TiO2 (or partially replace TiO2 with these high GE brightness products), and (3) to provide resistance to "crimping" before installation. Where optimum permeability resistance or a higher loading is desired, product P1 would be preferred to product P3.

TABLE 5______________________________________White EPDM Roofing Formulation I J______________________________________Epsyn 5206 100.00 100.00Irganox 1035 1.00 1.00ZnO 5.00 5.00Silane Treated Clay P1 100.00 --Silane Treated Clay P3 -- 100.00TiO.sub.2 25.00 25.00Napthenic Oil 30.00 30.00Zn Stearate 1.00 1.00MBTS 0.75 0.75ZDBC 0.75 0.75Sulfasan R 1.25 1.25Sulfur 0.75 0.75TOTAL 265.50 265.50______________________________________ ______________________________________White EPDM Roofing DataCured 30 min. @ 160.degree. C. I J______________________________________Modulus 100% kg/sq. cm. Orig. 28.2 21.1 Aged 59.1 47.8 % Change +52.4 +55.9Modulus 300% kg/sq. cm. Orig. 44.4 43.0 Aged 78.7 88.6 % Change +42.8 +51.6Tensile kg/sq. cm. Orig. 148.6 159.2 Aged 88.6 99.1 % Change -40.0 -37.6Elongation % Orig. 740 750 Aged 440 420 % Change -40.5 -44.0Hardness Shore A Orig. 65 63 Aged 80 78 Change pts. +15 +15Fluid Immersion % Wt. Change +4.4 +4.4______________________________________

Aging Conditions: 28 days @ 100.degree. C. in air circulating oven; 24 hour recovery.

Fluid Immersion Conditions: 168 hours @ 100.degree. C. in distilled water with 1/2 hour recovery in 27.degree. C. distilled water.

The market for EPDM single ply roofing continues to expand. Chemically modified clays can be used as a reinforcing filler in black roofing compositions to help reduce cost.

The black EPDM roofing formulation is given in Table 6. Tables 7 and 8 show the physical properties of the unaged and aged test samples respectively.

These data show that product P2 can be used to partially replace the carbon black content and meet all unaged and aged specifications.

TABLE 6______________________________________Black EPDM Roofing Formulation______________________________________Royalene 502 100.00N660 85.00Silane Treated Clay P2 100.00Napthenic Oil 95.00ZnO 5.00Stearic Acid 1.00MBT 1.50TMTM 2.00Sulfur 1.00Diethylene Glycol 0.50TOTAL 391.00______________________________________ TABLE 7______________________________________Black EPDM Roofing DataUnaged Physical PropertiesCured 20 min. @ 160.degree. C. Original Specifications______________________________________Modulus100% kg/sq. cm. 23.9200% kg/sq. cm. 52.7300% kg/sq. cm. 82.9Tensile kg/sq. cm. 106.2 93.4 min.Elongation % 630 300 min.Hardness Shore A 62 60 to 70Viscosity ML4 @ 100.degree. C. 28.5Scorch MS3 @ 121.degree. C. 11.0Trouser Tear kg/cm. 18.9 5.4 min.______________________________________ TABLE 8______________________________________Black EPDM Roofing DataAged Physical PropertiesCured 20 min. @ 160.degree. C. Aged % Change Specifications______________________________________Modulus100% kg/sq. cm. 26.7 +10.5200% kg/sq. cm. 59.7 +11.8300% kg/sq. cm. 91.4 +9.2Tensile kg/sq. cm. 101.2 -4.6 -28 max.Elongation % 560 -11.1 -25 max.Hardness Shore A 65 +3 pts.Fluid Immersion% Vol. Change +2.3 +8 max.% Wt. Change +2.0 +8 max.Low Temp. Brittle Point -56 -52 min.Deg. .degree.C.Ozone ResistanceDay 1 0 0 crackingDay 2 0 0 crackingDay 3 0 0 crackingDay 4 0 0 crackingDay 5 0 0 crackingDay 6 0 0 crackingDay 7 0 0 cracking______________________________________

The aging conditions for the preceding test results are as follows:

Oven Aging: 7 days @ 70.degree. C. in air circulating oven; 24 hour recovery.

Fluid Immersion: 166 hours @ 70.degree. C. in distilled water; 1/2 hour recovery in distilled water @ 27.degree. C.

Low Temperature Brittle Point: 5 specimens each tested in 100% Methanol cooling medium.

Ozone Resistance: Exposure 7 days @ 40.degree. C. @ 100 pphm at 20% elongation; 24 hours prestretch @ 27.degree. C.; rated every 24 hours.

Thus it can be seen that silane treated clays of the present invention have a higher safety factor with respect to tear and adhesion properties than can be achieved with prior art mineral filler products of another silane composition. They have the capability of partial replacement of carbon black. The novel products of this invention are the first low energy depending mineral fillers which provide rubber properties similar to those of carbon black.

TABLE 9______________________________________The following compounding ingredients are acknowledgedas registered tradenames:Tradename Source Compositional Type______________________________________Natsyn 2200 Goodyear Polyisoprine RubberVultac 5 Pennwalt Curing AgentVistalon 4608 Exxon Chemicals EPDM Polymer AmericasHT1066 Exxon Chemicals Halogenated Butyl Americas RubberMistron Vapor Cypress Industrial Talc Minerals CoEpsyn 5206 CoPolymer Rubber EPDM PolymerIrganox 1035 Ciba-Geigy Curing AgentSulfasan R Monsanto Sulfur Donor Curing AgentRoyalene 502 Uniroyal Chemical EPDMAgerite White R. T. Vanderbilt AntioxidantNordel 1070 DuPont EPDMOctamine Uniroyal Chemical Curing AgentHycar 1042 B. F. Goodrich Nitrile RubberKrynac 870/60 Polysar Nitrile PVC Rubber BlendWingstay 100 Goodyear Chemicals AntioxidantMethyl Zimate R. T. Vanderbilt Curing AgentSMR-S Standard Grade Natural RubberOBTS ThiobenzothiazoleTMTD Tetramethyl Thiuram Disulfide______________________________________ TABLE 10______________________________________ASTM D3182 Preparation of MaterialsASTM D412 Physical PropertiesASTM D2240 HardnessASTM D470 Modified Trouser TearASTM D1646 Mooney Viscosity and ScorchASTM D623 Heat Generation and Flex FatigueASTM D945 Compression SetASTM D573 Oven AgingFirestone Procedure for Ply to Ply Adhesion______________________________________

While the present invention has been particularly described in terms of specific embodiments thereof, it will be understood in view of the instant disclosure, that numerous variations upon the invention will now be enabled to those skilled in the art, which variations yet reside within the scope of the present teachings. Accordingly, the invention is to be broadly construed, and limited only by the scope and spirit of the claims now appended hereto.

Claims

1. A finely divided particulate reinforcing filler pigment for elastomers comprising a hydrous clay, the surface of which has been modified by treatment with a mercaptosilane having the formula: ##STR6## wherein R is alkyl, R' is (CH.sub.2).sub.3, X is SH and R" is alkyl or aryl.

2. A filler pigment in accordance with claim 1, in which the clay used is a kaolin that has not been dehydroxylated.

3. A filler pigment as set forth in claim 2 in which from about 0.2% to about 0.7% of the silane is used based on the weight of the dry clay.

4. A filler pigment as set forth in claim 2 in which the silane is an alkyldimethoxy mercatopropylsilane.

5. A filler pigment as set forth in claim 4 in which the silane is methyldimethoxy mercaptopropylsilane.