Patent Application
20050230138
1. Field of the Invention
The present invention relates to a switch container for hermetically encapsulating switch members, particularly to a switch container comprising a hollow ceramic body for hermetically encapsulating switch members, and a method for producing the switch container.
2. Description of the Related Art
Conventionally, a switch such as a vacuum switch and a circuit contactor used for shutting-off or switching electrical power, has generally employed a cylindrical ceramic tube comprising at least 85% by weight of alumina, in view of the strength, insulation and air-tightness required for the switch container.
In a conventional process of forming the cylindrical ceramic tube, a slurry of alumina is spray-dried into a powder, and then the powder is placed into a rubber mold and pressed into a green (unfired) cylindrical ceramic body. A firing temperature exceeding 1500° C. is normally needed to fire or rather sinter the green cylindrical ceramic body, due to the high alumina content thereof.
In order to encapsulate, and more particularly, hermetically seal various switch members inside the switch container, both open ends of the ceramic cylindrical tube are circularly metallized. Furthermore, two metallic end caps are each brazed onto the metallized ends so as to hermetically seal the switch members therein, as disclosed in Japanese Patent Application Laid-Open (Kokai) No. 2003-2768.
3. Problems to be Solved by the Invention
When a high alumina content of at least 85% by weight is employed for producing a ceramic cylindrical body, it is difficult to carry out extrusion-molding due to the high alumina content. This is one of the main reasons why the powder-pressing process, which requires the spray-drying of an alumina slurry and additional complicated works, has been conventionally adopted for forming the cylindrical ceramic body.
Since a very high temperature of more than 1500° C. has been required to obtain an airtight ceramic container having a high alumina content for use in a vacuum switch, etc., the processing cost, including furnace cost and energy cost for producing a high-alumina content ceramic body, has been a substantive problem.
Notably, air-tightness is one of the most important requirements for a vacuum switch and a circuit contactor. A circuit contactor for use in a hybrid or electric engine using a high power battery or capacitor requires hermetic encapsulation of a non-oxidative gas such as hydrogen inside the contactor.
It is therefore a first object of the invention to provide a reliable and low-cost switch container comprising a hollow ceramic body capable of hermetically encapsulating or sealing switch members therein, and particularly usable for a vacuum switch, a circuit breaker, a circuit contactor or the like requiring a high airtight or rather hermetic seal encapsulation for contacting or disconnecting switch-electrodes therein.
A second object of the present invention is to provide a method for producing a reliable and low-cost hollow ceramic body for use as a switch container capable of hermetically sealing switch members therein and usable as a ceramic container for a vacuum switch, a circuit breaker, a circuit contactor and the like.
The above first object of the invention has been achieved by providing a switch container for hermetically sealing switch members therein, comprising a hollow ceramic body, wherein the ceramic body contains 45 to 65% by weight of alumina and 35 to 55% by weight of crystallized glass.
In a first aspect of the invention, when the hollow ceramic body contains mullite, at least the following advantages are realized.
An advantage of the above switch container is that the hollow ceramic body itself has a high breakdown voltage (given in units of kV/mm) higher than or at least comparable to a conventional hollow ceramic body containing 85% by weight or more alumina. Another advantage of the inventive hollow ceramic body is that it has good air-tightness and good strength at least comparable to a conventional one. Therefore, the inventive hollow ceramic body is usable as a hermetic seal container for a vacuum switch, a circuit breaker, a circuit contactor, etc., requiring good insulation and high air-tightness. In addition, formation of a reliable airtight metallization on the hollow ceramic body is advantageously attained.
These advantages are more reliably secured, according to a second aspect of the invention, when the hollow ceramic body exhibits an X-ray diffraction pattern having an X-ray diffraction peak intensity of alumina that is higher than that of mullite, and an X-ray diffraction intensity peak of mullite that is higher than that of any other substance except alumina.
In other words, a desirable ceramic switch container is attained when the aforementioned crystallized glass contains mullite. Notably, mullite is a covalent orthorhombic crystal formed from Al2O3 and SiO2 and has a chemical constitution expressed by Al4+2xSi2−2xO10−x, where x=0.25-0.4.
Specifically, when the X-ray diffraction peak intensity of alumina observed at a glancing angle (2θ) of 35.152 degrees is greater than that of mullite observed at a glancing angle (2θ) of 26.267 degrees, and when the X-ray diffraction peak intensity of any other substance such as quartz is not substantially detected or more particularly does not exceed that of mullite, a ceramic switch container according to a preferred embodiment of the invention is obtained. In this X-ray diffraction analysis, X-ray scanning is carried out at a diffraction-scanning angle of 20-60 degrees using a Cu target and a Ni filter.
More specifically, as shown in
Another important advantage of the hollow ceramic body according to the invention is that a surface of the ceramic body is reliably metallized at low temperature so that various types of metal members such as an end cap and an arc shield cover can be strongly and air-tightly brazed and bonded onto the ceramic body. Notably, the term “metallization” as used herein means formation of a metallizing layer on a surface of the ceramic body. The following composition, for example, is recommended for the low temperature metallization: a composition comprising 70-94% by weight of at least one of tungsten and molybdenum, 0.5 to 10% by weight of nickel, and 2 to 23% by weight of silica. A feature of this low temperature metallization composition is that 0.5 to 10% by weight of nickel is contained therein so that the metallization is carried out at a low temperature of 1080 to 1250° C. in a hydrogen gas atmosphere. Up to 3% by weight of titanium and/or manganese may be added to the composition of the metallizing layer.
In order to hermetically bond metal members such as an end cap and an arc shield cover to the metallizing layer formed on the ceramic body by means of brazing, the metallizing layer is further baked or plated with a metal layer such as a Ni, Cu, Au or Ag layer, preferably a nickel plating layer, so as to facilitate joining the metal member and the metallizing layer via a brazing material such as an Ag, Au, Al, Ti, In or Sn based brazing material, and mixtures thereof, preferably via a Ag—Cu eutectic alloy. The hollow ceramic body for use in a hermetically sealed product such as a vacuum switch and a circuit contactor is normally cylindrical or tubular in shape. Two open ends of the cylindrical ceramic body are metallized by forming a metallizing layer comprising the aforementioned metallization composition, and the metallizing layer is metal-plated, preferably nickel-plated, so that the metal member can be hermetically bonded thereto by the brazing material.
When the switch container, which comprises a hollow ceramic body, adopts a cylindrical or tubular form, a ceramic body having a transverse strength of at least 150 Mpa as measured in accordance with Japanese Industrial Standards: JIS 1601(1981) provides the requisite strength for a switch container such as a vacuum switch container and a circuit contactor.
When a higher breakdown voltage is required for the hollow ceramic body, a glazing layer having a thickness of 0.05 to 0.20 mm and containing silica may be applied to an outer surface of the hollow ceramic body.
The second object of the invention has been achieved by providing: a method for producing a switch container for encapsulating and/or hermetically sealing a switch member therein, which comprises adjusting an amount of alumina in preparation of a raw material comprising alumina powder and clay powder; extruding the raw material into an unfired (green) hollow ceramic body; and firing the unfired hollow ceramic body at a temperature of 1200 to 1350° C. to obtain a hollow ceramic body containing 45 to 65% by weight of alumina and 55 to 35% by weight of crystallized glass the hollow ceramic body having an X-ray diffraction peak intensity of mullite that is higher than that of other substances except alumina, as measured in a X-ray diffraction analysis. In a preferred embodiment, the method comprises forming an unfired metallizing layer on a surface of the fired cylindrical ceramic body; and firing the green metallizing layer at a temperature of 1080 to 1250° C. in a hydrogen gas atmosphere to obtain a fired metallizing layer hermetically bonded to the fired cylindrical ceramic body, the fired metallizing layer containing about 70-94% by weight of at least one of tungsten and molybdenum, about 0.5 to 10% by weight of nickel, and about 2 to 23% by weight of silica.
An advantage of the above method according to the invention is that a low-cost and reliable ceramic container for a hermetically sealed product such as a vacuum switch and a circuit contactor can be obtained by extrusion-molding a raw material comprising alumina and clay. This is mainly because the extrusion-molding process is inexpensive compared to a conventional process including spray-drying and powder-pressing, and because a polycrystalline ceramic containing alumina and mullite is obtained through a comparatively low temperature firing process.
Notably, clay is a natural resource material such as kaolinite and halloysite, comprised of microscopic fine particles mainly comprising aluminosilicate. Most clays comprise about 40-80% by weight of SiO2, about 10-40% by weight of alumina and up to about 25% of other substances such as Fe2O3, TiO2, CaO, MgO, K2O, and Na2O. Since the clay comprises very fine particles and has high plasticity, it is easy to process a raw material through an extrusion-molding and the clay allows for a relatively low firing temperature if included in the raw material.
An Al2O3 powder is added to a raw material comprising a clay powder to result in a fired hollow ceramic body containing 45 to 65% by weight of alumina and 35 to 55% by weight of crystallized glass comprising mullite, according to the invention. The proportion of clay to the raw material comprising alumina powder and clay powder should fall in the range of 20 to 50% by weight, according to a preferred aspect of the method according to the invention. For extrusion-molding, an adequate amount of water is added to the raw material. In addition to adding alumina powder for adjusting the alumina content of the raw material, a suitable amount of feldspar (as a sintering conditioner) and/or silica stone (as a plasticity adjustor) may be added.
Another advantage of the above method is that a reliable and airtight metallizing layer can be formed on the ceramic container using a low temperature metallization process. The metallizing layer formed on the surface of the ceramic body by the low temperature metallization exhibits good air-tightness (i.e., a high degree of hermetic seal) and high bonding strength at the interface between the metallized surface of the ceramic body and the metallizing layer formed thereon.
The above method may further comprise baking or plating a metal layer such as a Ni, Cu, Au or Ag layer, preferably plating a nickel layer, on the surface of the metallizing layer. As a result, brazing a metal cap onto the metal-plated metallizing layer with a brazing material such as an Ag, Au, Al, Ti, In or Sn based brazing material, and mixtures thereof, preferably via an Ag—Cu eutectic alloy, becomes feasible so that a reliable switch container for hermetically sealing switch members therein is attained.
Since the hollow ceramic body comprising 45 to 65% by weight of alumina is produced by firing a green hollow ceramic body comprising alumina powder and clay powder at a firing temperature of 1200 to 1350° C. much lower than the conventional firing temperature of at least 1500° C., and since a low temperature metallization of a surface of the ceramic body is reliably attained, according to the method of present invention, furnace energy consumption is greatly reduced so as to obtain a low-cost and reliable hollow ceramic body.
In addition, the present invention allows for extrusion-molding such that spray drying of a slurry, which is required for a conventional powder-pressing process, can be avoided. As such, the production cost of the hollow ceramic body is further reduced.
Notably, the metallization temperature recommended for metallizing the hollow ceramic body, according to the invention, is lower than the firing temperature of the hollow ceramic body. Otherwise, deformation of the hollow ceramic body and/or metallization adhesion failure could occur. If alumina content is more than 65% by weight, it is difficult to prepare a green hollow ceramic body precursor using an extrusion-molding process. If the alumina content is less than 45% by weight, less polycrystalline alumina and too much mullite is formed in the hollow ceramic body as observed by X-ray diffraction analysis (see
Reference numerals used to identify various structural features shown in the drawings include the following.
A high air-tightness, and particularly, a hermetic seal is necessary for a vacuum switch and a circuit contactor incorporating switch members therein. In addition, high breakdown voltage and high strength are necessary for the vacuum switch. The contactor is a switch that controls comparably low voltage and low power, not necessarily in a vacuum but in an insulating gas such as hydrogen gas. The vacuum switch is a heavy load switch for switching high voltage and high power current, and incorporates switch members such as electrodes in a vacuum container constituting the vacuum switch.
An embodiment of a vacuum switch is described hereinafter in detail by reference to the drawings, but the present invention should not be construed as being limited thereto.
Referring to
The ceramic cylindrical tube 3 is a fired hollow ceramic body containing 45 to 65% by weight of alumina and 35 to 55% by weight of mullite and has an inner diameter of about 80 mm a wall thickness of about 5 mm, and a longitudinal length 100 mm. A glaze layer (not shown) having a thickness of about 0.15 mm may be provided on an outer circumferential surface of ceramic cylindrical tube 3.
The first and second end caps 5 and 7 are formed from a discoid plate of KOVAR (Fe—Ni—Co alloy) each having a center hole 19, 21, respectively. The movable electrode 9 composes a movable shaft 23 that is inserted through the hole 19 and an electrode 25 attached to the end of movable shaft 23. This movable electrode 9 allows an on/off switching operation in a vacuum condition by a pleated metallic bellows 27.
The fixed electrode 11 comprises a discoid electrode 31 attached to the end of a shaft 29 fixed in the hole 21. An arc shield cover 33 is provided such that it embraces the contact point 13 cylindrically. The arc shield cover 33 is brazed to the second end cap 7 in a lower flange area 35 of the ceramic cylindrical tube 3. This construction prevents metallic vapor generated from the contact point 13 at the time of turning on/off current from scattering to an inner circumferential wall of the ceramic cylindrical tube 3.
The metallizing layer 41 comprises preferably 70-88% by weight of Mo, 0.7-5.5% by weight of Ni, and 3 to 18% by weight of SiO2. The metallizing layer is formed by firing at a temperature of 1080 to 1250° C. Notably, W or a mixture of Mo and W may be used instead of Mo for the composition of the metallizing layer 41.
Next, a method of producing the ceramic cylindrical tube 3 is described.
Alumina powder, clay powder comprising kaolinite, feldspar, silica stone and water are placed into a mill, finely ground and mixed to produce a raw material for extrusion-molding. In this process of forming the raw material, the amount of alumina is adjusted, based on a pre-analyzed alumina content of the raw material, so as to produce a fired hollow ceramic body containing 45 to 65% by weight of alumina as analyzed by EPMA (Electron Probe Microbeam Analysis). When about 50-80% by weight of alumina constitutes the raw material except water, the desired hollow ceramic body containing 45 to 65% by weight of alumina and 35-55% by weight of crystallized glass comprising mullite is attained.
Next, the raw material produced by the above-process is placed into an extrusion-molding machine so as to extrude a raw tubular body having, e.g., an outer diameter of 108 mm and an inner diameter of 96 mm through an extrusion-mouth ring thereof. This raw tubular body is cut into a green cylindrical tube having, e.g., a length of about 120 mm and then dried.
Notably, a glaze-slurry may be applied to an outer surface of the green cylindrical tube, dried and fired in case a higher breakdown voltage is required, although the hollow ceramic body according to the invention has a high enough breakdown voltage normally required for the vacuum switch. The following glaze composition is recommended for that purpose: a glaze composition comprising about 75% by weight of SiO2, about 15% by weight of Al2O3, about 5% by weight of K2O, about 4% by weight of MgO and 1% by weight of Na2O.
The green cylindrical tube is placed in a furnace and fired at 1300° C. in an ambient atmosphere. Both ends of fired cylindrical tube are ground so as to obtain flat ends of a ceramic cylindrical tube 3 for metallization.
Next, a paste of low temperature metallization material is applied to both ends of the ceramic cylindrical tube 3 and dried to form green metallizing layers having a thickness of about 0.03 mm. This paste is a compound comprising about 87% by weight of the aforementioned metallization composition and about 13% by weight of an organic binder containing ethyl cellulose or the like organic binder. The low temperature metallization is performed by firing a green metallizing layer at 1100 to 1200° C. in a hydrogen atmosphere so that the metallizing layer 41 is sintered and bonded to the ends of the ceramic cylindrical tube 3.
Next, the metallizing layers 41 sintered onto the ends of the ceramic cylindrical tubes are plated by nickel so as to form plating layers 43 having a thickness of about 0.015 mm. Then, first and second end caps 5 and 7 are brazed and connected to the plating layers 43 by the brazing layer 45 comprising an eutectic silver-copper alloy. This brazing process is conducted at a temperature of about 830° C.
The switch members such as the fixed electrode 9 and the movable electrode 11 should be assembled inside of the ceramic cylindrical tube 3 and also the arc shield cover 33 should be brazed on the second end cap 7 before brazing the first and second end caps 5 and 7 onto the nickel-plated metallizing layer 43.
As described above, since the ceramic cylindrical tube 3 is produced by extrusion-molding using a low content alumina ceramic composition comprising clay, and since the low temperature metallizing layers 41 are formed on the open ends of the ceramic cylindrical tube 3 for hermetically bonding the first and second end caps 5 and 7 therewith, the production process is simplified and the production cost is greatly reduced. Furthermore, because the firing temperature of low temperature metallization is lower than that of the ceramic cylindrical tube 3, it is unlikely to cause any adverse effect such as deformation of the ceramic cylindrical tube 3. As a result, the end caps 5 and 7 connected thereto ensure a reliable, hermetic seal.
Furthermore, the ceramic cylindrical tube 3 in itself secures the necessary switch properties such as strength and insulation property, as is hereinafter explained with respect to the following Examples which confirm the advantages of the present invention.
As shown in Table 1, a total of nine kinds of experimental ceramic switch containers (namely, ceramic cylindrical tubes) each having a different alumina content and the same other materials, and each employing the same metallization composition except Sample No. 9, were made by the same aforementioned processes.
The metallization on Sample No. 9 was carried out using a metallization composition comprising 92-95% by weight of Mo and 5-8% by weight of Mn, and by sintering the composition at a temperature of about 1380° C. in a hydrogen gas atmosphere. Samples Nos. 1-7 were prepared by extrusion-molding and firing at about 1300° C. Samples Nos. 8-9 were prepared by a conventional process of spray-drying and powder-pressing, and firing at about 1300° C. and about 1550° C., respectively. The alumina contents of the ceramic cylindrical tubes after firing were each determined by means of fluorescent X-ray element analysis. Samples Nos. 3-7 are examples according to the present invention, and Samples Nos. 1, 2, 8 and 9 are comparative examples.
(1) Hermetic Seal Testing
As schematically illustrated in
A pipe 59 was formed by extending a center portion of the end cap 55 and hermetically bonding to an opening of a second chamber of a hermetic seal-testing device. As such, gas inside the switch container 57 could communicate through the pipe 59 to the second chamber, while the switch container is placed in the first chamber of the hermetic seal-testing device. A helium detector 61 (Helium Leak Detector supplied from Veeco Corp.) for detecting He was placed in the second chamber and close to an opening of the pipe 59, as shown in
Then, Helium (He) gas was supplied to the first chamber where the switch container 57 was located. On the other hand, a vacuum state of about 10−7 Torr was formed in the second chamber so that the inside of the switch container 57 was in the same vacuum state as the second chamber.
Under this condition, a leak test was conducted to check whether the helium detector 61 could detect any He leaking from the circumference of the switch container 57 into the inside of the switch container. If the helium detector 61 detects helium, it means that the switch container 57 has a compromised hermetic seal or compromised air-tightness. In this way, a leak test or more particularly, hermetic evaluation was carried out on every sample.
The results of the hermetic evaluation are shown in Table 1, wherein the mark (O) indicates no He-leakage. As is apparent from Table 1, all the samples had no He-leakage and showed good hermetic performance. This means that the hollow ceramic body according to the invention is capable of being metallized. In addition, the low temperature metallization using the aforementioned metallization composition provides excellent air-tightness between the metal end caps and the ends of the ceramic cylindrical ceramic tube.
(2) Transverse Strength Measurement
Two ceramic pieces 50 mm in length, 4 mm in width and 3 mm in thickness were cut out from each sample for measuring the transverse strength thereof.
The transverse strength measurement was conducted on each sample, according to Japanese Industrial Standards: JIS R1601 (1981), which specifies a three-point bending test.
The transverse strength measurement was carried out before and after heat treatment at a first temperature elevation of up to 1200° C. and cooling to room temperature and at a second temperature elevation of up to 800° C. and cooling to room temperature.
The results of the transverse strength measurements are shown in Table 1. As is apparent from Table 1, the strength of the ceramic body decreases as the alumina content decreases. However, Sample Nos. 3-7 according to the present invention show adequate strength, and have a transverse strength value higher than 150 Mpa that is minimally required for a vacuum switch container and a contactor container.
(3) Breakdown Voltage Measurement
As shown in
The breakdown voltage causing dielectric breakdown was measured by a breakdown voltage tester supplied by Meiji Denki Co. The results of the test are shown in Table 1. As is apparent from Table 1, the breakdown voltage increases as the alumina content decreases. Samples Nos. 3-7 according to the invention showed adequate breakdown voltage higher or at least comparably as high as that of Sample No. 9 made by a conventional method.
(4) Bonding Strength Test on Metallization
As schematically shown in
Then, as schematically illustrated in
An average value of the maximum puling strengths of the five metal pins pulled apart from each ceramic cylindrical tube is given in Table 1 as the bonding strength of metallization. As is apparent from Table 1, the bonding strength of metallization decreases as the alumina content decreases. However, Sample Nos. 3-7 according to the present invention show a sufficient bonding strength, higher than 150 Mpa that is minimally required for a vacuum switch container and a contactor container.
(5) X-Ray Diffraction Analysis
An X-ray diffraction analysis was carried out on the samples so as to identify the types of microcrystalline substances formed in the ceramic body.
The X-ray diffraction analysis patterns observed on Comparative Samples Nos. 1 and 2 were similar to
It is understood from the above X-ray diffraction analyses that when the alumina content does not exceed about 40% by weight in the hollow ceramic body, polycrystalline alumina that diffracts X-rays either is not formed, or formed to a lesser degree, and that mullite and/or quartz are formed instead. In other words, the alumina and clay contained in the raw material dissolves to form covalent mullite during firing of the green hollow ceramic body made from a raw material of low alumina content. If SiO2 is abundant in clay and less Al2O3 is added to the raw material, the tendency is that less mullite and more quartz is formed.
The X-ray diffraction analysis patterns carried out on Samples Nos. 3-8 were similar to
The above X-ray diffraction analysis patterns demonstrate that Samples Nos. 3-8 of the invention comprised polycrystalline alumina and crystallized glass containing mullite. This is because the X-ray diffraction intensity peaks of crystalline substances other than polycrystalline alumina and mullite were not noticeably detected. Crystallized glass as used herein means glass containing mullite and some amorphous glass. The amount of amorphous glass formed in the crystallized glass is up to 25% by weight of the total crystallized glass. This is because the raw material comprising clay contains about 5-25% by weight of various glass-forming substances such as Fe2O3, TiO2, CaO, MgO, K2O and Na2O other than mullite-forming substances of Al2O3 and SiO2, and no detectable X-ray diffraction intensity peaks of crystals formed from these glass-forming substances were detected. Notably, the mullite is formed from SiO2 and Al2O3 at a temperature of about more than 1200° C.
In sample No. 9, six X-ray diffraction intensity peaks of alumina similar to those in
Overall Evaluation of the Samples
All of transverse strength, breakdown voltage, bonding strength of metallization and air-tightness (hermetic seal) are necessarily required properties for the switch container and contactor. Comparative Samples Nos. 1 and 2 showed lower values in both transverse strength and bonding strength of metallization than Sample Nos. 3-7 of the invention, as shown in Table 1. This is probably because the alumina grains are not aggregated and instead, quartz is formed in the hollow ceramic bodies of Samples Nos. 1 and 2. The overall evaluation on Sample Nos. 1 and 2 are judged poor, as indicated by X in Table 1.
Comparative Samples Nos. 8 and 9 have a production cost problem. This is because it is difficult to utilize an extrusion-molding process for extruding a raw material containing about 70% or more by weight of alumina. Therefore, a costly powder-pressing process that requires spray-drying and/or other complicated works is necessary. The overall evaluation of Sample Nos. 8 and 9 was not so good, as indicated by A in Table 1, mainly because of the production cost.
In contrast, the overall evaluation of Samples Nos. 3-7 comprising 45-65% by weight of alumina and 35-55% by weight of crystallized glass containing mullite, according to the invention, was excellent as indicated by O in Table 1. This is because the transverse strength, voltage, air-tightness and capability of low temperature metallization were all satisfactory for the switch container, and most importantly because low cost extrusion-molding can be used for producing the hollow ceramic body.
The present invention is by no means limited to the foregoing Examples, but various types of embodiments may of course be executed without departing from the scope and spirit of the present invention.
For example, although a single-layer low temperature metallization was described in the aforementioned embodiments, a multilayer low temperature metallization may be adopted. For instance, a double-layer metallization may be used, which comprises formation of a bottom metallizing layer and a top alloy layer. The bottom layer may be made of a low temperature metallizing layer comprising 70 to 88% by weight of Mo and 0.7 to 5.5% by weight of Ni and the top layer may be made of an alloy comprising 35 to 75% by weight of Ni and 25 to 65% by weight of Cu and/or 2 to 30% by weight of Mn. The multilayer metallization is made by firing the layers at 1100-1200° C. in a hydrogen gas atmosphere.
The extrusion-molding process as described in forming the aforementioned switch container comprising a hollow ceramic body (e.g. a ceramic cylindrical tube) includes an injection molding process.
The best mode product according to the invention is attained when roughly middle values of the aforementioned compositions and temperatures are utilized.
This application is based on Japanese Patent Application No. 2004-119208 filed Apr. 14, 2004, incorporated herein by reference in its entirety.
| Number | Date | Country | Kind |
|---|---|---|---|
| 2004-119208 | Apr 2004 | JP | national |
