The present invention broadly relates to gasifier technology and, more particularly relates to a gasifier system configured for energy-efficient generation of an oxidizing air/steam mixture and distribution of same within the gasifier chamber to optimize a biogas production.
Gasification is a high-temperature thermal decomposition process for converting a fuel or feedstock, such as solid coal, petroleum coke, biomass, and/or solid waste, or liquid feedstock, such as black liquid oil, or a gaseous feedstock, into a fuel gas, consisting primarily of hydrogen (H2) and carbon monoxide (CO), with lesser amounts of carbon dioxide (CO2), water (H2O), methane (CH4), higher hydrocarbons and nitrogen (N2) using reactants such as air, steam and oxygen, either alone or in any combination thereof.
Thermal gasification processes are highly endothermic chemical reactions. The general methods for supplying heat for the gasification use either of the following: a) an external source, e.g. sensible heat from hot char recirculation, and/or sensible heat from a heated gasification agent, b) reaction heat from oxidization of a part of the feedstock (incoming carbonaceous materials), and c) exothermal reaction heat from a non-carbonaceous material such as calcined lime and CO2.
The heated air/steam mixture 30, which contains oxygen, may be said to “roast” the biomass fuel 20 in pyrolysis and gasification zones in the lower part the reaction chamber 15. That is, the biomass fuel 20 is partially combusted using the oxygen in the air/steam mixture 30. Partial combustion and pyrolysis result in the production of heated biogas 45 (referred to interchangeably herein as produced gas or synthetic gas), which heated biogas exits from gas outlet port 50 and is captured by means known to the skilled artisan. Ash including carbon, charcoal, etc., and other combustion and pyrolysis by-products 55, such as burnt embers, exits the reaction chamber 15 though an opening or port 60 in a bottom surface.
Tar is an undesirable by-product which is produced when the partial combustion temperature drops from 1000 degrees Centigrade to below 800 degrees C. The temperature inside of the reaction chamber 15 is controlled by controlling the rate of combustion therein by adjusting the amount of air/steam supplied. Ideal reaction chamber temperatures for optimized biogas generation are as follows: bottom or combustion zone temperature: about 1000 degrees C. or greater; lower middle or gasification zone temperature: about 600 degrees C.; upper middle or pyrolysis zone temperature: about 200 degrees C.; and top or reheating zone temperature: about 60 degree C. Typically, the reaction chamber temperature is controlled so that it drops to a temperature in which tar is produced after the biogas exits the gasifier chamber 15 (see inventive system depicted in
Conventional gasifier constructions (such as shown in
As the gasifier uses steam as an oxidant, it is quite difficult to maintain conditions that allow gasifier to properly crack the gas, typically resulting in a large mass of tar being unintentionally produced. When humidity of bio-mass at entry port 25 is more than 4%, more tar is produced. When tar is produced in the reaction chamber, it damages steam generator, hot air generator as well as any heat exchanger, requiring maintenance. Secondarily, the inability to effectively distribute the heated air/steam mixture results in limited biogas quality, for example, a diminished H2 content.
The present invention presents a gasifier system that overcomes the shortcomings of known gasification systems and methods.
The gasifier system of the invention does not need to use extra fuel to boil water and heat air as it reuses waste heat of the gasifier, resulting in cost savings in the generation of biogas and in view of the fact that extra burners for heating the air and water/steam are unnecessary.
The inventive gasifier system operates with Double-Decker tube manifold construction formed to effectively disperse oxidizing air/steam through the biomass/reactions chamber. The burner manifold comprising the Double-decker tubes is located on a water-cooled support bar such that the Double-Decker tubes may move with heat expansion independently of the gasifier wall structure to prevent lock up and damage to the structure or tubes.
In an embodiment, the invention provides a gasifier system for converting biomass to biogas includes a reaction chamber with a biomass supply port for receiving a biomass volume, a waste outlet port for discharging biomass conversion by-products, a gas inlet for receiving heated oxidizing gas, a gas outlet for discharging generated biogas and a burner manifold for distributing oxidizing gas within the chamber to react the biomass. The burner manifold includes primary tubes and secondary tubes, positioned in a vertically lower part of the chamber and configured with multiple openings or ports for dispensing the oxidizing gas, where the secondary tubes extend into, inject and evenly distribute the oxidizing gas into the biomass volume to optimize conversion to biogas.
The gasifier system may includes a water-cooled support system positioned in the reaction chamber to support and enable the burner manifold to expand and contract in response to changes in temperature without obstruction, and a controller. Preferably, the water-cooled support system is physically attached to a reaction chamber wall with a top surface that extends into the reaction chamber and is in sliding contact with the burner manifold.
In another embodiment, the invention provides a gasifier system converting biomass to biogas that includes a reaction chamber including a regulated input port for receiving a biomass volume, a waste outlet port for discharging biomass to biogas conversion by-products, a regulated gas inlet for receiving heated oxidizing gas, a regulated gas outlet for discharging generated biogas, a burner manifold and a water heating chamber. The burner manifold is included for distributing oxidizing gas within the reaction chamber that comprises primary and secondary conduits, is positioned in a vertically lower portion of the chamber and is configured with multiple outlets or ports for injecting the oxidizing gas into the biomass volume, substantially evenly distributing the oxidizing gas therethrough.
The water heating chamber is in fluid communication with the gas outlet for receiving a flow of hot biogas, exposing water to the hot biogas to heat the water to steam and supplying the steam to the gas inlet port as oxidizing gas. Preferably, the gasifier system further includes an air heating chamber in fluid communication with the gas outlet for receiving a flow of hot biogas, exposing air to the hot biogas to heat the air and supplying the heated air to the gas inlet port as oxidizing gas, where the heated air and steam are first mixed before being supplied as oxidizing gas.
The present invention can best be understood in connection with the accompanying drawings. It is noted that the invention is not limited to the precise embodiments shown in drawings, in which:
The following is a detailed description of example embodiments of the invention depicted in the accompanying drawings. The example embodiments are in such detail as to clearly communicate the invention and are designed to make such embodiments obvious to a person of ordinary skill in the art. However, the amount of detail offered is not intended to limit the anticipated variations of embodiments; on the contrary, the intention is to cover all modifications, equivalents, and alternatives falling within the spirit and scope of the present invention, as defined by the appended claims.
Air and/or steam 30 are supplied to the double-decker tubes 85 through a gas inlet port 35. As can be seen in the
The oxidizing gas distribution manifold 82 relies on the double-decker tubes 85 (comprising two main conduits) to function as primary conduits and further comprises a plurality of secondary tubes 88 that extend from the primary conduits or tubes 85. The surfaces of the secondary tubes 88 are configured with a distribution of small through-holes 86 to allow oxidizing gas, an air/steam mixture, to effectively distribute the air/steam mixture within the volume of biomass in the reaction chamber 15. For that matter, some part of the surfaces of the primary double-decker tube conduits also may be configured with through-holes 86 to disperse the air/steam mixture.
The air/steam mixture 30 is blown out via the small holes 86 of the secondary tubes 88, spouting in all directions, i.e., the upper direction, the side directions and the lower direction to evenly mix within and heat to decompose the bio fuel. This distribution mechanism, i.e., the oxidizing gas distribution manifold 82, results in a more effective dispersion of oxidant and heat throughout the biomass volume with the reaction chamber 15, thereby optimizing temperature control and gasification. Please note that while not shown, the double-decker tubes also may include through-holes to support air/steam dispersion.
The oxidizing gas distribution manifold 82, comprising double-decker tubes 85, secondary tubes 88 and through-holes 86, offers a significant advantage over the use of a single inlet to deliver oxidizing gas in known gasifier designs. For that matter, while double-decker tubes are preferred, single or triple-decker tubes may be used in place of double-decker tubes without deviating from the inventive scope. The arrangement of the secondary tubes 88 and through holes 86 for dispersing the oxidant throughout the biomass volume is of primary importance as same arrangement defines the effectiveness of the oxidizing mixture with the biomass and, therefore, the effectiveness of biogas generation.
As already mentioned, while the double-decker tubes 85 are preferred, a single layer or level of tubes (as distinguished from double-decker layer of tubes) may be used to form the oxidizing gas distribution manifold 82. A single (horizontal) tube layer formed in a rectangular shape is much more likely to be unstable, however, as there is at times an uneven weight distribution of biomass fuel across the oxidizing gas distribution manifold 82. Consequently, even where the single level (primary conduit) design is arranged in an inverted quadrangular pyramidal structure, same may nevertheless be unstable and more likely to twist and possibly topple over inside the chamber 15 when compared to the preferred oxidizing gas distribution manifold 82 formed with the double-decker tubes.
The formation or manufacture of the oxidizing gas distribution manifold 82 with double-decker tubes 85 and secondary tubes 88 is now described in cooperation with
During gasifier system operation, biomass fuel is decomposed and burned in the gasifier chamber 15 at rates that change according to the amounts of available air and steam. When the burning rate changes, the temperature changes accordingly. For that matter, there are different zones within the reaction chamber, with ideal temperature ranges to optimize the process and therefore biogas generation. For example, in and around what may be described as a first or pre-heating zone A, the temperature is preferably maintained at or around 60° C. This pre-heating zone operates to remove moisture from the bio fuel. In the drying area, or zone A, the bio-mass dries as the temperature rises.
In a pyrolysis zone B, the temperature preferably is around 200° C., to which the biomass or bio fuel begins decomposition reacts to generate carbon (C) and volatiles. Vertically lower in the chamber is a gasification zone C. Gasification zone is preferably maintained at or around 600° C. to react carbon (C) compounds with H2O and air (O2) to realize carbon fuels (CxHy), carbon dioxide (CO2), carbon monoxide (CO) and hydrogen (H2). The simplest way to adjust the product (gas) is to select to bio-mass material. Woodchip is the best material, then rice husk and straw. Food residue is also available but it contains large amounts of water that precipitate tar formation.
In the pyrolysis zone, or zone B, the bio-mass material is thermally decomposed according to
CxHyO2->Ch4,CO,CO2,H2,H2O,Cs,Tar.
At reduction zone, or gasification zone C, gasification of solid carbon at heat decomposition according to C+H2O->CO+H2.
At oxidation zone, or zone D, heat is generated with controlled burning (oxidation).
C+½O2->CO+29.4 kcal
C+O2->CO2+97 kcal
In gasifier 100 (
In more detail, the coefficient of thermal expansion for SUS 304S steel is 17.3×10−6/° C. The temperature of the incoming air/steam 30, for example, is likely less than or equal to 100° C. (212° F.), where the temperature of the biogas produced is in a range around 800° C. (1500° F.). As this temperature differential is about 700 Centigrade degrees, the steel comprising the double-decker tube 85 and secondary tubes 88 likely expands and contracts significantly over time. For example, the length of a 2 meter steel pipe will change in length with a 700 degree Centigrade increase in temperature (2×700° C.×17.3×10−6/° C., or 0.02422 m) This is about one inch over 2 meters.
As the stainless steel double-decker tubes 85 are fixed or locked to the inner chamber wall, expansion is limited and likely results in bending of the tubes and/or of the inner chamber wall to which the tubes are attached via plates 90.
If expansion is extreme, the deformation of the chamber walls may be irreversible, resulting in a need for shutdown and refurbishment. But even where the expansion is not so extreme, when the gasifier cools, the oxidizing gas distribution manifold 82 including the double-decker tubes 85 contracts in the direction of arrow 95′ shown in
An embodiment depicted in
Each water support bar 107 is fixed to and extends through the reaction chamber wall. The in-chamber portion of the water-support bars 107 contact and support the oxidizing gas distribution manifold 82 and double-decker tubes. Left and right sides of the double-decker tube 85 slidably rest upon the respective left and right water support bars at contact points 108, as shown. The water flow through the water-support bar 107 is controlled in order to limit the amount of heat captured. Under normal conditions, the water flow rate is maintained so that the water exiting outlets 109 is not greater that 50 to 95 Centigrade degrees, preferably 60° C. Means for monitoring water temperature and regulating the water flow rate (for example, where the left and right side flow rates are different) are known to the skilled artisan, and therefore, not directly represented in the figure.
Please note that the water cooled support system including water support bars 107 obviates a need for means for fixing or attaching 90 the oxidizing gas distribution manifold 82 to the inner chamber wall. The water support bars 107 allow the double-decker tube structure to slide and move with respect to the chamber wall during expansion and contractions resulting from changes of temperature. That is, the double-decker tubes 85 are supported by and essentially slide over the water-support bar 107 at contact points 108. While not shown in
A steam generator chamber 140 generates steam and provides sit to air and steam mixing chamber 120 via steam conduit or line 145. To generate steam, water from outside water tank 150 is heated in boiler tank 155 by burner 160. The heated water and steam passes within steam tubes 165, where it is further heated from the flames generated by burner 160, moving into the conduit 145 and to the air and steam mixing chamber 120. A steam back off/backflow valve 170 allows for the control of the steam flow and/or volume into the air and steam mixing chamber 120, and prevents backflow. Combustion products are exhausted from the steam generator via stack 175.
In greater detail, water and steam are heated in steam tubes 165 within steam generator chamber 142 using heat supplied by the high-temperature biogas flowing from gas outlet 50. Like steam generator chamber 140 (
The biogas is further directed from steam generator chamber 142 to hot air generator chamber 180 via gas conduit/line 190. Therein, part of the heat remaining in the biogas is transferred to air within air heating tubes 185. The heated air then proceeds via conduit 125, under pressure by air blower 135, to air and steam mixing chamber 120. Using the heat from the generated biogas avoids the need for a separate heat source to heat the air prior to injection into reaction chamber 15. Using heat from the hot biogas to heat both the air and steam results in an energy cost reduction that is essentially twofold. Not only is the heat from the biogas used to generate and superheat steam, and heat air for mixing with the steam, but by transferring some of the heat from the biogas, less energy is required to cool the hot biogas to condense it for use.
A catalyzing chamber 210 is connected to gas outlet port 50 which removes tar-based constituents from the generated gas before it flows into the steam generating chamber 142 and the air heating chamber 180. Generated biogas flows out air heating chamber 180 via biogas outlet 192 to heat exchanger 215 (
A waste gas exhaust port 230 exhausts gases not suited for consumption by engine/generator 200. A gas analyzer 228 senses or identifies gas constituents. While not shown, a gas filter or separator may be included to distinguish and separate gases not suited for engine/generator consumption. A flare port 235 provides for burning the biomass at times when the engine/generator is not operational, ready to receive and burn the generated biogas. Burner 238 is controlled by a controller 300 (
Any number of sensors, flow detectors, level detectors, etc. may be disposed throughout the engine/generator and gasifier system. For example, and as shown in
Pressure sensor P1 is positioned at heated steam outlet 170 and pressure sensor P2 is positioned at hot air outlet 130. Level sensors L1 and L2 are positioned to detect the closed and open positions, respectively, of upper shutter 22. Level sensors L3 and L4 are positioned to detect the closed and open positions of lower shutter 22. Level sensor L5 is positioned at the halfway container of shutter 22. Signals generated by the level sensors L1-L5 are utilized to activate solenoid valves that are controlled to open and close the shutters during various stages of the gasification process. Level sensor L6 is positioned at an upper location within the gasifier chamber 15 (zone A) to detect a full level of biomass fuel, while level sensor L7 is positioned at a lower location within the gasifier chamber 15 (zone B) to provide a low fuel indication. Signals generated by level sensors L6 and L7 are used to control the amount of bio-fuel to be processed at any given time.
Level sensor L8 is positioned in water tank 150 outside steam boiler 155, to control solenoids that regulate water flow in. Similarly, level sensors are preferably positioned in the conduits comprising the water-cooled support system for supporting and cooling the oxidizing gas distribution manifold 82 in the gasifier 100′. The level sensors control solenoids which open and close to control the flow of water. Level sensors L9 and L10 are positioned at the respective open and closed positions of exhaust port 230, to control open and closing, and level sensors L11 and L12 are positioned at the respective open and closed positions of flare port 235. While not shown, flow sensors may be included to detect the air flow, biogas flow and the air/steam mixture flow at the respective air blower 135, biogas outlet 192 and gas inlet 35.
The controller 300 processes the sensor inputs (i.e., the sensor signals), and generates sensor outputs in the form of control signals to control gasification processes. The signal from every sensor go into input port and change the signal from analog to digital, if needed, and the Controller calculate using the algorism. And then it outputs the signal to actuators through output port. D/A converter will be used if needed. Actuators are for example, motors, solenoid valves for shutter cylinders and flare valves.
The process flow of the generator system depicted in
When level sensor L5 senses that the bio-fuel level is full a signal is generated to control motor M1 to stop, and to close the upper shutter. At this time, the level sensor L1 should be “on,”, and solenoid valve at level sensor L2 should be in an open state. When level sensor L1 is on, the lower shutter is opened. When L3 is off and L4 is on, biomass is fed into the gasifier 100′. The procedure is repeated several times until L7 is on and then L6 is on. When L6 is on, the bio-mass is at full in the gasifier.
The controller 300 starts up blower 135 in order to add air into the gasifier 110′ and starts up blower 225 to suck the gas from the gasifier 100′. P2 senses the air pressure. Then, ignition is manually carried at an ignition port, which is closed and sealed upon ignition. As combustion occurs, temperature sensor T2 sensing the increasing temperature. When T2 senses that the desired temperature (around 800 to 1000 degree in centigrade) is reached, the speed of blower 9 is adjusted o decrease the amount of oxygen. When sensor T6 detects that the temperature reaches 100 degree C., vapor is released. When P1 senses the steam pressure, it blows out from the Double Decker tubes 85 in the gasifier.
The exhaust port is actuated, which sets the valve L9 in open position. The initial gas which does not contain fuel gas and not suited to engine fuel goes out to atmosphere. The controller 300 receives sensor data from gas analyzer G1. If the density of gas is low, the speed of blower 135 is decreased and bio-mass is added until the level sensor L6 generates an active signal. The operational speed of blower 225 is decreased to enlarge the burning zone in the gasifier 100′. When gas contains enough fuel (CmHn and Hydrogen and Carbon monoxide), the operational speed of blower 225 is increased
The biogas first leaving the reaction chamber through outlet 50 contains tar, which is reduced in catalyzing chamber 210. When the gas is found to contain a sufficient amount of CmHn, the flare port 235 and burner 238 are actuated, setting the valve L12 to its closed position. Then, the exhaust port 230 is actuated, setting valve L10 to its closed position. Biogas is the burned.
When engine is ready, the flare port 235 is actuated to close and valve L11 is opened to transfer Biogas to engine 200. A start signal is sent to the engine controller 240, which operates the engine. When engine speed is slower than the set value, it is receiving less biogas than required whereby the controller increases the operational speed of blower 225 and the operational speed of blower 210. When the engine speed is higher than the set value, the operational speed of the blower 225 and the blower 210 are decreased to decrease biogas.
In order to shut down operation, the upper and lower shutters are closed by setting level sensors L1 and L3 to an on state. Blowers 225 and 210 are stopped, flare port 225 is opened and burner 238 is ignited. For that matter, conveyer M1 must be stopped. As the temperature at sensor T4 is indicated as decreasing, the water supply is still maintained. When temperature T4 is sensed to be around 40 degrees C., the system is essentially shut down. Hence, the burner 238 at flare port 235 may be extinguished as there is no more biogas being generated. The level sensors L9 then open and exhaust any remaining gas to atmosphere. Only when the temperature sensor T2 is sensed to be below 30 degrees C. is the water supply stopped.
In the foregoing description, certain terms and visual depictions are used to illustrate the preferred embodiment. However, no unnecessary limitations are to be construed by the terms used or illustrations depicted, beyond what is shown in the prior art, since the terms and illustrations are exemplary only, and are not meant to limit the scope of the present invention.
It is further known that other modifications may be made to the present invention, without departing the scope of the invention, as noted in the appended claims.