Swash plate type compressor

Information

  • Patent Grant
  • 6694864
  • Patent Number
    6,694,864
  • Date Filed
    Wednesday, March 6, 2002
    22 years ago
  • Date Issued
    Tuesday, February 24, 2004
    20 years ago
Abstract
A swash plate (3, 18) included in a swash plate type compressor for compressing a refrigerant is made of an aluminum alloy as a base material. Sliding contact surfaces (3a, 18a) of the swash plate (3, 18) in sliding contact with shoes (7, 19) linking the swash plate (3, 18) to pistons (6, 17) are coated with a film of a solid lubricant containing at least one lubricating material selected from molybdenum disulfide, tungsten disulfide and graphite by a transfer method. Therefore, the performance of the film and the productivity thereof are improved.
Description




BACKGROUND ART




A double-headed swash plate type compressor applied to an automobile air conditioning system, for example, has a drive shaft, a pair of cylinder blocks supporting the drive shaft for rotation, and a swash plate fixedly supported on the drive shaft for rotation together with the drive shaft in a swash plate chamber formed in a region including the boundary between the pair of cylinder blocks. A plurality of cylinder bores are formed so as to extend in both the cylinder blocks and are arranged around the drive shaft. Double-headed pistons are fitted for axial movement in the cylinder bores, respectively. Each piston is operatively engaged with the swash plate via shoe elements. The rotary motion of the swash plate is converted into the linear motion of the pistons for the suction, compression and discharge of a refrigerant gas.




A single-headed swash plate type compressor has a cylinder block, and a housing closing an inner end of the cylinder block and having a swash plate chamber or a crank chamber. A swash plate is mounted on a drive shaft in the swash plate chamber and is engaged with pistons by shoes. Further, in a variable-displacement swash plate type compressor, a swash plate is engaged with single-headed pistons fitted in a plurality of cylinder bores by shoes, and is mounted on a drive shaft so as to wobble on a supporting point. The inclination of the swash plate is changed according to pressure in the crank chamber so that gas pressures acting on the opposite ends of the single-headed piston balance each other. Consequently, the stroke of the single-headed piston is adjusted to control the displacement of the compressor.




The demand for weight reduction in the aforementioned swash plate type compressors has progressively increased and the swash plate type compressors for automobile air conditioning or climate control systems, including the swash plates, the pistons, and the cylinder blocks are now made of aluminum alloys. Therefore, abrasion-resistant and seizing-preventive measures have been examined to protect surfaces exposed to severe, high-speed abrasive actions for a long time, such as the surfaces of the swash plate in sliding contact with the shoes, and the sliding contact surface of the piston in sliding contact with the surface of the bore. Such measures include the formation of a fluorocarbon resin film on the sliding contact surface of the piston and the formation of a film of a solid lubricant on the sliding contact surface of the swash plate.




The double-headed piston, however, is provided with a recess extending across the periphery of the swash plate, and interfering surfaces formed in the recess to prevent the piston from rotation about its own axis come into impulsive contact with the outer circumference of the swash plate to prevent the piston from rotation by a rotation moment acting on the piston. The single-headed piston is provided with a rotation-preventive interfering surface in its base end part, and the interfering surface comes into impulsive contact with the inner surface of the housing to restrain the piston from rotation. Accordingly, it is possible, under a substantially nonlubricated state which occurs at the start of the compressor, that seizing occurs between the interfering surface of the piston and the outer circumference of the swash plate, and attempts have been made to form a lubricating film over the interfering surface of the piston and the outer circumference of the swash plate. However, in formtion of a lubricating film, when, for example, a spray coating process for coating the swash plate with a lubricating film is used, the yield of formation of the coating material film is usually very low. Furthermore, since the strength of an adhesive bond of the lubricating film and the sliding contact surface is low, such a protective measure using the lubricating film is not satisfactory in reliability as well as in its seizing-preventive effect.




DISCLOSURE OF THE INVENTION




It is an object of the present invention to provide an improved swash plate type compressor capable of providing improved functional reliability attained by employing an improved swash plate coated with an excellent film and capable of being manufactured with a high productivity.




Another object of the present invention is to provide a long-life swash plate type compressor capable of properly functioning, over an extended period of use, when applied to an automobile air conditioning system and driven by the engine of a vehicle to compress a refrigerant.




In accordance with the present invention, there is provided a swash plate type compressor which comprises: a cylinder block provided with a plurality of cylinder bores; pistons fitted in the cylinder bores; a drive shaft supported for rotation about its axis of rotation; and a swash plate supported for rotation together with the drive shaft, having at least sliding contact surfaces to be in sliding contact with shoes and operatively engaged with the pistons via the shoes; wherein the sliding contact surfaces of the swash plate in sliding contact with the shoes are coated with a film of at least one solid lubricant selected from molybdenum disulfide, tungsten disulfide and graphite by a transfer method.




The film of the solid lubricant formed on the sliding contact surface of the swash plate in sliding contact with the shoes exercises excellent lubricating performance, and the transfer method of forming the film of the solid lubricant is very advantageous from the viewpoint of economy and productivity in the yield of the coating material and the control of the thickness of the film.




If the swash plate has an outer circumference to be in impulsive contact with interfering surfaces formed respectively in the pistons, it is preferable that a film of the solid lubricant is formed on the outer circumference by a transfer method. Thus, the contact surface to be in impulsive contact with the piston, in addition to the sliding contact surface in sliding contact with the shoes, is able to secure a further satisfactory seizing-resistant property.




If the sliding contact surfaces of the swash plate on which the film is formed, i.e., base surfaces for the film, are subjected to a surface roughening process, a coating material for forming the film is forced to dig into minute irregularities formed by the plastic deformation of the base surfaces to provide an anchoring effect which enhances the strength of connection of the film to the base surfaces. If the sliding contact surface and the outer circumference of the swash plate are coated for surface preparation with a plated film of a material containing tin as a principal component, the plated film prevents the aluminum base of the swash plate from being exposed even if part of the plated film falls off, and serves as a lubricating layer. Therefore, the swash plate has excellent durability.




Preferably, the film formed on the sliding contact surface of the swash plate is finished by grinding to adjust the thickness of the film and finish the surface of the film in a high surface accuracy (flatness).











BRIEF DESCRIPTION OF THE DRAWINGS




The above and other objects, features and advantages will become apparent from the ensuing description of the preferred embodiments taken in conjunction with the accompanying drawings, wherein:





FIG. 1

is a longitudinal sectional view of a double-headed swash plate type compressor in a preferred embodiment according to the present invention;





FIG. 2A

is a perspective view of a double-headed piston employed in the compressor of

FIG. 1

;





FIG. 2B

is a longitudinal sectional view taken on line


2


B—


2


B in

FIG. 2A

;





FIG. 3

is a longitudinal sectional view of a single-headed swash plate type compressor in another embodiment according to the present invention;





FIG. 4A

is a front view of a single-headed piston employed in the compressor of

FIG. 3

;





FIG. 4B

is a rear end view showing a rotation preventing interfering surface formed in the single-headed piston;





FIG. 5

is a typical view of a transfer apparatus for processing the sliding contact surface of a swash plate;





FIG. 6A

is a typical view of a transfer apparatus for processing the outer circumference of a swash plate; and





FIG. 6B

is a typical development showing the relation between a workpiece for making a swash plate, and rollers.





FIGS. 7A and 7B

are showing a roller coating method of applying a lubricating film to a sliding contact surface (flat surface) of a swash plate.











BEST MODE OF CARRYING OUT THE INVENTION




Referring to

FIGS. 1

,


2


A and


2


B, a double-headed swash plate type compressor has a front cylinder block


1


A and a back cylinder block


1


B, and a drive shaft


2


is supported for rotation about an axis of rotation on the cylinder blocks


1


A and


1


B. A swash plate chamber


4


is formed in a region around the joint of the cylinder blocks


1


A and


1


B in the cylinder blocks


1


A and


1


B. A swash plate


3


is contained in the swash plate chamber


4


and is combined with the drive shaft


2


for rotation together with the drive shaft


2


. Bores of a predetermined diameter are formed in the cylinder blocks


1


A and


1


B, and the cylinder blocks


1


A and


1


B are joined together with the respective axes of the corresponding bores aligned with each other so as to form a plurality of axial cylinder bores (hereinafter referred to simply as “bores”)


5


arranged around the drive shaft


2


. Opposite end parts of double-headed pistons


6


are fitted in the bores


5


, respectively, for axial sliding movement. Each piston


6


is linked to the sliding contact surfaces


3




a


of the swash plate


3


by shoes


7


. A rotary motion of the swash plate


3


is converted into a linear motion of the piston


6


for the suction, compression and discharge of a refrigerant gas.




In this embodiment, the shoes


7


are made of an iron based material and the cylinder blocks


1




a


and


1


B, the swash plate


3


and the double-headed pistons


6


are made of an aluminum alloy such as a hypereutectic aluminum-silicon alloy.




As best shown in

FIGS. 2A and 2B

, the double-headed piston


6


has cylindrical sliding contact surfaces


6




a


of a predetermined length formed in the opposite end parts thereof and capable of being slidably fitted in the bores


5


, and a recess


6




b


formed in a middle part thereof between the opposite end parts provided with the sliding contact surfaces


6




a


so as to extend across the outer circumference of the swash plate


3


. Semispherical seats


6




c


in which the shoes


7


are seated, respectively, are formed axially opposite to each other in the recess


6




b


. Interfering surfaces


6




d


for restraining the piston


6


from rotation are formed axis-symmetrically in the middle part. The interfering surfaces


6




d


come into impulsive contact with the outer circumference


3




b


of the swash plate


3


to inhibit the rotation of the piston


6


about its axis by a rotation moment exerted by the shoes


7


on the piston


6


.




Referring to

FIGS. 3

,


4


A and


4


B, a variable-displacement swash plate type compressor in another embodiment according to the present invention has a cylinder block


10


having opposite end surfaces, a front housing


11


connected to the cylinder block


10


so as to cover the front end of the cylinder block


10


, a valve plate


12


placed on the rear end surface of the cylinder block


10


, and a rear housing


13


connected to the cylinder block


10


so as to cover the rear end of the cylinder block


10


. The cylinder block


10


, the front housing


11


and the rear housing


13


are firmly fastened together with through bolts so that the connecting portions thereof are tightly sealed. In the compressor, the cylinder block


10


and the front housing


11


define a crank chamber


14


, and a drive shaft


15


is extended axially in the crank chamber


14


and is supported for rotation in a pair of radial bearings held respectively on the cylinder block


10


and the front housing


11


.




A plurality of cylinder bores (hereinafter referred to simply as “bores”)


16


are formed around the drive shaft


15


in the cylinder block


10


, and single-headed pistons


17


are fitted for reciprocation in the bores


16


, respectively.




In the crank chamber, a rotor


20


is fixedly mounted on the drive shaft


15


for rotation together with the drive shaft


15


. An axial load exerted on the rotor


20


is sustained, through a thrust bearing, by the front housing


11


. A swash plate


18


is mounted on the drive shaft


15


at a position behind the rotor


20


. The swash plate


18


is always biased backward by the resilience of a compression spring interposed between the swash plate


18


and the rotor


20


.




The swash plate


18


has a shape generally resembling a plate and is provided with flat sliding contact surfaces


18




a


formed on the opposite sides of a peripheral part thereof. Semispherical shoes


19


are put in contact with the sliding contact surfaces


18




a


, respectively. The shoes


19


are in sliding contact with semispherical seats


17




c


formed in the piston


17


. A hinge mechanism K is formed between the swash plate


18


and the rotor


20


to allow the swash plate


18


to move pivotally relative to the rotor


20


.




The swash plate


18


is provided with a bent central hole


18




b


formed through a central part thereof. The drive shaft


15


is extended through the central hole


18




b


to support the swash plate


18


thereon. The inclination of the swash plate


18


is variable without varying the top dead center of each single-headed piston


17


relative to the corresponding bore


16


.




In this embodiment, the cylinder block


10


, the swash plate


18


and the piston


17


are made of an aluminum alloy, such as a hypereutectic aluminum-silicon alloy. Each piston


17


is provided in its head part with a sliding contact surface


17




a


of a predetermined length fitting the bore


16


, in its tail end part with a recess


17




b


(

FIG. 4A

) extending across the swash plate


18


, and on the back side of a part thereof forming the recess


17




b


with a curved interfering surface


17




d


of a large radius of curvature capable of coming into impulsive contact with the inner surface


14




a


defining the crank chamber


14


to prevent the piston


17


from rotation about its own axis.




The surface treatment of the swash plate, which is a feature of the present invention, will be described with reference to

FIGS. 5

,


6


A and


6


B.




The swash plate


8


linked to the double-headed pistons


6


in the former embodiment and the swash plate


18


linked to the single-headed pistons


17


in the latter embodiment differ from each other in that the former swash plate


3


has the outer circumference


3




b


with which the interfering surfaces


6




d


of the pistons


6


come into impulsive contact, while the latter swash plate


18


has the outer circumference with which the pistons


17


do not come into direct contact. Therefore, the outer circumference of the swash plate


18


need not be subjected to a surface treatment process for providing the same with a lubricating property. However, the surface treatment of the sliding contact surfaces


3




a


of the swash plate


3


to be in contact with the shoes


7


, and the surface treatment of the sliding contact surfaces


18




a


of the swash plate


18


are substantially the same and hence only the surface treatment of the swash plate


3


will be described.




Although not clearly shown in the drawings, the sliding contact surfaces


3




a


formed on a workpiece


3


W, i.e., a swash plate


3


that is being manufactured, are selectively processed to finish the sliding contact surfaces


3




a


in a surface roughness of 0.4 μm Rz or above by a surface roughening process, such as a shot blasting process, for a pretreatment to enhance the strength of adhesion of a film of a solid lubricant to the sliding contact surfaces


3




a.






Both the sliding contact surfaces


3




a


(and the outer circumference


3




b


, if necessary) of the workpiece


3


W are plated with a metal containing tin as a principal component for a selective pretreatment regardless of whether the sliding contact surfaces


3




a


are processed by a surface roughening process. The surface roughness of the sliding contact surfaces


3




a


processed by the surface roughening process is increased to a surface roughness on the order of 12 μm Rz by plating. Those base surfaces may be finished to a certain surface roughness by a cutting process, and these pretreatment processes may be omitted.




A transfer method (pad transfer method) for forming a film of a solid lubricant on the sliding contact surfaces


3




a


of the workpiece


3


W thus pretreated will be described below.




Referring to

FIG. 5

, a transfer apparatus


70


has a tank


71


. The tank


71


contains a coating material C containing a solid lubricant, such as a mixture of molybdenum disulfide and graphite, and an unsolidified thermosetting resin, such as a polyimide resin. The tank


71


is installed on a slide table


72


. The slide table


72


is in sliding contact with the lower open end of the tank


71


and moves horizontally in the directions of the arrows. An annular material holding groove


72




a


of a surface area substantially corresponding to that of the sliding contact surface


3




a


is engraved on the upper surface of the slide table


72


. A cylindrical transfer pad


73


of a synthetic rubber is disposed at a waiting position at a predetermined distance in the direction of movement of the slide table


72


from the tank


71


. The transfer pad


73


can vertically be moved. The stroke of the slide table


72


is determined so that the material holding grooves


72




a


reciprocate between the waiting position and the center of the tank


71


.




The transfer pad


73


is formed so that its lower end surface


73




b


excluding a part in which a relief hole


73




a


for receiving the boss of the workpiece


3


W therein bends slightly and fills up the material holding groove


72




a


. The transfer pad


73


can move horizontally between the waiting position and a transfer position, and can move vertically at the waiting position and the transfer position as indicated by the arrows. A support table


74


provided with a positioning recess


74


of a shape corresponding to that of the boss of the workpiece


3


W is disposed under the transfer pad


73


as positioned at the transfer position. The support table


74


can be moved between the position shown in

FIG. 5 and a

drying apparatus, not shown.




The slide table


72


is moved to the left from the waiting position shown in

FIG. 5

to locate the material holding groove


72




a


in alignment with the center of the tank


71


, i.e., to locate the material holding groove


72




a


so that a circle defining the outer boundary of the material holding groove


72




a


coincides with the edge of the lower open end of the tank


71


as indicated by alternate long and two short dashed lines. Consequently, the material holding groove


72




a


is filled up automatically with the coating material C. Then, the slide table


72


is returned (is moved to the right) to the waiting position and the transfer pad


73


is lowered. Consequently, the lower end surface


73




b


is bent slightly and enters the material holding groove


72




a


and the coating material C adheres to the lower end surface


73




b


of the transfer pad


73


.




The transfer pad


73


thus wetted with the coating material C is raised, is moved to the right to the transfer position corresponding to the support table


74


, is lowered to press the lower end surface


73




b


against the sliding contact surface


3




a


of the workpiece


3


W to transfer the coating material C from the lower end surface


73




b


to the sliding contact surface


3




a


, i.e., to coat the sliding contact surface


3




a


with the coating material C.




If necessary, the workpiece


3


W having the sliding contact surface


3




a


thus coated with the coating material C is put in a drying apparatus for drying together with the support table


74


, and the foregoing steps are repeated to adjust the thickness of the film. Similarly, the sliding contact surface


3




a


formed on the other side of the workpiece


3


W is coated with the coating material C, and the films formed on the sliding contact surfaces


3




a


are made to adhere firmly to the sliding contact surfaces


3




a


by a baking process.




A transfer method (roller transfer method) for forming a film of a solid lubricant on the outer circumference


3




b


of the workpiece


3


W will be described below with reference to

FIGS. 6A and 6B

.




A transfer apparatus


80


has a tank


82


containing a coating material C containing a solid lubricant, such as a mixture of molybdenum disulfide and graphite, and an unsolidified thermosetting resin, such as a polyamidimide resin, a metal roller


83


partly dipped in the coating material C contained in the tank


82


, a comma roller


84


disposed near the metal roller


83


with a predetermined gap therebetween, a transfer roller


85


of a synthetic rubber having a coating part


85




a


of an increased diameter conforming to the locus of rotation of the outer circumference


3




b


of the workpiece


3


W, and disposed with the coating part


85




a


in contact with the metal roller


83


, a work holder


86


for rotatably holding the workpiece


3


W, and a driving mechanism


81


for driving the rollers


83


and


85


for rotation in the directions of the arrows.




When the rollers


83


and


85


are rotated by the driving mechanism


81


, the coating material C adheres to the circumference of the metal roller


83


, the thickness of a layer of the coating material C on the metal roller


83


is adjusted by the comma roller


84


, and the layer of the coating material C is transferred from the metal roller


83


to the coating part


85




a


of the transfer roller


85


. When the rotating workpiece


3


W is brought into contact with the transfer roller


85


by the work holder


86


, the coating material C is applied (transferred) to the outer circumference


3




b


of the workpiece


3


W from the transfer roller


85


. Then the workpiece


3


W is separated from the transfer roller


85


and is removed from the work holder


86


. The workpiece


3


W is subjected to a drying process to remove a solvent from the coating material C and is subjected to a baking process to form a film firmly adhering to the outer circumference


3




b.






The representative processes of forming the films of the solid lubricant on the workpiece


3


W illustrated in

FIGS. 5

,


6


A and


6


B may be carried out in the following manner.




The sliding contact surfaces


3




a


and the outer circumference of


3




b


of the workpiece


3


W may be roughened by shot blasting to a desirable surface roughness in the range of 2 to 12 μm Rz, and films of the solid lubricant may directly be formed on the sliding contact surfaces


3




a


and the outer circumference


3




b


without plating the sliding contact surfaces


3




a


and the outer circumference


3




b


of the workpiece


3


W. It is obvious that the films of the solid lubricant can be formed by the transfer apparatus


70


shown in

FIG. 5

or the transfer apparatus


80


shown in

FIGS. 6A and 6B

.




In another embodiment, sprayed layers of a copper-bearing metal may be formed by spraying on the sliding contact surfaces


3




a


and the outer circumference


3




b


of the workpiece


3


W, and films of the solid lubricant may be formed on the sprayed layers. The surfaces of the sprayed layers may be roughened by shot blasting to a surface roughness in the range of 2 to 12 μm Rz, and then the films of the solid lubricant may be formed on the roughened sprayed layers.




It should be understood that shot peening, sand blasting or cutting by a tool may be used instead of shot blasting for surface roughening.




Naturally, the foregoing embodiments relating to the workpiece


3


W are applicable also to the manufacture of the swash plate


18


.




A transfer method (roller transfer method) for forming a film of a solid lubricant on the flat surface of the workpiece (swash plate)


3


W will be described below with reference to

FIGS. 7A and 7B

. When a metal roller


93


and a rubber roller


94


are rotated by a driving mechanism, a coating material C is supplied from a dispenser


91


. The coating material is applied to the metal roller


93


. The thickness of a layer of the coating material C supplied on the metal roller


93


is adjusted to the thickness to be required by a blade


92


. The layer of the coating material C on the metal roller


93


is transferred from the metal roller


93


to the rubber roller


94


. The metal roller


93


and the rubber roller


94


rotate in the same direction. When a rotating workpiece (a swash plate)


3


W is brought into contact with the roller


94


, and the rotation of the swash plate synchronizes to that of the rubber roller


94


, the coating material is applied to a flat sliding contact surface


3




a


of the swash plate (workpiece) from the rubber roller


94


. The rotating direction of the swash plate (workpiece) is at a right angle to that of the rubber roller


94


, as shown in FIG.


7


A.




In this case, since the speed of the coating surface is different between the inner circumference side and the outer circumference side of the coating surface (the speed of the outer circumference side is faster than that of the inner circumference side), the thickness of the layer on the outer circumference side of the coating surface tends to become thinner. Therefore, the blade


92


is slightly inclined and the thickness of the layer corresponding to the outer circumference side of the coating surface is made thicker when the coating material is supplied from the dispenser


91


to the metal roller


93


. Thus, the coating material is coated uniformly on the coating surface (flat surface


3




a


) of the swash plate (workpiece).




As is apparent from the foregoing description, according to the present invention, the swash plate included in the swash plate type compressor has sliding contact surfaces coated with the film of the solid lubricant, the film of the solid lubricant, provides an excellent lubricating performance, and the coating of the sliding contact surfaces with the film of the solid lubricant by the transfer method is very advantageous from the viewpoint of economy and productivity in the yield of the coating material and the control of the thickness of the film.




If the sliding contact surfaces of the swash plate on which the film is formed, i.e., the base surfaces for the film, are finished by a surface roughening process, the coating material is forced to dig into the irregularities formed to provide an anchoring effect which enhances the strength of adhesion of the film to the sliding contact surfaces. If the sliding contact surfaces and the outer circumference of the swash plate are coated for surface preparation with plated films of a material containing tin as a principal component, a further satisfactory durability will be guaranteed.















LIST OF REFERENCE CHARACTERS


























 1A




Cylinder block







 1B




Cylinder block







 2




Drive shaft







 3




Swash plate







 3a




Sliding contact surface







 3b




Outer circumference







 4




Swash plate chamber







 5




Cylinder bore







 6




Double-headed piston







 6a




Sliding contact surface







 6b




Recess







 6d




Interfering surface







 7




Shoe







10




Cylinder block







11




Front housing







12




Valve plate







13




Rear housing







14




Crank chamber







15




Drive shaft







16




Cylinder bore







17




Single-headed piston







18




Swash plate







19




Shoe














Claims
  • 1. A method of applying a lubricating film to a piston assembly bearing surface of a swash plate type compressor, comprising:providing a swash plate having at least one sliding contact surface, which is formed on a flat surface of the swash plate, for engaging a piston assembly in sliding contact therewith; supplying a solid lubricating material from a source of supply to a roller; rotating the swash plate about an axis that is different from the axis of rotation of the roller so that the sliding contact surface of the swash plate moves in a direction different from the direction of the movement of the roller surface and in close proximity thereto; and applying a solid lubricating material film to the roller surface whereby a film of the lubricating material transfers from the roller to the sliding contact surface of the swash plate.
  • 2. The method of claim 1, wherein the thickness of a layer of said solid lubricating material is adjusted by a blade to the thickness required to coat said flat surface of the swash plate when said lubricating material is supplied to said roller.
  • 3. The method of claim 1, wherein the axis of rotation of said swash plate is generally perpendicular to that of said roller.
  • 4. The method of claim 2, wherein said blade is inclined relative to the roller surface so that the amount of said lubricating material supplied to the outer circumference side of the flat surface of said swash plate is greater than the amount of lubricating material supplied to the inner circumference side thereof.
TECHNICAL FIELD

This application is a Continuation-in-Part of U.S. application Ser. No. 09/308,946, entitled “Swash Plate Type Compressor”, filed May 26, 1999 now abandoned. The present invention relates to a swash plate type compressor and, more particularly, to a highly reliable swash plate type compressor provided with a swash plate finished by surface treatment and capable of functioning with improved performance.

US Referenced Citations (9)
Number Name Date Kind
1768528 Short Jun 1930 A
4512175 Kaku et al. Apr 1985 A
5056417 Kato et al. Oct 1991 A
5655432 Wilkosz et al. Aug 1997 A
5941160 Kato et al. Aug 1999 A
5996467 Churgay et al. Dec 1999 A
6129996 Cordy Oct 2000 A
6192784 Kato et al. Feb 2001 B1
6217295 Kato et al. Apr 2001 B1
Foreign Referenced Citations (2)
Number Date Country
0 776 986 Jun 1997 EP
6-022080 Feb 1985 JP
Continuation in Parts (1)
Number Date Country
Parent 09/308946 May 1999 US
Child 10/091961 US