The present application relates to the field of cathodoluminescent light emitting devices, and in particular relates to device structure and methods for manufacturing such devices.
It has been known for more than a century that electrons accelerated towards and striking an anode at high energies will cause a cathodoluminescent phosphor on the anode to emit light. When used with tightly focused electron beams and magnetic or electrostatic deflection systems, this method of producing light from phosphors has been widely used in display devices for generations. It has been proposed to use an electron beam to excite phosphors for general room lighting.
There are many differences in detail between the requirements for general room lighting devices and display devices.
A prior anode fabrication method for monochromatic phosphor screens is as follows:
Electron guns are commonly used for generating an electron beam for use in Cathode Ray Tubes (CRTs), electron microscopes, x-ray tubes, and other applications. In common use, the electron gun or electron source has electron optics for beam control, typically forming a narrow beam, and in order to stabilize emission. Each electron source has at least one cathode.
In every basic free electron-source lamp, regardless of the type of electron source (thermionic cathode, cold cathode, field-emission cathode), it is required to have an anode contact that allows return of current from the anode. These contacts are typically spring-formed contacts that extend into a glass envelope of the lamp to contact the anode layer.
A device for lighting a room is described. The device has an envelope with a transparent face, the face having an interior surface coated with a cathodoluminescent screen and a thin, reflective, conductive, anode layer. There is a broad-beam electron gun mounted directly to feedthroughs in a base of the envelope with a heated, button-on-hairpin, cathode for emitting electrons in a broad beam towards the anode, and a power supply mounted on the feedthroughs at the base of the envelope that drives the cathode to a multi-kilovolt negative voltage. A two-prong snubber serves as an anode contact to permit the power supply to drive the anode to a voltage near ground. A method of manufacture of the anode uses a single step deposition and lacquering process followed by a metallization using a conical-spiral tungsten filament coated with aluminum by a thermal spray coating process.
A method of manufacturing an anode for a cathodoluminescent lighting device includes depositing a layer of aluminum on a spiral tungsten filament, inserting the spiral tungsten filament into the envelope under vacuum, preheating the filament to a first temperature, the first temperature above a melting temperature of the aluminum but below a temperature required to significantly evaporate the aluminum, and then rapidly heating the filament to a second temperature, the second temperature above a melting temperature of the aluminum. The filament is held the second temperature for a predetermined time of about one to three seconds, cooled, and removed from the envelope. An oxidizing atmosphere is admitted to heated envelope to burn off excess lacquer. In particular embodiments, the spiral tungsten filament has a conical shape with an apex of the filament closest to the phosphor layer on the face of the envelope on which the anode is being formed. In an embodiment, the filament is coated with aluminum prior to deposition with a thermal-spray coating process.
After the metallization is completed, a multiform assembly having an electron gun and a 2-point contact snubber for contacting the anode are directly mounted within the envelope on one millimeter diameter passthroughs embedded in a glass disk that is then fused into a base of the envelope, and the envelope is evacuated. Also mounted on, and electrically coupled to, the passthroughs, but outside the envelope, is a power supply unit that has a connector for attachment to a lighting fixture. Empty space within the power supply unit and connector is filled with an encapsulant.
It is proposed to take advantage of the glow produced by cathodoluminescent phosphors when struck by electrons for general room lighting. In a general lighting device, a broad, unfocused electron beam may be used in a vacuum device to illuminate a wide anode equipped with a cathodoluminescent screen without need of a deflection system. General lighting devices are, however, quite price-sensitive; it is desirable to prepare the vacuum device, including its anode, at low cost while producing an efficient anode.
An exemplary cathodoluminescent light emitting device 100, as illustrated in
A desired construction of the facial portion of anode 106 may in some embodiments have an optional transparent conductive layer 150 (
A cushion solution is prepared in step 307, by dissolving one gram of barium acetate in water. A portion of cushion solution is placed into the envelope, in step 308. A smaller portion of slurry is then injected into the envelope on the cushion solution, in step 309. Phosphor particles are allowed to settle, in step 310. For example, phosphor particles are allowed to settle onto face 112 of envelope 114 while envelope 114 is gently tilted and rotated to encourage formation of a phosphor layer 110 of nearly uniform thickness on face 112. In an embodiment, 150 milliliters of cushion solution and seventeen milliliters of phosphor slurry are used for each envelope, and twelve minutes are allowed for settlement. Rotation of the envelope is then stopped.
A lacquer is prepared as a solution of a film-forming organic lacquer or polymer compound in an organic solvent that is immiscible in the slurry carrier solvent and cushion solution. In an alternative embodiment that ues an electrolyte solution, the organic solvent is immiscible in the electrolyte solution. The lacquer solution has a specific gravity lighter than the carrier solvent, cushion solution, or electrolyte solution. In an embodiment, the lacquer has a three to five percent solid content of nitrocellulose or an acrylic lacquer dissolved in a solvent comprising ethyl acetate and other organic solvents.
In an embodiment, lacquer is applied directly over the cushion solution in the envelope. In an alternative embodiment that makes use of an electrolyte solution, lacquer is applied over the electrolyte solution. In either embodiment, lacquer is applied over an underlying liquid in the envelope.
In the alternative embodiment using an electrolyte solution, the liquid in the envelope, including remaining cushion solution and carrier solvent, is removed 311. Those portions of the envelope for which phosphor coating is not desired are cleaned with deionized water, the phosphor coating is dried, and an aliquot of the electrolyte solution is added to the envelope.
An aliquot of the prepared lacquer is then added on top of, or floated on, the underlying liquid in the envelope, in step 312. Since the lacquer solvent has specific gravity less than that of the underlying liquid in envelope 114, the lacquer floats on the liquid. In an embodiment, the aliquot of prepared lacquer ranges from 0.3 to 0.5 milliliter.
The prepared lacquer is allowed to spread over the carrier solvent and at least a portion of the volatile organic lacquer solvent is allowed to evaporate, in step 314. This allows the lacquer or polymer content of the lacquer solution to form a smooth, and at least partially solidified, film 402 (
In an embodiment, envelope 114 is gently rotated to an inverted position. During this rotation, gravity causes the underlying liquid 404 (the underlying liquid being carrier solvent and cushion solution, or electrolyte solution), 404 to burst through lacquer film 402 at a lower edge, and underlying liquid 404 then pours out of envelope 114. As carrier solvent 404 pours out, lacquer film 402 rises to settle onto phosphor layer 110.
In an alternative embodiment, a probe 406 is introduced to envelope 114, extending below lacquer film 402. Underlying liquid 404 is carefully suctioned or siphoned to remove underlying liquid 404 in step 316. In embodiments using suctioning, envelope 114 may be tipped, as illustrated in
The resulting structure of phosphor coated by lacquer is then baked dry at a temperature of less than 100 Celsius, in step 317. Baking drives out remaining lacquer solvent from the lacquer film. Further, baking helps evaporate the remaining carrier solvent 404 and cushion solution through lacquer film 402. After baking, the resulting structure has a final lacquer layer 154 (
Excess lacquer is then removed, in step 318, for example by mechanically wiping the interior of the envelope at locations where a phosphor screen is not desired.
In some alternative embodiments, an optional transparent conductor layer is deposited on face 112 of envelope 114 after cleaning and before placing the slurry in envelope 114 (step 308) as shown in optional step 304.
It has been found that a thin and uniform metal coating over lacquer layer 402 at face 112 of envelope 114 is desirable for efficient operation of the lighting device. It has been found that achieving a uniform metal coating requires care. Uniformity of the coating layer is sensitive to deposition filament shape as well as a method of applying metal to be deposited to the deposition filament.
In an embodiment, the narrow end, or apex, of the spiral is approximately five millimeters in diameter, and an angle 504 between an axis of the spiral and the sides of the spiral is between five and forty-five degrees, and preferably approximately ten degrees. The apex of filament 502 is fed through an axial branch 505 of filament 502. In an embodiment, the spiral portion of filament 502 is approximately sixteen millimeters long and has a winding pitch of two millimeters.
In a particular embodiment, the spiral is coiled more tightly at a center-apex of filament 502, as illustrated in
Filament 502 is equipped with a masking cup 507 that obstructs line of sight from filament 502 to those portions of envelope 606, primarily in lower neck 609 of envelope 606, on which aluminum conductive coating is not desired. Filament 502 is mounted to a pair of buss-bars 630 that are capable of carrying the high current used for coating face 610.
Returning to method 300 (
In an alternative embodiment, the conductive metal is aluminum and is applied to filament 502 by draping a thin aluminum foil over filament 502, and then heating filament 502 to at least 680 Celsius under non-oxidizing atmosphere to melt some of the foil such that resulting melted aluminum adheres to filament 502.
In an alternative embodiment filament 502 is coated with aluminum by dipping filament 502 into molten aluminum. This method may, however, be difficult to control. In yet another alternative embodiment, filament 502 is coated with aluminum by dusting or painting filament 502 with material comprising a finely-ground aluminum powder.
Coated metal filament 502 on its buss-bar support 630 is inserted into envelope 606, in step 322. Envelope 606 has already been coated with phosphor and lacquer layers as previously described. In an embodiment, insertion is achieved by inverting envelope 606 and placing it over filament 502. A vacuum is applied to envelope 606 and filament 502 in step 324, so as to avoid oxidation of the aluminum during evaporation. In an embodiment, the apical tip of filament 502 is between two and six, and preferably about four, centimeters from the phosphor and lacquer layers
Once the vacuum is applied, filament 502 is preheated, in step 326. Filament 502 is for example heated to a temperature close to and slightly above the six hundred sixty degree Celsius melting point of the aluminum with which it has been coated. The preheat temperature is selected to be low enough that the vapor pressure of aluminum is quite low, and little evaporation occurs. The preheat temperature is high enough that the aluminum wets the surface of the filament.
Filament 502 is then heated to a temperature above the melting point of the coating metal (i.e., aluminum), in step 328. In one example, filament 502 is brought rapidly to a temperature of substantially above the preheat temperature and well above six hundred sixty Celsius to evaporate the aluminum and coat the envelope, lacquer, and phosphor within about one to three seconds. This may be achieved by an electric current of approximately one hundred sixty amperes maximum. Other embodiments having other filament diameters may use other current levels. Once the aluminum is evaporated, condensing to form a coating on the lacquer and phosphor, filament 502 is cooled and removed from the envelope, and air or oxygen is admitted, in step 330. Envelope 606 is heated to approximately 450 degrees Celsius in an oxidizing environment, such as air or oxygen, to char and thereby burn off the lacquer, leaving a final structure of a smooth-surfaced reflective metal film adherent over the somewhat rougher phosphor layer.
In an embodiment, for operation with a cathode-anode voltage of approximately fifteen to sixteen thousand volts, the aluminum coating over the phosphor is preferably in the range of approximately sixty to ninety nanometers thick. The resulting aluminum coating is in contact with, and adherent to, phosphor particles and silica binder at high points of the microscopically-rough phosphor layer, while tenting over low points of the phosphor layer.
In an embodiment of method 300, a rack 620 (
The envelope is then transferred to an oxidizing atmosphere and heated; the lacquer layer oxidizes and disappears; a step known as burning off the lacquer.
Once the lacquer has been burned off, the envelope, with phosphor coating and metallization is ready for a base assembly having an anode contact and a cathode 700 to be inserted into it; the glass base of the base assembly is fused with the edges of the envelope with vacuum applied, thereby completing assembly of the bulb portion of the light emitting device.
The base assembly has a cathode 700 as illustrated in
A tungsten, or tungsten alloy, wire 708 is bent to form an inverted ‘U’ shape with a flat bottom 710 to provide a heating element 707. Substrate 702 is attached electrically and mechanically to wire 708 at flat bottom 710. For example, substrate 702 is attached to wire 708 using one of resistance spot welding, laser welding, brazing, or other attachment processes known in the art. Tungsten wire 708 incandesces and directly heats substrate 702 and emissive material 704. In this example, substrate 702 and tungsten wire 708 are also electrically connected. In another embodiment, a simple incandescing tungsten wire having a coating of emissive material, but with no cathode substrate attached, is used for electron emission. Materials other than tungsten may be used and formed other than as wire, without departing from the scope hereof. For example, other resistive materials having suitable high-temperature mechanical strength may be adapted for heating substrate 702 and emissive material 704, and may be formed as wire, plate, ribbon, tape, bar, or any other physical configuration.
Emissive material 704 is for example formed by applying a “Triple Carbonate” (predominantly a Barium Carbonate mixture) to substrate 702. The Triple Carbonate is converted, under vacuum, to a BaO layer. Emissive material is carefully patterned onto substrate 702 in order to maximize uniformity, and thereby does not require the use of additional electron-optics to achieve uniformity.
A current is passed through tungsten wire 708 (i.e., by applying a voltage differential between wire 708(A) and wire 708(B)) such that substrate 702 and emissive material 704 are directly heated from wire 708. The current through tungsten wire 708 may be a direct current (DC), an alternating current (AC), or a pulsed current.
By having substrate 702 in direct intimate contact with wire 708, cost and complexity are minimized and a quick start-up time of the associated light emitting device is realized. Thus, the lamp may appear to turn on ‘instantly’.
In one example of operation, substrate 702 and its coating of emissive material 704 are heated to 900 C by tungsten wire 708, and an electric field 712 is created proximate emissive surface 706. Electrons, shown as arrows 714, emitted from emissive surface 706 result in a total cathode emitter current of approximately 1 mA. The total cathode emitter current may be within a range of between 0.1 mA and 5 mA without departing from the scope hereof. Emitted electrons are allowed to spread, without any focus, into a flood beam having diameter of approximately 100 mm when it strikes a cathodoluminescent phosphor (e.g., phosphor layer 776,
A first metal heater bar 744 attaches to a wire portion 708(A) of heating element 737 and a second metal heater bar 746 attaches to a wire portion 708(B) of heating element 737. Attachment of wire portions 708(A) and 708(B) is by one of resistance spot welding, laser welding, brazing, or other known methods of connecting. Metal of components 732, 734, 736, 738, 740, 744 and 746 may be one of more of stainless steel, molybdenum and nickel, Inconel® and other materials having similar properties.
Metal guard ring 732 is held at substantially the same potential as, or at a more negative potential than, cathode 700. Metal guard ring 732 shields the sides of cathode 700 from undesired electrical fields. Metal extraction ring 734 is held at a potential higher than that of cathode 700 to form an electric field 712 that causes electrons to be emitted from emissive surface 706 of cathode 700 (see
Metal components 732, 734, 736 and 744 are secured in position by two opposed dielectric attachment bars (not shown in
Assembly 730 functions as an electron source within a light emitting device. Optionally, metal guard ring 732 may be omitted where greater precision is used in forming emissive material 704 on substrate 702. Further, metal components may also be made three dimensional in order to minimize size, for example. Three dimensional shaping of components may also be used to optimize electric field confinement. Metal components 732, 734, 736 and 744 (both flat and three dimensional) may be manufactured inexpensively from sheet metal using a stamping technology.
Envelope 772 has a face portion 773 through which light is emitted during operation of light emitting device 770 when used to form a light emitting device (e.g., light emitting device 400,
Base section 794 provides electrical connectivity (shown as an Edison thread in this example) to an external source of electricity and may include one or more power converters 796 (and/or other electronic circuitry) for supplying appropriate potentials to spring 788, cathode 700, metal guard ring 732, metal extraction ring 734, and metal field-forming ring 736, and thereby operating light emitting device 770 to produce light.
Envelope 772 has a face portion 773 through which light is emitted during operation of light emitting device 770. An inner surface of face portion 773 of enclosure 772 is coated with a phosphor layer 776. Envelope 772 has a glass feedthrough base 780 that is formed with a plurality of feedthrough conductors 810 (not all conductors are shown for clarity of illustration) that pass from the inside to the outside of envelope 772. As shown in
Two-point sprung anode contact 802, 788 is shown electrically contacting, at position 798, a mirror anode 774 formed within envelope 772 over phosphor layer 776 and towards a neck 790 of envelope 772. More particularly, two-point sprung anode contact 802, 788 is compressed, inserted into neck 790 and the compression released such that dimples 844 and 846 of anode contact 802, 788 touch a painted graphite ring (i.e., a DAG ring formed with a water-based graphite paint, known in the art) painted around the inside of neck 790, including at position 798.
Base section 794 provides electrical connectivity (shown as an Edison thread in this example) to an external source of electricity and may include one or more circuits 796 (e.g., power converters) for supplying appropriate potentials to two-point sprung contact 802, 788 and assembly 804, and thereby operating light emitting device 770 to produce light.
Of note, contact 802, 788 is substantially perpendicular to neck 790 and rod 820 and provides mechanical support to rod 820 with respect to neck 790. Contact 802 has only two, diametrically opposed, contacts (i.e., at dimples 844, 846) with neck 790 and requires substantially no force from rod 820 to maintain contact with anode 774. When getter ring 826, 786 is included, rod 820 is bent such that getter ring 826, 786 positions the getter material (e.g., an evaporable barium getter material) out of the line of flight of electrons emitted from assembly 804 towards phosphor layer 776. This configuration also allows the getter material to be evaporated against walls of envelope 772 and thereby isolates the getter evaporant away from other interior parts of device 770 where it could potentially cause unwanted side-effects, such as electrical shorts.
The use of two-point sprung contact 802 within light emitting device 770 is believed to be unique for at least the following reasons. Spring 842 is substantially perpendicular to the axis of neck 790. The force applied by spring 842 against enclosure 772 is substantially derived from spring 842 such that spring 842 holds its position within device 770 without creating forces on rod 820 or feedthrough conductor 810(A) (or any other conductor 810 or part of assembly 804). However, spring 842 does maintain position of rod 820 (and optional getter ring 826) within envelope 772. This allows rod 820 and spring 842 to be configured within device 770 as far as possible from an electron source of assembly 804, thereby aiding in avoiding arc-shorts where potential differences are greatest (i.e., between cathode and the anode which derives its potential from two-point strung anode contact 802) and also avoids unwanted electric fields that might distort the flood electrons; trajectories from assembly 804 towards phosphor layer 776.
The two-point sprung anode contact 802 and getter ring 826 (when included) are highly suitable to large-scale manufacturing by being simple, low cost, robust, and reliable. Optionally, graphite (not shown) may be applied to envelope 772 at position 798 to ensure good contact between two-point sprung anode contact 802 and anode 774.
Tool 860 includes a compression tube 862 and a plunger 870. Compression tube 862 has a front portion 864 that has a smaller diameter than neck 790 of envelope 772 and thereby allows insertion of compression tube 862 into neck 790 as shown in
As shown in
Since front section 872 of plunger 870 is sprung and substantially the same diameter and shape as two-point sprung anode contact 802, minimal force is exerted onto rod 820 during compression and insertion of two-point sprung anode contact 802 into neck 790.
Glass base 780 is shown with eight feedthrough positions as indicated by applied support glass bumps 904 that are symmetrically spaced around evacuation tube 792. Six of the eight positions each support one of feedthrough conductors 810. Other spacing may be used without departing from the scope hereof. In particular, conductor 810(A) provides electrical connectivity to mirror anode 774,
In
As shown in
Within light emitting device 770, an acceleration voltage of approximately fifteen thousand volts is applied by the power supply circuits 796(A) and 796(B) between mirror anode 744 and cathode 700, with the cathode 700 negative with respect to anode 744.
In an embodiment of light emitting device 770, cathode 700 operates at highly-negative acceleration voltages, typically on the order of sixteen thousand volts, and mirror anode 774 is at ground potential. This mode of operation eliminates electrostatic attraction (of dust, etc.) to the outside of the lamp because there is no potential drop, nor electric field, proximate to the surface of envelope 772 or base section 794. This configuration also allows for solid, reliable positioning of electron gun or multiform assembly 730 directly on feedthrough conductors 810 of glass base 780, thereby lowering manufacturing costs by increasing throughput, maximizing robustness and reliability of light emitting device 770, and allowing for maximum dielectric isolation within glass base 780.
In an alternative embodiment, in order to simplify power supply circuits 796(A) and 796(B), cathode 700 is near ground potential, and anode 744 is held at a positive potential of fifteen thousand volts. In this embodiment, an optional transparent conductive layer, such as a thin layer of indium tin oxide, may be applied to an exterior surface of the face 773 of the envelope to bleed off static charges accumulating thereon and avoid undue accumulation of dust and dirt. In embodiments having a transparent conductive layer on an exterior of the face, this layer may be coupled to a ground connection at the base section 794 through DAG or conductive paint on the outside of the envelope. The DAG or conductive paint is preferably highly resistive to reduce any shock hazards should a lighting fixture into which the lighting device 770 is inserted have been mistakenly wired with the shell of the Edison socket connected to a hot wire instead of neutral.
Heater bars 744 and 746 provide electrical connectivity between conductors 810(B), 810(C) and wire portions 136(A), 136(B), respectively. Further, as shown in
This attachment method is not believed to have been used in any other vacuum device. Specifically, feedthrough conductors 810 are larger (e.g., 1 mm diameter, and may be in a range of 0.5 mm to 2 mm in diameter) than typically used for similar sized lighting devices to provide enough rigidity such that heater bars 744 and 746 are directly attached thereto by spot or laser welding. This eliminates wiring within light emitting device 770. Thus, heater bars 744, 746 provide two mechanical supports and a third support is provided by conductor 810(D) attaching to metal field forming ring 736. This method of attaching multiform assembly 730 to feedthrough conductors 810 of glass base 780 allows for greater rigidity and robustness of the internal parts of light emitting device 770. This attachment method minimizes the overall length of light emitting device 770 and simplifies the manufacturing process, increases operational reliability, lends to high-volume manufacturing throughput, and lowers the cost.
This method of attaching multiform assembly 730 to feedthrough conductors 810 of glass base 780 also allows for isolation of all the low-voltage feedthrough conductors (which typically operate at negative kV values) to positions of furthest spacing from feedthrough conductors 810 connecting to mirror anode 774, which also has its feedthrough conductor 810(A) in the same glass base. Such isolation of conductors 810 with great potential differences substantially increases reliability of light emitting device 770 by averting potential electrical arcs between these feedthrough conductors and minimizes any electric field within glass base 780 to minimize the danger of electromigration within glass base 780.
This attachment method, and feedthrough conductor configuration, also allows for judicious isolation of the low-voltage signals from all external surfaces of light emitting device 770. Such ability to isolate the kV signals allows for substantial safety assurance for users of light emitting device 770. It also prevents forming any significant electric fields between the low-voltage signals and the grounded exterior of the lamp. Such field prevention is important to eliminate dust, eliminate electrostatic attraction of ambient insects (or moisture, or ionized materials or debris, etc.) and eliminate glass failures through electromigration in envelope 772.
The use of thicker feedthrough conductors 810 on glass base 780 works well with automated equipment that is useful for high-volume manufacturing. The clustering of all feedthrough conductors 810 close to evacuation tube 792 allows all of the (kV-range) low voltages components (e.g., circuits 796) to be safely sealed into potting material 902 in base section 794. As with the interior spacing of conductor 810(A) from conductor 810(D) (i.e., anode to cathode potentials), the same spacing occurs on the exterior of glass base 780 to facilitate dielectric isolation of the significantly-differing voltages, and thus prevents arc-discharge or plasma formation exterior of glass base 780. It also protects the consumer by facilitating completely insulated electronics and interconnects.
Direct mounted electron source 730 is suitable to large-scale manufacturing by being very simple, low cost, robust, and very reliable. Although glass base 780 is shown with eight feedthrough conductors 810 in the above examples, more or fewer feedthrough conductors 810 may be used without departing from the scope hereof.
For purposes of this document, transparent means that visible light can pass through the object, and includes objects generally known as both translucent and transparent.
Changes may be made in the above methods and systems without departing from the scope hereof. It should thus be noted that the matter contained in the above description or shown in the accompanying drawings should be interpreted as illustrative and not in a limiting sense. The following claims are intended to cover all generic and specific features described herein, as well as all statements of the scope of the present method and system, which, as a matter of language, might be said to fall there between.
The present application claims priority to U.S. Provisional Patent Application No. 61/164,861; U.S. Provisional Patent Application No. 61/164,865; U.S. Provisional Patent Application No. 61/164,858; U.S. Provisional Patent Application No. 61/164,866 and U.S. Provisional Patent Application No. 61/164,852, all of which were filed on 30 Mar. 2009, and are hereby incorporated herein by reference.
Filing Document | Filing Date | Country | Kind | 371c Date |
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PCT/US10/29142 | 3/30/2010 | WO | 00 | 2/24/2012 |
Number | Date | Country | |
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61164858 | Mar 2009 | US | |
61164866 | Mar 2009 | US | |
61164865 | Mar 2009 | US | |
61164852 | Mar 2009 | US | |
61164861 | Mar 2009 | US |