Various applications exist for the separation of gaseous mixtures. For example, the separation of nitrogen from atmospheric air can provide a highly concentrated source of oxygen. These various applications include the provision of elevated concentrations of oxygen for medical patients and flight personnel. Hence, it is desirable to provide systems that separate gaseous mixtures to provide a concentrated product gas, such as a breathing gas with a concentration of oxygen.
Several existing product gas or oxygen concentrating systems and methods, for example, are disclosed in U.S. Pat. Nos. 4,449,990, 5,906,672, 5,917,135, 5,988,165, 7,294,170, 7,455,717, 7,722,700, 7,875,105, 8,062,003, 8,070,853 and U.S. patent application Ser. Nos. 12/106,861, 61/661,260, 61/750,517, 13/790,312, and 13/790,473, which are commonly assigned to Invacare Corporation of Elyria, Ohio and fully incorporated herein by reference.
In one embodiment, a system for producing a product gas is provided. The system includes, for example, at least one separation bed to separate adsorbable components from a gas source, a valving means to selectively direct gas from the gas source to the at least one separation bed, at least one sensing device associated with the at least one separation bed to sense the progress of an adsorption zone within the separation bed, and a controller. The controller includes logic to read the output of the at least one sensing device and control the gas separation process based on the progress of the adsorption zone.
The descriptions of the invention do not limit the words used in the claims in any way or the scope of the claims or invention. The words used in the claims have all of their full ordinary meanings.
In the accompanying drawings, which are incorporated in and constitute a part of the specification, embodiments of the invention are illustrated, which, together with a general description of the invention given above, and the detailed description given below, serve to exemplify embodiments of this invention.
As described herein, when one or more components are described or shown as being connected, joined, affixed, coupled, attached, or otherwise interconnected, such interconnection may be direct as between the components or may be in direct such as through the use of one or more intermediary components. Also as described herein, reference to a member, component, or portion shall not be limited to a single structural member, component, element, or portion but can include an assembly of components, members, elements, or portions. Furthermore, any one or more components may be integrated into common housings, assemblies or other components.
Illustrated in
System 100 includes a housing 102 having a front portion 104 and a rear portion 106. Front and rear portions 104 and 106 include a plurality of openings for the intake and discharge of various gases such as, for example, the intake of room air and the discharge of nitrogen and other gases in the case of oxygen concentration. System 100 generally intakes room air, which is mostly comprised of nitrogen and oxygen, and separates the nitrogen from the oxygen. The oxygen may be stored in one or more storage tanks and the nitrogen is discharged back into the room air. For example, the oxygen gas may be discharged through port 108 to a user, such as a patient, through tubing and nasal cannula. In another embodiment, the oxygen gas may be discharged through a supplemental port to an oxygen cylinder filling device, such as HOMEFILL® that is manufactured by Invacare Corp. of Elyria, Ohio, USA.
With reference to
A cross-over valving means 320, which can include various combinations and types of valves, such as, for example, a four-way valve 321, to selectively and cyclically connect the inlet end of one of the two separation beds 310, 312, in an alternating fashion, during a production/fill phase or cycle with a source of the gas mixture, for example, air under pressure supplied from a compressor or pressure source 322, while the other separation beds 310, 312 is vented to atmosphere during a purge phase or cycle. The cross-over valving means 320 selectively connects one of the separation beds 310, 312 in fluid communication with an air pump or compressor 322, which supplies air under about 15-30 pounds per square inch, during the fill phase. As used herein, “fluid communication” refers to means allowing flow of the appropriate gases. Another pressure or vacuum source (not shown) can also be used during the purge phase to enhance evacuation of the purging bed. The compressor 322 is connected to a drive motor 323.
A solenoid or other cross-over valve actuating means can selectively cause the cross-over valving means 320 to move alternately between first and second positions. In the first position, illustrated in
As the gas mixture is introduced through a separation bed inlet 315, 317 to an adsorbed, gas-free or regenerated separation bed 310, 312, an adsorption zone of finite, relatively large size is formed. This adsorption zone is a region of the separation bed 310, 312 in which the full capacity of the adsorbent to hold the adsorbable components has not been reached. The composition of the gas in the voids of the zeolite varies from substantially pure primary-product gas at the separation bed outlet 314, 316, to the ambient gaseous mixture composition at the separation bed inlet 315, 317.
This adsorption zone moves from the separation bed inlet 315, 317 toward a separation bed outlet 314, 316 with a velocity significantly less than the superficial gas velocity in the separation bed 310, 312. When the adsorption zone reaches the separation bed outlet 314, 316, adsorbable components begin to flow through the separation bed outlet 314, 316 into the nonadsorbable primary product stream. This time is hereinafter referred to as the “breakthrough.” For a given gaseous composition, the breakthrough is defined by the size and configuration of the bed container as well as the packing configuration of the molecular sieve and the flow rate and bed gas pressure. The bed container configuration is generally cylindrical, while the output volume rate can vary from about 0 to 6 liters per minute, and more specifically 3, 5, and 6 liters, respectively. The breakthrough is the time required for the diffusion reaction as the nitrogen saturates and is weakly bonded to the separation bed 310, 312 separation media.
Before breakthrough occurs, primary product-enriched bed gas in the zeolite voids varies from a higher primary product gas concentration at the separation bed outlet 314, 316 to a lower concentration at the separation bed inlet 315, 317. When breakthrough occurs, the primary product gas concentration at the separation bed outlet 314, 316 begins to shift to the lower concentration found at the separation bed inlet 315, 317, since the adsorption zone within the bed 310, 312 is nearly or completely filled. In the illustrated embodiment, the primary product-enriched bed gas is about 80 percent or more primary product at breakthrough. While adsorption is occurring in one separation bed 310, 312, the adsorbable components adsorbed by the separation media of the other separation bed 310, 312 are purged from the other separation bed 310, 312 because of the drop in pressure due to atmospheric venting and because of exposure to relatively pure product gas from the first separation bed 310, 312.
The control means 350 causes the cross-over valving means 320 to alternate between its first and second positions for the appropriate period during each cycle segment. A cycle segment can be either the product gas generation (e.g., fill) cycle or the purge cycle. The cycle duration is selected or determined such that each separation bed 310, 312 is connected with the source of air for a duration, which, for example, may be equal to or less than the breakthrough time.
The first separation bed 310 is connected with a reservoir or product tank 330 by way of a first valve 332, which may be, in this embodiment, a check valve or other unidirectional valving means. Product tank 330 may be a single tank or a plurality of individual tanks. The first valve 332 can permit the primary product gas from the first separation bed 310 to flow into the reservoir or product tank 330 when product gas pressure in the first separation bed 310 exceeds the pressure of product gas in the reservoir or product tank 330. The first valve 332 can prohibit the product gas from flowing from the reservoir or product tank 330 when the pressure in the first separation bed 310 is lower than in the reservoir or product tank 330. For example, the first valve 332 can impose a 1.5 psi bias such that flow is only permitted when the pressure in the first separation bed 310 exceeds the pressure in the reservoir or product tank 330 by 1.5 psi. The product gas concentration and pressure relative to the product tank 330 may also be read by sensors 343 and 345
The second separation bed 312 is connected with the reservoir or product tank 330 by way of a second valve 334, which may be, in this embodiment, a check valve or other unidirectional valving means. The second valve 334 again can provide for unidirectional flow of the primary product gas through product conduit 346 from the second separation bed 312 to the reservoir or product tank 330. In some embodiments, the system 300 may include another valve or union 336. In other embodiments, the separation beds 310 and 312 can be structurally integrated with the product tank 330, such as described in U.S. Patent Application Publication No. 2008/0257145, which is hereby fully incorporated by reference for this and other features.
In this embodiment, a pressure equalization flow path 340 extends between separation bed outlets 314 and 316 of the first and second separation beds 310 and 312. An equalization device or means 342, which can be a valve or similar flow control device, is either open or closed to selectively permit or prevent gas flow through the equalization flow path 340. An equalization valve 342 can be used to equalize the gas pressure and/or the gas concentration on either side of the equalization valve 342. A control means 350, which can be a microprocessor executing logic or software, cyclically can cause the cross-over valve actuating means (e.g., solenoids) 320 and the equalization valve 342 to be operated. The control means 350 can periodically and cyclically enable an equalization valve actuator which can also be a solenoid.
In this context, the gas mixture is supplied up to 32 pounds of pressure to the first separation bed 310, 312. Concurrently, the second separation bed 310, 312 (i.e., a “used” bed) is vented to atmosphere to cause purging of the nitrogen-enriched molecular sieves. Before the breakthrough time, the equalization valve 342 can be opened, allowing primary product-enriched gas from the filling first bed 310, 312 to flow into the evacuated second bed 310, 312. During the equalization period, one bed 310, 312 is or has been evacuated and the other bed 310, 312 has just reached the pressure set point which can drive flow between the beds 310, 312. The equalization flow is of high oxygen content so that the first product gas to pass into the product tank 330 from the newly filling bed 310, 312 is essentially product gas rather than vent gas.
After the primary product-enriched gas from the first bed 310, 312 is evacuated through the second bed 310, 312, the cross-over valving means 320 can be actuated to reverse its position. Actuating the cross-over valving means 320 discontinues supplying of the gaseous mixture to the first bed 310, 312 and commences evacuating it and concurrently discontinues evacuating the second bed 310, 312 and commences supplying it with the gaseous mixture.
Subsequent to the actuation of the cross-over valving means 320, the equalization valve 342 can remain open to continue allowing a purge supply of product-enriched gas to flow into the second bed 310, 312. This equalizes the pressure and/or concentration of gas which is supplied to the product tank 330 since the cycling is sequenced so that the product gas flows into the product tank 330 before breakthrough. Subsequently, the equalization valve 342 closes and terminates the flow of primary-product gas between the beds 310, 312.
In the second segment of the cycle, the pressure in the second bed 310, 312 increases, approaching the 32 psi gas mixture source pressure. Concurrently, the pressure in the first bed 310, 312 decreases approaching atmospheric pressure. Before the secondary product molecules have traversed the second bed 310, 312, the equalization valve 342 can be opened, allowing the primary product-enriched gas in the zeolite voids of the second bed 310, 312 to flow to the first bed 310, 312. While the primary product-enriched gas is flowing to the first bed 310, 312, the cross-over valving means 320 can be actuated. Actuating the cross-over valving means 320 discontinues the evacuation of the first bed 310, 312 and commences supplying the gaseous mixture and concurrently discontinues supplying the gaseous mixture to the second bed 310, 312 and commences evacuating it. Subsequent to actuating the cross-over valving means 320, the equalization valve 342 can be closed, terminating the pressure equalizing flow of the primary product-enriched gas between the beds 310, 312. The steps are cyclically repeated to provide continuing fractionating of the primary product gas from the source gas mixture.
In one embodiment, the mechanism triggering the cross-over valving means 320 and/or the equalization device 342 is the progress of the adsorption zone within each separation bed 310, 312, as sensed by sensing device 352. Based on the readings of sensing device 352 (e.g., oxygen concentration, nitrogen concentration, temperature, pressure, flow rate, etc.), the triggering mechanism can appropriately actuate cross-over valving means 320 and/or equalization device 342 when the adsorption zone reaches or nearly reaches the separation bed outlet 314, 316. The triggering mechanism may also be based on sampling over multiple fill cycles the average time it takes the adsorption zone to reach the separation bed outlet 314, 316. Further, the triggering mechanism can be based on a percentage of the average time that is less than the full time.
In yet other embodiments, the above triggering mechanism can further be combined with pressure, such as a pressure set point or set point range, associated with a bleed line from the product tank 330 as is used in a pressure-based control cycle, or it can be based strictly on a input gas residence time from the product-producing bed 310, 312, such as in a timing cycle-based control cycle. In accordance with another embodiment of the invention, the control cycle can utilize variable pressure in order to achieve an input gas residence time within a defined range based upon a projected breakthrough time.
In these embodiments, the progress of the adsorption zone towards the active separation bed outlet 314, 316 can be sensed through a variety of sensing devices or means 352 (e.g., oxygen concentration, nitrogen concentration, temperature, pressure, flow rate, etc.). For an oxygen producing separation bed 310, 312, when the adsorption zone reaches the separation bed outlet 314, 316, a significant drop in oxygen concentration (or a significant rise in nitrogen concentration) can be sensed. Similarly, when the adsorption zone reaches the separation bed outlet 314, 316, a rise in temperature and/or pressure can be sensed. This information is read by control means 350 through sensing device or means 352 and used to adjust the pneumatic components of the system such as, for example, the compressor 322, the cross-over valving means 320, the equalization device 342, etc., as described above. Other components can also be controlled including, for example, the speed of the compressor 322.
In another embodiment, as shown
As the separation bed 310 approaches breakthrough, as sensed by the sensing device or means 352, the control means 350 can change the position of valves 324, 326, and 328, such that valve 324 prevents the source gas mixture from entering the separation bed 310, valve 328 prevents the product gas from flowing to the product tank 330, and valve 326 connects the separation bed inlet 315 to the atmosphere to allow the separation bed to vent nitrogen as the pressure within the separation bed 310 equalizes. In another embodiment, as shown by the dashed flow path, valves 324 and 328 may also direct the gas mixture to the separation bed outlet 314 to assist in purging the nitrogen from the separation bed 310 during the purge cycle. Once separation bed 310 is purged, the valves 324, 326, 328 return to their fill cycle orientation to begin the next fill cycle.
It should be appreciated that the adsorption and desorption process is common to many types and configurations of gas concentrating systems, for example, as described in U.S. patent application Ser. No. 13/790,312, which is incorporated herein by reference in full. In addition, the feedback and control associated with the sensing devices (e.g., 352) described herein are applicable to these gas concentration systems.
In one embodiment, as shown in
In this embodiment, appropriate control valving may be used to control from which separation bed 310, 312 sensing device or means 352 is obtaining a reading. The control valving may be internal to sensing device or means 352 or may be in sensing paths 402 and 404.
While sensing device or means 352 can be any suitable sensor, in one embodiment it can be an oxygen concentration sensor or other type of oxygen sensor. Additionally, sensing device or means 352 can be a nitrogen sensor. Further still, sensing device or means 352 can be a temperature sensor that measures temperature differences as the adsorption zone travels through the separation bed. Any other type of sensor suitable for indicating the progress of the adsorption zone within a separation bed 310, 312 may be utilized. Moreover, in other embodiments, a plurality of sensors and sensor types can be used.
Still referring to
Similarly, referring to
Referring to
In one example, initial control parameters 502 include the timing sequence of equalization device 342. The control means 350 uses those parameters to initially control when and for how long equalization device 342 allows product gas to flow from one separation bed 310, 312 to another bed 310, 312, as described above. After one or more fill/purge cycles, control means 350 reads the data from sensing device or means 352, which may be an oxygen concentration sensor associated with the separation bed outlet 314, 316, and uses that data to adjust the timing and/order duration of the opening and closing of equalization device 342 during a fill/purge cycle. Control means 350 can use that data from sensing device or means 352 upon every fill/purge cycle or intervals defined by one or more fill/purge cycles, time, or any other sequence.
Similarly, referring to
In this manner, for example, the sensing device 352 can additionally identify when the adsorption zone is approaching the separation bed inlet 315, 317 during a purge cycle of the separation bed 310, 312. In particular, for example, when the nitrogen concentration level drops, for example, and compared to a particular predetermined threshold, the adsorption zone has returned to its unadsorbed size, the purging bed is considered purged, and is ready for the next fill cycle. Control means 350 can control the various components associated with the fill and purge cycles of systems 700, 700′ to additionally optimize the purge cycle along with optimization of the fill cycle, as mentioned above. In other words, the control means 350 can initiate switching from a purge cycle to a fill cycle after a certain amount of desorption has occurred. In yet other embodiments, the sensing device can be connected portions between the upper and lower sections of a separation sieve bed.
As mentioned above, in this and other embodiments, appropriate control valving may be used to control from which location in the separation bed 310, 312 sensing device or means 352 is obtaining a reading, for example, from sensing paths 702, 704, 706, and 708. The control valving may be internal to sensing device or means 352 or may be in sensing paths 702, 704, 706, and 708.
Any of the above sensing devices or means 352 and their associated sensed locations may be combined in any number of various embodiments. For example,
Referring now to
In block 1002, control logic can read a first set of parameters associated with the control of the gas concentrating system. These parameters can be read, for example, from a memory associated with control means 350. The parameters can include, for example, all the operational settings for the pneumatic and other components of the gas concentrating system, such as, for example, in a two-bed gas concentrating system, crossover valving means 320, equalization device 342, and other controllable devices, such as motors and valves. The data may include timing, sequence, pressure, oxygen concentration, nitrogen concentration and other process or flow settings and subsets of the foregoing. In block 1004, the logic operates the components of the gas concentrating system according to the first set of parameters in order to produce concentrated gas product.
In block 1006, the sensing device or means 352 is read and input into control means 350. As described above, sensing device or means 352 provides information indicative of parameters associated with the separation bed 310, 312, including, for example, the progress of an adsorption zone during a fill cycle or the progress of desorption during a purge cycle. In one example, sensing device or means 352 is monitored to determine when the adsorption zone will reach the outlet 314, 316 or an area proximate to the outlet 314, 316 of a separation bed 310, 312. In this situation, sensing device or means 352 will indicate a change in its reading to indicate, for example, the adsorption zone has reached the outlet 314, 316 of the separation bed 310, 312, thereby producing a decrease in the oxygen concentration and/or increase in the nitrogen concentration measured at that outlet 314, 316. The timing of such an event is used in block 1008 to adjust one or more of the gas concentrating system control parameters, such as, for example, the opening and closing of equalization device 342. Other pneumatic and other components can also be adjusted, such as, for example, the timing of crossover valving means 320. Adjusting one or more of these parameters can result in a more efficient production of product gas from the system.
In block 1010, the adjusted control parameters are stored in memory and used to operate the system's pneumatic and other components according thereto. The logic then loops back to block 1006 to once again read the output of sensing device or means 352. As described above, the logic may loop back to block 1006 after each fill/purge cycle, or after a designated plurality of fill/purge cycles.
In this manner, the gas concentrating system can adjust its operating parameters, for example, based on the characteristics of actual absorption and desorption processes occurring in the separation beds, which may allow the system to account for various other factors affecting the effectiveness and/or efficiency of the absorption and desorption processes, including, for example, ambient temperature, ambient humidity, concentrations/content of source gas, etc. Other factors affecting the effectiveness and/or efficiency of the absorption and desorption processes may include, unanticipated flow impediments, including, for example, flow path obstructions, dirty filters, etc., moisture trapped in separation beds, exhaustion or contamination of separation material, leaking valves, weak pressure and/or vacuum sources, etc. Because these types of factors can affect the absorption and desorption processes, the adjusted parameter set may become quite different than the original parameter set, thereby maximizing the effectiveness, efficiency, etc., of the system in light of many possible conditions unanticipated by the original parameters. In some cases, the original parameter set may be based on ideal conditions, whereas the adjusted parameter set can account for non-ideal conditions. In these situations, the optimum performance of the system may not be possible, however, maximizing the effectiveness, efficiency, etc., of the non-ideal system may still be desirable.
The control or flow logic shown and described herein preferably resides in or on a computer readable medium such as, for example, a Read-Only Memory (ROM), Random-Access Memory (RAM), programmable read-only memory (PROM), electrically programmable read-only memory (EPROM), electrically erasable programmable read-only memory (EEPROM), magnetic disk or tape, and optically readable mediums including CD-ROM and DVD-ROM. Still further, the processes and logic described herein can be merged into one large process flow or divided into many sub-process flows. The order in which the process flows herein have been described is not critical and can be rearranged while still accomplishing the same results. Indeed, the process flows described herein may be rearranged, consolidated, and/or re-organized in their implementation as warranted or desired.
While the present invention has been illustrated by the description of embodiments thereof, and while the embodiments have been described in considerable detail, it is not the intention of the applicants to restrict or in any way limit the scope of the appended claims to such detail. Additional advantages and modifications will readily appear to those skilled in the art. For example, sensing including pressure, flow, and concentration (oxygen and/or nitrogen) can be employed to control the fill and purge cycle times. Furthermore, by using a elements such as, for example, micro-pumps, the entire gas concentrating system can be made smaller, quieter, more compact, having less vibration, and more efficient in terms of energy usage. The system can be powered by one or more batteries or other sources of mobile power. Furthermore, by integrating one or more of the components, modular assemblies can be made assisting in assembly, disassembly and repair of systems. Therefore, the invention, in its broader aspects, is not limited to the specific details, the representative apparatus, and illustrative examples shown and described. Accordingly, departures can be made from such details without departing from the spirit or scope of the applicants' general inventive concept.
This application claims priority to, and the benefits of, U.S. application Ser. No. 14/852,721, filed on Sep. 14, 2015 (Attorney Docket Number 12873/06754), which is a continuation of U.S. application Ser. No. 13/790,826, filed on Mar. 8, 2013 (Attorney Docket Number 12873/06368), which claims the benefit of U.S. provisional application Ser. No. 61/608,874, filed on Mar. 9, 2012 (Attorney Docket Number 12873/06179), which is incorporated by reference herein in full.
Number | Date | Country | |
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61608874 | Mar 2012 | US |
Number | Date | Country | |
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Parent | 14852721 | Sep 2015 | US |
Child | 15640680 | US | |
Parent | 13790826 | Mar 2013 | US |
Child | 14852721 | US |